CN1080972A - Ink jet dyeing method - Google Patents
Ink jet dyeing method Download PDFInfo
- Publication number
- CN1080972A CN1080972A CN 93105460 CN93105460A CN1080972A CN 1080972 A CN1080972 A CN 1080972A CN 93105460 CN93105460 CN 93105460 CN 93105460 A CN93105460 A CN 93105460A CN 1080972 A CN1080972 A CN 1080972A
- Authority
- CN
- China
- Prior art keywords
- cloth
- ink
- ink jet
- diffusion
- dyestuff
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coloring (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
In a kind of ink jet dyeing method, before with the ink ejecting method dyed cloth, the high-absorbable high polymer is applied over the cloth of fiber.Consequently by before dyeing, preventing that preferably dye ink from spreading on cloth as long as a small amount of anti-diffusion agent is applied over cloth.Because this a spot of anti-diffusion agent, can keep the quality of cloth and excellent water resistance is provided, this even anti-diffusion agent that is applied over cloth not can by as processing such as washing and removing.
Description
The present invention relates to a kind of ink jet dyeing method, this method by ink-jet can clearly dye various patterns and on the non-weaving cloth of woven product, knitwear or various fibers effectively dyeing.
As Japanese patent application No. clear 54-18957(open) in disclose a kind of by ink jet dyeing method as described in the paper printing technological improvement, this method by ink-jet can be effectively on the surface of woven product, knitwear or nonwoven fabric the various patterns of dyeing.Among ink ejecting method various are improved one's methods and study in the dyeing field.
For example, carried out the test that prevents that dyestuff from spreading on the cloth surface, this is the most valued in the cloth ink jet dyeing.Reduce the dye diffusion on cloth surface though can increase the viscosity of dying China ink, thereby printing ink can block in nozzle and makes the processing of nozzle become complicated, also is difficult to reach simultaneously quiet run.
Thereby another test is the diffusion that prevents to dye China ink by the solvent on the printing ink on flash evaporation cloth surface.Yet in this case, cloth must be heated to high temperature before dyeing, can go bad and causes product rotten thereby its result not only is easy to damage cloth but also dyestuff.
Perhaps, disclose a kind of method that prevents to dye the China ink diffusion in as the clear 63-31594 of Japan Patent open piece of writing application number, this method is can be applied to the cloth surface with dyestuff adhesion and the anti-diffusion agent that keeps with a kind of earlier before dyeing.Especially in preparation process, at least a compound that is selected from water soluble polymer, water soluble salt and the combination of water-soluble inorganic micromolecule is attached to the cloth surface with the 1-50% ratio, these compounds can not be with the dyestuff adhesions on substantially but can be kept dyestuff, ink-jet method is coated and is dyed China ink then, and heating is fixed and the water flush away compound again.
Disclosed colouring method in the clear 63-31594 of Japan Patent open piece of writing application number is not because it causes that nozzle blockage and product go bad, so be effective.But the not mentioned any anti-diffusion agent method of utilizing of this method keeps mechanism attached to the cloth surface with dyestuff, and undeniablely is, uses the method for identical dyestuff to compare with other, and this method can reduce the consumption degree.And, being heated to fixing back by flush away owing to keep the anti-diffusion agent of dyestuff at dyestuff, dyestuff also can be removed in washing process, and this will further reduce the adhesion performance of dyestuff.
Purpose of the present invention just provides a kind of ink jet dyeing method that dye diffusion and cloth quality are rotten and have the high flow rate degree of exempting, and therefrom can also expect to be colored second effect of product.
According to the present invention, a kind of ink jet dyeing method that utilizes ink-jet to come the coloured fibre cloth is provided, wherein before ink-jet, earlier a high-hydroscopicity high polymer is applied to cloth.
Below describe the present invention in detail by its operation format.
The ink ejecting method that the present invention uses is not subjected to the restriction of particular form.Typical traditional form is for example as the electrostatic attraction method, and this method is to place a highfield between the accelerating electrode of nozzle and nozzle front portion, and according to a cue, ink particles sprays from nozzle; Supersonic oscillations method, this method are according to a cue printing ink of using under high pressure to be sprayed from nozzle with the fine particle form under the vibration of crystal oscillator; With the piezoelectric element method, thereby this method is to give signal of telecommunication of piezoelectric element to impel printing ink to spray from nozzle to exert pressure to printing ink.
As for printing ink, can use known dyestuff such as direct dyes, ACID DYES, chrome dye, REACTIVE DYES, DISPERSE DYES or cation dyes, the dye ink can be by various additives are added in dyestuff and the liquid and prepare as anti-agent such as glyceryl, dye solvent, property adjustments agent, bactericide, disinfectant and the chelating agent etc. done according to the kind of fabric fibre.
If according to ink ejecting method but only use the above-mentioned dye ink that makes that pattern is printed to fiber cloth, dyestuff will spread very seriously, and the product that obtains will become substandard products.But in the present invention, the quality that postpones dye diffusion (being at least after dyestuff is attached to cloth) and do not damage cloth has been possible.
The anti-diffusion agent of Shi Yonging is a kind of water insoluble but can absorb the high polymer of volume moisture, promptly a kind of high polymer that is called " super absorbent resin " in the present invention.What this super absorbent resin was given an example has vinyl acrylate, sodium acrylate copolymer, dextrin-graft polymerization of acrylic ester thing vulcanized latex and vulcanizes polyacrylate.As pulsation, dipping or spraying anti-diffusion agent is applied over cloth by suitable method.
The insoluble high polymer of individual other high suction has the moisture content of heavy ten to thousands of times of instantaneous absorptance gels itself.Therefore,, absorb and keep dye ink with regard to the available insoluble high polymer that should height absorbs water is temporary transient if the insoluble high polymer that earlier height absorbed water is applied over cloth, even and if the insoluble high polymer of a small amount of high suction also can get a desired effect.When dyestuff was fixed, by the water evaporates of the temporary transient absorption of the insoluble high polymer of high suction, the dyestuff that is kept by same compound combined and sprawls quality with fiber, and compound also can be attached to the cloth surface and be fixed simultaneously.
Because it is fewer that the height that adheres to and be fixed in the cloth surface absorbs the amount of high polymer, so the cloth quality can not be damaged.As additional good result, the compound that is present in the cloth surface can not make raindrop infiltrate into the back side from the front.
In a word, after color is sprawled, finish dyeing with drying steps.In drying steps, be fixed on the cloth surface and and can not remove, and be retained in interfibrous space equally to obtain favorable waterproof property from cloth as the height absorption high polymer of anti-diffusion agent.
Describe the present invention in detail by embodiment.
Embodiment 1, comparative example 1 and 2
Prepare three kinds of aqueous solution, contain the rice stuck glue SP510(Sumika Gel. embodiment of Soviet Union 1 of every liter 10 gram respectively, colloidal solution; Vinyl acrylate copolymer by Sumitomo Chemical Co.Ltd. production), Arabic gum (comparative example 1) and montmorillonite (comparative example 2).The cloth that the yarn processing that will be made by polyester fiber be made into impregnated in above-mentioned three kinds of solution and with mat extruding 60%, and cloth was in 100 ℃ of dryings 10 minutes then.The cloth that obtains dyes under following condition.
(1) preparation of ink-jet dispersion liquid:
With 10%(weight) the Dianix Black FG-P(DISPERSE DYES of producing by Mitsubishi Chemical-Hechist Co.Ltd.), 15%(weight) polyethylene glycol (mean molecule quantity: 400), 15%(weight) glycerine and 60%(weight) ion exchange water is mixed together, at room temperature use a fine grinder such as sand milling or paint regulator with this mixture pulverize, produce the largest hole diameter by Iwaki Glass Co.Ltd. with glass filter 11P5VF(: about 1.0 μ m) filter.
(2) ink jet printing condition:
Ink ejecting method kind: requirement
Nozzle diameter: 60 μ m
Dot density: 180 point/inches (vertical, level)
Distance between nozzle and cloth: 1mm
(3) dyeing condition:
The cloth that processing is printed with the reduction washing, with after washing, neutralization, washing, carries out drying more at last also under the following conditions to sprawl color.
Color is sprawled: 200 ℃ of heat dryings 3 minutes.
The reduction washing: under 90 ℃, dipping is 20 minutes in bath, and this bath contains bisulfites and the NaOH that 0.5g/ rises and 1.0g/ rises respectively.
Neutralization: flooded 10 minutes at acetate liquation (0.1g/ liter) at 60 ℃.
(4) result:
Table 1
Diffusion L value
Embodiment 1 does not have 22.64
The comparative example 1 slight 22.93
The comparative example 2 slight 23.07
Diffusion: judge with bore hole.
L value: with the cloth surface brightness value of colorimeter mensuration; Color is dark more, and the L value is more little.
Colorimeter: by the COLOR EYE MS-2020 of Macbeth Corp production.
Table 1 has shown and has occurred in the present invention spreading that then occurred diffusion in the comparative example, L value in the present invention is less than the comparative example simultaneously.
Embodiment 2, comparative example 3 and 4
Prepare three kinds of aqueous solution, dextrin-acrylate graft copolymers vulcanized latex that the Sanwet IM1000MPS(embodiment 2 that contains 10 grams per liters respectively, Sanyo Chemical Co.Ltd. produce), Arabic gum (comparative example 3) and montmorillonite (comparative example 4).To process that woven cloth (cloth that the viscose rayon yarn is made into) impregnated in above-mentioned three kinds of solution and with mat extruding 60% by the yarn that cellulose fibre makes, cloth was in 100 ℃ of dryings 10 minutes then.The cloth that obtains dyes under following condition.
(1) preparation of REACTIVE DYES printing ink:
With 10%(weight) C.I. reactive black 5 (REACTIVE DYES), 15%(weight) polyethylene glycol (mean molecule quantity: 400), 15%(weight) glycerine and 60%(weight) ion exchange water is mixed together, at room temperature stir, and produce the largest hole diameter by Iwaki Co.Ltd. with glass filter 11P5VF(: about 1.0 μ m) filter.
(2) ink jet printing condition
Ink ejecting method kind: requirement
Nozzle diameter: 60 μ m
Dot density: 180 point/inches (vertical, level)
Distance between nozzle and cloth: 1mm
(3) dyeing condition:
Processing is printed cloth, be exposed to 100 ℃ saturated vapour 15 minutes, and then wash with water, with acetic acid solution (0.1g/ liter) neutralization and with 90 ℃ of hot washes 10 minutes, wash with water at last, drying is finished the color process of sprawling again.
(4) result
Table 2
Diffusion L value
Embodiment 2 does not have 34.73
The comparative example 1 slight 35.29
The comparative example 2 slight 34.80
Table 2 also demonstrates the effect that prevents the ink-jet diffusion in the present invention and is better than the comparative example.
Can find out significantly from the description of front,, before dyeing, cloth be used a small amount of anti-diffusion agent earlier and just can prevent the diffusion of dye ink on cloth preferably according to the present invention.In addition, because this a spot of anti-diffusion agent can keep the quality of cloth and excellent water resistance can be provided, this even anti-diffusion agent that is applied over cloth can be because of not removing as processing such as washings.
Claims (2)
1, a kind of ink jet dyeing method that utilizes the cloth of ink jet dyeing fiber is characterized in that before ink-jet a kind of high-hydroscopicity high polymer being applied over cloth.
2, ink jet dyeing method as claimed in claim 1 is characterized in that described high-hydroscopicity high polymer is made up of vinyl acrylate, sodium acrylate copolymer, dextrin-acrylate graft copolymers vulcanized latex or the polyacrylate that vulcanized.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP115647/92 | 1992-05-08 | ||
| JP4115647A JPH05311583A (en) | 1992-05-08 | 1992-05-08 | Method for ink jet dyeing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1080972A true CN1080972A (en) | 1994-01-19 |
Family
ID=14667820
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93105460 Pending CN1080972A (en) | 1992-05-08 | 1993-05-03 | Ink jet dyeing method |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0568955A1 (en) |
| JP (1) | JPH05311583A (en) |
| KR (1) | KR960004639B1 (en) |
| CN (1) | CN1080972A (en) |
| BR (1) | BR9301064A (en) |
| CA (1) | CA2094100A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102433699A (en) * | 2011-08-30 | 2012-05-02 | 吴江市福辉纺织有限公司 | Dyeing method for spraying and coloring cloth |
| CN105421109A (en) * | 2014-09-17 | 2016-03-23 | 株式会社御牧工程 | Textile printing ink, and printing method using same |
| CN115745665A (en) * | 2022-12-12 | 2023-03-07 | 佛山欧神诺陶瓷有限公司 | Ink-jet printing baking-free decorative light ceramic plate and preparation method thereof |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5867197A (en) * | 1994-07-21 | 1999-02-02 | Canon Kabushiki Kaisha | Ink-jet printing cloth, ink-jet printing process and production process of print |
| JP3265136B2 (en) * | 1994-09-14 | 2002-03-11 | 三洋化成工業株式会社 | Interior base material and printing method |
| WO2000003081A1 (en) * | 1998-07-08 | 2000-01-20 | Ciba Specialty Chemicals Holding Inc. | Method for printing fibrous textile materials using the ink jet technique |
| JP2001146689A (en) * | 1999-11-16 | 2001-05-29 | Murakami:Kk | Printing substrate based on flexible woven fabric, printed body using the same and method for printing the printing substrate made of flexible woven fabric |
| DE60120846T2 (en) * | 2000-07-26 | 2007-01-11 | Seiren Co. Ltd. | Process for producing a fabric for inkjet printing |
-
1992
- 1992-05-08 JP JP4115647A patent/JPH05311583A/en active Pending
-
1993
- 1993-04-15 CA CA 2094100 patent/CA2094100A1/en not_active Abandoned
- 1993-05-03 CN CN 93105460 patent/CN1080972A/en active Pending
- 1993-05-03 EP EP93107158A patent/EP0568955A1/en not_active Withdrawn
- 1993-05-07 KR KR1019930007836A patent/KR960004639B1/en not_active IP Right Cessation
- 1993-05-10 BR BR9301064A patent/BR9301064A/en not_active Application Discontinuation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102433699A (en) * | 2011-08-30 | 2012-05-02 | 吴江市福辉纺织有限公司 | Dyeing method for spraying and coloring cloth |
| CN105421109A (en) * | 2014-09-17 | 2016-03-23 | 株式会社御牧工程 | Textile printing ink, and printing method using same |
| CN115745665A (en) * | 2022-12-12 | 2023-03-07 | 佛山欧神诺陶瓷有限公司 | Ink-jet printing baking-free decorative light ceramic plate and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| KR960004639B1 (en) | 1996-04-11 |
| EP0568955A1 (en) | 1993-11-10 |
| CA2094100A1 (en) | 1993-11-09 |
| BR9301064A (en) | 1993-11-16 |
| JPH05311583A (en) | 1993-11-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |