CN108083847A - A kind of organic silicon infiltration waterproofing agent - Google Patents

A kind of organic silicon infiltration waterproofing agent Download PDF

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Publication number
CN108083847A
CN108083847A CN201711398891.0A CN201711398891A CN108083847A CN 108083847 A CN108083847 A CN 108083847A CN 201711398891 A CN201711398891 A CN 201711398891A CN 108083847 A CN108083847 A CN 108083847A
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CN
China
Prior art keywords
parts
waterproofing agent
organic silicon
silicon infiltration
polyurethane
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711398891.0A
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Chinese (zh)
Inventor
郑劼
王珊
蔡悦
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Shangrao Normal University
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Shangrao Normal University
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Priority to CN201711398891.0A priority Critical patent/CN108083847A/en
Publication of CN108083847A publication Critical patent/CN108083847A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/62Coating or impregnation with organic materials
    • C04B41/64Compounds having one or more carbon-to-metal of carbon-to-silicon linkages
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/49Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
    • C04B41/4905Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon
    • C04B41/495Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes containing silicon applied to the substrate as oligomers or polymers
    • C04B41/4961Polyorganosiloxanes, i.e. polymers with a Si-O-Si-O-chain; "silicones"
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04Polysiloxanes
    • C08G77/38Polysiloxanes modified by chemical after-treatment
    • C08G77/382Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/388Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing nitrogen
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/23Acid resistance, e.g. against acid air or rain
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/27Water resistance, i.e. waterproof or water-repellent materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Sealing Material Composition (AREA)
  • Building Environments (AREA)

Abstract

The invention discloses a kind of organic silicon infiltration waterproofing agents.It is made of the raw material of following parts by weight:40~80 parts of the polyurethane organic siliconresin of NCO sealing ends, 10~20 parts of polymethyl siloxane, 10 30 parts of dodecyl triethoxysilane, 5 10 parts of n-octytriethoxysilane.Organic silicon infiltration waterproofing agent provided by the invention is with viscosity is low, permeability is strong, the superior feature of water resistance.

Description

A kind of organic silicon infiltration waterproofing agent
Technical field
The present invention relates to building material technical fields, and in particular to a kind of organic silicon infiltration waterproofing agent.
Background technology
For a long time, building infiltration has brought great puzzlement, and building infiltration may cause indoor suspended ceiling With metope it is moist, it is mouldy, change colour, come off, it is also possible to cause reinforcement corrosion inside wall, seriously affect housing quality.With People improve the environment and quality requirement of inhabitation, and solving the problems, such as building to seep water, this is very urgent.Concrete cracking is to lead The basic reason of concrete water-permeating is caused, causes the factor of concrete cracking mainly to have the settlement of foundation, concrete proportioning unreasonable, mixed Solidifying soil treatment of construction joints is improper, inside concrete is influenced by water erosion expands.Structure water-proof system can subtract as far as possible The infiltration of few water, among these including constructional waterproofing and surface layer waterproof.Constructional waterproofing is mainly from raising concrete density, draining Structure design, connection detail handle three aspects and improve buildings waterproof, more demanding to building design units and unit in charge of construction. Surface layer waterproof is the main anti-aqueous mode for carrying out water-proofing treatment on built building and using at present, generally have with Under several processing modes:Mated formation using waterproof roll or brush flexible paint and reached in concrete substrate surface formation shielded layer The purpose of waterproof;Concrete surface, which is penetrated into, using inorganic infiltration waterproofing agent generates silicate not soluble in water with hydrolysis product of cement So as to block hole and capillary porosity duct to improve the impermeability of concrete;Concrete is penetrated into using organic silicon infiltration waterproofing agent Surface layer makes hole and capillary hole surface have hydrophobicity.Mated formation using waterproof roll, brush flexible paint and inorganic infiltration waterproof The shortcomings that agent is all poor there are durability, the short life that discharges water.Organic silicon water-proofing bleeding agent has low surface tension, waterproof, breathes freely, but Its intensity is low, adhesion is poor and waterproof effect continuously decreases as time went on.
The content of the invention
In view of the deficiencies of the prior art, have the technical problem to be solved by the invention is to provide one kind good weather-proof Property, the infiltration of excellent water resistant and acid-proof alkaline, caking ability are high, environmentally protective waterproofing agent of organosilicon.
To solve prior art problem, technical solution provided by the invention is:A kind of organic silicon infiltration waterproofing agent, feature It is, is formulated by the raw material of following parts by weight:40~80 parts of the polyurethane organic siliconresin of NCO sealing ends, n-dodecane 10-30 parts of ethyl triethoxy silicane alkane, 5-10 parts of n-octytriethoxysilane.
Above-mentioned organic silicon infiltration waterproofing agent, is formulated by the raw material of following parts by weight:The polyurethane of NCO sealing ends is organic 80 parts of silicones, 15 parts of dodecyl triethoxysilane, 5 parts of n-octytriethoxysilane.
Above-mentioned organic silicon infiltration waterproofing agent, used in NCO sealing end polyurethane organic siliconresin structural formula it is as follows:
4. organic silicon infiltration waterproofing agent as claimed in claim 3, used in NCO sealing ends polyurethane organic siliconresin In structural formula, R is-CH2(CH2)4CH2- or, n is 3~8, preferably 5.
Compared with prior art, technological merit of the invention is:
Waterproofing agent of organosilicon of the present invention is made of organosiloxane and the NCO organic silicon modified polyurethane blocked, can To form cross-linked network structure with the hydroxyl reaction in concrete, water-repellent layer can not only be formed, and due to forming cross-linked structure It can effectively extend its durability, it is easy for construction and have the characteristics that good weatherability, water resistance are good and ageing-resistant performance is good.
Specific embodiment
It is further illustrated the present invention below by embodiment.
Embodiment 1
The polyurethane organic siliconresin of NCO sealing ends prepares as follows:It is put into a kettle according to amount of substance than 2: 1 ratios Hexamethylene diisocyanate and hydroxy silicon oil add in a certain amount of anhydrous propanone as solvent, are warming up under reflux temperature anti- A few hours are answered, until system nco value reaches or less than preset value, stops reaction, vacuum extracts acetone, cools down, discharging.
Embodiment 2
The polyurethane organic siliconresin of NCO sealing ends prepares as follows:It is put into a kettle according to amount of substance than 2: 1 ratios Isophorone diisocyanate and hydroxy silicon oil add in a certain amount of anhydrous propanone as solvent, are warming up under reflux temperature anti- A few hours are answered, until system nco value reaches or less than preset value, stops reaction, vacuum extracts acetone, cools down, discharging.
Embodiment 3
Weigh 80 parts of the polyurethane organic siliconresin of the NCO sealing ends of the preparation of embodiment 1, dodecyl triethoxysilane 15 parts, 5 parts of n-octytriethoxysilane is uniformly mixed, sealing, kept dry.
Embodiment 4
Weigh 80 parts of the polyurethane organic siliconresin of the NCO sealing ends of the preparation of embodiment 1, dodecyl triethoxysilane 10 parts, 10 parts of n-octytriethoxysilane is uniformly mixed, sealing, kept dry.
Embodiment 5
Weigh 60 parts of the polyurethane organic siliconresin of the NCO sealing ends of the preparation of embodiment 1, dodecyl triethoxysilane 30 parts, 10 parts of n-octytriethoxysilane is uniformly mixed, sealing, kept dry.
Embodiment 6
Weigh 40 parts of the polyurethane organic siliconresin of the NCO sealing ends of the preparation of embodiment 1, dodecyl triethoxysilane 40 parts, 20 parts of n-octytriethoxysilane is uniformly mixed, sealing, kept dry.
Embodiment 7
Weigh 80 parts of the polyurethane organic siliconresin of the NCO sealing ends of the preparation of embodiment 2, dodecyl triethoxysilane 15 parts, 5 parts of n-octytriethoxysilane is uniformly mixed, sealing, kept dry.
Embodiment 8
Weigh 80 parts of the polyurethane organic siliconresin of the NCO sealing ends of the preparation of embodiment 2, dodecyl triethoxysilane 10 parts, 10 parts of n-octytriethoxysilane is uniformly mixed, sealing, kept dry.
Embodiment 9
Weigh 60 parts of the polyurethane organic siliconresin of the NCO sealing ends of the preparation of embodiment 2, dodecyl triethoxysilane 30 parts, 10 parts of n-octytriethoxysilane is uniformly mixed, sealing, kept dry.
Embodiment 10
Weigh 40 parts of the polyurethane organic siliconresin of the NCO sealing ends of the preparation of embodiment 2, dodecyl triethoxysilane 40 parts, 20 parts of n-octytriethoxysilane is uniformly mixed, sealing, kept dry.
Embodiment 11
The polyurethane organic siliconresin of NCO sealing ends prepares as follows:It is put into a kettle according to amount of substance than 1.5: 1 ratios Hexamethylene diisocyanate and hydroxy silicon oil, add in a certain amount of anhydrous propanone as solvent, be warming up under reflux temperature A few hours are reacted, until system nco value reaches or less than preset value, stops reaction, vacuum extracts acetone, cools down, discharging.
Embodiment 12
Waterproofing tests:10cm × 10cm concrete test blocks are taken, the organosilicon of embodiment 3-11 is brushed respectively on its surface Waterproofing agent is permeated, when placement 2 is small at room temperature, after dry tack free, weighs and records weight, then test block is immersed in water, 72 It after erasing surface water is taken out after hour, weighs and records its weight, increased weight is water suction quality.
Embodiment 13
Yellowing resistance is tested:Glass plate is taken, brushes organic silicon infiltration waterproofing agent of embodiment 3-11, room respectively on its surface Temperature is lower place 2 it is small when, under ultra violet lamp 72 it is small when, observe whether it turns yellow.
Embodiment 14
Testing permeability:10cm × 10cm concrete test blocks are taken, the organosilicon of embodiment 3-11 is brushed respectively on its surface Waterproofing agent is permeated, when placement 24 is small at room temperature, cuts test block from middle part with cutting machine, the area thickness that darkens is organosilicon Permeate waterproofing agent penetration depth.
Embodiment 12-15 test results are as shown in table 1.
1 embodiment 3-11 the performance test results of table
The above described is only a preferred embodiment of the present invention, being not that the invention has other forms of limitations, appoint What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc. Imitate embodiment.But it is every without departing from technical solution of the present invention content, technical spirit according to the invention is to above example institute Any simple modification, equivalent variations and the remodeling made still fall within the protection domain of technical solution of the present invention.

Claims (4)

1. a kind of organic silicon infiltration waterproofing agent, which is characterized in that it is formulated by the raw material of following parts by weight:NCO sealing ends 40~80 parts of polyurethane organic siliconresin, 10-40 parts of dodecyl triethoxysilane, n-octytriethoxysilane 5-20 Part.
2. a kind of organic silicon infiltration waterproofing agent, which is characterized in that it is formulated by the raw material of following parts by weight:NCO sealing ends 80 parts of polyurethane organic siliconresin, 15 parts of dodecyl triethoxysilane, 5 parts of n-octytriethoxysilane.
3. organic silicon infiltration waterproofing agent as described in claim 1, used in NCO sealing ends polyurethane organic siliconresin structure Formula is as follows:
4. organic silicon infiltration waterproofing agent as claimed in claim 3, used in NCO sealing ends polyurethane organic siliconresin structure In formula, R is-CH2(CH2)4CH2- orN is 3~8, preferably 5.
CN201711398891.0A 2017-12-10 2017-12-10 A kind of organic silicon infiltration waterproofing agent Pending CN108083847A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111154387A (en) * 2020-01-16 2020-05-15 长沙大禹建材科技有限公司 Transparent waterproof coating for controlling water seepage on back water surface

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Publication number Priority date Publication date Assignee Title
CN1696237A (en) * 2004-05-10 2005-11-16 上海市建筑科学研究院有限公司 Combination of waterproof latex, and waterproof application on surface of building
KR100663186B1 (en) * 2006-09-04 2007-01-05 장수관 Silane modified polyurethane waterproofing membrane composition and manufacturing method thereof
CN101786901A (en) * 2010-03-05 2010-07-28 浙江凌志精细化工有限公司 Organosilicon emulsion-type waterproofing agent for building material surfaces and preparation method thereof
CN102918071A (en) * 2010-03-29 2013-02-06 莫门蒂夫性能材料股份有限公司 Silylated polyurethane/polyorganosiloxane blend and sealant composition and fumed silica composition containing same
CN102911597A (en) * 2012-10-23 2013-02-06 江苏博特新材料有限公司 Environment-friendly coating for protecting bare concrete and preparation method thereof
CN103602304A (en) * 2013-11-11 2014-02-26 苏州毫邦新材料有限公司 Fast moisture-cured composition
CN105198274A (en) * 2015-08-17 2015-12-30 华南农业大学 Fluoroalkyl-modified composite organosilicon water-proofing agent and preparing method and application thereof
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CN101786901A (en) * 2010-03-05 2010-07-28 浙江凌志精细化工有限公司 Organosilicon emulsion-type waterproofing agent for building material surfaces and preparation method thereof
CN102918071A (en) * 2010-03-29 2013-02-06 莫门蒂夫性能材料股份有限公司 Silylated polyurethane/polyorganosiloxane blend and sealant composition and fumed silica composition containing same
CN102911597A (en) * 2012-10-23 2013-02-06 江苏博特新材料有限公司 Environment-friendly coating for protecting bare concrete and preparation method thereof
CN103602304A (en) * 2013-11-11 2014-02-26 苏州毫邦新材料有限公司 Fast moisture-cured composition
CN105198274A (en) * 2015-08-17 2015-12-30 华南农业大学 Fluoroalkyl-modified composite organosilicon water-proofing agent and preparing method and application thereof
CN107216845A (en) * 2017-06-29 2017-09-29 华南理工大学 A kind of environment-friendly type end siloxy group polyurethane sealant and preparation method thereof

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高传花等: ""建筑用水性有机硅-聚氨酯嵌段共聚物防水剂"", 《中国建筑防水》 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111154387A (en) * 2020-01-16 2020-05-15 长沙大禹建材科技有限公司 Transparent waterproof coating for controlling water seepage on back water surface

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