CN108147480A - A kind of medicament handled for river pollution and preparation method thereof - Google Patents

A kind of medicament handled for river pollution and preparation method thereof Download PDF

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Publication number
CN108147480A
CN108147480A CN201711486163.5A CN201711486163A CN108147480A CN 108147480 A CN108147480 A CN 108147480A CN 201711486163 A CN201711486163 A CN 201711486163A CN 108147480 A CN108147480 A CN 108147480A
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China
Prior art keywords
parts
powder
cross
cyanobacteria
water
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CN201711486163.5A
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Chinese (zh)
Inventor
张力
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Zhengzhou Yuanran Biology Technology Co Ltd
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Zhengzhou Yuanran Biology Technology Co Ltd
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Priority to CN201711486163.5A priority Critical patent/CN108147480A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/007Contaminated open waterways, rivers, lakes or ponds

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicines Containing Material From Animals Or Micro-Organisms (AREA)
  • Water Treatment By Sorption (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a kind of for medicament of river pollution processing and preparation method thereof, include the raw material of following parts by weight:15 20 parts of 10 16 parts of clay mineral, 4 10 parts of medical stone, 26 35 parts of cross-linked rectorite, 2.4 5 parts of five water aluminum sulfate, 36 parts of nano silicon dioxide, 24 parts of sodium carbonate, 1.6 3 parts of polyacrylamide, 5 10 parts of wooden sodium sulfonate, 35 parts of ferrous sulfate and cyanobacteria.Raw material sources of the present invention are extensive, and preparation process is simple, and the finished product prepared by the interaction between various raw materials only needs to be sprayed at river surface, by agglomerating, precipitating and decompose various pollutants, pollutant in river can be purified, use cost is low, has a vast market prospect.

Description

A kind of medicament handled for river pollution and preparation method thereof
Technical field
The present invention relates to sewage treatment field, specifically a kind of medicament for river pollution processing.
Background technology
In today that people's living standard is continuously improved, quality of life, especially health become focal issue, and water exists A moment can not lack in people's life, and concern health must just pay close attention to essential water during we live.Water is as a kind of Essential resource is considered inexhaustible, nexhaustible always for a long time.Under the driving of this viewpoint, water The quality of environment is more and more severe, shortage of water resources is also increasingly severe, brings a series of ecologies for jeopardizing the survival and development Environmental problem, river pollution are exactly one of which water pollution.River refers to be fed by surface water and groundwater in certain area, warp Often or intermittently along long and narrow lowland flowing water stream, river is the important path of hydrologic cycle on the earth, be silt, salt and Chemical element etc. enters the channel of lake, ocean.
People are using sewage-treating agent and establish the method for artificial swamp come the river of pollution administration, but existing sewage The treatment effect of inorganic agent is bad, and establishing artificial swamp needs huge economic input, and take a long time just take effect, This just brings inconvenience for people's pollution of harnessing a river.
Invention content
The purpose of the present invention is to provide a kind of medicament for river pollution processing, to solve to carry in above-mentioned background technology The problem of going out.
To achieve the above object, the present invention provides following technical solution:
A kind of medicament for river pollution processing includes the raw material of following parts by weight:10-16 parts of clay mineral, wheat meal 4-10 parts of stone, 2.4-5 parts of five water aluminum sulfate, 3-6 parts of nano silicon dioxide, 2-4 parts of sodium carbonate, gathers 26-35 parts of cross-linked rectorite 15-20 parts of 1.6-3 parts of acrylamide, wooden sodium sulfonate 5-10 parts, 3-5 parts of ferrous sulfate and cyanobacteria.
As further embodiment of the present invention:Clay mineral include kaolinite, montmorillonite and attapulgite in one kind or Person is two or more with the arbitrary mixture than mixing.
As further embodiment of the present invention:The granularity of medical stone is 0.48-2.56mm, and the granularity of sodium carbonate is 10-20 Mesh.
The preparation method of the medicament for river pollution processing, is as follows:
Cyanobacteria is carried out water stirring that is broken and adding in 3-4 times of its weight and impregnated 30-45 minutes by step 1, Ran Hou 75-90 degrees Celsius of boiling 60-80 minutes filters and filtrate is carried out distillation and concentration, obtain cyanobacteria concentrate;
Clay mineral, medical stone and cross-linked rectorite are distributed and crush and cross 360-400 mesh sieve, glued by step 2 Native mineral dust, maifanite powder and cross-linked rectorite powder;
Step 3 by clay mineral powder and the water of 2-4 times of its weight, then adds in wooden sodium sulfonate and ultrasound thereto Dispersion 25-30 minutes, obtains the first mixed solution;
Five water aluminum sulfate, nano silicon dioxide and ferrous sulfate are added in reaction kettle and add in total weight by step 4 1.5-2 times of water stirs 40-60 minutes under 30-35 degrees Celsius, then adds in cyanobacteria concentrate, sodium carbonate thereto and gathers Acrylamide is fully reacted, and obtains the first mixture;
Step 5, by the first mixture, the first mixed solution, maifanite powder and cross-linked rectorite powder in high-speed stirred It stirs evenly, stirring product is dried, you can obtain finished product in machine.
As further embodiment of the present invention:The temperature of ultrasonic disperse is 42-54 degrees Celsius in step 3, power 245- 300W, frequency 40-60KHz.
Compared with prior art, the beneficial effects of the invention are as follows:Raw material sources of the present invention are extensive, and preparation process is simple, lead to Finished product prepared by the interaction crossed between various raw materials only needs to be sprayed at river surface, by agglomerating, precipitating and decompose various Pollutant can purify the pollutant in river, and use cost is low, has a vast market prospect.
Specific embodiment
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of medicament for river pollution processing includes the raw material of following parts by weight:10 parts of clay mineral, medical stone 4 Part, 26 parts of cross-linked rectorite, 2.4 parts of five water aluminum sulfate, 3 parts of nano silicon dioxide, 2 parts of sodium carbonate, 1.6 parts of polyacrylamide, 15 parts of 5 parts of wooden sodium sulfonate, 3 parts of ferrous sulfate and cyanobacteria.Clay mineral uses montmorillonite.
The preparation method of the medicament for river pollution processing, is as follows:
Cyanobacteria is carried out water stirring that is broken and adding in 3 times of its weight and impregnated 36 minutes by step 1, then Celsius 81 Boiling 65 minutes are spent, filter and filtrate is subjected to distillation and concentration, obtain cyanobacteria concentrate;
Clay mineral, medical stone and cross-linked rectorite are distributed and crush and cross 380 mesh sieve, obtain clay pit by step 2 Object powder, maifanite powder and cross-linked rectorite powder;
Step 3 by clay mineral powder and the water of 4 times of its weight, then adds in wooden sodium sulfonate and ultrasound point thereto It dissipates 28 minutes, obtains the first mixed solution;
Five water aluminum sulfate, nano silicon dioxide and ferrous sulfate are added in reaction kettle and add in total weight by step 4 1.5 times of water stirs 48 minutes under 32 degrees Celsius, then adds in cyanobacteria concentrate, sodium carbonate and polyacrylamide thereto It is fully reacted, obtains the first mixture;
Step 5, by the first mixture, the first mixed solution, maifanite powder and cross-linked rectorite powder in high-speed stirred It stirs evenly, stirring product is dried, you can obtain finished product in machine.
Embodiment 2
A kind of medicament for river pollution processing includes the raw material of following parts by weight:12 parts of clay mineral, medical stone 6 Part, 30 parts of cross-linked rectorite, 3.2 parts of five water aluminum sulfate, 3.8 parts of nano silicon dioxide, 2.7 parts of sodium carbonate, polyacrylamide 2.1 17 parts of part, 7 parts of wooden sodium sulfonate, 3.6 parts of ferrous sulfate and cyanobacteria.The granularity of medical stone is 0.92mm, and the granularity of sodium carbonate is 10 mesh.
The preparation method of the medicament for river pollution processing, is as follows:
Cyanobacteria is carried out water stirring that is broken and adding in 4 times of its weight and impregnated 36 minutes by step 1, then Celsius 80 Boiling 66 minutes are spent, filter and filtrate is subjected to distillation and concentration, obtain cyanobacteria concentrate;
Clay mineral, medical stone and cross-linked rectorite are distributed and crush and cross 390 mesh sieve, obtain clay pit by step 2 Object powder, maifanite powder and cross-linked rectorite powder;
Step 3 by clay mineral powder and the water of 3 times of its weight, then adds in wooden sodium sulfonate and ultrasound point thereto It dissipates 28 minutes, obtains the first mixed solution;
Five water aluminum sulfate, nano silicon dioxide and ferrous sulfate are added in reaction kettle and add in total weight by step 4 1.8 times of water stirs 55 minutes under 33 degrees Celsius, then adds in cyanobacteria concentrate, sodium carbonate and polyacrylamide thereto It is fully reacted, obtains the first mixture;
Step 5, by the first mixture, the first mixed solution, maifanite powder and cross-linked rectorite powder in high-speed stirred It stirs evenly, stirring product is dried, you can obtain finished product in machine.
Embodiment 3
A kind of medicament for river pollution processing includes the raw material of following parts by weight:14.5 parts of clay mineral, medical stone 8 parts, 32 parts of cross-linked rectorite, 4.5 parts of five water aluminum sulfate, 5.3 parts of nano silicon dioxide, 3.8 parts of sodium carbonate, polyacrylamide 19 parts of 2.6 parts, 9 parts of wooden sodium sulfonate, 4.8 parts of ferrous sulfate and cyanobacteria.Clay mineral includes kaolinite and attapulgite to appoint It anticipates than the mixture of mixing.
The preparation method of the medicament for river pollution processing, is as follows:
Cyanobacteria is carried out water stirring that is broken and adding in 3 times of its weight and impregnated 41 minutes by step 1, then Celsius 86 Boiling 77 minutes are spent, filter and filtrate is subjected to distillation and concentration, obtain cyanobacteria concentrate;
Clay mineral, medical stone and cross-linked rectorite are distributed and crush and cross 380 mesh sieve, obtain clay pit by step 2 Object powder, maifanite powder and cross-linked rectorite powder;
Step 3 by clay mineral powder and the water of 2 times of its weight, then adds in wooden sodium sulfonate and ultrasound point thereto It dissipates 28 minutes, the temperature of ultrasonic disperse obtains the first mixed solution for 48 degrees Celsius, power 280W, frequency 40KHz;
Five water aluminum sulfate, nano silicon dioxide and ferrous sulfate are added in reaction kettle and add in total weight by step 4 1.8 times of water stirs 55 minutes under 33 degrees Celsius, then adds in cyanobacteria concentrate, sodium carbonate and polyacrylamide thereto It is fully reacted, obtains the first mixture;
Step 5, by the first mixture, the first mixed solution, maifanite powder and cross-linked rectorite powder in high-speed stirred It stirs evenly, stirring product is dried, you can obtain finished product in machine.
Embodiment 4
A kind of medicament for river pollution processing includes the raw material of following parts by weight:16 parts of clay mineral, medical stone 10 It is part, 35 parts of cross-linked rectorite, 5 parts of five water aluminum sulfate, 6 parts of nano silicon dioxide, 4 parts of sodium carbonate, 3 parts of polyacrylamide, wooden 20 parts of 10 parts of sodium sulfonate, 5 parts of ferrous sulfate and cyanobacteria.Clay mineral includes kaolinite, montmorillonite and attapulgite arbitrarily to compare The mixture of mixing.The granularity of medical stone is 2.42mm, and the granularity of sodium carbonate is 10 mesh.
The preparation method of the medicament for river pollution processing, is as follows:
Cyanobacteria is carried out water stirring that is broken and adding in 3 times of its weight and impregnated 36 minutes by step 1, then Celsius 82 Boiling 75 minutes are spent, filter and filtrate is subjected to distillation and concentration, obtain cyanobacteria concentrate;
Clay mineral, medical stone and cross-linked rectorite are distributed and crush and cross 400 mesh sieve, obtain clay pit by step 2 Object powder, maifanite powder and cross-linked rectorite powder;
Step 3 by clay mineral powder and the water of 3 times of its weight, then adds in wooden sodium sulfonate and ultrasound point thereto It dissipates 28 minutes, the temperature of ultrasonic disperse obtains the first mixed solution for 50 degrees Celsius, power 280W, frequency 60KHz;
Five water aluminum sulfate, nano silicon dioxide and ferrous sulfate are added in reaction kettle and add in total weight 2 by step 4 Water again stirs 55 minutes under 35 degrees Celsius, then adds in cyanobacteria concentrate, sodium carbonate and polyacrylamide thereto and carries out Fully reaction, obtains the first mixture;
Step 5, by the first mixture, the first mixed solution, maifanite powder and cross-linked rectorite powder in high-speed stirred It stirs evenly, stirring product is dried, you can obtain finished product in machine.
Comparative example 1
Except cyanobacteria is not contained, remaining component and preparation method are same as Example 2.
The product of embodiment 1-4 and the product of comparative example 1 is dirty to identical river with 3/10000ths weight additive amount Water carries out sprinkling processing, and every test is carried out after processing, and test result is shown in Table 1.
Table 1
Initial sewage Comparative example Embodiment 1 Embodiment 2 Embodiment 3 Embodiment 4 Standard
Suspended matter 1630 9.8 6.2 5.8 4.9 5.4 10
COD 23650 48.9 41.3 38.9 36.4 42.6 50
BOD 6560 10.2 6.7 7.8 6.3 7.1 10
Coloration 1345 28.6 18.2 19.6 15.3 16.7 30
Ammonia nitrogen 14.56 4.89 3.65 3.68 3.84 3.41 5
Total phosphorus 14.67 0.51 0.23 0.32 0.27 0.19 0.5
Total nitrogen 153.6 14.8 9.6 7.2 6.7 7.7 15
From table 1 it follows that the product of embodiment 1-4 is significantly larger than comparative example in the effect that river wastewater is handled 1 product, treated, and water quality detection effect meets standard, meets the use demand of people.
It is obvious to a person skilled in the art that the present invention is not limited to the details of above-mentioned exemplary embodiment, Er Qie In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Profit requirement rather than above description limit, it is intended that all by what is fallen within the meaning and scope of the equivalent requirements of the claims Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in each embodiment can also be properly combined, forms those skilled in the art The other embodiment being appreciated that.

Claims (5)

1. a kind of medicament for river pollution processing, which is characterized in that include the raw material of following parts by weight:Clay mineral 10- 16 parts, 4-10 parts of medical stone, 26-35 parts of cross-linked rectorite, 2.4-5 parts of five water aluminum sulfate, 3-6 parts of nano silicon dioxide, carbonic acid 15-20 parts of 2-4 parts of sodium, 1.6-3 parts of polyacrylamide, wooden sodium sulfonate 5-10 parts, 3-5 parts of ferrous sulfate and cyanobacteria.
2. the medicament according to claim 1 for river pollution processing, which is characterized in that the clay mineral includes height It is one or two kinds of above with the arbitrary mixture than mixing in ridge stone, montmorillonite and attapulgite.
3. the medicament according to claim 1 for river pollution processing, which is characterized in that the granularity of the medical stone is 0.48-2.56mm, the granularity of sodium carbonate is 10-20 mesh.
4. a kind of preparation method of the medicament as described in any one of claims 1-3 for river pollution processing, which is characterized in that It is as follows:
Cyanobacteria is carried out water stirring that is broken and adding in 3-4 times of its weight and impregnated 30-45 minutes, then in 75-90 by step 1 Degree Celsius boiling 60-80 minutes filters and filtrate is carried out distillation and concentration, obtains cyanobacteria concentrate;
Clay mineral, medical stone and cross-linked rectorite are distributed and crush and cross 360-400 mesh sieve, obtain clay pit by step 2 Object powder, maifanite powder and cross-linked rectorite powder;
Step 3 by clay mineral powder and the water of 2-4 times of its weight, then adds in wooden sodium sulfonate and ultrasonic disperse thereto 25-30 minutes, obtain the first mixed solution;
Five water aluminum sulfate, nano silicon dioxide and ferrous sulfate are added in reaction kettle and add in total weight 1.5-2 by step 4 Water again stirs 40-60 minutes under 30-35 degrees Celsius, then adds in cyanobacteria concentrate, sodium carbonate and polyacrylamide thereto Amine is fully reacted, and obtains the first mixture;
Step 5, by the first mixture, the first mixed solution, maifanite powder and cross-linked rectorite powder in homogenizer It stirs evenly, stirring product is dried, you can obtain finished product.
5. the preparation method of the medicament according to claim 1 for river pollution processing, which is characterized in that the step The temperature of ultrasonic disperse is 42-54 degrees Celsius, power 245-300W, frequency 40-60KHz in three.
CN201711486163.5A 2017-12-30 2017-12-30 A kind of medicament handled for river pollution and preparation method thereof Pending CN108147480A (en)

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Application Number Priority Date Filing Date Title
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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102266750A (en) * 2011-08-01 2011-12-07 武汉工程大学 In situ preparation method of magnetic bio-absorbent
CN104310508A (en) * 2014-10-31 2015-01-28 广东工业大学 Wastewater treating agent
CN104365670A (en) * 2014-11-19 2015-02-25 沈阳建筑大学 Blue algae removing agent applied to northern rivers and lakes in low-temperature environment
CN105347455A (en) * 2015-10-28 2016-02-24 杨洋 Printing and dyeing wastewater purification powder and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102266750A (en) * 2011-08-01 2011-12-07 武汉工程大学 In situ preparation method of magnetic bio-absorbent
CN104310508A (en) * 2014-10-31 2015-01-28 广东工业大学 Wastewater treating agent
CN104365670A (en) * 2014-11-19 2015-02-25 沈阳建筑大学 Blue algae removing agent applied to northern rivers and lakes in low-temperature environment
CN105347455A (en) * 2015-10-28 2016-02-24 杨洋 Printing and dyeing wastewater purification powder and preparation method thereof

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Application publication date: 20180612

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