CN108128754A - A kind of System and method for for being easy to judge whether HyCO ice chests block - Google Patents

A kind of System and method for for being easy to judge whether HyCO ice chests block Download PDF

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Publication number
CN108128754A
CN108128754A CN201711463469.9A CN201711463469A CN108128754A CN 108128754 A CN108128754 A CN 108128754A CN 201711463469 A CN201711463469 A CN 201711463469A CN 108128754 A CN108128754 A CN 108128754A
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Prior art keywords
ice chests
hyco
hyco ice
temperature
chests
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CN201711463469.9A
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Chinese (zh)
Inventor
李现民
钟华
苏科峰
项吴定
吉荣
徐晶
钱海玲
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Shanghai Hualin Industrial Gas Co Ltd
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Shanghai Hualin Industrial Gas Co Ltd
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Priority to CN201711463469.9A priority Critical patent/CN108128754A/en
Publication of CN108128754A publication Critical patent/CN108128754A/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01VGEOPHYSICS; GRAVITATIONAL MEASUREMENTS; DETECTING MASSES OR OBJECTS; TAGS
    • G01V9/00Prospecting or detecting by methods not provided for in groups G01V1/00 - G01V8/00
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/048Composition of the impurity the impurity being an organic compound
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/0495Composition of the impurity the impurity being water

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Geophysics (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

The present invention relates to a kind of System and method for for being easy to judge whether HyCO ice chests block, including the first temperature-change adsorption tower, the second temperature-change adsorption tower, the first HyCO ice chests, the 2nd HyCO ice chests and the CO/H to be connected by pipeline2Knockout drum is both provided with heat exchanger, the CO/H in the first HyCO ice chests and the 2nd HyCO ice chests2Knockout drum draws raw hydrogen pipeline and CO pipelines, the raw hydrogen pipeline sequence is drawn after flowing through the 2nd HyCO ice chests and the heat exchanger of the first HyCO ice chests, material synthesis gas pipeline is introduced before the first temperature-change adsorption tower, first pressure transmitter is provided on pipeline between the second temperature-change adsorption tower and the first HyCO ice chests, second pressure transmitter is provided on the raw hydrogen pipeline after the first HyCO ice chests.First pressure transmitter and second pressure transmitter show pressure difference value Δ P as the standard for judging the first HyCO ice chests or the 2nd HyCO ice chests and whether blocking.System structure provided by the invention is simple, easy to use, and this method is intuitively quick, and accuracy is high.

Description

A kind of System and method for for being easy to judge whether HyCO ice chests block
Technical field
The present invention relates to a kind of HyCO cold box systems, it is easy to judge whether HyCO ice chests block more particularly, to a kind of and is System and method.
Background technology
HyCO synthesis gas is containing 54%CO and 45%H2And micro N2、CH4、Ar、H2O、CO2Deng industrial gaseous mixture Body.HyCO isolation of purified systems are by H in synthesis gas2O and CO2It is removed by TSA adsorption towers (temperature-change adsorption tower), secondly utilized CO、H2、N2、CH4It is different with the boiling point of the gases such as Ar in cold box interior by CO and H2It separates, H2By PSA (pressure-variable adsorption, Pressure Swing Adsorption.) it sends outside after purifying, CO gives client by outer after the pressurization of CO compressors, generate Tail gas then put to torch burning.
Heat exchanger is provided in HyCO ice chests, heat transferring medium flows through heat exchanger so that temperature change in heat exchanger, so as to profit With CO, H2、N2、CH4It is different with the boiling point of the gases such as Ar in cold box interior by CO and H2It separates, during general operation, HyCO is cold Operation temperature is at -180 DEG C or so in case.
Because the ice chest operation temperature of HyCO is at -180 DEG C or so, to the CO in raw material2And H2O requirements are higher, CO2Content into ice chest is less than 0.2ppm, H2The requirement of O is raw material dew point at -86 DEG C (0.19ppm), is generally increased before ice chest If two TSA (temperature swing adsorption, temp.-changing adsorption) towers are used to purify the CO in raw material2And H2O, just It is often that two TSA bed tandems use simultaneously, through first bed is cut out with high temperature N after a period of time2It is regenerated, is regenerated Putting behind after cooling ensures CO2And H2O is not pierced.
If contain CO into the gas in HyCO ice chests2Or H2O, due in HyCO ice chests operation temperature on -180 DEG C of left sides The right side, at this point, the CO in gaseous mixture2Or H2O easily blocks ice chest, lacks be monitored for whether ice chest blocks at present into solid Device and method.
Invention content
It is an object of the present invention to overcome the above-mentioned drawbacks of the prior art and provide one kind is easy to judge HyCO The System and method for whether ice chest blocks.System structure provided by the invention is simple, easy to use, and this method is intuitively quick, accurate True property is high.
The purpose of the present invention can be achieved through the following technical solutions:
A kind of system for being easy to judge whether HyCO ice chests block, including connected by pipeline the first temperature-change adsorption tower, Second temperature-change adsorption tower, the first HyCO ice chests, the 2nd HyCO ice chests and CO/H2Knockout drum, the first HyCO ice chests and second Heat exchanger, the CO/H are both provided in HyCO ice chests2Knockout drum draws raw hydrogen pipeline and CO pipelines, the raw hydrogen pipeline Sequence is drawn after flowing through the 2nd HyCO ice chests and the heat exchanger of the first HyCO ice chests, and raw material is introduced before the first temperature-change adsorption tower and is closed Into gas pipeline, first pressure transmitter is provided on the pipeline between the second temperature-change adsorption tower and the first HyCO ice chests, in place In being provided with second pressure transmitter on the raw hydrogen pipeline after the first HyCO ice chests.First pressure transmitter becomes with second pressure Device is sent to show pressure difference value Δ P as the standard for judging the first HyCO ice chests or the 2nd HyCO ice chests and whether blocking.
Further, temperature transmitter is provided on the pipeline between the first HyCO ice chests and the 2nd HyCO ice chests, temperature Degree transmitter displays temperature value T0 is as the standard for judging the first HyCO ice chests or the 2nd HyCO ice chests and whether blocking.
Further, the first pressure transmitter, second pressure transmitter are connect with dcs.
Further, the temperature transmitter is connect with dcs.
Further, valve is provided on Material synthesis gas pipeline, in the first temperature-change adsorption tower and the second temp.-changing adsorption Valve is provided on pipeline between tower, valve is provided on the pipeline between the second temperature-change adsorption tower and the first HyCO ice chests Door.
Further, high pressure CO flow path sequence flows through the heat exchanger of the first HyCO ice chests and the 2nd HyCO ice chests, low pressure CO Flow path sequence flows through the heat exchanger of the 2nd HyCO ice chests and the first HyCO ice chests.
A kind of method for being easy to judge whether HyCO ice chests block, based on following system:
Including the first temperature-change adsorption tower, the second temperature-change adsorption tower, the first HyCO ice chests, the 2nd HyCO to be connected by pipeline Ice chest and CO/H2Knockout drum is both provided with heat exchanger, the CO/H in the first HyCO ice chests and the 2nd HyCO ice chests2Separation Tank draws raw hydrogen pipeline and CO pipelines, and the raw hydrogen pipeline sequence flows through changing for the 2nd HyCO ice chests and the first HyCO ice chests It is drawn after hot device, material synthesis gas pipeline is introduced before the first temperature-change adsorption tower, it is cold in the second temperature-change adsorption tower and the first HyCO First pressure transmitter is provided on pipeline between case, is provided on the raw hydrogen pipeline after the first HyCO ice chests Two pressure transmitters are provided with temperature transmitter on the pipeline between the first HyCO ice chests and the 2nd HyCO ice chests;
Judgment method is one or both of following two methods:
1st, first pressure transmitter and second pressure transmitter show pressure difference value Δ P as judge the first HyCO ice chests or The standard whether the 2nd HyCO ice chests block, the first HyCO ice chests of Δ P stably expresseds or the 2nd HyCO ice chests do not block, Δ P Rise and represent that the first HyCO ice chests or the 2nd HyCO ice chests block;
2nd, temperature transmitter displays temperature value T0 is as judging the first HyCO ice chests or whether the 2nd HyCO ice chests block Standard, the first HyCO ice chests of T0 stably expresseds or the 2nd HyCO ice chests do not block, and T0, which rises, represents the first HyCO ice chests or the Two HyCO ice chests block.
First pressure transmitter shows that pressure value is P1, and second pressure transmitter shows pressure value as P2, Δ P=P1-P2, △ P are fluctuated up and down with the adjustment of the load of ice chest, and in the case of ice chest steady load, △ P also stablize relatively, if ice chest Steady load, △ P have the tendency that being gradually increasing, and illustrate the heat exchanger of ice chest and have H2O or CO2Into and block, so as to △ P Rise, therefore, judge whether HyCO ice chests block according to △ P.
T0 generally will not up and down be fluctuated with the load of ice chest, in a kind of trend of stabilization, if T0 is gradually increasing Trend, illustrating the heat exchanger of ice chest has H2O or CO2Into and block, accordingly it is also possible to according to the temperature trend of T0 come Judge whether ice chest blocks.
The first HyCO ice chests or the blocking of the 2nd HyCO ice chests are referred in the first HyCO ice chests or the 2nd HyCO ice chests Heat exchanger block.
When occur △ P or T0 it is on the rise in the case of, have to search reason, usually the adsorbent of TSA penetrate, The moisture of other techniques penetrates into the H in technique gas side, raw material2O or CO2The reasons such as content is high, the adsorption cycle of TSA is long.
Once ice chest blocks, being in the process of running can not be H2O or CO2It is removed, it is necessary to right after a stoppage Ice chest risen again (>0 DEG C), with dry N2(dew point<- 80 DEG C) it is purged.
Compared with prior art, the present invention has the following advantages and beneficial effects:
1st, it is simple in structure, the normal use of HyCO ice chests and temperature-change adsorption tower etc. is not influenced.
2nd, by setting pressure transmitter and temperature transmitter, whether can intuitively, fast and accurately judge Hyco ice chests There is the situation of blocking.
3rd, System and method for using the present invention, detection efficiency is high, and speed is fast, can take measures in time, can avoid stopping Vehicle reduces loss.
Description of the drawings
Fig. 1 is the system structure diagram for being easy to judge whether HyCO ice chests block.
Figure label:1 is the first temperature-change adsorption tower, and 2 be the second temperature-change adsorption tower, and 3 be the first HyCO ice chests, and 4 be second HyCO ice chests, 5 be CO/H2Knockout drum, 6 be first pressure transmitter, and 7 be second pressure transmitter, and 8 be temperature transmitter, and 9 are Valve, A are Material synthesis gas pipeline, and B is high pressure CO flow path, and C is low pressure CO flow paths, and D is raw hydrogen pipeline, and E is CO pipelines.
Specific embodiment
The present invention is described in detail with specific embodiment below in conjunction with the accompanying drawings.
Embodiment
A kind of system for being easy to judge whether HyCO ice chests block, as shown in Figure 1, first including being connected by pipeline becomes Warm adsorption tower 1, the second temperature-change adsorption tower 2, the first HyCO ice chests 3, the 2nd HyCO ice chests 4 and CO/H2Knockout drum 5, the first HyCO Heat exchanger is both provided in 3 and the 2nd HyCO ice chests 4 of ice chest, CO/H2Knockout drum 5 draws raw hydrogen pipeline D and CO pipeline E, slightly Hydrogen gas lines D sequences are drawn after flowing through the 2nd HyCO ice chests 4 and the heat exchanger of the first HyCO ice chests 3, in the first temperature-change adsorption tower 1 Preceding introducing material synthesis gas pipeline A is provided with first on the pipeline between the second temperature-change adsorption tower 2 and the first HyCO ice chests 3 Pressure transmitter 6 is provided with second pressure transmitter 7 on the raw hydrogen pipeline D after the first HyCO ice chests 3.First Temperature transmitter 8 is provided on pipeline between 3 and the 2nd HyCO ice chests 4 of HyCO ice chests.
First pressure transmitter 6, second pressure transmitter 7 are connect with dcs.Temperature transmitter 8 is with dividing Cloth control system connects.
Valve 9 is provided on Material synthesis gas pipeline A, between the first temperature-change adsorption tower 1 and the second temperature-change adsorption tower 2 Pipeline on be provided with valve 9, be provided with valve 9 on the pipeline between the second temperature-change adsorption tower 2 and the first HyCO ice chests 3.
High pressure CO flow path B sequences flow through the heat exchanger of the first HyCO ice chests 3 and the 2nd HyCO ice chests 4, and low pressure CO flow paths D is suitable Sequence flows through the heat exchanger of the 2nd HyCO ice chests 4 and the first HyCO ice chests 3.
A kind of method for being easy to judge whether HyCO ice chests block, based on system as shown in Figure 1, judgment method is following One or both of two methods:
1st, first pressure transmitter 6 is used as with the display pressure difference value Δ of second pressure transmitter 7 P judges the first HyCO ice chests 3 or the 2nd standard for whether blocking of HyCO ice chests 4, the first HyCO ice chests 3 of Δ P stably expresseds or the 2nd HyCO ice chests 4 are without stifled Plug, Δ P, which rises, represents that the first HyCO ice chests 3 or the 2nd HyCO ice chests 4 block;
2nd, 8 displays temperature value T0 of temperature transmitter, which is used as, judges whether the first HyCO ice chests 3 or the 2nd HyCO ice chests 4 block Standard, the first HyCO ice chests 3 of T0 stably expresseds or the 2nd HyCO ice chests 4 do not block, and T0, which rises, represents the first HyCO ice chests 3 Or the 2nd HyCO ice chests 4 block.
First pressure transmitter 6 shows that pressure value is P1, and second pressure transmitter 7 shows that pressure value is P2, Δ P=P1- P2, △ P are fluctuated up and down with the adjustment of the load of ice chest, and in the case of ice chest steady load, △ P also stablize relatively, if Ice chest steady load, △ P have the tendency that being gradually increasing, and illustrate the heat exchanger of ice chest and have H2O or CO2Into and block, so as to △ P rise, and therefore, judge whether HyCO ice chests block according to △ P.
T0 generally will not up and down be fluctuated with the load of ice chest, in a kind of trend of stabilization, if T0 is gradually increasing Trend, illustrating the heat exchanger of ice chest has H2O or CO2Into and block, accordingly it is also possible to according to the temperature trend of T0 come Judge whether ice chest blocks.
First HyCO ice chests 3 or the blocking of the 2nd HyCO ice chests 4 are referred in the first HyCO ice chests 3 or the 2nd HyCO ice chests 4 Heat exchanger block.
When occur △ P or T0 it is on the rise in the case of, have to search reason, usually the adsorbent of TSA penetrate, The moisture of other techniques penetrates into the H in technique gas side, raw material2O or CO2The reasons such as content is high, the adsorption cycle of TSA is long.
Once ice chest blocks, being in the process of running can not be H2O or CO2It is removed, it is necessary to right after a stoppage Ice chest risen again (>0 DEG C), with dry N2(dew point<- 80 DEG C) it is purged.
The above description of the embodiments is intended to facilitate ordinary skill in the art to understand and use the invention. Person skilled in the art obviously can easily make these embodiments various modifications, and described herein general Principle is applied in other embodiment without having to go through creative labor.Therefore, the present invention is not limited to above-described embodiment, abilities Field technique personnel announcement according to the present invention, improvement and modification made without departing from the scope of the present invention all should be the present invention's Within protection domain.

Claims (7)

1. a kind of system for being easy to judge whether HyCO ice chests block, which is characterized in that first including being connected by pipeline becomes Warm adsorption tower (1), the second temperature-change adsorption tower (2), the first HyCO ice chests (3), the 2nd HyCO ice chests (4) and CO/H2Knockout drum (5), heat exchanger, the CO/H are both provided in the first HyCO ice chests (3) and the 2nd HyCO ice chests (4)2Knockout drum (5) draws Go out raw hydrogen pipeline (D) and CO pipelines (E), the raw hydrogen pipeline (D) sequentially flows through the 2nd HyCO ice chests (4) and the first HyCO It is drawn after the heat exchanger of ice chest (3), material synthesis gas pipeline (A) is introduced before the first temperature-change adsorption tower (1), inhaled in the second alternating temperature First pressure transmitter (6) is provided on pipeline between attached tower (2) and the first HyCO ice chests (3), cold positioned at the first HyCO Second pressure transmitter (7) is provided on raw hydrogen pipeline (D) after case (3), first pressure transmitter (6) becomes with second pressure Device (7) is sent to show pressure difference value Δ P as the standard for judging the first HyCO ice chests (3) or the 2nd HyCO ice chests (4) and whether blocking.
2. a kind of system for being easy to judge whether HyCO ice chests block according to claim 1, which is characterized in that first Temperature transmitter (8), temperature transmitter (8) display are provided on pipeline between HyCO ice chests (3) and the 2nd HyCO ice chests (4) Temperature value T0 is as the standard for judging the first HyCO ice chests (3) or the 2nd HyCO ice chests (4) and whether blocking.
3. a kind of system for being easy to judge whether HyCO ice chests block according to claim 1, which is characterized in that described One pressure transmitter (6), second pressure transmitter (7) are connect with dcs.
A kind of 4. system for being easy to judge whether HyCO ice chests block according to claim 2, which is characterized in that the temperature Degree transmitter (8) is connect with dcs.
5. a kind of system for being easy to judge whether HyCO ice chests block according to claim 1, which is characterized in that in raw material Valve (9) is provided on synthesis gas pipeline (A), the pipeline between the first temperature-change adsorption tower (1) and the second temperature-change adsorption tower (2) On be provided with valve (9), be provided with valve on the pipeline between the second temperature-change adsorption tower (2) and the first HyCO ice chests (3) (9)。
A kind of 6. system for being easy to judge whether HyCO ice chests block according to claim 1, which is characterized in that high pressure CO Flow path (B) sequentially flows through the heat exchanger of the first HyCO ice chests (3) and the 2nd HyCO ice chests (4), and low pressure CO flow paths (D) sequentially flow through The heat exchanger of 2nd HyCO ice chests (4) and the first HyCO ice chests (3).
A kind of 7. method for being easy to judge whether HyCO ice chests block, which is characterized in that based on following system:
Including connected by pipeline the first temperature-change adsorption tower (1), the second temperature-change adsorption tower (2), the first HyCO ice chests (3), Two HyCO ice chests (4) and CO/H2It is both provided in knockout drum (5), the first HyCO ice chests (3) and the 2nd HyCO ice chests (4) Heat exchanger, the CO/H2Knockout drum (5) draws raw hydrogen pipeline (D) and CO pipelines (E), raw hydrogen pipeline (D) sequential flow It draws, is introduced before the first temperature-change adsorption tower (1) former after heat exchanger of the 2nd HyCO ice chests (4) with the first HyCO ice chests (3) Expect synthesis gas pipeline (A), the first pressure is provided on the pipeline between the second temperature-change adsorption tower (2) and the first HyCO ice chests (3) Power transmitter (6) is provided with second pressure transmitter (7) on the raw hydrogen pipeline (D) after the first HyCO ice chests (3), Temperature transmitter (8) is provided on pipeline between the first HyCO ice chests (3) and the 2nd HyCO ice chests (4);
Judgment method is one or both of following two methods:
1st, first pressure transmitter (6) is used as with second pressure transmitter (7) display pressure difference value Δ P judges the first HyCO ice chests (3) or the standard that whether blocks of the 2nd HyCO ice chests (4), the first HyCO ice chests (3) of Δ P stably expresseds or the 2nd HyCO ice chests (4) it does not block, Δ P, which rises, represents that the first HyCO ice chests (3) or the 2nd HyCO ice chests (4) block;
2nd, temperature transmitter (8) displays temperature value T0, which is used as, judges whether the first HyCO ice chests (3) or the 2nd HyCO ice chests (4) block up The standard of plug, the first HyCO ice chests (3) of T0 stably expresseds or the 2nd HyCO ice chests (4) do not block, and T0, which rises, represents first HyCO ice chests (3) or the 2nd HyCO ice chests (4) block.
CN201711463469.9A 2017-12-28 2017-12-28 A kind of System and method for for being easy to judge whether HyCO ice chests block Pending CN108128754A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101245967A (en) * 2007-02-15 2008-08-20 林德股份公司 Method and device for separating a gas mixer
CN102351147A (en) * 2011-07-15 2012-02-15 清华大学 Moderate temperature pressure swing adsorption method for CO2, H2S and H2 mixed gas separation
WO2014012629A2 (en) * 2012-07-17 2014-01-23 Linde Aktiengesellschaft Method and system for producing an h2 product flow and a co product flow
CN105987937A (en) * 2015-01-30 2016-10-05 上海华林工业气体有限公司 Real-time monitoring device for synthetic gas separation HyCO apparatus
CN207933040U (en) * 2017-12-28 2018-10-02 上海华林工业气体有限公司 It is easy to judge the system whether HyCO ice chests block

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101245967A (en) * 2007-02-15 2008-08-20 林德股份公司 Method and device for separating a gas mixer
CN102351147A (en) * 2011-07-15 2012-02-15 清华大学 Moderate temperature pressure swing adsorption method for CO2, H2S and H2 mixed gas separation
WO2014012629A2 (en) * 2012-07-17 2014-01-23 Linde Aktiengesellschaft Method and system for producing an h2 product flow and a co product flow
CN105987937A (en) * 2015-01-30 2016-10-05 上海华林工业气体有限公司 Real-time monitoring device for synthetic gas separation HyCO apparatus
CN207933040U (en) * 2017-12-28 2018-10-02 上海华林工业气体有限公司 It is easy to judge the system whether HyCO ice chests block

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