CN108060021A - A kind of cleaned and reduced dose of automobile three-element catalytic and preparation method thereof - Google Patents

A kind of cleaned and reduced dose of automobile three-element catalytic and preparation method thereof Download PDF

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Publication number
CN108060021A
CN108060021A CN201711412184.2A CN201711412184A CN108060021A CN 108060021 A CN108060021 A CN 108060021A CN 201711412184 A CN201711412184 A CN 201711412184A CN 108060021 A CN108060021 A CN 108060021A
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CN
China
Prior art keywords
cleaned
automobile
isopropanol
ether
reduced dose
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201711412184.2A
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Chinese (zh)
Inventor
钟立专
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Dayawan Huizhou Yi Car Technology Co Ltd
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Dayawan Huizhou Yi Car Technology Co Ltd
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Priority to CN201711412184.2A priority Critical patent/CN108060021A/en
Publication of CN108060021A publication Critical patent/CN108060021A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D1/721End blocked ethers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/52Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids oxygen-containing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/64Liquid treating or treating in liquid phase, e.g. dissolved or suspended using alkaline material; using salts
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/044Hydroxides or bases
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/2017Monohydric alcohols branched
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2093Esters; Carbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/26Organic compounds containing nitrogen
    • C11D3/33Amino carboxylic acids
    • C11D2111/20

Abstract

The invention discloses a kind of cleaned and reduced dose of automobile three-element catalytics and preparation method thereof, consist of the following components in percentage by weight:Carbon deposit blows down agent 5% 10%;Sodium hydroxide 0.5% 1.5%;Tetrasodium ethylenediamine tetraacetate 0.3% 4.5%;Nonylphenol polyoxyethylene ether 0.1% 3%;Isopropanol 0.5% 4%;Monoethylene glycol monobutyl ether 0.5% 1%;Water surplus.The carbon deposit that the present invention adds blows down agent, plays an important role of cleaning to ternary catalyzing unit surface attachments, decomposes.It is added in cleaned and reduced dose of system, has the characteristics that cleaning speed is fast, effect is good, can thoroughly remove sulfide, phosphide and carbon distribution in ternary catalyzing unit, ternary catalyzing unit is allowed to keep good working order.

Description

A kind of cleaned and reduced dose of automobile three-element catalytic and preparation method thereof
Technical field
The present invention relates to automotive fields, and in particular to a kind of cleaned and reduced dose of automobile three-element catalytic and preparation method thereof.
Background technology
Ternary catalyzing unit is mounted in most important outer purifier in automobile exhaust system, it can will be in vehicle exhaust The pernicious gases such as CO, HC, NOx of discharge are changed into harmless carbon dioxide, water and nitrogen by oxidation and reduction.Work as height When the vehicle exhaust of temperature passes through purifier, the cleanser in ternary catalyzing unit will enhance the work of tri- kinds of gas of CO, HC and NOx Property, it is promoted to carry out a series of oxidationreduction chemical reaction, wherein CO is oxidized to colourless, nontoxic titanium dioxide at high temperature Carbon gas, HC compounds are oxidized to water (H2O) and carbon dioxide at high temperature, and NOJlj is reduced to nitrogen and oxygen, therefore pass through Ternary catalyzing unit is handled, and three kinds of pernicious gases in vehicle exhaust become innocuous gas, and vehicle exhaust is purified.
After automobile longtime running, carbon distribution, sulphur phosphate mixture of generation etc. can be accumulated on the poroid material of ternary catalyzing unit, It results in blockage to ternary catalyzing unit, influences the adsorption effect of ternary catalyzing unit, cause vehicle discharge exceeded.
The content of the invention
To solve the above problems, the present invention provides a kind of cleaned and reduced dose of automobile three-element catalytics.Can dissolve rapidly carbon distribution, Sulphur phosphate mixture recovers ternary catalyzing unit activity.
Technical scheme is as follows:
A kind of cleaned and reduced dose of automobile three-element catalytic, consists of the following components in percentage by weight:Carbon deposit blows down 5 % -10 of agent %;Sodium hydroxide 0.5%-1.5%;Tetrasodium ethylenediamine tetraacetate 0.3%-4.5%;0.1 %-3 % of nonylphenol polyoxyethylene ether;Isopropyl 0.5 %-4 % of alcohol;0.5 %-1% of monoethylene glycol monobutyl ether;Water surplus.
Further, the carbon deposit blows down agent as the mixed of butyl acetate, butyl glycol ether, isopropanol and ethyl acetate It closes, and butyl acetate, butyl glycol ether, the weight ratio of isopropanol and ethyl acetate are 10:4:4:4.
Further, a kind of cleaned and reduced dose of automobile three-element catalytic, consists of the following components in percentage by weight:Carbon deposit Blow down 5 % -8% of agent;Sodium hydroxide 0.5%-1%;Tetrasodium ethylenediamine tetraacetate 0.3%-4%;0.5 %-2 of nonylphenol polyoxyethylene ether %;0.5 %-2% of isopropanol;0.5 %-0.8% of monoethylene glycol monobutyl ether;Water surplus.
The present invention also provides a kind of preparation methods of cleaned and reduced dose of automobile three-element catalytic, include the following steps:
1)Butyl acetate, butyl glycol ether, isopropanol and ethyl acetate are mixed evenly, carbon deposit is made and blows down agent;
2)Tetrasodium ethylenediamine tetraacetate, nonylphenol polyoxyethylene ether, isopropanol, monoethylene glycol monobutyl ether, water are mixed equal It is even, sodium hydroxide is slowly added to, is stirred evenly;
3)Carbon deposit is blown down into agent and adds in step 2)In, it stirs evenly.
Compared with prior art, the invention has the advantages that:
The carbon deposit that the present invention adds blows down agent, plays an important role of cleaning to ternary catalyzing unit surface attachments, decomposes.It is added to clear It washes in reducing agent system, has the characteristics that cleaning speed is fast, effect is good, can thoroughly remove sulfide, phosphorus in ternary catalyzing unit Compound and carbon distribution allow ternary catalyzing unit to keep good working order.The present invention can effectively recover ternary catalyzing unit surface-active, The harmful substance in Vehicular exhaust is reduced, solves the problems, such as tail gas pollution, existing automobile is avoided and reduces exhaust pollutant discharge Technology in, cleaning agent carry out administer tail gas by way of it is poor there are cleaning effect, can not effectively reduce pollution emission The problem of object.
Specific embodiment
With reference to specific embodiment, the present invention is described in further detail.
Embodiment 1
A kind of cleaned and reduced dose of automobile three-element catalytic, consists of the following components in percentage by weight:Carbon deposit blows down agent 7%;Hydrogen-oxygen Change sodium 0.8%;Tetrasodium ethylenediamine tetraacetate 2%;1.5 % of nonylphenol polyoxyethylene ether;Isopropanol 1.5%;Monoethylene glycol monobutyl ether 0.6%;Water surplus, the carbon deposit blow down agent by butyl acetate, butyl glycol ether, isopropanol and ethyl acetate the ratio between by weight For 10:4:4:4 compositions.
Embodiment 2
A kind of cleaned and reduced dose of automobile three-element catalytic, consists of the following components in percentage by weight:Carbon deposit blows down 5 % of agent;Hydrogen-oxygen Change sodium 1.5%;Tetrasodium ethylenediamine tetraacetate 4.5%;0.1 % of nonylphenol polyoxyethylene ether;4 % of isopropanol;Monoethylene glycol monobutyl ether 0.5 %;Water surplus, the carbon deposit blow down agent by butyl acetate, butyl glycol ether, isopropanol and ethyl acetate the ratio between by weight For 10:4:4:4 compositions.
Embodiment 3
A kind of cleaned and reduced dose of automobile three-element catalytic, consists of the following components in percentage by weight:Carbon deposit blows down 10 % of agent;Hydrogen Sodium oxide molybdena 0.5%;Tetrasodium ethylenediamine tetraacetate 0.3%;3 % of nonylphenol polyoxyethylene ether;0.5 % of isopropanol;Monoethylene glycol only son Ether 1%;Water surplus, the carbon deposit blow down agent by butyl acetate, butyl glycol ether, isopropanol and ethyl acetate the ratio between by weight For 10:4:4:4 compositions.
A kind of preparation method of cleaned and reduced dose of automobile three-element catalytics of above-described embodiment 1-3, includes the following steps:
1)Butyl acetate, butyl glycol ether, isopropanol and ethyl acetate are mixed evenly, carbon deposit is made and blows down agent;
2)Tetrasodium ethylenediamine tetraacetate, nonylphenol polyoxyethylene ether, isopropanol, monoethylene glycol monobutyl ether, water are mixed equal It is even, sodium hydroxide is slowly added to, is stirred evenly;
3)Carbon deposit is blown down into agent and adds in step 2)In, it stirs evenly.
The cleaning performance of ternary catalyzing unit cleaning agent is tested, test method is as follows:
Using Guangdong B365M vehicles Audi A62.0T as test vehicle, vehicle condition is:Vehicle travels 120,000 kilometers.
On the way normally travel, start to walk bad Acceleration, hundred kilometers of 13 liters of oil consumptions.After parking, ternary catalyzing unit is carried out Cleaning, method are:Ternary catalyzing unit together with lambda sensor is removed, the ternary catalyzing unit dismantled is placed in cleaning container; It sprays water to the carrier in ternary catalyzing unit, with 2 liters of water, carrier is made to fully absorb moisture;It it is prepared by 300ml embodiments 3 Cleaning agent add in manual watering can, after spraying 10ml cleaning agents to carrier top, stop 5 minutes, after carbon distribution softening, with can stretch The carbon distribution that the hairbrush that contracting rotates softens carrier top is purged, and after making the hole exposing of carrier, remaining 200ml is cleaned Agent is spurted into carrier, is retained 15 minutes;It is sprayed water with giant to carrier, remaining cleaning agent and waste liquid is thoroughly rushed It washes off.
Engine is closed, lambda sensor is installed.Continue to travel using the vehicle, any event does not occur for ternary catalyzing unit Barrier, fuel consumption per hundred kilometers decline 1.5 2 liters.
It is 4 carrier of Europe that the ternary catalyzing unit that test vehicle Audi A62.0T makees, which uses, mesh number 600, the discharge of national standard Standard is HC0.LCOl.0, NOx0.08.After tested, in the present embodiment, in return, the discharge HC0.08 of vehicle used, C00.08, NOx0.06.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art is in the technical scope of present disclosure, the change or replacement that can readily occur in, It should all be included within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection of claims Subject to scope.

Claims (5)

1. a kind of cleaned and reduced dose of automobile three-element catalytic, which is characterized in that consist of the following components in percentage by weight:Carbon deposit Blow down 5 % -10 % of agent;Sodium hydroxide 0.5%-1.5%;Tetrasodium ethylenediamine tetraacetate 0.3%-4.5%;Nonylphenol polyoxyethylene ether 0.1 %-3 %;0.5 %-4 % of isopropanol;0.5 %-1% of monoethylene glycol monobutyl ether;Water surplus.
2. cleaned and reduced dose of automobile three-element catalytic according to claim 1, which is characterized in that by following weight percent Component forms:Carbon deposit blows down 5 % -8% of agent;Sodium hydroxide 0.5%-1%;Tetrasodium ethylenediamine tetraacetate 0.3%-4%;Nonyl phenol gathers 0.5 %-2 % of ethylene oxide ether;0.5 %-2% of isopropanol;0.5 %-0.8% of monoethylene glycol monobutyl ether;Water surplus.
3. cleaned and reduced dose of automobile three-element catalytic according to claim 1 or 2, which is characterized in that the carbon deposit is blown down Agent is the mixing of butyl acetate, butyl glycol ether, isopropanol and ethyl acetate.
4. cleaned and reduced dose of automobile three-element catalytic according to claim 3, which is characterized in that butyl acetate, ethylene glycol fourth The weight ratio of ether, isopropanol and ethyl acetate is 10:4:4:4.
5. a kind of method prepared such as cleaned and reduced dose of claim 1-4 any one of them automobile three-element catalytic, feature exist In including the following steps:
1)Butyl acetate, butyl glycol ether, isopropanol and ethyl acetate are mixed evenly, carbon deposit is made and blows down agent;2)It will Tetrasodium ethylenediamine tetraacetate, nonylphenol polyoxyethylene ether, isopropanol, monoethylene glycol monobutyl ether, water are mixed evenly, and slowly add Enter sodium hydroxide, stir evenly;3)Carbon deposit is blown down into agent and adds in step 2)In, it stirs evenly.
CN201711412184.2A 2017-12-23 2017-12-23 A kind of cleaned and reduced dose of automobile three-element catalytic and preparation method thereof Withdrawn CN108060021A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711412184.2A CN108060021A (en) 2017-12-23 2017-12-23 A kind of cleaned and reduced dose of automobile three-element catalytic and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201711412184.2A CN108060021A (en) 2017-12-23 2017-12-23 A kind of cleaned and reduced dose of automobile three-element catalytic and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108837701A (en) * 2018-06-29 2018-11-20 河南妙天控股有限公司 A kind of purifying vehicle exhaust liquid and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108837701A (en) * 2018-06-29 2018-11-20 河南妙天控股有限公司 A kind of purifying vehicle exhaust liquid and preparation method thereof

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Application publication date: 20180522

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