CN108083638A - A kind of freedom from cracking tempered glass and its manufacturing method - Google Patents
A kind of freedom from cracking tempered glass and its manufacturing method Download PDFInfo
- Publication number
- CN108083638A CN108083638A CN201711454569.5A CN201711454569A CN108083638A CN 108083638 A CN108083638 A CN 108083638A CN 201711454569 A CN201711454569 A CN 201711454569A CN 108083638 A CN108083638 A CN 108083638A
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- parts
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- plastid
- cracking
- freedom
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Classifications
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
- C03C14/002—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of fibres, filaments, yarns, felts or woven material
Abstract
The invention discloses a kind of freedom from cracking tempered glass and its manufacturing method, which includes 2 parts 3 parts of 5 parts 8 parts of 85 parts 90 parts of silica, boron oxide, sodium oxide molybdena, 6 parts 10 parts of high-temperature resistant silicone colloid, 5 parts 8 parts of the fine copper silk of diameter 0.1mm of the modification of linear backbone silicon systems organic moiety cageization by weight；This liposome surface is also compounded with a layer polypropylene acid esters, the present invention by essence it is modifies and fire, surface is modified is made.Freedom from cracking tempered glass itself linear expansion coefficient of the present invention is low, good toughness, from solidity can it is good, shock resistance is good, also has from cushion performance, suitable for curing in frame size, under the operating mode that the use environment temperature difference is big.
Description
Technical field
The present invention relates to glassware field more particularly to a kind of freedom from cracking tempered glass and its manufacturing methods.
Background technology
Tempered glass, i.e. surface have the glass of compression, can be obtained in routine techniques by physical method or chemical method
, glass bears to offset skin stress first during external force, and so as to improve bearing capacity, reinforcing glass itself anti-wind pressure is trembled with fear
Heat, impact etc..No sharp side, security are preferable when these glass rupture.
But with the development of the times, residential building is higher and higher, and it is swollen to be limited to glass itself for tempered glass of the prior art
Swollen coefficient is high, outer framework is fixed, rigidity is strong and poor toughness, heat dissipation performance are poor, does not possess speciality from cushion performance, in height thermally
The big area (such as desert) of area (Xi'an in such as summer), extremely frigid zones (Heilungkiang in such as winter), day and night temperature is easily by heat expansion
Shrinkage influence is easily cracked, and high-altitude is caused to fall the hidden danger of object.
Therefore, be badly in need of on the market a kind of itself low linear expansion coefficient, good toughness, from solidity can it is good, shock resistance is good,
Also there is the freedom from cracking tempered glass and its manufacturing method from cushion performance.
The content of the invention
In view of the above defects of the prior art, the present invention is intended to provide itself a kind of linear expansion coefficient is low, tough
Property it is good, from solidity can it is good, shock resistance is good, also has from the freedom from cracking tempered glass and its manufacturing method of cushion performance.
To achieve these goals, the present invention uses following technical scheme：A kind of manufacturing method of freedom from cracking tempered glass,
Comprise the following steps：
1) prepare before production
1. glass raw material prepares：Prepare 85 parts -90 parts of silica, 5 parts -8 parts of boron oxide, sodium oxide molybdena 2 by weight
- 3 parts of part；
2. essential modified material prepares：Prepare 5 parts -8 parts of linear polysiloxane, 1 part -2 parts of carbon decaborane, hydrogen by weight
5 parts -8 parts of the fine copper silk of 0.05 part -0.06 part of sodium oxide molybdena, diameter 0.1mm；
3. surface modifying material prepares：Enough polyacrylate；
2) this plastid of glass is fired
1. 1) 2. linear polysiloxane, carbon decaborane and sodium hydroxide and 30-40 parts of pure water that step in is obtained mix
Polycondensation reaction, reaction time 5h-6h, filter are carried out after conjunction under 580 DEG C of -600 DEG C of temperature, the stir speed (S.S.) of 150rpm-180rpm
Except the high-temperature resistant silicone colloid that the modification of linear backbone silicon systems organic moiety cageization is obtained after liquid；
2. preparation is built-in with electrode, inner surface is coated with containing aluminium graphite cast iron mold of the insulation except adhesion coating, in 1)
2. fine copper silk spinning that step prepares is made into the layer net that smooth vertical and horizontal and aperture is length of side 5mm square holes, is equidistantly spread using 5mm as interlamellar spacing
If in a mold；
3. by 1. high-temperature resistant silicone colloid that step obtains with 1) in the raw material that 1. prepare of step be uniformly mixed, obtain
Mixture；
4. 3. mixture that step is obtained pours into the mold for being equipped with fine copper silk screen, mold is then placed in vacuum electric heating
Mixture is energized to after 350 DEG C are warming up in treatment furnace, in stove as kinematic viscosity 5mm2/s-10mm2The fluid of/s, Ran Houkai
Beginning, (magnetic agitation is mainly used for stirring or the simultaneously liquid of heating stirring low sticky degree with the rate magnetic agitation of 60rpm-80rpm
Body or solidliquid mixture.Its basic principle is using the magnetic field principle that identical charges repel each other, there is a natural attraction between the sexes, is promoted and placed using magnetic field
Magnetic substance carries out circumferential running in a reservoir, so as to achieve the purpose that agitated liquid.Coordinate heating and temperature control system,
It can be heated according to specific requirement of experiment and control sample temperature, maintain the temperature conditionss needed for production, ensure liquid mixing
Reach demand), this plastid of acquisition glass after stirring；
3) this plastid of glass tempering
1. this plastid of glass that flow-like is filled in mold is gas-cooled under the nitrogen of 5bar-6bar, that is, obtain physics
This plastid of tempered glass；
4) glass essence surface modification
1. 1) 3. polyacrylate that step in prepares is heated to molten condition；
2. by the stage 3) polypropylene of molten condition that is 1. obtained to step of physical toughened this plastid of glass infiltration for obtaining
In acid esters；
3. 2. physical toughened this plastid of glass for having infiltrated polyacrylate that step is obtained takes out, treat its surface in half
Minute surface is mechanically processed as during fluid state, freedom from cracking tempered glass i.e. needed for acquisition completely after cooling.
The freedom from cracking tempered glass manufactured using the above method, this plastid composition include silica by weight
85 parts -90 parts, 5 parts -8 parts of boron oxide, 2 parts -3 parts of sodium oxide molybdena, linear backbone silicon systems organic moiety cageization be modified high temperature resistant
5 parts -8 parts of the fine copper silk of 6 parts -10 parts of organosilicon colloid, diameter 0.1mm；This liposome surface is also compounded with layer polypropylene acid
Ester.
Compared with the prior art, the present invention has the following advantages as a result of said program：(1) using existing
Be not applied to the borosilicate glass of building in technology, and be low boron class borosilicate glass therein, i.e. SiO2-B2O3-
R2(in routine techniques, this kind of glass is usually using its light, electricity, hot property, for front glass, heat-resisting cooker, peace for O systems glass
Small jar glass, neutral density glass, electric-vacuum glass, optical glass, LCD substrates, solar panel and heat collector), it is ground according to correlation
Study carefully, the coefficient of expansion of such glass is that minimum in all glass and heat dissipation performance is best.(2) present invention is also in glass
The modification of linear backbone silicon systems organic moiety cageization is added in matrix, and (the cageization modification specifically just refers to the shallow lake of straight-chain
Powder forms cylinder mould shape knot by the moiety segments of the epoxy-modified object of high energy and the effect aftercondensated product of catalyst sodium hydroxide
Structure) high-temperature resistant silicone colloid, which it is epoxy-modified to add high energy based on heat safe linear polysiloxane
Object, and polycondensation reaction is carried out under the action of catalyst sodium hydroxide, acquisition is with soft elastic and opposite with vitreum close
The high-temperature resistant silicone colloid of sum subsequently not by conventional heating but carries out glass this plastid exclusively by electrical heating processing
On the one hand melting is that make use of principle conductive under borosilicate glass high temperature, be on the other hand also to promote under electric power effect
Part-S-O- keys in glass polymerize with organosilicon colloid, and colloid is made to be integrally formed with glass, and with molecule or a small amount of molecules
Group's form is solidificated in glass this plastid, obtains flexible buffering colloid, is aided with the low-expansion coefficient of borosilicate glass itself
With heat dissipation performance and soft fine copper silk from solidity energy, the overall performance system of a freedom from cracking is constituted.(3) covered by surface
The processing of film, is the outer Extended lift cushion space of the present invention, and reduces impact force, reduces tearing tendency, polyacrylate
Adhesive ability is strong, itself is soft flexible, and translucency is good, good weatherability, not easy to change and aging and in the prior art never
Material applied to glassware field.(4) very thin fine copper silk screen built in, according to correlative study, hot tearing is mainly due to temperature
Excessive or internal stress is excessive causes for difference, and the internal stress under regular situation during most hot tearings is only slightly born beyond tempered glass
The limit, only because tempered glass itself brittleness in routine techniques is high and without ability, therefore the present invention is increased admittedly certainly
Very thin fine copper silk can effectively reduce the possibility of hot tearing, and according to the practice of applicant, hot tearing of the invention can be solely routine
The 5%-6% of tempered glass.
Specific embodiment
Embodiment 1：
A kind of freedom from cracking tempered glass, this plastid composition include silica 85Kg, boron oxide by weight
High-temperature resistant silicone colloid 10Kg, the diameter 0.1mm that 8Kg, sodium oxide molybdena 3Kg, linear backbone silicon systems organic moiety cageization are modified
Fine copper silk 8Kg；This liposome surface is also compounded with a layer polypropylene acid esters.
The manufacturing method of above-mentioned freedom from cracking tempered glass is manufactured, is comprised the following steps：
1) prepare before production
1. glass raw material prepares：Prepare silica 85Kg, boron oxide 8Kg, sodium oxide molybdena 3Kg；
2. essential modified material prepares：Prepare linear polysiloxane 8Kg, carbon decaborane 2Kg, sodium hydroxide 0.06Kg, straight
The fine copper silk 8Kg of footpath 0.1mm；
3. surface modifying material prepares：Enough polyacrylate；
2) this plastid of glass is fired
1. 1) after 2. linear polysiloxane, carbon decaborane and sodium hydroxide that step in is obtained are mixed with 40Kg pure water
Polycondensation reaction is carried out under 580 DEG C of temperature, the stir speed (S.S.) of 150rpmm, reaction time 5h obtains linear backbone after filtering out liquid
The high-temperature resistant silicone colloid that silicon systems organic moiety cageization is modified；
2. preparation is built-in with electrode, inner surface is coated with containing aluminium graphite cast iron mold of the insulation except adhesion coating, in 1)
2. fine copper silk spinning that step prepares is made into the layer net that smooth vertical and horizontal and aperture is length of side 5mm square holes, is equidistantly spread using 5mm as interlamellar spacing
If in a mold；
3. by 1. high-temperature resistant silicone colloid that step obtains with 1) in the raw material that 1. prepare of step be uniformly mixed, obtain
Mixture；
4. 3. mixture that step is obtained pours into the mold for being equipped with fine copper silk screen, mold is then placed in vacuum electric heating
Mixture is energized to after 350 DEG C are warming up in treatment furnace, in stove as kinematic viscosity 5mm2The fluid of/s, then start with
The rate magnetic agitation of 60rpm, this plastid of acquisition glass after stirring；
3) this plastid of glass tempering
1. this plastid of glass that flow-like is filled in mold is gas-cooled under the nitrogen of 5bar, that is, obtain physical toughened glass
This plastid of glass；
4) glass essence surface modification
1. 1) 3. polyacrylate that step in prepares is heated to molten condition；
2. by the stage 3) polypropylene of molten condition that is 1. obtained to step of physical toughened this plastid of glass infiltration for obtaining
In acid esters；
3. 2. physical toughened this plastid of glass for having infiltrated polyacrylate that step is obtained takes out, treat its surface in half
Minute surface is mechanically processed as during fluid state, freedom from cracking tempered glass i.e. needed for acquisition completely after cooling.
The glass produced according to the present embodiment, linear expansion coefficient (3.0) × 10-6/ K, thermal conductivity factor 1.3W/mK.
Embodiment 2：
A kind of freedom from cracking tempered glass, this plastid composition include silica 90Kg, boron oxide by weight
High-temperature resistant silicone colloid 6Kg, the diameter 0.1mm that 5Kg, sodium oxide molybdena 2Kg, linear backbone silicon systems organic moiety cageization are modified
Fine copper silk 5Kg；This liposome surface is also compounded with a layer polypropylene acid esters.
The manufacturing method of above-mentioned freedom from cracking tempered glass is manufactured, is comprised the following steps：
1) prepare before production
1. glass raw material prepares：Prepare silica 90Kg, boron oxide 5Kg, sodium oxide molybdena 2Kg by weight；
2. essential modified material prepares：Prepare linear polysiloxane 5Kg, carbon decaborane 1Kg, sodium hydroxide by weight
The fine copper silk 5Kg of 0.05Kg, diameter 0.1mm；
3. surface modifying material prepares：Enough polyacrylate；
2) this plastid of glass is fired
1. 1) after 2. linear polysiloxane, carbon decaborane and sodium hydroxide that step in is obtained are mixed with 30Kg pure water
Polycondensation reaction is carried out under 600 DEG C of temperature, the stir speed (S.S.) of 180rpm, reaction time 6h obtains linear backbone after filtering out liquid
The high-temperature resistant silicone colloid that silicon systems organic moiety cageization is modified；
2. preparation is built-in with electrode, inner surface is coated with containing aluminium graphite cast iron mold of the insulation except adhesion coating, in 1)
2. fine copper silk spinning that step prepares is made into the layer net that smooth vertical and horizontal and aperture is length of side 5mm square holes, is equidistantly spread using 5mm as interlamellar spacing
If in a mold；
3. by 1. high-temperature resistant silicone colloid that step obtains with 1) in the raw material that 1. prepare of step be uniformly mixed, obtain
Mixture；
4. 3. mixture that step is obtained pours into the mold for being equipped with fine copper silk screen, mold is then placed in vacuum electric heating
Mixture is energized to after 350 DEG C are warming up in treatment furnace, in stove as kinematic viscosity 10mm2The fluid of/s, then start with
The rate magnetic agitation of 80rpm, this plastid of acquisition glass after stirring；
3) this plastid of glass tempering
1. this plastid of glass that flow-like is filled in mold is gas-cooled under the nitrogen of 6bar, that is, obtain physical toughened glass
This plastid of glass；
4) glass essence surface modification
1. 1) 3. polyacrylate that step in prepares is heated to molten condition；
2. by the stage 3) polypropylene of molten condition that is 1. obtained to step of physical toughened this plastid of glass infiltration for obtaining
In acid esters；
3. 2. physical toughened this plastid of glass for having infiltrated polyacrylate that step is obtained takes out, treat its surface in half
Minute surface is mechanically processed as during fluid state, freedom from cracking tempered glass i.e. needed for acquisition completely after cooling.
The glass produced according to the present embodiment, linear expansion coefficient (2.8) × 10-6/ K, thermal conductivity factor 1.2W/mK.
The foregoing description of the disclosed embodiments, only for professional and technical personnel in the field is enable to realize or use this
Invention.A variety of modifications of these embodiments will be apparent for those skilled in the art, institute herein
The General Principle of definition can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore,
The present invention is not intended to be limited to the embodiments shown herein, and is to fit to special with principles disclosed herein and novelty
The consistent most wide scope of point.
Claims (2)
1. a kind of manufacturing method of freedom from cracking tempered glass, it is characterised in that comprise the following steps：
1) prepare before production
1. glass raw material prepares：Prepare 85 parts -90 parts of silica, 5 parts -8 parts of boron oxide, 2 part -3 of sodium oxide molybdena by weight
Part；
2. essential modified material prepares：Prepare 5 parts -8 parts of linear polysiloxane, 1 part -2 parts of carbon decaborane, hydroxide by weight
5 parts -8 parts of the fine copper silk of 0.05 part -0.06 part of sodium, diameter 0.1mm；
3. surface modifying material prepares：Enough polyacrylate；
2) this plastid of glass is fired
1. 1) after 2. linear polysiloxane, carbon decaborane and sodium hydroxide that step in is obtained are mixed with 30-40 parts of pure water
Polycondensation reaction is carried out under 580 DEG C of -600 DEG C of temperature, the stir speed (S.S.) of 150rpm-180rpm, reaction time 5h-6h filters out liquid
The high-temperature resistant silicone colloid that linear backbone silicon systems organic moiety cageization is modified is obtained after body；
2. prepare to be built-in with electrode, inner surface is coated with containing aluminium graphite cast iron mold of the insulation except adhesion coating, by step in 1)
2. the fine copper silk spinning prepared is made into the layer net that smooth vertical and horizontal and aperture is length of side 5mm square holes, equidistantly it is laid on using 5mm as interlamellar spacing
In mold；
3. by 1. high-temperature resistant silicone colloid that step obtains with 1) in the raw material that 1. prepare of step be uniformly mixed, mixed
Object；
4. 3. mixture that step is obtained pours into the mold for being equipped with fine copper silk screen, mold is then placed in vacuum electric heating processing
Mixture is energized to after 350 DEG C are warming up in stove, in stove as kinematic viscosity 5mm2/s-10mm2The fluid of/s, then start with
The rate magnetic agitation of 60rpm-80rpm, this plastid of acquisition glass after stirring；
3) this plastid of glass tempering
1. this plastid of glass that flow-like is filled in mold is gas-cooled under the nitrogen of 5bar-6bar, that is, obtain physical toughened
This plastid of glass；
4) glass essence surface modification
1. 1) 3. polyacrylate that step in prepares is heated to molten condition；
2. by the stage 3) polyacrylate of molten condition that is 1. obtained to step of physical toughened this plastid of glass infiltration for obtaining
In；
3. 2. physical toughened this plastid of glass for having infiltrated polyacrylate that step is obtained takes out, it is in semifluid to treat its surface
Minute surface is mechanically processed as during state, freedom from cracking tempered glass i.e. needed for acquisition completely after cooling.
2. a kind of freedom from cracking tempered glass manufactured using claim 1 the method, it is characterised in that：Its this plastid composition bag
It is organic to include 2 parts -3 parts of 5 parts -8 parts of 85 parts -90 parts of silica, boron oxide, sodium oxide molybdena by weight, linear backbone silicon systems
6 parts -10 parts of high-temperature resistant silicone colloid, 5 parts -8 parts of the fine copper silk of diameter 0.1mm of object part cageization modification；The essence body surface
Face is also compounded with a layer polypropylene acid esters.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711454569.5A CN108083638A (en) | 2017-12-28 | 2017-12-28 | A kind of freedom from cracking tempered glass and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711454569.5A CN108083638A (en) | 2017-12-28 | 2017-12-28 | A kind of freedom from cracking tempered glass and its manufacturing method |
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| Publication Number | Publication Date |
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| CN108083638A true CN108083638A (en) | 2018-05-29 |
Family
ID=62180703
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