CN108096987A - A kind of molecular sieve adsorber secondary absorption air separator of oxygenerator and recovery method - Google Patents

A kind of molecular sieve adsorber secondary absorption air separator of oxygenerator and recovery method Download PDF

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Publication number
CN108096987A
CN108096987A CN201810088523.4A CN201810088523A CN108096987A CN 108096987 A CN108096987 A CN 108096987A CN 201810088523 A CN201810088523 A CN 201810088523A CN 108096987 A CN108096987 A CN 108096987A
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China
Prior art keywords
class absorber
absorber
molecular sieve
pipeline
class
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CN201810088523.4A
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Chinese (zh)
Inventor
王海斌
黄冬冬
郎晓锋
王子煜
董开封
李运涛
李波
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LUOYANG TIANBAO ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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LUOYANG TIANBAO ENVIRONMENTAL PROTECTION TECHNOLOGY Co Ltd
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Priority to CN201810088523.4A priority Critical patent/CN108096987A/en
Publication of CN108096987A publication Critical patent/CN108096987A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/3416Regenerating or reactivating of sorbents or filter aids comprising free carbon, e.g. activated carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/34Regenerating or reactivating
    • B01J20/345Regenerating or reactivating using a particular desorbing compound or mixture
    • B01J20/3458Regenerating or reactivating using a particular desorbing compound or mixture in the gas phase
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/40083Regeneration of adsorbents in processes other than pressure or temperature swing adsorption
    • B01D2259/40088Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating
    • B01D2259/4009Regeneration of adsorbents in processes other than pressure or temperature swing adsorption by heating using hot gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/40Further details for adsorption processes and devices
    • B01D2259/402Further details for adsorption processes and devices using two beds

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Treating Waste Gases (AREA)

Abstract

A kind of molecular sieve adsorber secondary absorption air separator of oxygenerator and recovery method, device be by:First class absorber, admission line, discharge duct, second class absorber, condenser, molecular sieve adsorber, wind turbine, heater and holding vessel are formed;Mouth sets admission line under first class absorber, first class absorber setting discharge duct suitable for reading, first class absorber one side sets second class absorber, second class absorber one side sets condenser, holding vessel, molecular sieve adsorber, wind turbine, heater respectively, and first class absorber, the suitable for reading of second class absorber set pipeline between condenser inlet respectively;Its recovery method includes level-one desorption and two level desorption.The present invention makes solvent desorbing that can remove the moisture in recycling design in the process using the two level desorption retracting device of molecular sieve adsorber, improves solvent recovering rate, reduces reclaimer investment and solvent recovery cost.This is simple in structure, and manufacture is at low cost, environmentally protective, alleviates the financial burden of enterprise.

Description

A kind of molecular sieve adsorber secondary absorption air separator of oxygenerator and recovery method
Technical field
The present invention relates to organic exhaust gas recycling field, especially a kind of molecular sieve adsorber secondary absorption organic exhaust gas recycling Device and recovery method.
Background technology
In VOCs treatment field, adsorption recovery is a kind of main and effective administering method, and adsorption recovery is to utilize After the organic volatile absorption in exhaust gas is discharged by adsorbent by enterprise, then the method by condensing recycling changes organic volatile For liquid, recycling is directly used in;The moisture adsorbed in above-mentioned removal process, in activated carbon in organic gas also can be with Organic matter condenses out, and about 6% ~ 10% waste water can be isolated in the stoste of recycling, and 3% organic solvent can be dissolved in waste water, gives up Water is difficult processing;In addition, can also dissolve 3% or so water in the stoste of recycling, need first to carry out at dehydration before solvent rectifying separation Reason;Second class absorber is in the condition of high temperature always in existing reclaimer, and at high operating temperatures, the ethyl acetate in organic matter Hydrolysis can occur with water, solvent dehydration can be influenced by generating ethyl alcohol and acetic acid, ethyl alcohol;It is required in combination process in solvent not Allow have ethyl alcohol;Water and acid are two key indexes that solvent strictly controls, the boiling point height of acetic acid, in rectifying column depickling just need Finished product substance is wanted all to steam, consumes big energy, rectification and purification cost is significantly increased, therefore, it is necessary to a kind of new recycling System is big to solve the problem of the energy expenditure of high cost of rectifying existing for existing recovery system.
The content of the invention
The present invention proposes a kind of molecular sieve adsorber secondary absorption air separator of oxygenerator and recovery method, for solving The problem of rectifying existing for certainly existing recovery system is of high cost, and energy expenditure is big.
The purpose of the present invention adopts the following technical scheme that realize:
A kind of molecular sieve adsorber secondary absorption air separator of oxygenerator, be by:First class absorber, admission line, exhaust pipe Road, second class absorber, condenser, molecular sieve adsorber, wind turbine, heater, holding vessel are formed;Under first class absorber mouth set into Feed channel, first class absorber setting discharge duct suitable for reading, first class absorber one side set second class absorber, second class absorber one side Condenser, holding vessel, molecular sieve adsorber, wind turbine, heater, first class absorber, suitable for reading point of second class absorber are set respectively Pipeline is not set between condenser inlet, first class absorber, second class absorber lower mouth respectively with the air outlet of heater it Between pipeline is set, pipeline is set under second class absorber between mouth and fan inlet, the outlet of condenser and the import of holding vessel it Between pipeline is set, setting pipeline between parsing the import of wind turbine, outlet and the molecular sieve of condenser adsorb for the outlet of condenser Pipeline between the import of device is set, pipeline, heater are set between the outlet of molecular sieve adsorber and the suitable for reading of second class absorber Import and wind turbine outlet between pipeline is set;It is all provided in the admission line, discharge duct and each component connecting pipe It is equipped with valve.
The first class absorber and second class absorber is the tank shape absorber of activated carbon effect sorbing material.
The molecular sieve adsorber is to be internally provided with 3A molecular sieves.
The wind turbine is enclosed circulation wind turbine.
A kind of molecular sieve adsorber secondary absorption method for organic waste gas recovery:It includes level-one desorption and two level is desorbed two Step:
Level-one is desorbed:VOC gas, which enter from admission line in first class absorber 1, to be adsorbed, and pure air is discharged from discharge duct, Level-one desorption is carried out after 1 adsorption saturation of first class absorber:After first class absorber saturation, close on admission line and discharge duct Valve, and close the valve between condenser and wind turbine, open the valve of other pipelines, open wind turbine and be sent into inert gas Heating, the gas after heating are entered from the lower mouth of first class absorber in first class absorber by pipeline in heater, heat gas The activated carbon for being adsorbed with organic solvent is heated, the VOC gas containing water is parsed, parses the VOC gas containing water and pass through The first class absorber pipeline suitable for reading between condenser inlet enters in condenser, within the condenser the high temperature VOC containing water Gas is down to room temperature, and a part of VOC gas containing water enter holding vessel by pipeline, and another part contains the VOC gas of water Entered by pipeline in molecular sieve adsorber, the 3A molecular sieves for Water Molecular Adsorption, molecular sieve are housed in molecular sieve adsorber Absorber carries out adsorption filtration to the water in the VOC gas containing water, and water-free VOC gas are gone out by molecular sieve adsorber Mouthful and second class absorber it is suitable for reading between pipeline enter secondary absorption carried out in second class absorber, in second class absorber after absorption Gas enter wind turbine, move in circles by more than operating procedure, make first class absorber be desorbed to standard requirement after, stop level-one taking off It is attached;
Two level is desorbed:The valve of pipeline above and below first class absorber is closed, the valve on admission line and discharge duct is opened, makes one Grade absorber carries out normal adsorption operation, then carries out two level desorption to second class absorber:Close molecular sieve adsorber and two level Valve between absorber top on pipeline between valve and second class absorber lower part and wind turbine, inert gas is sent by wind turbine to be added Hot wind is sent into through pipeline in second class absorber by heating in hot device, heater 6, and the liquid VOC in second class absorber is evaporated vapour VOC gas are turned to, VOC gas enter along pipeline is down to room temperature in condenser, the liquid VOC after cooling enters holding vessel, room temperature VOC gas enter wind turbine, move in circles by more than operating procedure, and second class absorber is made to be desorbed to standard requirement, stops desorption; Complete entire two level desorption and removal process.
Technical solution proposed by the present invention has reached good effect:Using molecular sieve adsorber, make solvent desorbing process In can remove moisture in recycling design, reduce dehydration in solvent post processing, separating technology, improve solvent recovering rate, Reduce reclaimer investment and solvent recovery cost.This is simple in structure, easy to operate, manufacture is at low cost, using effect is preferable, Environmentally protective, the post processing of whole solvent and cycling and reutilization play the role of good after being desorbed to second class absorber, greatly The energy has been saved, has reduced production cost, has alleviated the financial burden of enterprise.
Description of the drawings
Fig. 1 is schematic structural view of the invention.
In figure:1st, first class absorber, 1-1, admission line, 1-2, discharge duct, 2, second class absorber, 3, condenser, 4th, molecular sieve adsorber, 5, wind turbine, 6, heater, 7, holding vessel, 8, valve.
Specific embodiment
With reference to the drawings and specific embodiments, the present invention will be further described:
A kind of molecular sieve adsorber secondary absorption organic waste gas recycling system as shown in Figure 1, be by:First class absorber 1, air inlet Pipeline 1-1, discharge duct 1-2, second class absorber 2, condenser 3, molecular sieve adsorber 4, wind turbine 5, heater 6,7 structure of holding vessel Into;It is characterized in that:1 time mouth of first class absorber sets admission line 1-1, the setting discharge duct 1-2 suitable for reading of first class absorber 1, 1 one side of first class absorber sets second class absorber 2, and 2 one side of second class absorber sets condenser 3, holding vessel 7, molecular sieve respectively Absorber 4, wind turbine 5, heater 6, first class absorber 1, the suitable for reading of second class absorber 2 are set between 3 import of condenser respectively Pipeline, first class absorber 1, the lower mouth of second class absorber 2 set pipeline, secondary absorption between the air outlet of heater 6 respectively Pipeline is set between 2 times mouths of device and parsing 5 import of wind turbine, pipeline is set between the outlet of condenser 3 and the import of holding vessel 7, Pipeline is set between the outlet of condenser 3 and the import of wind turbine 5, between the outlet of condenser 3 and the import of molecular sieve adsorber 4 Pipeline is set, pipeline, the import of heater 6 and solution are set between the outlet of molecular sieve adsorber 4 and the suitable for reading of second class absorber 2 Pipeline is set between the outlet of analysis wind turbine 5, is all provided in the admission line 1-1, discharge duct 1-2 and each component connecting pipe It is equipped with valve 8;The first class absorber 1 and second class absorber 2 is the tank shape absorber of activated carbon effect sorbing material;Institute The molecular sieve adsorber 4 stated is the Water Molecular Adsorption device for being internally provided with 3A molecular sieves;The wind turbine 5 is enclosed circulation Wind turbine.
During a kind of molecular sieve adsorber secondary absorption organic waste gas recycling system normal use, VOC gas are from admission line 1-1, which enters in first class absorber 1, to be adsorbed, and pure air is discharged from discharge duct 1-2, after 1 adsorption saturation of first class absorber Carry out level-one desorption:After 1 saturation of first class absorber, the valve 8 on admission line 1-1 and discharge duct 1-2 is closed, and is closed cold Valve 8 between condenser and wind turbine opens the valve 8 of other pipelines, and opening wind turbine 5 will add in inert gas feeding heater 6 Heat, the gas after heating are entered from the lower mouth of first class absorber 1 in first class absorber 1 by pipeline, and heat gas is to being adsorbed with The activated carbon heating of organic solvent, parses the VOC gas containing water, parses the VOC gas containing water and pass through primary adsorption Pipeline between 3 import suitable for reading with condenser of device 1 enters in condenser 3, the high temperature VOC gas containing water in condenser 3 Room temperature is down to, a part of VOC gas containing water enter holding vessel 7 by pipeline, and the VOC gas that another part contains water pass through Pipeline enters in molecular sieve adsorber 4, and the 3A molecular sieves for Water Molecular Adsorption are housed in molecular sieve adsorber 4, and molecular sieve is inhaled Adnexa 4 carries out adsorption filtration to the water in the VOC gas containing water, and water-free VOC gas are gone out by molecular sieve adsorber 4 Mouthful and second class absorber 2 it is suitable for reading between pipeline enter secondary absorption carried out in second class absorber 2, inhaled in second class absorber 2 Attached gas enters wind turbine 5, moves in circles by more than operating procedure, and first class absorber 1 is made to be desorbed to standard requirement, is stopped Level-one is desorbed;
After completing level-one desorption, the valve 8 of first class absorber pipeline about 1 is closed, opens admission line 1-1 and discharge duct 1- Valve 8 on 2 makes first class absorber 1 carry out normal adsorption operation, then carries out two level desorption to second class absorber 2:It closes and divides Valve 8 between 2 top of son sieve absorber 4 and second class absorber on pipeline between valve and 2 lower part of second class absorber and wind turbine, Inert gas is sent into heating in heater 6 by wind turbine 5, and hot wind is sent into through pipeline in second class absorber 2 by heater 6, by two level Liquid VOC carburation by evaporations in absorber 2 are VOC gas, and VOC gas, which enter along pipeline in condenser 3, is down to room temperature, after cooling Liquid VOC enter holding vessel 7, room temperature VOC gas enter wind turbine 5, move in circles by more than operating procedure, make second class absorber After 2 desorptions to standard requirement, stop desorption;Complete entire two level desorption and removal process.
Part not in the detailed description of the invention is the prior art.

Claims (5)

1. a kind of molecular sieve adsorber secondary absorption air separator of oxygenerator, it is characterized in that:By first class absorber, air inlet pipe Road, discharge duct, second class absorber, condenser, molecular sieve adsorber, wind turbine, heater, holding vessel are formed;First class absorber Lower mouth sets admission line, first class absorber setting discharge duct suitable for reading, and first class absorber one side sets second class absorber, two level Absorber one side sets condenser, holding vessel, molecular sieve adsorber, wind turbine, heater, first class absorber, secondary absorption respectively The suitable for reading of device sets pipeline between condenser inlet respectively, first class absorber, second class absorber lower mouth respectively with heater Air outlet between pipeline is set, pipeline, the outlet and storage of condenser are set under second class absorber between mouth and fan inlet Pipeline is set between the import of tank, the outlet of condenser setting pipeline between parsing the import of wind turbine, the outlet of condenser with Pipeline between the import of molecular sieve adsorber is set, pipe is set between the outlet of molecular sieve adsorber and the suitable for reading of second class absorber Road sets pipeline between the import of heater and the outlet of wind turbine;Admission line, discharge duct and each component connecting tube Valve is both provided on road.
2. a kind of molecular sieve adsorber secondary absorption organic waste gas recycling system according to claim 1, it is characterized in that:Institute The first class absorber and second class absorber stated are the tank shape absorber of activated carbon effect sorbing material.
3. a kind of two level desorption recovery system equipped with molecular sieve adsorber according to claim 1, it is characterized in that:It is described Molecular sieve adsorber to be internally provided with 3A molecular sieves.
4. a kind of molecular sieve adsorber secondary absorption organic waste gas recycling system according to claim 1, it is characterized in that:Institute The wind turbine stated is enclosed circulation wind turbine.
5. a kind of molecular sieve adsorber secondary absorption method for organic waste gas recovery as described in claims 1 or 2 or 3 or 4, It is characterized in:It includes level-one desorption and two level is desorbed two steps:
Level-one is desorbed:VOC gas, which enter from admission line in first class absorber, to be adsorbed, and pure air is discharged from discharge duct, Level-one desorption is carried out after first class absorber adsorption saturation:After first class absorber saturation, close on admission line and discharge duct Valve, and close the valve between condenser and wind turbine, open the valve of other pipelines, open wind turbine and be sent into inert gas Heating, the gas after heating are entered from the lower mouth of first class absorber in first class absorber by pipeline in heater, heat gas The activated carbon for being adsorbed with organic solvent is heated, the VOC gas containing water is parsed, parses the VOC gas containing water and pass through The first class absorber pipeline suitable for reading between condenser inlet enters in condenser, within the condenser the high temperature VOC containing water Gas is down to room temperature, and a part of VOC gas containing water enter holding vessel by pipeline, and another part contains the VOC gas of water Entered by pipeline in molecular sieve adsorber, the 3A molecular sieves for Water Molecular Adsorption, molecular sieve are housed in molecular sieve adsorber Absorber carries out adsorption filtration to the water in the VOC gas containing water, and water-free VOC gas are gone out by molecular sieve adsorber Mouthful and second class absorber it is suitable for reading between pipeline enter secondary absorption carried out in second class absorber, in second class absorber after absorption Gas enter wind turbine, move in circles by more than operating procedure, make first class absorber be desorbed to standard requirement after, stop level-one taking off It is attached;
Two level is desorbed:The valve of pipeline above and below first class absorber is closed, the valve on admission line and discharge duct is opened, makes one Grade absorber carries out normal adsorption operation, then carries out two level desorption to second class absorber:Close molecular sieve adsorber and two level Valve between absorber top on pipeline between valve and second class absorber lower part and wind turbine, inert gas is sent by wind turbine to be added Heating in hot device, hot wind is sent into through pipeline in second class absorber by heater, by the liquid VOC carburation by evaporations in second class absorber For VOC gas, VOC gas enter along pipeline is down to room temperature in condenser, the liquid VOC after cooling enters holding vessel, room temperature VOC Gas enters wind turbine, moves in circles by more than operating procedure, and second class absorber is made to be desorbed to standard requirement, stops desorption;It is complete Into entire two level desorption and removal process.
CN201810088523.4A 2018-01-30 2018-01-30 A kind of molecular sieve adsorber secondary absorption air separator of oxygenerator and recovery method Pending CN108096987A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108918717A (en) * 2018-07-25 2018-11-30 上海兰宝环保科技有限公司 A kind of performance of the adsorbent test device
CN110548364A (en) * 2019-10-17 2019-12-10 清远先导材料有限公司 method and device for recovering special gas adsorbed by molecular sieve
CN113521963A (en) * 2021-08-12 2021-10-22 伯乐氛(北京)环境技术有限公司 Industrial organic waste gas treatment method
CN114768469A (en) * 2022-05-23 2022-07-22 北人伯乐氛(西安)环境技术有限公司 Organic waste gas solvent recovery process

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CN206444409U (en) * 2017-01-24 2017-08-29 杭州大伟装饰材料有限公司 Organic solvent is recycled nitrogen desorption retracting device
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CN101318717A (en) * 2008-05-15 2008-12-10 复旦大学 Method and apparatus for removing and recycling organic phase in wastewater with distillation-free complete-molecular sieve
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108918717A (en) * 2018-07-25 2018-11-30 上海兰宝环保科技有限公司 A kind of performance of the adsorbent test device
CN110548364A (en) * 2019-10-17 2019-12-10 清远先导材料有限公司 method and device for recovering special gas adsorbed by molecular sieve
CN113521963A (en) * 2021-08-12 2021-10-22 伯乐氛(北京)环境技术有限公司 Industrial organic waste gas treatment method
CN114768469A (en) * 2022-05-23 2022-07-22 北人伯乐氛(西安)环境技术有限公司 Organic waste gas solvent recovery process
CN114768469B (en) * 2022-05-23 2024-04-12 北人伯乐氛(西安)环境技术有限公司 Organic waste gas solvent recovery process

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Application publication date: 20180601