CN108107017A - Method based on the distribution of terahertz detection high-risk chemical - Google Patents

Method based on the distribution of terahertz detection high-risk chemical Download PDF

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Publication number
CN108107017A
CN108107017A CN201711329777.2A CN201711329777A CN108107017A CN 108107017 A CN108107017 A CN 108107017A CN 201711329777 A CN201711329777 A CN 201711329777A CN 108107017 A CN108107017 A CN 108107017A
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risk chemical
concentration
air high
target acquisition
information
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CN108107017B (en
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郑小平
李浩华
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Tsinghua University
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Tsinghua University
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Priority to CN201711329777.2A priority Critical patent/CN108107017B/en
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Priority to PCT/CN2018/092436 priority patent/WO2019114239A1/en
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Priority to US16/446,620 priority patent/US20190302012A1/en
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3581Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using far infrared light; using Terahertz radiation
    • G01N21/3586Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light using far infrared light; using Terahertz radiation by Terahertz time domain spectroscopy [THz-TDS]
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N21/00Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
    • G01N21/17Systems in which incident light is modified in accordance with the properties of the material investigated
    • G01N21/25Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
    • G01N21/31Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
    • G01N21/35Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light
    • G01N21/3504Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infrared light for analysing gases, e.g. multi-gas analysis

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  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Toxicology (AREA)
  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

The present invention relates to a kind of methods of terahertz detection air high-risk chemical distribution:The concentration distribution information of the air high-risk chemical of current detecting location is obtained by detection device;Target acquisition position is drawn according to the concentration distribution information, driving detection device marches to the target acquisition position;The air high-risk chemical concentration distribution information of the target acquisition position is obtained again, obtains the air high-risk chemical concentration distribution information of multigroup detecting location;By the invention it is possible to which realizing is needing to make the complex environment judged rapidly, can more elements such as air high-risk chemical composition, concentration, trend be subjected to solid and showed;It realizes the originally discrete concentration data progress continuous treatment for measuring and obtaining, crowd evacuation measure and malicious source suppressing method can quickly and effectively be made in air high-risk chemical leak scene by realizing.

Description

Method based on the distribution of terahertz detection high-risk chemical
Technical field
The present invention relates to Environmental security field, more particularly to a kind of based on the distribution of terahertz detection high-risk chemical Method.
Background technology
Usually, at explosion or attack of terrorism scene, it is high-risk often to there is the indefinite air of one or several kinds of ingredients Chemicals.But due to the complexity of site environment, people are often difficult to determine that the ingredient of air high-risk chemical, air are high The source of danger chemicals and the propagation path of air high-risk chemical, therefore can not quickly and effectively make crowd and dredge The measure of dissipating and malicious source suppressing method, great loss is caused to the security of the lives and property of the people, and is the high-risk chemistry of air The tracking and inhibition in product source eliminate work and bring many difficulties.
Existing gas detecting system is only limitted to demarcate air high-risk chemical species and its concentration, measure, and Composite measurement cannot be carried out to the distribution situation of the air high-risk chemical leakage information in leakage region and intuitively showed, it is difficult Commanding to be helped to formulate the Restrain measurement of gas leakage source and crowd evacuation scheme rapidly.
The content of the invention
Based on this, it is necessary in traditional technology, it is impossible to the air high-risk chemical leakage information in leak area Distribution situation composite measurement and intuitively show, it is difficult to it is rapid formulate air high-risk chemical source of leaks Restrain measurement with The problem of formulating crowd evacuation scheme, provide it is a kind of flexibly, intuitively probe gas spatial distribution method.
A kind of method based on terahertz detection high-risk chemical, the described method includes:
The concentration distribution information of the air high-risk chemical of current detecting location is obtained by detection device;
According to the air high-risk chemical concentration distribution acquisition of information target acquisition position, driving detection device is advanced To the target acquisition position;
The air high-risk chemical concentration distribution information of the target acquisition position is obtained again;
Next target acquisition position is obtained according to the air high-risk chemical concentration distribution information of the target acquisition position It puts, until the coordinate of next target acquisition position is overlapped with the coordinate of any detecting location before, obtains multigroup detection position The air high-risk chemical concentration distribution information put;
The Gas concentration distribution information of multigroup detecting location is sent to data handling system to handle, is obtained Air high-risk chemical spatial distribution image information.
In one of the embodiments, the detection device is terahertz time-domain system.
In one of the embodiments, the terahertz time-domain system is transmission-type terahertz time-domain system.
In one of the embodiments, the acquisition methods of next target acquisition position include:
All concentration distribution information acquired in three-dimensional coordinate are ranked up, obtain concentration highest in three-dimensional coordinate The direction of point is the direct of travel of the driving device;
The driving device marches to next target acquisition position along the direct of travel.
In one of the embodiments, it is described to all concentration distribution information acquired in the three dimensions of current location Be ranked up, including by Bubble Sort Algorithm to all concentration distribution information acquired in the three dimensions of current location into Row sequence.
In one of the embodiments, it is described to be visited according to the air high-risk chemical concentration distribution information acquisition target Location is put, and detection device is driven to march to the target acquisition position and is further included:
To the concentration information averaged in the different height of current location, the highest height of mean concentration is obtained as mesh Absolute altitude degree;
The concentration of different angle in the highest height of the mean concentration is ranked up, obtains the mean concentration The highest angle of concentration is the target angle of the driving device in highest height;
The detection device is driven to march to the target acquisition position according to the object height and target angle.
In one of the embodiments, the concentration information by multigroup a certain air high-risk chemical distribution transmits The step of being handled to data handling system, obtaining air high-risk chemical spatial distribution image information includes:
Multigroup a certain air high-risk chemical is sent to numerical value compared with the concentration information that three-dimensional coordinate is distributed Fitting system carries out numerical fitting, obtains a certain air high-risk chemical and believes compared with the continuously distributed concentration of three-dimensional coordinate Breath;
The concentration information continuously distributed compared with three-dimensional coordinate is identified, obtains a certain air high-riskization Product spatial distribution map;
In one of the embodiments, the air high-risk chemical concentration distribution information according to the current location, The air high-risk chemical concentration distribution information of the target acquisition position, obtains air high-risk chemical spatial distribution image It further includes afterwards:
Different types of air high-risk chemical is detected respectively by multiple detection devices, is obtained a variety of The gas compartment distributed image of variety classes gas;
Different types of air high-risk chemical distributed image is overlapped processing, obtains variety classes air High-risk chemical spatial distribution superimposed image, and the variety classes air high-risk chemical spatial distribution superimposed image is defeated Go out.
In one of the embodiments, the concentration information continuously distributed compared with three-dimensional coordinate is subjected to color mark Know.
A kind of computer readable storage medium, is stored thereon with computer program, which can when being executed by processor The step of realizing any of the above embodiment.
Description of the drawings
Fig. 1 is the reflexive feedback system of Terahertz for the air high-risk chemical detection that one embodiment provides;
Fig. 2 is the structure chart of the telescope support that one embodiment provides and cantilever;
Fig. 3 is the transmission-type terahertz time-domain system that one embodiment provides;
Fig. 4 is the method flow diagram for the terahertz detection air high-risk chemical concentration distribution that one embodiment provides;
Fig. 5 is the method flow diagram for the single high-risk chemical source of leakage of terahertz detection that one embodiment provides;
Fig. 6 is the method flow diagram that the judgement detection device that one embodiment provides reaches source of leaks;
Fig. 7 is multiple high-risk chemical source of leaks detection method flow charts that one embodiment provides;
Fig. 8 is provided for one embodiment when detection tri- kinds of air high-risk chemicals of a, b, c, sets specific rotating shaft The method flow diagram of the wicking height of rotation angle and telescope support;
Fig. 9 is a certain air high-risk chemical concentration result of detection distribution map that one embodiment provides;
Figure 10 is that a variety of air high-risk chemical concentration result of detection that one embodiment provides are distributed stacking chart.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, it is right with reference to the accompanying drawings and embodiments The present invention is further elaborated.It should be appreciated that specific embodiment described herein is only to explain the present invention, and It is not used in the restriction present invention.
Referring to Fig. 1, a kind of reflexive feedback system of Terahertz of air high-risk chemical detection is provided in one embodiment 1000, described device includes:
Detection device 100, the detection device 100 are used for atmospheric sounding high-risk chemical information.
Specifically, detection device 100 is for being sampled to air high-risk chemical, and obtain the high-risk chemistry of air The device of product Terahertz feature, air high-risk chemical information specifically includes air high-risk chemical concentration information and air is high Danger chemical race category information.
Mechanic adjustment unit 110, the mechanic adjustment unit 110 is connected with the detection device 100, for adjusting The height and orientation of detection device 100 are stated, to obtain the air high-risk chemical information of different height and orientation.
Mechanic adjustment unit 110 carries out the position of detection device 100 pair by mechanical structure according to the instruction of processor It should adjust, height and orientation including adjusting detection device 100, be sat so as to change the three-dimensional of 100 stop places of detection device It marks (x, y, z), including abscissa x, ordinate y and vertical coordinate z.Specifically, mechanic adjustment unit adjusts detection device 100 Three-dimensional coordinate, to obtain in three dimensions the air high-risk chemical concentration distribution under different three-dimensional coordinates, obtain (n, a, B, c), including air high-risk chemical concentration n, abscissa a, ordinate b and vertical coordinate c.When detection device 100 In (x1,y1,z1) detect air high-risk chemical concentration distribution coordinate (n1,a1,b1,c1) when, then there is x1=a1,y1=b1,z1 =c1
Moving bearing device 120, the moving bearing device 120 carries the mechanic adjustment unit 110, and drives institute It states detection device 100 to move in space, to obtain the air high-risk chemical information of different position.
Wherein moving bearing device 120 can be mechanically connected with mechanic adjustment unit 110, and mechanic adjustment unit 110 can be set In on moving bearing device 120, moved with the movement of moving bearing device 120.It is similar, mechanic adjustment unit 110 with Detection device 100 is mechanically connected, and is moved with the movement of moving bearing device 120.Moving bearing device 120 passes through shifting Dynamic mechanic adjustment unit 110 is carried out movement detector 100 and is moved in space, and moving bearing device 120 is for detection device 100 movement can be to move horizontally;Meanwhile mechanic adjustment unit 110 can adjust the height and orientation of detection device 100 simultaneously.
Processor 130, the processor 130 are used to handle the high-risk chemistry of air that the detection device 100 is detected Product information, and according to the handling result of air high-risk chemical information feedback, that the mechanic adjustment unit is controlled to adjust is high Degree, orientation and moving bearing device movement, and the air high-risk chemical information is handled.
Processor 130 be information receive center, Information Analysis Center, feedback information generation center, information dispatching centre with And control centre, be realize air high-risk chemical detection system detection accuracy device.
In one of the embodiments, the moving bearing device includes babinet 121;The mechanic adjustment unit installation On the moving bearing device, the processor 130 is located in the babinet 121.Specifically, mechanic adjustment unit can lead to It crosses shaft 113 to be connected with moving bearing device, shaft can carry out 360 ° of rotations, so as to which mechanic adjustment unit be driven to carry out 360 ° of rotations.For example, shaft can carry out 360 ° of rotations in the horizontal direction, so that detection device 100 can be located In different orientation, i.e., different (x, y) coordinates.In one of the embodiments, processor is placed in babinet 121, to processing Device has protective effect.Specifically, the move mode of mobile bearing mode is unlimited, and moving bearing device 120 may include universal wheel 126, pulley and other can realize moving bearing device movement device or method all may be used.
In one of the embodiments, the processor 130 may include data processing module and control module, the number Sort operation, the source of leakage that the computing carried out according to processing module includes carrying out the air high-risk chemical information are sentenced Disconnected computing, data fitting operation, image superposition computing, coordinate coincidence judge computing, and the control module is used for according to the number Instruction is sent to the air high-risk chemical spatial distribution detection device 100 according to the operation result of processing module, and drives institute Air high-risk chemical spatial distribution detection device 100 is stated to be moved.
In one embodiment, the reflexive feedback system detection device 100 of Terahertz of air high-risk chemical detection is terahertz Hereby time domain system, including air high-risk chemical sampling room 1021.
In addition, Terahertz air high-risk chemical detection system 1000 further includes feedback and instruction transmission electric wire 122, use In the result of detection of reception detection device 100, and result of detection is transmitted to processor 130, and processor 130 is exported Control instruction passes to moving bearing device and mechanic adjustment unit, and to control, moving bearing device is mobile, adjusts mechanical adjustment Device, such as height of telescoping shoring column 113 etc..
Meanwhile Terahertz air high-risk chemical detection system 1000 may also include power set 124, the power dress 124 are put to may be disposed in moving bearing device 120;The power set 124 can be accumulator, be Terahertz air high-riskization Product detection system provides power.
The detection device 100 may include terahertz time-domain system, and further, detection device 100 may include transmission-type too Hertz time domain system, detects object for passing through THz wave.
Also referring to Fig. 2, in one of the embodiments, the mechanic adjustment unit 110 includes telescope support 114 With cantilever 112, telescope support 114 has card slot 1141, and card slot 1141 is used to cantilever 112 being fixed on telescope support 114; Spring 1142 is provided in card slot 1141, spring 1142 controls the vertical height of cantilever to change by self-deformation, and then controls Detection device height change.The telescope support is connected with the moving bearing device;It is stretched with described described 112 one end of cantilever Contracting stent connects, and the other end is connected with the detection device 100.
Optionally, the connection mode of telescope support and cantilever is not limited to spring card slot connection, other can realize flexible branch Frame control cantilever carries out the connection mode of height change.
Also referring to Fig. 3, a kind of terahertz time-domain system of air high-risk chemical, the time domain system are provided Including:Laser generator 301, for generating pumping pulse and direct impulse;Delayer 307, for receiving laser generator The 301 pumping pulse laser generated, and adjust the pumping pulse of the generation of laser generator 301 and the time delay of direct impulse. Signal generator 302, for emitting terahertz signal;Terahertz detection device 303, for air high-riskization in environment Product sampling detection;Signal receiver 304, for finishing receiving air high-risk chemical in high-risk chemical sampling room 1021 The terahertz signal of information detection;Signal processor 305 for being analyzed and processed to the terahertz signal received, obtains Air high-risk chemical information.
In one embodiment, the laser generator 301 includes femtosecond laser 3011 and beam splitter 3012;The letter Number generator 302 includes lens, for generating terahertz signal;The terahertz detection device 303 is high-risk to carry air Sample chemicals 3031, the first off axis paraboloidal mirror 3032, the second off axis paraboloidal mirror 3033, the 3rd off axis paraboloidal mirror 3034th, the 4th off axis paraboloidal mirror 3035.Wherein, 3032 and second off axis paraboloidal mirror of the first off axis paraboloidal mirror 3033 are oppositely arranged, and the 3rd off axis paraboloidal mirror 3034 is oppositely arranged with the 4th off axis paraboloidal mirror 3035.The signal Receiver 304 includes lens, for receiving terahertz signal;The signal processor 305 includes lock-in amplifier 3051 and letter Number processing unit 3052;
In one of the embodiments, the femtosecond laser 3011 that femto-second laser is sent is divided into two beams by beam splitter 3012 Pulse is respectively pumping pulse and direct impulse.Wherein pumping pulse reaches delayer 307, after delayer 307, enters It is mapped in lock-in amplifier 3051;The terahertz pulse that wherein direct impulse and signal generator 302 generate successively through the 3rd from Axis paraboloidal mirror 3034, the first off axis paraboloidal mirror 3032 are incided on air high-risk chemical sample 3031, high-risk to air Sample chemicals 3031 are detected, and are obtained result of detection signal, then are thrown off axis through the second off axis paraboloidal mirror the 3033, the 4th 3035 arriving signal receiver 304 of object plane mirror.Delayer 307 adjusts the time delay between pumping pulse and direct impulse, from And change the time that detection light reaches terahertz detector.Utilize different detection light arrival times, Terahertz electric field strength The amount of changing with time can be measured.Signal processing apparatus 3052 carries out the Terahertz electric field strength amount of changing with time Analysis and processing, such as Fourier transformation is carried out, transmission spectrum is obtained, gained transmission spectrum is analyzed to obtain air height The species and concentration information of danger chemicals;
In one of the embodiments, air high-risk chemical sample 3031 is placed in air high-risk chemical sampling room In 1021 (not marked in figure), the air high-risk chemical sampling room 1021 in the terahertz time-domain system is in communication with the outside, The terahertz time-domain system is used for the air high-risk chemical sample 3031 to the air high-risk chemical sampling room 1021 It is detected, obtains the air high-risk chemical information.In traditional technology, by air high-risk chemical be placed in gas chamber into Row test, but during being detected by gas chamber, certain loss of THz wave, while the material of gas chamber can be caused Certain property delayed of spectrum can be also caused, so that result of detection is inaccurate.
In toxic gas leakage scene or explosion scene, gas chamber sampling is often not easy to, and needs to obtain in real time, really Live air high-risk chemical species and concentration levels, then detector is then needed to be placed directly in atmospheric environment and is carried out The measurement of contact.
In one of the embodiments, air humidity tester is also installed on the terahertz time-domain system probe.Due to Vapor is very strong for the absorption of Terahertz, therefore can select to eliminate vapor to result of detection using " making poor method " Influence, gained Terahertz collection of illustrative plates will be detected and subtract the Terahertz collection of illustrative plates of the vapor of existing similary concentration in database, from And the Terahertz profile information of corresponding air high-risk chemical to be measured is obtained, and then judge high-risk air high-risk chemical Species and concentration information.
In one of the embodiments, testing time 20ps is chosen, the Terahertz of 1-2THz wave bands surveys air Examination, obtains collection of illustrative plates;By Terahertz pop one's head on subsidiary air humidity tester atmospheric humidity is tested, obtain air Relative humidity is 5%;For relative air humidity when being respectively 20ps in 5%, sampling time, water is in 1~3THz in called data storehouse The absworption peak collection of illustrative plates of wave band;The collection of illustrative plates of measurement is subtracted into database collection of illustrative plates, you can obtain characteristic peak collection of illustrative plates;To characteristic peak collection of illustrative plates In frequency and the peak height of fingerprint peaks carry out database and compare and calculate, you can obtain the high-risk substance of air under real time environment Species and concentration.
Also referring to Fig. 4, a kind of high-risk chemical source of leaks detection method based on Terahertz, the described method includes:
S402 obtains the air high-risk chemical concentration distribution information of current location by detection device;
S404 according to the air high-risk chemical concentration distribution information acquisition target acquisition position, and drives detection to fill It puts and marches to the target acquisition position;
S406 obtains the air high-risk chemical concentration distribution information of the target acquisition position again;According to the mesh The air high-risk chemical concentration distribution information of mark detecting location obtains next target acquisition position;Obtain multigroup detection position The air high-risk chemical concentration distribution information put;
The air high-risk chemical concentration distribution information of multigroup detecting location is sent at processing system by S408 Reason;Export air high-risk chemical spatial distribution image information.
In one of the embodiments, the detection device is terahertz time-domain system and device.
Specifically, THz wave is electromagnetic wave of the frequency in the range of 0.l~10THz (wavelength is 3mm~30 μm).Too With many special materials fully effect, therefore in terms of environmental monitoring, Terahertz is suitable for solid, liquid can occur for hertz The research of the electricity, acoustic properties of the media such as body, air high-risk chemical and fluid, it can also be used to pollutant monitoring, biology and The quality control of detection and the food industry of chemical substance.
THz wave has a broadband property, and the frequency band of single terahertz-wave pulse can be covered from several hertz to tens terahertzs Hereby, detection device can by fourier transform infrared spectroscopy, microwave spectrum, far-infrared laser, non-linear frequency mixing technology, Far red light grating spectrum and the equally method of energy atmospheric sounding high-risk chemical information, detect detected object.Specifically , the light source of terahertz time-domain spectroscopy is terahertz pulse of the pulsewidth in picosecond level, and temporal resolution can reach skin Second;Terahertz time-domain spectroscopy measurement measures for the electric field to terahertz pulse, belongs to coherent measurement, not only includes shaking The information of width, while the information comprising phase can directly obtain the refractive index of sample;In addition, for some macromolecular air High-risk chemical, the absworption peak that the spectral line obtained using THz wave is obtained is more sharp, and line style overlapping is less so that big The discrimination of gas high-risk chemical is more prone to.Particularly, many air high-risk chemicals have uniqueness in THz wave spectral coverage Absorption line, ingredient, concentration of air high-risk chemical etc. can be measured using terahertz time-domain spectroscopic technology; Meanwhile terahertz light spectral technology can be used for the absorption for measuring heterogeneity in hybrid atmospheric high-risk chemical, and measure mixed The chemical composition of air high-risk chemical and the concentration of each component are closed, there is higher accuracy.
Specifically, THz wave has good compared to other detection means in many dielectric materials and nonpolar liquid Good penetrability, therefore THz wave can carry out perspective imaging to opaque object.Further, since the typical case of Terahertz Wavelength is much larger than the scale of the soot dust granule in air, these soot dust granules to suspend to the scattering of THz wave much smaller than pair The scattering of other electromagnetic waves, therefore detection means can be made in more complicated site environment.
Specifically, THz wave has fingerprint spectrality, has absworption peak and the reflection of different frequency to different substances Peak can efficiently and accurately demarcate the species of air high-risk chemical substance according to the existing finger print information of database;It simultaneously can The concentration of air high-risk chemical is judged with the feature according to vibration amplitude.Optionally, judged according to the feature of vibration amplitude The method of air high-risk chemical concentration include the size according to characteristic peak, the peak according to characteristic peak amplitude it Than be equal to the ratio between air high-risk chemical concentration or and other can reflect that vibration amplitude and air high-risk chemical concentration are closed The method of system.
Specifically, terahertz emission belongs to the scope of submillimeter wave, and photon energy and characteristic temperature are very low.One frequency The energy for the photon that rate is 1THz is 4.1MeV, corresponding to 33 wave beams, characteristic temperature 48K, less than various chemical bonds Bond energy, and the required photon energy of ionized biological tissue will usually reach 16eV, therefore far from making biological tissue or cell Ionization, therefore harmful ionization reaction will not be caused, suitable for the occasion that explosive is diffused He the crowd is dense.
In one of the embodiments, the terahertz time-domain system is transmission-type terahertz time-domain system.Optionally too Hertz time domain system is not limited to transmission-type, can also select reflective, differential type, ellipse inclined formula and can atmospheric sounding it is high Other time domain systems of danger chemicals and high-risk substance probe.
In one of the embodiments, the acquisition methods of target acquisition position include described in step S404:
All concentration distribution information acquired in three-dimensional coordinate are ranked up, obtain concentration highest in three-dimensional coordinate The direction of point is the direct of travel of the detection device;
The driving detection device marches to the target acquisition position along the direct of travel.
Specifically, the target acquisition position refers to, detection device determines next according to the result of detection of current location Walk the position that will be detected.Three-dimensional coordinate includes abscissa x, ordinate y and vertical coordinate z.It is described to institute in three-dimensional coordinate All concentration distribution information obtained are ranked up, and are that all concentration acquired in three-dimensional coordinate are carried out from big to small Sequence, obtains the coordinate of the point of concentration maximum, i.e. the coordinate (x ', y ', z ') of target acquisition position.
In one of the embodiments, it is described to all concentration distribution information acquired in the three dimensions of current location Be ranked up, including by Bubble Sort Algorithm to all concentration distribution information acquired in the three dimensions of current location into Row sequence.
Specifically, it is described according to the air high-risk chemical concentration distribution information acquisition target acquisition position, and drive Detection device marches to the target acquisition position, including:
S4041 is ranked up all concentration distribution information acquired in the three dimensions of current location, obtains three-dimensional The direction of peak concentration in space, the direct of travel as the detection device;
S4042 drives the detection device to march to the target acquisition position to the direct of travel.
In one of the embodiments, it is described to all concentration distribution information acquired in the three dimensions of current location Be ranked up, including by Bubble Sort Algorithm to all concentration distribution information acquired in the three dimensions of current location into Row sequence.Optionally, the method being ranked up to all concentration distribution information acquired in the three dimensions of current location is unlimited In bubble sort, simple selection sequence, Straight Insertion Sort, Shell sorting, heapsort, merger sequence, quicksort are further included And other can realize the algorithm of sequence.
In one of the embodiments, it is described to be visited according to the air high-risk chemical concentration distribution information acquisition target Location is put, and detection device is driven to march to the target acquisition position and may also include:
S4041 ' to the air high-risk chemical concentration information averaged in the different height of current location, is put down The highest height of equal concentration is the object height z that detection device is advanced;
S4042 ' is ranked up the concentration of the different angle in the highest height of the mean concentration, obtains described flat The highest angle of concentration is the target angle of the driving device in the highest height of equal concentration;
S4043 ' drives the detection device to march to the target acquisition according to the object height and target angle Position.Specifically, the target angle is in a horizontal plane, it is reference with former direction of advance using detection device as origin (i.e. using the vectorial angle of former direction of advance as 0 °), origin be directed toward the vector of target acquisition position and former direction of advance institute into Angle.
It in one of the embodiments, can be by multigroup a certain air high-risk chemical distribution in step S408 Concentration information be sent to data handling system and handled.
In one of the embodiments, according to the air high-risk chemical concentration point of the current location in step S408 Cloth information, the air high-risk chemical concentration distribution information of the target acquisition position, output air high-risk chemical space point The step of cloth image information air high-risk chemical, includes:
S4081 sends the concentration information that multigroup a certain air high-risk chemical is distributed compared with three-dimensional coordinate Numerical fitting is carried out to numerical fitting system, it is continuously distributed compared with three-dimensional coordinate to obtain a certain air high-risk chemical Concentration information;
The concentration information continuously distributed compared with three-dimensional coordinate is identified, obtains a certain air by S4082 High-risk chemical spatial distribution map.
In one of the embodiments, in step S4122, by the concentration continuously distributed compared with three-dimensional coordinate Information carries out colour code, such as area with high mercury is identified with light colour, and low concentration region is represented with dark colour, alternatively, with Blueness represents a kind of air high-risk chemical, and another air high-risk chemical is represented with red.
Optionally, the concentration information continuously distributed compared with three-dimensional coordinate is not limited to carry out colour code, also Can carry out words identification, picture identification and other can reflect the identification method of air high-risk chemical concentration information.
In one of the embodiments, the air high-risk chemical concentration distribution information according to the current location, The air high-risk chemical concentration distribution information of the target acquisition position, obtains air high-risk chemical spatial distribution image It further includes afterwards:
S4083 respectively detects different types of air high-risk chemical by multiple detection devices, obtains To the spatial distribution image of a variety of variety classes air high-risk chemicals;
Different types of air high-risk chemical distributed image is overlapped processing, obtained not of the same race by S4084 Class air high-risk chemical spatial distribution superimposed image, and the variety classes air high-risk chemical spatial distribution is superimposed Image exports.
In one of the embodiments, a kind of computer readable storage medium is also provided, is stored thereon with computer journey Sequence, wherein, when which is executed by processor, it can be achieved that in any of the above-described embodiment the step of method.
Please refer to fig. 5, a kind of single high-risk chemical source of leaks detection method based on Terahertz, the method Including:
S502 obtains the air high-risk chemical concentration distribution information of current location by detection device;
S504 according to the air high-risk chemical concentration distribution information acquisition target acquisition position, and drives detection to fill It puts and marches to the target acquisition position;
S506 obtains the air high-risk chemical concentration distribution information of the target acquisition position, according to the mesh again The air high-risk chemical concentration distribution information of mark detecting location obtains next target acquisition position, until next target The air high-risk chemical concentration of detecting location is peak value, reaches S508 at air high-risk chemical source of leaks, is worked as according to described Air high-risk chemical concentration distribution information, the concentration distribution information of the target acquisition position of front position, obtain air height Danger chemicals spatial distribution image information.
It is wherein step S502, step S504, step S508 and S402, S404, S408, essentially identical, it is no longer superfluous herein It states.
Particularly, S506 in one of the embodiments, when the air high-risk chemical of next target acquisition position is dense Spend for peak value when, reach air high-risk chemical source of leaks at.
The air high-risk chemical source of leaks is the position in a region, can set the phase of the detection of detection device The distance of adjacent two detecting locations is a step-length.
In one embodiment, when the air high-risk chemical peak concentration point determination methods using the S4041, During the method for S4042, air high-risk chemical source of leaks is using detection gained air high-risk chemical peak concentration point as origin Using a step-length as the sphere of radius.
In one embodiment, described in being used when the determination methods of the air high-risk chemical peak concentration point S4041 ', S4042 ' method when, air high-risk chemical source of leaks is that the gas concentration peak point in corresponding height is origin Using a step-length as the border circular areas of radius.Optionally, air high-risk chemical leakage source region selection mode be not limited to Upper two kinds, in varied situations, it can flexibly use multiple choices mode.
Please with reference to Fig. 6, a kind of single air high-risk chemical source of leaks detection method based on Terahertz is described Method includes:
S602 obtains the air high-risk chemical concentration distribution information and peak value of current location by detection device;
S604 according to the air high-risk chemical concentration distribution information acquisition target acquisition position, and drives detection to fill It puts and marches to the target acquisition position;
S606 obtains the air high-risk chemical concentration distribution information and peak value of the target acquisition position again, according to The air high-risk chemical concentration distribution information and peak value of the target acquisition position obtain next target acquisition position, and Driving detection device marches to next target acquisition position again;
S608, if the magnitude relationship between the peak value of multiple target acquisition positions meets preset condition, according to more The peak value of a target acquisition position obtains the location information of air high-risk chemical source of leaks;
S610, according to the air high-risk chemical concentration distribution information of the current location, the target acquisition position Air high-risk chemical concentration distribution information obtains air high-risk chemical spatial distribution image information.
Wherein S602, S604, S606, S610, with S502, S504 in specification, S506, S510, essentially identical, herein It repeats no more;
Particularly, in one of the embodiments, if magnitude relationship between the peak value of multiple target acquisition positions Meet preset condition, then the position of air high-risk chemical source of leaks is obtained according to the peak value of multiple target acquisition positions Information specifically includes:
The air for comparing continuous two target acquisition positions after the current location and the current location is high-risk The peak value of chemical concentration;
If the peak value of the air high-risk chemical concentration of continuous two target acquisition positions is small after the current location In the peak value of the air high-risk chemical concentration of the current location, then judge the current location for air high-riskization Product source of leaks.
In one of the embodiments, if the magnitude relationship between the peak value of multiple target acquisition positions meets in advance If condition, then the location information for obtaining air high-risk chemical source of leaks according to the peak value of multiple target acquisition positions has Body further includes:
If the peak value of the air high-risk chemical concentration of the first aim detecting location after the current location is less than The peak value of the air high-risk chemical concentration of the current location, and the second target detection position after the current location The air high-risk chemical peak concentration put is more than the air high-risk chemical peak concentration of the current location, then continues to compare The peak value of the air high-risk chemical concentration of the 3rd target acquisition position after the current location and the present bit Put the size of air high-risk chemical concentration;
If the peak value of the air high-risk chemical concentration of the 3rd target acquisition position after the current location is less than The peak value of the air high-risk chemical concentration of the current location, then the current location is that the air high-risk chemical is let out Drain-source.
Also referring to Fig. 7, a kind of method of multiple high-risk chemicals leakage source detection based on Terahertz, the side Method includes:
S702 obtains the concentration distribution information of the high-risk chemical of current detecting location by detection device;
S704 draws target acquisition position according to the high-risk chemical concentration distribution information, and driving detection device is advanced To the target acquisition position;
S706 obtains the concentration distribution information of the target acquisition position again,
Next target acquisition position is obtained according to the high-risk chemical concentration distribution information of the target acquisition position, When the detection device obtains all source of leaks of a certain high-risk chemical in search coverage, multigroup detecting location is obtained High-risk chemical concentration distribution information;
The Gas concentration distribution information of multigroup detecting location is sent to data handling system and handled by S708, Obtain high-risk chemical spatial distribution image information.Wherein S702, S704, S708 and step S602, the S604 in specification, S608 corresponding steps are essentially identical, and details are not described herein.
Particularly, in one of the embodiments, when air high-risk chemical space exploration imaging method detection obtains When obtaining all source of leaks of a certain air high-risk chemical in search coverage, the coordinate where the detection device is described Terminal point coordinate.
In one of the embodiments, judge that the detection device obtains the high-risk chemistry of a certain air in search coverage The method of all source of leaks of product includes:It is obtained according to the air high-risk chemical concentration distribution information of the target acquisition position To next target acquisition position, until the coordinate of the coordinate of next target acquisition position and any detecting location before It overlaps, then judges that the detection device obtains all source of leaks of a certain air high-risk chemical in search coverage.
In one of the embodiments, also referring to Fig. 8, it is described until the coordinate of next target acquisition position with The coordinate of any detecting location before overlaps, then it is high to judge that the detection device obtains a certain air in search coverage The method of all source of leaks of danger chemicals includes:
It obtains the coordinate of each target acquisition position and stores in the processing system;
The coordinate of each target acquisition position of the processing system to getting carries out data analysis;
Coordinate when next target acquisition position that processing system detects and the target acquisition position before any one When the coordinate put overlaps;
Halt instruction is sent to detection device;
The detection device stops detection.
Also referring to Fig. 8, additionally provide in one of the embodiments a kind of based on terahertz detection toxic gas Method includes:
S802, detection device 100 demarcate gas componant, determine tri- kinds of toxic gases of a, b, c in marked gas;
S804 measures the concentration of toxic gas a;
S8061 adjusts mechanic adjustment unit, the runing rest of connection shaft is made to rotate 0 °, 90 °, 180 °, 270 ° respectively;
S8062 makes telescope support raise 1m, 10m, 20m, 30m height respectively;
S808 measures the concentration data under different coordinates;Concentration data is ranked up by S809, determines detecting devices row Into direction and height;
If processor sends halt instruction;All concentration datas are carried out numerical fitting by S812 compared with coordinate;S814, Continuous concentration data is transmitted back to headquarter and is imaged.
If processor does not send halt instruction, repeatedly step S802, S804, S8061, S8062, S808, S809.
The step of repeating S802, S804, S8061, S8062, S808, S809, S810, S812, S814 measures toxic gas B and c, measure obtain toxic gas b, c concentration distribution information, then the concentration distribution matrix of toxic gas a, b, c is as follows:
By the respective concentration of toxic gas a, b, c according to sorting from big to small, such as a23>a13>a33> a43>…>a22> a12>a32>A42, it is known that somewhere concentration axyMiddle x represents certain height, and y represents certain angle direction, so that it is determined that 2 → 3 direction of coordinate For the most fast direction of air high-risk chemical a increasing concen-trations, height 2 is the height of toxic gas a concentration maximums, and coordinate 4 is to have The height of poisonous gas a concentration minimums;By feeding back electric wire 122, instruction is sent to universal wheel 126, makes universal wheel along increasing concen-trations Most fast direction, i.e., opposite -135 ° of directions are advanced.All data are collected, by processor 130, by discrete concentration Numerical fitting is carried out compared with coordinate, so as to obtain gas a, b, c compared with the continuous concentration distribution of three-dimensional coordinate;
Also referring to Fig. 9, Fig. 9 is the concentration result of detection distribution map of poison gas a, by that can be clearly seen than vitta, Dark color represents low concentration air high-risk chemical, and light color represents high concentration air high-risk chemical, therefore light color aggregation position is The higher position of poison gas a concentration is judged as the leakage source position of poison gas a, it is proposed that inhibits position for poison gas emphasis.Light color is to deeply Color extending direction is judged as poison gas a descending concentrations direction, it is proposed that is crowd's escape route;Dark color is sentenced to light extending direction Break as the concentration sharp increase direction of poison gas a, it is proposed that evade route for crowd's emphasis.
Also referring to Figure 10, situation that Figure 10 a, b two kind poison gas are distributed in space, as seen from the figure, b points of poison gas Cloth is in high-altitude, and for poison gas a in low latitude, situations such as this density and same day wind-force to gas in itself is related.According to different types of gas The sprinkling of corresponding chemical treatment medicament can be effectively performed in the space distribution situation of body.Since low latitude poison gas is to people's Life security influence is big compared with high-altitude poison gas, and judges that poison gas a concentration is big compared with poison gas b, therefore Ying You from shade First handle the leakage of poison gas a.
It can be with the leakage situation of accurate judgement poison gas a and poison gas b, so as to help by intuitively showing for Fig. 9 and Figure 10 Poison gas Restrain measurement and crowd evacuation scheme are made in commanding.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited In contradiction, the scope that this specification is recorded all is considered to be.
Embodiment described above only expresses the several embodiments of the present invention, and description is more specific and detailed, but simultaneously Cannot the limitation to the scope of the claims of the present invention therefore be interpreted as.It should be pointed out that for those of ordinary skill in the art For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the present invention's Protection domain.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.

Claims (10)

  1. A kind of 1. method based on the distribution of terahertz detection high-risk chemical, which is characterized in that the described method includes:
    The concentration distribution information of the air high-risk chemical of current detecting location is obtained by detection device;
    According to the air high-risk chemical concentration distribution acquisition of information target acquisition position, driving detection device marches to described Target acquisition position;
    The air high-risk chemical concentration distribution information of the target acquisition position is obtained again;
    Next target acquisition position is obtained according to the air high-risk chemical concentration distribution information of the target acquisition position, directly Coordinate to next target acquisition position is overlapped with the coordinate of any detecting location before, obtains the big of multigroup detecting location Gas high-risk chemical concentration distribution information;
    The Gas concentration distribution information of multigroup detecting location is sent to data handling system to handle, obtains air height Danger chemicals spatial distribution image information.
  2. 2. according to the method described in claim 1, it is characterized in that, the detection device is terahertz time-domain system.
  3. 3. according to the method described in claim 2, it is characterized in that, the terahertz time-domain system is transmission-type terahertz time-domain System.
  4. 4. according to the method described in claim 1, it is characterized in that, the acquisition methods of next target acquisition position include:
    All concentration distribution information acquired in three-dimensional coordinate are ranked up, obtain the side of concentration peak in three-dimensional coordinate To the direct of travel for the driving device;
    The driving device marches to next target acquisition position along the direct of travel.
  5. 5. according to the method described in claim 4, it is characterized in that, described own to acquired in the three dimensions of current location Concentration distribution information is ranked up, including by Bubble Sort Algorithm to all concentration acquired in the three dimensions of current location Distributed intelligence is ranked up.
  6. 6. according to the method described in claim 1, it is characterized in that, described believe according to the air high-risk chemical concentration distribution Breath obtains target acquisition position, and detection device is driven to march to the target acquisition position and is further included:
    To the concentration information averaged in the different height of current location, it is high for target to obtain the highest height of mean concentration Degree;
    The concentration of different angle in the highest height of the mean concentration is ranked up, it is highest to obtain the mean concentration The highest angle of concentration is the target angle of the driving device in height;
    The detection device is driven to march to the target acquisition position according to the object height and target angle.
  7. 7. according to the method described in claim 1, it is characterized in that, by multigroup a certain air high-risk chemical distribution Concentration information is sent to data handling system and is handled, and the step of obtaining air high-risk chemical spatial distribution image information wraps It includes:
    Multigroup a certain air high-risk chemical is sent to numerical fitting compared with the concentration information that three-dimensional coordinate is distributed System carries out numerical fitting, obtains a certain air high-risk chemical compared with the continuously distributed concentration information of three-dimensional coordinate;
    The concentration information continuously distributed compared with three-dimensional coordinate is identified, it is empty to obtain a certain air high-risk chemical Between distribution map.
  8. 8. the according to the method described in claim 5, it is characterized in that, air high-risk chemical according to the current location Concentration distribution information, the air high-risk chemical concentration distribution information of the target acquisition position, obtain air high-risk chemical It is further included after spatial distribution image:
    Different types of air high-risk chemical is detected respectively by multiple detection devices, is obtained a variety of not of the same race The gas compartment distributed image of class gas;
    Different types of air high-risk chemical distributed image is overlapped processing, obtains variety classes air high-riskization Product spatial distribution superimposed image, and the variety classes air high-risk chemical spatial distribution superimposed image is exported.
  9. 9. according to the method described in claim 5, it is characterized in that, the concentration continuously distributed compared with three-dimensional coordinate is believed Breath carries out colour code.
  10. 10. a kind of computer readable storage medium, is stored thereon with computer program, which is characterized in that the program is by processor The step of any one the method in claim 1-9 can be realized during execution.
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PCT/CN2018/092436 WO2019114239A1 (en) 2017-12-13 2018-06-22 Terahertz detection method and system for highly hazardous chemical in atmosphere
US16/446,620 US20190302012A1 (en) 2017-12-13 2019-06-20 Terahertz detection method and system for high-risk chemical in atmosphere

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