CN108178532A - A kind of method of copper ashes flotation tailings comprehensive utilization - Google Patents

A kind of method of copper ashes flotation tailings comprehensive utilization Download PDF

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Publication number
CN108178532A
CN108178532A CN201711360502.5A CN201711360502A CN108178532A CN 108178532 A CN108178532 A CN 108178532A CN 201711360502 A CN201711360502 A CN 201711360502A CN 108178532 A CN108178532 A CN 108178532A
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China
Prior art keywords
tailings
magnetic separation
copper ashes
flotation tailings
comprehensive utilization
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Pending
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CN201711360502.5A
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Chinese (zh)
Inventor
李博
胡建杭
魏永刚
王�华
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Kunming University of Science and Technology
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Kunming University of Science and Technology
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Priority to CN201711360502.5A priority Critical patent/CN108178532A/en
Publication of CN108178532A publication Critical patent/CN108178532A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/14Cements containing slag
    • C04B7/147Metallurgical slag
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03CMAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C1/00Magnetic separation
    • B03C1/02Magnetic separation acting directly on the substance being separated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/38Preparing or treating the raw materials individually or as batches, e.g. mixing with fuel
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/38Preparing or treating the raw materials individually or as batches, e.g. mixing with fuel
    • C04B7/42Active ingredients added before, or during, the burning process
    • C04B7/421Inorganic materials
    • C04B7/424Oxides, Hydroxides
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00Hydraulic cements
    • C04B7/36Manufacture of hydraulic cements in general
    • C04B7/43Heat treatment, e.g. precalcining, burning, melting; Cooling
    • C04B7/44Burning; Melting
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/10Production of cement, e.g. improving or optimising the production methods; Cement grinding

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention discloses a kind of methods of copper ashes flotation tailings comprehensive utilization, belong to technical field of resource comprehensive utilization.The present invention crushes copper ashes flotation tailings, fine grinding;Under the conditions of magnetic separation strength is 200 ~ 250mT, magnetic separator separation Fe is carried out3O4Obtain magnetic separation of iron ore concentrate and magnetic separation tailings;Processing is dried in magnetic separation tailings;Quick lime is added in magnetic separation tailings and is uniformly mixed, then is placed in 3 ~ 5h of progress high temperature sintering processing under the conditions of temperature is 900 ~ 1100 DEG C and obtains clinker.The synthetical recovery of the achievable copper ashes flotation tailings high added value of the present invention.

Description

A kind of method of copper ashes flotation tailings comprehensive utilization
Technical field
The present invention relates to a kind of methods of copper ashes flotation tailings comprehensive utilization, belong to technical field of resource comprehensive utilization.
Background technology
More than 90% enterprise carries out Copper making using thermal process in the world, can a large amount of copper of output in copper pyrometallurgy process Slag(1 ton of copper by-product, 2~3 tons of copper ashes), including smelting slag, blowing slag, refining slag, Copper in Slag is about 3~6%.Contain for slag The problem of copper is higher, most domestic cupper smelting recycle copper using floatation process, which is the skill of current comparative maturity Art.Copper ashes flotation can generate a large amount of flotation tailings, and flotation tailings copper content is 0.2~0.4%, without the value of recycling copper.
The common processing method of flotation tailings is stockpiling, but stockpiling can occupy a large amount of soils, and tailings belongs to solid waste Object, there are some potential safety problemss.Copper ashes flotation tailings can as production cement, the additive of the construction materials such as concrete, Cement production enterprise can be inexpensively sold to, but most enterprises to flotation tailings and lose interest in.Exist for copper ashes flotation tailings Yield it is big, it is difficult, pollution environment the problems such as, with reference in copper ashes flotation tailings contain a large amount of valuable metal iron, part expert The technique that scholar proposes copper ashes flotation tailings recycling iron.Liu Yu et al. using magnetic separation roughing, regrind, magnetic separation is selected, reverse flotation etc. Technique carried out from copper ashes nominal group process recycle iron ore concentrate and coal separation heavymedia separation experiment, can obtain yield for 10.24 %, The qualified iron ore concentrate and yield that Iron grade is 51.56 % are 17.66 %, Iron grade is 53.38 %, density is 4.35 g/cm3Choosing Coal dense media.Chinese patent application No. is 201510231002.6 discloses a kind of copper smelting-furnace slag flotation mining tailing iron Technique, copper flotation tailing by low intensity magnetic separation, reverse flotation, scan, it is dense, filtering method recycle ferrous metal resource.This method work Skill is complicated, flow is longer, has only recycled iron resource, and there is no realize comprehensive utilization of resources.
Invention content
For existing copper slag flotation tailings comprehensive utilization technique problem, the present invention provides a kind of copper ashes flotation tailings synthesis profit Method, the valuable component that the method for the present invention can be in Recovering Copper slag flotation tailings realize that the height of copper ashes flotation tailings is attached Value added, inexpensive, high efficiency utilizes.
A kind of method of copper ashes flotation tailings comprehensive utilization, is as follows:
(1)Pretreatment:Copper ashes flotation tailings is crushed, is finely ground to grain size as 0.1 ~ 0.4mm;
(2)Under the conditions of magnetic separation strength is 200 ~ 250mT, by step(1)The copper ashes flotation tailings of pretreatment carries out magnetic separator Detach Fe3O4Obtain magnetic separation of iron ore concentrate and magnetic separation tailings;Processing is dried in magnetic separation of iron ore concentrate and magnetic separation tailings respectively;
(3)Quick lime is added to step(2)It is uniformly mixed in the magnetic separation tailings of drying process, then it is 900 ~ 1100 to be placed in temperature 3 ~ 5h of high temperature sintering processing is carried out under the conditions of DEG C and obtains clinker;
The step(3)The addition of middle quick lime is the 20 ~ 30% of magnetic separation tailings quality;
It is calculated in mass percent, the step(1)Cu accounts for 0.2 ~ 0.4%, Fe and accounts for 40 ~ 50%, SiO in copper ashes flotation tailings2Account for 25 ~ 30%, surplus CaO, MgO and Al2O3;The object of Fe is mutually Fe3O4And Fe2SiO4
CaOSiO in the clinker2、Al2O3、Fe2O3Gross mass percentage be not less than 96%;
It is calculated in mass percent, Fe in the magnetic separation of iron ore concentrate3O4Content be not less than 55%, Fe3O4The rate of recovery be not less than 99%。
Beneficial effects of the present invention:The method of the present invention can be in Recovering Copper slag flotation tailings valuable component, realize copper The comprehensive utilization of slag flotation tailings high added value, low cost, short route;Metallurgical solid waste resource clean and effective is solved to utilize Problem.
Specific embodiment
The present invention is described in further detail With reference to embodiment, but protection scope of the present invention and unlimited In the content.
Embodiment 1:It is calculated in mass percent, Cu accounts for 0.4%, Fe and accounts for 48%, SiO in copper ashes flotation tailings in the present embodiment2 29% is accounted for, surplus CaO, MgO and Al2O3;The object of Fe is mutually Fe3O4And Fe2SiO4
A kind of method of copper ashes flotation tailings comprehensive utilization, is as follows:
(1)Pretreatment:Copper ashes flotation tailings is crushed, is finely ground to grain size as 0.10 ~ 0.15mm;
(2)Under the conditions of magnetic separation strength is 220mT, by step(1)The copper ashes flotation tailings of pretreatment carries out 3 times points of magnetic separator From Fe3O4Obtain magnetic separation of iron ore concentrate and magnetic separation tailings;Magnetic separation of iron ore concentrate is placed under the conditions of temperature is 160 DEG C and processing is dried;Magnetic Tailings is selected to be placed under the conditions of temperature is 120 DEG C, processing is dried;
(3)Quick lime is added to step(2)It is uniformly mixed in the magnetic separation tailings of drying process, then is placed in temperature as 900 DEG C of items High temperature sintering processing 3h is carried out under part and obtains clinker;Wherein the addition of quick lime is the 27% of magnetic separation tailings quality;
CaOSiO in the present embodiment clinker2、Al2O3、Fe2O3Gross mass percentage be 96.8%;
It is calculated in mass percent, Fe in the magnetic separation of iron ore concentrate3O4Content be 56%, Fe3O4The rate of recovery be 99.3%.
Embodiment 2:It is calculated in mass percent, Cu accounts for 0.3%, Fe and accounts for 45%, SiO in copper ashes flotation tailings in the present embodiment2 30% is accounted for, surplus CaO, MgO and Al2O3;The object of Fe is mutually Fe3O4And Fe2SiO4
A kind of method of copper ashes flotation tailings comprehensive utilization, is as follows:
(1)Pretreatment:Copper ashes flotation tailings is crushed, is finely ground to grain size as 0.25 ~ 0.30mm;
(2)Under the conditions of magnetic separation strength is 250mT, by step(1)The copper ashes flotation tailings of pretreatment carries out 3 times points of magnetic separator From Fe3O4Obtain magnetic separation of iron ore concentrate and magnetic separation tailings;Magnetic separation of iron ore concentrate is placed under the conditions of temperature is 180 DEG C and processing is dried;Magnetic Tailings is selected to be placed under the conditions of temperature is 130 DEG C, processing is dried;
(3)Quick lime is added to step(2)It is uniformly mixed in the magnetic separation tailings of drying process, then is placed in temperature as 1100 DEG C of items High temperature sintering processing 5h is carried out under part and obtains clinker;Wherein the addition of quick lime is the 25% of magnetic separation tailings quality;
CaOSiO in the present embodiment clinker2、Al2O3、Fe2O3Gross mass percentage be 97.5%;
It is calculated in mass percent, Fe in the magnetic separation of iron ore concentrate3O4Content be 58%, Fe3O4The rate of recovery be 99.5%.
Embodiment 3:It is calculated in mass percent, Cu accounts for 0.2%, Fe and accounts for 46%, SiO in copper ashes flotation tailings in the present embodiment2 26% is accounted for, surplus CaO, MgO and Al2O3;The object of Fe is mutually Fe3O4And Fe2SiO4
A kind of method of copper ashes flotation tailings comprehensive utilization, is as follows:
(1)Pretreatment:Copper ashes flotation tailings is crushed, is finely ground to grain size as 0.10 ~ 0.20mm;
(2)Under the conditions of magnetic separation strength is 240mT, by step(1)The copper ashes flotation tailings of pretreatment carries out 2 times points of magnetic separator From Fe3O4Obtain magnetic separation of iron ore concentrate and magnetic separation tailings;Magnetic separation of iron ore concentrate is placed under the conditions of temperature is 170 DEG C and processing is dried;Magnetic Tailings is selected to be placed under the conditions of temperature is 150 DEG C, processing is dried;
(3)Quick lime is added to step(2)It is uniformly mixed in the magnetic separation tailings of drying process, then is placed in temperature as 1050 DEG C of items High temperature sintering processing 4h is carried out under part and obtains clinker;Wherein the addition of quick lime is the 23% of magnetic separation tailings quality;
CaOSiO in the present embodiment clinker2、Al2O3、Fe2O3Gross mass percentage be 97.2%;
It is calculated in mass percent, Fe in the magnetic separation of iron ore concentrate3O4Content be 57%, Fe3O4The rate of recovery be 99.4%.

Claims (3)

  1. A kind of 1. method of copper ashes flotation tailings comprehensive utilization, which is characterized in that be as follows:
    (1)Pretreatment:Copper ashes flotation tailings is crushed, is finely ground to grain size as 0.1 ~ 0.4mm;
    (2)Under the conditions of magnetic separation strength is 200 ~ 250mT, by step(1)The copper ashes flotation tailings of pretreatment carries out magnetic separator Detach Fe3O4Obtain magnetic separation of iron ore concentrate and magnetic separation tailings;Processing is dried in magnetic separation of iron ore concentrate and magnetic separation tailings respectively;
    (3)Quick lime is added to step(2)It is uniformly mixed in the magnetic separation tailings of drying process, then it is 900 ~ 1100 to be placed in temperature 3 ~ 5h of high temperature sintering processing is carried out under the conditions of DEG C and obtains clinker.
  2. 2. the method for copper ashes flotation tailings comprehensive utilization according to claim 1, it is characterised in that:Step(3)Middle quick lime Addition be magnetic separation tailings quality 20 ~ 30%.
  3. 3. the method for copper ashes flotation tailings comprehensive utilization according to claim 1, it is characterised in that:It is calculated in mass percent, Step(1)Cu accounts for 0.2 ~ 0.4%, Fe and accounts for 40 ~ 50%, SiO in copper ashes flotation tailings2Account for 25 ~ 30%, surplus CaO, MgO and Al2O3;The object of Fe is mutually Fe3O4And Fe2SiO4
CN201711360502.5A 2017-12-18 2017-12-18 A kind of method of copper ashes flotation tailings comprehensive utilization Pending CN108178532A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109304256A (en) * 2018-09-11 2019-02-05 湖北大江环保科技股份有限公司 A kind of method of comprehensive utilization of copper metallurgy tailings
CN109534476A (en) * 2018-11-01 2019-03-29 昆明理工大学 A kind of method that copper ashes handles arsenic in nonferrous smelting waste acid
CN109647616A (en) * 2018-11-30 2019-04-19 铜陵有色金属集团股份有限公司 The method of Comprehen Siving Recovery of Magnetite and copper mineral from Cu-S ore flotation tailing
CN110156353A (en) * 2019-05-31 2019-08-23 北方民族大学 A kind of methods and applications of Combined Treatment copper ashes and magnesium slag
CN111760874A (en) * 2020-06-03 2020-10-13 武汉理工大学 Fine separation method of carbide slag iron and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102828039A (en) * 2012-09-07 2012-12-19 白银有色集团股份有限公司 Recycling method of slag of copper melting pool smelting furnace
CN103572059A (en) * 2013-10-11 2014-02-12 张汝华 Method for producing sponge iron and cement by using iron-containing materials through reduction and recovering valuable elements

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102828039A (en) * 2012-09-07 2012-12-19 白银有色集团股份有限公司 Recycling method of slag of copper melting pool smelting furnace
CN103572059A (en) * 2013-10-11 2014-02-12 张汝华 Method for producing sponge iron and cement by using iron-containing materials through reduction and recovering valuable elements

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李磊等: "铜渣综合利用的研究进展", 《冶金能源》 *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109304256A (en) * 2018-09-11 2019-02-05 湖北大江环保科技股份有限公司 A kind of method of comprehensive utilization of copper metallurgy tailings
CN109304256B (en) * 2018-09-11 2020-11-10 湖北大江环保科技股份有限公司 Comprehensive utilization method of copper smelting tailings
CN109534476A (en) * 2018-11-01 2019-03-29 昆明理工大学 A kind of method that copper ashes handles arsenic in nonferrous smelting waste acid
CN109647616A (en) * 2018-11-30 2019-04-19 铜陵有色金属集团股份有限公司 The method of Comprehen Siving Recovery of Magnetite and copper mineral from Cu-S ore flotation tailing
CN109647616B (en) * 2018-11-30 2020-09-08 铜陵有色金属集团股份有限公司 Method for comprehensively recovering magnetite and copper minerals from copper slag flotation tailings
CN110156353A (en) * 2019-05-31 2019-08-23 北方民族大学 A kind of methods and applications of Combined Treatment copper ashes and magnesium slag
CN110156353B (en) * 2019-05-31 2021-04-30 北方民族大学 Method for combined treatment of copper slag and magnesium slag and application
CN111760874A (en) * 2020-06-03 2020-10-13 武汉理工大学 Fine separation method of carbide slag iron and application thereof
CN111760874B (en) * 2020-06-03 2022-07-08 武汉理工大学 Fine separation method of carbide slag iron and application thereof

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Application publication date: 20180619