CN108102437A - A kind of anti-aging colloidal sol Co-TiO2 Nano sols - Google Patents
A kind of anti-aging colloidal sol Co-TiO2 Nano sols Download PDFInfo
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- CN108102437A CN108102437A CN201711493263.0A CN201711493263A CN108102437A CN 108102437 A CN108102437 A CN 108102437A CN 201711493263 A CN201711493263 A CN 201711493263A CN 108102437 A CN108102437 A CN 108102437A
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- parts
- colloidal sol
- nano
- aging
- tio2
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
Abstract
The invention discloses a kind of anti-aging colloidal sol Co TiO2 Nano sols, the anti-aging colloidal sol Co TiO2 Nano sols are as follows according to the formula of weight：40 80 parts of Co, TiO210 30 parts, 0.5 1.5 parts of additive, 4.5 5.5 parts of nano silicon oxide, 3.5 4.5 parts of antimildew and antibacterial agent, 6.2 8.5 parts of age resister, 8.2 12 parts of gelling agent, 0.1 0.4 parts of colorant, micro- 0.2 0.75 parts, 30 50 parts of water.The anti-aging function of increase more excellent simultaneously, it avoids bringing it in the case of sunlight and bad weather damage, ensure that use it is more permanent, it is more beautiful, corrosion rust staining is avoided, influences service life, it solves simultaneously and is easier to be damaged, the problem of intensity is low is more conform with consumption view instantly, is promoted the use of after being worth.
Description
Technical field
The present invention relates to Nano sol technical field more particularly to a kind of anti-aging colloidal sol Co-TiO2 Nano sols.
Background technology
Industrial area, coastal area or haze are seriously regional, due to being subject to soot dust granule in air, sulfur dioxide gas or salt
Point effect, the coloured coating corrosion and ageing of color coating plate surface is serious, especially sunburst irradiate in the case of, rainwater and
The pollutants such as sulfur dioxide accelerate Coil Coating Products aging in air, and color is decorporated, and becomes intensely dark, final corrosion rust staining occur,
Service life and beauty are influenced, is easier to be damaged, intensity is low, and does not possess the effect of heat-insulated, therefore, it is proposed to one
The anti-aging colloidal sol Co-TiO2 Nano sols of kind.
The content of the invention
It is an object of the invention to provide a kind of anti-aging colloidal sol Co-TiO2 Nano sols, to solve above-mentioned background skill
The problem of being proposed in art.
To achieve these goals, present invention employs following technical solutions：
A kind of anti-aging colloidal sol Co-TiO2 Nano sols, the anti-aging colloidal sol Co-TiO2 Nano sols are according to weight
Formula is as follows：40-80 parts of Co, TiO210-30 parts, 0.5-1.5 parts of additive, 0.2-25 parts of sodium metasilicate, cerium oxide sol
0.2-8 parts, 0.1-0.15 parts of complexing agent, 30-45 parts of deionized water, 1.2-1.8 parts of Nano titanium nitride, nano aluminium oxide 4.2-
5.5 parts, 3.5-4.5 parts of nano zine oxide, 4.5-5.5 parts of nano silicon oxide, 3.5-4.5 parts of antimildew and antibacterial agent, age resister
6.2-8.5 parts, 8.2-12 parts of gelling agent, 0.1-0.4 parts of colorant, 0.2-0.75 parts of trace element, 30-50 parts of water.
Preferably, described Co, TiO2, additive, sodium metasilicate, cerium oxide sol weight ratio be 45-75：12-25：0.7-
1.2：0.21-24：0.25-7.5.
Preferably, the deionized water, Nano titanium nitride, nano aluminium oxide, nano zine oxide, the weight of nano silicon oxide
Than for 32-42：1.3-1.7：4.4-5.4：3.6-4.3：4.8-5.2.
Preferably, the complexing agent, antimildew and antibacterial agent, age resister, the weight ratio of gelling agent are 0.11-0.13：3.8-
4.2：6.5-8.2：8.5-11.
Preferably, the colorant, trace element, the weight ratio of water are 0.2-0.35：0.3-0.7：35-45.
Preferably, the trace element is W, Al, Cu, Zn, Mn
Preferably, the colorant is water-soluble reddish blue dyestuff.
Preferably, it is described to pass through roller coating, spraying or pressure in Coil Coating Products for anti-aging colloidal sol Co-TiO2 Nano sols
Painting mode forms anti-aging colloidal sol Co-TiO2 Nano sol layers.
Preferably, the thickness of the anti-aging colloidal sol Co-TiO2 Nano sol layers is 50-450nm.
A kind of anti-aging colloidal sol Co-TiO2 Nano sols provided by the invention, the present invention in Co, TiO2, additive
The intensity of Nano sol can be increased, avoid being damaged easily, using deionized water, Nano titanium nitride, nano aluminium oxide, received
Rice zinc oxide, nano silicon oxide, complexing agent, antimildew and antibacterial agent, age resister, gelling agent can increase the heat-proof quality of the present invention
And the function of stain resistant, while the anti-aging function of more excellent increase, it avoids in sunlight and boisterous situation
Under damage is brought to it, ensure that use it is more permanent, it is more beautiful, avoid corrosion rust staining, influence service life, solve simultaneously
It has determined and has been easier to be damaged, the problem of intensity is low, be more conform with consumption view instantly, promoted the use of after being worth.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, below in conjunction with specific embodiment, to this
Invention is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, not
For limiting the present invention.
Embodiment 1
A kind of anti-aging colloidal sol Co-TiO2 Nano sols, the anti-aging colloidal sol Co-TiO2 Nano sols are according to weight
Formula is as follows：40 parts of Co, TiO210 parts, 0.5 part of additive, 0.2 part of sodium metasilicate, 0.2 part of cerium oxide sol, complexing agent 0.1
Part, 30 parts of deionized water, 1.2 parts of Nano titanium nitride, 4.2 parts of nano aluminium oxide, 3.5 parts of nano zine oxide, nano silicon oxide 4.5
Part, 3.5 parts of antimildew and antibacterial agent, 6.2 parts of age resister, 8.2 parts of gelling agent, 0.1 part of colorant, micro- 0.2 part, water 30
Part.
Embodiment 2
A kind of anti-aging colloidal sol Co-TiO2 Nano sols, the anti-aging colloidal sol Co-TiO2 Nano sols are according to weight
Formula is as follows：45 parts of Co, TiO215 parts, 0.58 part of additive, 15 parts of sodium metasilicate, 0.3 part of cerium oxide sol, complexing agent 0.12
Part, 32 parts of deionized water, 1.3 parts of Nano titanium nitride, 4.5 parts of nano aluminium oxide, 4.2 parts of nano zine oxide, nano silicon oxide 4.8
Part, 4.2 parts of antimildew and antibacterial agent, 6.8 parts of age resister, 9 parts of gelling agent, 0.3 part of colorant, micro- 0.5 part, 35 parts of water.
Embodiment 3
A kind of anti-aging colloidal sol Co-TiO2 Nano sols, the anti-aging colloidal sol Co-TiO2 Nano sols are according to weight
Formula is as follows：45 parts of Co, TiO215 parts, 0.8 part of additive, 0.23 part of sodium metasilicate, 0.5 part of cerium oxide sol, complexing agent
0.13 part, 40 parts of deionized water, 1.5 parts of Nano titanium nitride, 5 parts of nano aluminium oxide, 4.2 parts of nano zine oxide, nano silicon oxide
4.8 parts, 3.8 parts of antimildew and antibacterial agent, 6. 5 parts of age resister, 8.5 parts of gelling agent, 0.3 part of colorant, micro- 0.3 part, water
35 parts.
Embodiment 4
A kind of anti-aging colloidal sol Co-TiO2 Nano sols, the anti-aging colloidal sol Co-TiO2 Nano sols are according to weight
Formula is as follows：70 parts of Co, TiO225 parts, 1.2 parts of additive, 0.22 part of sodium metasilicate, 6 parts of cerium oxide sol, complexing agent 0.13
Part, 40 parts of deionized water, 1.6 parts of Nano titanium nitride, 4.5 parts of nano aluminium oxide, 4 parts of nano zine oxide, 5 parts of nano silicon oxide,
4 parts of antimildew and antibacterial agent, 8 parts of age resister, 10 parts of gelling agent, 0.35 part of colorant, micro- 0.7 part, 450 parts of water.
Embodiment 5
A kind of anti-aging colloidal sol Co-TiO2 Nano sols, the anti-aging colloidal sol Co-TiO2 Nano sols are according to weight
Formula is as follows：80 parts of Co, TiO230 parts, 1.5 parts of additive, 25 parts of sodium metasilicate, 8 parts of cerium oxide sol, 0.15 part of complexing agent,
45 parts of deionized water, 1.8 parts of Nano titanium nitride, 5.5 parts of nano aluminium oxide, 4.5 parts of nano zine oxide, 5.5 parts of nano silicon oxide,
4.5 parts of antimildew and antibacterial agent, 8.5 parts of age resister, 12 parts of gelling agent, 0.4 part of colorant, micro- 0.75 part, 50 parts of water.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art in the technical scope disclosed by the present invention, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (9)
1. a kind of anti-aging colloidal sol Co-TiO2 Nano sols, it is characterised in that：Described anti-aging colloidal sol Co-TiO2 nanometers
Colloidal sol is as follows according to the formula of weight：40-80 parts of Co, TiO210-30 parts, 0.5-1.5 parts of additive, sodium metasilicate 0.2-25
Part, 0.2-8 parts of cerium oxide sol, 0.1-0.15 parts of complexing agent, 30-45 parts of deionized water, 1.2-1.8 parts of Nano titanium nitride are received
4.2-5.5 parts of aluminium oxide of rice, 3.5-4.5 parts of nano zine oxide, 4.5-5.5 parts of nano silicon oxide, antimildew and antibacterial agent 3.5-4.5
Part, 6.2-8.5 parts of age resister, 8.2-12 parts of gelling agent, 0.1-0.4 parts of colorant, 0.2-0.75 parts of trace element, water 30-
50 parts.
2. a kind of anti-aging colloidal sol Co-TiO2 Nano sols according to claim 1, it is characterised in that：The Co,
TiO2, additive, sodium metasilicate, cerium oxide sol, weight ratio be 45-75：12-25：0.7-1.2：0.21-24：0.25-7.5.
3. a kind of anti-aging colloidal sol Co-TiO2 Nano sols according to claim 1, it is characterised in that：It is described go from
Sub- water, Nano titanium nitride, nano aluminium oxide, nano zine oxide, the weight ratio of nano silicon oxide are 32-42：1.3-1.7：4.4-
5.4：3.6-4.3：4.8-5.2.
4. a kind of anti-aging colloidal sol Co-TiO2 Nano sols according to claim 1, it is characterised in that：The complexing
Agent, antimildew and antibacterial agent, age resister, the weight ratio of gelling agent is 0.11-0.13：3.8-4.2：6.5-8.2：8.5-11.
5. a kind of anti-aging colloidal sol Co-TiO2 Nano sols according to claim 1, it is characterised in that：The coloring
Agent, trace element, the weight ratio of water are 0.2-0.35：0.3-0.7：35-45.
6. a kind of anti-aging colloidal sol Co-TiO2 Nano sols according to claim 1, it is characterised in that：It is described micro
Element is W, Al, Cu, Zn, Mn.
7. a kind of anti-aging colloidal sol Co-TiO2 Nano sols according to claim 1, it is characterised in that：The coloring
Agent is water-soluble reddish blue dyestuff.
8. a kind of anti-aging colloidal sol Co-TiO2 Nano sols according to claim 1, it is characterised in that：It is described to be used for
Anti-aging colloidal sol Co-TiO2 Nano sols form anti-aging colloidal sol in Coil Coating Products by roller coating, spraying or extrusion mode
Co-TiO2 Nano sol layers.
9. a kind of anti-aging colloidal sol Co-TiO2 Nano sols according to claim 8, it is characterised in that：It is described anti-ageing
The thickness for changing colloidal sol Co-TiO2 Nano sol layers is 50-450nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711493263.0A CN108102437A (en) | 2017-12-30 | 2017-12-30 | A kind of anti-aging colloidal sol Co-TiO2 Nano sols |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711493263.0A CN108102437A (en) | 2017-12-30 | 2017-12-30 | A kind of anti-aging colloidal sol Co-TiO2 Nano sols |
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| CN108102437A true CN108102437A (en) | 2018-06-01 |
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| CN201711493263.0A Pending CN108102437A (en) | 2017-12-30 | 2017-12-30 | A kind of anti-aging colloidal sol Co-TiO2 Nano sols |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102796412A (en) * | 2011-05-27 | 2012-11-28 | 苏州艾贝尔新材料有限公司 | Nano intermediate of reflective thermal insulation material and complexometry technology of nano intermediate |
| CN103923501A (en) * | 2014-04-10 | 2014-07-16 | 上海理工大学 | Nano-sol for forming anti-aging and stain-resistant nano-coating and preparation method and application thereof |
| CN104831125A (en) * | 2015-05-09 | 2015-08-12 | 安徽鼎恒再制造产业技术研究院有限公司 | High-strength Co-TiO2-Mo nanocoating material and preparation method thereof |
| CN105102550A (en) * | 2012-12-10 | 2015-11-25 | 康宁股份有限公司 | Methods and formulations for spray coating sol-gel thin films on substrates |
| CN105315743A (en) * | 2014-07-29 | 2016-02-10 | 金承黎 | Nano porous corrosion-resistant heat-insulated coating material taking thixotropic colloid as template agent and preparation method for corrosion-resistant heat-insulated coating material |
-
2017
- 2017-12-30 CN CN201711493263.0A patent/CN108102437A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102796412A (en) * | 2011-05-27 | 2012-11-28 | 苏州艾贝尔新材料有限公司 | Nano intermediate of reflective thermal insulation material and complexometry technology of nano intermediate |
| CN105102550A (en) * | 2012-12-10 | 2015-11-25 | 康宁股份有限公司 | Methods and formulations for spray coating sol-gel thin films on substrates |
| CN103923501A (en) * | 2014-04-10 | 2014-07-16 | 上海理工大学 | Nano-sol for forming anti-aging and stain-resistant nano-coating and preparation method and application thereof |
| CN105315743A (en) * | 2014-07-29 | 2016-02-10 | 金承黎 | Nano porous corrosion-resistant heat-insulated coating material taking thixotropic colloid as template agent and preparation method for corrosion-resistant heat-insulated coating material |
| CN104831125A (en) * | 2015-05-09 | 2015-08-12 | 安徽鼎恒再制造产业技术研究院有限公司 | High-strength Co-TiO2-Mo nanocoating material and preparation method thereof |
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Application publication date: 20180601 |