CN108064662B - A kind of organic magnetic planting soil and preparation method thereof - Google Patents

A kind of organic magnetic planting soil and preparation method thereof Download PDF

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CN108064662B
CN108064662B CN201711449877.9A CN201711449877A CN108064662B CN 108064662 B CN108064662 B CN 108064662B CN 201711449877 A CN201711449877 A CN 201711449877A CN 108064662 B CN108064662 B CN 108064662B
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sludge
red mud
planting soil
organic
magnetized
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CN108064662A (en
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马跃
庞鹤
孙雅楠
王洪志
杨秋雨
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Dalian Earth Environment Technology Co Ltd
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Abstract

The present invention provides a kind of organic magnetized planting soils and preparation method thereof, the organic magnetized planting soil is mainly prepared by the raw material of following mass ratio: sludge 100 ~ 130: magnetic active carbon 30 ~ 40: dealkalize red mud 45 ~ 55: turfy soil 10 ~ 15, a kind of organic magnetized planting soil preparation method obtains mixture the following steps are included: sludge, magnetic active carbon, dealkalize red mud, turfy soil are that 100 ~ 130:30 ~ 40:45 ~ 55:10 ~ 15 mix by (1) in mass ratio;(2) step (1) mixture is subjected to aerobic compost maturity, decomposed 12 ~ 14 days, obtains planting soil.The invention enables stalk, dolomite waste residue, phosphorus tailing, iron tailings, red muds to be widely applied in abandoned mine, the problem of not only solving land occupation resource caused by tailing is largely stored up and pollution environment, also achieve the resource utilization of tailing, turn waste into wealth, improve the effective rate of utilization of resource, recycling sludge, minimizing, stabilisation, innoxious application are realized, it is energy saving, reduce preparation cost.

Description

A kind of organic magnetic planting soil and preparation method thereof
Technical field
The present invention relates to planting soil preparation technical field, specifically a kind of organic magnetic planting soil and preparation method thereof.
Background technique
Mine Solid Wastes refer to selected smelting to produce including barren rock caused by during mining and ore after institute The tailing or waste residue of generation become a great problem of environmental protection to measure big, complex treatment process.And sludge is as sewage The by-product of processing, complicated component contain sex pheromone, parasitic ovum, poisonous and hazardous heavy metal and a large amount of difficult drop Substance is solved, is such as dealt with improperly, is easy to cause secondary pollution to environment.Mine Solid Wastes and sludge is studied to carry out as resource Efficient comprehensive utilization, can not only improve the ecological environment in mine, but also can make full use of the useful component in waste, change give up into Treasured has realistic meaning to the increasingly serious environmental problem in China is alleviated.
Currently, general planting soil matches Preparation Method mainly with the raw materials such as zeolite, biological organic fertilizer, turfy soil, perlite, choosing With Mine Solid Wastes and sludge, decomposed manure system such as the iron tailings of magnetizing roast, phosphorus tailing, dolomite waste residue, red muds The research data of standby organic magnetic planting soil is less, does not find that pertinent literature is described it also.
Summary of the invention
In view of the foregoing, the object of the present invention is to provide a kind of organic magnetic planting soils and preparation method thereof, it is intended to full The demand that soil moved in improve the original is largely used in sufficient land restoration in mining area, solve Mine Solid Wastes stockpiling occupy a large amount of land resource, The environmental problems such as atmosphere, water resource pollution, open sludge reduction, stabilisation, innoxious, resource utilization thinking, alleviate or The objective demand of soil moved in improve the original during solution abandoned mine restoration harness.
To achieve the goals above, the present invention the following technical schemes are provided:
A kind of organic magnetized planting soil, is mainly prepared by the raw material of following mass ratio: sludge 100 ~ 130: magnetism is living Property charcoal 30 ~ 40: dealkalize red mud 45 ~ 55: turfy soil 10 ~ 15.
A kind of organic magnetized planting soil and preparation method thereof, comprising the following steps:
(1) by sludge, magnetic active carbon, dealkalize red mud, turfy soil be in mass ratio 100 ~ 130:30 ~ 40:45 ~ 55:10 ~ 15 are mixed, and mixture is obtained;
(2) step (1) mixture is subjected to aerobic compost maturity, decomposed 12 ~ 14 days, obtains planting soil.
Further, step (1) sludge is prepared in the following manner:
I. sludge is concentrated by machinery, anaerobic digestion;
II. sludge after step I digestion is sent into 10 meshes to sieve, obtains -10 mesh sludge;The moisture percentage in sewage sludge is 78%~82%。
Further, step (1) the dealkalize red mud is prepared in the following manner:
A. red mud is configured to the slurry that solid-to-liquid ratio is 1:4.5 ~ 5, spray type desulphurization tower is pumped by screw rod and is taken off Alkali process;The red mud is Bayer process red mud, and pH value 12 ~ 13, partial size is -200 mesh, and moisture content is 60% ~ 70%;
B. red mud after dealkalize is sent into filter press and carries out filter-press dehydration, obtain dealkalize red mud;The dealkalize red mud moisture content It is 35% ~ 40%, pH value is 7.5 ~ 8.0.
Further, step (1) magnetic active carbon is prepared in the following manner:
A. in mass ratio by dewatered sludge, magnetization iron tailings, phosphorus mine tailing, dolomite waste residue powder, straw powder material are as follows: 80 ~ 100:12 ~ 15:15 ~ 20:10 ~ 15:15 ~ 20 are mixed, and mixture is obtained;The phosphorus mine tailing is by carrying out to phosphorus tailing Grinding, screening are made, and partial size is -200 mesh;The dolomite waste residue powder be by being crushed to dolomite waste residue, ore grinding, Screening is made, and partial size is -200 mesh;The straw powder material is made by carrying out natural air drying, crushing to stalk, sieving, Partial size is -100 mesh, and moisture content is 15% ~ 20%;
B. step A mixture feeding high-speed compound pelletizer is granulated;
C. step B mixture pelleting is sent into 750 DEG C ~ 800 DEG C retorts and carries out pyrolysis charring;
D., step C is solved to granulation feeding 8000 ~ 9000mT magnetization field strength after carbonizing to magnetize, 10 ~ 12s of magnetization is obtained Magnetic active carbon with magnetic temperature stability;The magnetic induction intensity of the magnetizing field is 40 ~ 45 μ T;The magnetic active carbon partial size For 0.5 ~ 1mm, 850 ~ 900m of specific surface area2/ g, 0.25 ~ 0.27cm of Micropore volume3/g。
Further, the step A dewatered sludge is prepared in the following manner:
I. sludge after step I digestion is subjected to desiccation using fume afterheat, obtaining moisture content is 10% sludge below;
Ii. step i sludge is subjected to ore grinding, screening, obtaining partial size is -200 mesh dewatered sludges.
Further, the step A magnetization iron tailings is prepared in the following manner:
1. iron tailings, coal dust are carried out magnetizing roast at a temperature of 600 DEG C ~ 650 DEG C, the coal dust incorporation is iron tailings The 30% ~ 35% of quality roasts 2 ~ 2.5min;
2. mixture is ground, sieved 1. step is roasted after, obtaining partial size is that -200 mesh magnetize iron tailings.
Further, the step flue gas that 1. magnetizing roast and step a magnetizing roast generate, is sent by pipeline and is sprayed Formula desulfurizing tower carries out desulfurization process, and the waste heat for exporting flue gas is sent into step i by pipeline to be used;In the output flue gas SO2Concentration is down to 30 ~ 70mg/m3, meet the national standard of flue gas emission.
Further, the decomposed condition of the step (2) are as follows: the moisture content of mixture remains 30%-36%, environment temperature It is 20 DEG C -25 DEG C, decomposed temperature is 55 DEG C -70 DEG C, and ventilation quantity is 9 ~ 15m3/ (h t), heap body oxygen content 5% ~ 15%.
The invention has the benefit that
It has obtained largely answering in abandoned mine the invention enables stalk, dolomite waste residue, phosphorus tailing, iron tailings, red mud With, not only solve land occupation resource caused by tailing is largely stored up and pollution environment the problem of, also achieve the money of tailing Sourceization utilizes, and turns waste into wealth, improves the effective rate of utilization of resource.Application of the sludge in magnetic planting soil, realizes sludge Recycling, minimizing, stabilisation, innoxious application.Meanwhile using red mud to the flue gas generated in magnetizing roast and sintering process Desulfurization process is carried out, national standard limit of smog release is reached, reduces also the alkalinity of red mud during this, that widens red mud applies model It encloses, fume afterheat can be used for sludge drying link, realize the maximization of using energy source in planting soil preparation process, save energy Source reduces preparation cost.
Detailed description of the invention
Fig. 1 is a kind of process flow diagram of organic magnetic planting soil and preparation method thereof.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described ground embodiment is only a part of the embodiment of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained all under the premise of not making creative work achievement Other embodiments shall fall within the protection scope of the present invention.
The technical problem to be solved by the present invention is in view of the deficiencies of the prior art, provide a kind of organic magnetic planting soil And preparation method thereof.A kind of organic magnetized planting soil, is mainly prepared by the raw material of following mass ratio: sludge 100 ~ 130: magnetic Property active carbon 30 ~ 40: dealkalize red mud 45 ~ 55: turfy soil 10 ~ 15.
A kind of organic magnetized planting soil and preparation method thereof, comprising the following steps:
(1) by sludge, magnetic active carbon, dealkalize red mud, turfy soil be in mass ratio 100 ~ 130:30 ~ 40:45 ~ 55:10 ~ 15 are mixed, and mixture is obtained;
(2) step (1) mixture is subjected to aerobic compost maturity, decomposed 12 ~ 14 days, obtains planting soil.
Embodiment 1
A kind of organic magnetized planting soil and preparation method thereof, comprising the following steps:
(1) by iron tailings, coal blending, 2 min of magnetizing roast is carried out at a temperature of 600 DEG C, by mixture after roasting into Row grinding, screening, obtaining partial size is that -200 mesh magnetize iron tailings, and coal dust incorporation is the 30% of iron tailings quality;
(2) sludge is concentrated, anaerobic digestion by machinery, sludge a part after digestion is carried out using fume afterheat Desiccation, then ore grinding, screening, obtain moisture content be 10% or less, partial size be -200 mesh dewatered sludges obtain;
(3) phosphorus tailing ground, sieved, obtain -200 mesh phosphorus mine tailings;
(4) dolomite waste residue is crushed, ore grinding, screening, obtains -200 mesh dolomite waste residue powders;
(5) stalk is subjected to natural air drying, crushing, screening, obtains -100 mesh straw powder materials;
(6) in mass ratio by dewatered sludge, magnetization iron tailings, phosphorus mine tailing, dolomite waste residue powder, straw powder material are as follows: 80: 12:15:10:20 is mixed, and is sent into high-speed compound pelletizer and is granulated, and is re-fed into 750 DEG C of retorts and is carried out pyrolytic carbon Change, feeding 8000mT magnetization field strength will be granulated after pyrolysis charring and is magnetized, magnetizes 10 s, obtains the magnetic with magnetic temperature stability Property active carbon;The magnetic induction intensity of the magnetizing field is 40 μ T;The magnetic active carbon partial size is 0.5 mm, specific surface area 900 m2/ g, Micropore volume 0.27;
(7) it will be concentrated after step (2) concentration, anaerobic digestion by machinery, another part sludge after anaerobic digestion It is sent into 10 meshes to be sieved, obtains -10 mesh sludge;
(8) red mud is configured to the slurry that solid-to-liquid ratio is 1:5, spray type desulphurization tower is pumped by screw rod and is carried out at dealkalize Red mud after dealkalize is sent into filter press and carries out filter-press dehydration, obtains dealkalize red mud, pH value 8.0 by reason;The red mud is Bayer Method red mud, pH value 12, partial size are -200 mesh;The spray type desulphurization produces step (2) magnetizing roast and step (6) pyrolysis charring Raw flue gas desulfurization is sent into spray type desulphurization tower by pipeline and carries out desulfurization process, and the waste heat for exporting flue gas is sent by pipeline Step is used in (2);
It (9) is in mass ratio that 100:40:55:10 is mixed by sludge, magnetic active carbon, dealkalize red mud, turfy soil, it will Mixture carries out aerobic compost maturity, decomposed 12 days, obtains planting soil.
The content of organic matter is 7.5 g/kg in planting soil made from present implementation, and N-P-K content is respectively 290mg/ Kg, 820mg/kg and 660mg/kg, wherein quick-acting nitrogen contents are 180mg/kg, available phosphorus contents 585mg/kg, available state potassium Content is 445mg/kg, pH value 8.0, percentage of seedgermination 94%, and every heavy metal index meets the mark of national planting soil It is quasi-.
Embodiment 2
A kind of organic magnetized planting soil and preparation method thereof, comprising the following steps:
(1) by iron tailings, coal blending, 2.3 min of magnetizing roast is carried out at a temperature of 630 DEG C, by mixture after roasting It ground, sieved, obtaining partial size is that -200 mesh magnetize iron tailings, and coal dust incorporation is the 32% of iron tailings quality;
(2) sludge is concentrated, anaerobic digestion by machinery, sludge a part after digestion is carried out using fume afterheat Desiccation, then ore grinding, screening, obtain moisture content be 10% or less, partial size be -200 mesh dewatered sludges obtain;
(3) phosphorus tailing ground, sieved, obtain -200 mesh phosphorus mine tailings;
(4) dolomite waste residue is crushed, ore grinding, screening, obtains -200 mesh dolomite waste residue powders;
(5) stalk is subjected to natural air drying, crushing, screening, obtains -100 mesh straw powder materials;
(6) in mass ratio by dewatered sludge, magnetization iron tailings, phosphorus mine tailing, dolomite waste residue powder, straw powder material are as follows: 90: 13:18:12:18 is mixed, and is sent into high-speed compound pelletizer and is granulated, and is re-fed into 780 DEG C of retorts and is carried out pyrolytic carbon Change, feeding 8500mT magnetization field strength will be granulated after pyrolysis charring and is magnetized, magnetizes 11 s, obtains the magnetic with magnetic temperature stability Property active carbon;The magnetic induction intensity of the magnetizing field is 42 μ T;The magnetic active carbon partial size is 0.8 mm, specific surface area 880 m2/ g, Micropore volume 0.26cm3/g;
(7) it will be concentrated after step (2) concentration, anaerobic digestion by machinery, another part sludge after anaerobic digestion It is sent into 10 meshes to be sieved, obtains -10 mesh sludge;
(8) red mud is configured to the slurry that solid-to-liquid ratio is 1:4.8, spray type desulphurization tower is pumped by screw rod and is taken off Red mud after dealkalize is sent into filter press and carries out filter-press dehydration, obtains dealkalize red mud, pH value 7.8 by alkali process;The red mud be for Bayer process red mud, pH value 12, partial size are -200 mesh;The spray type desulphurization is by step (2) magnetizing roast and step (6) pyrolytic carbon Change the flue gas desulfurization generated, spray type desulphurization tower is sent by pipeline and carries out desulfurization process, the waste heat for exporting flue gas passes through pipeline It is sent into step (2) and is used;
It (9) is in mass ratio that 115:38:45:12 is mixed by sludge, magnetic active carbon, dealkalize red mud, turfy soil, it will Mixture carries out aerobic compost maturity, decomposed 13 days, obtains planting soil.
The content of organic matter is 7.6 g/kg in planting soil made from present implementation, and N-P-K content is respectively 300mg/ Kg, 830mg/kg and 675mg/kg, wherein quick-acting nitrogen contents are 190mg/kg, available phosphorus contents 600mg/kg, available state potassium Content is 450mg/kg, pH value 7.8, percentage of seedgermination 95%, and every heavy metal index meets the mark of national planting soil It is quasi-.
Embodiment 3
A kind of organic magnetized planting soil and preparation method thereof, comprising the following steps:
(1) by iron tailings, coal blending, 2.5 min of magnetizing roast is carried out at a temperature of 650 DEG C, by mixture after roasting It ground, sieved, obtaining partial size is that -200 mesh magnetize iron tailings, and powder incorporation is the 35% of iron tailings quality;
(2) sludge is concentrated, anaerobic digestion by machinery, sludge a part after digestion is carried out using fume afterheat Desiccation, then ore grinding, screening, obtain moisture content be 10% or less, partial size be -200 mesh dewatered sludges obtain;
(3) phosphorus tailing ground, sieved, obtain -200 mesh phosphorus mine tailings;
(4) dolomite waste residue is crushed, ore grinding, screening, obtains -200 mesh dolomite waste residue powders;
(5) stalk is subjected to natural air drying, crushing, screening, obtains -100 mesh straw powder materials;
(6) in mass ratio by dewatered sludge, magnetization iron tailings, phosphorus mine tailing, dolomite waste residue powder, straw powder material are as follows: 100:15:20:15:15 is mixed, and is sent into high-speed compound pelletizer and is granulated, and is re-fed into 800 DEG C of retorts and is carried out heat Solution charing will be granulated feeding 9000mT magnetization field strength and magnetize, and magnetize 12s, obtain with magnetic temperature stability after pyrolysis charring Magnetic active carbon;The magnetic induction intensity of the magnetizing field is 45 μ T;The magnetic active carbon partial size is 1mm, specific surface area 850m2/ g, Micropore volume 0.25cm3/g;
(7) it will be concentrated after step (2) concentration, anaerobic digestion by machinery, another part sludge after anaerobic digestion It is sent into 10 meshes to be sieved, obtains -10 mesh sludge;
(8) red mud is configured to the slurry that solid-to-liquid ratio is 1:4.5, spray type desulphurization tower is pumped by screw rod and carries out dealkalize Red mud after dealkalize is sent into filter press and carries out filter-press dehydration, obtains dealkalize red mud, pH value 7.5 by processing;The red mud is to visit Ear method red mud, pH value 12, partial size are -200 mesh;The spray type desulphurization is by step (2) magnetizing roast and step (6) pyrolysis charring The flue gas desulfurization of generation is sent into spray type desulphurization tower by pipeline and carries out desulfurization process, and the waste heat for exporting flue gas is sent by pipeline Enter and is used in step (2);
It (9) is in mass ratio that 130:35:40:15 is mixed by sludge, magnetic active carbon, dealkalize red mud, turfy soil, it will Mixture carries out aerobic compost maturity, decomposed 14 days, obtains planting soil.
In planting soil made from present implementation the content of organic matter be 7.7g/kg, N-P-K content be respectively 310mg/kg, 840mg/kg and 680mg/kg, wherein quick-acting nitrogen contents are 200mg/kg, available phosphorus contents 615mg/kg, available state potassium content For 455mg/kg, pH value 7.5, percentage of seedgermination 96%, every heavy metal index meets the standard of national planting soil.
The foregoing is merely most preferred embodiments in experiment of the invention, are not intended to limit the invention, it is all Within the spirit and principles in the present invention, any modification, equivalent replacement, improvement and so on should be included in protection of the invention Within the scope of.

Claims (6)

1. a kind of organic magnetized planting soil, is mainly prepared by the raw material of following mass ratio: sludge 100 ~ 130: magnetic activity Charcoal 30 ~ 40: dealkalize red mud 45 ~ 55: turfy soil 10 ~ 15;
The organic magnetized planting soil is prepared by the following steps:
(1) by sludge, magnetic active carbon, dealkalize red mud, turfy soil be in mass ratio 100 ~ 130:30 ~ 40:45 ~ 55:10 ~ 15 into Row mixes, and obtains mixture;
The magnetic active carbon is prepared in the following manner:
A. in mass ratio by dewatered sludge, magnetization iron tailings, phosphorus mine tailing, dolomite waste residue powder, straw powder material are as follows: 80 ~ 100: 12 ~ 15:15 ~ 20:10 ~ 15:15 ~ 20 are mixed, and mixture is obtained;The phosphorus mine tailing is by grinding to phosphorus tailing Mill, screening are made, and partial size is -200 mesh;The dolomite waste residue powder be by being crushed to dolomite waste residue, ore grinding, sieve Divide and be made, partial size is -200 mesh;The straw powder material is made by carrying out natural air drying, crushing to stalk, sieving, grain Diameter is -100 mesh, and moisture content is 15% ~ 20%;
B. step A mixture feeding high-speed compound pelletizer is granulated;
C. step B mixture pelleting is sent into 750 DEG C ~ 800 DEG C retorts and carries out pyrolysis charring;
D., step C is solved to granulation feeding 8000 ~ 9000mT magnetization field strength after carbonizing to magnetize, 10 ~ 12s of magnetization is had The magnetic active carbon of magnetic temperature stability;The magnetic induction intensity of the magnetizing field is 40 ~ 45 μ T;The magnetic active carbon partial size is 0.5 ~ 1mm, 850 ~ 900m2/g of specific surface area, 0.25 ~ 0.27cm3/g of Micropore volume;
(2) step (1) mixture is subjected to aerobic compost maturity, decomposed 12 ~ 14 days, obtains planting soil, decomposed condition are as follows: mixing The moisture content of object remains 30%-36%, and environment temperature is 20 DEG C -25 DEG C, and decomposed temperature is 55 DEG C -70 DEG C, ventilation quantity is 9 ~ 15m3/(h t), heap body oxygen content 5% ~ 15%.
2. a kind of organic magnetized planting soil according to claim 1, which is characterized in that step (1) sludge passes through following It is prepared by mode:
I. sludge is concentrated by machinery, anaerobic digestion;
II. sludge after step I digestion is sent into 10 meshes to sieve, obtains -10 mesh sludge;The moisture percentage in sewage sludge be 78% ~ 82%。
3. a kind of organic magnetized planting soil according to claim 1, which is characterized in that step (1) the dealkalize red mud passes through Following manner preparation:
A. red mud is configured to the slurry that solid-to-liquid ratio is 1:4.5 ~ 5, spray type desulphurization tower is pumped by screw rod and is carried out at dealkalize Reason;The red mud is Bayer process red mud, and pH value 12 ~ 13, partial size is -200 mesh, and moisture content is 60% ~ 70%;
B. red mud after dealkalize is sent into filter press and carries out filter-press dehydration, obtain dealkalize red mud;The dealkalize red mud moisture content is 35% ~ 40%, pH value is 7.5 ~ 8.0.
4. a kind of organic magnetized planting soil according to claim 1, which is characterized in that the step A dewatered sludge by with Under type preparation:
I. sludge after step I digestion is subjected to desiccation using fume afterheat, obtaining moisture content is 10% sludge below;
Ii. step i sludge is subjected to ore grinding, screening, obtaining partial size is -200 mesh dewatered sludges.
5. a kind of organic magnetized planting soil according to claim 1, which is characterized in that the step A magnetization iron tailings passes through Following manner preparation:
1. iron tailings, coal dust are carried out magnetizing roast at a temperature of 600 DEG C ~ 650 DEG C, the coal dust incorporation is iron tailings quality 30% ~ 35%, roast 2 ~ 2.5min;
2. mixture is ground, sieved 1. step is roasted after, obtaining partial size is that -200 mesh magnetize iron tailings.
6. a kind of organic magnetized planting soil according to claim 5, which is characterized in that the step 1. magnetizing roast and step The flue gas that C charing pyrolysis generates, is sent into spray type desulphurization tower by pipeline and carries out desulfurization process, the waste heat for exporting flue gas passes through pipe Road is sent into step i and is used;The output so2 concentration in flue gas is down to 30 ~ 70mg/m3, meets the country of flue gas emission Standard.
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CN108901535A (en) * 2018-06-27 2018-11-30 贵州松桃正大振兴生态农旅开发有限公司 A kind of implantation methods of peach
CN108718993B (en) * 2018-07-13 2020-06-26 大连地拓环境科技有限公司 Boron tailing planting soil and preparation method thereof
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CN106278730A (en) * 2016-08-15 2017-01-04 大连地拓重工有限公司 A kind of suspension roasting iron tailings planting soil and preparation method thereof
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