CN108047783A - A kind of preparation method of the corrosion-resistant batch can of fertilizer applicator - Google Patents
A kind of preparation method of the corrosion-resistant batch can of fertilizer applicator Download PDFInfo
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- CN108047783A CN108047783A CN201711409778.8A CN201711409778A CN108047783A CN 108047783 A CN108047783 A CN 108047783A CN 201711409778 A CN201711409778 A CN 201711409778A CN 108047783 A CN108047783 A CN 108047783A
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- parts
- batch
- corrosion
- fertilizer applicator
- resistant
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Fertilizers (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention discloses a kind of preparation method of the corrosion-resistant batch can of fertilizer applicator, including following operating procedure：（1）It will prepare after molding batch can cleans up, surface carries out grinding process using 1000# sand paper, the sulfuric acid solution for being then 5% in its surfaces externally and internally sprinkling mass fraction；（2）After 25 30min, by step（1）The batch can surfaces externally and internally of processing is uniformly brushed on corrosion resistant coating, then being put into batch can in baking oven, after drying and processing, finished product.A kind of preparation method of the corrosion-resistant batch can of fertilizer applicator provided by the invention, operating procedure is stablized, it is environmentally protective, corrosion resistant coating obtained, the paint film formed after drying, with excellent resistance to bubble, corrosion-resistant and oxidation resistent susceptibility, the service life of fertilizer applicator batch can is effectively extended, prevents it the rust on occurring during use and leakage the phenomenon that.
Description
Technical field
The invention belongs to fertilizer applicator manufacturing technology fields, and in particular to a kind of preparation method of the corrosion-resistant batch can of fertilizer applicator.
Background technology
Fertilizer applicator is the farm machinery generally used in modern agriculture, original manual watering can be replaced to apply fertilizer, liberation
While labour, the efficiency of fertilising is improved, shortens the time applied fertilizer.Wherein, the batch can of fertilizer applicator is in fertilizer applicator
One important component is the place for storing liquid fertilizer or solid fertilizer, but fertilizer applicator batch can of the prior art,
Corrosion resistance is poor, in use, it is easy to be corroded by fertilizer, and then the phenomenon that serious upper rust occurs, shorten
The service life of fertilizer applicator.
The content of the invention
In order to solve the above technical problem, the present invention provides a kind of preparation methods of the corrosion-resistant batch can of fertilizer applicator.
The present invention is achieved by the following technical solutions.
A kind of preparation method of the corrosion-resistant batch can of fertilizer applicator, including following operating procedure：
（1）It will prepare after molding batch can cleans up, surface carries out grinding process using 1000# sand paper, then inside and outside it
The sulfuric acid solution that surface sprinkling mass fraction is 5%；
（2）After 25-30min, by step（1）The batch can surfaces externally and internally of processing is uniformly brushed on corrosion-resistant painting
Material, then being put into batch can in baking oven, after drying and processing, finished product, wherein corrosion resistant coating by following parts by weight group
Divide and be made：35-44 parts of methyl methacrylates, 17-20 parts of ethylene glycol dimethacrylate, 14-18 parts of methacrylic acid rings
Three ethoxy silane of oxygen propyl ester, 4-8 part vinyl, 6-10 parts of 4- halogen trimethylsilylbenzenes ethylene, 1-3 parts of initiators, 17-22 parts go from
Sub- water, 9-11 part tetrabromo-bisphenol s, 14-18 parts of salicylanilides, 22-26 parts of color stuffings, 4-7 parts of auxiliary agents.
Specifically, above-mentioned steps（1）In, the fountain height of 5% sulfuric acid solution is 250-300g/m2。
Specifically, above-mentioned steps（2）In, corrosion resistant coating is made of following methods：By methyl methacrylate, diformazan
Base acrylic acid glycol ester, glycidyl methacrylate, three ethoxy silane of vinyl, 4- halogen trimethylsilylbenzenes ethylene, initiation
Agent and deionized water after mixing, after being heated to 80-85 DEG C, when isothermal holding 4-5 is small after, it is double then to add in tetrabromo thereto
After mixing, corrosion resistant coating is made in phenol S, salicylanilide, color stuffing, auxiliary agent.
Specifically, the color stuffing is calcium carbonate and kaolin according to 1:1 mass ratio is mixed, the auxiliary agent by with
The component of lower parts by weight is made：1-3 parts of dimethyl silicone polymer, 2-4 parts of TEGODispers685 wetting dispersing agents, lauryl alcohol ester
6-8 parts.
From the above technical scheme, it can be seen that the beneficial effects of the invention are as follows：
A kind of preparation method of the corrosion-resistant batch can of fertilizer applicator provided by the invention, operating procedure is stablized, environmentally protective, obtained resistance to
Etching ground, the paint film formed after dry have excellent resistance to bubble, corrosion-resistant and oxidation resistent susceptibility, effectively extend
The service life of fertilizer applicator batch can prevents its rust and the phenomenon that leakage on occurring during use.Wherein, the present invention provides
Corrosion resistant coating, three ethoxy silane of vinyl and 4- halogen trimethylsilylbenzenes ethylene synergistic effect after, can effectively promote paint film
Compactness, the phenomenon that effectively can preventing fertilizer from being permeated in paint film；Tetrabromo-bisphenol s and salicylanilide are in paint film
It is strong with film forming matter combination power, be not susceptible to be precipitated the phenomenon that, meanwhile, the two synergistic effect after, can be effectively corrosive
Fertilizer causes the strand in paint film the phenomenon that degradation, and then the effective corrosion resistance for improving paint film.
Specific embodiment
Below by specific embodiment, the present invention is described in detail, but the purposes of these illustrative embodiments and
Purpose is only used for enumerating the present invention, not forms any type of any restriction to the real protection scope of the present invention, more non-to incite somebody to action
Protection scope of the present invention is confined to this.
Embodiment 1
A kind of preparation method of the corrosion-resistant batch can of fertilizer applicator, including following operating procedure：
（1）It will prepare after molding batch can cleans up, surface carries out grinding process using 1000# sand paper, then inside and outside it
The sulfuric acid solution that surface sprinkling mass fraction is 5%；
（2）After 25min, by step（1）The batch can surfaces externally and internally of processing is uniformly brushed on corrosion resistant coating, so
Being put into batch can in baking oven afterwards, after drying and processing, finished product, wherein corrosion resistant coating by following parts by weight component system
Into：35 parts of methyl methacrylates, 17 parts of ethylene glycol dimethacrylate, 14 parts of glycidyl methacrylate, 4 parts of ethylene
Three ethoxy silane of base, 6 parts of 4- halogen trimethylsilylbenzenes ethylene, 1 part of initiator, 17 parts of deionized waters, 9 parts of tetrabromo-bisphenol s, 14 parts of water
Poplar anilide, 22 parts of color stuffings, 4 parts of auxiliary agents.
Specifically, above-mentioned steps（1）In, the fountain height of 5% sulfuric acid solution is 250g/m2。
Specifically, above-mentioned steps（2）In, corrosion resistant coating is made of following methods：By methyl methacrylate, diformazan
Base acrylic acid glycol ester, glycidyl methacrylate, three ethoxy silane of vinyl, 4- halogen trimethylsilylbenzenes ethylene, initiation
Agent and deionized water after mixing, after being heated to 80 DEG C, when isothermal holding 4 is small after, then thereto add in tetrabromo-bisphenol s,
After mixing, corrosion resistant coating is made in salicylanilide, color stuffing, auxiliary agent.
Specifically, the color stuffing is calcium carbonate and kaolin according to 1:1 mass ratio is mixed, the auxiliary agent by with
The component of lower parts by weight is made：1 part of dimethyl silicone polymer, 2 parts of TEGODispers685 wetting dispersing agents, 6 parts of lauryl alcohol ester.
Embodiment 2
A kind of preparation method of the corrosion-resistant batch can of fertilizer applicator, including following operating procedure：
（1）It will prepare after molding batch can cleans up, surface carries out grinding process using 1000# sand paper, then inside and outside it
The sulfuric acid solution that surface sprinkling mass fraction is 5%；
（2）After 28min, by step（1）The batch can surfaces externally and internally of processing is uniformly brushed on corrosion resistant coating, so
Being put into batch can in baking oven afterwards, after drying and processing, finished product, wherein corrosion resistant coating by following parts by weight component system
Into：40 parts of methyl methacrylates, 18 parts of ethylene glycol dimethacrylate, 16 parts of glycidyl methacrylate, 6 parts of ethylene
Three ethoxy silane of base, 8 parts of 4- halogen trimethylsilylbenzenes ethylene, 2 parts of initiators, 20 parts of deionized waters, 10 parts of tetrabromo-bisphenol s, 16 parts
Salicylanilide, 24 parts of color stuffings, 5 parts of auxiliary agents.
Specifically, above-mentioned steps（1）In, the fountain height of 5% sulfuric acid solution is 28g/m2。
Specifically, above-mentioned steps（2）In, corrosion resistant coating is made of following methods：By methyl methacrylate, diformazan
Base acrylic acid glycol ester, glycidyl methacrylate, three ethoxy silane of vinyl, 4- halogen trimethylsilylbenzenes ethylene, initiation
Agent and deionized water after mixing, after being heated to 83 DEG C, when isothermal holding 4.5 is small after, then add in tetrabromobisphenol thereto
S, after mixing, corrosion resistant coating is made in salicylanilide, color stuffing, auxiliary agent.
Specifically, the color stuffing is calcium carbonate and kaolin according to 1:1 mass ratio is mixed, the auxiliary agent by with
The component of lower parts by weight is made：2 parts of dimethyl silicone polymer, 3 parts of TEGODispers685 wetting dispersing agents, 7 parts of lauryl alcohol ester.
Embodiment 3
A kind of preparation method of the corrosion-resistant batch can of fertilizer applicator, including following operating procedure：
（1）It will prepare after molding batch can cleans up, surface carries out grinding process using 1000# sand paper, then inside and outside it
The sulfuric acid solution that surface sprinkling mass fraction is 5%；
（2）After 30min, by step（1）The batch can surfaces externally and internally of processing is uniformly brushed on corrosion resistant coating, so
Being put into batch can in baking oven afterwards, after drying and processing, finished product, wherein corrosion resistant coating by following parts by weight component system
Into：44 parts of methyl methacrylates, 20 parts of ethylene glycol dimethacrylate, 18 parts of glycidyl methacrylate, 8 parts of ethylene
Three ethoxy silane of base, 10 parts of 4- halogen trimethylsilylbenzenes ethylene, 3 parts of initiators, 22 parts of deionized waters, 11 parts of tetrabromo-bisphenol s, 18 parts
Salicylanilide, 26 parts of color stuffings, 7 parts of auxiliary agents.
Specifically, above-mentioned steps（1）In, the fountain height of 5% sulfuric acid solution is 300g/m2。
Specifically, above-mentioned steps（2）In, corrosion resistant coating is made of following methods：By methyl methacrylate, diformazan
Base acrylic acid glycol ester, glycidyl methacrylate, three ethoxy silane of vinyl, 4- halogen trimethylsilylbenzenes ethylene, initiation
Agent and deionized water after mixing, after being heated to 85 DEG C, when isothermal holding 5 is small after, then thereto add in tetrabromo-bisphenol s,
After mixing, corrosion resistant coating is made in salicylanilide, color stuffing, auxiliary agent.
Specifically, the color stuffing is calcium carbonate and kaolin according to 1:1 mass ratio is mixed, the auxiliary agent by with
The component of lower parts by weight is made：3 parts of dimethyl silicone polymer, 4 parts of TEGODispers685 wetting dispersing agents, 8 parts of lauryl alcohol ester.
Finally illustrate, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although with reference to compared with
The present invention is described in detail in good embodiment, it will be understood by those of ordinary skill in the art that, it can be to the skill of the present invention
Art scheme is modified or replaced equivalently, and without departing from the objective and scope of technical solution of the present invention, should all be covered at this
Among the right of invention.
Claims (4)
1. a kind of preparation method of the corrosion-resistant batch can of fertilizer applicator, which is characterized in that including following operating procedure：
（1）It will prepare after molding batch can cleans up, surface carries out grinding process using 1000# sand paper, then inside and outside it
The sulfuric acid solution that surface sprinkling mass fraction is 5%；
（2）After 25-30min, by step（1）The batch can surfaces externally and internally of processing is uniformly brushed on corrosion-resistant painting
Material, then being put into batch can in baking oven, after drying and processing, finished product, wherein corrosion resistant coating by following parts by weight group
Divide and be made：35-44 parts of methyl methacrylates, 17-20 parts of ethylene glycol dimethacrylate, 14-18 parts of methacrylic acid rings
Three ethoxy silane of oxygen propyl ester, 4-8 part vinyl, 6-10 parts of 4- halogen trimethylsilylbenzenes ethylene, 1-3 parts of initiators, 17-22 parts go from
Sub- water, 9-11 part tetrabromo-bisphenol s, 14-18 parts of salicylanilides, 22-26 parts of color stuffings, 4-7 parts of auxiliary agents.
A kind of 2. preparation method of the corrosion-resistant batch can of fertilizer applicator according to claim 1, which is characterized in that above-mentioned steps
（1）In, the fountain height of 5% sulfuric acid solution is 250-300g/m2。
A kind of 3. preparation method of the corrosion-resistant batch can of fertilizer applicator according to claim 1, which is characterized in that above-mentioned steps
（2）In, corrosion resistant coating is made of following methods：By methyl methacrylate, ethylene glycol dimethacrylate, methyl-prop
Olefin(e) acid polyglycidyl, three ethoxy silane of vinyl, 4- halogen trimethylsilylbenzenes ethylene, initiator and deionized water after mixing,
After being heated to 80-85 DEG C, when isothermal holding 4-5 is small after, then thereto add in tetrabromo-bisphenol s, salicylanilide, color stuffing,
After mixing, corrosion resistant coating is made in auxiliary agent.
A kind of 4. preparation method of the corrosion-resistant batch can of fertilizer applicator according to claim 3, which is characterized in that the color stuffing
It is calcium carbonate and kaolin according to 1:1 mass ratio is mixed, and the auxiliary agent is made of the component of following parts by weight：Poly- diformazan
1-3 parts of radical siloxane, 2-4 parts of TEGODispers685 wetting dispersing agents, 6-8 parts of lauryl alcohol ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711409778.8A CN108047783A (en) | 2017-12-23 | 2017-12-23 | A kind of preparation method of the corrosion-resistant batch can of fertilizer applicator |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711409778.8A CN108047783A (en) | 2017-12-23 | 2017-12-23 | A kind of preparation method of the corrosion-resistant batch can of fertilizer applicator |
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| Publication Number | Publication Date |
|---|---|
| CN108047783A true CN108047783A (en) | 2018-05-18 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711409778.8A Pending CN108047783A (en) | 2017-12-23 | 2017-12-23 | A kind of preparation method of the corrosion-resistant batch can of fertilizer applicator |
Country Status (1)
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| CN (1) | CN108047783A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1944476A (en) * | 2006-10-19 | 2007-04-11 | 湖北大学 | Process for preparing fluorin, silicon, epoxide modified low surface energy acrylate emulsion for heavy anti-corrosion paint |
| CN102337065A (en) * | 2011-07-06 | 2012-02-01 | 江苏金陵特种涂料有限公司 | Water-based epoxy terrace paint |
-
2017
- 2017-12-23 CN CN201711409778.8A patent/CN108047783A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1944476A (en) * | 2006-10-19 | 2007-04-11 | 湖北大学 | Process for preparing fluorin, silicon, epoxide modified low surface energy acrylate emulsion for heavy anti-corrosion paint |
| CN102337065A (en) * | 2011-07-06 | 2012-02-01 | 江苏金陵特种涂料有限公司 | Water-based epoxy terrace paint |
Non-Patent Citations (2)
| Title |
|---|
| 蔡永源 等: "《高分子材料阻燃技术手册》", 28 February 1993, 化学工业出版社 * |
| 马世昌: "《化学物质辞典》", 30 April 1999, 陕西科学技术出版社 * |
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Application publication date: 20180518 |
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