CN108084778A - High solvent-proof optical fiber coloring ink composite and preparation method thereof - Google Patents
High solvent-proof optical fiber coloring ink composite and preparation method thereof Download PDFInfo
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- CN108084778A CN108084778A CN201711479089.4A CN201711479089A CN108084778A CN 108084778 A CN108084778 A CN 108084778A CN 201711479089 A CN201711479089 A CN 201711479089A CN 108084778 A CN108084778 A CN 108084778A
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- optical fiber
- coloring ink
- fiber coloring
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- ink composite
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/108—Hydrocarbon resins
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Optical Fibers, Optical Fiber Cores, And Optical Fiber Bundles (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention provides a kind of high solvent-proof optical fiber coloring ink composites；The composition includes each component of following parts by weight：10~30 parts of urethane acrylate, 15~25 parts of epoxy acrylate, 5~30 parts of monomer, 1~10 part of mill base, 5~9 parts of photoinitiator, 2~10 parts of wax powder, 0.1~1 part of levelling agent, 0.1~1 part of antifoaming agent.The urethane acrylate is the aliphatic urethane acrylate resin of low degree of functionality (2~4 official)；The epoxy acrylate is bisphenol A-type；The mill base is outsourcing mill base (being purchased from BASF) particle size range D50 between 200~500nm.The curing rate of optical fiber coloring ink of the present invention is fast, and solidification effect is good, using its coloring after optical fiber bright do not fade, surface smooth touch it is good, solvent resistant number reaches 200 times.
Description
Technical field
The invention belongs to optical fiber coloring ink areas, and in particular to a kind of high solvent-proof optical fiber coloring ink composite and
Its preparation method.
Background technology
Optical fiber coloring ink is used exclusively for a kind of ultraviolet radioactive light-curable ink of optical fiber coloring, and main function is system
Making colored optical fiber makes optical fiber be prepared to still can effectively distinguish after optical cable.High performance optical fiber coloring ink is to light
Fine performance such as intensity, reliability, stability, attenuation, micro-bend without influence.Ink coated in outside of fiber can also play
To the iris action of environment, particularly to the iris action of dust and water clearly, optical fiber is made so as to reduce environmental activity
With the influence of performance.
Traditional optical fiber coloring speed makes ink that must have what is be exceedingly fast to consolidate in 500~2400m/min, the coating of such high speed
Change speed and quick levelability.The optical fiber that has coloured need resistance to butanone wipe do not fade for 100 times, this is to the curing degree of ink and resistance to
Solvent borne has strict requirements.The optical fiber coloured can be invaded bubble for a long time when being prepared into optical cable by fiber paste, so ink and fibre
The compatibility experiments of cream just seem extremely important.The optical fiber that major optical cable factory requirement has coloured at present impregnates 1 in 85 DEG C of fiber pastes
Month dyed layer is without obscission, this has the ageing-resistant performance of dyed layer strict requirements, and common UV ink completely can not
Meet the requirement of optical fiber coloring ink.
The content of the invention
It is an object of the invention to provide a kind of high solvent-proof optical fiber coloring ink to reach high solvent resistance
Composition.
The present invention is achieved by the following technical solutions：
In a first aspect, the present invention provides a kind of high solvent-proof optical fiber coloring ink composite, including by weight
The following component of number meter：
Preferably, the urethane acrylate is the aliphatic urethane acrylate of degree of functionality 2~4, excellent
Select the aliphatic urethane acrylate that degree of functionality is 4.
Preferably, the epoxy acrylate is bisphenol-a epoxy acrylate.
Preferably, the monomer is selected from tripropylene glycol diacrylate, trimethylol propane trimethyl acrylic acid
One or more of ester, pentaerythritol triacrylate, third oxidation pentaerythritol tetraacrylate.
Preferably, the photoinitiator be selected from benzophenone, 1- hydroxy-cyclohexyl-phenyls ketone, 2- hydroxyls-
One kind in 2- methyl-1s--1 acetone of phenyl, 2,4,6- trimethylbenzoy-diphenies phosphine oxide, isopropyl thioxanthone
It is or several.
Preferably, the median of the mill base is 200~500nm.
Preferably, the levelling agent is selected from organic silicon modified by polyether, polyester resin change properties of organic silicon, polydimethylsiloxanes
One or more of alkane, fluorin modified crylic acid ester, acrylate copolymer.
Preferably, the antifoaming agent is one or both of non-silicon defoaming agent and organic silicon defoamer.
Preferably, the wax powder is selected from least one of polyethylene wax, polypropylene wax and polytetrafluoroethylwax wax.
Second aspect, the present invention also provides a kind of preparations of the solvent-proof optical fiber coloring ink composite of height as the aforementioned
Method includes the following steps：
By urethane acrylate, epoxy acrylate, monomer, photoinitiator, wax powder, mill base, levelling agent and antifoaming agent
It is stirred, after photoinitiator is completely dissolved, is filtered, deaeration after mixing, obtain the solvent-proof optical fiber coloring of height
Ink composite.
Compared with prior art, the present invention has following advantageous effect：
The addition of wax powder can float on coating surface starvation before curing, the effect of control oxygen inhibition be played, so as to carry
High surface crosslinking density, and the quality of solvent-resisting is determined that crosslink density is higher, and solvent-resisting is got over by the crosslink density on surface layer
It is good, solvent-resisting can be increased to 200 times by the addition of wax powder, it is (most of to take second place 100~130 far more than existing product
Between), in addition when 85 DEG C of fiber pastes are impregnated 1.5 months dyed layer without obscission.
Specific embodiment
With reference to specific embodiment, the present invention is described in detail.Following embodiment will be helpful to the technology of this field
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill to this field
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection domain.
Embodiment 1
The present embodiment is related to a kind of preparation method of high solvent-proof optical fiber coloring ink composite, specifically includes following step
Suddenly：
A kind of high solvent-proof optical fiber coloring ink, by weight percentage, the content of each component is：White colorant
5%, monomer 27%, urethane acrylate 30%, epoxy acrylate 25%, wax powder 2%, levelling agent 2%, antifoaming agent 2%,
Photoinitiator 7%.
The preparation method of the optical fiber coloring ink of above-mentioned radiation-hardenable is：By said ratio, each raw material components are weighed, are made
It is stirred 60 minutes at 40 DEG C or so with 1000 revs/min of rotating speed with dispersion machine, after photoinitiator is completely dissolved, uses 1500 mesh
Filter filters, and is placed in 40 DEG C of baking ovens and gets product optical fiber coloring ink behind deaeration day.
The viscosity of optical fiber coloring ink prepared by the present embodiment is 3820mpa.s (25 DEG C), and elongation at break is
3.5%, specific modulus (2.5% elongation) is 960MPa, tensile strength 30MPa.
Embodiment 2
The present embodiment is related to a kind of preparation method of high solvent-proof optical fiber coloring ink composite, specifically includes following step
Suddenly：
A kind of high solvent-proof optical fiber coloring ink, by weight percentage, the content of each component is：Yellow color mill base
10%, monomer 30%, urethane acrylate 25%, epoxy acrylate 20%, wax powder 8%, levelling agent 1%, antifoaming agent
1%, photoinitiator 5%.
The preparation method of the optical fiber coloring ink of above-mentioned radiation-hardenable is：By said ratio, each raw material components are weighed, are made
It is stirred 60 minutes at 40 DEG C or so with 1000 revs/min of rotating speed with dispersion machine, after photoinitiator is completely dissolved, uses 1500 mesh
Filter filters, and is placed in deaeration in 40 DEG C of baking ovens and gets product optical fiber coloring ink after 1 day.
The viscosity of optical fiber coloring ink prepared by the present embodiment is 4130mpa.s (25 DEG C), and elongation at break is
7.9%, specific modulus (2.5% elongation) is 952MPa, tensile strength 36MPa.
Embodiment 3
The present embodiment is related to a kind of preparation method of high solvent-proof optical fiber coloring ink composite, specifically includes following step
Suddenly：
A kind of high solvent-proof optical fiber coloring ink, by weight percentage, the content of each component is：Purple color mill base
4%, monomer 27%, urethane acrylate 30%, epoxy acrylate 25%, wax powder 3%, levelling agent 2%, antifoaming agent 1%,
Photoinitiator 8%.
The preparation method of the optical fiber coloring ink of above-mentioned radiation-hardenable is：By said ratio, each raw material components are weighed, are made
It is stirred 60 minutes at 40 DEG C or so with 1000 revs/min of rotating speed with dispersion machine, after photoinitiator is completely dissolved, uses 1500 mesh
Filter filters, and is placed in deaeration in 40 DEG C of baking ovens and gets product optical fiber coloring ink after 1 day.
The viscosity of optical fiber coloring ink prepared by the present embodiment is 3115mpa.s (25 DEG C), and elongation at break is
5.8%, specific modulus (2.5% elongation) is 1025MPa, tensile strength 48MPa.
Embodiment 4
The present embodiment is related to a kind of preparation method of high solvent-proof optical fiber coloring ink composite, specifically includes following step
Suddenly：
A kind of high solvent-proof optical fiber coloring ink, by weight percentage, the content of each component is：Black color mill base
8%, monomer 23%, urethane acrylate 23%, epoxy acrylate 25%, wax powder 8%, levelling agent 4%, antifoaming agent 3%,
Photoinitiator 6%.
The preparation method of the optical fiber coloring ink of above-mentioned radiation-hardenable is：By said ratio, each raw material components are weighed, are made
It is stirred 60 minutes at 40 DEG C or so with 1000 revs/min of rotating speed with dispersion machine, after photoinitiator is completely dissolved, uses 1500 mesh
Filter filters, and is placed in deaeration in 40 DEG C of baking ovens and gets product optical fiber coloring ink after 1 day.
The viscosity of optical fiber coloring ink prepared by the present embodiment is 2601mpa.s (25 DEG C), and elongation at break is
12.9%, specific modulus (2.5% elongation) is 886MPa, tensile strength 23MPa.
Comparative example 1
Certain optical fiber coloring ink on the market, viscosity be 3991mpa.s (25 DEG C), elongation at break 7.9%, specific modulus
(2.5% elongation) is 1286MPa, tensile strength 53MPa.
Comparative example 2
The present embodiment is related to a kind of preparation method of high solvent-proof optical fiber coloring ink composite, specifically includes following step
Suddenly：
A kind of high solvent-proof optical fiber coloring ink, by weight percentage, the content of each component is：Black color mill base
8%, monomer 23%, urethane acrylate 23%, epoxy acrylate 25%, calcium carbonate 8%, levelling agent 4%, antifoaming agent
3%, photoinitiator 6%.
The preparation method of the optical fiber coloring ink of above-mentioned radiation-hardenable is：By said ratio, each raw material components are weighed, are made
It is stirred 60 minutes at 40 DEG C or so with 1000 revs/min of rotating speed with dispersion machine, after photoinitiator is completely dissolved, uses 1500 mesh
Filter filters, and is placed in deaeration in 40 DEG C of baking ovens and gets product optical fiber coloring ink after 1 day.
The viscosity of optical fiber coloring ink prepared by the present embodiment is 2031mpa.s (25 DEG C), and elongation at break is
6.2%, specific modulus (2.5% elongation) is 492MPa, tensile strength 13MPa.
Comparative example 3
The present embodiment is related to a kind of preparation method of high solvent-proof optical fiber coloring ink composite, specifically includes following step
Suddenly：
A kind of high solvent-proof optical fiber coloring ink, by weight percentage, the content of each component is：Yellow color mill base
10%, monomer 30%, urethane acrylate (9 degree of functionality) 25%, epoxy acrylate 20%, wax powder 8%, levelling agent 1%,
Antifoaming agent 1%, photoinitiator 5%.
The preparation method of the optical fiber coloring ink of above-mentioned radiation-hardenable is：By said ratio, each raw material components are weighed, are made
It is stirred 60 minutes at 40 DEG C or so with 1000 revs/min of rotating speed with dispersion machine, after photoinitiator is completely dissolved, uses 1500 mesh
Filter filters, and is placed in deaeration in 40 DEG C of baking ovens and gets product optical fiber coloring ink after 1 day.
The viscosity of optical fiber coloring ink prepared by the present embodiment is 5630mpa.s (25 DEG C), and elongation at break is
19.2%, specific modulus (2.5% elongation) is 1352MPa, tensile strength 49MPa.Since viscosity is excessively high, be not suitable for optical fiber
Coating, and tensile strength is too high, causes ink layer excessively crisp, influences to use.
The coating test of optical fiber coloring ink：
Attenuation refers to the phenomenon that signal strength dies down in fiber middle light signal transmission process, and the attenuation of optical fiber is by national standard
GB/T15972《Fiber Optic Test method specification》The decay testing method of middle offer measures.It will be one described in comparative example and embodiment 1-4
The solvent resistance of kind of high solvent-proof optical fiber coloring ink, compatibility according to GJB6792-2009 optical fiber coloring ink specifications into
Row test, carries out coloring experiment using import M-S machines, is as a result shown in Table 1 respectively.
1 import M-S machine colouring results of table
Optical fiber attenuation is almost unchanged before and after the optical fiber coloring ink colorant prepared through above-mentioned formula, in addition in terms of resistance to butanone
With compatibility experiments it can be seen that data are significantly better than comparative example, main cause also comes from wax powder and floats on surface starvation
Make surface layer.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (10)
1. a kind of high solvent-proof optical fiber coloring ink composite, which is characterized in that including the following component counted in parts by weight：
2. high solvent-proof optical fiber coloring ink composite as described in claim 1, which is characterized in that the polyurethane propylene
Acid esters is the aliphatic urethane acrylate of degree of functionality 2~4.
3. high solvent-proof optical fiber coloring ink composite as described in claim 1, which is characterized in that the epoxy acrylic
Ester is bisphenol-a epoxy acrylate.
4. high solvent-proof optical fiber coloring ink composite as described in claim 1, which is characterized in that the monomer is selected from three
Propylene glycol diacrylate, trimethylol-propane trimethacrylate, pentaerythritol triacrylate, the third oxidation pentaerythrite
One or more of tetraacrylate.
5. high solvent-proof optical fiber coloring ink composite as described in claim 1, which is characterized in that the photoinitiator choosing
From benzophenone, 1- hydroxy-cyclohexyl-phenyls ketone, -1 acetone of 2- hydroxy-2-methyl -1- phenyl, 2,4,6- trimethylbenzene first
One or more of acyl group-diphenyl phosphine oxide, isopropyl thioxanthone.
6. high solvent-proof optical fiber coloring ink composite as described in claim 1, which is characterized in that the middle position of the mill base
Grain size is 200~500nm.
7. high solvent-proof optical fiber coloring ink composite as described in claim 1, which is characterized in that the levelling agent is selected from
In organic silicon modified by polyether, polyester resin change properties of organic silicon, dimethyl silicone polymer, fluorin modified crylic acid ester, acrylate copolymer
One or more.
8. high solvent-proof optical fiber coloring ink composite as described in claim 1, which is characterized in that the antifoaming agent is non-
One or both of silicon defoaming agent and organic silicon defoamer.
9. high solvent-proof optical fiber coloring ink composite as described in claim 1, which is characterized in that the wax powder is selected from poly-
At least one of ethylene waxes, polypropylene wax and polytetrafluoroethylwax wax.
10. a kind of preparation side of solvent-proof optical fiber coloring ink composite of height as described in any one in claim 1~9
Method, which is characterized in that include the following steps：
Urethane acrylate, epoxy acrylate, monomer, photoinitiator, wax powder, mill base, levelling agent and antifoaming agent are mixed
After be stirred, after photoinitiator is completely dissolved, be filtered, deaeration, obtain the solvent-proof optical fiber coloring ink of the height
Composition.
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| CN201711479089.4A CN108084778A (en) | 2017-12-29 | 2017-12-29 | High solvent-proof optical fiber coloring ink composite and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108864805A (en) * | 2018-07-11 | 2018-11-23 | 东莞市菲德诺新材料科技有限公司 | A kind of preparation method of UV type LED light fibre coloring printing ink |
| CN111073387A (en) * | 2019-12-20 | 2020-04-28 | 上海乘鹰新材料有限公司 | Low-energy fast-curing LED optical fiber coloring ink and preparation method thereof |
| WO2020103827A1 (en) * | 2018-11-19 | 2020-05-28 | 上海飞凯光电材料股份有限公司 | Optical fiber coating having color fixation capability, outer coating layer for optical fiber, optical fiber, and preparation methods thereof |
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| CN102286230A (en) * | 2011-09-15 | 2011-12-21 | 哈尔滨大东方卷烟材料科技开发有限责任公司 | Ultraviolet curable ink and preparation method thereof |
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| CN107286735A (en) * | 2017-06-08 | 2017-10-24 | 滁州金桥德克新材料有限公司 | Electronic beam curing high chemical resistance PET printing-ink and preparation method thereof |
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| CN1896156A (en) * | 2006-06-23 | 2007-01-17 | 中国乐凯胶片集团公司 | Ultraviolet light-curing sand vein ink |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108864805A (en) * | 2018-07-11 | 2018-11-23 | 东莞市菲德诺新材料科技有限公司 | A kind of preparation method of UV type LED light fibre coloring printing ink |
| WO2020103827A1 (en) * | 2018-11-19 | 2020-05-28 | 上海飞凯光电材料股份有限公司 | Optical fiber coating having color fixation capability, outer coating layer for optical fiber, optical fiber, and preparation methods thereof |
| CN111073387A (en) * | 2019-12-20 | 2020-04-28 | 上海乘鹰新材料有限公司 | Low-energy fast-curing LED optical fiber coloring ink and preparation method thereof |
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Application publication date: 20180529 |