CN108099426B - Techniques for printing ink volume control to deposit fluids within precise tolerances - Google Patents

Abstract

An ink printing process employs per-nozzle drop volume measurement and processing software that programs drop combinations to achieve a specific aggregate ink fill per target zone, ensuring compliance with minimum and maximum ink fills set by specifications. In various embodiments, different drop combinations are generated by different printhead/substrate scan offsets, offsets between printheads, the use of different nozzle drive waveforms, and/or other techniques. Optionally, a pattern of fill variations may be introduced to mitigate observable line markings in the finished display device. The disclosed technology has many other possible applications.

Description

Techniques for printing ink volume control to deposit fluids within precise tolerances

The present disclosure claims priority from each of the following patent applications: U.S. provisional patent application No. 61/746545 for "Smart Mixing" filed on day 27 of 2012 in the name of the first inventor, Conor Francis Madigan; U.S. provisional patent application No. 61/822855 for "Systems and methods Providing uniformity Printing of OLED Panels" filed in 2013, 5, 13, 2013 in the name of the first inventor, Nahid Harjee; us provisional patent application No. 61/842351 for "Systems and methods Providing uniformity Printing of OLED Panels", filed first in 2013, on day 7, month 2, in the name of inventor Nahid Harjee; U.S. provisional patent application No. 61/857298 for "Systems and methods Providing uniformity Printing of OLED Panels", filed first in 2013 in 23/7/23 under the name of inventor Nahid Harjee; us provisional patent application No. 61/898769 for "Systems and methods Providing uniformity Printing of OLED Panels", filed first in 2013 on day 11, month 1, in the name of inventor Nahid Harjee; and U.S. provisional patent application No. 61/920,715 for "Techniques for Print Ink Volume Control To circulation Fluids with in preference Tolerans" filed first in 24/12/2013 in the name of inventor NaHid Harjee. Each of the above-mentioned patent applications is incorporated herein by reference.

The present disclosure relates to the use of a printing process to deliver fluid to a target area of a substrate. In one non-limiting application, the techniques provided by the present disclosure may be applied to manufacturing processes for large-scale displays.

Background

In a printing process where the printhead has multiple nozzles, not every nozzle reacts in the same way to a standard drive waveform, i.e. each nozzle can produce a drop of slightly different volume. In cases where nozzles are relied upon to deposit fluid into each fluid deposition zone ("target zone"), the lack of uniformity can cause problems.

Fig. 1A, used to describe this nozzle drop inconsistency problem, is referred to generally by the numeral 101 in the description. In fig. 1, the printhead 103 is seen to have five ink nozzles, each depicted using a small triangle at the bottom of the printhead, each numbered (1) - (5), respectively. It should be assumed that in an exemplary application, it is desired to deposit fifty picoliters (50.00 pl) of fluid into each of the five specific target zones of such an array of regions, and further, each of the five nozzles of the printhead will eject ten picoliters (10.00 pl) of fluid into each of the various target zones with each relative movement ("pass" or "scan") between the printhead and the substrate. The target area may be any surface area of the substrate, including contiguous unseparated areas (e.g., such that deposited fluid ink is partially dispersed to mix together between areas) or fluidly isolated areas. These regions are generally represented in FIG. 1 using ellipses 104-108, respectively. Thus, it may be assumed that there must be exactly five passes of the print head to fill each of the five specific target zones as described. However, the printhead nozzles will actually have some slight variation in structure or actuation, so that a given drive waveform applied to each nozzle transducer provides a slightly different drop volume for each nozzle. For example, as depicted in fig. 1A, the firing of nozzle (1) provides a drop volume of 9.80 picoliters (pL) with each pass, describing five 9.80pL drops within an ellipse 104. Note that each drop is represented in the figure by a different location within the target zone 104, but in practice, the location of each drop may be the same or may overlap. In contrast, nozzles (2) - (5) provided slightly different individual droplet volumes of 10.01pL, 9.89pL, 9.96pL and 10.03 pL. With five passes between the print head and the substrate where each nozzle deposits liquid into the target zones 104-108, mutually exclusive, this deposition will result in a total deposited ink volume change of 1.15pL across the five target zones; this may be unacceptable for many applications. For example, in certain applications, as little as one percent (or even much less) of the difference in deposition fluid may cause problems.

One exemplary application in which this problem arises is in manufacturing processes applied to the manufacture of displays, such as organic light emitting diode ("OLED") displays. Where the printing process is used to deposit the ink-transporting luminescent materials of such displays, differences in volume across rows or columns of fluid containers or "wells" (e.g., 3 such containers per pixel) can result in visible color or illumination defects in the displayed image. Note that "ink" as used herein refers to any fluid applied to a substrate by the nozzles of a printhead, regardless of the color characteristics; in such manufacturing applications, the ink is typically deposited in place and then treated or cured to directly form a layer of permanent material. Thus, television and display manufacturers will effectively specify an accurate volume range that must be observed with high accuracy, e.g., 50.00pL, ± 0.25pL, in order for the resulting product to be considered acceptable; note that in this application, the specified tolerance must be within one-half percent of the target of 50.00 pL. In applications where each nozzle represented in fig. 1 is to deposit into a pixel in a horizontal line of a high definition television ("HDTV") screen, the described variation of 49.02 pL-50.17 pL may thus provide unacceptable quality. While the display technique has been cited as an example, it should be understood that nozzle drop inconsistency issues may arise in other contexts.

In fig. 1A, the nozzles are specifically aligned with a target region (e.g., a well) such that a particular nozzle prints into a particular target region. In FIG. 1B, an alternative situation 151 is shown in which the nozzles are not specifically aligned, but in which the nozzle density is high relative to the target zone density; in this case, the target area is printed using whatever nozzles happen to pass through a particular target area during a scan or pass, potentially multiple nozzles passing through each target area in each pass. In the example shown, the printhead 153 is seen to have five ink nozzles, and the substrate is seen to have two target zones 154-155, each positioned such that nozzles (1) and (2) will pass through target zone 154, nozzles (4) and (5) will pass through target zone 155, and nozzle (3) will not pass through either target zone. As shown, in each pass, one or two droplets are deposited into each well as described. Note that again, the droplets may be deposited in a manner that overlaps or is at discrete points within each target region, and the particular illustration in fig. 1B is merely illustrative; as with the example presented in FIG. 1A, assume again that fifty picoliters (50.00 pL) of fluid is desired to be deposited to each of the target zones 154-155, and each nozzle has a nominal drop volume of about 10.00 pL. With the same per nozzle drop volume change as observed in connection with the example of fig. 1A, and assuming that each nozzle that overlaps the target zone on a given pass will deliver a drop into that target zone until a total of five drops have been delivered, it can be observed that the target zone is filled in three passes, and that there is a total deposited ink volume change of 0.58 pL across the two target zones compared to a 50.00pL target; again, this may be unacceptable for many applications.

While techniques have been proposed to address the consistency issue, in general, these techniques have not reliably provided fill volumes that remain within desired tolerances, or they have significantly increased manufacturing time and cost, i.e., they are inconsistent with the goal of having a high quality with a low consumer price point; such quality and low price points may be critical for applications where commercial products such as HDTV are involved.

There is therefore a need for techniques useful in depositing fluids into a target area of a substrate using a printhead having nozzles. More specifically, there is a need for a technique for accurately controlling the volume of deposited fluid in each target area of a substrate given variations in nozzle drop ejection volume, ideally in a cost-effective manner that allows for fast fluid deposition operations and thus improves device manufacturing speed. The techniques described below meet these needs and provide other related advantages.

Drawings

FIG. 1A is a diagram presenting a hypothetical (hypothetic) problem of depositing ink in target areas of a substrate, where a printhead with five nozzles is used to deposit 50.00pL of target fill in each of five specific target areas.

FIG. 1B is another graph presenting the hypothetical problem of depositing ink in a target area of a substrate, where a printhead with five nozzles is used to deposit a target fill of 50.00pL in each of two specific target areas.

Fig. 2A is an explanatory diagram showing a hypothetical arrangement of a printer and a substrate in an application in which the substrate will eventually form a display panel having pixels.

FIG. 2B is a cross-sectional close-up view of the printhead and substrate of FIG. 2A taken at an angle from line A-A of FIG. 2A.

FIG. 3A is a graph similar to FIG. 1A, but illustrating the use of a combination of drop volumes to reliably produce an ink fill volume for each target area within a predetermined tolerance range; in one alternative embodiment, different drop volume combinations are generated from a set of predetermined nozzle firing waveforms, and in another alternative embodiment, different drop volume combinations are generated from the nozzles of the printhead using relative motion (305) between the printhead and the substrate.

Fig. 3B is a diagram illustrating relative printhead/substrate motion and the ejection of different drop volume combinations into target areas of the substrate.

FIG. 3C is a graph similar to FIG. 1B, but illustrating the use of a combination of drop volumes to reliably produce an ink fill volume for each target area within a predetermined tolerance range; in one alternative embodiment, different drop volume combinations are generated from a set of predetermined nozzle firing waveforms, and in another alternative embodiment, different drop volume combinations are generated from the nozzles of the printhead using relative motion (372) between the printhead and the substrate.

FIG. 4 provides an illustrative diagram showing a series of optional layers, products or services that may each independently embody the previously described techniques.

FIG. 5 provides a block diagram illustrating a method of planning a combination of drops for each target area of a substrate; this method can be applied to any of the alternative embodiments described with reference to fig. 3A.

Fig. 6A provides a block diagram for selecting a particular set of acceptable drop combinations for each target region of a substrate, which may be used, for example, with any of the embodiments previously described.

Fig. 6B provides a block diagram for iteratively planning printhead/substrate motion and nozzle usage based on a user's combination of drops per print zone.

Fig. 6C provides a block diagram illustrating further optimization of printhead/substrate motion and nozzle usage, particularly in order to have the scans ordered in such a way that printing can be performed as efficiently as possible.

FIG. 6D is a hypothetical plan view of a substrate that will ultimately result in multiple flat panel display devices (e.g., 683); as represented by region 687, the printhead/substrate motion can be optimized for a particular region of a single flat panel display device, using the optimization repeatedly or periodically across each display device (such as the four depicted flat panel display devices).

Fig. 7 provides a block diagram for deliberately varying the fill volume within acceptable tolerances in order to reduce visual artifacts in a display device.

Fig. 8A provides a graph illustrating the change in target zone fill volume without adjustment for inter-nozzle drop volume changes of the printhead.

Fig. 8B provides a graph showing the variation in target zone fill volume, where different nozzles are randomly used to statistically compensate for inter-nozzle drop volume variation of the printhead.

Fig. 8C provides a graph illustrating the variation of target zone fill volume, wherein the target zone fill volume is achieved within precise tolerances as planned using one or more droplets of different volumes.

Fig. 9A provides a graph illustrating the change in target zone fill volume without adjustment for inter-nozzle drop volume changes of the printhead.

Fig. 9B provides a graph showing the variation in target zone fill volume, where different nozzles are randomly used to statistically compensate for inter-nozzle drop volume variation of the printhead.

Fig. 9C provides a graph illustrating the variation of target zone fill volume, wherein the target zone fill volume is achieved within precise tolerances as planned using one or more droplets of different volumes.

FIG. 10 shows a plan view of a printer used as part of a manufacturing apparatus; the printer may be in an air bag that allows printing to occur in a controlled atmosphere.

FIG. 11 provides a block diagram of a printer; such a printer may optionally be employed, for example, in the manufacturing apparatus depicted in fig. 10.

Fig. 12A shows an embodiment in which multiple printheads (each with a nozzle) are used to deposit ink on a substrate.

FIG. 12B shows the multiple printheads rotated to better align the nozzles of each printhead with the substrate.

Fig. 12C shows that individual ones of the multiple printheads are offset in association with a smart scan to intentionally create a particular drop volume combination.

FIG. 12D shows a cross-section of a substrate including layers that may be used in an Organic Light Emitting Diode (OLED) display.

Fig. 13A illustrates many different ways of customizing or changing the nozzle firing waveform.

FIG. 13B illustrates the manner in which a waveform is defined from discrete waveform segments.

Fig. 14A illustrates an embodiment in which different combinations of drop volume can be achieved using different combinations of predetermined nozzle firing waveforms.

FIG. 14B shows circuitry associated with generating and applying programming waveforms to the nozzles of the printhead at programming times (or locations); for example, this circuit provides one possible implementation of each of the circuits 1423/1431, 1424/1432, and 1425/1433 from fig. 14A.

FIG. 14C illustrates a flow diagram of one embodiment of firing waveforms using different nozzles.

The subject matter defined by the enumerated claims may be better understood by reference to the following detailed description, which is to be read in conjunction with the accompanying drawings. The following description of one or more specific embodiments set forth to enable a person to construct and use various implementations of the technology set forth in the claims is not intended to limit the enumerated claims, but is instead provided to exemplify their application. Without limiting the foregoing, the present disclosure provides a number of different examples of techniques for fabricating a layer of material by planning printhead movements so as to maintain the deposited ink volume within predetermined tolerances while not unduly increasing the number of printhead passes (and thus the time required to complete the deposited layer). The techniques may be embodied in software for performing the techniques, in the form of a computer, printer, or other device running such software, in the form of control data (e.g., printed images) for forming a layer of material, as a deposition mechanism, or in the form of an electronic or other device (e.g., a tablet device or other consumer end product) manufactured as a result of the techniques. While specific examples are presented, the principles described herein may also be applied to other methods, devices, and systems.

Detailed Description

The present disclosure relates to the use of a printing process to transfer layer material to a substrate. The nozzle consistency problem introduced above is solved by measuring the drop volume per nozzle (or the variation in drop volume across a nozzle) of the printhead for a given nozzle firing waveform. This allows the print head firing pattern (pattern) and/or motion to be planned to deposit a precisely polymerized fill volume of ink in each target area. With an understanding of how drop volumes vary across the nozzles, the print head/ground position offset and/or drop firing pattern can be planned in a manner that accommodates differences in drop volumes, but still deposits drops in adjacent target zones simultaneously with each pass or scan. From a different perspective, instead of normalizing or averaging the inter-nozzle variation in drop volume, specific drop volume characteristics for each nozzle are measured and used in a programmatic manner to achieve a specific in-range aggregate volume simultaneously for multiple target regions of the substrate; in many embodiments, this task is performed using an optimization process that reduces the number of scans or print head passes according to one or more optimization criteria.

In an alternative embodiment, the printhead and/or substrate are "stepped" in variable amounts to appropriately vary the nozzles used for each target zone in various passes to eject a specifically desired drop volume. Multiple passes are planned so that each target zone receives a particular aggregate fill. That is, each target region (e.g., each well in a row of wells that will form a pixilated component of a display) receives a planned combination of one or more drop volumes to achieve a collective volume within a specified tolerance range using different geometric steps of the printhead relative to the substrate. In a more detailed feature of this embodiment, given the mutual positional relationship of the nozzles, a pareto optimal solution may be calculated and applied such that a tolerable amount of volume change in each target zone is allowed within specification, but at the same time, the printhead/substrate movement is planned to maximize the average simultaneous use of the nozzles for each target deposition zone. In an optional refinement, a function is applied to reduce and even minimize the number of printhead/substrate passes required for printing. Temporarily reflected on these different features, the manufacturing costs are significantly reduced, since the printing of the material layer on the substrate can be performed quickly and efficiently.

Note that in a typical application, the target areas to receive ink may be arranged in an array, i.e. in a row and column layout, where swaths described with respect to the print head/substrate motion will deposit ink in a subset of all rows (of the target area of the array), but in a manner that covers all columns of the array in a single pass; also, the number of rows, columns and printhead nozzles can be quite large, e.g., involving hundreds or thousands of rows, columns and/or printhead nozzles.

The second alternative embodiment addresses the nozzle consistency problem in a slightly different manner. Making available to each nozzle a set of multiple pre-arranged replacement nozzle firing waveforms having known (and different) drop volume characteristics; for example, a set of four, eight, or another number of alternative waveforms may be hardwired or otherwise predefined to provide a corresponding set of optionally slightly different drop volumes. The volumetric data (or difference data) for each nozzle is then used to plan simultaneous deposition of multiple target zones by determining sets of nozzle waveform combinations for each target zone of the substrate. Again, a particular fill volume is achieved depending on the particular volume characteristics of each nozzle (and in this case, each nozzle waveform combination); that is, instead of attempting to correct for each nozzle volume variation, the variations are used in combination specifically to achieve a particular fill volume. Note that there will generally be many alternative combinations that may be used to deposit droplets to reach the desired range in each target area of the substrate. In more detailed embodiments, a "common set" of nozzle waveforms may be shared across some (or even all) of the nozzles of a printhead, each nozzle drop volume being stored and available for mixing and matching different drop volumes to achieve a particular fill. As another option, a calibration phase may be used to select different waveforms in an off-line process, based on which a particular set of nozzle firing waveforms is selected to achieve each specifically desired volume characteristic of the set. Again, in other detailed embodiments, optimization may be performed to plan printing in a manner that improves printing time, such as by minimizing the number of scans or print head passes, by maximizing simultaneous nozzle usage, or by optimizing some other criteria.

An alternative third embodiment relies on the use of multiple printheads, each having nozzles that may be offset relative to each other (or equivalently, a print architecture having multiple rows of nozzles that may be offset relative to each other). With such deliberate offsets, each nozzle volume change can be combined intelligently across the print head (or rows of nozzles) with each pass or scan. Again, there will typically be many alternative combinations that may be used to deposit droplets to reach the desired range in each target region of the substrate, and in detailed embodiments, optimization is performed to plan the use of offsets in a manner that improves print time, for example by minimizing the number of scans or print head passes or by maximizing simultaneous nozzle use, etc.

Note that one benefit of the above technique is that by tolerating drop volume variations but combining them to achieve a particular predetermined target zone fill volume, one can achieve a high degree of control over not only the ability to meet desired fill tolerance ranges, but also over precise volume amounts and deliberately controlled (or injected) variations in such amounts. For example, in one exemplary application of the described techniques, namely the manufacture of display devices, the above-described techniques facilitate controlled intentional variations in fill volume between pixels that will obscure any display artifacts in the finished display (i.e., will mitigate "line-shaped patterns" that might otherwise be visible to the human eye in the finished electrically-operable display). That is, even slight differences in the display at low spatial frequencies may result in unintended artifacts that are visible to the human eye and are therefore undesirable. It is therefore desirable in some embodiments to deliberately vary the fill volume of each target zone, yet still be within specification. Using an exemplary tolerance of 49.75 pL-50.25 pL, instead of simply arbitrarily ensuring that all target areas are filled to a common precise value within this tolerance range, it may be desirable for such applications to deliberately introduce random variations within this range so that any pattern of variation or discrepancy is not observable as a pattern by the human eye in the finished operational display. Applied to color displays, one exemplary embodiment intentionally adds such fill volume changes in a statistically independent manner for at least one of (a) the x-dimension (e.g., direction along a row of target regions), (b) the y-dimension (e.g., direction along a column of target regions), and/or (c) across one or more color dimensions (e.g., independently for red versus blue, blue versus green, red versus green target regions). In one embodiment, the variation is statistically independent across each of these dimensions. It is believed that such variations will cause any fill volume variation to become imperceptible to the human eye and thereby contribute to the high image quality of such displays.

Examples will help introduce some concepts regarding intelligent planning of the fill volume of each target zone. Simultaneous deposition of multiple target zones can be planned using per-nozzle volume data (or difference data) for a given nozzle firing waveform by determining a set of possible nozzle drop volumes for each target zone. There will typically be many possible combinations of nozzles that can deposit ink drops in multiple passes to fill each target area to a desired fill volume within a narrow tolerance range that meets specifications. Returning briefly to the assumptions introduced using FIG. 1A, if the acceptable fill volume according to specifications is between 49.75pL and 50.25pL (i.e., within 0.5% of the target), a number of different sets of nozzles/passes can also be used to achieve an acceptable fill volume, including without limitation: (a) five passes of nozzle 2 (10.01 pL) to a total of 50.05 pL; (b) a single pass of nozzle 1 (9.80 pL) and four passes of nozzle 5 (10.03 pL) to a total of 49.92 pL; (c) a single pass of nozzle 3 (9.89 pL) and four passes of nozzle 5 (10.03 pL) for a total of 50.01 pL; (d) a single pass of nozzle 3 (9.89 pL) and three passes of nozzle 4 (9.96 pL) and a single pass of nozzle 5 (10.03 pL) for a total of 49.80 pL; and (e) a single pass of nozzle 2 (10.01 pL), two passes of nozzle 4 (9.96 pL) and two passes of nozzle 5 (10.03 pL) to a total of 49.99 pL. Other combinations are clearly possible. Thus, even if only one selection of nozzle drive waveforms is available for each nozzle (or all nozzles), the first embodiment described above may be used to shift the print head relative to the substrate in a series of planned shifts or "geometric steps" that apply as many nozzles as possible to deposit droplets (e.g., in different target areas) during each scan, but which combine the deposited droplets for each target area in a specific predetermined manner. That is, many combinations of nozzle drop volumes in this assumption may be used to achieve a desired fill volume, and particular embodiments effectively select a particular one of the selectively acceptable drop combinations for each target zone (i.e., for a particular set of each region) by its selection of scanning motion and/or nozzle drive waveforms, thereby facilitating simultaneous filling of different rows and/or columns of target zones using respective nozzles. This first embodiment provides substantially improved manufacturing throughput by selecting the pattern of relative printhead/substrate motion in a manner that minimizes the time that printing occurs. Note that this improvement may optionally be embodied in a form that minimizes the number of printhead/substrate scans or "passes," in a manner that minimizes the original distance moved relative to the printhead/substrate, or in a manner that otherwise minimizes the overall printing time. That is, print head/substrate movement (e.g., scanning) may be preprogrammed and used to fill the target zone in a manner that satisfies predefined criteria, such as a minimum print head/substrate pass or scan, a minimum print head and/or substrate movement in a defined dimension(s), a minimum amount of time to print, or other criteria.

The method is all equally applicable to the assumption of fig. 1B in which the nozzles are not specifically aligned to each target zone. Again, if the acceptable fill volume according to specification is between 49.75pL and 50.25pL (i.e., within 0.5% of either side of the target), then acceptable fill volumes can also be achieved with many different sets of nozzles/passes, including without limitation all of the examples listed above for fig. 1A and additional examples specified by the assumptions of fig. 1B, where two adjacent nozzles are used in a single pass to fill a particular target zone, e.g., two passes of nozzle 4 (4) (9.96 pL) and nozzle (5) (10.03 pL) and one pass of nozzle (2) (10.01 pL), for a total of 49.99 pL. Other combinations are clearly possible.

These principles also apply to the second embodiment described above. For example, in the assumption presented by fig. 1A, each nozzle may be driven by five different firing waveforms identified as firing waveforms a through E, such that the resulting volumetric characteristics of the different nozzles for the different firing waveforms are described below with table 1A. Considering only the target zone 104 and only the nozzle (1), it would be possible to deposit a 50.00pL target in five passes, for example a first print head using the emission waveform D (to produce 9.96pL drops from the nozzle (1)) and four subsequent passes using the predefined emission waveform E (to produce 10.01pL drops from the nozzle (1)), all without any offset in the scan path. Likewise, different combinations of firing waveforms may be used simultaneously in each pass for each nozzle to produce a volume in each target zone that is close to the target value without any offset in the scan path. Thus, using multiple passes in this manner would be advantageous for embodiments in which it is desirable to deposit droplets simultaneously in different target areas (i.e., in different rows of pixels, for example).

TABLE 1A

These methods all apply equally to the assumption of fig. 1B. For example, considering only target zone 104 and nozzles (1) and (2) (i.e., the two nozzles that overlap target zone 154 during scanning), 50.00pL may be achieved in three passes, e.g., a first printhead by using nozzle (1) and predefined waveform B (up to a drop volume of 9.70 pL) and a second nozzle (2) and predefined waveform C (up to a drop volume of 10.10), a second printhead by using nozzle (1) and predefined waveform E (up to a drop volume of 10.01 pL) and nozzle (2) and predefined waveform D (up to a drop volume of 10.18 pL), and a third printhead by using nozzle (1) and predefined waveform E (up to a drop volume of 10.01 pL).

Note that it would also be possible for both the assumptions of fig. 1A and the assumptions of fig. 1B to fill the target volume in a single pass, each deposition in a single row of target zones in the present example; for example, it would be possible to rotate the print head ninety degrees and deposit exactly 50.00pL from each nozzle with a single drop for each target area in a row, for example using waveform (E) for nozzle (1), waveform (a) for nozzles (2), (4) and (5) and waveform (C) for nozzle (3) (10.01 pL +9.99pL +9.96pL +10.03 pL-50.00 pL).

These principles also apply to the third embodiment described above. For example, for the assumptions presented by fig. 1A, the volume characteristics may reflect the nozzles for a first printhead (e.g., "printhead a"), which is integrated with four additional printheads (e.g., printheads "B" through "E"), each driven by a single firing waveform and having a respective per-nozzle drop volume characteristic. The printheads are collectively organized such that, when a scan pass is performed, each nozzle identified as nozzle (1) for a printhead is aligned to print into a target zone (e.g., target zone 104 from FIG. 1A), each nozzle identified as nozzle (2) from various printheads is aligned to print into a second target zone (e.g., target zone 105 from FIG. 1A), and so on, the volumetric characteristics of different nozzles for different printheads are described below with Table 1B. Alternatively, motors that adjust, for example, the spacing between scans may be used to offset the printheads from one another. Considering only the target zone 104 and the nozzles (1) on each printhead, it would be possible to deposit 50.00pL in four passes, e.g., a first printhead pass in which both printhead D and printhead E emit droplets into the target zone and three subsequent passes in which only printhead E emits droplets into the target zone. Other combinations using even higher passes are possible, which can still produce volumes in the target region close to the 50.00pL target, for example in the range of 49.75pL and 50.25 pL. Considering again only the target zone 104 and nozzle (1) on each printhead, 49.83 pL would be deposited in two passes, e.g., a first printhead pass where printheads C, D and E all fire droplets into the target zone and a second printhead pass where both printheads D and E fire droplets into the target zone. Likewise, different combinations of nozzles from different print heads can be used simultaneously in each pass to produce a volume in each target zone that is close to the target value without any offset in the scan path. Thus, using multiple passes in this manner would be advantageous for embodiments in which it is desirable to deposit droplets simultaneously in different target areas (i.e., in different rows of pixels, for example).

TABLE 1B

All this method applies equally to the assumption of fig. 1B. Considering again only the target zone 154 and nozzles (1) and (2) on each printhead (i.e., nozzles that overlap the target zone 154 during scanning), 50.00pL may be deposited in two passes, e.g., a first printhead in which printheads C and E fire nozzle (1) and printheads B and C pass a first printhead firing nozzle (2) and a second printhead in which printhead C passes a second printhead firing nozzle (2). 49.99pL (obviously, within the exemplary target ranges of 49.75pL and 50.25 pL) may also be deposited in a single pass, e.g., with printheads C, D and E firing nozzle (1) and printheads B and E firing a printhead pass that fires nozzle (2).

It should also be apparent that the use of alternate nozzle firing waveforms, optionally in combination with scan path offsets, dramatically increases the number of drop volume combinations that can be achieved for a given printhead, and these options are further increased by using multiple printheads (or equivalently, multiple rows of nozzles) as described above. For example, in the hypothetical example conveyed by the discussion of fig. 1 above, the combination of five nozzles with respective inherent jetting characteristics (e.g., drop volumes) with eight alternative waveforms may provide almost thousands of different sets of possible drop volume combinations. Optimizing the sets of nozzle waveform combinations and selecting a particular set of nozzle waveform combinations for each target region (or for each row of print wells in the array) enables further optimization of printing according to desired criteria. In embodiments using multiple printheads (or rows of printhead nozzles), selectively offsetting those printheads/rows also further increases the number of combinations that can be applied per printhead/substrate scan. Again, for these embodiments, this second embodiment selects a particular one of the "acceptable" sets for each target zone, with this selection across that particular one of the target zones generally corresponding to simultaneous printing of multiple target zones using multiple nozzles, assuming that multiple sets of nozzle waveform combination(s) may alternatively be used to achieve the specified fill volume. That is, by changing parameters to minimize the time that printing occurs, these embodiments each improve manufacturing throughput and facilitate minimizing the number of print head/substrate scans or "passes" required, the raw distance moved relative to the print head/substrate along a particular dimension(s), the total print time, or help meet some other predetermined criteria.

Note that these techniques are optional with respect to each other; that is, for example, multiple nozzle firing waveforms may be used to achieve a desired drop combination without changing the position steps of the printhead/substrate scan and without offsetting multiple printheads/nozzle rows, and printhead/nozzle row offsets may be used without changing the position steps or changing the nozzle firing waveforms.

These different techniques may also optionally be combined with each other or with other techniques in any desired manner. For example, the nozzle drive waveform can be "tuned" on a per nozzle basis to reduce variations in drop volume per nozzle (e.g., shaping of the drive pulses by varying the drive voltage, rise or fall slope, pulse width, decay time, number and respective levels of pulses used per drop, etc.).

While certain applications discussed herein refer to fill volumes in discrete fluid containers or "wells," they may also use the techniques to deposit "over-coatings" having large layouts relative to other structures of the substrate (e.g., such as relative to transistors, vias, diodes, and other electronic components). In such a context, a fluid ink-transfer layer material (e.g., that would need to be cured, dried, or hardened in situ to form a permanent device layer) would spread to some extent, but would still retain specific characteristics (given ink viscosity and other factors) relative to other targeted deposition areas of the substrate. The techniques herein in this context may be used, for example, to deposit a cover layer, such as a seal or other layer, with specific localized control over the ink fill volume for each target zone. The techniques discussed herein are not limited to the specifically proposed applications or embodiments.

Other variations, advantages, and applications from the techniques described above will be apparent to those skilled in the art. That is, these techniques may be applied to many different fields, and are not limited to the fabrication of display devices or pixilated devices. Printing "well" as used herein refers to any receptacle that will receive a substrate upon which ink is deposited, and thus has chemical or structural properties suitable for restricting the flow of that ink. As will be exemplified below for OLED printing, this may include the case where the fluid containers will each receive a respective volume of ink and/or a respective type of ink; for example, in a display application where the techniques are used to deposit different colors of emissive material, successive printing processes may be performed for each color using respective printheads and respective inks — in this case, each process may deposit "every second well" in an array (e.g., for each "blue" color component) or, equivalently, every well in every second array (which intersperses wells with overlapping arrays for other color components). Other variations are also possible. Note also that "rows" and "columns" are used in this disclosure without implying any absolute direction. For example, a "row" of print wells may extend the length or width of the substrate, or in another manner (linear or non-linear); in general, "rows" and "columns" will be used herein to refer to directions that each represent at least one independent dimension, but this is not required for all embodiments. Also, note that since modern printers may use relative substrate/printhead motion involving multiple dimensions, the relative motion need not be linear in path or velocity, that is, the printhead/substrate relative motion need not follow a straight line or even a continuous path or constant velocity. Thus, "passing" or "scanning" of the printhead relative to the substrate simply refers to iterations of depositing droplets on multiple target areas using multiple nozzles involving relative printhead/substrate motion. However, in many of the embodiments described below for the OLED printing process, each pass or scan may be a substantially continuous linear motion, with each subsequent pass or scan being parallel to the next, offset in geometric steps relative to each other. This offset or geometric step may be a pass or scan start position, average position, difference in end position, or some other type of positional offset, and does not imply a necessarily parallel scan path. It should also be noted that the various embodiments discussed herein deal with the "simultaneous" use of different nozzles that will deposit in different target zones (e.g., different rows of target zones); this term "simultaneous" does not require simultaneous droplet ejection, but instead merely refers to the concept that different nozzles or groups of nozzles may be used to eject ink into target areas that are mutually exclusive during any scan or pass. For example, a first set of one or more nozzles may be fired during a given scan to deposit a first droplet in a first row of fluid wells, while a second set of one or more nozzles may be fired during the given scan to deposit a second droplet in a second row of fluid wells.

Thus, the essential parts of a number of different embodiments are presented, as the disclosure is organized substantially as follows. Fig. 2A-3C will be used to introduce some general principles regarding nozzle uniformity issues, OLED printing/manufacturing, and how the embodiments address the nozzle uniformity issues. These figures will also be used to introduce concepts related to planning printhead/substrate motion, for example where offset variation is used to vary which printhead nozzles are used to deposit drops in each row of a target area array of a substrate. Fig. 4-7 will be used to illustrate a software process that can be used to plan the drop composition for each target area of the substrate. Fig. 8A-9C are used to present certain empirical data, i.e., they demonstrate the effectiveness of the technique in improving well fill uniformity. Fig. 10-11 will be used to discuss an exemplary application to OLED panel manufacturing and associated printing and control mechanisms. Fig. 12A-12C are used to discuss printhead offsets that can be used to vary the combination of drops that can be deposited with each scan. Finally, fig. 13A-14C are used to further discuss different alternative nozzle firing waveforms as applied to providing different drop volumes.

As represented in fig. 2A, in one application, a printing process may be used to deposit one or more layers of material onto a substrate. The techniques discussed above may be used to generate print control instructions (e.g., an electronic control file that may be transmitted to a printer) for subsequent use in manufacturing a device. In one particular application, the instructions may be adapted to an inkjet printing process useful in printing a layer of low cost, scalable organic light emitting diode ("OLED") displays. More specifically, the techniques may be applied to deposit one or more light-emitting or other layers of such OLED devices, such as "red", "green", and "blue" (or other) pixelated color components or other light-emitting layers or components of such devices. This exemplary application is non-limiting, and the techniques may be applied to the manufacture of many other types of layers and/or devices, whether or not those layers are light emitting and whether or not the device is a display device. In this exemplary application, various conventional design constraints of inkjet printheads present challenges to process efficiency and film coverage coating uniformity for various layers of an OLED stack that can be printed using various inkjet printing systems. Those challenges may be addressed by the teachings herein.

More specifically, fig. 2A is a plan view of one embodiment of the printer 201. The printer includes a printhead 203 for depositing fluid ink onto a substrate 205. Unlike printer applications that print text and graphics, the printer 201 in this example is used during the manufacturing process to deposit fluid ink that will have a desired thickness. That is, in typical manufacturing applications, the ink carries the material that will be used to form a permanent layer of the finished device, where the layer has a specifically desired thickness that depends on the volume of ink applied. The ink is typically characterized by one or more materials that will form part of the finished layer, either as monomers, polymers, or materials carried by a solvent or other transport medium. In one embodiment, these materials are organic. After the ink is deposited, the ink is dried, cured or hardened to form a permanent layer; for example, some applications use an Ultraviolet (UV) curing process to convert monomers or polymers into a hardened material, while other processes dry the ink to remove the solvent and leave the transferred material in a permanent location. Other processes are also possible. Note that there are many other variations that distinguish the depicted printing process from conventional graphics and text applications; for example, in certain embodiments, the deposition of the desired material layer is performed in an environment that is controlled to adjust the ambient atmosphere to something other than air or to otherwise exclude unwanted particles. For example, as will be described further below, one contemplated application uses a manufacturing mechanism that encloses printer 201 within a plenum such that printing is performed in the presence of a controlled atmosphere, such as an inert environment, including, but not limited to, nitrogen, any inert gas, and any combination thereof.

As further seen in fig. 2A, the print head 203 includes a number of nozzles, such as nozzle 207. Note that in fig. 2A, the print head 203 and nozzles are depicted as opening out from the top of the page for purposes of illustration, but in fact face down toward the substrate and are hidden from view from the perspective of fig. 2A (i.e., fig. 2A shows what the cross-sectional view of the print head 203 is in fact). The nozzles are seen to be arranged in rows and columns (such as exemplary rows 208 and columns 209), but this is not required for all embodiments, i.e., certain embodiments use only a single row of nozzles (such as rows 208). In addition, rows of nozzles may be provided on print heads, each print head being (optionally) individually displaceable relative to each other, as described above. In applications where a printer is used to manufacture a portion of a display device, for example, for the material of each of the individual red, green and blue color components of the display device, the printer typically uses a dedicated print head component for each different ink or material, and the techniques discussed herein may be applied individually to each respective print head.

Fig. 2A illustrates one printhead 203. In this example, the printer 201 includes two different motion mechanisms that can be used to position the print head 203 relative to the substrate 205. First, a slip ring (riser) or carriage 211 may be used to mount the printhead 203 and allow relative movement as indicated by arrow 213. Second, however, a substrate transport mechanism may be used to move the substrate along one or more dimensions relative to the slip ring. For example, as represented by arrow 215, the substrate transport mechanism may allow movement in each of two orthogonal directions, such as according to x and y cartesian dimensions (217), and may optionally support substrate rotation. In one embodiment, the substrate transport mechanism includes an air bearing table for selectively securing and permitting movement of the substrate on the air bearing. Note also that the printer optionally allows rotation of the print head 203 relative to the slip ring 211, as represented by the rotation pattern 218. Such rotation allows the apparent spacing and relative configuration of the nozzles 207 to be changed relative to the substrate; for example, where each target region of the substrate is defined as a particular area or as having a certain spacing relative to another target region, rotation of the printhead and/or the substrate may vary the relative spacing of the nozzles in a direction along or perpendicular to the scan direction. In embodiments, the height of the print head 203 relative to the substrate 205 may also be varied, for example along the z-cartesian dimension into and out of the view direction of fig. 2A.

The two scan paths are respectively illustrated in fig. 2A with directional arrows 219 and 220, respectively. Briefly, the substrate motion mechanism moves the substrate back and forth in the direction of arrows 219 and 220 as the printhead moves in the direction of arrow 213 in geometric steps or offsets. With these combinations of movements, the nozzles of the print head can reach any desired area of the substrate to deposit ink. As previously mentioned, the ink is deposited in a controlled manner into discrete target areas of the substrate. The target regions may be arrayed, i.e., arranged in rows and columns, such as optionally along the depicted y and x dimensions, respectively. Note that in this figure it is seen that rows of nozzles (such as row 208) are perpendicular to the rows and columns of the target area, i.e., such that a row of nozzles is swept along the direction of each row of target area with each scan across each column of the target area of the substrate (e.g., along direction 219). This is not required for all embodiments. To obtain motion efficiency, subsequent scans or passes then reverse the direction of motion, hitting the target areas of the columns in the reverse order, i.e., along direction 220.

The arrangement of the target zones in this example is depicted with a highlighted area 221 seen on the right side of the figure in an enlarged view. That is, each of two rows of pixels, each having red, green, and blue color components, is represented by the numeral 223, while each of the columns of pixels orthogonal to the scan direction (219/220) is represented by the numeral 225. In the upper left pixel, it is seen that the red, green and blue components will occupy different target areas 227, 229 and 231 as part of each overlapping array of areas. Each color component in each pixel may also have associated electronics, such as represented by numeral 233. Where the device to be manufactured is a backlit display (e.g., as part of a conventional type LCD television), these electronics can control the selective generation of light filtered with red, green, and blue regions. In case the device to be manufactured is a new type of display, i.e. the red, green and blue areas directly generate their own light with corresponding color characteristics, these electronic means 233 may comprise patterned electrodes and other material layers that contribute to the desired light generation and light characteristics.

FIG. 2B provides a close-up cross-sectional view of printhead 203 and substrate 205 taken at the angle of line A-A in FIG. 2A. In fig. 2B, the numerals already described with reference to fig. 2A indicate the same features. More specifically, numeral 201 generally denotes a printer, and numeral 208 denotes a line of print nozzles 207. Each nozzle is designated using bracketed numbers such as (1), (2), (3), etc. A typical printhead typically has a plurality of such nozzles, such as 64, 128 or another number; in one embodiment, more than 1000 nozzles may be arranged in one or more rows. As previously described, the print head in this embodiment is moved relative to the substrate to achieve a geometric step or offset between scans in the direction referenced by arrow 213. Depending on the substrate motion mechanism, the substrate may be moved orthogonal to this direction (e.g., into and out of the page relative to the view of FIG. 2B), and in some embodiments, also in the direction represented by arrow 213. Note that fig. 2B also shows columns 225 of target areas 253 of the substrate, in this case arranged as "wells" that will receive deposited ink and retain the deposited ink within the structural confines of each well. It will be assumed for purposes of fig. 2B that only one ink is represented (e.g., each depicted well 253 represents only one color of the display, such as a red color component, other color components and associated wells not shown). Note that the figures are not to scale, for example, see that the nozzles are numbered from (1) to (16), while the wells are marked with letters from (a) to (ZZ), representing 702 wells. In certain embodiments, the nozzles will be aligned to each well such that the depicted printhead having 16 nozzles will deposit ink in the direction of arrow 255 in up to 16 wells simultaneously using a scan of relative printhead/substrate motion into and out of the page from the perspective of fig. 2B. In other embodiments, as described (e.g., with reference to fig. 1B), the nozzle density will be much greater than the target zone density, and as any scan or pass, a subset of the nozzles (e.g., a set of one to many, depending on which nozzles pass through each target zone) will be used for deposition. For example, again using the illustrative example of sixteen nozzles, it is possible that nozzles (1) - (3) could be used to deposit ink in a first target zone and nozzles (7-10) could be used simultaneously to deposit ink in a second target zone, in a mutually exclusive manner for a given pass.

Conventionally, it is possible to operate the printer using sixteen nozzles to deposit ink simultaneously in up to sixteen rows of wells, moving back and forth as required with subsequent scans until, for example, five drops are deposited in each well, the print head being advanced as required using a fixed step which is an integer multiple of the width of the swath traversed by the scan. However, the techniques provided by the present disclosure utilize droplets produced by different nozzles in combinations suitable for producing a particular fill volume for each wellAn inherent change in volume. Different embodiments rely on different technologies to implement these combinations. In one embodiment, the geometric steps are varied to achieve different combinations and are free to be something other than an integer multiple of the width described by the printhead swath. For example, if suitable for depositing selected sets of drop combinations in the wells 253 of FIG. 2A, the geometric stride may be 1/160 of swaths of the print head^thIn this example, it actually represents the relative displacement between the substrate and the printhead at a pitch of one tenth of a row of wells. The downshifting offset or geometric step may be different depending on the particular combination of drops desired in each well, e.g., 5/16 for the printhead swath^thsCorresponding to an integer spacing of the wells; this change can be continued in positive and negative steps as needed to deposit ink to achieve the desired fill volume. Note that there may be many different types or sizes of offsets, and the step size need not be fixed or a particular fraction of the well spacing between scans. However, in many manufacturing applications, it is desirable to minimize printing time in order to maximize production rates and minimize manufacturing costs per unit as much as possible; to this end, in certain embodiments, print head motion is planned and ordered in a manner that minimizes the total number of scans, the total number of geometric steps, the size of the offset or geometric steps, and the cumulative distance traversed by the geometric steps. These and other measures may be used individually, together, or in any desired combination to minimize the total print time. In embodiments where independently offsetable rows of nozzles (e.g., multiple printheads) are used, the geometric steps may be represented in part by offsets between printheads or nozzle rows; such offsets, combined with the overall offset of the printhead components (e.g., a fixed step for the printhead assembly), may be used to achieve variable size geometric steps and thus deposit drop combinations into each well. In embodiments where variations in the nozzle drive waveforms are used individually, conventional fixed steps may be used, with drop volume variation being achieved using multiple printheads and/or multiple printhead passes. As will be noted below, in one embodiment,the nozzle drive waveform can be programmed for each nozzle between drops, thus allowing each nozzle to generate and contribute a respective drop volume to each well within a row of wells.

Fig. 3A, 3B, and 3C are used to provide additional detail regarding the dependence on a particular drop volume when achieving a desired fill volume.

Fig. 3A presents an illustrative view 301 of the print head 303 and two related illustrations seen below the print head 303. The printhead is optionally used in embodiments that provide a non-fixed geometric step of the printhead relative to the substrate, and thus the offset that aligns a particular printhead nozzle (e.g., a total of 16 nozzles with nozzles (1) -5) depicted in fig. 1) with different target zones (five in this example, 307, 308, 309, 310, and 311) is represented using numeral 305. Attention is drawn back to the example of fig. 1A, if nozzles (1) - (16) produce drop volumes of 9.80, 10.01, 9.89, 9.96, 10.03, 9.99, 10.08, 10.00, 10.09, 10.07, 9.99, 9.92, 9.97, 9.8110.04, and 9.95 pL, respectively, of fluid ink, and if 50.00pL is desired to be deposited per target area, a percentage of this value of ± 0.5, the printhead may be used to deposit drops in five passes or scans, using geometric steps of 0, -1, -2, and-4, respectively, resulting in a total fill value for each region of 49.82, 49.92, 49.95, 49.90, and 50.16pL, as depicted in the figure; this is clearly within the desired tolerance range of 49.75-50.25 pL for each delineated target area. Each step in this example is represented incrementally with respect to the previous position, but other measures may be used. Thus, as can be seen, a precise adjusted filling can be achieved with a high degree of reliability using a combination of droplets in an intentional manner depending on the respective droplet volumes and the desired filling for each target area.

Note that this figure may be used to illustrate nozzle drive waveform variations and/or the use of multiple printheads. For example, if the nozzle reference numbers (1) - (16) refer to drop volumes for a single nozzle generated by sixteen different drive waveforms (i.e., using waveforms 1-16), then each region fill volume could theoretically be obtained simply by using different drive waveforms, such as waveform numbers 1, 2, 3, 5, and 9 for the target region 307. In practice, since process variations can result in different per-nozzle characteristics, the system will measure drop volumes for each nozzle for each waveform, and will intelligently plan drop combinations based thereon. In embodiments where nozzle reference numerals (1) - (15) refer to multiple printheads (e.g., reference numerals (1) - (5) refer to a first printhead, reference numerals (6) - (10) refer to a second printhead, and reference numerals (11) - (15) refer to a third printhead), offsets between printheads may be used to reduce the number of passes or scans; for example, the rightmost target zone 311 may have three drops deposited in a single pass, including drop volumes of 10.03, 10.09, and 9.97pL (printhead (1), 0 offset; printhead (2), +1 offset; and printhead (3), +2 offset). It should be apparent that the combination of these different techniques facilitates many possible combinations of specific volume droplets to achieve a specific fill volume within tolerances. Note that in fig. 3A, the variation in the polymerized ink fill volume between target areas is small and within tolerance, i.e., in the range of 49.82pL to 50.16 pL.

Fig. 3B shows another illustrative view 351 with different rectangles or bars representing each scan, such as referenced by numerals 353-360. In connection with this figure, it should be assumed that the print head/substrate relative motion advances in a sequence of variable-size geometric steps. Note again that, in general, each step will specify a scan of five areas that sweep a target area (e.g., pixels) of multiple columns beyond a single column represented on the plane of the page (and denoted by reference numerals 362-366). The scans are shown in top-down order, including a first scan 353 in which the printhead is seen to be displaced to the right relative to the substrate so that only nozzles (1) and (2) are aligned with the target zones 365 and 366, respectively. Within each print scan description (such as block 353), a circle is filled in solid black to represent each nozzle to indicate that the nozzle will fire when it is on a specifically delineated target area during the scan, or "open", i.e., filled in white, to indicate that the nozzle will not fire at the relevant time (but perhaps for other target areas encountered on the scan). Note that in this embodiment, each nozzle is fired in a binary manner, i.e., firing or not firing according to any adjustable parameter, for example to deposit a predetermined drop volume for each target region encountered during scanning. A "binary" firing scheme is optionally employed for any of the embodiments described herein (i.e., for example, where multiple firing waveforms are used, the waveform parameters are adjusted between drops). In the first pass 353, it is seen that nozzle (1) is fired to deposit 9.80pL droplets into the second rightmost target zone, while nozzle (2) is fired to deposit 10.01pL droplets into the rightmost target zone 366. The scan continues across the target areas of the other columns (e.g., the pixel wells of the other rows) and the ink drops are properly deposited. After the first pass 535 is complete, the print head is advanced by a geometric step of-3, which moves the print head to the left relative to the substrate so that nozzle (1) will now traverse the target zone 362 during a second scan 354 in the opposite direction to the first scan. During this second scan 354, nozzles (2), (3), (4), and (5) will also pass through regions 363, 364365, and 366, respectively. The circles filled with black see that at the appropriate time the drop volumes that would fire nozzles (1), (2), (3) and (5) to deposit 9.80pL, 10.01pL, 9.89pL and 10.03pL respectively, correspond to the inherent characteristics of nozzles (1), (2), (3) and (5). Note also that in any one pass, the nozzles in a row of nozzles used to deposit ink will do so in a mutually exclusive manner into each target zone, e.g., for pass 354, nozzle (1) is used to deposit ink into target zone 362 (but none of target zones 363-366), nozzle (2) is used to deposit ink in target zone 363 (but none of zones 362 or 364-366), nozzle (3) is used to deposit ink in target zone 365 (but none of zones 362-363 or 365-366), and nozzle (5) is used to deposit ink in target zone 366 (but none of zones 362-365). The third scan, represented by numeral 355, is used to effectively advance the print head by the target area of one line (-1 geometric step) so that nozzles (2), (3), (4), (5), and (6) will pass through regions 362, 363, 364, 365, and 366, respectively, during the scan; the solid filled nozzle graph indicates that during this pass each of the nozzles (2) - (6) will be actuated to emit a droplet, producing volumes of 10.01, 9.89, 9.96, 10.03 and 9.99pL respectively.

If the printing process stops at this point in time, region 366 would have, for example, a fill of 30.03pL (10.01 pL +10.03pL +9.96 pL) corresponding to three drops, while region 362 would have a fill of 19.81pL (9.80 pL +10.01 pL) corresponding to two drops. Note that the scan pattern in one embodiment follows a back and forth pattern represented by arrows 219 and 220 of fig. 2A. After the passage 356, 357, 358, 359, 360 and 361 (or scanning of multiple columns of such regions) of these target zones respectively: (a) droplets of 10.01pL, 0.00pL, 10.08pL, and 10.09pL in region 362, corresponding to the passage of nozzles (2), (3), (4), (7), and (9) in successive scans; (b) droplets of 0.00pL, 10.03pL, 10.00pL, and 10.07pL in the region 363 correspond to respective passes of the nozzles (3), (4), (5), (8), and (10) in the continuous scan; (c) droplets of 9.89pL, 9.96pL, 10.03pL, 9.99pL, 10.09pL and 0.00pL in region 364, corresponding to the passage of nozzles (4), (5), (6), (9) and (11) in successive scans; (d) droplets of 0.00pL, 9.99pL, 10.08pL, 10.07pL and 0.00pL in region 365 correspond to the passage of nozzles (5), (6), (7), (10) and (12) in successive scans; and (e) 9.99pL, 0.00pL, 10.00pL, 0.00pL and 0.00pL droplets in region 366, corresponding to the passage of nozzles (6), (7), (8), (11) and (13) in successive scans. Again, note that the nozzle in this example is used in a binary fashion with only a single firing waveform (i.e., such that its drop volume characteristics do not change between scans), e.g., in fifth scan 357, nozzle (7) does not fire, producing no drops (0.00 pL) for region 366, while on subsequent scans it fires, producing 10.08pL drops for region 365.

As seen in the chart at the bottom-most portion of the page, this hypothetical scanning procedure produced aggregate fills of 49.99pL, 50.00pL, 49.96pL, 49.99pL, and 50.02pL, easily within the desired range of the target value (50.00 pL) plus or minus percent (49.75 pL-50.25 pL). Note that in this example, the nozzles are used to deposit ink into multiple target zones substantially simultaneously for each scan, and the particular combination of drop volumes for each delineated region (i.e., as identified by the graphics at numerals 362, 363, 364, 365, and 366) is planned so that multiple drops can be deposited in each target zone with multiple passes. The eight depicted passes together relate to a particular set (or particular combination) of drop volumes that produce a fill volume within specified tolerances (e.g., the combination of drops from nozzles (1), (2), (7), and (9) in the case of region 362), although other sets of possible drops may also be used. For example, for region 362, five droplets from nozzle (2) (5 × 10.01 pL-50.05 pL) would alternatively be used; however, this replacement would be inefficient because additional scanning would be required because, for example, nozzle (3) (9.89 pL) could not be used extensively simultaneously during this time (i.e., the result from five droplets from this nozzle would be 5 x 9.89 ═ 49.45pL, outside the desired tolerance range). In the example superseded by fig. 3B, the particular scan and its sequence are selected so that less printing time, fewer passes, smaller geometric strides, and potentially a small aggregate geometric stride distance are used, or according to some other criteria. Note that the depicted example is for illustrative discussion only, and it may be possible to further reduce the number of scans using the presented liquid volume to less than eight scans to achieve target filling. In some embodiments, the scanning process is planned in a manner that avoids a worst case scenario with a required number of scans (e.g., one scan per line of the target area with ninety degrees of printhead rotation). In other embodiments, this optimization is applied to a degree based on one or more maxima or minima, for example, planning a scan in a manner that results in the fewest number of scans possible given all possible drop combinations for each target zone for a given ink.

Fig. 3C presents an illustrative view 301 of the print head 303 and two related illustrations seen below the print head 303, similar to fig. 3A, but here with nozzles that are not specifically aligned to a particular well. The printhead is optionally used in embodiments that provide a non-fixed geometric step of the printhead relative to the substrate, and thus the offset that aligns a particular printhead nozzle (e.g., a total of 16 nozzles with nozzles (1) - (5) depicted in fig. 1) with different target zones (two, 374 and 375 in this example) is represented using numeral 305. Again following the assumptions of fig. 3A, if nozzles (1) - (16) produce drop volumes of 9.80, 10.01, 9.89, 9.96, 10.03, 9.99, 10.08, 10.00, 10.09, 10.07, 9.99, 9.92, 9.97, 9.81, 10.04, and 9.95 pL, respectively, of fluid ink, and if it is desired to deposit 50.00pL per target area, a percentage of this value of ± 0.5, then the print head can be used to deposit drops in three passes or scans, using geometric steps of 0, -1, and-3, respectively, and firing one or two drops into each target area per scan. This will result in a total fill value for each of the regions of 49.93 and 50.10, as depicted in the figure, which is again clearly within the desired tolerance range of 49.75-50.25 pL for each depicted target region. Thus, as can be seen, the method is equally applicable to situations where the nozzles are not aligned to the wells, and a precise adjusted filling can be achieved using a combination of droplets in a deliberate manner depending on the individual droplet volumes and the desired filling for each target area. Further, as described above with respect to the assumptions of FIG. 3A, this figure may be used to represent nozzle drive waveform variations and/or the use of multiple printheads. For example, if the nozzle reference numbers (1) - (16) refer to drop volumes for a single nozzle generated by sixteen different drive waveforms (i.e., using waveforms 1-16), then each region fill volume could theoretically be obtained simply by using a different drive waveform. Those skilled in the art will see that the same method as described above with reference to figure 3B is equally applicable to the case where the nozzles are not specifically aligned to the wells, i.e. groups of one or more nozzles are used for simultaneous droplet deposition into each well. Finally, it is noted that fig. 3A, 3B and 3C also represent relatively simple examples; in typical applications, there may be hundreds to thousands of nozzles and millions of target areas. For example, in applications where the disclosed techniques are applied in the fabrication of each pixel color component of a current-resolved high-definition television screen (e.g., each pixel having red, green, and blue wells, the pixels being arranged in 1080 horizontal lines of vertical resolution and 1920 vertical lines of horizontal resolution), there are about six million wells (i.e., three overlapping arrays of each of two million wells) that may receive ink. It is expected that the next generation of television will increase this resolution by a factor of four or more. In such processes, to improve the speed of printing, the print head may use thousands of nozzles for printing, for example, there will typically be an alarming number of possible printing process changes. The simplified example presented above serves to introduce the concept, but it should be noted that given the incredible number presented in a typical combination, the changes represented by real tv applications are quite complex, print optimization is usually applied by software and using complex mathematical operations. Fig. 4-7 are intended to provide non-limiting examples of how these operations may be applied.

Note that the techniques presented in this disclosure can be illustrated in many different ways. For example, fig. 4 represents a number of different implementation levels, collectively designated by reference numeral 401, each of which represents a potentially separate implementation of the techniques introduced above. First, the techniques introduced above may be embodied as instructions stored on a non-transitory machine-readable medium, as represented by graph 403 (e.g., software for controlling a computer or printer). Second, these techniques may be implemented as part of a computer or network, such as within a company that designs or manufactures parts for sale or use in other products, according to computer icon 405. For example, the above-described techniques may be implemented as design software by a company that consults or performs a design for a High Definition Television (HDTV) manufacturer; alternatively, these techniques may be used directly by such manufacturers to manufacture televisions (or display screens). Third, as previously introduced and exemplified using storage media graphic 407, the previously introduced techniques may take the form of printer instructions, for example as storage instructions or data, which when acted upon will cause a printer to fabricate one or more component layers in accordance with the above discussion in accordance with the use of a planned drop aggregation technique. Fourth, as represented by manufacturing equipment icon 409, the techniques disclosed above may be implemented as part of a manufacturing device or machine, or in the form of a printer within such a device or machine. For example, a manufacturing machine may be sold or customized in a manner in which the translation of drop measurements and externally supplied "layer data" is automatically translated by the machine (e.g., by using software) into printer instructions to be printed using the techniques described herein to transparently optimize/accelerate the printing process. Such data can also be calculated offline and then reapplied in a reproducible manner during scalable, inline manufacturing to make many units. It should be noted that the particular depiction of the manufacturing device icon 409 represents one exemplary printer device that will be discussed below (e.g., with reference to fig. 8-9). The techniques introduced above may also be embodied as an assembly, such as an array 411 of multiple parts sold separately; for example, in fig. 4, a plurality of such components are depicted in the form of an array of semi-finished flat panel devices that will later be separated and sold for incorporation into the final consumer product. The depicted apparatus may have one or more layers (e.g., color component layers, semiconductor layers, sealing layers, or other materials) deposited, for example, according to the methods introduced above. The above-introduced techniques may also be embodied in the form of, for example, the mentioned end consumer product, for example, in the form of a display screen for a portable digital device 413 (such as, for example, an electronic board or smart phone), as a television display screen 415 (e.g., HDTV), or other type of device. For example, fig. 4 uses a solar panel graph 417 to indicate that the process introduced above may be applied to other forms of electronic equipment, for example to deposit each target area structure (such as one or more layers making up a separate unit of a polymerization apparatus) or a cover layer (e.g., a sealing layer for a TV or solar panel). Obviously, many examples are possible.

Without limitation, the techniques introduced above may be applied to any of the levels or components shown in fig. 4. For example, one embodiment of the technology disclosed herein is an end consumer device; a second embodiment of the technology disclosed herein is an apparatus comprising fabrication of a combined control layer that will use a specific nozzle volume to obtain data specific to each target zone fill; the nozzle volume may be predetermined or measured and applied in situ. Another embodiment is a deposition machine that prints one or more inks using the techniques described above, for example using a printer. The techniques may be implemented on one machine or more than one machine, such as a network or series of machines in which different steps are applied at different machines. All such embodiments and others may independently utilize the techniques presented in this disclosure.

An exemplary process for planning a print is described with reference to fig. 5. Reference is made generally to this process and associated methods and apparatus using the numeral 501.

More specifically, a drop volume is specifically determined for each nozzle (and for each waveform, if multiple drive waveforms are applied) 503. Such measurements may be performed, for example, using a variety of techniques, including, without limitation, optical imaging or laser imaging devices built into printers (or factory resident machines) that image drops during flight (e.g., during calibration printing operations or real-time printing operations) and accurately calculate volumes based on drop shape, velocity, trajectory, and/or other factors. Other techniques, including printing ink and then using post-print imaging or other techniques to calculate individual drop volumes based on pattern recognition, may also be used. Alternatively, the identification may be based on data supplied by the printer or printhead supplier, for example based on measurements taken at the factory and supplied by the machine (or online) well before the manufacturing process. In certain applications, the drop volume characteristics may change over time, for example, depending on the ink viscosity or type, temperature, nozzle clogging or other degradation, or due to other factors; thus, in one embodiment, drop volume measurements may be performed dynamically in-situ, such as at power-up (or upon the occurrence of other types of power cycling events), with each new printing of the substrate, upon expiration of a predetermined time, or based on another calendar or non-calendar time. This data (measured or provided) is stored for use in the optimization process, as represented by numeral 504.

In addition to each nozzle (and optionally each drive waveform) drop volume data, information is received regarding a desired fill volume for each target zone (505). This data may be a single target fill value to be applied to all target areas, individual target fill values to be applied to individual target areas, rows of target areas or columns of target areas, or values resolved in some other way. For example, when applied to the fabrication of a single "blanket" layer of material that is large relative to individual electronic device structures (such as transistors or vias), such data may consist of a single thickness to be applied to the entire layer (e.g., software then converts it into a desired ink fill volume per target area based on predetermined conversion data specific to the relevant ink); in this case, the data may be converted into a common value for each "print unit" (which in this case is equivalent to each target area or is composed of a plurality of target areas). In another example, the data may represent a particular value (e.g., 50.00 pL) for one or more wells, with the range data being provided or understood based on context. As will be appreciated from these examples, the desired fill may be specified in many different forms, including, without limitation, as thickness data or volume data. Additional filtering or processing criteria may also optionally be provided to or performed by the receiving device; for example, as previously mentioned, random variations in fill volume may be injected by the receiving device into one or more provided thickness or volume parameters to make the linear pattern invisible to the human eye in the finished display. Such changes may be performed in advance (and provided as individual per-target zone fills that differ from zone to zone), or may be derived intelligently and transparently from the receiving device (e.g., by a downstream computer or printer).

Based on the target fill volume and individual drop volume measurements for each region (i.e., each printhead nozzle and each nozzle drive waveform), the process then optionally proceeds to calculate various drop combinations that sum to a fill volume within a desired tolerance (i.e., each process block 506). As noted, targeted fill data may be provided for this scope, or may be "understood" based on context. In one embodiment, the range is understood to be ± one percent of the offered fill value. In another embodiment, the range is understood to be ± zero-five percent of the provided fill value. It will be apparent that there are many other possibilities for the tolerance ranges, whether greater or less than these exemplary ranges.

Here, the examples will help convey one possible method for calculating sets of possible drop combinations. Returning to the simplified example previously described, it should be assumed that there are five nozzles, each with a respective assumed droplet volume of 9.80pL, 10.01pL, 9.89pL, 9.96pL, and 10.03pL, and that a target volume of 50.00pL + -123% (49.75 pL-50.25 pL) is expected to be deposited in five wells. This method begins by determining the number of drops that can be combined to reach but not exceed a tolerance range and the minimum and maximum number of drops from each nozzle that can be used in any acceptable variation for that nozzle. For example, in this assumption, given the minimum and maximum drop volumes of the nozzle under consideration, no more than a single drop from nozzle (1), two drops from nozzle (3), and four drops from nozzle (4) may be used in any combination. This step limits the number of combinations that need to be considered. Providing such constraints on the set consideration, the method then takes into account a combination of the required number of droplets (five in this example), taking each nozzle in turn. For example, the method starts first with a nozzle (1), it being understood that the only acceptable combinations involving this nozzle feature one droplet or less from this nozzle. Considering the combination involving a single drop from this nozzle, the method then considers the minimum and maximum drop volumes of the other nozzle waveform combinations under consideration; for example, assuming that nozzle (1) is determined to produce a drop volume of 9.80pL for a given drive waveform, no more than one drop from nozzle (3) or two drops from nozzle (4) may be used in combination with a drop from nozzle (1) to achieve a desired tolerance range. The method proceeds to consider the combination of drops from nozzle (1) and four drops from other nozzles, e.g. four drops from nozzle (2) or (5), a combination of three drops from nozzle (2) and one drop from nozzle (4), etc. Considering only the combination involving the nozzles (1), any of the following different combinations involving the first nozzle could potentially be used within the tolerance range for simplicity of discussion:

{1 (1), (2), (1), (3), (2), (1), (4), (1), (2), (1), (5), (1), (2), (1), (4), (1), (2), (1), (3), (5), (1), (2), (1), (4), (5), (1), (2), (5), (1), (4), (5), (1), (4), (5) and (1), (5).

In the mathematical expressions set forth above, the use of parentheses indicates a set of five droplets representing a combination of droplet volumes from one or more nozzles, each parenthesis within the parentheses identifying a particular nozzle; for example, the expression {1 (1), 4 (2) } represents one droplet from the nozzle (1) and four droplets from the nozzle (2), 9.80pL + (4 × 10.01 pL) =49.84pL, which is within a specified tolerance. In fact, the method in this example considers the highest number of droplets from the nozzle (1), which can be used to produce the desired tolerance, evaluates the combination involving this highest number, reduces the number by one, and repeats the process of consideration. In one embodiment, this process is repeated to determine all possible sets of non-redundant drop combinations that may be used. When the combination involving nozzle (1) has been fully explored, the method proceeds to involve the combination of nozzle (2) instead of nozzle (1) and repeat the process, and so on, testing each possible nozzle combination to determine if it can achieve the desired tolerance range. For example, in the present embodiment, the method has determined that combinations of two or more droplets from nozzles (1) cannot be used, and therefore it starts with considering combinations involving one droplet from nozzle (1) and four droplets from other nozzles in various combinations. The method actually evaluates whether four droplets of nozzle (2) can be used, determines that it can be {1 (1), 4 (2) }, reduces this number by one (three droplets from nozzle 2), and determines that this number can be used in combination with a single droplet from nozzle (4) or (5), providing acceptable sets of {1 (1), 3 (2), 1 (4) }, {1 (1), 3 (2), 1 (5) }. The method then further reduces the number of acceptable droplets from nozzle (2) by one and evaluates the combination of {1 (1), 2 (2) … } and then {1 (1), 1 (2) … } and so on. Once the combination involving (2) is considered in combination with the droplets from nozzle (1), the method then takes the next nozzle, nozzle (3), and determines the only acceptable combination given by {1 (1), 1 (3), 3 (5) }, taking into account the combination involving this nozzle rather than the jet set (2). Once all combinations involving droplets from nozzle (1) have been considered, the method then considers 5 droplet combinations involving droplets from nozzle (2) instead of nozzle (1), for example {5 (2) }, {4 (2), 1 (3) }, {4 (2), 1 (4) }, {4 (2), 1 (5) }, {3 (2), 2 (3) }, {3 (2), 1 (3), 1 (4) }, etc. It should also be noted that this method is equally applicable where the nozzle can be driven with multiple firing waveforms, each producing a different drop volume. These additional nozzle waveform combinations simply provide additional drop volumes for use in selecting a set of drop combinations that are within the target volume tolerance. The use of multiple firing waveforms may also improve the efficiency of the printing process by making a larger number of acceptable drop combinations available and thereby increasing the likelihood of firing drops from a large fraction of nozzles simultaneously on each pass. Where a nozzle has multiple drive waveforms and also uses geometric steps, the selection of a set of drop combinations will incorporate both the geometric offset to be used in a given scan and the nozzle waveform to be used for each nozzle.

Note that the brute force approach has been described for narrative purposes, and in practice will typically present an amazing number of possible combinations, for example where the number of nozzles and target zones is large (e.g., more than 128 each). However, such calculations are well within the capabilities of high-speed processors with appropriate software. Also, note that there are various mathematical shortcuts that can be applied to reduce computations. For example, in a given embodiment, the method may exclude from consideration any combination that would correspond to using less than half of the available nozzles in any single pass (or alternatively, may limit consideration to combinations that minimize the difference in volume across the target zone (TR) in any single pass). In one embodiment, the method determines only certain sets of drop combinations that will yield acceptable aggregate fill values; in a second embodiment, the method exhaustively computes each possible set of drop combinations that will yield an acceptable aggregate fill value. An iterative approach may also be used in which, in a number of iterations, a print scan is performed and the volume of ink still to be deposited to reach the desired tolerance range(s) is considered for the purpose of optimizing the next subsequent scan. Other processes are also possible.

Note also that as an initial operation, if the same fill value (and tolerance) applies to each target area, it is sufficient to compute the combination once (e.g., for one target area) and store these possible drop combinations for initial use with each target area. This need not be the case for all aggregate calculation methods and for all applications (e.g., in some embodiments, the acceptable fill range may vary for each target zone).

In another embodiment, the method uses mathematical shortcuts such as approximation, matrix mathematics, random selection, or other techniques to determine the set of acceptable drop combinations for each target zone.

As represented by process block 507, once a set of acceptable combinations has been determined for each target zone, the method then effectively plans the scan in a manner associated with the particular set (or drop combination) for each target zone. This particular set selection is performed in a process-saving manner where a particular geometry (one for each target zone) is made by using at least one scan to deposit drop volumes in multiple target zones simultaneously. That is, ideally, the method selects a particular set for each target zone, where the particular set represents a particular drop volume combination in such a way that the printhead can print into multiple rows of target zones simultaneously at once. The particular drop selection in the selected combination represents a printing process that matches a predetermined criteria, such as a minimum print time, a minimum number of scans, a minimum size of geometric steps, a minimum aggregate geometric step distance, or other criteria. These criteria are represented by the numeral 508 in fig. 5. In one embodiment, the optimization is pareto-optimal, with the particular set selected in such a way that each of the scan coefficients, the aggregate geometric step distance, and the geometric step size are minimized in that order. Again, this selection of a particular set may be performed in any desired manner, a number of non-limiting examples being discussed further below.

In one example, the method selects a drop from each set for each target zone that corresponds to a particular geometric step or waveform that applies to all regions under consideration, and then it subtracts this drop from the available set and determines the remainder. For example, if the selection of the available set is initially {1 (1), 4 (2) }, {1 (1), 3 (2), 1 (4) }, {1 (1), 3 (2), 1 (5) }, {1 (1), 2 (2), 1 (4), 1 (5) }, {1 (1), 1 (2), 1 (3), 2 (5) }, {1 (1), 1 (2), 1 (4), 2 (5) }, {1 (1), 1 (2), 3 (5) }, {1 (1), 1 (3), 3 (5) }, {1 (1), 2 (4), 2 (5) }, {1 (1), 1 (4), 3 (5) }, and {1 (1), 4 (5) }, for each of the five target areas, then one droplet (1) from this initial set is subtracted to obtain the first remaining portion of the five target areas, one drop (2) is subtracted from the initial set to obtain the second specified remainder of the five target zones, one drop (3) is subtracted from the initial set to obtain the third specified remainder of the target zones, and so on. This evaluation will represent a geometric step of "0". The method will then evaluate the remaining portion and repeat the process for other possible geometric steps. For example, if a geometric stride of "-1" is then applied, the method would subtract one droplet from the initial set for a first of the five target regions (2), one droplet from the initial set for a second of the target regions (3), and so on, and evaluate the remainder.

In selecting a particular geometric step (and nozzle firing) as part of a print plan, the method analyzes the various remaining portions according to a score or priority function and selects the geometric step with the best score. In one embodiment, a score is applied to weight more heavily the steps of (a) maximizing the number of nozzles used simultaneously and (b) maximizing the minimum number of remaining combinations for the affected target region. For example, scanning using droplets from four nozzles during scanning would be more advantageous than scanning using droplets from only two nozzles. Likewise, if the subtraction process discussed above is used while considering the different steps resulting in 1, 2, 4, and 5 remaining combinations for each target region for one possible step and 2, 3, and 4 remaining combinations for each target region for a second possible step, the method will weight the latter more heavily (i.e., the largest minimum number is "2"). In practice, the appropriate weighting coefficients may be developed empirically. It will be apparent that other algorithms may be applied, and that other forms of analysis or algorithm shortcuts may be applied. For example, matrix mathematics (e.g., using eigenvector analysis) can be used to determine the particular drop combinations and associated scan parameters that satisfy predetermined criteria. In another variation, other formulas may be used that factor in the use of planned random fill variations to mitigate threadlines, for example.

Once a particular set and/or scan path has been selected, as per numeral 507, the printer actions are ordered, via numeral 509. For example, it should be noted that if aggregate fill volume is the only consideration, a set of droplets may generally be deposited in any order. The order of the geometric steps may also be selected to minimize printhead/substrate motion if the printing is planned to minimize the number of scans or passes; for example, if it is assumed that the acceptable scans in the example involve geometric steps of {0, +3, -2, +6, and-4 }, the scans may be reordered to minimize printhead/substrate motion and thus further improve printing speed, e.g., ordering the scans into a sequence of steps of {0, +1, +1, +2, and +4 }. The second sequence of geometric steps {0, +1, +1, +2, and +4} relates to an aggregate step increment distance of 8, which facilitates faster response by the printer, as compared to the first sequence of geometric steps relating to an aggregate step increment distance of 15. As indicated by numeral 510, for applications involving a large number of rows of target areas that will receive the same target fill, the particular solution may also be represented as a repeatable pattern that is then reproduced within a subset area of the substrate. For example, if there are 128 nozzles and 1024 rows of target zones arranged in a single row in one application, it is contemplated that the optimal scan pattern may be determined for 255 rows of target zones or less of the subset area; thus, in this example, the same print pattern may be applied to four or more subset areas of the substrate. Some embodiments thus utilize a repeatable pattern as represented by optional process block 510.

Note the use of non-transitory machine-readable medium icon 511; this icon represents that the above-described method is optionally implemented as instructions for controlling one or more machines (e.g., software or firmware for controlling one or more processors). The non-transitory medium may include any machine-readable physical medium, such as a flash drive, floppy disk, tape, server storage or mass storage, Dynamic Random Access Memory (DRAM), Compact Disk (CD), or other local or remote storage. This storage may be embodied as part of a larger machine (e.g., resident memory in a desktop computer or printer) or separately (e.g., a flash drive or separate storage that will later transfer files to another computer or printer). Each of the functions described with reference to fig. 5 may be implemented as part of a combined program or as separate modules, stored together on a single media presentation (e.g., a single floppy disk) or on multiple separate storage devices.

Once the planning process is complete, data effectively representing a set of printer instructions, including nozzle firing data for the print head and instructions for relative movement between the print head and the substrate that will support the firing pattern, will have been generated, as indicated by numeral 513 in fig. 5. This data, which effectively represents the scan path, scan order, and other data, is an electronic file (513) that can be stored for later use (e.g., as depicted by the non-transitory machine-readable medium icon 515) or immediately applied to control the printer (517) to deposit ink representing the selected combination (a particular set of nozzles for each target zone). For example, the method may be applied to a standalone computer, with the instruction data stored in RAM for later use or downloaded to another machine. Alternatively, the method may be implemented by a printer and dynamically applied to "in-going" data to automatically plan a scan according to printer parameters (such as nozzle-drop-volume data). Many other alternatives are possible.

Fig. 6A-6C provide a flow chart generally relating to a nozzle selection and scan planning process. Again, note that the scanning need not be continuous or linear in direction or speed of movement, and need not always advance from one side of the substrate to the other.

The first block diagram is denoted by numeral 601 in fig. 6A; this figure represents many of the exemplary processes discussed in the previous description. The method begins by first retrieving from memory a set of acceptable drop volume combinations for each target zone, via numeral 603. These sets may be dynamically computed, or may be pre-computed using software, for example, on different machines. Note the use of database icon 605, which represents a locally stored database (e.g., stored in local RAM) or a remote database. The method then effectively selects a particular one of the acceptable sets for each target region (607). In many embodiments, this selection is indirect, i.e., the method processes the acceptable combinations to select particular scans (e.g., using the techniques mentioned above), and it is these scans that actually define the particular set. However, by planning the scan, the method selects a particular set of combinations for each respective target region. This data is then used to sequence the scans and ultimately determine the motion and emission patterns (609), as mentioned above.

The middle and right diagrams of fig. 6A illustrate several process options for planning the scan path and nozzle firing pattern, and in fact, selecting a particular drop combination for each target zone in a manner that represents print optimization. The illustrated technique represents just one possible method for performing this task, as represented by numeral 608. Via numeral 611, the analysis may involve determining minimum and maximum usage of each nozzle (or nozzle-waveform combination, in those cases where the nozzles are driven by more than one firing waveform) in an acceptable combination. If a particular nozzle is bad (e.g., does not fire or fires at an unacceptable trajectory), that nozzle may be excluded from use (and consideration). Second, if a nozzle has a very small or very large drop volume, this can limit the number of drops that can be used from that nozzle in an acceptable combination; numeral 611 denotes a preprocessing for reducing the number of combinations to be considered. As represented by numeral 612, a process/shortcut can be used to limit the number of sets of drop combinations to be evaluated; for example, instead of considering "all" possible drop combinations for each nozzle, the method may be configured to optionally exclude combinations involving less than half of the nozzles (or another number of nozzles, such as ¼), combinations in which more than half of the nozzles are from any particular nozzle waveform, or combinations that represent high differences in drop volume or large differences in drop volume while applying across the target zone. Other metrics may also be used.

The method then proceeds to calculate and consider acceptable drop combinations, via numeral 613, according to any limit on the number of sets to be calculated/considered. As noted with numerals 614 and 615, various processes may be used to plan the scan and/or otherwise effectively select a particular set of drop volumes for each Target Region (TR). For example, as introduced above, one approach takes a scan path (e.g., a particular geometric stride selection) and then considers the maximum value selected across the least remaining set of all TRs being considered; the method may advantageously weight those scan paths (alternate geometric steps) that maximize the ability of subsequent scans to cover multiple target areas at once. Alternatively or additionally, the method may advantageously weight the geometric step that maximizes the number of nozzles used at one time; returning to the simplified five nozzle discussed above, the scan that would apply five nozzles to the target zone may be more advantageously weighted than a scan or pass that would have only three nozzles fired in the pass. Thus, in one embodiment, the following algorithm may be applied by software:

。

in this exemplary equation, "i" represents a particular choice of geometric step or scan path, w₁Representing an empirically determined weight, w₂Indicates a second empirically determined weight, # _ RemCoombs_TR，iDenotes the number of remaining combinations of each target area taking scan path i, and # _ Simult. Nozzles_iA metric representing the number of nozzles used for scan path i; note that this latter value need not be an integer, e.g., if the fill value of each TR changes (e.g., to hide potentially visible artifacts in the display device), then a given scan path may feature a varying number of nozzles used per column of the target area, e.g., an average or some other metric may be used. Note also that these factors and weights are merely illustrative, i.e., weights and/or considerations that differ from these may be used, only one variable may be used instead of another, or may be used upA totally different algorithm.

Fig. 6A also shows a number of other options. The consideration of the set of droplets in one embodiment is performed according to an equation/algorithm, for example, via numeral 617. The comparative metric may be expressed as a score that may be calculated for each possible alternative geometric stride in order to select a particular stride or offset. For example, another possible algorithmic approximation involves an equation with three terms, as follows:

S _i = W _v (S _v,min / S _v ) + W _e (S _e / S _e,max ) + W _d (S _d,min / S _d ),

wherein is based onS _v 、S _e AndS _d the terms of (a) are the fractions calculated separately for the difference in deposited drop volume, efficiency (maximum nozzles used per pass) and change in geometric step. In a formula, the term:S _v,min / S _v ) "try to minimize the change in fill volume compared to the target value per pass in a manner dependent on the total number of droplets.

Numeral 619 in FIG. 6A indicates that in one embodiment, drop combination selection can be performed using matrix mathematics, for example, by using a mathematical technique that considers all drop volume combinations simultaneously and uses one kind of eigenvector analysis to select the scan path.

As indicated by numeral 621, an iterative process may be applied to reduce the number of drop combinations considered. That is, the geometric strides may be calculated one at a time, as represented, for example, by the previous description of one possible processing technique. Each time a particular scan path is planned, the method determines the incremental volume still needed in each target zone under consideration, and then proceeds to determine the scan or geometric offset that best fits the aggregate or fill volume that produces each target zone within the desired tolerance. This process is then repeated as iterations until all scan paths and nozzle firing patterns have been planned.

A hybrid process may also be used, via numeral 622. For example, in one embodiment, a first set of one or more scans or geometric steps may be selected and used, e.g., based on a minimum deviation in drop volume per nozzle and a maximum efficiency (e.g., nozzles used per scan). Once a certain number of scans, e.g., 1, 2, 3, or more, have been applied, different algorithms, e.g., maximizing the nozzles used per scan (e.g., regardless of the deviation in drop volume applied), may be invoked. One of the algorithms may be applied in such a hybrid process to optionally apply any of the specific equations or techniques (or other techniques) discussed above, and no doubt other variations will occur to those skilled in the art.

Note that as previously mentioned, each target region fill volume may have been intentionally implanted (623) to mitigate plan randomization of the wirelines during exemplary display manufacturing. In one embodiment, a generator function (625) is optionally applied to deliberately change the target fill volume (or skew the aggregate volume generated for the drop combination for each target zone) in a manner that achieves this planning randomization or other effect. As previously mentioned, in different embodiments, such variations may also be calculated into the target fill volume and tolerance, i.e. even before analyzing the drop combinations, and e.g. applying an algorithmic approach as indicated previously to meet each target zone fill requirement.

Fig. 6B and numeral 631 refer to more detailed block diagrams related to the iterative solution mentioned above. As indicated by numerals 633 and 635, first, the possible drop combinations are again suitably identified, stored and retrieved for evaluation by the software. For each possible scan path (or geometric stride), the method stores, via numeral 637, footprints identifying the scan path (639) and the applied nozzles, and it subtracts each nozzle firing (641) from each target zone geometry to determine a remaining portion combination (643) for each target zone. These are also stored. The method then evaluates the stored data according to predefined criteria, via numeral 645. For example, as indicated by optional (dashed line) block 647, a method that seeks to maximize the minimum number of drop combinations across all relevant target regions may assign a score that indicates whether the combination just stored is better or worse than the previously considered alternative. If the specified criteria are met (645), a particular scan or geometric stride may be selected, and the remaining portion combination stored or otherwise marked for use in considering another print head/substrate scan or pass, as represented by numerals 649 and 651. If the criteria is not met (or the consideration is not complete), another stride may be considered and/or the method may adjust the consideration of the geometric stride (or previously selected portion) under consideration, via numeral 653. Again, many variations are possible.

It was previously noted that the order in which the scanning is performed or the droplets are deposited is not important for the final fill value for the target area. Notwithstanding this, to maximize printing speed and throughput, it is preferable to order the scans so as to result in the fastest or most efficient printing possible. Thus, if not previously calculated into the geometric stride analysis, then sorting and/or ordering of scans or strides may be performed. This process is illustrated in fig. 6C.

In particular, the method of fig. 6C is generally designated using the numeral 661. Software running on a suitable machine, for example, causes the processor to retrieve (663) the selected geometric step, the particular set, or other data identifying the selected scan path (and the appropriate nozzle firing pattern, which may also include data specifying which of a plurality of firing waveforms is to be used for each drop in those embodiments in which certain nozzles may be driven by more than one firing waveform). These steps or scans are then sorted or ordered in a manner that minimizes the incremental step distance. For example, referring again to the previously introduced hypothetical example, if the selected stride/scan path is {0, +3, -2, +6, and-4 }, then these maximums may be reordered to minimize each incremental stride and to minimize the total (aggregate) distance traversed between scans by the motion system. The incremental distances between these offsets would be equal to 3, 2, 6, and 4 (so that the aggregate distance traversed in this example would be "15"), without reordering, for example. If the scans (e.g., scans "a", "b", "c", "d", and "e") are reordered in the manner described (e.g., in the order of "a", "c", "b", "e", and "d"), the delta distances will be +1, +2, and +4 (so that the aggregate distance traversed will be "8"). As represented by numeral 667, here the method can assign motion to the print head motion system and/or the substrate motion system and reverse the order of nozzle firing (e.g., via numerals 219 and 220 of fig. 2A if alternating back and forth scan path directions are used). As previously described and represented by optional process block 669, in certain embodiments, planning and/or optimization may be performed for a subset of the target region, and then the solution applied in a spatially repetitive manner over a large substrate.

This repetition is represented in part by figure 6D. As suggested by fig. 6D, it should be assumed for this description that it is desirable to fabricate an array of flat panel devices. The common base is denoted by the numeral 681 and a set of dashed boxes, such as box 683, represent the geometry for each flat panel device. Fiducials 685 having two-dimensional characteristics are formed on the substrate and used to position and align the various manufacturing processes. After these processes are finally completed, each panel 683 is separated from the common substrate using a cutting or similar process. Where the panel array represents each OLED display, the common substrate 681 will typically be glass, the substrate being deposited on top of the glass, followed by one or more sealing layers; each panel is then inverted so that the glass substrate forms the light emitting surface of the display. For some applications, other substrate materials may be used, such as transparent or opaque flexible materials. As noted, many other types of devices may be fabricated in accordance with the techniques described. A solution may be computed for a particular subset 687 of the slab 683. This solution is then repeated for other similarly sized subsets 689 of the slab 683, and the entire solution set may then be repeated for each panel to be formed from a given substrate.

Recall that the various techniques and considerations introduced above, a manufacturing process can be performed to mass produce products quickly and at low cost per unit. Applied to display device manufacturing (e.g., flat panel display), these techniques enable a fast per-panel printing process, producing multiple panels from a common substrate. By providing a fast repeatable printing technique (e.g., using a common ink and print head between panels), it is believed that printing can be substantially improved, e.g., reducing each layer printing time to a fraction of the time that would be required without the above technique, all while ensuring that each target zone fill volume is within specification. Returning again to the example of a large HD television display, it is believed that each color component layer can be accurately and reliably printed for a large substrate (e.g., resulting in an 8.5 substrate that is about 220cm by 250 cm) in one hundred eighty seconds or less, or even ninety seconds or less, representing a significant process improvement. Improving the efficiency and quality of printing paves the way to significantly reduce the cost of producing large HD television displays and thus the cost of low end consumer devices. As previously mentioned, while display manufacturing (and in particular OLED manufacturing) is one application of the techniques described herein, these techniques may be applied to a variety of processes, computers, printers, software, manufacturing equipment, and end devices, and are not limited to display panels.

One benefit of the ability to deposit a precise target region volume (e.g., well volume) within tolerance is the ability to inject intentional variations within the tolerance as described. These techniques facilitate significant quality improvements of the display as they provide the ability to hide pixelation artifacts of the display such that such "line-shapes" are not perceptible to the human eye. Fig. 7 provides a block diagram 701 associated with one method for injecting this variation. As with the various methods and block diagrams discussed above, block diagram 701 and related methods may optionally be implemented as software, on a separate medium or as part of a larger machine.

As indicated by numeral 703, may vary depending on the particular frequency criteria. For example, it is generally understood that the sensitivity of the human eye to contrast variations is related to brightness, expected viewing distance, display resolution, color, and other factors. As part of the frequency criterion, a measure is used to ensure that given typical human eye sensitivity to spatial variations in contrast between colors between different brightness levels, such variations will be smoothed in a manner that is not visible to the human eye, e.g., altered in a manner that does not contribute human observable patterns between color components in (a) any one or more directions or (b) given expected viewing conditions. This may optionally be achieved using a planning randomization function, as previously mentioned. With the minimum criteria specified, the target fill volume for each color component and each pixel may be intentionally changed in a manner suitable to hide any visible artifacts from the human eye, as represented by numeral 705. Note that the right side of fig. 7 represents various process options, for example the variations may be independent across color components (707), and tests for the perceptible pattern are applied based on algorithms to ensure that filling variations do not cause the perceptible pattern. As indicated with numeral 707, the variation may also be made independent in each of a plurality of spatial dimensions (e.g., x and y dimensions) for any given color component (e.g., any given ink) (709). Again, in one embodiment, not only is the variation smoothed for each dimension/color component so that it is not perceptible, but any pattern of differences between each of these dimensions is also suppressed so that it is not visible. Via numeral 711, one or more generator functions can be applied to ensure that these criteria are met, such as by optionally using any desired criteria to assign a slight target fill variation to the filling of each target zone prior to drop volume analysis. As indicated by numeral 713, in one embodiment, the variation may optionally be made random.

The selection of a particular drop combination for each target zone is thus weighted in favor of the selected variation criterion, via numeral 715. As noted, this can be performed via target fill variation or at selected times of the drop (e.g., scan path, nozzle waveform combination, or both). Other methods for imparting this variation also exist. For example, in one contemplated embodiment, changing the scan path in a non-linear manner, via numeral 717, effectively changes the drop volume across the average scan path direction. Via numerals 719, the nozzle firing pattern can also be varied, such as by adjusting the firing pulse rise time, fall time, voltage, pulse width, or using multiple signal levels per pulse (or other forms of pulse shaping techniques) to provide small drop volume changes; in one embodiment, these variations may be pre-calculated, and in a different embodiment, only waveform variations that produce very minor volume variations are used, with other measures taken to ensure that the aggregate fill remains within specified tolerances. In one embodiment, for each target zone, a number of drop combinations that fall within a specified tolerance are calculated, and for each target zone, the selection of which drop combination to use in that target zone is varied (e.g., randomly or based on a mathematical function), thereby effectively varying the drop volume across the target zone and mitigating streaking. Such variations may be implemented along the scan path direction on a row of target areas, on a column of target areas, or both.

Figures 8A-9C are used to provide simulation data for the techniques discussed herein. Fig. 8A-8C show fill volumes based on five droplets, while fig. 9A-9C show fill volumes based on ten droplets. For each of these figures, the letter designation "a" (e.g., fig. 8A and 9A) represents the case where the nozzle is used to deposit a droplet without consideration of volume differences. Conversely, the letter designation "B" (e.g., fig. 8B and 9B) indicates a combination in which a random combination of (5 or 10) droplets is selected to "average" the expected volume difference between the nozzles. Finally, the letter designation "C" (e.g., fig. 8C and 9C) denotes the specific polymerized ink volume per target zone where scanning and nozzle firing depend on trying to minimize the polymerized fill variation across the target zone. In these different figures, it is assumed that the variation of each nozzle will coincide with the variation observed in an actual device, each vertical axis representing the aggregate fill volume in pL and each horizontal axis representing the number of target regions, e.g. pixel wells or pixel color components. Note that the emphasis of these figures will show the variation in aggregate fill volume, assuming a random distribution of drop variations around the assumed mean. For fig. 8A-8C, the average volume per nozzle is assumed to be slightly below 10.00pL per nozzle, and for fig. 9A-9C, the average drop volume per nozzle is assumed to be slightly above 10.00pL per nozzle.

A first graph 801 represented in fig. 8A shows each well volume change that takes the differences in nozzle drop volume without attempting to mitigate these differences. Note that these variations can be extreme (e.g., each peak 803), with a polymeric fill volume range of about ± 2.61%. As noted, the average of five droplets was slightly below 50.00 pL; fig. 8A shows two sets of sample tolerance ranges centered on this mean, including a first range 805 representing a range of ± 1.00% centered on this value and a second range 807 representing a range of ± 0.50% centered on this value. Such a printing process results in many wells that will not meet specifications (e.g., one or the other of these ranges), as seen with many peak and trough points that exceed the ranges (e.g., peak 803).

A second graph 811 represented in fig. 8B shows each well volume change using a randomized set of five nozzles per well in an attempt to statistically average the effect of drop volume change. Note that such techniques do not allow for the precise production of a specific volume of ink in any particular well, nor do such processes guarantee an aggregate volume within range. For example, while the percentage of fill volume that falls outside of specification represents a much better case than represented by fig. 8A, there are cases where individual wells (such as identified with sink points 813) fall outside of specification, such as ± 1.00% and ± 0.50% variation, represented by numerals 805 and 807, respectively. In this case, the min/max error is ± 1.01%, reflecting the improvement in the case of random mixing relative to the data presented in fig. 8A.

Fig. 8C shows a third case, using a specific combination of droplets per nozzle according to the above-described technique. In particular, the graph 821 shows that the variation is well within the range of ± 1.00% and quite close to satisfying the range of ± 0.50% for all representations of the target zone; again, these ranges are indicated by the numbers 805 and 807, respectively. In this example, the wells in each scan line are filled with five specifically selected drop volumes, with the printhead/substrate being appropriately displaced for each pass or scan. The min/max error is ± 0.595%, reflecting further improvement in the case of this form of "intelligent mixing". Note that this refinement and data observation is consistent for any form of intelligent drop volume combination to achieve a particular fill or tolerance range, such as where offsets between nozzle rows (or multiple printheads) are used or where multiple preselected drive waveforms are used to allow for a particular selected combination of drop volumes.

As noted, fig. 9A-9C present similar data, but assuming a combination of 10 drops per well, with an average drop volume of about 10.30pL per nozzle. In particular, graph 901 in fig. 9A represents a situation in which mitigation of drop volume differences is not noted, graph 911 in fig. 9B represents a situation in which drops are randomly applied in an attempt to statistically "average" the volume differences, and graph 921 in fig. 9C represents a situation in which planned mixing of particular drops (to achieve the average fill volume of fig. 9A/9B, i.e., about 103.10 pL) is achieved. These different figures show tolerance ranges that vary by + -1.00% and + -0.50% around this mean, represented by range arrows 905 and 907, respectively. Each of the figures further shows the respective peaks 903, 913, and 923 represented by the variations. Note, however, that fig. 9A represents a variation of ± 2.27% around the target, fig. 9B represents a variation of ± 0.707% around the target, and fig. 9C represents a variation of ± 0.447% around the target. By averaging over a larger number of drops, it is seen that the "random drops" of FIG. 9B will achieve a tolerance of + -1.00% around the mean rather than a + -0.50% range. Conversely, it is seen that the solution described in fig. 9C will meet two tolerance ranges, illustrating that variations can be constrained to fall within specification while still allowing for variations in drop combinations between wells.

These terms are used to describe an alternative embodiment of the technology described in this disclosure. That is to say, for use therein withFor a printing process where x% of the maximum drop volume change nozzles deposit a polymerized fill volume with y% of the maximum expected volume change, there are conventionally few means to ensure that the polymerized fill volume will change by less than x%. This presents a potential problem for applications where x% is greater than y%. The drop averaging technique (e.g., as represented by the data seen in fig. 8B and 9B) statistically reduces the volume change across the target zone tox%/(n) ^1/2 Where n is the average number of droplets required per target zone to achieve the desired fill volume. Note that even with such statistical methods, there is no mechanism for reliably ensuring that the actual target zone fill volume will fall within the tolerance of y%. The techniques discussed herein provide mechanisms for providing such reliability. An alternative embodiment thus provides a method of generating control data or controlling a printer, and related apparatus, systems, software and systems in which the statistical volume difference across the target area is better thanx%/(n) ^1/2 (e.g., substantially better thanx%/(n) ^1/2 ) The method of (1). In particular embodiments, this condition is met in cases where the printhead nozzles are used simultaneously to deposit droplets in rows of target areas (e.g., pixel wells) with each scan. Unless otherwise specified, in such particular embodiments, a nozzle representing a drop variation of ± x% of the target drop volume will have its drops combined to achieve a target zone fill volume, wherein the target zone aggregate fill volume has less thanx%/(n) ^1/2 And is characterized by the simultaneous use of different nozzles for different rows of target areas for each printhead/substrate scan.

With a basic set of techniques for combining droplets such that the sum of their volumes is specifically selected to meet the specific goals thus described, the present document will now turn to a more detailed discussion of specific devices and applications that may benefit from these principles. This discussion is intended to be non-limiting, i.e., to describe a few specifically contemplated embodiments for practicing the methods presented above.

As seen in fig. 10, the multi-chamber manufacturing apparatus 1001 includes a plurality of general modules or subsystems, including a transfer module 1003, a print module 1005, and a process module 1007. Each module maintains a controlled environment such that, for example, printing may be performed by the printing module 1005 in a first controlled atmosphere, and other processes, for example, another deposition process such as an inorganic sealing layer deposition or curing process (e.g., for printed materials), may be performed in a second controlled atmosphere. The apparatus 1001 uses one or more mechanical handlers to move substrates between modules without exposing the substrates to an uncontrolled atmosphere. Within any given module, other substrate handling systems and/or specific equipment and control systems suitable for the process to be performed for that module may be used.

Various embodiments of the transfer module 1003 may include an input load lock 1009 (i.e., a chamber that provides buffering between different environments while maintaining a controlled atmosphere), a transfer chamber 1011 (also having a carrier for transporting substrates), and an atmosphere buffer chamber 1013. Within print module 1005, other substrate handling mechanisms, such as a floating table, may be used for stable support of the substrate during the printing process. Additionally, an xyz motion system, such as a split axis or gantry motion system, may be used for precise positioning of the at least one printhead relative to the substrate and to provide a y-axis transport system for transport of the substrate through the print module 1005. Multiple inks may also be used for printing within the print chamber, for example using respective print head assemblies, so that two different types of deposition processes may be performed within the print module, for example in a controlled atmosphere. The printing module 1005 may include a gas enclosure 1015 housing an inkjet printing system with means for introducing an inert atmosphere (e.g., nitrogen, a noble gas, another similar gas, or a combination thereof) and otherwise controlling the atmosphere with respect to environmental regulations (e.g., temperature and pressure), gas composition, and particle presence.

The process module 1007 can include, for example, a transfer chamber 1016; the transfer chamber also has a carrier for transporting the substrate. In addition, the process module may further include an output load lock 1017, a nitrogen stack buffer 1019, and a curing chamber 1021. In certain applications, a curing chamber may be used to cure the monomer film into a uniform polymer film, for example using a thermal or UV radiation curing process.

In one application, the apparatus 1001 is suitable for mass production of large batches of liquid crystal or OLED displays, for example, eight arrays of screens fabricated at a time on a single large substrate. These screens can be used for televisions and as display screens for other forms of electronic equipment. In a second application, the device can be used in substantially the same way for mass production of solar panels.

Applied to the drop volume combining techniques described above, print module 1005 may be advantageously used in display panel manufacturing to deposit one or more layers, such as filter layers, light emitting layers, barrier layers, conductive layers, organic or inorganic layers, sealing layers, and other types of materials. For example, the described apparatus 1001 may be loaded with a substrate and may be controlled to move back and forth between various chambers to deposit and/or cure or harden one or more printed layers, all in a manner that is not interrupted by intermediate exposure to an uncontrolled atmosphere. The substrate may be loaded via input load lock 1009. The carrier located in transfer module 1003 may move the substrate from input load lock 1009 to print module 1005 and after the printing process is complete to process module 1007 for curing. By repeated deposition of subsequent layers, each controlled volume of each target zone, the polymeric layer properties can be built up to suit any desired application. Again, note that the techniques described above are not limited to display panel manufacturing processes and many different types of tools may be used. For example, the configuration of apparatus 1001 may be altered to place the various modules 1003, 1005, and 1007 in different juxtapositions; also, additional or fewer modules may be used.

Although fig. 10 provides one example of a set of linked chambers or manufactured components, it is apparent that many other possibilities exist. The droplet deposition technique described above may be used with the apparatus described in figure 10 or, indeed, to control a manufacturing process carried out by any other type of deposition apparatus.

FIG. 11 provides a block diagram illustrating various subsystems of an apparatus that may be used to fabricate a fabrication facility having one or more layers as specified herein. Coordination for the various subsystems is provided by the processor 1103, acting on instructions provided by software (not shown in fig. 11). During the manufacturing process, the processor feeds data to the print head 1105 to cause the print head to eject various volumes of ink in accordance with firing instructions provided by, for example, a halftone printed image. The printhead 1105 typically has a plurality of inkjet nozzles arranged in rows (or an array of rows) and associated reservoirs that allow for the ejection of ink in response to the activation of a piezoelectric or other transducer of each nozzle; such transducers cause the nozzles to eject a controlled amount of ink in an amount controlled by an electronic nozzle drive waveform signal applied to the corresponding piezoelectric transducer. Other transmission mechanisms may also be used. The printhead applies ink to the substrate 1107 at various x-y positions corresponding to grid coordinates within various print units, as represented by the halftone print image. The change in position is accomplished by both the printhead motion system 1109 and the substrate handling system 1111 (e.g., causing the printing to trace one or more swaths across the substrate). In one embodiment, the printhead motion system 1109 moves the printhead back and forth along the slip ring while the substrate handling system provides stable substrate support and "y" dimension transport of the substrate to enable "split axis" printing of any portion of the substrate; the substrate handling system provides relatively fast y-dimension transport while the printhead motion system 1009 provides relatively slow x-dimension transport. In another embodiment, substrate handling system 1111 may provide both x and y dimension transfer. In another embodiment, the primary transport may be provided entirely by substrate handling system 1111. Image capture device 1113 may be used to locate any fiducials and aid in alignment and/or error detection.

The apparatus also includes an ink delivery system 1115 and a printhead maintenance system 1117 to assist in printing operations. The print head may be periodically calibrated or subjected to a maintenance process; to this end, during a maintenance sequence, printhead maintenance system 1117 is used to perform appropriate priming, ink or gas purging, testing and calibration, and other operations, as the case may be for a particular process.

As previously introduced, the printing process may be performed in a controlled environment, i.e. in a manner that presents a reduced risk of contaminants that may reduce the effectiveness of the deposited layer. To this end, the apparatus includes a chamber control system 1119 that controls the atmosphere within the chamber, as represented by function block 1121. An optional process variation as described may include performing the jetting of the deposition material in the presence of an ambient nitrogen atmosphere.

As previously described, in the embodiments disclosed herein, the individual drop volumes are combined to achieve a particular fill volume for each target zone selected according to the target fill volume. A specific fill volume can be planned for each target region, the fill value varying around the target value within an acceptable tolerance range. For such embodiments, drop volume is specifically measured in a manner that depends on ink, nozzle, drive waveform, and other factors. To this end, reference numeral 1123 denotes an optional drop volume measurement system, in which a drop volume 1125 is measured for each nozzle and for each drive waveform, and then stored in a memory 1127. Such a drop measurement system may be an optical strobe camera or laser scanning device (or other volumetric measuring tool) incorporated into a commercial printing device, as previously described. In one embodiment, such devices operate in real time (or near real time) to measure individual drop volumes, deposition trajectories, drop velocities, and the like. This data is provided to the processor 1103 during printing or during a one-time, intermittent, or periodic calibration operation. As indicated by numeral 1129, a pre-arranged set of firing waveforms may also optionally be associated with each nozzle for later use in generating a particular each target area drop combination; if such a set of waveforms is used for the present embodiment, it is advantageous to calculate drop volume measurements during calibration using the drop measurement system 1127 for each nozzle for each waveform. Providing a real-time or near real-time droplet volume measurement system greatly enhances the reliability in providing target zone volume filling within a desired tolerance range, since measurements can be taken and processed (e.g., averaged) as needed to minimize statistical volume measurement errors.

Numeral 1131 refers to the use of print optimization software running on the processor 1103. More specifically, this software uses this information based on drop volumes 1125 (measured in situ or otherwise provided) to plan printing in a manner that appropriately combines the drop volumes to obtain a specific fill volume for each target zone. In one embodiment, according to the above embodiments, the aggregate volume can be planned to a resolution of 0.01pL or better, within a certain error tolerance. Once printing has been planned, the processor calculates printing parameters such as the number and sequence of scans, drop size, relative drop firing time, and similar information, and constructs a print image that is used to determine nozzle firing for each scan. In one embodiment, the printed image is a halftone image. In another embodiment, the printhead has a plurality of nozzles, up to 10,000. As will be described below, each drop may be described in terms of a time value and an emission value (e.g., data describing an emission waveform or data indicating whether an ink drop is to be emitted "digitally"). In embodiments where the drop volume of each well is varied depending on geometric steps and binary nozzle firing decisions, each drop may be defined by one bit of data, a step size value (or number of scans), and a position value indicating where the drop will be placed. In embodiments where the scanning represents continuous motion, a time value may be used as an equivalent to a position value. Whether in time/distance or absolute position, the value describes the position relative to a reference (e.g., a synchronization mark, position, or pulse) that accurately specifies the position and time at which the nozzle should fire. In some embodiments, multiple values may be used. For example, in one particularly contemplated embodiment, a synchronization pulse is generated for each nozzle in a manner corresponding to relative printhead/substrate motion per micron during scanning; with respect to each synchronization pulse, each nozzle is programmed with: (a) a description of an offset value that delays the integer clock cycle before the nozzle fires, (b) a 4-bit waveform selection signal to describe one of fifteen waveform selections programmed into memory dedicated to a particular nozzle driver (i.e., one of sixteen possible values specifies the "off" or non-firing state of the nozzle), and (c) a repeatability value that specifies that the nozzle should fire only once, once for each sync pulse, or once for every n sync pulses. In this case, the address and waveform selection for each nozzle is associated by the processor 1103 with specific drop volume data stored in the memory 1127, the firing of a specific waveform from a specific nozzle representing a planning decision that a specific corresponding drop volume is to be used to supply polymerized ink to a specific target area of the substrate.

Figures 12A-14C will be used to describe other techniques that can be used to combine different drop volumes to obtain a precisely toleranced fill volume for each target region. In a first technique, rows of nozzles can be selectively offset relative to one another during printing (e.g., between scans). This technique is described with reference to fig. 12A-12B. In a second technique, the nozzle drive waveform can be used to adjust the properties (including volume) of the piezoelectric transducer firing and thus each ejected drop. Fig. 13A-13B are used to discuss a number of options. Finally, in one embodiment, a set of multiple replacement drop firing waveforms is pre-computed and made available to each print nozzle. This technique and related circuitry are discussed with reference to fig. 14A-C.

Fig. 12A provides a layout 1201 of a printhead 1203 traversing a substrate 1205 in a scan direction indicated by arrow 1207. Here it is seen that the substrate will be comprised of a number of pixels 1209, each having wells 1209-R, 1209-G, and 1209-B associated with each color component. Again, note that this description is merely an example, i.e., the techniques as used herein may be applied to any layer of a display (e.g., not limited to a separate color component and not limited to a color-imparting layer); these techniques may also be used to fabricate things other than display devices. In this case, the intent is that the print head deposits one ink at a time, and assuming that the inks are color component specific, separate printing processes will be performed for each well of the display, one for each of the color components. Thus, if the first process is being used to deposit ink specific to the occurrence of red light, only the first well of each pixel will receive ink during the first printing process, such as wells 1209-R of pixel 1209 and similar wells of pixel 1211. During a second printing process, only the second well (1209-G) of pixel 1209 and a similar well of pixel 1211 will receive the second ink, and so on. The various wells are thus shown as three different overlapping arrays of target regions (in this case fluid containers or wells).

The printhead 1203 includes a number of nozzles, such as represented using numerals 1213, 1215, and 1217. In this case, each numeral refers to a separate row of nozzles, each row extending along a column axis 1218 of the substrate. Nozzles 1213, 1215 and 1217 are seen to form a first column of nozzles relative to substrate 1205, and nozzle 1229 represents a second column of nozzles. As depicted with fig. 12A, the nozzles are not aligned with the pixels, and as the printhead traverses the substrate in a scan, some nozzles will pass over the target area while others will not. Further, in the figure, while print nozzles 1213, 1215, and 1217 are precisely aligned to the center of a row of pixels starting from pixel 1209, and print nozzle 1229 of the second column will also pass over the row of pixels starting from pixel 1211, the alignment is not precisely to the center of the pixels. However, in many applications, the precise location at which the droplets are deposited within the target area is not important, and such misalignment is acceptable. Note that this figure is merely illustrative, for example, in practice the nozzles may be spaced sufficiently close together in some embodiments that more than one nozzle of a single printhead may be used in any pass to deposit ink in a given well (e.g., as shown in the assumptions of fig. 1B and 3C). Alignment/misalignment of the nozzle columns to the well rows is depicted by lines 1225 and 1227, respectively, which represent the centers of the print wells that will receive ink.

Fig. 12B provides a second view 1231 in which it is seen that all three rows of nozzles (or individual print heads) have been rotated approximately thirty degrees relative to the shaft 1218. This optional capability was previously referenced in fig. 2A with numeral 218. More specifically, due to the rotation, the spacing of the nozzles along the column axis 1218 has now changed, with each column of nozzles aligned with the trap centers 1225 and 1227. Note, however, that due to the scanning motion 1207, the nozzles from each column of nozzles will pass through a column of pixels (e.g., 1209 and 1211) at different relative times and thus potentially have different positional emission data (e.g., different timing for emitting droplets). In certain embodiments, such specifically aligned arrangement is preferred, particularly where the deposited droplets must be accurately positioned within the target zone. In other embodiments, arrangements in which the nozzles are not specifically or precisely aligned to the target zone are preferred due to reduced system complexity, particularly where it is not necessary to position each droplet at a precise location within the target zone.

As represented in fig. 12C, in one embodiment, a printhead optionally assigned rows of nozzles can have such rows selectively offset from each other. That is, fig. 12C provides another plan view in which each of the printheads (or nozzle rows) 1219, 1221, and 1223 are offset relative to one another, as represented by offset arrows 1253 and 1255. These rows represent the use of alternative motion mechanisms, one for each row of nozzles, to allow selective offset of the respective row relative to the printhead assembly. This provides different combinations of nozzles (and associated particular drop volumes) with each scan and thus for different particular drop combinations (e.g., via numeral 1207). For example, in such embodiments, and as depicted with fig. 12C, such offsets allow both nozzles 1213 and 1257 to be aligned with centerline 1225, and thus their respective drop volumes to be combined in a single pass. Note that the present embodiment is considered to be a specific example of an embodiment that changes the geometric step size, e.g., even if the geometric step size between successive scans of the printhead assembly 1203 relative to the substrate 1205 is fixed, each such scanning motion of a given row of nozzles is effectively located at a variable offset or step in other scans using a motion mechanism relative to the position of the given row. However, it should be appreciated that such embodiments allow for the aggregation of individual per-nozzle drop volumes in a particular combination (or set of drops) for each well, but with a reduced number of scans or passes, in accordance with the principles previously described. For example, with the embodiment depicted in fig. 12C, three droplets may be deposited in each target region (e.g., a well for a red component) with each scan, and furthermore, this offset allows for a planned variation of droplet volume combinations.

FIG. 12D illustrates a cross-section of the finished display taken in the scan direction for one well (e.g., well 1209-R from FIG. 12A). In particular, this view shows a substrate 1252 of a flat panel display, in particular an OLED device. The depicted cross-section shows the active region 1253 and the conductive terminals 1255 that will receive electrical signals to control the display (including the color of each pixel). The small oval region 1261 of the view is seen enlarged at the right side of the figure to illustrate the layers in the active area above the base 1252. These layers include an anode layer 1269, a hole injection layer ("HIL") 1271, a hole transport layer ("HTL") 1273, an emissive or emissive layer ("EML") 1275, an electron transport layer ("ETL") 1277, and a cathode layer 1278, respectively. Additional layers such as polarizers, barrier layers, primers, and other materials may also be included. In some cases, an OLED device may include only a subset of these layers. When the depicted stack is finally operated after fabrication, the current causes recombination of electrons and "holes" in the EML, resulting in emission of light. Anode layer 1269 may include one or more transparent electrodes common to multiple color components and/or pixels; for example, the anode may be formed of Indium Tin Oxide (ITO). Anode layer 1269 may also be reflective or opaque, and other materials may be used. Cathode layer 1278 is typically comprised of patterned electrodes to provide selective control of the color components for each pixel. The cathode layer may comprise a reflective metal layer, such as aluminium. The cathode layer may also comprise an opaque or transparent layer, such as a thin layer of metal in combination with a layer of ITO. The cathode and anode together serve to supply and collect electrons and holes into and/or through the OLED stack. The HIL 1271 is generally used to transport holes from the anode into the HTL. The HTL 1273 is generally used to transport holes from the HIL into the EML while also blocking the transport of electrons from the EML into the HTL. The ETL 1277 is generally used to transport electrons from the cathode into the EML, while also preventing transport of electrons from the EML into the ETL. These layers thus together serve to supply electrons and holes into the EML 1275 and confine those electrons and holes in the layer so that they can recombine to generate light. Typically, the EML is composed of an individually controlled active material for each of the three primary colors, red, green and blue, for each pixel of the display, and as mentioned, is represented in this case by a material that produces red light.

The layers in the active region may be degraded by exposure to oxygen and/or moisture. It is therefore desirable to enhance OLED lifetime by sealing the layers on the sides and sides (1262/1263) and lateral edges of those layers opposite the substrate. The purpose of the seal is to provide an oxygen and/or moisture resistant barrier. Such seals may be formed, in whole or in part, via deposition of one or more thin film layers.

The techniques discussed herein may be used to deposit any of these layers as well as combinations of such layers. Thus, in one contemplated application, the techniques discussed herein provide ink volumes for the EML layer for each of the three primary colors. In another application, the techniques discussed herein are used to provide ink volumes for HIL layers, and the like. In another application, the techniques discussed herein are used to provide ink volumes for one or more OLED sealing layers. The printing techniques discussed herein may be used to deposit organic or inorganic layers (as the case may be for process technologies) as well as layers for other types of displays and non-display devices.

Fig. 13A is used to describe nozzle drive waveform adjustment and the use of alternative nozzle drive waveforms that will provide different ejected drop volumes from each nozzle of the printhead. The first waveform 1303 is considered a single pulse, consisting of a quiescent interval 1305 (0 volts), a rising slope 1313 associated with a decision that the nozzle is to fire at time t2, a voltage pulse or signal level 1307, and a falling slope 1311 at time t 3. The effective pulse width, represented by the numeral 1309, has a duration approximately equal to t3-t2, depending on the difference between the rising and falling slopes of the pulse. In one embodiment, any of these parameters (e.g., rising slope, voltage, falling slope, pulse duration) may be varied to potentially change the drop volume ejection characteristics for a given nozzle. The second waveform 1323 is similar to the first waveform 1303 except that it represents a larger drive voltage 1325 relative to the signal level 1307 of the first waveform 1303. Due to the larger pulse voltage and the limited rising slope 1327, it will take longer to reach this higher voltage, and as such, the falling slope 1329 generally lags relative to a similar slope 1311 from the first waveform. The third waveform 1333 is also similar to the first waveform 1303, except that in this case a different rising slope 1335 and or a different falling slope 1337 can be used in place of slopes 1313 and 1311 (e.g., by adjustment of nozzle impedance). The different slopes may be made steeper or shallower (in the depicted case, steeper). Conversely, in the case of the fourth waveform 1343, the pulse is made longer, for example using a delay circuit (e.g., a voltage controlled delay line) to increase both the time of the pulse at a given signal level (as represented by the numeral 1345) and the falling edge of the delayed pulse (as represented by the numeral 1347). Finally, a fifth waveform 1353 represents the use of multiple discrete signal levels that also provide a means of pulse shaping. For example, it is seen that this waveform will include a time at the first noted signal level 1307, but then apply a slope that rises to the second signal level 1355 halfway between times t3 and t 2. Due to the larger voltage, the trailing edge of this waveform 1357 is seen to lag behind the falling edge 1311.

Any of these techniques may be used in combination with any of the embodiments discussed herein. For example, drive waveform adjustment techniques can optionally be used to vary drop volume within a small range after the scanning motion and nozzle firing have been planned to mitigate line striping. Designing the waveform variations in a manner such that the second tolerance is within specification facilitates deposition of high quality layers with planned non-random or planned random variations. For example, returning to the previously introduced assumption where the television manufacturer specified a fill volume of 50.00pL + -0.50%, the per-region fill volume could be calculated within a first range of 50.00pL + -0.25% (49.785 pL-50.125 pL), applying a non-random or stochastic technique to the waveform variations that statistically contributed to a volume variation per droplet of no more than + -0.025 pL (given the 5 droplets needed to reach the aggregate fill volume). Obviously, many variations exist.

As described above, in one embodiment represented by the fifth waveform 1353 from fig. 13A, multiple signal levels may be used to shape the pulse. This technique is further discussed with reference to fig. 13B.

That is, in one embodiment, the waveform may be predefined to define a sequence of discrete signal levels, for example, from digital data, with the drive waveform being generated by a digital-to-analog converter (DAC). Numeral 1351 in fig. 13B refers to a waveform 1353 having discrete signal levels 1355, 1357, 1359, 1361, 1363, 1365, and 1367. In this embodiment, each nozzle driver includes circuitry that receives and stores up to sixteen different signal waveforms, each waveform being defined by a series of up to sixteen signal levels, each represented as a multi-bit voltage and duration. That is, in such embodiments, the pulse width can be effectively varied by defining different durations for one or more signal levels, and the drive voltage is waveform shaped in a manner selected to provide a small drop size variation, e.g., the drop volume is measured to provide a particular volume level increment such as in 0.10 pL. Thus, with such embodiments, wave shaping provides the ability to tailor drop volume to approximate a target drop volume value; when combined with other specific drop volumes, such as using the techniques exemplified above, these techniques facilitate accurate fill volumes for each target zone. In addition, however, these wave forming techniques also facilitate strategies for reducing or eliminating thread-like patterns; for example, in one alternative embodiment, the drops of a particular volume are combined, as discussed above, but the last drop (or drops) is selected in a manner that provides variation with respect to the boundaries of the desired tolerance range. In another embodiment, the predetermined waveform may be applied with optional further waveform shaping applied as appropriate to adjust the volume. In another example, the use of the burst drive waveform alternative provides a mechanism to plan the volume such that no further waveform shaping is required.

Typically, the effect of different drive waveforms and resulting drop volumes are measured in advance. For each nozzle, up to sixteen different drive waveforms are then stored in a 1k Synchronous Random Access Memory (SRAM) for each nozzle for later selective use in providing discrete volume changes selected by software. With different drive waveforms at hand, each nozzle is then commanded drop by drop as to which waveform to apply via data programming that implements the particular drive waveform.

Figure 14A illustrates such an embodiment, generally designated by the numeral 1401. In particular, the processor 1403 is used to receive data defining a predetermined fill volume for each target region. This data may be a layout file or bitmap file that defines the drop volume for each grid point or location address, as represented by numeral 1405. A series of piezoelectric transducers 1407, 1408, and 1409 produce associated ejected drop volumes 1411, 1412, and 1413, respectively, that depend on a number of factors, including nozzle drive waveforms and printhead-to-printhead manufacturing variations. During the calibration operation, each of a set of variables, including the use of nozzle-to-nozzle variation and different drive waveforms, is tested for its effect on drop volume, assuming that a particular ink will be used; this calibration operation may be made dynamic, if desired, for example to respond to temperature changes, nozzle clogging, or other parameters. This calibration is represented by a drop measurement device 1415, which provides measurement data to the processor 1403 for use in managing the print plan and subsequent printing. In one embodiment, this measurement data is calculated during operation that takes almost a few minutes, such as no more than thirty minutes, and preferably less (e.g., for thousands of printhead nozzles and potentially tens of possible nozzle firing waveforms). This data may be stored in memory 1417 for use in processing the layout or bitmap data 1405 as it is received. In one embodiment, the processor 1403 is part of a computer that is remote from the actual printer, while in a second embodiment, the processor 1403 is integrated with the manufacturing mechanism for the product (e.g., the system for manufacturing the display) or with the printer.

To perform the emission of the droplets, one of a group is receivedOr a plurality of timing or synchronization signals 1419 for use as a reference, and these are passed through a clock tree 1421 for assignment to each nozzle driver 1423, 1424, and 1425 to generate drive waveforms for the particular nozzle (1427, 1428, and 1429, respectively). Each nozzle driver has one or more registers 1431, 1432, and 1433, respectively, which receive multi-bit programming data and timing information from processor 1403. Each nozzle driver and its associated registers receive one or more dedicated write enable signals (we) for the purpose of programming registers 1431, 1432, and 1433, respectively_n). In one embodiment, each of the registers includes a large amount of memory, including 1k SRAM to store a plurality of predetermined waveforms and a programmable register to select between those waveforms and the generation of further control waveforms. The data and timing information from the processor is described as multi-bit information, and this information can be provided to each nozzle via a serial or parallel bit connection (as will be seen in FIG. 14B, discussed below, in one embodiment this connection is serial, as opposed to the parallel signal representation seen in FIG. 14A).

For a given deposition, print head, or ink, the processor selects, for each nozzle, a set of sixteen drive waveforms that can be selectively applied to produce a drop; note that this number is arbitrary, e.g., four waveforms may be used in one design and four thousand in another. These waveforms are advantageously selected to provide a desired change in output drop volume for each nozzle, for example to cause each nozzle to have at least one waveform selection that produces a near ideal drop volume (e.g., 10.00 pL) and to provide a range of intentional volume changes for each nozzle. In various embodiments, the same set of sixteen drive waveforms is used for all nozzles, but in the depicted embodiment, each of sixteen potentially unique waveforms, each waveform contributing a respective drop volume characteristic, is defined separately in advance for each nozzle.

During printing, to control the deposition of each drop, data selecting one of the predefined waveforms is then programmed to each nozzle by nozzleIn each register 1431, 1432, or 1433 of the nozzle. For example, given a target volume of 10.00pL, the nozzle driver 1423 may be configured by writing data into the register 1431 to set one of sixteen waveforms corresponding to one of sixteen different drop volumes. The volume produced by each nozzle will have been measured with a drop measurement device 1415, and the nozzle-by-nozzle (and waveform-by-waveform) drop volumes registered by the processor 1403 and stored in memory to help produce the desired target fill. The processor may define by programming register 1431 whether it wants a particular nozzle driver 1423 to output a processor-selected one of the sixteen waveforms. In addition, the processor may program the registers to have, for a given scan line, each nozzle delay or offset for nozzle firing (e.g., to align each nozzle with the grid traversed by the print head to correct errors and for other purposes); this offset is achieved by a counter that offsets a particular nozzle by a programmable number of timing pulses for each scan. In one embodiment, the synchronization signal assigned to all nozzles occurs at defined time intervals (e.g., one microsecond), and in another embodiment, the synchronization signal is adjusted relative to printer motion and substrate layout, e.g., fired for incremental relative motion between the printhead and the substrate per micron. High-speed clock (φ _hs ) Operate thousands of times faster than the synchronization signal, e.g., at 100 megahertz, 33 megahertz, etc.; in one embodiment, a plurality of different clock or other timing signals (e.g., strobe signals) may be used in combination. The processor further programming a value defining a grid spacing; in one embodiment, the grid spacing is common to the entire pool of available nozzles, but this is not required for every embodiment. For example, in some cases, a regular grid may be defined in which each nozzle will fire "every five microns". In one contemplated embodiment, memory is shared across all nozzles, which allows the processor to pre-store many different grid spacings (e.g., 16) shared across all nozzles so that the processor can select a new grid spacing (as needed), which is then read out to all jetsMouth (e.g., to define an irregular grid). For example, in embodiments where the nozzle is to emit for each color component well of the OLED (e.g., to deposit a non-color specific layer), three or more different grid spacings may be applied sequentially by the processor in a cyclical manner. Obviously, many design alternatives are possible. Note that the processor 1403 may also dynamically reprogram the registers of each nozzle during operation, applying the synchronization pulse as a trigger to start any programmed waveform pulse set in its registers, and if new data is received asynchronously before the next synchronization pulse, the new data will be applied with the next synchronization pulse. In addition to setting parameters for sync pulse generation (1436), processor 1403 also controls the initiation and speed of the scan (1435). In addition, the processor controls the rotation of the printhead (1437) for the various purposes described above. In this way, each nozzle can fire concurrently (or simultaneously) with any one of sixteen different waveforms for each nozzle at any time (i.e., with any "next" synchronization pulse), and the selected firing waveform can be switched between firing, dynamically, with any other of the sixteen different waveforms, during a single scan.

FIG. 14B shows additional detail of circuitry (1441) used in such embodiments to generate output nozzle drive waveforms for each nozzle; the output waveform is represented as in fig. 14B "nzzl-drv. wvfm". More specifically, circuit 1441 receives an input of a synchronization signal, a unit line carrying serial data ("data"), a dedicated write enable signal (we), and a high speed clock ((we))φ _hs ). Register file 1443 provides data for at least three registers that convey initial offsets, grid definition values, and drive waveform IDs, respectively. The initial offset is a programmable value that adjusts each nozzle to align with the starting point of the grid, as described. For example, given implementation variables such as multiple printheads, multiple rows of nozzles, different printhead rotations, nozzle firing speeds and patterns, and other factors, an initial offset may be used to bring the drop pattern of each nozzle from the gridThe starting points are aligned to account for delay and other factors. The grid definition value is a number representing the number of synchronization pulses that are "counted" before the programmed waveform is triggered; in the case of printing an embodiment of a flat panel display (e.g., an OLED panel), the target area in which the macro outline is printed has one or more regular pitches, corresponding to a regular (constant pitch) or irregular (multi-pitch) grid, with respect to the different printhead nozzles. As previously described, in one embodiment, the processor maintains its own sixteen-entry SRAM to define up to sixteen different grid pitches that can be read out to the register circuits for all nozzles as needed. Thus, if the grid spacing value is set to two (e.g., two per micron), each nozzle will fire at this interval. The drive waveform ID represents a selection of one of the pre-stored drive waveforms for each nozzle and may be programmed and stored in a number of ways depending on the embodiment. In one embodiment, the drive waveform ID is a four-bit selection value and each nozzle has its own dedicated 1 kbyte SRAM to store up to sixteen predetermined nozzle drive waveforms, stored as 16 × 16 × 4B entries. Briefly, each of the sixteen entries for each waveform contains four bytes representing programmable signal levels, representing two byte resolution voltage levels and two byte programmable durations, for counting the number of pulses of the high speed clock. Each programmable waveform may thus consist of (zero to one) up to sixteen discrete pulses, each having a programmable voltage and duration (e.g., having a duration of 1-255 pulses equal to a 33 megahertz clock).

Numerals 1445, 1446, and 1447 specify one embodiment of circuitry showing how a specified waveform may be generated. The first counter 1445 receives a synchronization pulse to initiate a countdown of the initial offset triggered by the start of the new scan line; the first counter 1445 counts down in micrometer increments and when zero is reached, a trigger signal is output from the first counter 1445 to the second counter 1446; this trigger signal essentially starts the firing process for each nozzle for each scan line. The second counter 1446 is then in micronsThe increments implement a programmable grid spacing. The first counter 1445 is reset in conjunction with a new scan line while the second counter 1446 is reset with the next edge of the high speed clock after its output flip-flop. The second counter 1446, when triggered, activates the waveform circuit generator 1447, which generates the selected drive waveform shape for the particular nozzle. This latter circuit is based on the high speed clock(s) (ii) as represented by dashed boxes 1448-1450 seen below the generator circuitφ _hs ) A clocked high speed digital to analog converter 1448, a counter 1449, and a high voltage amplifier 1450. Upon receipt of a trigger from the second counter 1446, the waveform generator circuit retrieves the digital pair (signal level and duration) represented by the pair of drive waveform IDs and generates a given output analog voltage from the signal level value, and the counter 1449 effectively maintains the DAC output for a certain duration from the counter. The relevant output voltage level is then applied to the high voltage amplifier 1450 and output as a nozzle drive waveform. The next digital pair is then latched out of register 1443 to define the next signal level value/duration, etc.

The depicted circuitry provides an efficient means of defining any desired waveform from the data provided by the processor 1403. As noted, in one embodiment, the processor pre-asserts a set of waveforms (e.g., 16 possible waveforms per nozzle), and then it writes definitions for each of these selected waveforms into the SRAM of the driver circuit for each nozzle, then implements the "firing time" assertion of the programmable waveforms by writing a four-bit drive waveform ID into each nozzle register.

FIG. 14C provides a flow chart 1451 that discusses a method of using different waveforms and different configuration options for each nozzle. As indicated at 1453, a system (e.g., one or more processors acting in accordance with instructions from appropriate software) selects a set of predetermined nozzle drive waveforms. The drop volume is measured for each waveform and for each nozzle (1455), in particular using, for example, a laser measuring device or a CCD camera. These volumes are stored in a processor-accessible memory, such as memory 1457. Again, the measurement parameters may vary depending on the choice of ink and many other factors; thus, calibration is performed based on those factors and the planned deposition activity. For example, in one embodiment 1461, calibration may be performed at the factory where the print head or printer is manufactured, and this data may be programmed into a vending device (e.g., printer) or made available for download. Alternatively, for printers with optional drop measurement devices or systems, these volume measurements may be performed at first use (1463), such as at initial device configuration. In another embodiment, the measurement (1465) is performed with each power cycle, such as each time the printer is turned on or awakened from a low power state or otherwise enters a state in which it is ready to print. As previously described, for embodiments in which the ejected drop volume is affected by temperature or other dynamic factors, calibration (1467) may be performed intermittently or periodically, such as after expiration of a defined time interval, upon detection of an error, at the state of each new substrate operation (e.g., during substrate loading and/or loading), daily, or in some other manner. Other calibration techniques and schedules (1469) may also be used.

The calibration technique may optionally be performed in an off-line process or during a calibration mode, as represented by process separation line 1470. As noted, in one embodiment, such a process is completed in less than thirty minutes, potentially for thousands of print nozzles and one or more associated nozzle firing waveforms. During online operation (or during a printing mode) represented below this process separation line 1470, measured drop volumes are used in selecting groups of drops for each target region based on the particular measured drop volumes, such that the drop volumes for each group sum to a particular aggregate volume, via 1471, within a defined tolerance range. The volume of each region may be selected based on a layout file, bitmap data, or some other representation, as represented by numeral 1472. Based on the allowable combinations of these drop volumes and drop volumes for each target area, the firing pattern and/or scan path is selected, effectively representing the particular combination of drops for each target area (i.e., one of the acceptable sets of combinations) to be used for the deposition process, as represented by numeral 1473. As part of this selection or planning process 1473, an optimization function 1474 may optionally be employed, for example, to reduce the number of scans or passes by at least the product of the average number of drops per target zone times the number of rows (or columns) of target zones (e.g., less than a row of nozzles turned to 90 degrees would be required so that all nozzles in the row can be used in each scan for each affected target zone and drops deposited in multiple passes for each row of target zones, one row at a time). For each scan, the printhead may be moved and each nozzle waveform data may be programmed into the nozzles to implement droplet deposition instructions according to a bitmap or layout file; these functions are denoted differently in fig. 14C by numerals 1477, 1479, and 1481. After each scan, the process is repeated for subsequent scans, via numeral 1483.

It is again noted that a number of different embodiments have been described above, which are optional with respect to each other. First, in one embodiment, the drive waveform is not changed, but is held constant for each nozzle. Drop volume combinations are created by covering different nozzles with different rows of target areas using variable geometric steps representing printhead/substrate offsets, as needed. Using the measured per nozzle drop volumes, this process allows a combination of specific drop volumes to achieve very specific fill volumes (e.g., up to 0.01pL resolution) per target zone. This process can be programmed so that multiple nozzles are used to deposit ink in different rows of target areas with each pass. In one embodiment, the printing solution is optimized to produce the fewest scans possible and the fastest printing times possible. Second, in another embodiment, a specific measured drop volume may again be used with a different drive waveform for each nozzle. The printing process controls these waveforms so that specific drop volumes are polymerized in specific combinations. Again, using the measured drop volumes per nozzle, this process allows for the combination of specific drop volumes to achieve very specific fill per target zoneFill volume (e.g., to 0.01pL resolution). This process can be programmed so that multiple nozzles are used to deposit ink in different rows of target areas with each pass. In both embodiments, a single row of nozzles may be used or multiple rows of nozzles may be used, arranged as one or more printheads; for example, in one contemplated embodiment, thirty print heads may be used, each having a single row of nozzles, each row having 256 nozzles. The print heads may also be organized into various groups; for example, the printheads may be organized into groups of five printheads that are mechanically mounted together, and the resulting six groups may be individually mounted into the printing system at the same time, providing simultaneous firing of nozzles from all printheads in a single scan. In another embodiment, a polymeric printhead is used having multiple rows of nozzles that may be further positionally offset from one another. This embodiment is similar to the first embodiment described above in that different drop volumes can be combined using variable effective positional offsets or geometric steps. Again, using the measured per nozzle drop volumes, this process allows the combination of specific drop volumes to achieve very specific fill volumes per target zone (e.g., up to 0.05pL, or even 0.01pL resolution). This does not necessarily mean that the measurement results have no statistical uncertainty, such as measurement error; in one embodiment, such errors are small and are taken into account in the target area fill plan. For example, if the drop volume measurement error is ± a%, the fill volume variation across the target area can be planned to be within the tolerance range of the target fill± (b-an ^1/2 )%The inner part of the inner part is provided with a plurality of grooves,± (b ² )%indicates a specification tolerance range, and± (n ^1/2 )represents the square root of the average number of droplets per target area or well. Unless otherwise noted, a range less than specification may be planned such that when the expected measurement error is taken into account, the resulting aggregate fill volume for the target zone may be expected to fall within the specification tolerance range. Naturally, the techniques described herein may optionally be combined with other statistical processes.

Drop deposition can optionally be planned such that multiple nozzles are used to deposit ink in different rows of target areas with each pass, optionally optimizing the printing solution to produce the fewest scans possible and fastest printing times possible. Any combination of these techniques with each other and/or with other techniques may also be employed, as previously described. For example, in one specifically contemplated scenario, variable geometric steps are used with each nozzle drive waveform variation and each nozzle, each drive waveform volume measurement to achieve a very specific volume combination for each target zone plan. For example, in one specifically contemplated scenario, fixed geometric steps are used with each nozzle drive waveform variation and each nozzle, each drive waveform volume measurement to achieve a very specific volume combination for each target zone plan.

These embodiments ensure a high quality display by maximizing the number of nozzles that can be used simultaneously during each scan and by planning the drop volume combinations such that they definitely meet specifications; by also reducing printing time, these embodiments help facilitate ultra-low cost per unit of printing, and thus lower price points to the end consumer.

As also described above, the use of a precise fill volume per target zone enables the use of advanced techniques that vary the fill volume according to defined criteria (within specification) so as to avoid line-like patterns. This provides a further quality improvement over conventional methods.

In the foregoing description and drawings, specific terms and drawing symbols are set forth to provide a thorough understanding of the disclosed embodiments. In some instances, terms and symbols may imply specific details that are not required to implement those embodiments. The terms "exemplary" and "embodiment" are used to mean an example and not a preference or requirement.

As indicated, various modifications and changes may be made to the embodiments set forth herein without departing from the broader spirit and scope of the disclosure. For example, features or aspects of any embodiment may be applied, at least where practicable, in combination with any other embodiment or in place of their equivalent features or aspects. Thus, for example, not all features are shown in each figure, and features or techniques shown in accordance with an embodiment of one figure, for example, should be assumed to be optionally usable as elements or combinations of features of any other figure or embodiment, even if not specifically stated in this specification. The specification and drawings are, accordingly, to be regarded in an illustrative rather than a restrictive sense.

Claims (29)

1. A method of manufacturing an electronic device, the method comprising:

ejecting droplets of a liquid onto a substrate using nozzles of a printhead;

selecting at least one electronic drive waveform for each nozzle from a waveform selection, wherein each waveform selection has been previously associated with a particular desired drop volume of the liquid when the waveform selection is applied to drive the respective nozzle; and

treating the liquid to form a layer after deposition onto a substrate;

wherein the selecting is performed so as to bring together drop volumes of a specific desired drop volume to obtain a specific accumulated desired volume for each target area of a substrate in which the liquid is to be deposited,

the specific desired volume of accumulation is limited to be within a predetermined volume tolerance for each target region, an

The use is performed to transport the print head relative to the substrate in one or more movements, and in so doing, a volume of liquid is deposited for each target area in accordance with the drops from the one or more nozzles corresponding to a particular accumulated desired volume for the target area, on the basis that at least some of the drops are ejected in a particular one of the movements into respective ones of the target areas along a spatial dimension independent of the direction of scanning movement between the print head and the substrate.

2. The method of claim 1, wherein the electronic device is a display device, wherein each target region is a pixel well, the pixel wells being for forming respective display cells of the display device.

3. The method of claim 2, wherein the display device is an organic light emitting display device, and wherein the layers are used to form layers of each respective display unit of a post-fabrication of a light emitting display device of the organic light emitting display device.

4. The method of claim 3, wherein the layer is a color filter layer.

5. The method of claim 3, wherein the layer is a layer for generating light.

6. The method of claim 1, wherein the layer is an organic sealing layer, wherein each target area comprises a unit area of the substrate, and wherein using the nozzle comprises simultaneously depositing droplets into respective unit areas of the substrate aligned along the spatial dimension in a manner such that the deposited liquid is continuous between the respective unit areas.

7. The method of claim 1, wherein the particular accumulated desired volume for at least one target region comprises a volume of droplets produced from a common nozzle according to a respective selection of waveform selections for the common nozzle, and wherein selecting comprises waveform selecting at least two electronic drive waveforms for the common nozzle from the waveform selections for the common nozzle.

8. The method of claim 1, wherein using a nozzle comprises: depositing, for the common target area, droplets from respective ones of the nozzles in respective iterations of the one or more motions distinguished by printhead offsets in a spatial dimension independent of a direction of the one or more motions to form an accumulated desired volume for the common target area.

9. The method of claim 1, wherein using the nozzle comprises printing within a controlled atmosphere, wherein treating comprises curing the deposited liquid with radiation to form the layer also within the controlled atmosphere, and wherein printing and curing is performed in a manner such that the deposited liquid is not exposed to an uncontrolled atmosphere prior to curing.

10. The method of claim 9, wherein the radiation is ultraviolet radiation.

11. The method of claim 1, wherein the liquid comprises an organic monomer, and wherein treating comprises converting the organic monomer to a polymer to form the layer.

12. The method of claim 1, wherein selecting at least one electronic drive waveform for each nozzle comprises programming a digital value into an electronic drive circuit for each nozzle, the digital value being used to define the electronic drive waveform relative to the waveform selection for the respective nozzle, and wherein using comprises providing electronic trigger signals to the electronic drive circuits for a plurality of the nozzles to responsively and simultaneously eject droplets for a plurality of the nozzles in accordance with the digital value programmed into the electronic drive circuit for each respective one of the plurality of nozzles.

13. The method of claim 1, wherein selecting at least one electronic drive waveform for each nozzle comprises programming a set of at least two parameters into an electronic drive circuit for each nozzle, each selected electronic drive waveform having a waveform shape defined according to the set of at least two parameters.

14. The method of claim 1, wherein the predetermined volume tolerance range for each target region is within a range of positive two percent of the accumulated volume and negative two percent of the accumulated volume.

15. An apparatus for manufacturing an electronic device, the apparatus comprising:

means for ejecting droplets of a liquid onto a substrate using nozzles of a printhead;

means for selecting at least one electronic drive waveform for each nozzle from a selection of waveforms, wherein each waveform selection has been previously associated with a particular desired drop volume of liquid when the waveform selection is applied to drive the respective nozzle; and

means for treating the liquid to form a layer after deposition onto a substrate;

wherein the means for selecting accumulates drop volumes together in a particular desired drop volume to obtain a particular accumulated desired volume for each target area of a substrate in which the liquid is to be deposited,

the specific desired volume of accumulation is limited to be within a predetermined volume tolerance for each target region, an

The means for using will transport the print head relative to the substrate in one or more movements and in so doing deposit a volume of liquid for each target area in accordance with the drops from the one or more nozzles corresponding to a particular accumulated desired volume for the target area on the basis that at least some of the drops are ejected in a particular one of the movements into respective ones of the target areas along a spatial dimension independent of the direction of scanning movement between the print head and the substrate.

16. An apparatus for manufacturing an electronic device, the apparatus comprising:

a printhead having nozzles to eject droplets of a liquid onto a substrate;

at least one processor for selecting at least one electronic drive waveform for each nozzle from a selection of waveforms, wherein each waveform selection has been previously associated with a particular desired drop volume of liquid when the waveform selection is applied to drive the respective nozzle; and

a processing mechanism for processing the liquid to form a layer after deposition onto a substrate;

wherein the at least one processor is to select the at least one electronic drive waveform to accumulate drop volumes together in a particular desired drop volume to obtain a particular accumulated desired volume for each target area of a substrate in which liquid is to be deposited,

the specific accumulated desired volume is limited to be within a predetermined volume tolerance range for each target region; and

the apparatus is for transporting the print head relative to the substrate in one or more movements and, in so doing, causing the print head to deposit a volume of liquid for each target area in accordance with the drops from the one or more nozzles corresponding to a particular accumulated desired volume for the target area on the basis that at least some of the drops are ejected in a particular one of the movements into respective ones of the target areas along a spatial dimension independent of the direction of scanning movement between the print head and the substrate.

17. The apparatus of claim 16, wherein the electronic device is a display device, wherein each target region is a pixel well, the pixel wells being configured to form a respective display cell of the display device.

18. The apparatus of claim 17, wherein the display device is an organic light emitting display device, and wherein the layer is for a layer of each respective display cell that forms a post-fabrication of a light emitting display device of the organic light emitting display device.

19. The device of claim 18, wherein the layer is a color filter layer.

20. The apparatus of claim 18, wherein the layer is a layer for generating light.

21. The apparatus of claim 16, wherein the layer is an organic sealing layer, wherein each target area comprises a unit area of the substrate, and wherein the apparatus causes the print head to simultaneously deposit droplets into the respective unit areas of the substrate aligned along the spatial dimension in a manner such that the deposited liquid is continuous between the respective unit areas.

22. The apparatus of claim 16, wherein the specific accumulation desired volume for at least one target region comprises a volume of droplets produced from a common nozzle according to a respective one of the waveform selections for the common nozzle, and the at least one processor is configured to select at least two electronic drive waveforms for the common nozzle from the waveform selections for the common nozzle.

23. The apparatus of claim 16, wherein the apparatus is to cause the print head to deposit, for a common target area, droplets from respective ones of the nozzles in respective iterations of the one or more movements that are distinguished by print head offsets in a spatial dimension that is independent of a direction of the one or more movements to form an accumulated desired volume for the common target area.

24. The apparatus of claim 16, wherein the apparatus comprises a housing for a controlled atmosphere, wherein the apparatus is for causing the printhead to perform printing within the controlled atmosphere, wherein the processing mechanism comprises a radiation source for curing the deposited liquid with radiation to form the layer also within the controlled atmosphere, and wherein the apparatus is to perform printing and curing in a manner that does not expose the deposited liquid to an uncontrolled atmosphere prior to curing.

25. The device of claim 24, wherein the radiation is ultraviolet radiation.

26. The device of claim 16, wherein the liquid comprises an organic monomer, and wherein the processing mechanism converts the organic monomer to a polymer to form the layer.

27. The apparatus of claim 16, wherein the at least one processor is configured to program digital values into the electronic drive circuitry for each nozzle, the digital values defining the electronic drive waveforms relative to the waveform selection for the corresponding nozzle, and wherein the apparatus is configured to provide electronic trigger signals to the electronic drive circuitry for a plurality of the nozzles to responsively and simultaneously eject drops for the plurality of ones of the nozzles in accordance with the digital values programmed into the electronic drive circuitry for each corresponding one of the plurality of nozzles.

28. The apparatus of claim 16, wherein the at least one processor is configured to program a set of at least two parameters into the electronic drive circuit for each nozzle, each selected electronic drive waveform having a waveform shape defined according to the set of at least two parameters.

29. The apparatus of claim 16, wherein the predetermined volume tolerance range for each target region is within a range of plus two percent of the accumulated volume and minus two percent of the accumulated volume.

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