CN108049174A - Excellent temperature sensitive intelligent textile material of a kind of dyeability and preparation method thereof - Google Patents
Excellent temperature sensitive intelligent textile material of a kind of dyeability and preparation method thereof Download PDFInfo
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- CN108049174A CN108049174A CN201711178833.7A CN201711178833A CN108049174A CN 108049174 A CN108049174 A CN 108049174A CN 201711178833 A CN201711178833 A CN 201711178833A CN 108049174 A CN108049174 A CN 108049174A
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- temperature sensitive
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- textile material
- cotton fabric
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M14/00—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials
- D06M14/18—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation
- D06M14/20—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin
- D06M14/22—Graft polymerisation of monomers containing carbon-to-carbon unsaturated bonds on to fibres, threads, yarns, fabrics, or fibrous goods made from such materials using wave energy or particle radiation on to materials of natural origin of vegetal origin, e.g. cellulose or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
- D06M13/21—Halogenated carboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
- D06P5/225—Aminalization of cellulose; introducing aminogroups into cellulose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
Abstract
The invention discloses a kind of excellent temperature sensitive intelligent textile material of dyeability, preparation arranges cotton fabric first with amino silicon oil emulsion, and active group amido is introduced in fabric surface；Afterwards using ethylenediamine and methyl acrylate as Material synthesis end group be four amidos dendritic macromole, it is mixed and the reaction of 2 bromine isobutyl acylbromides with the cotton fabric after collated, introduce initiator, trigger the atom transfer radical polymerization of temperature sensitive monomer N N-isopropylacrylamides, temperature sensitive polymer is introduced in surface of cotton fabric, has prepared the textile material with temperature sensitive effect.The present invention contains on temperature sensitive textile material surface a large amount of active amido, imino groups, and protonation or deprotonation can occur so as to change the charge density on its surface, realize the absorption to oppositely charged dye molecule, improve the dyeability of textile material.
Description
Technical field
The present invention relates to a kind of temperature sensing material fields, and in particular to a kind of excellent temperature sensitive intelligent textile material of dyeability
And preparation method thereof.
Background technology
In recent years, scientific worker has carried out a series of research to stimuli responsive type material, and environmental stimuli is because being known as：Temperature
Degree, pH value, light, ionic strength, electricity, magnetic field, ultrasound, enzymatic activity etc..In this environmental response sexual system, temperature sensitive polymeric
Object can be easily applied to the multiple fields such as biology, medicine, detection, meanwhile, the variation of ambient temperature is easily controlled again, because
This temperature is increasingly becoming most widely used irritation signal.At the same time, the species of temperature sensitive polymer is also very more.Such as poly- N-
N-isopropylacrylamide, polyvinyl alcohol-vinyl acetate copolymer, polyvinylether and polyethers and polypeptide and artificial polyaminoacid
Temperature sensitive polymer etc..
Using plasma technique in surface of cotton fabric graft N-N-isopropylacrylamide (PNIPAAm), when temperature is less than
During lowest critical solution temperature (LCST), hydrogen bond is formed between the PNIPAAm macromoleculars being grafted on hydrone and cotton fabric, is polymerize
Object volume sweell(ing), the intertexture hole of cotton fabric is shielded or blocks, and moisture can not penetrate；Conversely, when temperature is higher than LCST, gather
It closes object to shrink, the intertexture hole of fabric opens, and moisture can pass through, it is achieved thereby that adjusting the air-moisture-permeable of fabric with temperature
Property.
Compared with traditional line style temperature sensitive polymer, the tree-like temperature with compact spherical or spherical structure emerging at present
The lower critical solution temperature of quick macromolecule and hyperbranched temperature sensitive polymer is more sensitive to the variation of self structure and external environment.Cause
This, it is contemplated that line style temperature sensitive polymer can be filled up or improved to tree-like temperature sensitive macromolecule and hyperbranched temperature sensitive polymer not
Foot.
The content of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of excellent temperature sensitive intelligent textile material of dyeability and its system
Preparation Method.
A kind of excellent temperature sensitive intelligent textile material of dyeability, prepares first with amino silicon oil emulsion to cotton fabric
It is arranged, active group amido is introduced in fabric surface；The end using ethylenediamine and methyl acrylate as Material synthesis afterwards
Base is the dendritic macromole of four amidos, is mixed and the reaction of 2- bromine isobutyl acylbromides, introducing initiation with the cotton fabric after collated
Agent triggers the atom transfer radical polymerization of temperature sensitive monomer n-isopropyl acrylamide, is introduced in surface of cotton fabric temperature sensitive poly-
Object is closed, has prepared the textile material with temperature sensitive effect.
It is as follows：
（1）The preparation of amino silicon oil emulsion：
First plus 5-12 parts of dye leveller O-20 are in beaker, are placed in 35-45 DEG C of water-bath and dissolve, and then add in 18-33 parts of ammonia
OFX-8822 and 8-18 parts of Emulsifier MOA -3 of base silicone oil add in 50-80 parts of acetums, fully after being sufficiently stirred 8-15 minutes
Stirring 10-15 minutes, then 20-30 parts of acetums are slowly added dropwise, continue stirring 8-15 minutes after being added dropwise, finally cut with height
Dispersion emulsifying machine is cut with rotating speed cutting 15-25 minutes of 3000r/min, obtains amino silicon oil emulsion；
（2）Above-mentioned amino silicon oil emulsion is configured to the dressing liquid that mass concentration is 6g/L, according to bath raio 1：50 soak cotton fabric
Enter in dressing liquid and impregnate 1-5 minutes, under 80% pick-up rate, an immersing and rolling, in 75-85 DEG C of preliminary drying 3-8 minutes, 120-140 DEG C of roasting
It is taken out after drying 1-2 minutes spare；
（3）Hold the synthesis of amido dendritic macromole：
1., 3-6 parts by weight ethylenediamines are added in the three-necked bottle with magnetic stir bar, reflux condensing tube and thermometer, with
Ethylenediamine and methyl acrylate mol ratio are 1:8 amount adds in methyl acrylate and 15-20 parts of methanol, is uniformly mixed,
Be stirred to react at 20-30 DEG C 5-7 it is small when, vacuum distillation, obtain weak yellow liquid；
2., will be added sequentially in above-mentioned weak yellow liquid with 15-20 parts of methanol, 35-50 parts of ethylenediamines in three-necked bottle, stirring is mixed
Close it is uniform, be stirred to react at 20-30 DEG C 20-26 it is small when, vacuum distillation obtains pale yellow transparent viscous liquid product；
（4）Graft initiator：
By step（2）Cotton fabric after collated is placed in reaction bulb, adds in 180-300 parts of dichloromethane, 18-23 parts of triethylamines
With step（3）The end amido dendritic macromole of synthesis, it is after mixing, slow with constant pressure funnel under the conditions of ice-water bath
The dichloromethane solution of 16-24 parts of 2- bromo isobutyl acylbromides is instilled, after being stirred to react 50-60 minutes under nitrogen protection, then at
When reaction 10-15 is small under room temperature, cotton fabric is taken out after reaction, is washed repeatedly 3 times with dichloromethane and deionized water, in
55-65 DEG C of drying；
（5）Polymerisation：
14-21 parts of pentamethyl-diethylenetriamines are dissolved into the mixed solution of 160-250 parts of methanol and water, then add in 2-5
Part cuprous bromide, it is to be dissolved completely after add 30-50 part n-isopropyl acrylamide, with polymeric solution, afterwards input walk
Suddenly（4）The product of initiator is connected to, with Bubbling method nitrogen charging deoxygenation 40-60 minutes after sealing, when 55-65 DEG C of reaction 6-8 is small, is taken out
Cotton fabric is washed with deionized 3-5 times, in 55-65 DEG C of drying to get temperature sensitive textile.
Wherein, the step（1）Middle acetum concentration is 1%.
Wherein, the step（4）The dichloromethane solution of middle 2- bromos isobutyl acylbromide refers to 2- bromo isobutyl acylbromides is molten
In dichloromethane, concentration 4%.
Wherein, the step（5）Both the mixed solution of middle methanol and water volume ratios are 3:1.
Compared with prior art, the present invention has the following advantages：
（1）Invention arranges amido silicon oil to surface of cotton fabric, amido silicon oil macromolecular by hydrophobic interaction,
The effects that hydrogen bond, is very strongly orientated and is adsorbed onto on fiber, introduces amine groups in surface of cotton fabric, improves fabric
Softness contains with end group reacted there are four the mixing of the dendritic macromole of amido with 2- bromine isobutyl acylbromides afterwards, introduces atom
The initiator of transition free radical polymerization reaction triggers temperature sensitive monomer n-isopropyl acrylamide to make it in surface of cotton fabric polymerization
With temperature sensitive outer layer, while amine dendrimer is introduced, make textile material combination amine dendrimer and temperature sensitive polymer of the present invention
Excellent performance has good breathable moisture permeability, water-proof function.
（2）The temperature sensitive textile material surface of the present invention introduces end amido dendritic macromole, lives on branch containing a large amount of
Amido, imino group are sprinkled, not only there is higher reactivity, but also since many dye molecules contain negatively charged sulphur
Acid group can make the textile material surface of amino-contained that protonation or deprotonation occur so as to change by the pH value for adjusting absorption environment
Become the charge density on its surface, realize the absorption to oppositely charged dye molecule, the dyeability of textile material is excellent.
Specific embodiment
A kind of excellent temperature sensitive intelligent textile material of dyeability, prepares first with amino silicon oil emulsion to cotton fabric
It is arranged, active group amido is introduced in fabric surface；The end using ethylenediamine and methyl acrylate as Material synthesis afterwards
Base is the dendritic macromole of four amidos, is mixed and the reaction of 2- bromine isobutyl acylbromides, introducing initiation with the cotton fabric after collated
Agent triggers the atom transfer radical polymerization of temperature sensitive monomer n-isopropyl acrylamide, is introduced in surface of cotton fabric temperature sensitive poly-
Object is closed, has prepared the textile material with temperature sensitive effect.
It is as follows：
（1）The preparation of amino silicon oil emulsion：
First plus 8 parts of dye leveller O-20 are in beaker, are placed in 40 DEG C of water-bath and dissolve, and then add in 23 parts of amido silicon oil OFX-
8822 and 11 Emulsifier MOA -3 are sufficiently stirred 60 parts of acetums of addition after ten minutes, are sufficiently stirred 12 minutes, then slowly drop
Add 25 parts of acetums, continue stirring 10 minutes after being added dropwise, finally turned with high-shearing dispersion emulsifying machine with 3000r/min
Speed shearing 20 minutes, obtains amino silicon oil emulsion；
（2）Above-mentioned amino silicon oil emulsion is configured to the dressing liquid that mass concentration is 6g/L, according to bath raio 1：50 soak cotton fabric
Enter in dressing liquid and impregnate 3 minutes, under 80% pick-up rate, an immersing and rolling, in 80 DEG C of preliminary dryings 5 minutes, 130 DEG C bake 1 minute after take
Go out spare；
（3）Hold the synthesis of amido dendritic macromole：
1., 5 parts by weight ethylenediamines are added in the three-necked bottle with magnetic stir bar, reflux condensing tube and thermometer, with second
Diamines and methyl acrylate mol ratio are 1:8 amount adds in methyl acrylate and 18 parts of methanol, is uniformly mixed, in 25 DEG C
Under be stirred to react 6 it is small when, vacuum distillation, obtain weak yellow liquid；
2., will be added sequentially in above-mentioned weak yellow liquid with 18 parts of methanol, 40 parts of ethylenediamines in three-necked bottle, be stirred
It is even, be stirred to react at 25 DEG C 24 it is small when, vacuum distillation, obtain pale yellow transparent viscous liquid product；
（4）Graft initiator：
By step（2）Cotton fabric after collated is placed in reaction bulb, adds in 210 parts of dichloromethane, 21 parts of triethylamines and step
（3）The end amido dendritic macromole of synthesis, after mixing, 20 is slowly dropped under the conditions of ice-water bath with constant pressure funnel
The dichloromethane solution of part 2- bromo isobutyl acylbromides, after being stirred to react 55 minutes under nitrogen protection, reacts 12 under room temperature
Hour, cotton fabric is taken out after reaction, is washed repeatedly 3 times with dichloromethane and deionized water, in 60 DEG C of drying；
（5）Polymerisation：
17 parts of pentamethyl-diethylenetriamines are dissolved into the mixed solution of 210 parts of methanol and water, then add in 3 parts of protobromides
Copper, it is to be dissolved completely after add 40 parts of n-isopropyl acrylamide, with polymeric solution, put into step afterwards（4）It is connected to and draws
The product of agent is sent out, with Bubbling method nitrogen charging deoxygenation 50 minutes after sealing, when 60 DEG C of reactions 8 are small, cotton fabric taken out, is washed with deionized water
It washs 4 times, in 60 DEG C of drying to get temperature sensitive textile.
Wherein, the step（1）Middle acetum concentration is 1%.
Wherein, the step（4）The dichloromethane solution of middle 2- bromos isobutyl acylbromide refers to 2- bromo isobutyl acylbromides is molten
In dichloromethane, concentration 4%.
Wherein, the step（5）Both the mixed solution of middle methanol and water volume ratios are 3:1.
Claims (5)
1. the excellent temperature sensitive intelligent textile material of a kind of dyeability, which is characterized in that it is prepared first with amido silicon oil breast
Liquid arranges cotton fabric, and active group amido is introduced in fabric surface；Afterwards using ethylenediamine and methyl acrylate as original
Material has synthesized dendritic macromole of the end group for four amidos, with it is collated after cotton fabric mix it is anti-with 2- bromine isobutyl acylbromides
Should, initiator is introduced, triggers the atom transfer radical polymerization of temperature sensitive monomer n-isopropyl acrylamide, in surface of cotton fabric
Temperature sensitive polymer is introduced, has prepared the textile material with temperature sensitive effect.
2. a kind of preparation method of the excellent temperature sensitive intelligent textile material of dyeability according to claims 1, special
Sign is, is as follows：
（1）The preparation of amino silicon oil emulsion：
First plus 5-12 parts of dye leveller O-20 are in beaker, are placed in 35-45 DEG C of water-bath and dissolve, and then add in 18-33 parts of ammonia
OFX-8822 and 8-18 parts of Emulsifier MOA -3 of base silicone oil add in 50-80 parts of acetums, fully after being sufficiently stirred 8-15 minutes
Stirring 10-15 minutes, then 20-30 parts of acetums are slowly added dropwise, continue stirring 8-15 minutes after being added dropwise, finally cut with height
Dispersion emulsifying machine is cut with rotating speed cutting 15-25 minutes of 3000r/min, obtains amino silicon oil emulsion；
（2）Above-mentioned amino silicon oil emulsion is configured to the dressing liquid that mass concentration is 6g/L, according to bath raio 1：50 soak cotton fabric
Enter in dressing liquid and impregnate 1-5 minutes, under 80% pick-up rate, an immersing and rolling, in 75-85 DEG C of preliminary drying 3-8 minutes, 120-140 DEG C of roasting
It is taken out after drying 1-2 minutes spare；
（3）Hold the synthesis of amido dendritic macromole：
1., 3-6 parts by weight ethylenediamines are added in the three-necked bottle with magnetic stir bar, reflux condensing tube and thermometer, with
Ethylenediamine and methyl acrylate mol ratio are 1:8 amount adds in methyl acrylate and 15-20 parts of methanol, is uniformly mixed,
Be stirred to react at 20-30 DEG C 5-7 it is small when, vacuum distillation, obtain weak yellow liquid；
2., will be added sequentially in above-mentioned weak yellow liquid with 15-20 parts of methanol, 35-50 parts of ethylenediamines in three-necked bottle, stirring is mixed
Close it is uniform, be stirred to react at 20-30 DEG C 20-26 it is small when, vacuum distillation obtains pale yellow transparent viscous liquid product；
（4）Graft initiator：
By step（2）Cotton fabric after collated is placed in reaction bulb, adds in 180-300 parts of dichloromethane, 18-23 parts of triethylamines
With step（3）The end amido dendritic macromole of synthesis, it is after mixing, slow with constant pressure funnel under the conditions of ice-water bath
The dichloromethane solution of 16-24 parts of 2- bromo isobutyl acylbromides is instilled, after being stirred to react 50-60 minutes under nitrogen protection, then at
When reaction 10-15 is small under room temperature, cotton fabric is taken out after reaction, is washed repeatedly 3 times with dichloromethane and deionized water, in
55-65 DEG C of drying；
（5）Polymerisation：
14-21 parts of pentamethyl-diethylenetriamines are dissolved into the mixed solution of 160-250 parts of methanol and water, then add in 2-5
Part cuprous bromide, it is to be dissolved completely after add 30-50 part n-isopropyl acrylamide, with polymeric solution, afterwards input walk
Suddenly（4）The product of initiator is connected to, with Bubbling method nitrogen charging deoxygenation 40-60 minutes after sealing, when 55-65 DEG C of reaction 6-8 is small, is taken out
Cotton fabric is washed with deionized 3-5 times, in 55-65 DEG C of drying to get temperature sensitive textile.
3. a kind of preparation method of the excellent temperature sensitive intelligent textile material of dyeability according to claims 2, special
Sign is, the step（1）Middle acetum concentration is 1%.
4. a kind of preparation method of the excellent temperature sensitive intelligent textile material of dyeability according to claims 2, special
Sign is, the step（4）The dichloromethane solution of middle 2- bromos isobutyl acylbromide refers to 2- bromo isobutyl acylbromides being dissolved in dichloro
In methane, concentration 4%.
5. a kind of preparation method of the excellent temperature sensitive intelligent textile material of dyeability according to claims 2, special
Sign is, the step（5）Both the mixed solution of middle methanol and water volume ratios are 3:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201711178833.7A CN108049174A (en) | 2017-11-23 | 2017-11-23 | Excellent temperature sensitive intelligent textile material of a kind of dyeability and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711178833.7A CN108049174A (en) | 2017-11-23 | 2017-11-23 | Excellent temperature sensitive intelligent textile material of a kind of dyeability and preparation method thereof |
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| CN108049174A true CN108049174A (en) | 2018-05-18 |
Family
ID=62120248
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115322789A (en) * | 2022-07-11 | 2022-11-11 | 杭州临安灵丰农业科技有限公司 | Soil conditioner for preventing and treating soil hardening and preparation method thereof |
| CN116657289A (en) * | 2023-08-01 | 2023-08-29 | 江苏恒力化纤股份有限公司 | Preparation method of thermosensitive polyester yarns |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1600149A1 (en) * | 2004-05-28 | 2005-11-30 | L'oreal | Dyeing composition for keratin fibers comprising a pigment and polymers which are able to react with each other by forming covalent bonds |
| CN107261868A (en) * | 2017-06-28 | 2017-10-20 | 安庆师范大学 | A kind of temperature sensitive type amphipathic nature polyalcohol is modified paper substrate filter membrane and preparation method thereof |
| CN107312137A (en) * | 2017-06-28 | 2017-11-03 | 安庆师范大学 | A kind of nano-cellulose base dendritic macromole temperature sensing material and preparation method thereof |
-
2017
- 2017-11-23 CN CN201711178833.7A patent/CN108049174A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1600149A1 (en) * | 2004-05-28 | 2005-11-30 | L'oreal | Dyeing composition for keratin fibers comprising a pigment and polymers which are able to react with each other by forming covalent bonds |
| CN107261868A (en) * | 2017-06-28 | 2017-10-20 | 安庆师范大学 | A kind of temperature sensitive type amphipathic nature polyalcohol is modified paper substrate filter membrane and preparation method thereof |
| CN107312137A (en) * | 2017-06-28 | 2017-11-03 | 安庆师范大学 | A kind of nano-cellulose base dendritic macromole temperature sensing material and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115322789A (en) * | 2022-07-11 | 2022-11-11 | 杭州临安灵丰农业科技有限公司 | Soil conditioner for preventing and treating soil hardening and preparation method thereof |
| CN116657289A (en) * | 2023-08-01 | 2023-08-29 | 江苏恒力化纤股份有限公司 | Preparation method of thermosensitive polyester yarns |
| CN116657289B (en) * | 2023-08-01 | 2023-11-24 | 江苏恒力化纤股份有限公司 | Preparation method of thermosensitive polyester yarns |
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