CN108178258A - Municipal sewage treatment agent - Google Patents
Municipal sewage treatment agent Download PDFInfo
- Publication number
- CN108178258A CN108178258A CN201711248687.0A CN201711248687A CN108178258A CN 108178258 A CN108178258 A CN 108178258A CN 201711248687 A CN201711248687 A CN 201711248687A CN 108178258 A CN108178258 A CN 108178258A
- Authority
- CN
- China
- Prior art keywords
- parts
- treatment agent
- sewage treatment
- potassium
- municipal sewage
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/40—Devices for separating or removing fatty or oily substances or similar floating material
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
- C02F2101/22—Chromium or chromium compounds, e.g. chromates
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
The invention discloses a kind of municipal sewage treatment agent, are prepared by the raw material of following weight parts:45 55 parts of bentonite, 5 15 parts of sepiolite, 35 45 parts of polyacrylamide, 25 35 parts of ferric trichloride, 15 25 parts of potassium phosphate, 5 15 parts of inorganic polymer flocculant.Municipal sewage treatment agent of the present invention, reaction speed is fast, is generated in the process without toxic and harmful gas;Product after reaction is stablized, and will not be further decomposed into noxious material;Efficiently, it is nontoxic, it is safe to the human body before and after reaction, it is corrosion-free to object.
Description
Technical field
The present invention relates to technical field of sewage, and in particular to a kind of municipal sewage treatment agent.
Background technology
Since population increases and economic development, excessive exploitation and unreasonable development to resource and the influence money that generates
A series of problems of source quality, these problems have directly threatened the existence of we and descendants.China is equally faced with
These problems, China are the countries of a water resources shortage, how to alleviate water resources shortage and have become the problems such as pollution
One it is very urgent the problem of.
With the fast development of national economy, city size constantly expands and the fast development of urbanization, urban industry are given up
The total emission volumn of water and sanitary sewage also increases year by year.If untreated waste water, sewage are directly discharged into natural water, not only can
It is serious to pollute the water quality of river, river, lake, library and underground water, and germ, virus, harmful substance and pernicious gas can be largely propagated,
Influence the quality of life and health of the people.
The method of sewage disposal has very much, but common are Physical and chemical method.Wherein, chemical Treatment sewage is people
It is most.And polyacrylamide is exactly most common water treatment agent in chemical method.Polyacrylamide is in water process work
Application in industry mainly includes three original sub-block, sewage disposal and Treatment of Industrial Water aspects.In original sub-block, polyacrylamide
Amine and activated carbon etc. are used cooperatively, cohesion and clarification available for suspended particulate in life water;In sewage disposal, polyacrylamide
Amine can be used and sludge dewatering;In Treatment of Industrial Water, it is mainly used as prescription medicament.In addition, in sewage disposal, using polypropylene
Amide can increase the utilization rate of water reuse cycle.It is existing although polyacrylamide plays very heavy effect in water process
It is typically all to use single polyacrylamide to have method, of high cost, it is inhibited to be applied even more extensively.Secondly, water resource is handled
Pollution problem has a variety of methods such as physics, chemistry, biology, synthesis, but physical method is mostly bad there are treatment effect, handling rate
Instability problem;Biological method processing cost is excessively high, is not suitable for promoting the use of;Mostly using chemical method come treated sewage, still
There is secondary pollution in existing sewage-treating agent, agent formulations, can also have a certain impact to environment.
Invention content
For above-mentioned deficiency in the prior art, it is dirty that the technical problems to be solved by the invention are to provide a kind of city
Water treatment agent.
The present invention seeks to what is be achieved through the following technical solutions:
A kind of municipal sewage treatment agent, is prepared by the raw material of following weight parts:45-55 parts of bentonite, sepiolite 5-
15 parts, 35-45 parts of polyacrylamide, 25-35 parts of ferric trichloride, 15-25 parts of potassium phosphate, inorganic polymer flocculant 5-15
Part.
Preferably, the potassium phosphate be potassium tripolyphosphate, it is potassium pyrophosphate, one or more mixed in tripotassium phosphate
Close object.
It is highly preferred that the potassium phosphate is mixed by potassium tripolyphosphate, potassium pyrophosphate, tripotassium phosphate, described three
PA 800K, potassium pyrophosphate, tripotassium phosphate mass ratio be (1-3):(1-3):(1-3).
Preferably, the inorganic polymer flocculant is aluminium polychloride, in polyaluminium sulfate, polymeric aluminium ferrum silicate
One or more mixtures.
It is highly preferred that the inorganic polymer flocculant is mixed by aluminium polychloride, polyaluminium sulfate, polymeric aluminium ferrum silicate
Close, the aluminium polychloride, polyaluminium sulfate, polymeric aluminium ferrum silicate mass ratio be (1-3):(1-3):(1-3).
The present invention also provides the preparation methods of above-mentioned municipal sewage treatment agent, and each raw material is uniformly mixed to obtain the final product.
Municipal sewage treatment agent of the present invention, reaction speed is fast, is generated in the process without toxic and harmful gas;Generation after reaction
Object is stablized, and will not be further decomposed into noxious material;Efficiently, it is nontoxic, it is safe to the human body before and after reaction, it is corrosion-free to object.
Specific embodiment
With reference to embodiment, the present invention is described further, as described below, is only the preferable implementation to the present invention
Example, not limits the present invention, any person skilled in the art is possibly also with the disclosure above
Technology contents be changed to the equivalent embodiment changed on an equal basis.Without departing from the concept of the present invention, according to the present invention
Any simple modification for being made to following embodiment of technical spirit or equivalent variations, all fall in protection scope of the present invention.
Each raw material introduction of embodiment:
Bentonite, the 200 mesh water process grade bentonites provided using Anji County Yi Guo bentonites factory.
Sepiolite, the 200 mesh sepiolite powders provided using mineral products processing factory of Lingshou County Cigna.
Polyacrylamide, No. CAS:9003-05-8, using Qingdao tide star clearly up to the production of environmental protection and energy saving Science and Technology Ltd.
The anionic polyacrylamide of model QD-522.
Ferric trichloride, No. CAS:7705-08-0.
Potassium tripolyphosphate, No. CAS:13845-36-8.
Potassium pyrophosphate, No. CAS:7320-34-5
Tripotassium phosphate, No. CAS:7778-53-2.
Aluminium polychloride, the 40 mesh aluminium polychlorides provided using Dengfeng City Lu Dian towns Henan and environment-friendly materials factory.
Polyaluminium sulfate, the 40 mesh polyaluminium sulfates provided using triumphant hundred million material for water treatment Co., Ltd of Gongyi City.
Polymeric aluminium ferrum silicate, the 40 mesh polymeric aluminium ferrum silicates provided using Henan Hai Yun Environmental Protection Technology Co., Ltd.
Embodiment 1
Municipal sewage treatment agent raw material:50 parts of bentonite, 10 parts of sepiolite, 40 parts of polyacrylamide, 30 parts of ferric trichloride,
18 parts of potassium phosphate, 9 parts of inorganic polymer flocculant.
The potassium phosphate is 1 in mass ratio by potassium tripolyphosphate, potassium pyrophosphate, tripotassium phosphate:1:1 is stirred
It is even to obtain.
The inorganic polymer flocculant is in mass ratio by aluminium polychloride, polyaluminium sulfate, polymeric aluminium ferrum silicate
1:1:1 is uniformly mixed to obtain.
It is prepared by municipal sewage treatment agent:Each raw material is uniformly mixed to obtain the final product.
Embodiment 2
It is substantially the same manner as Example 1, it differs only in:The potassium phosphate presses matter by potassium pyrophosphate, tripotassium phosphate
Amount is than being 1:1 is uniformly mixed to obtain.
Embodiment 3
It is substantially the same manner as Example 1, it differs only in:The potassium phosphate is pressed by potassium tripolyphosphate, tripotassium phosphate
Mass ratio is 1:1 is uniformly mixed to obtain.
Embodiment 4
It is substantially the same manner as Example 1, it differs only in:The potassium phosphate is pressed by potassium tripolyphosphate, potassium pyrophosphate
Mass ratio is 1:1 is uniformly mixed to obtain.
Embodiment 5
It is substantially the same manner as Example 1, it differs only in:The inorganic polymer flocculant is by polyaluminium sulfate, poly-
It is 1 in mass ratio to close aluminium iron silicate:1 is uniformly mixed to obtain.
Embodiment 6
It is substantially the same manner as Example 1, it differs only in:The inorganic polymer flocculant is by aluminium polychloride, poly-
It is 1 in mass ratio to close aluminium iron silicate:1 is uniformly mixed to obtain.
Embodiment 7
It is substantially the same manner as Example 1, it differs only in:The inorganic polymer flocculant is by aluminium polychloride, poly-
It is 1 in mass ratio to close aluminum sulfate:1 is uniformly mixed to obtain.
Test case 1
Municipal sewage treatment test is carried out to the municipal sewage treatment agent that embodiment 1-7 is prepared.By embodiment 1-7 systems
Standby obtained municipal sewage treatment agent is separately added into from the waste water that same water body takes (COD 354mg/L), municipal sewage treatment
Agent addition is 1g/L (i.e. 1g municipal sewage treatments agent is added in every liter of water), and constant temperature stirs, speed of agitator 140r/min, stirring
25 DEG C of temperature, 0.45 μm of membrane filtration is up to water after processing after settling 30min.
The pollutant concentration in solution before and after the processing is measured according to national standard method, calculates removal rate, detection method is as follows:
TN:GB/T 11894-89
TP:GB11893-89
BOD5:GB/T 7488-87
COD:GB/T 11914-89
Cd2+Pb2+Zn2+Cu2+:GB/T 7475-87
Cr6+:GB/T 7467-87
Hg2+:GB/T 7468-87
Specific test result is shown in Table 1.
Table 1:Municipal sewage treatment agent handles waste water effect table
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (potassium tripolyphosphate, potassium pyrophosphate, tripotassium phosphate compounding) pollution
It is (both arbitrary multiple in potassium tripolyphosphate, potassium pyrophosphate, tripotassium phosphate that object removal rate test result is substantially better than embodiment 2-4
With).Comparing embodiment 1 and embodiment 5-7, embodiment 1 (aluminium polychloride, polyaluminium sulfate, polymeric aluminium ferrum silicate compounding) are dirty
Dye object removal rate test result test result is substantially better than embodiment 5-7 (aluminium polychloride, polyaluminium sulfate, polymer aluminium silicate
Both arbitrary compounding in iron).
Test case 2
The municipal sewage treatment agent that embodiment 1-4 is prepared is added in the sewage that oil content is 1131mg/L, thrown
Dosage 1g/L, constant temperature stirring, speed of agitator 140r/min, 25 DEG C of whipping temp, settle 30min after 0.45 μm of membrane filtration to obtain the final product
Water after processing.Concrete outcome is shown in Table 2.
Table 2:Municipal sewage treatment agent handles oily waste water effect table
Oil removal rate, % |
Embodiment 1 | 95.1 |
Embodiment 2 | 91.6 |
Embodiment 3 | 89.4 |
Embodiment 4 | 89.7 |
Comparing embodiment 1 and embodiment 2-4, embodiment 1 (potassium tripolyphosphate, potassium pyrophosphate, tripotassium phosphate compounding) oil removing
Rate test result is substantially better than embodiment 2-4 (both arbitrary compounding in potassium tripolyphosphate, potassium pyrophosphate, tripotassium phosphate).
Claims (4)
1. a kind of municipal sewage treatment agent, which is characterized in that be prepared by the raw material of following weight parts:45-55 parts of bentonite,
5-15 parts of sepiolite, 35-45 parts of polyacrylamide, 25-35 parts of ferric trichloride, 15-25 parts of potassium phosphate, inorganic polymer flocculation
5-15 parts of agent.
2. municipal sewage treatment agent as described in claim 1, which is characterized in that the potassium phosphate for potassium tripolyphosphate,
One or more mixtures in potassium pyrophosphate, tripotassium phosphate.
3. municipal sewage treatment agent as claimed in claim 2, which is characterized in that the potassium phosphate by potassium tripolyphosphate,
Potassium pyrophosphate, tripotassium phosphate mix, the potassium tripolyphosphate, potassium pyrophosphate, tripotassium phosphate mass ratio be(1-3):(1-
3):(1-3).
4. the municipal sewage treatment agent as described in any one of claim 1-3, which is characterized in that the inorganic polymer wadding
Solidifying agent is aluminium polychloride, one or more mixtures in polyaluminium sulfate, polymeric aluminium ferrum silicate.
Priority Applications (1)
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CN201711248687.0A CN108178258A (en) | 2017-12-01 | 2017-12-01 | Municipal sewage treatment agent |
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CN201711248687.0A CN108178258A (en) | 2017-12-01 | 2017-12-01 | Municipal sewage treatment agent |
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CN108178258A true CN108178258A (en) | 2018-06-19 |
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CN201711248687.0A Pending CN108178258A (en) | 2017-12-01 | 2017-12-01 | Municipal sewage treatment agent |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114349186A (en) * | 2020-12-18 | 2022-04-15 | 淇净环保科技(江苏)有限公司 | Sewage treatment agent and preparation method thereof |
Citations (4)
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CN101327976A (en) * | 2008-07-15 | 2008-12-24 | 南通立源水处理技术有限公司 | Efficient water treatment flocculant |
US20130059949A1 (en) * | 2007-09-12 | 2013-03-07 | Weiguo Cheng | Preflocculation of fillers used in papermaking |
WO2015047279A1 (en) * | 2013-09-26 | 2015-04-02 | Halliburton Energy Services, Inc. | Absorbent clumping animal litter compositions |
CN105776467A (en) * | 2016-03-16 | 2016-07-20 | 徐亚萍 | Preparation method of composite flocculant for wastewater purification |
-
2017
- 2017-12-01 CN CN201711248687.0A patent/CN108178258A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20130059949A1 (en) * | 2007-09-12 | 2013-03-07 | Weiguo Cheng | Preflocculation of fillers used in papermaking |
CN101327976A (en) * | 2008-07-15 | 2008-12-24 | 南通立源水处理技术有限公司 | Efficient water treatment flocculant |
WO2015047279A1 (en) * | 2013-09-26 | 2015-04-02 | Halliburton Energy Services, Inc. | Absorbent clumping animal litter compositions |
CN105776467A (en) * | 2016-03-16 | 2016-07-20 | 徐亚萍 | Preparation method of composite flocculant for wastewater purification |
Non-Patent Citations (2)
Title |
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张玉龙等: "《水处理剂配方设计与实例》", 31 May 2011, 北京:中国纺织出版社 * |
张金廷等译: "《洗涤剂通论》", 31 August 1992, 北京:中国轻工业出版社 * |
Cited By (1)
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CN114349186A (en) * | 2020-12-18 | 2022-04-15 | 淇净环保科技(江苏)有限公司 | Sewage treatment agent and preparation method thereof |
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