CN108135037A - A kind of graphene superconductive far infrared heat generating pastes preparation method - Google Patents
A kind of graphene superconductive far infrared heat generating pastes preparation method Download PDFInfo
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- CN108135037A CN108135037A CN201810068931.3A CN201810068931A CN108135037A CN 108135037 A CN108135037 A CN 108135037A CN 201810068931 A CN201810068931 A CN 201810068931A CN 108135037 A CN108135037 A CN 108135037A
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- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heater elements characterised by the composition or nature of the materials or by the arrangement of the conductor
- H05B3/12—Heater elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material
- H05B3/14—Heater elements characterised by the composition or nature of the materials or by the arrangement of the conductor characterised by the composition or nature of the conductive material the material being non-metallic
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B30/00—Energy efficient heating, ventilation or air conditioning [HVAC]
Abstract
The invention discloses a kind of graphene superconductive far infrared heat generating pastes preparation methods, include the following steps：By graphene, glass dust and carrier are respectively placed in grinding distribution machine, disperseed, then to graphene, glass dust and carrier are filtered respectively, and bulky grain object is disperseed again, the graphene of processing and carrier are mixed again, after 20 26min are mixed, add glass dust thereto again, it then proceedes to that 30 45min are mixed, treat that it is completed after mixing, add auxiliary agent and mixed solution thereto again, then it is carried out again under conditions of 45 60 degrees Celsius that 40 55min are mixed, form mixture, mixture after stripping and slicing is again placed in sand mill.The graphene superconductive far infrared heat generating pastes preparation method can effectively ensure that the quality of slurry, additionally it is possible to improve its scope of application by the control to feed particles diameter.
Description
Technical field
The present invention relates to heat generating pastes preparing technical field more particularly to a kind of graphene superconductive far infrared heat generating pastes systems
Preparation Method.
Background technology
Graphene is the two dimension crystalline substance of only one layer atomic thickness for being stripped out from graphite material, being made of carbon atom
Body.2004, Univ Manchester UK physicist An Deliegaimu and Constantine's Nuo Woxiao loves, success was from stone
Graphene is isolated in ink, it was demonstrated that therefore it can also obtain Nobel Prize in physics in 2010 jointly with individualism, two people.Stone
Black alkene is both most thin material and most tough material, 200 times more taller than best steel of fracture strength.While it is again
There is good elasticity, stretch range can reach the 20% of own dimensions.It is that current nature is most thin, the highest material of intensity,
If making hammock with the graphene of one piece of 1 square metre of area, weight itself can bear one one kilogram less than 1 milligram
Cat.Graphene most potential application at present is the substitute as silicon, manufactures ultra micro transistor npn npn, for producing following surpass
Grade computer.Replace silicon with graphene, the speed of service of computer processor will be hundreds times fast.In addition, graphene is almost
Fully transparent, the light of absorption 2.3%.Traditional thick film heating component is mainly by the use of noble metal as function phase, cost
It is higher, it needs to replace these noble metal function phases with cheap conductive material.Heating temp is limited, and life cycle is shorter, fever
Temperature should not rise too high.In order to meet the needs of growing, there is an urgent need for exploitation one kind, and there is high temperature to issue thermostabilization, fever height
Slurry.For this purpose, we have proposed a kind of graphene superconductive far infrared heat generating pastes preparation methods.
Invention content
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes preparation method, to solve in above-mentioned background technology
The problem of proposition.
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes preparation method, includes the following steps：
S1：Graphene, glass dust, auxiliary agent and carrier are chosen as raw material, and graphene, glass dust, auxiliary agent and carrier
Molal weight ratio be 5：1：1：2, it also needs to ensure raw material before use, be stored in 20-30 degrees Celsius of gnotobasis, it is different
It needs individually placed between raw material, does not contact between each other；
S2：By treated in S1, graphene, glass dust and carrier are respectively placed in grinding distribution machine, and in 35-50
Under conditions of degree Celsius, above-mentioned raw materials are disperseed, and jitter time be 12-15min, complete dispersion after, need to graphene,
Glass dust and carrier are filtered respectively, so as to remove bulky grain object therein, and bulky grain object are disperseed again, directly
Diameter to raw material is less than 100nm；
S3：The graphene handled in S2 and carrier are placed in ultrasonic dispersing machine, and it is mixed again,
After 20-26min is mixed, glass dust being added thereto again, then proceeding to that 30-45min is mixed, it is mixed to treat that it is completed
After closing uniformly, add auxiliary agent and mixed solution thereto again, then it is carried out again under conditions of 45-60 degrees Celsius
40-55min is mixed；
S4：After the completion of being handled in S3, mixture is formed, then mixture is placed in mulser, carry out emulsification treatment,
And mixture is placed in sterile normal temperature environment, natural cooling molding, and mixture after molding is subjected to stripping and slicing, but stripping and slicing
The length of mixture is between 3-6mm afterwards；
S5：Mixture after stripping and slicing is again placed in sand mill, carries out fine gtinding processing, and the rate of sand mill is
800-1000 turns/min, and the means ground in filtering are taken in grinding, and filter diameter is 25-48nm, and will be greater than 25-48nm
Mixture block repeatedly ground, so as to ensure the quality of heat generating pastes；
S6：After the completion of grinding, uniform mixed phase is formed to get to graphene superconductive far infrared heat generating pastes.
Preferably, the auxiliary agent in S3 is the mixed liquor of dispersant, cast charge, coupling agent, antioxidant and bonding agent,
And dispersant, cast charge, coupling agent, antioxidant and bonding agent molal weight ratio be 2：1：0.2：1：0.1.
Preferably, the mixed solution in S3 be glycine, butyl carbitol, diethylene glycol and pine tar mixture, and
Glycine, butyl carbitol, diethylene glycol and pine tar molal weight ratio be 2：0.5：0.5：1.
Preferably, the carrier is made of following raw material：24-30 parts of amination fluorinated graphene, synthetic resin 12-15
Part, 12-15 parts of magnetic rubber powder, 9-12 parts of ethyl cellulose, 3-6 parts of aluminium oxide powder.
The present invention also provides a kind of preparation methods of carrier, are as follows：
Grinding distribution machine is chosen, and amination fluorinated graphene, synthetic resin and ethyl cellulose are being uniformly mixed
Afterwards, be placed in grinding distribution machine, carry out fine gtinding processing, after the completion of grinding, formed mixed material, and by mixed material into
Row filtering, and filter diameter is 25-48 μm, then the mixed material after filtering is placed in agitating device, again by magnetic rubber
Rubber powder and aluminium oxide powder are placed in one, and carry out mixing processing to it, treat its complete after mixing to get to
Carrier.
Preferably, the rate of the mixing in S3 turns/min for 300-400.
Preferably, the molal weight ratio of the auxiliary agent added in S3 and mixed solution is 1：2.
A kind of graphene superconductive far infrared heat generating pastes preparation method proposed by the present invention, advantageous effect are：
1st, the graphene superconductive far infrared heat generating pastes preparation method is by introducing graphene carrier, using synthetic resin,
Mutual cooperation between magnetic rubber powder and aluminium oxide powder improves the electric conductivity of heat generating pastes；
2nd, the graphene superconductive far infrared heat generating pastes preparation method passes through the coupling agent and bonding agent of addition, Neng Gougai
The high temperature bond performance of kind heat generating pastes, so as to improve its service life, dispersant can improve the dispersibility of powder, into
And the electric conductivity of heat generating pastes is improved, the addition of cast charge so that the far infrared transmissivity of heat generating pastes reaches more than 90%；
3rd, the graphene superconductive far infrared heat generating pastes preparation method, can be effective by the control to feed particles diameter
Ensure the quality of slurry, additionally it is possible to improve its scope of application.
Specific embodiment
With reference to specific embodiment, the present invention will be further described.
Embodiment 1
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes preparation method, includes the following steps：
S1：Graphene, glass dust, auxiliary agent and carrier are chosen as raw material, and graphene, glass dust, auxiliary agent and carrier
Molal weight ratio be 5：1：1：2, it also needs to ensure raw material before use, be stored in 20 degrees Celsius of gnotobasis, it is different former
It needs individually placed between material, does not contact between each other；
S2：By treated in S1, graphene, glass dust and carrier are respectively placed in grinding distribution machine, and Celsius 35
Under conditions of degree, above-mentioned raw materials are disperseed, and jitter time is 12min, it, need to be to graphene, glass dust after completing dispersion
And carrier is filtered respectively, so as to remove bulky grain object therein, and bulky grain object is disperseed again, until raw material
Diameter be less than 100nm；
S3：The graphene handled in S2 and carrier are placed in ultrasonic dispersing machine, and it is mixed again,
After 20min is mixed, glass dust is added thereto again, then proceed to that 30min is mixed, treat that it completes to be uniformly mixed
Afterwards, auxiliary agent and mixed solution are added thereto again, then it is mixed again under conditions of 45 degrees Celsius
40min；
S4：After the completion of being handled in S3, mixture is formed, then mixture is placed in mulser, carry out emulsification treatment,
And mixture is placed in sterile normal temperature environment, natural cooling molding, and mixture after molding is subjected to stripping and slicing, but stripping and slicing
The length of mixture is between 3-6mm afterwards；
S5：Mixture after stripping and slicing is again placed in sand mill, carries out fine gtinding processing, and the rate of sand mill is
800-1000 turns/min, and the means ground in filtering are taken in grinding, and filter diameter is 25-48nm, and will be greater than 25-48nm
Mixture block repeatedly ground, so as to ensure the quality of heat generating pastes；
S6：After the completion of grinding, uniform mixed phase is formed to get to graphene superconductive far infrared heat generating pastes.
Auxiliary agent in S3 is the mixed liquor of dispersant, cast charge, coupling agent, antioxidant and bonding agent, and disperses
Agent, cast charge, coupling agent, antioxidant and bonding agent molal weight ratio be 2：1：0.2：1：0.1.
Mixed solution in S3 is glycine, butyl carbitol, diethylene glycol and pine tar mixture, and glycine,
The molal weight ratio of butyl carbitol, diethylene glycol and pine tar is 2：0.5：0.5：1.
The carrier is made of following raw material：24 parts of amination fluorinated graphene, 12 parts of synthetic resin, magnetic rubber powder
12 parts, 9 parts of ethyl cellulose, 3 parts of aluminium oxide powder.
The present invention also provides a kind of preparation methods of carrier, are as follows：
Grinding distribution machine is chosen, and amination fluorinated graphene, synthetic resin and ethyl cellulose are being uniformly mixed
Afterwards, be placed in grinding distribution machine, carry out fine gtinding processing, after the completion of grinding, formed mixed material, and by mixed material into
Row filtering, and filter diameter is 25-48 μm, then the mixed material after filtering is placed in agitating device, again by magnetic rubber
Rubber powder and aluminium oxide powder are placed in one, and carry out mixing processing to it, treat its complete after mixing to get to
Carrier.
The rate of mixing in S3 turns/min for 300-400.
The molal weight ratio of the auxiliary agent added and mixed solution in S3 is 1：2.
Embodiment 2
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes preparation method, includes the following steps：
S1：Graphene, glass dust, auxiliary agent and carrier are chosen as raw material, and graphene, glass dust, auxiliary agent and carrier
Molal weight ratio be 5：1：1：2, it also needs to ensure raw material before use, be stored in 24 degrees Celsius of gnotobasis, it is different former
It needs individually placed between material, does not contact between each other；
S2：By treated in S1, graphene, glass dust and carrier are respectively placed in grinding distribution machine, and Celsius 40
Under conditions of degree, above-mentioned raw materials are disperseed, and jitter time is 13min, it, need to be to graphene, glass dust after completing dispersion
And carrier is filtered respectively, so as to remove bulky grain object therein, and bulky grain object is disperseed again, until raw material
Diameter be less than 100nm；
S3：The graphene handled in S2 and carrier are placed in ultrasonic dispersing machine, and it is mixed again,
After 22min is mixed, glass dust is added thereto again, then proceed to that 35min is mixed, treat that it completes to be uniformly mixed
Afterwards, auxiliary agent and mixed solution are added thereto again, then it is mixed again under conditions of 50 degrees Celsius
45min；
S4：After the completion of being handled in S3, mixture is formed, then mixture is placed in mulser, carry out emulsification treatment,
And mixture is placed in sterile normal temperature environment, natural cooling molding, and mixture after molding is subjected to stripping and slicing, but stripping and slicing
The length of mixture is between 3-6mm afterwards；
S5：Mixture after stripping and slicing is again placed in sand mill, carries out fine gtinding processing, and the rate of sand mill is
800-1000 turns/min, and the means ground in filtering are taken in grinding, and filter diameter is 25-48nm, and will be greater than 25-48nm
Mixture block repeatedly ground, so as to ensure the quality of heat generating pastes；
S6：After the completion of grinding, uniform mixed phase is formed to get to graphene superconductive far infrared heat generating pastes.
Auxiliary agent in S3 is the mixed liquor of dispersant, cast charge, coupling agent, antioxidant and bonding agent, and disperses
Agent, cast charge, coupling agent, antioxidant and bonding agent molal weight ratio be 2：1：0.2：1：0.1.
Mixed solution in S3 is glycine, butyl carbitol, diethylene glycol and pine tar mixture, and glycine,
The molal weight ratio of butyl carbitol, diethylene glycol and pine tar is 2：0.5：0.5：1.
The carrier is made of following raw material：26 parts of amination fluorinated graphene, 13 parts of synthetic resin, magnetic rubber powder
13 parts, 10 parts of ethyl cellulose, 4 parts of aluminium oxide powder.
The present invention also provides a kind of preparation methods of carrier, are as follows：
Grinding distribution machine is chosen, and amination fluorinated graphene, synthetic resin and ethyl cellulose are being uniformly mixed
Afterwards, be placed in grinding distribution machine, carry out fine gtinding processing, after the completion of grinding, formed mixed material, and by mixed material into
Row filtering, and filter diameter is 25-48 μm, then the mixed material after filtering is placed in agitating device, again by magnetic rubber
Rubber powder and aluminium oxide powder are placed in one, and carry out mixing processing to it, treat its complete after mixing to get to
Carrier.
The rate of mixing in S3 turns/min for 300-400.
The molal weight ratio of the auxiliary agent added and mixed solution in S3 is 1：2.
Embodiment 3
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes preparation method, includes the following steps：
S1：Graphene, glass dust, auxiliary agent and carrier are chosen as raw material, and graphene, glass dust, auxiliary agent and carrier
Molal weight ratio be 5：1：1：2, it also needs to ensure raw material before use, be stored in 28 degrees Celsius of gnotobasis, it is different former
It needs individually placed between material, does not contact between each other；
S2：By treated in S1, graphene, glass dust and carrier are respectively placed in grinding distribution machine, and Celsius 45
Under conditions of degree, above-mentioned raw materials are disperseed, and jitter time is 14min, it, need to be to graphene, glass dust after completing dispersion
And carrier is filtered respectively, so as to remove bulky grain object therein, and bulky grain object is disperseed again, until raw material
Diameter be less than 100nm；
S3：The graphene handled in S2 and carrier are placed in ultrasonic dispersing machine, and it is mixed again,
After 24min is mixed, glass dust is added thereto again, then proceed to that 40min is mixed, treat that it completes to be uniformly mixed
Afterwards, auxiliary agent and mixed solution are added thereto again, then it is mixed again under conditions of 55 degrees Celsius
50min；
S4：After the completion of being handled in S3, mixture is formed, then mixture is placed in mulser, carry out emulsification treatment,
And mixture is placed in sterile normal temperature environment, natural cooling molding, and mixture after molding is subjected to stripping and slicing, but stripping and slicing
The length of mixture is between 3-6mm afterwards；
S5：Mixture after stripping and slicing is again placed in sand mill, carries out fine gtinding processing, and the rate of sand mill is
800-1000 turns/min, and the means ground in filtering are taken in grinding, and filter diameter is 25-48nm, and will be greater than 25-48nm
Mixture block repeatedly ground, so as to ensure the quality of heat generating pastes；
S6：After the completion of grinding, uniform mixed phase is formed to get to graphene superconductive far infrared heat generating pastes.
Auxiliary agent in S3 is the mixed liquor of dispersant, cast charge, coupling agent, antioxidant and bonding agent, and disperses
Agent, cast charge, coupling agent, antioxidant and bonding agent molal weight ratio be 2：1：0.2：1：0.1.
Mixed solution in S3 is glycine, butyl carbitol, diethylene glycol and pine tar mixture, and glycine,
The molal weight ratio of butyl carbitol, diethylene glycol and pine tar is 2：0.5：0.5：1.
The carrier is made of following raw material：28 parts of amination fluorinated graphene, 14 parts of synthetic resin, magnetic rubber powder
14 parts, 11 parts of ethyl cellulose, 5 parts of aluminium oxide powder.
The present invention also provides a kind of preparation methods of carrier, are as follows：
Grinding distribution machine is chosen, and amination fluorinated graphene, synthetic resin and ethyl cellulose are being uniformly mixed
Afterwards, be placed in grinding distribution machine, carry out fine gtinding processing, after the completion of grinding, formed mixed material, and by mixed material into
Row filtering, and filter diameter is 25-48 μm, then the mixed material after filtering is placed in agitating device, again by magnetic rubber
Rubber powder and aluminium oxide powder are placed in one, and carry out mixing processing to it, treat its complete after mixing to get to
Carrier.
The rate of mixing in S3 turns/min for 300-400.
The molal weight ratio of the auxiliary agent added and mixed solution in S3 is 1：2.
Embodiment 4
The present invention proposes a kind of graphene superconductive far infrared heat generating pastes preparation method, includes the following steps：
S1：Graphene, glass dust, auxiliary agent and carrier are chosen as raw material, and graphene, glass dust, auxiliary agent and carrier
Molal weight ratio be 5：1：1：2, it also needs to ensure raw material before use, be stored in 30 degrees Celsius of gnotobasis, it is different former
It needs individually placed between material, does not contact between each other；
S2：By treated in S1, graphene, glass dust and carrier are respectively placed in grinding distribution machine, and Celsius 50
Under conditions of degree, above-mentioned raw materials are disperseed, and jitter time is 15min, it, need to be to graphene, glass dust after completing dispersion
And carrier is filtered respectively, so as to remove bulky grain object therein, and bulky grain object is disperseed again, until raw material
Diameter be less than 100nm；
S3：The graphene handled in S2 and carrier are placed in ultrasonic dispersing machine, and it is mixed again,
After 26min is mixed, glass dust is added thereto again, then proceed to that 45min is mixed, treat that it completes to be uniformly mixed
Afterwards, auxiliary agent and mixed solution are added thereto again, then it is mixed again under conditions of 60 degrees Celsius
55min；
S4：After the completion of being handled in S3, mixture is formed, then mixture is placed in mulser, carry out emulsification treatment,
And mixture is placed in sterile normal temperature environment, natural cooling molding, and mixture after molding is subjected to stripping and slicing, but stripping and slicing
The length of mixture is between 3-6mm afterwards；
S5：Mixture after stripping and slicing is again placed in sand mill, carries out fine gtinding processing, and the rate of sand mill is
800-1000 turns/min, and the means ground in filtering are taken in grinding, and filter diameter is 25-48nm, and will be greater than 25-48nm
Mixture block repeatedly ground, so as to ensure the quality of heat generating pastes；
S6：After the completion of grinding, uniform mixed phase is formed to get to graphene superconductive far infrared heat generating pastes.
Auxiliary agent in S3 is the mixed liquor of dispersant, cast charge, coupling agent, antioxidant and bonding agent, and disperses
Agent, cast charge, coupling agent, antioxidant and bonding agent molal weight ratio be 2：1：0.2：1：0.1.
Mixed solution in S3 is glycine, butyl carbitol, diethylene glycol and pine tar mixture, and glycine,
The molal weight ratio of butyl carbitol, diethylene glycol and pine tar is 2：0.5：0.5：1.
The carrier is made of following raw material：30 parts of amination fluorinated graphene, 15 parts of synthetic resin, magnetic rubber powder
15 parts, 12 parts of ethyl cellulose, 6 parts of aluminium oxide powder.
The present invention also provides a kind of preparation methods of carrier, are as follows：
Grinding distribution machine is chosen, and amination fluorinated graphene, synthetic resin and ethyl cellulose are being uniformly mixed
Afterwards, be placed in grinding distribution machine, carry out fine gtinding processing, after the completion of grinding, formed mixed material, and by mixed material into
Row filtering, and filter diameter is 25-48 μm, then the mixed material after filtering is placed in agitating device, again by magnetic rubber
Rubber powder and aluminium oxide powder are placed in one, and carry out mixing processing to it, treat its complete after mixing to get to
Carrier.
The rate of mixing in S3 turns/min for 300-400.
The molal weight ratio of the auxiliary agent added and mixed solution in S3 is 1：2.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (7)
1. a kind of graphene superconductive far infrared heat generating pastes preparation method, which is characterized in that include the following steps：
S1：Choose graphene, glass dust, auxiliary agent and carrier are raw material, and graphene, glass dust, auxiliary agent and carrier rub
Your mass ratio is 5：1：1：2, it also needs to ensure raw material before use, be stored in 20-30 degrees Celsius of gnotobasis, different material
Between need individually placed, do not contact between each other；
S2：By treated in S1, graphene, glass dust and carrier are respectively placed in grinding distribution machine, and Celsius in 35-50
Under conditions of degree, above-mentioned raw materials are disperseed, and jitter time is 12-15min, it, need to be to graphene, glass after completing dispersion
Powder and carrier are filtered respectively, so as to remove bulky grain object therein, and bulky grain object are disperseed again, until former
The diameter of material is less than 100nm；
S3：The graphene handled in S2 and carrier are placed in ultrasonic dispersing machine, and it is mixed again, mixed
After closing stirring 20-26min, glass dust being added thereto again, then proceeding to that 30-45min is mixed, it is equal to treat that it completes mixing
After even, add auxiliary agent and mixed solution thereto again, then it is mixed again under conditions of 45-60 degrees Celsius
Stir 40-55min；
S4：After the completion of being handled in S3, mixture is formed, then mixture is placed in mulser, carry out emulsification treatment, and will
Mixture is placed in sterile normal temperature environment, natural cooling molding, and mixture after molding is carried out stripping and slicing, is but mixed after stripping and slicing
The length of object is closed between 3-6mm；
S5：Mixture after stripping and slicing is again placed in sand mill, carries out fine gtinding processing, and the rate of sand mill is 800-
1000 turns/min, the means ground in filtering are taken in grinding, and filter diameter is 25-48nm, and will be greater than the mixed of 25-48nm
It closes object block repeatedly to be ground, so as to ensure the quality of heat generating pastes；
S6：After the completion of grinding, uniform mixed phase is formed to get to graphene superconductive far infrared heat generating pastes.
2. a kind of graphene superconductive far infrared heat generating pastes preparation method according to claim 1, it is characterised in that：In S3
In auxiliary agent be dispersant, cast charge, coupling agent, antioxidant and bonding agent mixed liquor, and dispersant, cast charge, idol
The molal weight ratio for joining agent, antioxidant and bonding agent is 2：1：0.2：1：0.1.
3. a kind of graphene superconductive far infrared heat generating pastes preparation method according to claim 1, it is characterised in that：In S3
In mixed solution for glycine, butyl carbitol, diethylene glycol and pine tar mixture, and glycine, butyl carbitol, two
The molal weight of ethylene glycol and pine tar ratio is 2：0.5：0.5：1.
4. a kind of graphene superconductive far infrared heat generating pastes preparation method according to claim 1, it is characterised in that：It is described
Carrier be made of following raw material：24-30 parts of amination fluorinated graphene, 12-15 parts of synthetic resin, magnetic rubber powder 12-15
Part, 9-12 parts of ethyl cellulose, 3-6 parts of aluminium oxide powder.
5. a kind of preparation method of carrier according to claim 4, which is characterized in that be as follows：
Grinding distribution machine is chosen, and amination fluorinated graphene, synthetic resin and ethyl cellulose are put after mixing
In in grinding distribution machine, fine gtinding processing is carried out, after the completion of grinding, forms mixed material, and mixed material was carried out
Filter, and filter diameter is 25-48 μm, then the mixed material after filtering is placed in agitating device, again by magnetic rubber powder
And aluminium oxide powder is placed in one, and carries out mixing processing to it, treats that it is completed after mixing to get to load
Body.
6. a kind of graphene superconductive far infrared heat generating pastes preparation method according to claim 1, it is characterised in that：In S3
In mixing rate for 300-400 turn/min.
7. a kind of graphene superconductive far infrared heat generating pastes preparation method according to claim 1, it is characterised in that：In S3
In the auxiliary agent added and mixed solution molal weight ratio be 1：2.
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| CN109629706A (en) * | 2018-11-29 | 2019-04-16 | 牛墨石墨烯应用科技有限公司 | A kind of assembled graphene fever wallboard |
| CN109721282A (en) * | 2019-02-18 | 2019-05-07 | 中山市君泽科技有限公司 | A kind of aqueous slurry preparation method based on graphene |
| CN110401990A (en) * | 2019-01-13 | 2019-11-01 | 北京烯研科技有限公司 | A kind of high-efficiency heat conduction graphene Far infrared heating membrane and preparation method thereof |
| CN112996153A (en) * | 2019-12-12 | 2021-06-18 | 上海烯有新材料有限公司 | Graphene heating plate and preparation method and application thereof |
| CN113056039A (en) * | 2019-12-27 | 2021-06-29 | 陈建波 | Ultra-low power consumption graphene high-temperature heating tube and manufacturing method thereof |
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| CN109629706A (en) * | 2018-11-29 | 2019-04-16 | 牛墨石墨烯应用科技有限公司 | A kind of assembled graphene fever wallboard |
| CN110401990A (en) * | 2019-01-13 | 2019-11-01 | 北京烯研科技有限公司 | A kind of high-efficiency heat conduction graphene Far infrared heating membrane and preparation method thereof |
| CN110401990B (en) * | 2019-01-13 | 2022-06-14 | 北京烯研科技有限公司 | Efficient heat-conducting graphene far-infrared heating film and preparation method thereof |
| CN109721282A (en) * | 2019-02-18 | 2019-05-07 | 中山市君泽科技有限公司 | A kind of aqueous slurry preparation method based on graphene |
| CN112996153A (en) * | 2019-12-12 | 2021-06-18 | 上海烯有新材料有限公司 | Graphene heating plate and preparation method and application thereof |
| CN113056039A (en) * | 2019-12-27 | 2021-06-29 | 陈建波 | Ultra-low power consumption graphene high-temperature heating tube and manufacturing method thereof |
| CN113056039B (en) * | 2019-12-27 | 2023-04-07 | 陈建波 | Ultra-low power consumption graphene high-temperature heating tube and manufacturing method thereof |
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