CN108102135A - A kind of preparation method of the continuous compound of melamine bubble with anti-static function - Google Patents
A kind of preparation method of the continuous compound of melamine bubble with anti-static function Download PDFInfo
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- CN108102135A CN108102135A CN201711487678.7A CN201711487678A CN108102135A CN 108102135 A CN108102135 A CN 108102135A CN 201711487678 A CN201711487678 A CN 201711487678A CN 108102135 A CN108102135 A CN 108102135A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/36—After-treatment
- C08J9/40—Impregnation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08G12/30—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with substituted triazines
- C08G12/32—Melamines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/038—Use of an inorganic compound to impregnate, bind or coat a foam, e.g. waterglass
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2361/00—Characterised by the use of condensation polymers of aldehydes or ketones; Derivatives of such polymers
- C08J2361/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08J2361/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08J2361/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
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- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The present invention relates to a kind of preparation methods of the continuous compound of melamine bubble with anti-static function, first, melamine resin is prepared under high temperature rapid mixing conditions, melamine resin is then added into auxiliary agent under ultrasonic wave and microwave operating mode and prepares melamine foam；Meanwhile water, glue and carbon black are prepared into carbon black solution according to a certain percentage；Then, 30min 60min in carbon black solution will be immersed under melamine foam vacuum environment, finally obtain the melamine foam compound with anti-static function；Melamine resin emulsification and bubbling efficiency are improved by the subsidiary conditions of ultrasonic wave and microwave, and carbon black is introduced to reduce the continuous resistivity of melamine bubble, so that melamine bubble is continuous to have good anti-static function in melamine steeps continuous matrix；The present invention is with antistatic effect is strong, the production used time is short, heat-resist, expansion rate is fast, environmentally friendly point.
Description
Technical field
The invention belongs to melamine foam preparing technical fields, and in particular to a kind of melamine with anti-static function
The preparation method of the continuous compound of amine bubble.
Background technology
Melamine foam be melamine with formaldehyde be obtained by the reaction melamine resin through Over emulsfication, foaming, consolidate
The cavernous body obtained after change has many advantages, such as high-dimensional stability, heat-resisting, have good sound insulation, denoising, stain removal it is excellent
Point；It is usually used in bullet train sound insulation, heat preservation and burnisher.However, the characteristics of melamine foam is due to itself chemical constitution,
Molecular-chain polarr is poor, and resistivity is very high, holds during use easy to produce static electricity and can not eliminate, in use and
It is inconvenient.On the other hand, the preparation time of current melamine resin is longer, the melamine resin prepared
Emulsification and foaming process are with often, and temperature requirement is also high, and preparation efficiency is relatively low.
The content of the invention
There is provided that a kind of antistatic effect is strong, the production used time is short, resistance to the purpose of the present invention is overcome the deficiencies in the prior art
Hot good, expansion rate is fast, the environmentally friendly melamine for having anti-static function steeps the preparation method of continuous compound.
Technical scheme is as follows：
A kind of preparation method of the continuous compound of melamine bubble with anti-static function, comprises the following steps：
S1, melamine foam is prepared；
S2, carbon black solution is prepared；
S3,30min-60min in carbon black solution will be immersed under melamine foam vacuum environment, finally obtained with antistatic
The melamine foam compound of function.
Further, have in the preparation method of the continuous compound of melamine bubble of anti-static function, trimerization in the step S1
The specific preparation method of cyanamide foam is：
1）, weigh following raw material in parts by weight, 1-15 parts of melamine, 25-90 parts of formalin, the alkalescence of 36%-40% are urged
1-8 parts of agent, 40-80 parts of acid regulator, 6-15 parts of surfactant are spare；
2）, surfactant, formalin, melamine and basic catalyst be added to heating stirring in reactor, heat
Temperature is 70 DEG C -90 DEG C, and mixing speed is 300r/min -800r/min, and mixing time 50min-80min obtains melamine
Amine-formaldehyde resins；
3）, by step 2）Obtained melamine resin is added in ultrasonic emulsification device, and ultrasonic emulsification is filled
It puts and is heated to 50 DEG C, add in acid regulator, be then stirred, mixing speed 900r/min-1200r/min is applied simultaneously
Ultrasonic wave ancillary vibration stirring 25min is added to obtain emulsifying mixt；
4）, by step 3）In obtained emulsifying mixt add in microwave foaming machine and carry out microwave foamed solidification and obtain melamine
Foam；
5）By step 4）15min-45min in the obtained continuous hot water for immersing 60 DEG C -80 DEG C of melamine bubble, then 200 DEG C -
40min-70min is toasted at a temperature of 250 DEG C and removes formaldehyde.
Further, the melamine for having anti-static function is steeped in the preparation method of continuous compound, the step S2
The specific preparation method of middle carbon black solution is：
A1, by weight 10-5:1:0.5 proportioning weighs water, glue and carbon black；
A2, water and glue are added in mixer are stirred in proportion, be heated to add in carbon black at 40 DEG C -60 DEG C, continued
The black mixed liquor being stirred until homogeneous obtains carbon black solution.
Preferably, the basic catalyst is at least one in diethanol amine, sodium hydroxide, calcium hydroxide, monoethanolamine
Kind.
Preferably, the acid regulator is at least one of hydrochloric acid, oxalic acid, aphthenic acids, acetic acid.
Preferably, the surfactant is lauryl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol, dodecyl
At least one of ethyoxyl sulfobetaines, phosphate-based glycine betaine.
Preferably, in the step 3), the power of the ultrasonic wave of application is 90W-140W.
Preferably, the step 4）The flat rate of microwave of middle application is 2450MHz.
Further, after completing the step S3, by the continuous compound of melamine bubble for having anti-static function at 300 DEG C
At a temperature of dry 10min.
Compared with prior art, the beneficial effects of the invention are as follows：
The present invention introduces carbon black in melamine bubble is continuous, and while melamine foam rigidity is improved, melamine is steeped
Silk floss plays the anti-electrical protection of good antistatic, steeps carbon black loadings to melamine on silk floss under evacuation environment, effectively
The pulling force of carbon black and the continuous matrix of melamine bubble is improved, carbon black is kept away and comes off；Using with emulsification, foaming, peptizaiton surface
Activating agent improves the pulling force between melamine and formaldehyde, is carried out rapidly and efficiently at a temperature of 50 DEG C using ultrasonic emulsification device
Emulsification, microwave foaming is then carried out by microwave foaming machine, in vivo moisture will be effectively foamed and organic gas is mentioned
Surface is removed, and effectively improves the continuous production efficiency of bubble, after ultrasonic emulsification and microwave foaming, effectively improves melamine
The continuous mechanical strength of amine-formaldehyde resins bubble；It will finally steep after being toasted in the continuous hot water for immersing 60 DEG C -80 DEG C, it is extra in de-bubble silk floss to go
Formaldehyde, so as to effectively improve the continuous environmental-protecting performance of bubble；In short, the present invention has, antistatic effect is strong, the production used time is short, heat-resisting
Property it is good, expansion rate is fast, environmental protection the advantages of.
Specific embodiment
Below in conjunction with the embodiment of the present invention, the technical solution in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only part of the embodiment of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, those of ordinary skill in the art's all other embodiments obtained without making creative work, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of preparation method of the continuous compound of melamine bubble with anti-static function, comprises the following steps：
S1, melamine foam is prepared；
S2, carbon black solution is prepared；
S3,30min in carbon black solution will be immersed under melamine foam vacuum environment, finally obtained with anti-static function
Melamine foam compound.
Wherein, the specific preparation method of melamine foam is in the step S1：
1）, weigh following raw material in parts by weight, 1 part of melamine, 36% 25 parts of formalin, 1 part of basic catalyst, acid
40 parts of conditioning agent of property, 6 parts of surfactant are spare；
2）, surfactant, formalin, melamine and basic catalyst be added to heating stirring in reactor, heat
Temperature obtains melamine resin for 70 DEG C, mixing speed 300r/min, mixing time 50min；
3）, by step 2）Obtained melamine resin is added in ultrasonic emulsification device, and ultrasonic emulsification is filled
It puts and is heated to 50 DEG C, add in acid regulator, be then stirred, mixing speed 900r/min, while apply power as 90W
Ultrasonic wave ancillary vibration stirring 25min obtain emulsifying mixt；
4）, by step 3）In obtained emulsifying mixt add in microwave foaming machine that apply frequency solid for the foaming of 2450MHz microwaves
Change obtains melamine foam；
5）By step 4）15min in the obtained continuous hot water for immersing 60 DEG C -80 DEG C of melamine bubble, then at a temperature of 200 DEG C
It toasts 40min and removes formaldehyde.
Wherein, the specific preparation method of carbon black solution is in the step S2：
A1, by weight 10:1:0.5 proportioning weighs water, glue and carbon black；
A2, water and glue are added in mixer are stirred in proportion, be heated to add in carbon black at 40 DEG C, continue stirring extremely
Uniform black mixed liquor obtains carbon black solution.
Wherein, after completing the step S3, by the continuous compound of melamine bubble for having anti-static function at 300 DEG C
At a temperature of dry 10min.
Embodiment 2
A kind of preparation method of the continuous compound of melamine bubble with anti-static function, comprises the following steps：
S1, melamine foam is prepared；
S2, carbon black solution is prepared；
S3,60min in carbon black solution will be immersed under melamine foam vacuum environment, finally obtained with anti-static function
Melamine foam compound.
Wherein, the specific preparation method of melamine foam is in the step S1：
1）, weigh following raw material in parts by weight, 15 parts of melamine, 40% 90 parts of formalin, 8 parts of basic catalyst, acid
80 parts of conditioning agent of property, 15 parts of surfactant are spare；
2）, surfactant, formalin, melamine and basic catalyst be added to heating stirring in reactor, heat
Temperature obtains melamine resin for 90 DEG C, mixing speed 800r/min, mixing time 80min；
3）, by step 2）Obtained melamine resin is added in ultrasonic emulsification device, and ultrasonic emulsification is filled
It puts and is heated to 50 DEG C, add in acid regulator, be then stirred, mixing speed 1200r/min, while apply power and be
The ultrasonic wave ancillary vibration stirring 25min of 140W obtains emulsifying mixt；
4）, by step 3）In obtained emulsifying mixt add in microwave foaming machine that apply frequency solid for the foaming of 2450MHz microwaves
Change obtains melamine foam；
5）By step 4）45min in the obtained continuous hot water for immersing 80 DEG C of melamine bubble, is then toasted at a temperature of 250 DEG C
70min removes formaldehyde.
Wherein, the specific preparation method of carbon black solution is in the step S2：
A1, by weight 10-5:1:0.5 proportioning weighs water, glue and carbon black；
A2, water and glue are added in mixer are stirred in proportion, be heated to add in carbon black at 60 DEG C, continue stirring extremely
Uniform black mixed liquor obtains carbon black solution.
Wherein, after completing the step S3, by the continuous compound of melamine bubble for having anti-static function at 300 DEG C
At a temperature of dry 10min.
Embodiment 3
A kind of preparation method of the continuous compound of melamine bubble with anti-static function, comprises the following steps：
S1, melamine foam is prepared；
S2, carbon black solution is prepared；
S3,50min in carbon black solution will be immersed under melamine foam vacuum environment, finally obtained with anti-static function
Melamine foam compound.
Wherein, the specific preparation method of melamine foam is in the step S1：
1）, weigh following raw material in parts by weight, 5 parts of melamine, 37% 50 parts of formalin, 5 parts of basic catalyst, acid
50 parts of conditioning agent of property, 10 parts of surfactant are spare；
2）, surfactant, formalin, melamine and basic catalyst be added to heating stirring in reactor, heat
Temperature obtains melamine resin for 75 DEG C, mixing speed 400r/min, mixing time 60min；
3）, by step 2）Obtained melamine resin is added in ultrasonic emulsification device, and ultrasonic emulsification is filled
It puts and is heated to 50 DEG C, add in acid regulator, be then stirred, mixing speed 1000r/min, while apply power and be
The ultrasonic wave ancillary vibration stirring 25min of 100W obtains emulsifying mixt；
4）, by step 3）In obtained emulsifying mixt add in microwave foaming machine that apply frequency solid for the foaming of 2450MHz microwaves
Change obtains melamine foam；
5）By step 4）30min in the obtained continuous hot water for immersing 70 DEG C of melamine bubble, is then toasted at a temperature of 220 DEG C
50min removes formaldehyde.
Wherein, the specific preparation method of carbon black solution is in the step S2：
A1, by weight 10-5:1:0.5 proportioning weighs water, glue and carbon black；
A2, water and glue are added in mixer are stirred in proportion, be heated to add in carbon black at 45 DEG C, continue stirring extremely
Uniform black mixed liquor obtains carbon black solution.
Wherein, after completing the step S3, by the continuous compound of melamine bubble for having anti-static function at 300 DEG C
At a temperature of dry 10min.
Embodiment 4
A kind of preparation method of the continuous compound of melamine bubble with anti-static function, comprises the following steps：
S1, melamine foam is prepared；
S2, carbon black solution is prepared；
S3,40min in carbon black solution will be immersed under melamine foam vacuum environment, finally obtained with anti-static function
Melamine foam compound.
Wherein, the specific preparation method of melamine foam is in the step S1：
1）, weigh following raw material in parts by weight, 10 parts of melamine, 38% 65 parts of formalin, 4 parts of basic catalyst, acid
65 parts of conditioning agent of property, 9 parts of surfactant are spare；
2）, surfactant, formalin, melamine and basic catalyst be added to heating stirring in reactor, heat
Temperature obtains melamine resin for 85 DEG C, mixing speed 550r/min, mixing time 75min；
3）, by step 2）Obtained melamine resin is added in ultrasonic emulsification device, and ultrasonic emulsification is filled
It puts and is heated to 50 DEG C, add in acid regulator, be then stirred, mixing speed 950r/min, while apply power and be
The ultrasonic wave ancillary vibration stirring 25min of 120W obtains emulsifying mixt；
4）, by step 3）In obtained emulsifying mixt add in microwave foaming machine that apply frequency solid for the foaming of 2450MHz microwaves
Change obtains melamine foam；
5）By step 4）30min in the obtained continuous hot water for immersing 75 DEG C of melamine bubble, is then toasted at a temperature of 240 DEG C
55min removes formaldehyde.
Wherein, the specific preparation method of carbon black solution is in the step S2：
A1, by weight 10-5:1:0.5 proportioning weighs water, glue and carbon black；
A2, water and glue are added in mixer are stirred in proportion, be heated to add in carbon black at 50 DEG C, continue stirring extremely
Uniform black mixed liquor obtains carbon black solution.
Wherein, after completing the step S3, by the continuous compound of melamine bubble for having anti-static function at 300 DEG C
At a temperature of dry 10min.
Embodiment 5
A kind of preparation method of the continuous compound of melamine bubble with anti-static function, comprises the following steps：
S1, melamine foam is prepared；
S2, carbon black solution is prepared；
S3,55min in carbon black solution will be immersed under melamine foam vacuum environment, finally obtained with anti-static function
Melamine foam compound.
Wherein, the specific preparation method of melamine foam is in the step S1：
1）, weigh following raw material in parts by weight, 13 parts of melamine, 39% 65 parts of formalin, 6 parts of basic catalyst, acid
60 parts of conditioning agent of property, 13 parts of surfactant are spare；
2）, surfactant, formalin, melamine and basic catalyst be added to heating stirring in reactor, heat
Temperature obtains melamine resin for 79 DEG C, mixing speed 750r/min, mixing time 75min；
3）, by step 2）Obtained melamine resin is added in ultrasonic emulsification device, and ultrasonic emulsification is filled
It puts and is heated to 50 DEG C, add in acid regulator, be then stirred, mixing speed 1150r/min, while apply power and be
The ultrasonic wave ancillary vibration stirring 25min of 120W obtains emulsifying mixt；
4）, by step 3）In obtained emulsifying mixt add in microwave foaming machine that apply frequency solid for the foaming of 2450MHz microwaves
Change obtains melamine foam；
5）By step 4）25min in the obtained continuous hot water for immersing 75 DEG C of melamine bubble, is then toasted at a temperature of 230 DEG C
65min removes formaldehyde.
Wherein, the specific preparation method of carbon black solution is in the step S2：
A1, by weight 10-5:1:0.5 proportioning weighs water, glue and carbon black；
A2, water and glue are added in mixer are stirred in proportion, be heated to add in carbon black at 55 DEG C, continue stirring extremely
Uniform black mixed liquor obtains carbon black solution.
Wherein, after completing the step S3, by the continuous compound of melamine bubble for having anti-static function at 300 DEG C
At a temperature of dry 10min.
Embodiment 6
A kind of preparation method of the continuous compound of melamine bubble with anti-static function, comprises the following steps：
S1, melamine foam is prepared；
S2, carbon black solution is prepared；
S3,35min in carbon black solution will be immersed under melamine foam vacuum environment, finally obtained with anti-static function
Melamine foam compound.
Wherein, the specific preparation method of melamine foam is in the step S1：
1）, weigh following raw material in parts by weight, 9 parts of melamine, 37% 65 parts of formalin, 4 parts of basic catalyst, acid
60 parts of conditioning agent of property, 8 parts of surfactant are spare；
2）, surfactant, formalin, melamine and basic catalyst be added to heating stirring in reactor, heat
Temperature obtains melamine resin for 87 DEG C, mixing speed 670r/min, mixing time 68min；
3）, by step 2）Obtained melamine resin is added in ultrasonic emulsification device, and ultrasonic emulsification is filled
It puts and is heated to 50 DEG C, add in acid regulator, be then stirred, mixing speed 960r/min, while apply power and be
The ultrasonic wave ancillary vibration stirring 25min of 110W obtains emulsifying mixt；
4）, by step 3）In obtained emulsifying mixt add in microwave foaming machine that apply frequency solid for the foaming of 2450MHz microwaves
Change obtains melamine foam；
5）By step 4）42min in the obtained continuous hot water for immersing 68 DEG C of melamine bubble, is then toasted at a temperature of 230 DEG C
60min removes formaldehyde.
Wherein, the specific preparation method of carbon black solution is in the step S2：
A1, by weight 10-5:1:0.5 proportioning weighs water, glue and carbon black；
A2, water and glue are added in mixer are stirred in proportion, be heated to add in carbon black at 55 DEG C, continue stirring extremely
Uniform black mixed liquor obtains carbon black solution.
Wherein, after completing the step S3, by the continuous compound of melamine bubble for having anti-static function at 300 DEG C
At a temperature of dry 10min.
Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art,
It still can modify to the technical solution recorded in foregoing embodiments or which part technical characteristic is carried out etc.
With replacing, within the spirit and principles of the invention, any modifications, equivalent replacements and improvements are made should be included in this
The protection domain of invention it.
Claims (9)
1. a kind of preparation method of the continuous compound of melamine bubble with anti-static function, which is characterized in that including following step
Suddenly：
S1, melamine foam is prepared；
S2, carbon black solution is prepared；
S3,30min-60min in carbon black solution will be immersed under melamine foam vacuum environment, finally obtained with antistatic
The melamine foam compound of function.
2. the melamine as described in claim 1 for having anti-static function steeps the preparation method of continuous compound, which is characterized in that
The specific preparation method of melamine foam is in the step S1：
1）, weigh following raw material in parts by weight, 1-15 parts of melamine, 25-90 parts of formalin, the alkalescence of 36%-40% are urged
1-8 parts of agent, 40-80 parts of acid regulator, 6-15 parts of surfactant are spare；
2）, surfactant, formalin, melamine and basic catalyst be added to heating stirring in reactor, heat
Temperature is 70 DEG C -90 DEG C, and mixing speed is 300r/min -800r/min, and mixing time 50min-80min obtains melamine
Amine-formaldehyde resins；
3）, by step 2）Obtained melamine resin is added in ultrasonic emulsification device, and ultrasonic emulsification is filled
It puts and is heated to 50 DEG C, add in acid regulator, be then stirred, mixing speed 900r/min-1200r/min is applied simultaneously
Ultrasonic wave ancillary vibration stirring 25min is added to obtain emulsifying mixt；
4）, by step 3）In obtained emulsifying mixt add in microwave foaming machine and carry out microwave foamed solidification and obtain melamine
Foam；
5）By step 4）15min-45min in the obtained continuous hot water for immersing 60 DEG C -80 DEG C of melamine bubble, then 200 DEG C -
40min-70min is toasted at a temperature of 250 DEG C and removes formaldehyde.
3. the melamine as described in claim 1 for having anti-static function steeps the preparation method of continuous compound, which is characterized in that
The specific preparation method of carbon black solution is in the step S2：
A1, by weight 10-5:1:0.5 proportioning weighs water, glue and carbon black；
A2, water and glue are added in mixer are stirred in proportion, be heated to add in carbon black at 40 DEG C -60 DEG C, continued
The black mixed liquor being stirred until homogeneous obtains carbon black solution.
4. the melamine as described in claim 1 for having anti-static function steeps the preparation method of continuous compound, it is characterised in that：
The basic catalyst is at least one of diethanol amine, sodium hydroxide, calcium hydroxide, monoethanolamine.
5. the melamine as described in claim 1 for having anti-static function steeps the preparation method of continuous compound, it is characterised in that：
The acid regulator is at least one of hydrochloric acid, oxalic acid, aphthenic acids, acetic acid.
6. the melamine as described in claim 1 for having anti-static function steeps the preparation method of continuous compound, it is characterised in that：
The surfactant is lauryl sodium sulfate, sodium sulfate of polyethenoxy ether of fatty alcohol, dodecyl ethyoxyl sulfobetaines
At least one of alkali, phosphate-based glycine betaine.
7. the melamine as described in claim 1 for having anti-static function steeps the preparation method of continuous compound, it is characterised in that：
In the step 3), the power of the ultrasonic wave of application is 90W-140W.
8. the melamine as described in claim 1 for having anti-static function steeps the preparation method of continuous compound, it is characterised in that：
The step 4）The flat rate of microwave of middle application is 2450MHz.
9. the melamine as described in claim 1 for having anti-static function steeps the preparation method of continuous compound, it is characterised in that：
After completing the step S3, the continuous compound of melamine bubble for having anti-static function is dried at a temperature of 300 DEG C
10min。
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