CN108083390A - Efficient micro-electrolysis reactor - Google Patents

Efficient micro-electrolysis reactor Download PDF

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Publication number
CN108083390A
CN108083390A CN201611033891.6A CN201611033891A CN108083390A CN 108083390 A CN108083390 A CN 108083390A CN 201611033891 A CN201611033891 A CN 201611033891A CN 108083390 A CN108083390 A CN 108083390A
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CN
China
Prior art keywords
reactor body
water
agitating paddle
inlet pipe
efficient micro
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Pending
Application number
CN201611033891.6A
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Chinese (zh)
Inventor
何旭红
吉宝钢
吉煜鹏
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Shanxi Bao Sheng Source Of Mechanical And Electrical Equipment Co Ltd
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Shanxi Bao Sheng Source Of Mechanical And Electrical Equipment Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Shanxi Bao Sheng Source Of Mechanical And Electrical Equipment Co Ltd filed Critical Shanxi Bao Sheng Source Of Mechanical And Electrical Equipment Co Ltd
Priority to CN201611033891.6A priority Critical patent/CN108083390A/en
Publication of CN108083390A publication Critical patent/CN108083390A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention belongs to field of waste water treatment, a kind of efficient micro-electrolysis reactor, including reactor body, water intake mechanism, admission gear, rabbling mechanism, charging mechanism and three phase separation mechanism;Admission gear includes being arranged on gas chamber, air inlet pipe and the orifice plate of reactor body bottom;Water intake mechanism is arranged on the top of admission gear, and three phase separation mechanism is located in the middle part of reactor body;Rabbling mechanism includes agitating shaft and the first agitating paddle and the second agitating paddle that are arranged on agitating shaft, first agitating paddle is located at the top of water intake mechanism, second agitating paddle is between water intake mechanism and admission gear, material in reactor body is stirred paddle stirring by the first agitating paddle towards second, and material in reactor body is stirred paddle stirring by the second agitating paddle towards first.Double-stirring machine structure in the application not only so that stirring evenly, but also is avoided the problem that assembling above orifice plate and resulted in blockage;Admission gear and water intake mechanism can also reach stirring action simultaneously.

Description

Efficient micro-electrolysis reactor
Technical field
The invention belongs to field of waste water treatment more particularly to a kind of efficient micro-electrolysis reactors.
Background technology
Micro-electrolysis method is using Principles of Metal Erosion, forms the good process that primary battery handles waste water.The technique The attention of many countries is just caused since be born.Change method to be widely used in printing and dyeing, heavy metal, pharmacy, have waste water It waits in sewage disposals, is a kind of emerging electrochemical method, with spies such as wide, the simple for process, high treating effects of use scope Point, particularly with high salinity, high COD and the higher waste water of colourity treatment effect have compared with other techniques it is more obvious excellent Gesture.
But difficult point arrogant in weak electrolysis mechanism is that iron carbon easily lumps, and easily leads to the problem of blocking, causes to handle Efficiency is low or even shutdown is needed to handle.
The content of the invention
The defects of the purpose of the present invention is light electrolysis existing in the prior art is overcome easily to generate blocking, provides a kind of efficient Micro-electrolysis reactor.
The technical solution adopted by the present invention to solve the technical problems is:A kind of efficient micro-electrolysis reactor, including reaction Device body, water intake mechanism, admission gear, rabbling mechanism, charging mechanism and three phase separation mechanism;
The admission gear includes being arranged on the gas chamber of the reactor body bottom, the air inlet pipe connected with the gas chamber With the orifice plate for separating the gas chamber and above-mentioned reactor body inner chamber body;
The water intake mechanism is arranged on the top of the admission gear, and the three phase separation mechanism is located at the reactor sheet In the middle part of body;The rabbling mechanism includes agitating shaft and the first agitating paddle and the second agitating paddle that are arranged on the agitating shaft, institute State the top that the first agitating paddle is located at the water intake mechanism, second agitating paddle is located at the water intake mechanism and described into mechanism of qi Between structure, by material in the reactor body towards the described second stirring paddle stirring, described second stirs first agitating paddle It mixes paddle and material in the reactor body is stirred into paddle stirring towards described first.
Further, in a ring, one side is provided with the air inlet being connected with source of the gas, the air inlet pipe to the air inlet pipe On be provided with the venthole that Open Side Down.The air inlet pipe of annular so that gas is more uniform in gas indoor distribution, and venthole Open Side Down, which is set, can effectively avoid venthole directly by, into blockings such as the particles of air inlet chamber, while gas is by hole by orifice plate Plate enters reactor body, and orifice plate can be distributed gas again so that gas is distributed more in reactor body It is even, while stirring action is played to material in reactor body, be conducive to that material is avoided to lump.
Preferably, the water intake mechanism includes water inlet pipe, water distribution ring, the water distribution ring is arranged on the reactor sheet In vivo, the water inlet pipe is for connecting the water distribution ring and external source, and be provided with that Open Side Down on the water distribution ring goes out Water hole.It is similar with admission gear, using annular water distribution ring, be conducive to uniform into water, effectively improve waste water and gas and iron carbon The uniform contact of material, is conducive to the uniformity and adequacy of micro-electrolysis reaction, and Open Side Down sets and can have for apopore Effect avoids apopore by blockings such as iron carbon filler particle, caking or flocculate precipitates;Water intake mechanism can be effectively to reaction simultaneously Material is stirred in device main body.
Preferably, the water intake mechanism further includes inclined tube, described inclined tube one end is connected with the water inlet pipe, the other end It stretches into the reactor body, and is set towards the water distribution ring lower part.Since water intake mechanism is located at the bottom of reactor body Portion, material easily lump in bottom precipitation, and generation stopping state is more, can be effectively to water distribution ring using inclined tube when blocking Bottom position is rinsed, and avoids the generation of stopping state;Or interruption opens inclined tube water inlet, and water distribution ring bottom is rushed It washes, achievees the effect that pulse lavage, avoid the blocking of water intake mechanism.
Further, for ease of the water inlet of control water distribution ring or inclined tube, the first control valve is provided on the water inlet pipe, Be provided with the second control valve on the inclined tube, first control valve be arranged at the junction of the inclined tube and the water inlet pipe with Between the water distribution ring.
Further, the water inlet end of the water inlet pipe is connected with Venturi tube, and the negative port of the Venturi tube is made For acid solution charge door, there is magnetic field at the trunnion of the Venturi tube.It is intake, is formed at negative port negative using Venturi tube Pressure, achievees the purpose that automatical dosing, while flow rate of liquid is higher at Venturi tube trunnion, liquid cutting magnetic induction line generate electric current compared with Greatly, achieve the effect that preliminary light electrolysis, improve light electrolysis effect, while there is sterilization, the effect of broken wall.
Specifically, the charging mechanism includes casing drum, charging spout and screw meter, and described casing drum one end is stretched into In the reactor body, the other end is connected by screw meter with the charging spout.It can first be added in by charging mechanism Disposable carbon material, then be interrupted during the reaction by screw meter or continuous and quantitative adds in iron material so that iron material It makes full use of, avoids iron material deposit clumps.
Further, for ease of the gas in reactor body is discharged, the three phase separation mechanism has emptying pipeline It is in communication with the outside.
Preferably, the reactor body upper dimension is more than the size of its underpart, size is smaller larger to size Section transitions part forms settling zone, and the settling zone top is provided with downflow weir;The settling zone is provided with towards described anti- The precipitation plate that device body sidewall slope is answered to set.Reactor upper dimension becomes larger so that flow rate of liquid is slack-off, is conducive to not three The particle of precipitation precipitates under transition region and precipitation plate effect in phase separation mechanism, prevents iron carbon material in reactor body By the loss of downflow weir.
Further, the reactor body bottom and the gas chamber bottom are both provided with drain.Utilize drain When can lump in reactor body, in gas chamber or block serious, emptying manipulation is carried out.
Advantageous effect:Double-stirring machine structure is set in the application between admission gear and water intake mechanism, in two agitating paddles Bottoms material towards top stirring, top material towards lower part is stirred under effect, not only so that stirring evenly, but also can be incited somebody to action The iron carbon and flocculate on orifice plate top stir upwards, avoid the problem that assembling above orifice plate resulting in blockage;Admission gear and into Water dispenser structure can also reach stirring action simultaneously, have multiple stirring in the application, can effectively avoid the caking of iron carbon, avoid blocking up Plug.
Description of the drawings
The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.
Fig. 1 is micro-electrolysis reactor structure diagram of the present invention;
Fig. 2 is schematic enlarged-scale view at A in Fig. 1;
Fig. 3 is schematic enlarged-scale view at B in Fig. 1;
Fig. 4 is rabbling mechanism structure diagram;
Fig. 5 is charging mechanism structure diagram.
Wherein:1. reactor body, 11. transition portions, 12. precipitation plates, 13. downflow weirs, 14. drains, 2. into water dispenser Structure, 21. water inlet pipes, 22. water distribution rings, 23. inclined tubes, 3. admission gears, 31. gas chambers, 32. air inlet pipe, 33. orifice plates, 4. chargers Structure, 41. casing drums, 42. charging spouts, 43. screw meters, 5. three phase separation mechanisms, 51. emptying pipelines, 6. agitating shafts, 7. the One agitating paddle, 8. second agitating paddles, 9. Venturi tubes, 91. negative ports, 92. trunnions, 93. electromagnetic coils.
Specific embodiment
Embodiment 1
As shown in Figure 1, a kind of efficient micro-electrolysis reactor, including reactor body 1, water intake mechanism 2, admission gear 3, stir Mix mechanism, charging mechanism 4 and three phase separation mechanism 5;
As illustrated in fig. 1 and 2, the admission gear 3 includes the gas chamber 31 and the institute that are arranged on 1 bottom of reactor body The orifice plate 33 stated the air inlet pipe 32 of the connection of gas chamber 31 and separate the gas chamber 31 and 1 inner chamber body of reactor body, institute In a ring, one side is provided with the air inlet being connected with source of the gas to the air inlet pipe 32 stated, be provided in the air inlet pipe 32 opening to Under venthole;
As illustrated in fig. 1 and 2, the water intake mechanism 2 is arranged on the top of the admission gear 3, including water inlet pipe 21, water distribution Circle 22, the water distribution ring 22 is arranged in the reactor body 1, the water inlet pipe 21 for connect the water distribution ring 22 with it is outer Boundary water source, as shown in figure 3, the water inlet end of the water inlet pipe 21 is connected with Venturi tube 9, the negative pressure of the Venturi tube 9 connects Mouth 91 is used as acid solution charge door, and there is magnetic field (can pass through electromagnetic coil 93 or strong magnet is real at the trunnion 92 of the Venturi tube 9 Now), the apopore that Open Side Down is provided on the water distribution ring 22, the water intake mechanism 2 further includes inclined tube 23, described oblique 23 one end of pipe is connected with the water inlet pipe 21, and the other end is stretched into the reactor body 1, and towards 22 lower part of water distribution ring It sets, the first control valve is provided on the water inlet pipe 21, the second control valve, first control are provided on the inclined tube 23 Valve processed is arranged between the inclined tube 23 and the junction of the water inlet pipe 21 and the water distribution ring 22.
As shown in figure 4, the rabbling mechanism include agitating shaft 6 and the first agitating paddle 7 for being arranged on the agitating shaft 6 with Second agitating paddle 8, first agitating paddle 7 are located at the top of the water intake mechanism 2, second agitating paddle 8 be located at it is described into Between water dispenser structure 2 and the admission gear 3, first agitating paddle 7 is by material in the reactor body 1 towards described second Agitating paddle 8 stirs, and second agitating paddle 8 stirs material in the reactor body 1 towards first agitating paddle 7.
As shown in figure 5, the charging mechanism 4 includes casing drum 41, charging spout 42 and screw meter 43, the charging 41 one end of cylinder are stretched into the reactor body 1, and the other end is connected by screw meter 43 with the charging spout 42.
As shown in Figure 1, the three phase separation mechanism 5 is located at 1 middle part of reactor body, there is emptying pipeline 51, And pass through and empty pipeline 51 and be in communication with the outside;1 upper dimension of reactor body is more than the size of its underpart, and size is smaller Settling zone is formed to size major part transition portion 11, the settling zone top is provided with downflow weir 13;The settling zone is set It is equipped with the precipitation plate 12 set towards 1 sidewall slope of reactor body.1 bottom of reactor body and the gas chamber 31 bottoms are both provided with drain 14.
Operation principle is as follows:It is carried by casing drum 41 to reaction and carbon material is added in main body, and from water inlet pipe 21 to reaction Waste water is passed through in device main body, at the same it is continuous into reactor body by charging spout 42 and screw meter 43 and casing drum 41 It is quantitatively adding iron material;When waste water passes through Venturi tube 9, the cutting magnetic induction line at trunnion 92 so that waste water is charged, and electricity occurs Solution reacts and reaches sterilization effect, while adds in acid at the negative port 91 of Venturi tube 9 according to wastewater property.Waste water is by cloth The apopore of hydrosphere 22 enters reactor body, at the same gas by the venthole of air inlet pipe 32 into air inlet chamber 31, and pass through orifice plate 33 are uniformly passed through in reactor body.Material further generates micro-electrolysis reaction under the effect of iron carbon material in reactor body, Agitating device is stirred simultaneously, and the second agitating paddle 8 stirs the material on 33 top of orifice plate towards top in the process, and first Agitating paddle 7 stirs the material on reactor body top towards lower part, forms Xun Huan so that waste water and iron carbon in reactor body Material is uniformly mixed so that the waste water that the waste water in reactor body enters with water inlet pipe 21 is sufficiently mixed, and reaction is abundant, without dead Angle, while solid accumulation at orifice plate 33 and water inlet pipe 21 is avoided to block.When the accumulation of 22 bottoms material of water distribution ring is more, open oblique Pipe 23 is intake, and can effectively be broken up the material of accumulation using inclined tube 23, is avoided the blocking of water intake mechanism 2.
Waste water carries out solid-liquid-gas three phase separation after micro-electrolysis reaction through three phase separation mechanism 5, and gas is by emptying pipeline 51 The particles such as emptying, iron carbon are precipitated to 5 bottom of three phase separation mechanism, and the liquid after reaction reaches the top of reactor body, pass through Changeover portion flow velocity reduces suddenly, is conducive to further precipitate the particulate matters such as wherein subsidiary iron carbon, avoid its with liquid by 13 overflow of downflow weir is discharged.
It should be appreciated that specific embodiment described above is only used for explaining the present invention, it is not intended to limit the present invention.By The obvious changes or variations that the spirit of the present invention is extended out is still in the protection scope of this invention.

Claims (10)

1. a kind of efficient micro-electrolysis reactor, it is characterised in that:Including reactor body (1), water intake mechanism (2), admission gear (3), rabbling mechanism, charging mechanism (4) and three phase separation mechanism (5);
The admission gear (3) includes being arranged on the gas chamber (31) of the reactor body (1) bottom, connect with the gas chamber (31) Logical air inlet pipe (32) and the orifice plate (33) for separating the gas chamber (31) and the reactor body (1) inner chamber body;
The water intake mechanism (2) is arranged on the top of the admission gear (3), and the three phase separation mechanism (5) is located at described anti- It answers in the middle part of device main body (1);The rabbling mechanism includes agitating shaft (6) and the first agitating paddle being arranged on the agitating shaft (6) (7) and the second agitating paddle (8), first agitating paddle (7) are located at the top of the water intake mechanism (2), second agitating paddle (8) between the water intake mechanism (2) and the admission gear (3), first agitating paddle (7) is by the reactor body (1) interior material is stirred towards second agitating paddle (8), and second agitating paddle (8) is by the reactor body (1) interior material It is stirred towards first agitating paddle (7).
2. efficient micro-electrolysis reactor according to claim 1, it is characterised in that:The air inlet pipe (32) in a ring, Its one side is provided with the air inlet being connected with source of the gas, and the venthole that Open Side Down is provided on the air inlet pipe (32).
3. efficient micro-electrolysis reactor according to claim 1, it is characterised in that:The water intake mechanism (2) include into Water pipe (21), water distribution ring (22), the water distribution ring (22) are arranged in the reactor body (1), and the water inlet pipe (21) is used In the connection water distribution ring (22) and external source, the water distribution ring apopore that Open Side Down is provided on (22).
4. efficient micro-electrolysis reactor according to claim 3, it is characterised in that:The water intake mechanism (2) further includes Inclined tube (23), described inclined tube (23) one end are connected with the water inlet pipe (21), and the other end is stretched into the reactor body (1), And it is set towards the water distribution ring (22) lower part.
5. efficient micro-electrolysis reactor according to claim 3, it is characterised in that:It is provided on the water inlet pipe (21) First control valve, is provided with the second control valve on the inclined tube (23), first control valve be arranged at the inclined tube (23) and Between the junction of the water inlet pipe (21) and the water distribution ring (22).
6. the efficient micro-electrolysis reactor according to claim 3 or 4, it is characterised in that:The water inlet pipe (21) into Water end (W.E.) is connected with Venturi tube (9), and the negative port (91) of the Venturi tube (9) is as acid solution charge door, the venturi Managing has magnetic field at the trunnion (92) of (9).
7. efficient micro-electrolysis reactor according to claim 1, it is characterised in that:The charging mechanism (4) includes adding The reactor body (1) is stretched into barrel (41), charging spout (42) and screw meter (43), described casing drum (41) one end Interior, the other end is connected by screw meter (43) with the charging spout (42).
8. efficient micro-electrolysis reactor according to claim 1, it is characterised in that:The three phase separation mechanism (5) has Emptying pipeline (51) is in communication with the outside.
9. efficient micro-electrolysis reactor according to claim 1, it is characterised in that:Described reactor body (1) top Size is more than the size of its underpart, and size is smaller to form settling zone, the settling zone to size major part transition portion (11) Top is provided with downflow weir (13);The settling zone is provided with the precipitation set towards the reactor body (1) sidewall slope Plate (12).
10. efficient micro-electrolysis reactor according to claim 1, it is characterised in that:Described reactor body (1) bottom Drain (14) is both provided with the gas chamber (31) bottom.
CN201611033891.6A 2016-11-22 2016-11-22 Efficient micro-electrolysis reactor Pending CN108083390A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201611033891.6A CN108083390A (en) 2016-11-22 2016-11-22 Efficient micro-electrolysis reactor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201611033891.6A CN108083390A (en) 2016-11-22 2016-11-22 Efficient micro-electrolysis reactor

Publications (1)

Publication Number Publication Date
CN108083390A true CN108083390A (en) 2018-05-29

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Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2552589Y (en) * 2002-06-07 2003-05-28 吴喜明 Vertical stirrer
CN200978237Y (en) * 2006-12-07 2007-11-21 浙江环盛环境工程有限公司 Continuous flow autoclave type micro electrolysis iron-carbon device
CN201161946Y (en) * 2007-06-30 2008-12-10 沈旋 Cavitation oxygenation disinfection running water apparatus of waterpower
CN102249486A (en) * 2011-05-25 2011-11-23 西安工程大学 Electrochemical-biological method combination device for treating printing and dyeing wastewater and wastewater treating method
CN103191664A (en) * 2013-04-08 2013-07-10 贵州大学 Adjustable stirring device
CN103214068A (en) * 2013-05-15 2013-07-24 陕西师范大学 Magnetic coupling hydrodynamic cavitation tubular type sewage treater
CN104511255A (en) * 2013-09-27 2015-04-15 沈阳铝镁设计研究院有限公司 Low-energy-consumption high-uniformity combined-blade stirring device
CN104876400A (en) * 2015-05-26 2015-09-02 桂林理工大学 Iron-carbon micro-electrolysis integrative reaction device
CN204727647U (en) * 2015-05-08 2015-10-28 江苏海澜正和环境科技有限公司 A kind of micro-electrolysis reactor
CN206502646U (en) * 2016-11-22 2017-09-19 山西宝晟源机电设备有限公司 Efficient micro-electrolysis reactor

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2552589Y (en) * 2002-06-07 2003-05-28 吴喜明 Vertical stirrer
CN200978237Y (en) * 2006-12-07 2007-11-21 浙江环盛环境工程有限公司 Continuous flow autoclave type micro electrolysis iron-carbon device
CN201161946Y (en) * 2007-06-30 2008-12-10 沈旋 Cavitation oxygenation disinfection running water apparatus of waterpower
CN102249486A (en) * 2011-05-25 2011-11-23 西安工程大学 Electrochemical-biological method combination device for treating printing and dyeing wastewater and wastewater treating method
CN103191664A (en) * 2013-04-08 2013-07-10 贵州大学 Adjustable stirring device
CN103214068A (en) * 2013-05-15 2013-07-24 陕西师范大学 Magnetic coupling hydrodynamic cavitation tubular type sewage treater
CN104511255A (en) * 2013-09-27 2015-04-15 沈阳铝镁设计研究院有限公司 Low-energy-consumption high-uniformity combined-blade stirring device
CN204727647U (en) * 2015-05-08 2015-10-28 江苏海澜正和环境科技有限公司 A kind of micro-electrolysis reactor
CN104876400A (en) * 2015-05-26 2015-09-02 桂林理工大学 Iron-carbon micro-electrolysis integrative reaction device
CN206502646U (en) * 2016-11-22 2017-09-19 山西宝晟源机电设备有限公司 Efficient micro-electrolysis reactor

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