CN108055854A - A kind of general color chips of emulsion-type - Google Patents
A kind of general color chips of emulsion-type Download PDFInfo
- Publication number
- CN108055854A CN108055854A CN201680027476.1A CN201680027476A CN108055854A CN 108055854 A CN108055854 A CN 108055854A CN 201680027476 A CN201680027476 A CN 201680027476A CN 108055854 A CN108055854 A CN 108055854A
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- Prior art keywords
- type
- emulsion
- color chips
- general color
- surfactant
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/52—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing synthetic macromolecular substances
- D06P1/5207—Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- D06P1/525—Polymers of unsaturated carboxylic acids or functional derivatives thereof
- D06P1/5257—(Meth)acrylic acid
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Developing Agents For Electrophotography (AREA)
- Paints Or Removers (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
Abstract
A kind of general color chips of emulsion-type is made of surfactant and 60~80% toner that mass percent is 20~40%, and the surfactant is formed by mass fraction for 60% 25 emulsifiers of AEO and 40% ammonium salt class dispersant.The color chips long shelf-life, applied widely, strong coloring force, technological process is simple, is carrier without the use of deionized water, production cost is low, will not cause environmental pollution.
Description
Technical field
The present invention relates to aqueous coloring field, more particularly to a kind of general color chips of emulsion-type.
Background technology
Oiliness color is used mostly due to being used for the coating on textile printing and dyestuff, synthetic leather material and building inside and outside wall
Slurry, however oil pastes are because the toxic gases such as its own volatile formaldehyde, azo cause environment certain destruction, to human body
With toxic.Therefore, it has been proposed that carrying out pigment coloration to weaving, synthetic leather using aqueous color paste.But currently on the market
Aqueous color paste, because its it is water base be difficult with various textiles, synthesis leather goods resinae blend, cause a kind of mill base can only
It paints to a kind of product, aqueous color paste is difficult to general, the interchangeability in various textiles, synthetic leather material and building inside and outside wall
Difference.And the waterborne general color paste manufactured using deionized water as matrix, solve the above problem to a certain extent.But because
Toner is not easy to disperse in deionized water solvent, therefore the toner content of existing deionized water solvent waterborne general color paste is not
Height, thus concentration property is not high, tinting strength, tinting power is also poor compared to oil pastes, particularly existing emulsion-type general color paste system,
Since it is desired that deionized water as base load thus have on color solid content upper physical limit, in storage time can not much longer easily make
It changes into its stability and rheological characteristic, is wrapped when transporting and using upper also because being liquid, transport inconvenience, and using
There is residual in dress, can cause environmental pollution, facilitate storage.
Therefore, how to realize one kind can steadily in the long term with various textiles, synthetic leather material and Discussion on architecture wall material
Material combines, strong coloring force and can be convenient for general color chips of emulsion-type and preparation method thereof of storage be urgently to be resolved hurrily in the industry
The technical issues of.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of general color chips of emulsion-type, and the color chips colorability is strong,
Stability is high and can place for a long time, applied widely, suitable for various leathers, textile, Discussion on architecture wall, transport and storage
It is convenient to hide, and will not cause secondary environmental pollution.
In order to solve the above-mentioned technical problem, the technical scheme is that, a kind of general color chips of emulsion-type, by quality
The surfactant and 60~80% toner composition that percentage is 20~40%.Wherein, surfactant is by following quality point
Several each components mix：
AEO-25 emulsifiers 60%
Ammonium salt class dispersant 40%
Preferably, ammonium salt class dispersant is selected from least one of ammonium polyacrylate dipersant, polycarboxylic acids ammonium salt dispersant.
A kind of method for making the general color chips of emulsion-type, comprises the steps of：
(1) surfactant and toner are added successively in kneading pot, and carries out tentatively being kneaded into colloid；
(2) above-mentioned colloid is subjected to high-speed kneading with kneader；
(3) after tilted back type three roll machine is heated to 125 DEG C, above-mentioned colloid is crossed into tilted back type three roll machine once, hot pressing is carried out and consolidates
Change, then place room temperature cooling, form color lump, the general color chips of emulsion-type can be obtained after color lump is crushed.
Using above-mentioned technical proposal, due to being combined using surfactant with colorant, the general color of emulsion-type is improved
The storage life of piece, and the scope of application for the color chips widened can be common in textile, synthetic leather material or building
Exterior wall, strong coloring force need to only pass through surfactant and colorant when being produced additionally, due to the general color chips of the emulsion-type
It mediates, cure, be carrier without the use of deionized water, technological process is simple, and production cost is low, and environment will not be caused dirty
Dye.
Specific embodiment
The specific embodiment of the present invention is described further below.It should be noted that for these implementations
The explanation of mode is used to help understand the present invention, but does not form limitation of the invention.In addition, invention described below
Involved technical characteristic can be combined with each other as long as they do not conflict with each other in each embodiment.
In the embodiment of the present invention, toner may be employed different colours and be tested, and can only be made using different toners
Into the difference of color, such as phthalocyanine blue toner, dark green toner, carbon black toner may be employed, different colors can't be to it
The characteristic of script has an impact, and in order to make to be comparable between different embodiment and comparative example, following embodiment, comparative example
Toner use carbon black toner.
Embodiment 1
A kind of general color chips of emulsion-type, by surfactant and 70% toner group of the mass percent for 30%
Into.Wherein, toner is carbon black toner, and surfactant is mixed by each component of following mass fraction：
AEO-25 emulsifiers 60%
Ammonium polyacrylate dipersant 40%.
A kind of method for making the general color chips of emulsion-type, comprises the steps of：
(1) surfactant, the carbon black mixed by emulsifier and ammonium polyacrylate salt is added successively in kneading pot
Toner, and carry out tentatively being kneaded into colloid；
(2) above-mentioned colloid is subjected to high-speed kneading with kneader；
(3) after tilted back type three roll machine is heated to 125 DEG C, above-mentioned colloid is crossed into tilted back type three roll machine once, hot pressing is carried out and consolidates
Change, then place room temperature cooling, form color lump, the general color chips of emulsion-type can be obtained after color lump is crushed.
Embodiment 2
A kind of general color chips of emulsion-type, by surfactant and 75% toner group of the mass percent for 25%
Into.Wherein, toner is carbon black toner, and surfactant is mixed by each component of following mass fraction：
AEO-25 emulsifiers 60%
Polycarboxylic acids ammonium salt dispersant 40%.
A kind of method for making the general color chips of emulsion-type, comprises the steps of：
(1) added successively in kneading pot formed by emulsifier and polycarboxylic acids ammonium salt dispersant surfactant,
Carbon black toner, and carry out tentatively being kneaded into colloid；
(2) above-mentioned colloid is subjected to high-speed kneading with kneader；
(3) after tilted back type three roll machine is heated to 125 DEG C, above-mentioned colloid is crossed into tilted back type three roll machine once, hot pressing is carried out and consolidates
Change, then place room temperature cooling, form color lump, the general color chips of emulsion-type can be obtained after color lump is crushed.
Embodiment 3
A kind of general color chips of emulsion-type, by surfactant and 80% toner group of the mass percent for 20%
Into.Wherein, toner is carbon black toner, and surfactant is mixed by each component of following mass fraction：
AEO-25 emulsifiers 60%
Polycarboxylic acids ammonium salt dispersant 40%.
A kind of method for making the general color chips of emulsion-type, comprises the steps of：
(1) added successively in kneading pot formed by emulsifier and polycarboxylic acids ammonium salt dispersant surfactant,
Carbon black toner, and carry out tentatively being kneaded into colloid；
(2) above-mentioned colloid is subjected to high-speed kneading with kneader；
(3) after tilted back type three roll machine is heated to 125 DEG C, above-mentioned colloid is crossed into tilted back type three roll machine once, hot pressing is carried out and consolidates
Change, then place room temperature cooling, form color lump, the general color chips of emulsion-type can be obtained after color lump is crushed.
Embodiment 4
A kind of general color chips of emulsion-type, by surfactant and 60% toner group of the mass percent for 40%
Into.Wherein, toner is carbon black toner, and surfactant is mixed by each component of following mass fraction：
AEO-25 emulsifiers 60%
Ammonium polyacrylate dipersant 40%.
A kind of method for making the general color chips of emulsion-type, comprises the steps of：
(1) surface-active formed by emulsifier and ammonium polyacrylate salt dispersant is added successively in kneading pot
Agent, carbon black toner, and carry out tentatively being kneaded into colloid；
(2) above-mentioned colloid is subjected to high-speed kneading with kneader；
(3) after tilted back type three roll machine is heated to 125 DEG C, above-mentioned colloid is crossed into tilted back type three roll machine once, hot pressing is carried out and consolidates
Change, then place room temperature cooling, form color lump, the general color chips of emulsion-type can be obtained after above-mentioned color lump is crushed.
Comparative example
At present, traditional color chips is made of the raw material of following mass fraction：1250~5600 parts of carbon black toner；Styrene-the third
2100~3700 parts of olefin(e) acid resin；300 parts of ethanolamine；5000 parts of water.During preparation, each original is weighed by above-mentioned mass fraction first
Material；Then styrene-acrylic resins, ethanolamine and water are poured into the material cylinder of ball mill, grinds 5~20 minutes, fill it
Lotion is made in the mixed dissolution divided；Then primary colors powder is poured into material cylinder, using ball mill grinding 2~2.5 it is small when disperse, make
Lotion is sufficiently mixed with primary colors powder, and slurry is made；Finally, slurry using drying machine is dried, obtains the water of solid
Property color chips.
When above example and comparative example are tested, test formulations that tinting strength, tinting power, dispersiveness and viscosity use for：
60g deionized waters add 40g color chips, while use commercially available laboratory high speed dispersor (model：KFS-400W) with speed
4000RPM carry out scattered 2 it is small when, last test result is as follows：
Tinting strength, tinting power is also known as tinctorial strength, refers to a certain pigment forms color power ability after being mixed with benchmark pigment,
Color power assay method is usually taken compared with standard sample, is determined, is expressed as a percentage with its difference ratio.
Dispersiveness is mainly filtered with 1000 mesh filter screens, its dispersed height is compared by determining whether there is residue.
Embodiments of the present invention are explained in detail above, but the invention is not restricted to described embodiments.It is right
For those skilled in the art, in the case where not departing from the principle of the invention and spirit, these embodiments are carried out more
Kind change, modification, replacement and modification, still fall in protection scope of the present invention.
Claims (3)
1. a kind of general color chips of emulsion-type, which is characterized in that by mass percent be 20~40% surfactant and
60~80% toner composition, the surfactant are mixed by each component of following mass fraction：
AEO-25 emulsifiers 60%
Ammonium salt class dispersant 40%
2. the general color chips of emulsion-type according to claim 1, which is characterized in that ammonium salt class dispersant is selected from polyacrylic acid
At least one of ammonium salt dispersant, polycarboxylic acids ammonium salt dispersant.
A kind of 3. method for making the general color chips of the emulsion-type of claim 1 or 2, which is characterized in that include following step
Suddenly：
(1) surfactant and toner are added successively in kneading pot, and carries out tentatively being kneaded into colloid；
(2) above-mentioned colloid is subjected to high-speed kneading with kneader；
(3) after tilted back type three roll machine is heated to 125 DEG C, above-mentioned colloid is crossed into tilted back type three roll machine once, carries out hot-press solidifying, then
Room temperature cooling is placed, forms color lump, the general color chips of emulsion-type can be obtained after above-mentioned color lump is crushed.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2016/091683 WO2018018400A1 (en) | 2016-07-26 | 2016-07-26 | Emulsion type water-based universal color sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108055854A true CN108055854A (en) | 2018-05-18 |
Family
ID=61015262
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680027476.1A Pending CN108055854A (en) | 2016-07-26 | 2016-07-26 | A kind of general color chips of emulsion-type |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN108055854A (en) |
| WO (1) | WO2018018400A1 (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090326132A1 (en) * | 2003-10-14 | 2009-12-31 | National Chung-Hsing University | Nanosilicate plates |
| CN101709185A (en) * | 2009-12-17 | 2010-05-19 | 浙江瑞克涂饰材料有限公司 | Waterborne general color paste and preparation method thereof |
| CN101760085A (en) * | 2009-03-23 | 2010-06-30 | 昆山市世名科技开发有限公司 | Inorganic pigment color paste and preparing method thereof |
| CN102002867A (en) * | 2010-11-24 | 2011-04-06 | 浙江深蓝轻纺科技有限公司 | Environmentally-friendly solid state colorant applied to synthetic leather dry method and preparation method thereof |
| CN102206360A (en) * | 2011-03-31 | 2011-10-05 | 佛山市顺德区天隆颜料有限公司 | Water-based color chip for artificial leather and preparation method thereof |
| CN102766352A (en) * | 2012-08-01 | 2012-11-07 | 广州保亮得塑料科技有限公司 | Preparation method and system of toner pre-dispersing material |
| CN105111784A (en) * | 2015-09-28 | 2015-12-02 | 温州金源化工有限公司 | Preparation method of high-performance pigment blue 60 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1100445A (en) * | 1994-04-28 | 1995-03-22 | 华东理工大学 | Preparation method for particulate pigment and its special composite assistants |
| MX2007011299A (en) * | 2005-03-18 | 2007-10-05 | Valspar Sourcing Inc | Low voc universal paint colorant compositions. |
| US9221984B2 (en) * | 2010-07-16 | 2015-12-29 | E I Du Pont De Nemours And Company | Cross-linked pigment dispersion based on polyurethane dispersants |
| CN101942770A (en) * | 2010-08-19 | 2011-01-12 | 苏州世名科技股份有限公司 | Ecotypic liquid pigment for synthetic leather and preparation method thereof |
| CN103773114B (en) * | 2014-01-11 | 2016-01-20 | 江门骅弘颜料有限公司 | A kind of waterborne general color paste and preparation method thereof |
-
2016
- 2016-07-26 WO PCT/CN2016/091683 patent/WO2018018400A1/en active Application Filing
- 2016-07-26 CN CN201680027476.1A patent/CN108055854A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090326132A1 (en) * | 2003-10-14 | 2009-12-31 | National Chung-Hsing University | Nanosilicate plates |
| CN101760085A (en) * | 2009-03-23 | 2010-06-30 | 昆山市世名科技开发有限公司 | Inorganic pigment color paste and preparing method thereof |
| CN101709185A (en) * | 2009-12-17 | 2010-05-19 | 浙江瑞克涂饰材料有限公司 | Waterborne general color paste and preparation method thereof |
| CN102002867A (en) * | 2010-11-24 | 2011-04-06 | 浙江深蓝轻纺科技有限公司 | Environmentally-friendly solid state colorant applied to synthetic leather dry method and preparation method thereof |
| CN102206360A (en) * | 2011-03-31 | 2011-10-05 | 佛山市顺德区天隆颜料有限公司 | Water-based color chip for artificial leather and preparation method thereof |
| CN102766352A (en) * | 2012-08-01 | 2012-11-07 | 广州保亮得塑料科技有限公司 | Preparation method and system of toner pre-dispersing material |
| CN105111784A (en) * | 2015-09-28 | 2015-12-02 | 温州金源化工有限公司 | Preparation method of high-performance pigment blue 60 |
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| Publication number | Publication date |
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| WO2018018400A1 (en) | 2018-02-01 |
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Application publication date: 20180518 |
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