CN108097453A - The method that magnetic iron ore is removed from iron concentrate containing high sulphur - Google Patents

The method that magnetic iron ore is removed from iron concentrate containing high sulphur Download PDF

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CN108097453A
CN108097453A CN201810147521.8A CN201810147521A CN108097453A CN 108097453 A CN108097453 A CN 108097453A CN 201810147521 A CN201810147521 A CN 201810147521A CN 108097453 A CN108097453 A CN 108097453A
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iron ore
magnetic iron
concentrate
ore
magnetic
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CN108097453B (en
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云伟
云文杰
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Inner Mongolia Fubao High-tech Development Co., Ltd.
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Baotou City Hui Lin Xinbao Mining LLC
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03BSEPARATING SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS
    • B03B7/00Combinations of wet processes or apparatus with other processes or apparatus, e.g. for dressing ores or garbage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D1/00Flotation
    • B03D1/001Flotation agents
    • B03D1/002Inorganic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00Specified effects produced by the flotation agents
    • B03D2201/007Modifying reagents for adjusting pH or conductivity
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2201/00Specified effects produced by the flotation agents
    • B03D2201/02Collectors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B03SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03DFLOTATION; DIFFERENTIAL SEDIMENTATION
    • B03D2203/00Specified materials treated by the flotation agents; Specified applications
    • B03D2203/02Ores

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The present invention relates to a kind of methods that magnetic iron ore is removed from iron concentrate containing high sulphur, belong to mineral engineering field.The higher quality to iron ore concentrate of sulfur content of iron concentrate containing high sulphur, which causes, to be seriously affected.Magnetic iron ore is oxidizable, easy argillization, and degree of oxidation is deep mixed, causes to be difficult that the sulphur in iron ore concentrate is down to less than 0.3%, and the rate of recovery loss of iron ore concentrate is larger.The present invention, can be by most of magnetic iron ore monomer dissociation and overground generation argillization by using appropriate ore grinding.The mixture of efficient, easy aluminum sulfate or aluminum sulfate and sodium phosphate, ammonium fluosilicate is used as the pH regulators and activator of magnetic iron ore, and the selective and preferable collecting agent of collecting performance, magnetic iron ore mineral surfaces are activated well, and the state-of-charge of the mineral surfaces in ore pulp is controlled well, efficiently separating for magnetic iron ore and magnetic iron ore is realized, obtains the fine quality iron concentrate of high-grade and high-recovery and magnetic iron ore rough concentrate.

Description

The method that magnetic iron ore is removed from iron concentrate containing high sulphur
Technical field
The invention belongs to mineral engineering fields, and in particular to a kind of side that magnetic iron ore is removed from iron concentrate containing high sulphur Method.
Background technology
Iron concentrate containing high sulphur sulfur content is higher, generally more than 2%, the quality of iron ore concentrate is caused and is seriously affected.Iron essence Containing sulfur minerals present in ore deposit not only pollute air in sintering process, but also in order to ensure that desulfurization effect must be added to more Lime, so as to cause quantity of slag increase, coke ratio rise, in addition the sulphur in steel can be also easy to produce " hot-short " in steel hot-working.Only Having reduces the sulfur content of iron ore concentrate, could eliminate influence of the sulphur to subsequent job, could improve the grade of iron ore concentrate.In iron ore concentrate Containing sulfur minerals be generally magnetic iron ore, magnetic iron ore is easier to aoxidize than other sulfide minerals, under oxygen and water effect, Magnetic iron ore Quick Oxidation, oxidation rate are 20 times~100 times of pyrite.Additionally, due to magnetic iron ore crystal structure difference Caused composition and electronic structure difference can influence magnetic iron ore oxidation to degree, micro- presence and content is how many, ring Border temperature can all have an impact the oxidation of magnetic iron ore and oxidation rate.Therefore, magnetic iron ore is in floatation process, due to it Oxidizable, argillization, and degree of oxidation is deep mixed, belongs to the mineral of more difficult removing.Magnetic iron ore is removed in iron ore concentrate Method is generally floatation, relatively more to the Oxidized copper ores of removing magnetic iron ore progress at present, mainly to flotation activating, suppression The research of preparation and collecting agent.The activator of research includes sulfuric acid, copper sulphate, hydrochloric acid, oxalic acid, ammonium nitrate, ammonium sulfate, fluosilicic acid Sodium, vulcanized sodium etc.;Inhibitor includes lime, sulfurous acid, sodium humate, sodium sulphate, dimethyldithiocarbamate, cyaniding Object etc.;Collecting agent includes ethyl xanthogenate, butyl xanthate, diethyldithiocarbamate, isoamyl xanthate, butyl ammonium aerofloat, sulfydryl sodium benzothiazole etc..These are floating The magnetic iron ore separating effect for selecting medicament deeper to iron concentrate containing high sulphur, especially degree of oxidation is bad, it is difficult to will be in iron ore concentrate Sulphur is down to less than 0.3%, and the rate of recovery loss of iron ore concentrate is more, below 88%.
The content of the invention
The object of the present invention is to provide a kind of methods that magnetic iron ore is removed from iron concentrate containing high sulphur, and this method is by iron ore concentrate In sulphur be down to less than 0.3%, and the rate of recovery of iron ore concentrate reaches more than 90%, reduces pollution of the sulphur to air.
The purpose of the present invention is realized as follows.
1st, the processing of raw material;
Iron concentrate containing high sulphur is subjected to ore grinding, -200 mesh is milled to and accounts for 70-85%, then concentrate ore milling product, is concentrated It is 35-45% to pulp density;
2nd, the activation of magnetic iron ore;
Using the ore pulp that above-mentioned steps obtain as the raw material of flotation magnetic iron ore, using aluminum sulfate or mass ratio 1-2:3-1: 2-1 sodium phosphates, the mixture of ammonium fluosilicate and aluminum sulfate or mass ratio 3-1:The mixture or matter of 1-2 aluminum sulfate and ammonium fluosilicate Amount compares 1-2:PH regulator and activator of the mixture of 3-2 aluminum sulfate and sodium phosphate as magnetic iron ore, pH regulators and work Agent dosage is 1.5-4.5kg/t iron concentrate containing high sulphurs, and 3-8min, adjustment pH value 4.5-5.5 are stirred under natural temperature;
3rd, magnetic iron ore roughing;
Using the raw material that above-mentioned steps obtain as roughing flotation raw material, mass ratio 3-2 is added in the raw material:2-1:1- The collecting agent of 0.5 amylic sodium xanthogenate, sodium ethylxanthate and fourth Sodium Aerofloat as magnetic iron ore, in collector dosage 0.2- 1-5min is stirred under the conditions of 0.8kg/t iron concentrate containing high sulphurs, natural temperature, roughing is carried out and sorts magnetic iron ore, obtain sulfur grade 17- 25%th, the magnetic iron ore rougher concentration of rate of recovery 80-86% and sulfur grade are less than 0.55% sand setting (iron ore concentrate), sand setting conduct Scan the raw material of recycling magnetic iron ore;
4th, magnetic iron ore is scanned;
The sand setting that above-mentioned steps are obtained scans raw material as flotation, with mass ratio 3-2:2-1:1-0.5 amyl xanthic acid The collecting agent of sodium, sodium ethylxanthate and fourth Sodium Aerofloat as magnetic iron ore, collector dosage 0.05-0.15kg/t high-sulfurs iron essence Ore deposit stirs 1-3min under the conditions of natural temperature, is then scanned under natural ph, obtains sulfur grade 8-15%, recycling Scavenger concentrate and sulfur grade 0.1-0.3%, the full Iron grade of rate 6-11% is more than the 67%, iron ore concentrate of rate of recovery 90-95%;
5th, the rougher concentration and scavenger concentrate obtained above-mentioned steps is incorporated as further selecting the raw material of sulphur.
Compared with prior art, the technology of the present invention effect includes:
This technology is first using appropriate ore grinding, by most of magnetic iron ore monomer dissociation, and cannot overground generation argillization, On the one hand ore grinding cost is saved, while obtains the Suitable base of removing magnetic iron ore;Using efficient activator and pH tune It whole dose, is well activated magnetic iron ore mineral surfaces, and controls the charged shape of the mineral surfaces in ore pulp well State;Using the combined capturing and collecting agent with preferable selectivity and collecting performance, can the magnetic iron ore different to degree of oxidation catch simultaneously It receives, obtains the fine quality iron concentrate of high-grade and high-recovery and magnetic iron ore rough concentrate, realize magnetic iron ore and magnetic iron ore Efficiently separate, solve the separation problem of iron concentrate containing high sulphur and magnetic iron ore.
The present invention, i.e., will using efficient pharmaceutical agent combinations using a kind of method that magnetic iron ore is removed from iron concentrate containing high sulphur Magnetic iron ore is removed from iron ore concentrate, and the sulphur in iron ore concentrate is made to be down to less than 0.3%, and ensures that the rate of recovery of iron ore concentrate exists More than 90%, the sulfur content of iron ore concentrate is not only reduced, eliminates influence of the sulphur to subsequent job, reduces dirt of the sulphur to air Dye, and the loss of iron ore concentrate is reduced, iron ore concentrate is become into fine quality iron concentrate.
Description of the drawings
Fig. 1 is the process flow chart for the method for removing magnetic iron ore in the present invention from iron concentrate containing high sulphur.
Specific embodiment
It is described below and specific embodiments of the present invention is fully shown, to enable those skilled in the art to put into practice it .
Embodiment 1
A kind of method that magnetic iron ore is removed from iron concentrate containing high sulphur, mainly including following components:
1st, the processing of raw material;
Full Iron grade 67.30%, the iron concentrate containing high sulphur containing sulfur grade 2.02% are subjected to ore grinding, -200 mesh is milled to and accounts for 82.1%, then ore milling product is concentrated, is concentrated into ore pulp mass concentration as 40%.
2nd, the activation of magnetic iron ore;
Using the ore pulp that above-mentioned steps obtain as the raw material of flotation magnetic iron ore, using pH of the aluminum sulfate as magnetic iron ore Regulator and activator, pH regulators and activator level are 2.2kg/t, and 5min is stirred under natural temperature, and adjustment pH value is 5。
3rd, magnetic iron ore roughing;
Using the raw material that above-mentioned steps obtain as roughing flotation raw material, mass ratio 2.5 is added in the raw material:1.5:0.6 The collecting agent of amylic sodium xanthogenate, sodium ethylxanthate and fourth Sodium Aerofloat as magnetic iron ore, collector dosage 0.4kg/t, It stirs 2min under the conditions of natural temperature, carries out roughing and sort magnetic iron ore, obtain sulfur grade 22.35%, the rate of recovery 85.43% Magnetic iron ore rougher concentration and the sand setting of sulfur grade 0.32% (iron ore concentrate), the raw material that sand setting is scanned as magnetic iron ore.
4th, magnetic iron ore is scanned;
The sand setting that above-mentioned steps are obtained scans raw material as flotation, with mass ratio 2.5:1.5:0.6 amylic sodium xanthogenate, The collecting agent of sodium ethylxanthate and fourth Sodium Aerofloat as magnetic iron ore, collector dosage 0.08kg/t, in natural temperature condition Lower stirring 2min, is then scanned under natural ph, obtain sulfur grade 9.28%, the rate of recovery 6.46% scavenger concentrate and Sulfur grade 0.18%, full Iron grade 68.40%, the iron ore concentrate of the rate of recovery 92.27%.
5th, the rougher concentration and scavenger concentrate obtained above-mentioned steps is incorporated as further selecting the raw material of sulphur.
Embodiment 2
A kind of method that magnetic iron ore is removed from iron concentrate containing high sulphur, mainly including following components:
1st, the processing of raw material;
Full Iron grade 67.40%, the iron concentrate containing high sulphur containing sulfur grade 3.01% are subjected to ore grinding, -200 mesh is milled to and accounts for 75.5%, then ore milling product is concentrated, is concentrated into pulp density as 38.5%.
2nd, the activation of magnetic iron ore;
Using the ore pulp that above-mentioned steps obtain as the raw material of flotation magnetic iron ore, using pH of the aluminum sulfate as magnetic iron ore Regulator and activator, pH regulators and activator level are 4kg/t, and 6min is stirred under natural temperature, and adjustment pH value is 4.6。
3rd, magnetic iron ore roughing;
Using the raw material that above-mentioned steps obtain as roughing flotation raw material, mass ratio 3 is added in the raw material:1:0.8 amyl The collecting agent of sodium xanthogenate, sodium ethylxanthate and fourth Sodium Aerofloat as magnetic iron ore, in collector dosage 0.60kg/t, nature 5min is stirred under temperature conditionss, roughing is carried out and sorts magnetic iron ore, it is yellow to obtain sulfur grade 24.18%, the magnetic of the rate of recovery 83.12% Iron ore rougher concentration and the sand setting of sulfur grade 0.52% (iron ore concentrate), the raw material that sand setting is scanned as magnetic iron ore.
4th, magnetic iron ore is scanned;
The sand setting that above-mentioned steps are obtained scans raw material as flotation, with mass ratio 3:1:0.8 amylic sodium xanthogenate, ethyl The collecting agent of sodium xanthogenate and fourth Sodium Aerofloat as magnetic iron ore, collector dosage 0.16kg/t are stirred under the conditions of natural temperature 5min is mixed, is then scanned under natural ph, obtains sulfur grade 14.55%, the scavenger concentrate and sulphur of the rate of recovery 7.61% Grade 0.29%, full Iron grade 68.60%, the iron ore concentrate of the rate of recovery 90.30%.
5th, the rougher concentration and scavenger concentrate obtained above-mentioned steps is incorporated as further selecting the raw material of sulphur.
Embodiment 3
A kind of method that magnetic iron ore is removed from iron concentrate containing high sulphur, mainly including following components:
1st, the processing of raw material;
Full Iron grade 66.70%, the iron concentrate containing high sulphur containing sulfur grade 1.41% are subjected to ore grinding, -200 mesh is milled to and accounts for 76.5%, then ore milling product is concentrated, is concentrated into pulp density as 41.1%.
2nd, the activation of magnetic iron ore;
Using the ore pulp that above-mentioned steps obtain as the raw material of flotation magnetic iron ore, using mass ratio 1:1 sodium phosphate and sulfuric acid PH regulator and activator of the mixture of aluminium as magnetic iron ore, pH regulators and activator level are 2.0kg/t, in nature At a temperature of stir 5min, adjustment pH value is 5.1.
3rd, magnetic iron ore roughing;
Using the raw material that above-mentioned steps obtain as roughing flotation raw material, mass ratio 2 is added in the raw material:2:0.5 amyl The collecting agent of sodium xanthogenate, sodium ethylxanthate and fourth Sodium Aerofloat as magnetic iron ore, in collector dosage 0.30kg/t, nature 5min is stirred under temperature conditionss, roughing is carried out and sorts magnetic iron ore, it is yellow to obtain sulfur grade 20.93%, the magnetic of the rate of recovery 82.79% Iron ore rougher concentration and the sand setting of sulfur grade 0.26% (iron ore concentrate), the raw material that sand setting is scanned as magnetic iron ore.
4th, magnetic iron ore is scanned;
The sand setting that above-mentioned steps are obtained scans raw material as flotation, with mass ratio 2:2:0.5 amylic sodium xanthogenate, ethyl The collecting agent of sodium xanthogenate and fourth Sodium Aerofloat as magnetic iron ore, collector dosage 0.08kg/t are stirred under the conditions of natural temperature 2min is mixed, is then scanned under natural ph, obtains sulfur grade 8.67%, the scavenger concentrate of the rate of recovery 7.95% and sulphur product Position 0.14%, full Iron grade 67.50%, the iron ore concentrate of the rate of recovery 94.12%.
5th, the rougher concentration and scavenger concentrate obtained above-mentioned steps is incorporated as further selecting the raw material of sulphur.
Embodiment 4
A kind of method that magnetic iron ore is removed from iron concentrate containing high sulphur, mainly including following components:
1st, the processing of raw material;
Full Iron grade 66.50%, the iron concentrate containing high sulphur containing sulfur grade 2.51% are subjected to ore grinding, -200 mesh is milled to and accounts for 78.6%, then ore milling product is concentrated, is concentrated into pulp density as 38.8%.
2nd, the activation of magnetic iron ore;
Using the ore pulp that above-mentioned steps obtain as the raw material of flotation magnetic iron ore, using mass ratio 2:1.5 ammonium fluosilicates and PH regulator and activator of the mixture of aluminum sulfate as magnetic iron ore, pH regulators and activator level are 2.8kg/t, 5min is stirred under natural temperature, adjustment pH value is 4.9.
3rd, magnetic iron ore roughing;
Using the raw material that above-mentioned steps obtain as roughing flotation raw material, mass ratio 3 is added in the raw material:2:0.8 amyl The collecting agent of sodium xanthogenate, sodium ethylxanthate and fourth Sodium Aerofloat as magnetic iron ore, in collector dosage 0.45kg/t, nature 6min is stirred under temperature conditionss, roughing is carried out and sorts magnetic iron ore, it is yellow to obtain sulfur grade 24.51%, the magnetic of the rate of recovery 81.43% Iron ore rougher concentration and the sand setting of sulfur grade 0.50% (iron ore concentrate), the raw material that sand setting is scanned as magnetic iron ore.
4th, magnetic iron ore is scanned;
The sand setting that above-mentioned steps are obtained scans raw material as flotation, with mass ratio 3:2:0.8 amylic sodium xanthogenate, ethyl The collecting agent of sodium xanthogenate and fourth Sodium Aerofloat as magnetic iron ore, collector dosage 0.12kg/t are stirred under the conditions of natural temperature 3min is mixed, is then scanned under natural ph, obtains sulfur grade 13.16%, the scavenger concentrate and sulphur of the rate of recovery 10.33% Grade 0.23%, full Iron grade 67.60%, the iron ore concentrate of the rate of recovery 91.11%.
5th, the rougher concentration and scavenger concentrate obtained above-mentioned steps is incorporated as further selecting the raw material of sulphur.
Embodiment 5
A kind of method that magnetic iron ore is removed from iron concentrate containing high sulphur, mainly including following components:
1st, the processing of raw material;
Full Iron grade 67.40%, the iron concentrate containing high sulphur containing sulfur grade 3.01% are subjected to ore grinding, -200 mesh is milled to and accounts for 75.5%, then ore milling product is concentrated, is concentrated into pulp density as 38.5%.
2nd, the activation of magnetic iron ore;
Using the ore pulp that above-mentioned steps obtain as the raw material of flotation magnetic iron ore, using mass ratio 1:3:2 sodium phosphates, fluorine silicon PH regulator and activator of the mixture of sour ammonium and aluminum sulfate as magnetic iron ore, pH regulators and activator level are 3.4kg/t, stirs 6min under natural temperature, and adjustment pH value is 4.7.
3rd, magnetic iron ore roughing;
Using the raw material that above-mentioned steps obtain as roughing flotation raw material, mass ratio 3 is added in the raw material:1:0.8 amyl The collecting agent of sodium xanthogenate, sodium ethylxanthate and fourth Sodium Aerofloat as magnetic iron ore, in collector dosage 0.60kg/t, nature 5min is stirred under temperature conditionss, roughing is carried out and sorts magnetic iron ore, it is yellow to obtain sulfur grade 24.98%, the magnetic of the rate of recovery 83.80% Iron ore rougher concentration and the sand setting of sulfur grade 0.54% (iron ore concentrate), the raw material that sand setting is scanned as magnetic iron ore.
4th, magnetic iron ore is scanned;
The sand setting that above-mentioned steps are obtained scans raw material as flotation, with mass ratio 3:1:0.8 amylic sodium xanthogenate, ethyl The collecting agent of sodium xanthogenate and fourth Sodium Aerofloat as magnetic iron ore, collector dosage 0.14kg/t are stirred under the conditions of natural temperature 5min is mixed, is then scanned under natural ph, obtains sulfur grade 14.85%, the scavenger concentrate and sulphur of the rate of recovery 7.31% Grade 0.30%, full Iron grade 68.60%, the iron ore concentrate of the rate of recovery 90.10%.
5th, the rougher concentration and scavenger concentrate obtained above-mentioned steps is incorporated as further selecting the raw material of sulphur.
It should be appreciated that the invention is not limited in the flow and structure that are described above and are shown in the drawings, And various modifications and changes may be made without departing from the scope thereof.The scope of the present invention is only limited by appended claim System.

Claims (4)

  1. A kind of 1. method that magnetic iron ore is removed from iron concentrate containing high sulphur, which is characterized in that use efficient activator and pH tune Whole dose, magnetic iron ore mineral surfaces are activated, and control the state-of-charge of the mineral surfaces in ore pulp;Using with preferable The combined capturing and collecting agent of selectivity and collecting performance, the magnetic iron ore different to degree of oxidation collecting simultaneously, obtains high-grade and height The magnetic iron ore rougher concentration of the rate of recovery:
    1) activation of magnetic iron ore:Using efficient activator and pH regulators, activation magnetic iron ore mineral surfaces step is as follows:
    Iron concentrate containing high sulphur is subjected to ore grinding, -200 mesh is milled to and accounts for 70-85%, then ore milling product is concentrated, is concentrated into ore deposit Slurry mass concentration is 35-45%;Then pH regulator and activator of the aluminum sulfate as magnetic iron ore, pH regulators and work are used Agent dosage is 1.5-4.5kg/t iron concentrate containing high sulphurs, and 3-8min, adjustment pH value 4.5-5.5 are stirred under natural temperature;
    2) collecting of magnetic iron ore:Using the combined capturing and collecting agent with preferable selectivity and collecting performance, magnetic iron ore step is removed It is as follows:
    A. magnetic iron ore roughing
    Ore pulp after the activation that above-mentioned steps are obtained adds in mass ratio 3-2 as roughing flotation raw material in the raw material:2-1: The collecting agent of 1-0.5 amylic sodium xanthogenates, sodium ethylxanthate and fourth Sodium Aerofloat as magnetic iron ore, in collector dosage 0.2- 1-5min is stirred under 0.8kg/t iron concentrate containing high sulphurs, natural temperature, roughing is carried out and sorts magnetic iron ore, obtain magnetic iron ore roughing Concentrate and iron ore concentrate sand setting;
    B. the raw material that iron ore concentrate sand setting is scanned as magnetic iron ore;
    C. magnetic iron ore is scanned
    Raw material is scanned using iron ore concentrate sand setting as flotation, with mass ratio 3-2:2-1:1-0.5 amylic sodium xanthogenate, ethoxy-dithioformic acid The collecting agent of sodium and fourth Sodium Aerofloat as magnetic iron ore, collector dosage 0.05-0.15kg/t iron concentrate containing high sulphurs, in natural temperature Lower stirring 1-3min, is then scanned under natural ph, obtains scavenger concentrate and iron ore concentrate;
    D. iron ore concentrate is I classes of C67 or II class standard;
    E. magnetic iron ore rougher concentration and scavenger concentrate are incorporated as further selecting the raw material of sulphur.
  2. 2. the method for magnetic iron ore is removed from iron concentrate containing high sulphur according to claim 1, which is characterized in that using mass ratio 1-2:3-1:PH regulator and activator of the mixture of 2-1 sodium phosphates, ammonium fluosilicate and aluminum sulfate as magnetic iron ore.
  3. 3. the method for magnetic iron ore is removed from iron concentrate containing high sulphur according to claim 1, which is characterized in that using mass ratio 3-1:PH regulator and activator of the mixture of 1-2 aluminum sulfate and ammonium fluosilicate as magnetic iron ore.
  4. 4. the method for magnetic iron ore is removed from iron concentrate containing high sulphur according to claim 1, which is characterized in that using mass ratio 1-2:PH regulator and activator of the mixture of 3-2 aluminum sulfate and sodium phosphate as magnetic iron ore.
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109261368A (en) * 2018-08-13 2019-01-25 昆明理工大学 A kind of inhibitor and application method for magnetic iron ore
CN109604070A (en) * 2018-12-05 2019-04-12 遵义市博莱金矿业有限责任公司 A kind of high-sulfur magnetic iron ore ore dressing medicament and its application method
CN109701736A (en) * 2019-02-27 2019-05-03 铜陵化工集团新桥矿业有限公司 Complex ore ore-dressing technique containing magnetic iron ore and magnetic iron ore
CN110560269A (en) * 2019-09-06 2019-12-13 中钢集团马鞍山矿山研究院有限公司 Beneficiation method for gradient recycling of high-sulfur magnetite concentrate
CN110898987A (en) * 2019-11-13 2020-03-24 鞍钢集团矿业有限公司 Oxidation desulfurization method of high-sulfur magnetite concentrate
CN111495601A (en) * 2020-04-20 2020-08-07 武汉理工大学 Combined collecting agent and method for removing pyrite and pyrrhotite from high-sulfur iron concentrate
CN114609000A (en) * 2022-05-11 2022-06-10 矿冶科技集团有限公司 Judgment method for reducing magnetic effectiveness of pyrrhotite and application

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2342277A (en) * 1943-02-02 1944-02-22 American Cyanamid Co Separation of pyrite, arsenopyrite, and pyrrhotite by flotation
JP2010088991A (en) * 2008-10-07 2010-04-22 Waseda Univ Water treatment agent and water treatment method
CN103316775A (en) * 2013-05-21 2013-09-25 内蒙古科技大学 High-sulfur magnetite concentrate efficient activated flotation desulfuration method
CN104069937A (en) * 2014-05-16 2014-10-01 马钢集团设计研究院有限责任公司 Ore dressing method for removing pyrrhotite from iron ore
CN104353557A (en) * 2014-10-09 2015-02-18 昆明冶金研究院 Method for reducing sulphur content in iron ore concentrate through flotation process
CN104689913A (en) * 2015-02-27 2015-06-10 铜陵化工集团新桥矿业有限公司 Pyrite mixed recycling method for polycrystal system
CN106076647A (en) * 2016-06-20 2016-11-09 武汉理工大学 Utilize the method for magnetic iron ore in combination medicament activation and flotation iron ore concentrate
CN107243409A (en) * 2017-07-27 2017-10-13 中钢集团马鞍山矿山研究院有限公司 A kind of high-sulfur magnetic iron ore puies forward the beneficiation method of iron sulfur reduction

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2342277A (en) * 1943-02-02 1944-02-22 American Cyanamid Co Separation of pyrite, arsenopyrite, and pyrrhotite by flotation
JP2010088991A (en) * 2008-10-07 2010-04-22 Waseda Univ Water treatment agent and water treatment method
CN103316775A (en) * 2013-05-21 2013-09-25 内蒙古科技大学 High-sulfur magnetite concentrate efficient activated flotation desulfuration method
CN104069937A (en) * 2014-05-16 2014-10-01 马钢集团设计研究院有限责任公司 Ore dressing method for removing pyrrhotite from iron ore
CN104353557A (en) * 2014-10-09 2015-02-18 昆明冶金研究院 Method for reducing sulphur content in iron ore concentrate through flotation process
CN104689913A (en) * 2015-02-27 2015-06-10 铜陵化工集团新桥矿业有限公司 Pyrite mixed recycling method for polycrystal system
CN106076647A (en) * 2016-06-20 2016-11-09 武汉理工大学 Utilize the method for magnetic iron ore in combination medicament activation and flotation iron ore concentrate
CN107243409A (en) * 2017-07-27 2017-10-13 中钢集团马鞍山矿山研究院有限公司 A kind of high-sulfur magnetic iron ore puies forward the beneficiation method of iron sulfur reduction

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
于传兵 等: "铜硫分离尾矿中黄铁矿活化的研究", 《有色金属工业科技创新——中国有色金属学会第七届学术年会论文集》 *
杨云 等: "磁黄铁矿活化剂及机理研究现状", 《矿冶工程》 *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109261368A (en) * 2018-08-13 2019-01-25 昆明理工大学 A kind of inhibitor and application method for magnetic iron ore
CN109604070A (en) * 2018-12-05 2019-04-12 遵义市博莱金矿业有限责任公司 A kind of high-sulfur magnetic iron ore ore dressing medicament and its application method
CN109701736A (en) * 2019-02-27 2019-05-03 铜陵化工集团新桥矿业有限公司 Complex ore ore-dressing technique containing magnetic iron ore and magnetic iron ore
CN110560269A (en) * 2019-09-06 2019-12-13 中钢集团马鞍山矿山研究院有限公司 Beneficiation method for gradient recycling of high-sulfur magnetite concentrate
CN110898987A (en) * 2019-11-13 2020-03-24 鞍钢集团矿业有限公司 Oxidation desulfurization method of high-sulfur magnetite concentrate
CN111495601A (en) * 2020-04-20 2020-08-07 武汉理工大学 Combined collecting agent and method for removing pyrite and pyrrhotite from high-sulfur iron concentrate
CN114609000A (en) * 2022-05-11 2022-06-10 矿冶科技集团有限公司 Judgment method for reducing magnetic effectiveness of pyrrhotite and application

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