CN108128990A - Garbage percolation liquid treating system and method - Google Patents

Garbage percolation liquid treating system and method Download PDF

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Publication number
CN108128990A
CN108128990A CN201810153589.7A CN201810153589A CN108128990A CN 108128990 A CN108128990 A CN 108128990A CN 201810153589 A CN201810153589 A CN 201810153589A CN 108128990 A CN108128990 A CN 108128990A
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level
pond
anoxic
nitrification tank
concentration basin
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CN108128990B (en
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龚浩
李哲
李大鹏
高智荣
崔鹏
许松
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China City Environment Protection Engineering Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/06Contaminated groundwater or leachate
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2203/00Apparatus and plants for the biological treatment of water, waste water or sewage
    • C02F2203/006Apparatus and plants for the biological treatment of water, waste water or sewage details of construction, e.g. specially adapted seals, modules, connections
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/08Chemical Oxygen Demand [COD]; Biological Oxygen Demand [BOD]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/14NH3-N
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/16Total nitrogen (tkN-N)
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/22O2
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/44Time
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/04Flow arrangements
    • C02F2301/046Recirculation with an external loop
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/30Aerobic and anaerobic processes
    • C02F3/302Nitrification and denitrification treatment

Abstract

The invention discloses garbage percolation liquid treating system and methods, are related to sewage treatment field.Garbage percolation liquid treating system provided by the invention includes pre- anoxic selection pond, level-one denitrification pond, level-one nitrification tank, intermediate sedimentation concentration basin, pre- anoxic buffer pool, two level denitrification pond, two level nitrification tank, two-stage precipitation concentration basin, intermediate clear water reserviors, ultrafiltration apparatus, level-one Catalyzed by Ultrasonic Wave device and two level Catalyzed by Ultrasonic Wave device.Method for treating garbage percolation liquid provided by the invention includes landfill leachate passing sequentially through above-mentioned garbage percolation liquid treating system.The second thickened sludge in two-stage precipitation concentration basin is back to pre- anoxic buffer pool, and the third thickened sludge in ultrafiltration apparatus is back to pre- anoxic buffer pool.Garbage percolation liquid treating system provided by the invention and method have the characteristics that simple, floor space is small, low energy consumption, operating cost is low, stability is good and investment-saving.

Description

Garbage percolation liquid treating system and method
Technical field
The present invention relates to sewage treatment field, in particular to garbage percolation liquid treating system and method.
Background technology
This part intends to provides background for the embodiments of the present invention stated in claims and specific embodiment Or context.Description herein recognizes it is the prior art not because not being included in this part.
With the fast development of China's economy, China's Municipal Domestic Garbage Output also rapidly increases, waste incineration and generating electricity Treating capacity it is growing day by day, waste incineration and generating electricity use incineration when, need to by new refuse garbage storing hole in store up It deposits 3~5 days and carries out fermentation curing, to achieve the purpose that leach moisture, improve calorific value, just can guarantee the normal fortune of follow-up incinerator Row.The moisture leached in above-mentioned rubbish fermentation maturing process is generally known as landfill leachate.The characteristics of percolate is:It is organic Pollutant COD, BOD5 are dense, and wherein BOD5/COD is about 0.5, and biodegradability is good, wherein, COD concentration about 30000~ 90000mg/L, BOD5 about 15000~50000mg/L, secondly NH4-N, TN are dense, wherein, NH4-N concentration about 1500 ~3000mg/L, TN concentration about 2500~4000mg/L, but the ratio of C/N is larger, is suitble to biochemical treatment.In addition, percolate The water quality and quantity of generation fluctuates huge, complicated component, and with strong foul odour, yellowish-brown or black is presented.Garbage filter The pollution effect of liquid be much larger than common sanitary sewage, so must by landfill leachate treatment it is up to standard after can just discharge or Reuse.The treatment technology of landfill leachate is at home and abroad widely paid close attention at present, the processing running or in research Technology mainly has biologic treating technique and membrane technology.
It is that the organic nitrogen of total nitrogen in landfill leachate, ammonia nitrogen are first passed through into nitrifier aerobic in bio-denitrification technology Under the conditions of be oxidized to nitrite nitrogen, followed by nitrate nitrogen is oxidized to, then nitrate nitrogen by denitrifying bacterium under anoxic conditions Nitrogen is reduced to, completes biological denitrificaion.The reaction condition difference of nitrifying process and denitrification process is larger, and nitrifying process is suitable Occur under the relatively low aerobic environment of organic concentration, denitrification process is suitable to be sent out in the environment of anoxic and there are organic matter It is raw, therefore bio-denitrification technology generally requires sewage first passing through nitration reaction, after by anti-nitration reaction can be only achieved biology The effect of denitrogenation.The combination treatment method of preceding denitrification process and nitrifying process as disclosed in patent No. CN1562508A, can be with There is Nitrogen removal effect to landfill leachate, but the removal rate of its total nitrogen is only 80%, the removal rate of organic matter is 90%, ammonia nitrogen Removal rate for 99%, total nitrogen is difficult to meet processing requirement.As disclosed in patent No. CN101244880A preceding denitrification process, in Between nitrifying process and rear-mounted denitrification process combination treatment method, preceding denitrification process lack effective nitrate nitrogen, Wu Fagao The completion Nitrogen removal effect of effect.
In landfill leachate biologic treating technique, sludge concentration in biological reaction pool generally in 10~20mg/L, due to Higher sludge concentration so that the enhancing of microorganism is mutual in biological reaction pool antagonism, list during compared to low concentration The activity of position microorganism is relatively low, and MLVSS/MLSS ratios are relatively low, and the effective rate of utilization of activated sludge is relatively low in biological reaction pool, So that whole biological treatment is relatively low to the removal effect of pollutant.
Invention content
The purpose of the present invention is to provide a kind of garbage percolation liquid treating system, have that simple, floor space is small, energy consumption It is low, operating cost is low, stability is good and the characteristics of investment-saving.
Another object of the present invention is to provide a kind of method for treating garbage percolation liquid, have simple, floor space is small, Low energy consumption, operating cost is low, stability is good and the characteristics of investment-saving.
The present invention provides a kind of technical solution:
A kind of garbage percolation liquid treating system, including pre- anoxic selection pond, level-one denitrification pond, level-one nitrification tank, centre Precipitation concentration pond, two level denitrification pond, two level nitrification tank, two-stage precipitation concentration basin, intermediate clear water reserviors, surpasses pre- anoxic buffer pool Filter equipment, level-one Catalyzed by Ultrasonic Wave device and two level Catalyzed by Ultrasonic Wave device.Pre- anoxic selection pond is connect with level-one denitrification pond, level-one Denitrification pond is connect with level-one nitrification tank, and level-one nitrification tank is connect with intermediate sedimentation concentration basin, and intermediate sedimentation concentration basin is lacked with pre- Oxygen buffer pool connects, and pre- anoxic buffer pool is connect with two level nitrification tank, and two level nitrification tank is connect with two level denitrification pond, and two level is anti- Nitrification tank is connect with two-stage precipitation concentration basin, and two-stage precipitation concentration basin is connect with intermediate clear water reserviors, and intermediate clear water reserviors are set with ultrafiltration Standby connection.Intermediate sedimentation concentration basin selects pond to connect by level-one Catalyzed by Ultrasonic Wave device with pre- anoxic, and two-stage precipitation concentration basin leads to It crosses two level Catalyzed by Ultrasonic Wave device to connect with pre- anoxic buffer pool, ultrafiltration apparatus is buffered by two level Catalyzed by Ultrasonic Wave device and pre- anoxic Pond connects.
Further, above-mentioned garbage percolation liquid treating system further includes mixing aeration device, mixing aeration device and level-one The madial wall connection of nitrification tank or mixing aeration device are connect with the madial wall of two level nitrification tank.
Further, above-mentioned mixing aeration device includes agitating shaft and stirrer paddle, and one end and the level-one of agitating shaft nitrify Pond is rotatablely connected, and stirrer paddle is set on agitating shaft and can be rotated with agitating shaft, and agitating shaft is provided with gas port along axis And agitating shaft has radially been positioned apart from multiple solarization air caps, multiple solarization air caps are connected with gas port.
Further, above-mentioned stirrer paddle includes the first blade and the second blade, and the first blade and the second blade are with stirring Mix axis connection, and the first blade and the interlaced setting of the second blade.
Further, the quantity of above-mentioned mixing aeration device is multiple, multiple mixing aeration devices with level-one nitrification tank Connection or which part mixing aeration device are connect with level-one nitrification tank, and another part mixing aeration device is nitrified with two level Pond connect with.
A kind of method for treating garbage percolation liquid, method for treating garbage percolation liquid use garbage percolation liquid treating system.Rubbish Percolation liquid treating system includes pre- anoxic selection pond, level-one denitrification pond, level-one nitrification tank, intermediate sedimentation concentration basin, pre- anoxic Buffer pool, two level denitrification pond, two level nitrification tank, two-stage precipitation concentration basin, intermediate clear water reserviors, ultrafiltration apparatus, level-one ultrasonic wave Catalyst converter and two level Catalyzed by Ultrasonic Wave device.Pre- anoxic selection pond is connect with level-one denitrification pond, level-one denitrification pond and level-one nitre Change pond connection, level-one nitrification tank is connect with intermediate sedimentation concentration basin, and intermediate sedimentation concentration basin is connect with pre- anoxic buffer pool, pre- to lack Oxygen buffer pool is connect with two level nitrification tank, and two level nitrification tank is connect with two level denitrification pond, two level denitrification pond and two-stage precipitation Concentration basin connects, and two-stage precipitation concentration basin is connect with intermediate clear water reserviors, and intermediate clear water reserviors are connect with ultrafiltration apparatus.Intermediate sedimentation is dense Contracting pond selects pond to connect by level-one Catalyzed by Ultrasonic Wave device with pre- anoxic, and two-stage precipitation concentration basin passes through two level Catalyzed by Ultrasonic Wave device It is connect with pre- anoxic buffer pool, ultrafiltration apparatus is connect by two level Catalyzed by Ultrasonic Wave device with pre- anoxic buffer pool.Landfill leachate Processing method includes:Landfill leachate is passed sequentially through pre- anoxic selects pond, level-one denitrification pond, level-one nitrification tank, centre heavy Shallow lake concentration basin, pre- anoxic buffer pool, two level denitrification pond, two level nitrification tank, two-stage precipitation concentration basin, intermediate clear water reserviors and ultrafiltration Equipment.The first thickened sludge generated in intermediate sedimentation concentration basin is back to pre- anoxic selection pond.By two-stage precipitation concentration basin The second interior thickened sludge is back to pre- anoxic buffer pool, and the third thickened sludge in ultrafiltration apparatus is back to pre- anoxic and is delayed Rush pond.
Further, landfill leachate is imported into pre- anoxic selection pond and is stirred plug-flow, and landfill leachate is pre- It is 6-10 hours that anoxic, which selects residence time in pond,.The landfill leachate in pond is selected to be directed into level-one denitrification pre- anoxic Pond is simultaneously stirred plug-flow, and landfill leachate residence time in level-one denitrification pond is 10~14 hours.By the anti-nitre of level-one The landfill leachate changed in pond is directed into level-one nitrification tank and carries out blast aeration, and landfill leachate stops in level-one nitrification tank Time be 120~144 hours.Landfill leachate in level-one nitrification tank is directed into intermediate sedimentation concentration basin and is precipitated, and Obtained supernatant is flow to pre- anoxic buffer pool, the first thickened sludge will be obtained and be back to pre- anoxic selection pond.Centre is heavy Landfill leachate in the concentration basin of shallow lake is directed into two level denitrification pond and stirs plug-flow, and landfill leachate is in intermediate sedimentation concentration basin Interior residence time is 10-14 hours.Landfill leachate in two level denitrification pond is directed into two level nitrification tank simultaneously air blast Aeration, landfill leachate residence time in two level nitrification tank is 10-14 hours.By the landfill leachate in two level nitrification tank It is directed into two-stage precipitation concentration basin and precipitates, and the supernatant obtained after being precipitated flow to intermediate clear water reserviors, by what is obtained Second thickened sludge is back to pre- anoxic buffer pool.
Further, the first thickened sludge generated in intermediate sedimentation concentration basin is flowed back by level-one Catalyzed by Ultrasonic Wave device Pond is selected to pre- anoxic.
Further, the second thickened sludge in two-stage precipitation concentration basin and ultrafiltration are set by two level Catalyzed by Ultrasonic Wave device Standby interior third thickened sludge is back to pre- anoxic buffer pool.
Further, the liquid that convection current enters in ultrafiltration apparatus carries out separation of solid and liquid, and the clear water isolated is carried out depth Processing, pre- anoxic buffer pool is back to by obtained third thickened sludge.
Compared with prior art, the advantageous effect of garbage percolation liquid treating system provided by the invention and method is:
Garbage percolation liquid treating system provided by the invention and the treatment effeciency of method are high:COD removal rates can to 95%, BOD5 removal rates can can be to 98.5% to 99.5%, TN removal rates to 98%, NH4-N removal rates.To landfill leachate treatment Afterwards, TN concentration can reach in clear water《Household refuse landfill sites contamination control standard》2 limit value mark of (GB 16889-2008) table Standard, when needing to reach the discharge standard without increasing reverse osmosis treatment system when controlling TN concentration of emissions.By being segmented back Flow Technique has carried out activated sludge the obligate bacterium hot housing of advantage and using the activity dirt of low-intensity ultrasonic radiation intensification Mud treatment effeciency so that floor space reduces 10%~30%.Oxygen in activated sludge is enhanced using low intensity ultrasound wave radiation Microcosmic mass-transfer efficiency, reduce required aeration quantity in nitrification tank, reduce the energy consumption of Aeration fan 10%~25%.Energy consumption It is low.Using efficient processing method, reduce the residence time of biological treatment tank, the specification of equipment for reducing Aeration fan is big It is small, save investment.And the energy consumption of Aeration fan is also reduced, saves operation power charge.Meanwhile it is also provided with pre- anoxic choosing It selects pond and employs activated sludge technique of backflow, the inoculation and selection of obligate microorganism have been carried out to landfill leachate, after being Continuous processing unit provides optimum condition, has the advantages that anti-shock loading is strong and stability is good.Rubbish provided by the invention Rubbish percolation liquid treating system and method have that simple, floor space is small, low energy consumption, operating cost is low, stability is good and investment-saving The characteristics of.
Description of the drawings
It in order to illustrate the technical solution of the embodiments of the present invention more clearly, below will be to needed in the embodiment attached Figure is briefly described.It should be appreciated that the following drawings illustrates only certain embodiments of the present invention, therefore it is not construed as pair The restriction of range.It for those of ordinary skill in the art, without creative efforts, can also be according to this A little attached drawings obtain other relevant attached drawings.
Fig. 1 is the structure diagram of garbage percolation liquid treating system that the embodiment of the present invention provides;
Fig. 2 is the structure diagram of mixing aeration device that the embodiment of the present invention provides;
Fig. 3 is the schematic cross-sectional view of mixing aeration device that the embodiment of the present invention provides;
Fig. 4 is the enlarged structure schematic diagram at IV in Fig. 2.
Icon:10- garbage percolation liquid treating systems;The pre- anoxic selection ponds of 101-;102- level-one denitrifications pond;103- level-ones Nitrification tank;104- intermediate sedimentation concentration basins;The pre- anoxic buffer pools of 105-;106- two level denitrifications pond;107- two level nitrification tanks; 108- two-stage precipitation concentration basins;Clear water reserviors among 109-;110- ultrafiltration apparatus;111- level-one Catalyzed by Ultrasonic Wave devices;112- two levels Catalyzed by Ultrasonic Wave device;200- mixing aeration devices;210- agitating shafts;211- gas ports;212- solarization air caps;220- stirrer paddles; The first blades of 221-;2211- first row stomatas;2212- first stirs protrusion;The second blades of 222-;2221- second row stomatas; 2223- second stirs protrusion.
Specific embodiment
Purpose, technical scheme and advantage to make the embodiment of the present invention are clearer, below in conjunction with the embodiment of the present invention In attached drawing, the technical solution in the embodiment of the present invention is clearly and completely described.Obviously, described embodiment is Part of the embodiment of the present invention, instead of all the embodiments.The present invention being usually described and illustrated herein in the accompanying drawings is implemented The component of example can be configured to arrange and design with a variety of different.
Therefore, below the detailed description of the embodiment of the present invention to providing in the accompanying drawings be not intended to limit it is claimed The scope of the present invention, but be merely representative of the present invention selected embodiment.Based on the embodiments of the present invention, this field is common Technical staff's all other embodiments obtained without creative efforts belong to the model that the present invention protects It encloses.
It should be noted that:Similar label and letter represents similar terms in following attached drawing, therefore, once a certain Xiang Yi It is defined in a attached drawing, does not then need to that it is further defined and explained in subsequent attached drawing.
In the description of the present invention, it is to be understood that the instructions such as term " on ", " under ", " interior ", " outer ", "left", "right" Orientation or position relationship be based on orientation shown in the drawings or position relationship or the invention product using when usually put Orientation or the orientation that usually understands of position relationship or those skilled in the art or position relationship, be for only for ease of and retouch It states the present invention and simplifies description rather than instruction or imply that signified equipment or element must have specific orientation, with specific Azimuth configuration and operation, therefore be not considered as limiting the invention.
In addition, term " first ", " second " etc. are only used for distinguishing description, and it is not intended that indicating or implying relatively important Property.
In the description of the present invention, it is also necessary to which explanation is unless specifically defined or limited otherwise, " setting ", " even Connect " etc. terms should be interpreted broadly, for example, " connection " can be fixedly connected or be detachably connected or integrally connect It connects;Can be mechanical connection or electrical connection;Can be directly connected to, can also be indirectly connected with by intermediary, it can To be the connection inside two elements.For the ordinary skill in the art, can understand as the case may be above-mentioned The concrete meaning of term in the present invention.
Below in conjunction with the accompanying drawings, the specific embodiment of the present invention is described in detail.
First embodiment
Referring to Fig. 1, present embodiments providing a kind of garbage percolation liquid treating system 10, there is simple, floor space It is small, low energy consumption, operating cost is low, stability is good and the characteristics of investment-saving.
Garbage percolation liquid treating system 10 provided in this embodiment includes pre- anoxic selection pond 101, level-one denitrification pond 102nd, level-one nitrification tank 103, intermediate sedimentation concentration basin 104, pre- anoxic buffer pool 105, two level denitrification pond 106, two level nitrification Pond 107, two-stage precipitation concentration basin 108, intermediate clear water reserviors 109, ultrafiltration pond ultrafiltration apparatus 110, level-one Catalyzed by Ultrasonic Wave device 111 and Two level Catalyzed by Ultrasonic Wave device 112.Pre- anoxic selection pond 101 is connect with level-one denitrification pond 102, level-one denitrification pond 102 and one Grade nitrification tank 103 connects, and level-one nitrification tank 103 is connect with intermediate sedimentation concentration basin 104, and intermediate sedimentation concentration basin 104 is lacked with pre- Oxygen buffer pool 105 connects, and pre- anoxic buffer pool 105 is connect with two level nitrification tank 107, two level nitrification tank 107 and two level denitrification Pond 106 connects, and two level denitrification pond 106 is connect with two-stage precipitation concentration basin 108, two-stage precipitation concentration basin 108 and intermediate clear water Pond 109 connects, and intermediate clear water reserviors 109 are connect with ultrafiltration pond ultrafiltration apparatus 110.Intermediate sedimentation concentration basin 104 passes through level-one ultrasound Wave catalyst converter 111 is connect with pre- anoxic selection pond 101, and two-stage precipitation concentration basin 108 is by two level Catalyzed by Ultrasonic Wave device 112 and in advance Anoxic buffer pool 105 connects, and ultrafiltration pond ultrafiltration apparatus 110 is connected by two level Catalyzed by Ultrasonic Wave device 112 and pre- anoxic buffer pool 105 It connects.
The processing procedure of landfill leachate is illustrated individually below:
Pre- anoxic selects pond 101:Landfill leachate is placed in pre- anoxic selection pond 101, while level-one ultrasonic wave is urged Change the activated sludge that device 111 flows back to be placed in together in pre- anoxic selection pond 101, plug-flow is continuously stirred in pre- anoxic selection pond 101. Activated sludge and landfill leachate are sufficiently mixed contact, are conducive to the ecological environment in pre- anoxic selection pond 101 selective Develop cotton-shaped bacterium, inhibit undue growth and the breeding of der Pilz with biological competition mechanism, pre- anoxic selection pond 101 not only can be with Sludge bulking is controlled, the environment of anoxic is suitble to denitrifying bacteria to grow, plays certain denitrification, next with selecting The effect of the dominant microflora of processing unit.Simultaneously reflux activated sludge have very high absorption property, with landfill leachate After mixing, organic matter can be largely adsorbed, and mass transfer improves the removal efficiency of polluter into the cell.Pre- anoxic selects pond 101 residence times were 6~10 hours.
Level-one denitrification pond 102:Landfill leachate in pre- anoxic selection pond 101 is flowed in level-one denitrification pond 102, together When the level-one nitrification liquid of level-one nitrification tank 103 is flowed back into level-one denitrification pond 102, continuously stirred in level-one denitrification pond 102 Mix plug-flow, additional carbon, the concentration ratio of carbon source and nitrate nitrogen is 2:1~5:1, preferably 3:1~4:1, to landfill leachate into Row anti-nitration reaction.Since pre- anoxic selects pond 101 to act on, while adsorbed a large amount of organic the Superior selection of denitrifying bacteria Object in the cell, mixes with the level-one denitrification liquid of reflux, forms good anti-nitration reaction condition, carry out efficient denitrification Denitrification reaction.102 residence time of level-one denitrification pond is 10~14 hours.
Level-one nitrification tank 103:Landfill leachate in level-one denitrification pond 102 is flowed in level-one nitrification tank 103, nitrification tank Interior continuous blast aeration, DO controls are in 2~5mg/L, and pH is 7~8, and sludge concentration is in 15~20g/L.Landfill leachate is carried out Nitration reaction and carburizing reagent, largely remove removal organic polluter and ammonia nitrogen, and level-one nitrification tank 103 is discharged a part and flows to intermediate sink Shallow lake concentration basin 104, a part flow back into level-one denitrification pond 102.103 residence time of level-one nitrification tank is 120~144 hours.
Intermediate sedimentation concentration basin 104:Landfill leachate in level-one nitrification tank 103 is flowed in intermediate sedimentation concentration basin 104, The supernatant obtained after being precipitated flow to pre- anoxic buffer pool 105, and the sludge after precipitation concentration flow to level-one Catalyzed by Ultrasonic Wave Device 111.The flocculation that intermediate sedimentation concentration basin 104 will be assembled using the effect that mechanical agitation is promoted in intermediate sedimentation concentration basin 104 Body has just taken off steady microscopic particles and has contacted with each other, adsorbs in the landfill leachate with entering intermediate sedimentation concentration basin 104, make suspended matter It is comparatively fast detached with supernatant.Simultaneously as the effect that mechanical agitation is promoted, has very high sludge condensation rate, makes intermediate sedimentation Higher sludge concentration can be kept in concentration basin 104, while makes the thickened sludge concentration of reflux higher.Intermediate sedimentation concentration basin 104 residence times were 1.5~2.5 hours, and it is handle water 3~5 times that mechanical agitation, which promotes water, and supernatant upflow velocity is 0.7~1.3mm/s.
Level-one Catalyzed by Ultrasonic Wave device 111:Thickened sludge in intermediate sedimentation concentration basin 104 flows back into level-one Catalyzed by Ultrasonic Wave Device 111, level-one Catalyzed by Ultrasonic Wave device 111 generate low-intensity ultrasonic, thickened sludge are catalyzed, and catalysis post activation sludge returns Flow to pre- anoxic selection pond 101.Low intensity ultrasound wave radiation is carried out to activated sludge has raising sludge absorption performance, enhancing dirt Mud activity, the work for improving MLVSS/MLSS ratios, enhancing microbial cell synthesis capability and reducing the average grain diameter of sludge flco With, therefore the treatment effeciency of activated sludge is improved, enhance the microcosmic mass-transfer efficiency of oxygen in activated sludge.Level-one ultrasonic wave is urged Change device 111 and use frequency as 20~22kHz, power density is 18~22W/L and radiated time is 4.5~5.5min.
Pre- anoxic buffer pool 105:Landfill leachate in intermediate sedimentation concentration basin 104 flows to pre- anoxic buffer pool 105, together When the activated sludge that two level Catalyzed by Ultrasonic Wave device 112 flows back is placed in together in pre- anoxic buffer pool 105, pre- anoxic buffer pool Plug-flow is continuously stirred in 105.Since level-one biological treatment tank and pollutant concentration difference in two stage biological processing are larger, this rubbish The high-efficient treatment method of rubbish percolate separates level-one biological treatment tank and the sludge in two stage biological processing pond, is level-one Mutual indepedent and metastable environment is formed in biological treatment tank and two stage biological processing pond, in every grade of biological treatment tank Activated sludge carries out obligate bacterium hot housing, to reach the highest treatment effeciency of activated sludge in every grade of biological treatment tank.It is logical The activated sludge of 112 reflux of reflux two level Catalyzed by Ultrasonic Wave device is crossed, water quality and quantity is carried out to the water of level-one biological treatment tank It buffers and adjusts and obligate selection is carried out to microorganism, ensure the obligate culture of activated sludge in two stage biological processing pond.In advance 105 residence time of anoxic buffer pool is 6~9 hours.
Two level denitrification pond 106:Landfill leachate in pre- anoxic buffer pool 105 is flowed in two level denitrification pond 106, and two Continuously stir plug-flow in grade denitrification pond 106, additional carbon, the concentration ratio of carbon source and nitrate nitrogen is 5:1~8:1, preferably 6:1 ~7:1, anti-nitration reaction is carried out to landfill leachate.106 residence time of two level denitrification pond is 10~14 hours.
Two level nitrification tank 107:Landfill leachate in two level denitrification pond 106 is flowed in two level nitrification tank 107, nitrification tank Interior continuous blast aeration, DO are controlled in 2~4mg/L, and nitration reaction and carburizing reagent are carried out to landfill leachate, and removal two level is anti- The carbon source excessive in being discharged of nitrification tank 106.107 residence time of two level nitrification tank is 10~14 hours.
Two-stage precipitation concentration basin 108:Landfill leachate in two level nitrification tank 107 is flowed in two-stage precipitation concentration basin 108, The supernatant obtained after being precipitated flow to intermediate clear water reserviors 109, and the sludge after precipitation concentration flow to two level Catalyzed by Ultrasonic Wave device 112.108 residence time of two-stage precipitation concentration basin is 1.0~1.5 hours, and it is handle water 3~5 that mechanical agitation, which promotes water, Times, supernatant upflow velocity is 1.0~1.5mm/s.
Intermediate clear water reserviors 109:Supernatant in two-stage precipitation concentration basin 108 is flowed in intermediate clear water reserviors 109, be ultrafiltration into Water provides advantage.Intermediate 109 residence time of clear water reserviors is 3~5 hours.
Ultrafiltration pond ultrafiltration apparatus 110:Supernatant in intermediate clear water reserviors 109 is flowed in ultrafilter, passes through the film of ultrafilter Component is to supernatant progress separation of solid and liquid, reuse after the clear water qualified discharge isolated or progress advanced treating, thickened sludge stream To two level Catalyzed by Ultrasonic Wave device 112.The membrane aperture of ultrafilter membrane module is less than or equal to 30 nanometers, in pipe operating pressure for 0.3~ 0.5MPa。
Two level Catalyzed by Ultrasonic Wave device 112:Thickened sludge one in thickened sludge and ultrafiltration in two-stage precipitation concentration basin 108 And flow back into two level Catalyzed by Ultrasonic Wave device 112, two level Catalyzed by Ultrasonic Wave device 112 generate low-intensity ultrasonic, to thickened sludge into Row catalysis, catalysis post activation sludge reflux to pre- anoxic buffer pool 105.Two level Catalyzed by Ultrasonic Wave device 112 use frequency for 19~ 21kHz, power density is 16~18W/L and radiated time is 4~5min.
It should be noted that the treatment effeciency of garbage percolation liquid treating system 10 provided in this embodiment is high:COD removal rates It can can can be to 98.5% to 99.5%, TN removal rates to 98%, NH4-N removal rates to 95%, BOD5 removal rates.Rubbish is oozed After filtrate processing, TN concentration can reach in clear water《Household refuse landfill sites contamination control standard》(GB 16889-2008) table 2 Standard limit, when needing to reach the discharge standard without increasing reverse osmosis treatment system when controlling TN concentration of emissions.Pass through Segment reflux technology has carried out activated sludge the obligate bacterium hot housing of advantage and has used low-intensity ultrasonic radiation intensification Active sludge treatment efficiency so that floor space reduces 10%~30%.Active dirt is enhanced using low intensity ultrasound wave radiation The microcosmic mass-transfer efficiency of oxygen in mud reduces required aeration quantity in nitrification tank, reduces the energy consumption of Aeration fan 10%~25%. Low energy consumption.Using efficient processing method, reduce the residence time of biological treatment tank, reduce the specification of equipment of Aeration fan Size saves investment.And the energy consumption of Aeration fan is also reduced, saves operation power charge.Meanwhile it is also provided with pre- anoxic It selects pond 101 and employs activated sludge technique of backflow, the inoculation and selection of obligate microorganism have been carried out to landfill leachate, Optimum condition is provided for subsequent processing units, has the advantages that anti-shock loading is strong and stability is good.The present embodiment carries The garbage percolation liquid treating system 10 of confession has that simple, floor space is small, low energy consumption, operating cost is low, stability is good and saves throwing The characteristics of money.
Fig. 2 to Fig. 4 is please referred to, in the present embodiment, garbage percolation liquid treating system 10 further includes mixing aeration device 200, mixing aeration device 200 is connect with the madial wall of level-one nitrification tank 103 or mixing aeration device 200 is nitrified with two level The madial wall connection in pond 107.
In the present embodiment, mixing aeration device 200 include agitating shaft 210 and stirrer paddle 220, the one of agitating shaft 210 End is rotatablely connected with level-one nitrification tank 103, and stirrer paddle 220 is set on agitating shaft 210 and can be rotated with agitating shaft 210, Axis is provided with gas port 211 to agitating shaft 210 and agitating shaft 210 has radially been positioned apart from multiple solarization air caps 212, more A solarization air cap 212 is connected with gas port 211.
In the present embodiment, stirrer paddle 220 includes the first blade 221 and the second blade 222, the first blade 221 and the Two blades 222 are connect with agitating shaft 210, and the first blade 221 and the second blade 222 mutually say a be staggered.
In the present embodiment, the first blade 221 is provided with first row stomata 2211, first row stomata 2211 and gas port 211 connections.Second blade 222 is provided with second row stomata 2221, and second row stomata 2221 is connected with gas port 211.
It is understood that the setting of first row stomata 2211 and second row stomata 2221 helps to introduce gas into liquid In vivo, and then promote to react.
In the present embodiment, the first blade 221 is additionally provided with multiple spaced first stirring protrusions 2212, the second paddle Leaf 222 is additionally provided with multiple spaced second stirring protrusions 2223.
It is understood that can promote to stir by the first stirring protrusion 2212 and the second stirring protrusion 2223, and then Promote reaction.
In the present embodiment, the quantity of mixing aeration device 200 is two, in two mixing aeration devices 200 wherein One mixing aeration device 200 is connect with the madial wall of level-one nitrification tank 103, another in two mixing aeration devices 200 The madial wall connection of 200 two level nitrification tank 107 of mixing aeration device.
In the present embodiment, the quantity of mixing aeration device 200 is multiple, and multiple mixing aeration devices 200 are and level-one Nitrification tank 103 connects or which part mixing aeration device 200 is connect with level-one nitrification tank 103, another part stirring aeration Device 200 is connect with two level nitrification tank 107.Garbage percolation liquid treating system 10 selects 101 level-one denitrification pond of pond with pre- anoxic 102 level-one nitrification tank, 103 intermediate sedimentation concentration basin, 104 pre- 105 two level denitrification pond of anoxic buffer pool, 106 two level nitrification tank 107 108 intermediate clear water reserviors 109 of two-stage precipitation concentration basin.
With pre- scarce with 103 intermediate sedimentation concentration basin 104 of pre- anoxic selection 101 102 level-one nitrification tank of level-one denitrification pond of pond 105 106 two level nitrification tank of two level denitrification pond of oxygen buffer pool, 107 two-stage precipitation concentration basin, 108 intermediate clear water reserviors 109 with with this The advantageous effect for the garbage percolation liquid treating system 10 that embodiment provides:Garbage percolation liquid treating system 10 provided in this embodiment Treatment effeciency it is high:COD removal rates can can be gone to 95%, BOD5 removal rates to 98%, NH4-N removal rates to 99.5%, TN Except rate can be to 98.5%.After landfill leachate treatment, TN concentration can reach in clear water《Household refuse landfill sites contamination control Standard》(GB16889-2008) 2 standard limit of table, when needing to reach the discharge standard without increasing when controlling TN concentration of emissions Add reverse osmosis treatment system.By segment reflux technology, the obligate bacterium hot housing of advantage is carried out to activated sludge and has been used Low-intensity ultrasonic radiation intensification active sludge treatment efficiency so that floor space reduces 10%~30%.Surpassed using low-intensity Acoustic irradiation enhances the microcosmic mass-transfer efficiency of oxygen in activated sludge, reduces required aeration quantity in nitrification tank, reduces aeration The energy consumption of wind turbine 10%~25%.Low energy consumption.Using efficient processing method, reduce the residence time of biological treatment tank, drop The low specification of equipment size of Aeration fan, saves investment.And the energy consumption of Aeration fan is also reduced, saves operation electricity Take.Meanwhile be also provided with pre- anoxic selection pond 101 and employ activated sludge technique of backflow, landfill leachate is carried out The inoculation and selection of obligate microorganism provide optimum condition for subsequent processing units, by force and steady with anti-shock loading The advantages of qualitative good.Garbage percolation liquid treating system 10 provided in this embodiment has that simple, floor space is small, low energy consumption, fortune Row expense is low, stability is good and the characteristics of investment-saving.
Second embodiment
Referring to Fig. 1, present embodiments providing a kind of method for treating garbage percolation liquid, method for treating garbage percolation liquid uses The garbage percolation liquid treating system 10 provided such as first embodiment.
Method for treating garbage percolation liquid provided in this embodiment includes:Landfill leachate is passed sequentially through into pre- anoxic selection pond 101st, level-one denitrification pond 102, level-one nitrification tank 103, intermediate sedimentation concentration basin 104, pre- anoxic buffer pool 105, the anti-nitre of two level Change pond 106, two level nitrification tank 107, two-stage precipitation concentration basin 108, intermediate clear water reserviors 109 and ultrafiltration pond ultrafiltration apparatus 110.By in Between the first thickened sludge for generating in precipitation concentration pond 104 be back to pre- anoxic selection pond 101.By two-stage precipitation concentration basin 108 The second interior thickened sludge is back to pre- anoxic buffer pool 105, and the third thickened sludge in ultrafiltration pond ultrafiltration apparatus 110 is returned It flow to pre- anoxic buffer pool 105.
Further, landfill leachate is imported into pre- anoxic selection pond 101 and is stirred plug-flow, and landfill leachate exists It is 6-10 hours that pre- anoxic, which selects residence time in pond 101,.The landfill leachate in pond 101 is selected to be directed into one pre- anoxic Grade denitrification pond 102 is simultaneously stirred plug-flow, and landfill leachate residence time in level-one denitrification pond 102 is small for 10~14 When.Landfill leachate in level-one denitrification pond 102 is directed into level-one nitrification tank 103 and carries out blast aeration, garbage filter Liquid residence time in level-one nitrification tank 103 is 120~144 hours.Landfill leachate in level-one nitrification tank 103 is imported It is precipitated in intermediate sedimentation concentration basin 104, and obtained supernatant is flow to pre- anoxic buffer pool 105, the first concentration will be obtained Sludge reflux to pre- anoxic selects pond 101.Landfill leachate in intermediate sedimentation concentration basin 104 is directed into two level denitrification pond 106 and plug-flow is stirred, landfill leachate residence time in intermediate sedimentation concentration basin 104 is 10-14 hours.By the anti-nitre of two level Change the landfill leachate in pond 106 and be directed into simultaneously blast aeration in two level nitrification tank 107, landfill leachate is in two level nitrification tank Residence time is 10-14 hours in 107.Landfill leachate in two level nitrification tank 107 is directed into two-stage precipitation concentration basin It is precipitated in 108, and the supernatant obtained after being precipitated flow to intermediate clear water reserviors 109, the second obtained thickened sludge is returned It flow to pre- anoxic buffer pool 105.
Further, it is by level-one Catalyzed by Ultrasonic Wave device 111 that the first concentration generated in intermediate sedimentation concentration basin 104 is dirty Mud is back to pre- anoxic selection pond 101.
Further, by two level Catalyzed by Ultrasonic Wave device 112 by the second thickened sludge in two-stage precipitation concentration basin 108 and Third thickened sludge in ultrafiltration pond ultrafiltration apparatus 110 is back to pre- anoxic buffer pool 105.
Further, the liquid in convection current excess of imports filter tank ultrafiltration apparatus 110 carries out separation of solid and liquid, and the clear water that will be isolated Advanced treating is carried out, obtained third thickened sludge is back to pre- anoxic buffer pool 105.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, that is made any repaiies Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of garbage percolation liquid treating system, which is characterized in that including pre- anoxic selection pond, level-one denitrification pond, level-one nitre Change pond, intermediate sedimentation concentration basin, pre- anoxic buffer pool, two level denitrification pond, two level nitrification tank, two-stage precipitation concentration basin, centre Clear water reserviors, ultrafiltration apparatus, level-one Catalyzed by Ultrasonic Wave device and two level Catalyzed by Ultrasonic Wave device;
The pre- anoxic selection pond is connect with the level-one denitrification pond, and the level-one denitrification pond connects with the level-one nitrification tank It connects, the level-one nitrification tank is connect with the intermediate sedimentation concentration basin, and the intermediate sedimentation concentration basin is buffered with the pre- anoxic Pond connects, and the pre- anoxic buffer pool is connect with the two level nitrification tank, the two level nitrification tank and the two level denitrification pond Connection, the two level denitrification pond are connect with the two-stage precipitation concentration basin, and the two-stage precipitation concentration basin and the centre are clear Pond connects, and the intermediate clear water reserviors are connect with the ultrafiltration apparatus;
The intermediate sedimentation concentration basin selects pond to connect by the level-one Catalyzed by Ultrasonic Wave device with the pre- anoxic, the two level Precipitation concentration pond is connect by the two level Catalyzed by Ultrasonic Wave device with the pre- anoxic buffer pool, and the ultrafiltration apparatus passes through described Two level Catalyzed by Ultrasonic Wave device is connect with the pre- anoxic buffer pool.
2. garbage percolation liquid treating system according to claim 1, which is characterized in that the garbage percolation liquid treating system Mixing aeration device is further included, the mixing aeration device is connect with the madial wall of the level-one nitrification tank or the stirring Aerator is connect with the madial wall of the two level nitrification tank.
3. garbage percolation liquid treating system according to claim 2, which is characterized in that the mixing aeration device includes stirring Axis and stirrer paddle are mixed, one end of the agitating shaft is rotatablely connected with the level-one nitrification tank, and the stirrer paddle is set to institute State on agitating shaft and can be rotated with the agitating shaft, the agitating shaft axis is provided with gas port and the agitating shaft along its Multiple solarization air caps are provided with to spaced radial, multiple solarization air caps are connected with the gas port.
4. garbage percolation liquid treating system according to claim 3, which is characterized in that the stirrer paddle includes the first paddle Leaf and the second blade, first blade and second blade with the stirring axis connection, and first blade and institute State the interlaced setting of the second blade.
5. according to the garbage percolation liquid treating system described in any one in claim 2-4, which is characterized in that the stirring exposes The quantity of device of air is multiple, and multiple mixing aeration devices are connect with the level-one nitrification tank or which part institute It states mixing aeration device to connect with the level-one nitrification tank, mixing aeration device described in another part connects with the two level nitrification tank It connects.
6. a kind of method for treating garbage percolation liquid, which is characterized in that the method for treating garbage percolation liquid uses such as claim Garbage percolation liquid treating system in 1-5 described in any one, the method for treating garbage percolation liquid include:By landfill leachate Pass sequentially through the pre- anoxic selection pond, the level-one denitrification pond, the level-one nitrification tank, the intermediate sedimentation concentration basin, The pre- anoxic buffer pool, the two level denitrification pond, the two level nitrification tank, the two-stage precipitation concentration basin, the centre Clear water reserviors and the ultrafiltration apparatus;
The first thickened sludge generated in the intermediate sedimentation concentration basin is back to pre- anoxic selection pond;
The second thickened sludge in the two-stage precipitation concentration basin is back to the pre- anoxic buffer pool, and the ultrafiltration is set Standby interior third thickened sludge is back to the pre- anoxic buffer pool.
7. method for treating garbage percolation liquid according to claim 6, which is characterized in that the landfill leachate is imported into institute State pre- anoxic selection pond and be stirred plug-flow, and the landfill leachate the pre- anoxic select in pond residence time for 6-10 hours;
The landfill leachate in the pre- anoxic selection pond is directed into the level-one denitrification pond and is stirred plug-flow, Landfill leachate residence time in the level-one denitrification pond is 10~14 hours;
The landfill leachate in the level-one denitrification pond is directed into the level-one nitrification tank and carries out blast aeration, institute It is 120~144 hours to state landfill leachate residence time in the level-one nitrification tank;
The landfill leachate in the level-one nitrification tank is directed into the intermediate sedimentation concentration basin and is precipitated, and will be obtained Supernatant flow to the pre- anoxic buffer pool, first thickened sludge will be obtained and be back to the pre- anoxic selection pond;
The landfill leachate in the intermediate sedimentation concentration basin is directed into the two level denitrification pond and stirs plug-flow, institute It is 10-14 hours to state landfill leachate residence time in the intermediate sedimentation concentration basin;
The landfill leachate in the two level denitrification pond is directed into the two level nitrification tank simultaneously blast aeration, it is described Landfill leachate residence time in the two level nitrification tank is 10-14 hours;
The landfill leachate in the two level nitrification tank is directed into the two-stage precipitation concentration basin and is precipitated, and will be carried out The supernatant obtained after precipitation flow to the intermediate clear water reserviors, and obtained second thickened sludge is back to the pre- anoxic Buffer pool.
8. method for treating garbage percolation liquid according to claim 6, which is characterized in that pass through the level-one Catalyzed by Ultrasonic Wave The first thickened sludge generated in the intermediate sedimentation concentration basin is back to the pre- anoxic and selects pond by device.
9. method for treating garbage percolation liquid according to claim 6, which is characterized in that pass through the two level Catalyzed by Ultrasonic Wave Third thickened sludge in the second thickened sludge and the ultrafiltration apparatus in the two-stage precipitation concentration basin is back to institute by device State pre- anoxic buffer pool.
10. method for treating garbage percolation liquid according to claim 6, which is characterized in that flowing into the ultrafiltration apparatus Liquid carry out separation of solid and liquid, and by the clear water isolated carry out advanced treating, obtained third thickened sludge is back to institute State pre- anoxic buffer pool.
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CN206089372U (en) * 2016-10-12 2017-04-12 北京高能时代环境技术股份有限公司 Processing apparatus of aged landfill filtration liquid
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CN104556361A (en) * 2013-10-11 2015-04-29 中国石油化工股份有限公司 Low-intensity ultrasonic synergistic aeration device
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