CN108107602A - A kind of ophthalmic len superhard coating - Google Patents

A kind of ophthalmic len superhard coating Download PDF

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Publication number
CN108107602A
CN108107602A CN201711343573.4A CN201711343573A CN108107602A CN 108107602 A CN108107602 A CN 108107602A CN 201711343573 A CN201711343573 A CN 201711343573A CN 108107602 A CN108107602 A CN 108107602A
Authority
CN
China
Prior art keywords
coating
ophthalmic len
glass ionomer
products
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711343573.4A
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Chinese (zh)
Inventor
孙为民
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Golden House Optical Glasses Ltd By Share Ltd
Original Assignee
Jiangsu Golden House Optical Glasses Ltd By Share Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Golden House Optical Glasses Ltd By Share Ltd filed Critical Jiangsu Golden House Optical Glasses Ltd By Share Ltd
Priority to CN201711343573.4A priority Critical patent/CN108107602A/en
Publication of CN108107602A publication Critical patent/CN108107602A/en
Pending legal-status Critical Current

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Classifications

    • GPHYSICS
    • G02OPTICS
    • G02CSPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
    • G02C7/00Optical parts
    • G02C7/02Lenses; Lens systems ; Methods of designing lenses
    • G02C7/024Methods of designing ophthalmic lenses
    • GPHYSICS
    • G02OPTICS
    • G02BOPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/10Optical coatings produced by application to, or surface treatment of, optical elements
    • G02B1/14Protective coatings, e.g. hard coatings

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  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Ophthalmology & Optometry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • General Health & Medical Sciences (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to a kind of ophthalmic len superhard coating, in parts by weight, including:10 15 parts of glass ionomer;Tetrem supports 10 15 parts of base silane;13 parts of alumina powder;15 20 parts of ethylene glycol;5 10 parts of glacial acetic acid.By adding glass ionomer in inventive formulation, the scratch resistant performance of entire coating can be improved.

Description

A kind of ophthalmic len superhard coating
Technical field
The present invention relates to glasses manufacturing fields, and in particular to a kind of ophthalmic len superhard coating.
Background technology
Resin lens are a kind of organic materials, and inside is a kind of macromolecule chain structure, connection and spatially net structure, Intermolecular structure relative relaxation, molecule interchain have the space that can generate relative displacement.Light-transmissive rate is 84%-90%, thoroughly Photosensitiveness is good, while optical resin lens anti-impact force is strong.
Existing ophthalmic len generally all selects resin lens, and existing resin lens generally select aluminium oxide or titanium dioxide Silicon coating, but the hardness of these coatings is general, and under extreme conditions, the minute surface of the coating still can damage.
In view of the above shortcomings, the designer, is actively subject to research and innovation, to found a kind of glasses of new structure Piece superhard coating makes it with more the utility value in industry.
The content of the invention
In order to solve the above technical problems, the object of the present invention is to provide a kind of ophthalmic len superhard coatings.
Technical scheme is as follows:
A kind of ophthalmic len superhard coating, which is characterized in that in parts by weight, including:
Further, a kind of preparation method of ophthalmic len superhard coating, which is characterized in that including following steps:
S1, alumina powder is ground to nanoscale by super grinder;
S2, alumina powder is added in glass ionomer, it is stirred by ultrasonic stirrer;
S3, glass ionomer is irradiated with ultraviolet light, irradiation time is specially 0.5 second, makes glass ionomer material Expect surface semi-solid preparation, then it is stirred by mixer;
S4, stirring simultaneously mix tetrem and support base silane, ethylene glycol and glacial acetic acid;
S5, step S3 products and step S4 products are mixed, and passes through infrared heater and be warming up to 80-90 DEG C;
S6, S5 products are cooled to room temperature, are ejected by jet blower on ophthalmic len and form coating, and shone by ultraviolet light Penetrate coating 8-10 seconds.
Further, a kind of preparation method of ophthalmic len superhard coating, it is characterised in that:In the step S5, the painting The thickness of layer is 200-300nm.
According to the above aspect of the present invention, the present invention has at least the following advantages:
(1) by adding glass ionomer in inventive formulation, the scratch resistant performance of entire coating can be improved;
(2) present invention is irradiated in preparation process using ultraviolet light twice, while by glass ion water during irradiation for the first time Door spit of fland semi-solid preparation, first, can cure a part of glass ionomer in preparation process, increases each material in mixed process Structural capacity, second is that mitigate the later stage injection after curing of coatings time.
Above description is only the general introduction of technical solution of the present invention, in order to better understand the technological means of the present invention, And can be practiced according to the content of specification, below with presently preferred embodiments of the present invention and be described in detail as after.
Specific embodiment
With reference to embodiment, the specific embodiment of the present invention is described in further detail.Following embodiment is used for Illustrate the present invention, but be not limited to the scope of the present invention.
Embodiment 1
A kind of preparation method of ophthalmic len superhard coating, including following steps:
S1, alumina powder is ground to nanoscale by super grinder;
S2, alumina powder is added in glass ionomer, it is stirred by ultrasonic stirrer;
S3, glass ionomer is irradiated with ultraviolet light, irradiation time is specially 0.5 second, makes glass ionomer material Expect surface semi-solid preparation, then it is stirred by mixer;
S4, stirring simultaneously mix tetrem and support base silane, ethylene glycol and glacial acetic acid;
S5, step S3 products and step S4 products are mixed, and passes through infrared heater and be warming up to 80-90 DEG C;
S6, S5 products are cooled to room temperature, are ejected by jet blower on ophthalmic len and form coating, and shone by ultraviolet light Penetrate coating 8 seconds.
In-step the S5, the thickness of the coating is 200nm.
In the above method in parts by weight, raw material includes:
Embodiment 2
A kind of preparation method of ophthalmic len superhard coating, including following steps:
S1, alumina powder is ground to nanoscale by super grinder;
S2, alumina powder is added in glass ionomer, it is stirred by ultrasonic stirrer;
S3, glass ionomer is irradiated with ultraviolet light, irradiation time is specially 0.5 second, makes glass ionomer material Expect surface semi-solid preparation, then it is stirred by mixer;
S4, stirring simultaneously mix tetrem and support base silane, ethylene glycol and glacial acetic acid;
S5, step S3 products and step S4 products are mixed, and passes through infrared heater and be warming up to 80-90 DEG C;
S6, S5 products are cooled to room temperature, are ejected by jet blower on ophthalmic len and form coating, and shone by ultraviolet light Penetrate coating 8 seconds.
In-step the S5, the thickness of the coating is 250nm.
In the above method in parts by weight, raw material includes:
Embodiment 3
A kind of preparation method of ophthalmic len superhard coating, including following steps:
S1, alumina powder is ground to nanoscale by super grinder;
S2, alumina powder is added in glass ionomer, it is stirred by ultrasonic stirrer;
S3, glass ionomer is irradiated with ultraviolet light, irradiation time is specially 0.5 second, makes glass ionomer material Expect surface semi-solid preparation, then it is stirred by mixer;
S4, stirring simultaneously mix tetrem and support base silane, ethylene glycol and glacial acetic acid;
S5, step S3 products and step S4 products are mixed, and passes through infrared heater and be warming up to 80-90 DEG C;
S6, S5 products are cooled to room temperature, are ejected by jet blower on ophthalmic len and form coating, and shone by ultraviolet light Penetrate coating 8 seconds.
In-step the S5, the thickness of the coating is 300nm.
In the above method in parts by weight, raw material includes:
Scratch resistant performance test
Project Test content Test front coating thickness (%) Coating layer thickness (nm) after test
Embodiment 1 1000 wipings of cotton 100 98.3
Embodiment 2 1000 wipings of cotton 100 97.9
Embodiment 3 1000 wipings of cotton 100 96.1
The present invention has at least the following advantages:
(1) by adding glass ionomer in inventive formulation, the scratch resistant performance of entire coating can be improved;
(2) present invention is irradiated in preparation process using ultraviolet light twice, while by glass ion water during irradiation for the first time Door spit of fland semi-solid preparation, first, can cure a part of glass ionomer in preparation process, increases each material in mixed process Structural capacity, second is that mitigate the later stage injection after curing of coatings time.
The above is only the preferred embodiment of the present invention, is not intended to limit the invention, it is noted that for this skill For the those of ordinary skill in art field, without departing from the technical principles of the invention, can also make it is several improvement and Modification, these improvements and modifications also should be regarded as protection scope of the present invention.

Claims (3)

1. a kind of ophthalmic len superhard coating, which is characterized in that in parts by weight, including:
2. the preparation method of a kind of ophthalmic len superhard coating according to claim 1, which is characterized in that including following Step:
S1, alumina powder is ground to nanoscale by super grinder;
S2, alumina powder is added in glass ionomer, it is stirred by ultrasonic stirrer;
S3, glass ionomer is irradiated with ultraviolet light, irradiation time is specially 0.5 second, makes glass ionomer material table Face semi-solid preparation, then it is stirred by mixer;
S4, stirring simultaneously mix tetrem and support base silane, ethylene glycol and glacial acetic acid;
S5, step S3 products and step S4 products are mixed, and passes through infrared heater and be warming up to 80-90 DEG C;
S6, S5 products are cooled to room temperature, are ejected by jet blower on ophthalmic len and form coating, and irradiated and applied by ultraviolet light Layer 8-10 seconds.
3. a kind of preparation method of ophthalmic len superhard coating according to claim 2, it is characterised in that:The step S5 In, the thickness of the coating is 200-300nm.
CN201711343573.4A 2017-12-15 2017-12-15 A kind of ophthalmic len superhard coating Pending CN108107602A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711343573.4A CN108107602A (en) 2017-12-15 2017-12-15 A kind of ophthalmic len superhard coating

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711343573.4A CN108107602A (en) 2017-12-15 2017-12-15 A kind of ophthalmic len superhard coating

Publications (1)

Publication Number Publication Date
CN108107602A true CN108107602A (en) 2018-06-01

Family

ID=62216073

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711343573.4A Pending CN108107602A (en) 2017-12-15 2017-12-15 A kind of ophthalmic len superhard coating

Country Status (1)

Country Link
CN (1) CN108107602A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002060342A (en) * 2000-08-17 2002-02-26 Gc Corp Glass ionomer-based fluorine coating material
CN101010400A (en) * 2004-09-01 2007-08-01 触媒化成工业株式会社 Coating liquid for forming transparent coating film and base with transparent coating film
CN102421861A (en) * 2009-05-20 2012-04-18 株式会社德山 Coating composition and optical article
CN106415330A (en) * 2014-02-04 2017-02-15 东海光学株式会社 Optical product, glasses lens and glasses

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002060342A (en) * 2000-08-17 2002-02-26 Gc Corp Glass ionomer-based fluorine coating material
CN101010400A (en) * 2004-09-01 2007-08-01 触媒化成工业株式会社 Coating liquid for forming transparent coating film and base with transparent coating film
CN102421861A (en) * 2009-05-20 2012-04-18 株式会社德山 Coating composition and optical article
CN106415330A (en) * 2014-02-04 2017-02-15 东海光学株式会社 Optical product, glasses lens and glasses

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王晓玲: "《口腔材料学》", 31 December 2013 *

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SE01 Entry into force of request for substantive examination
CB02 Change of applicant information

Address after: 212300 Situ Town Eyeglasses Industrial Park, Danyang City, Zhenjiang City, Jiangsu Province

Applicant after: Jiangsu Golden House Optical Glasses Co., Ltd.

Address before: 212300 Situ Town Eyeglasses Industrial Park, Danyang City, Zhenjiang City, Jiangsu Province

Applicant before: Jiangsu Golden House optical glasses Limited by Share Ltd

CB02 Change of applicant information
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20180601

WD01 Invention patent application deemed withdrawn after publication