CN108124864A - A kind of stable type compound sodium nitrophenolate and preparation method thereof - Google Patents
A kind of stable type compound sodium nitrophenolate and preparation method thereof Download PDFInfo
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- CN108124864A CN108124864A CN201810123069.1A CN201810123069A CN108124864A CN 108124864 A CN108124864 A CN 108124864A CN 201810123069 A CN201810123069 A CN 201810123069A CN 108124864 A CN108124864 A CN 108124864A
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- Prior art keywords
- sodium
- sodium nitrophenolate
- compound sodium
- stable type
- nitrophenolate
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N33/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds
- A01N33/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic nitrogen compounds containing nitrogen-to-oxygen bonds
- A01N33/18—Nitro compounds
- A01N33/20—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group
- A01N33/22—Nitro compounds containing oxygen or sulfur attached to the carbon skeleton containing the nitro group having at least one oxygen or sulfur atom and at least one nitro group directly attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/12—Powders or granules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/22—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients stabilising the active ingredients
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- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Fireproofing Substances (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of stable type compound sodium nitrophenolate and preparation method thereof, the stable type compound sodium nitrophenolate is prepared by the raw material of following weight percent：Compound sodium nitrophenolate 80 98%, fire retardant 1~20%；The compound sodium nitrophenolate of the present invention is overcome during 5 nitre guaiacol sodium, Sodium p-nitrophenoxide, sodium onitrophenol co-grinding prepare compound sodium nitrophenolate pulvis, it is flammable to avoid three monomers chance high fevers, the problem of being thermally decomposed by height, and the addition of fire retardant reduces dangerous hidden danger in production process, improves the stability of product；And fire retardant without organic solvent, has the advantages that nontoxic, harmless, smokeless, Halogen in itself, has had both the advantages of environmental protection is low with use cost.
Description
Technical field
The present invention relates to compound sodium nitrophenolate fields, are specifically related to a kind of stable type compound sodium nitrophenolate and preparation method thereof.
Background technology
Compound sodium nitrophenolate is a kind of strength cell-activating agent, and chemical analysis is 5- nitroguaiacol sodium salts, o-nitrophenol
Sodium, Sodium p-nitrophenoxide.With being penetrated into plant rapidly after plant contact, the plasm of cell being promoted to flow, is improved thin
Born of the same parents' vigor.Compound sodium nitrophenolate pulvis by sodium onitrophenol, three monomers of Sodium p-nitrophenoxide and 5- nitroguaiacol sodium salts according to
Certain proportion mixes.Sodium onitrophenol：Red acicular crystal, has light alcohol fragrance, and 44.9 DEG C of fusing point is soluble in
Water dissolves in ethyl alcohol, acetone and other organic solvent, stable storing under normal condition；Sodium p-nitrophenoxide：Yellow flat crystal melts
113-114 DEG C of point, it is soluble easily in water, dissolve in ethyl alcohol, acetone and other organic solvent, stable storing under normal condition；5- nitros are more created
Wooden phenol sodium：Chinese red or purplish red flaky crystal, 105-106 DEG C of fusing point is soluble easily in water, dissolves in ethyl alcohol, methanol, acetone etc.
Organic solvent, stable storing under normal condition.
But prepare compound nitrophenol sodium powder in 5- nitre guaiacol sodium, Sodium p-nitrophenoxide, sodium onitrophenol co-grinding
During agent, three monomers often occur meet high fever it is flammable, the problem of thermal decomposition by height；And compound sodium nitrophenolate finished product is in life
It is susceptible to during production, packaging, transport, use and meets the problem of high fever is flammable.
Invention content
In view of the deficiencies of the prior art mentioned above, the present invention provides a kind of stable type compound sodium nitrophenolate and preparation method thereof.
To achieve these goals, the technical solution used in the present invention is：A kind of stable type compound sodium nitrophenolate, it be by with
The raw material of lower weight percent is prepared：Compound sodium nitrophenolate 80-98%, fire retardant 1~20%.
Further, fire retardant of the present invention is selected from aluminium hydroxide, magnesium hydroxide, monoammonium phosphate, Diammonium phosphate (DAP), chlorine
Change the mixing of one or more of ammonium, boric acid, tetrabromobisphenol A, methenamine.
The preparation method of aforementioned stable type compound sodium nitrophenolate includes the following steps：
Step 1: 5- nitroguaiacol sodium salts, o-nitrophenol sodium, p- p-nitrophenol sodium are weighed by proportion speed, then will be each
Monomer is dried 2 hours under 105 DEG C of vacuum condition；
Step 2: dried each monomer is crushed respectively and adds in fire retardant, then the material after crushing is pressed into certain proportioning
It is uniformly mixed；
Step 3: being sieved by sealing vibrating screen, the mesh number of vibrating screen is 18-30；
Step 4: sample examination, indices are qualified, you can compound sodium nitrophenolate pulvis, then it is packaged after obtain finished product.
The principle of the present invention is：Due to adding fire retardant in the present invention so that the active constituent content of the present invention is steady
It is fixed, it avoids 5- nitroguaiacol sodium salts, sodium onitrophenol, Sodium p-nitrophenoxide co-grinding and prepares compound sodium nitrophenolate in the presence of chance
High fever is flammable, by the situation of height thermal decomposition；Fire retardant：Also known as incombustible agent, fire-proofing chemical or fireproof agent are to confer to combustible polymers hardly possible
The functional aid of combustion property；It is divided into additive flame retardant and reactive flame retardant according to application mode.According to composition, additive flame retardant
Agent mainly includes inorganic combustion inhibitor, halogenated flame retardant（Organic chloride and organic bromide）, phosphorus flame retardant（Red phosphorus, phosphoric acid
Ester and halogenated phosphate etc.）With nitrogenated flame retardant etc..By adding fire retardant in the production of compound sodium nitrophenolate pulvis, multiple nitre is reduced
The resolution ratio of three monomer components of phenol sodium, while it is high to avoid chance of the compound sodium nitrophenolate during production, packaging, transport, use
The problem of heat is flammable reduces potential hazard for the processing of compound sodium nitrophenolate powder product, and the safety in production for compound sodium nitrophenolate pulvis makes
It is ensured with providing.
The beneficial effects of the invention are as follows：The present invention compound sodium nitrophenolate overcome 5- nitre guaiacol sodium, Sodium p-nitrophenoxide,
During sodium onitrophenol co-grinding prepares compound sodium nitrophenolate pulvis, avoiding three monomers, to meet high fevers flammable, by high fever
The problem of decomposition, and the addition of fire retardant reduces dangerous hidden danger in production process, improves the stability of product；It is and fire-retardant
Agent has the advantages that nontoxic, harmless, smokeless, Halogen in itself without organic solvent, has had both environmentally friendly low with use cost excellent
Point.
Specific embodiment
With reference to embodiment, embodiment of the present invention is described further.
Embodiment 1
The stable type compound sodium nitrophenolate of the present invention is prepared by the raw material of following weight percent：Compound sodium nitrophenolate 82%, hydroxide
Magnesium 3%.
The preparation method of stable type compound sodium nitrophenolate includes the following steps described in the present embodiment：
Step 1: 5- nitroguaiacol sodium salts, o-nitrophenol sodium, p- p-nitrophenol sodium are weighed by proportion speed, then will be each
Monomer is dried 2 hours under 105 DEG C of vacuum condition；
Step 2: dried each monomer is crushed respectively and adds in fire retardant, then the material after crushing is pressed into certain proportioning
It is uniformly mixed；
Step 3: being sieved by sealing vibrating screen, the mesh number of vibrating screen is 18-30；
Step 4: sample examination, indices are qualified, you can compound sodium nitrophenolate pulvis, then it is packaged after obtain finished product.
Embodiment 2
The stable type compound sodium nitrophenolate of the present invention, it is prepared by the raw material of following weight percent：Compound sodium nitrophenolate 88%, phosphorus
Sour monoammonium and Diammonium phosphate (DAP) totally 9%, preparation method is the same as embodiment 1.
Embodiment 3
The stable type compound sodium nitrophenolate of the present invention, it is prepared by the raw material of following weight percent：Compound sodium nitrophenolate 90%, chlorine
Change ammonium 13%, preparation method is the same as embodiment 1.
Embodiment 4
The stable type compound sodium nitrophenolate of the present invention, it is prepared by the raw material of following weight percent：Compound sodium nitrophenolate 92%, four
Bromine bisphenol-A 16%, preparation method is the same as embodiment 1.
Embodiment 5
The stable type compound sodium nitrophenolate of the present invention, it is prepared by the raw material of following weight percent：Compound sodium nitrophenolate 95%, hydrogen
Aluminium oxide 19%, preparation method is the same as embodiment 1.
Claims (3)
1. a kind of stable type compound sodium nitrophenolate, it is characterised in that：It is prepared by the raw material of following weight percent：Compound nitrophenol
Sodium 80-98%, fire retardant 1~20%.
2. stable type compound sodium nitrophenolate according to claim 1, it is characterised in that：The fire retardant be selected from aluminium hydroxide,
One or more of magnesium hydroxide, monoammonium phosphate, Diammonium phosphate (DAP), ammonium chloride, boric acid, tetrabromobisphenol A, methenamine mix
It closes.
A kind of 3. method for preparing stable type compound sodium nitrophenolate described in claim 1, it is characterised in that：The method includes following steps
Suddenly：
Step 1: 5- nitroguaiacol sodium salts, o-nitrophenol sodium, p- p-nitrophenol sodium are weighed by proportion speed, then will be each
Monomer is dried 2 hours under 105 DEG C of vacuum condition；
Step 2: dried each monomer is crushed respectively and adds in fire retardant, then the material after crushing is pressed into certain proportioning
It is uniformly mixed；
Step 3: being sieved by sealing vibrating screen, the mesh number of vibrating screen is 18-30；
Step 4: sample examination, indices are qualified, you can compound sodium nitrophenolate pulvis, then it is packaged after obtain finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810123069.1A CN108124864A (en) | 2018-02-07 | 2018-02-07 | A kind of stable type compound sodium nitrophenolate and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810123069.1A CN108124864A (en) | 2018-02-07 | 2018-02-07 | A kind of stable type compound sodium nitrophenolate and preparation method thereof |
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| CN108124864A true CN108124864A (en) | 2018-06-08 |
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| CN201810123069.1A Pending CN108124864A (en) | 2018-02-07 | 2018-02-07 | A kind of stable type compound sodium nitrophenolate and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109479889A (en) * | 2018-11-08 | 2019-03-19 | 镇江先锋植保科技有限公司 | The preparation method of non-combustible thiodicarb shot agent |
| CN113207879A (en) * | 2021-05-13 | 2021-08-06 | 何志松 | Preparation method of compound sodium nitrophenolate for plant growth regulator |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1501837A (en) * | 2001-04-10 | 2004-06-02 | 拜尔农作物科学股份公司 | Microcapsules |
| CN103053515A (en) * | 2013-02-04 | 2013-04-24 | 广西田园生化股份有限公司 | Thermal spray drug delivery agent |
| CN103583538A (en) * | 2013-10-14 | 2014-02-19 | 广东中迅农科股份有限公司 | Flame-retardant-containing mancozeb wettable powder |
| CN103975950A (en) * | 2013-06-04 | 2014-08-13 | 桂林桂开生物科技股份有限公司 | Plant growth regulator and preparation method thereof |
| CN107624762A (en) * | 2017-10-12 | 2018-01-26 | 江西天祥通用航空股份有限公司 | Bromine cyanogen insect amide opens up film oil-suspending agent |
-
2018
- 2018-02-07 CN CN201810123069.1A patent/CN108124864A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1501837A (en) * | 2001-04-10 | 2004-06-02 | 拜尔农作物科学股份公司 | Microcapsules |
| CN103053515A (en) * | 2013-02-04 | 2013-04-24 | 广西田园生化股份有限公司 | Thermal spray drug delivery agent |
| CN103975950A (en) * | 2013-06-04 | 2014-08-13 | 桂林桂开生物科技股份有限公司 | Plant growth regulator and preparation method thereof |
| CN103583538A (en) * | 2013-10-14 | 2014-02-19 | 广东中迅农科股份有限公司 | Flame-retardant-containing mancozeb wettable powder |
| CN107624762A (en) * | 2017-10-12 | 2018-01-26 | 江西天祥通用航空股份有限公司 | Bromine cyanogen insect amide opens up film oil-suspending agent |
Non-Patent Citations (1)
| Title |
|---|
| 郭玉人: "《农药安全使用手册》", 30 September 2009 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109479889A (en) * | 2018-11-08 | 2019-03-19 | 镇江先锋植保科技有限公司 | The preparation method of non-combustible thiodicarb shot agent |
| CN113207879A (en) * | 2021-05-13 | 2021-08-06 | 何志松 | Preparation method of compound sodium nitrophenolate for plant growth regulator |
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