CN108046697A - A kind of rapid-hardening curing agent for urban rivers and lakes sludge solidification dredging - Google Patents

A kind of rapid-hardening curing agent for urban rivers and lakes sludge solidification dredging Download PDF

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Publication number
CN108046697A
CN108046697A CN201711334543.7A CN201711334543A CN108046697A CN 108046697 A CN108046697 A CN 108046697A CN 201711334543 A CN201711334543 A CN 201711334543A CN 108046697 A CN108046697 A CN 108046697A
Authority
CN
China
Prior art keywords
parts
curing agent
rapid
lakes
dredging
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711334543.7A
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Chinese (zh)
Inventor
陈建康
肖颖
梅丰
陆伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujian Harbour Geotechnical Engineering Group Co Ltd
Original Assignee
Fujian Harbour Geotechnical Engineering Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujian Harbour Geotechnical Engineering Group Co Ltd filed Critical Fujian Harbour Geotechnical Engineering Group Co Ltd
Priority to CN201711334543.7A priority Critical patent/CN108046697A/en
Publication of CN108046697A publication Critical patent/CN108046697A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/008Sludge treatment by fixation or solidification
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00767Uses not provided for elsewhere in C04B2111/00 for waste stabilisation purposes

Abstract

The invention discloses a kind of rapid-hardening curing agent for urban rivers and lakes sludge solidification dredging, the curing agent is made of following raw material:1.8 ~ 2.0 parts of portland cement, 2.1 ~ 2.3 parts of S95 granulated blast-furnace slags, 1.0 ~ 1.5 parts of quick lime, 2.0 ~ 2.5 parts of flyash, 0.3 ~ 0.6 part of gypsum, 0.4 ~ 0.8 part of calcium-base bentonite, 0.5 ~ 1.0 part of metakaolin, 0.4 ~ 0.8 part of accelerator.The curing agent of the present invention improves the physico-mechanical properties of mud by physical-chemical reaction, and the harmful substance in absorption solidification mud solves the cleaning problem of river and interior lake silt, avoids causing secondary pollution to environment during dredging.

Description

A kind of rapid-hardening curing agent for urban rivers and lakes sludge solidification dredging
Technical field
The present invention relates to a kind of rapid-hardening curing agent for urban rivers and lakes sludge solidification dredging, belong to sludge curing agent neck Domain.
Background technology
With the sharp increase of urban population, society, economic fast development, a large amount of untreated production waste water, life are dirty Water is discharged into inland lake, month after month, in one thick layer bed mud of riverbed and lake bed deposits throughout the year.Cause external source in city seriously polluted, water Body eutrophication is constantly aggravated, deteriorating water quality, significantly impacts the ecological environment in city and resident living environment.The siltation in river The contradictions such as problem, environmental problem become increasingly conspicuous.Riverway sludge how is disposed, finds practicable most effective solution route, it is real The comprehensive utilization of existing resource, gives full play to audit immunization, it has also become the problem of social concerns.
It is traditional to cure dredging there are curing rate is slow, and curing undesirable to the sludge solidification effect of moisture content superelevation The problems such as of high cost.
The content of the invention
It is an object of the invention in view of the shortcomings of the prior art, providing a kind of speed for urban rivers and lakes sludge solidification dredging Solidifying type curing agent.The curing agent of the present invention improves the physico-mechanical properties of mud, absorption solidification mud by physical-chemical reaction In harmful substance, solve the cleaning problem of river and interior lake silt, avoid causing environment during dredging secondary dirt Dye.
To achieve the above object, the present invention adopts the following technical scheme that:
A kind of rapid-hardening curing agent for urban rivers and lakes sludge solidification dredging is counted, the curing agent is by following in parts by weight Raw material is made:
Portland cement:1.8 ~ 2.0 parts;
S95 granulated blast-furnace slags:2.1 ~ 2.3 parts;
Quick lime:1.0 ~ 1.5 parts;
Flyash:2.0 ~ 2.5 parts;
Gypsum:0.3 ~ 0.6 part;
Calcium-base bentonite:0.4 ~ 0.8 part;
Metakaolin:0.5 ~ 1.0 part;
Accelerator:0.4 ~ 0.8 part.
The portland cement is 42.5 Portland cements of P.O.
The quick lime is CL90 quick limes.
The flyash is II grades of flyash of F classes.
The raw material composition of the accelerator is calculated by weight as:3.5 parts of polyacrylamide, 2.2 parts of Sodium Polyacrylate, partially 0.8 part of 2.0 parts of sodium aluminate, 0.5 part of aluminum sulfate, 1.0 parts of sodium nitrate and iron chloride.
The metakaolin be by kaolin at moderate temperatures(600℃~900℃)Through dehydration formation with silicic acid anhydride Aluminium(Al2O3·2SiO2)For main essential mineral, grinding is more than 400m into specific surface area2The high activity powder body material of/g.
For the calcium-base bentonite using montmorillonite as the nonmetallic minerals of main mineral constituent, smectite structure is by two silicon Oxygen tetrahedron presss from both sides the 2 of one layer of alumina octahedral composition:1 type crystal structure, calcium-base bentonite have strong hygroscopicity and dilatancy, The water of adsorbable 8~15 times of own vols, volume expansion is up to several times to 30 times;It can be dispersed into aqueous medium as a form of gel And suspension, this medium solution have certain viscosity, thixotropy and lubricity;There is stronger cation exchange capacity (CEC); There is certain adsorption capacity to various gases, liquid, organic substance, maximal absorptive capacity is up to 5 times of weight of itself;It with The admixture of water, mud or fine sand has plasticity and cohesiveness;Acid bleaching soil with surface-active can adsorb coloured ion.
The beneficial effects of the present invention are:
(1)The rate of set of curing agent of the present invention is fast, can reduce rapidly Free water in mud, improves the plasticity of mud, reaches The construction time is shortened in the requirement of outward transport;
(2)Curing agent of the present invention has prosthetic to soil, can adsorb the harmful substance in mud, improves silt structure.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be further described, but the present invention is not limited only to these embodiments.
Embodiment 1
A kind of rapid-hardening curing agent for urban rivers and lakes sludge solidification dredging is counted, the curing agent is by following in parts by weight Raw material is made:
42.5 portland cements of P.O:1.8 part;
S95 granulated blast-furnace slags:2.1 part;
CL90 quick limes:1.2 part;
F.II grades of flyash:2.2 part;
Gypsum:0.5 part;
Calcium-base bentonite:0.4 part;
Metakaolin:0.5 part;
Accelerator:0.4 part;
The accelerator is by 3.5 parts of polyacrylamide, 2.2 parts of Sodium Polyacrylate, 2.0 parts of sodium metaaluminate, 0.5 part of aluminum sulfate, nitre Sour 1.0 parts of sodium is mixed with 0.8 part of iron chloride.
The rapid-hardening curing agent is made after above-mentioned each raw material is mixed in proportion.
Embodiment 2
A kind of rapid-hardening curing agent for urban rivers and lakes sludge solidification dredging is counted, the curing agent is by following in parts by weight Raw material is made:
42.5 portland cements of P.O:1.9 part;
S95 granulated blast-furnace slags:2.3 part;
CL90 quick limes:1.5 part;
F.II grades of flyash:2.5 part;
Gypsum:0.6 part;
Calcium-base bentonite:0.8 part;
Metakaolin:0.8 part;
Accelerator:0.8 part;
The accelerator is by 3.5 parts of polyacrylamide, 2.2 parts of Sodium Polyacrylate, 2.0 parts of sodium metaaluminate, 0.5 part of aluminum sulfate, nitre Sour 1.0 parts of sodium is mixed with 0.8 part of iron chloride.
The rapid-hardening curing agent is made after above-mentioned each raw material is mixed in proportion.
Embodiment 3
A kind of rapid-hardening curing agent for urban rivers and lakes sludge solidification dredging is counted, the curing agent is by following in parts by weight Raw material is made:
42.5 portland cements of P.O:2.0 part;
S95 granulated blast-furnace slags:2.2 part;
CL90 quick limes:1.0 part;
F.II grades of flyash:2.0 part;
Gypsum:0.3 part;
Calcium-base bentonite:0.5 part;
Metakaolin:1.0 part;
Accelerator:0.6 part;
The accelerator is by 3.5 parts of polyacrylamide, 2.2 parts of Sodium Polyacrylate, 2.0 parts of sodium metaaluminate, 0.5 part of aluminum sulfate, nitre Sour 1.0 parts of sodium is mixed with 0.8 part of iron chloride.
The rapid-hardening curing agent is made after above-mentioned each raw material is mixed in proportion.
The present invention is by analyzing Fuzhou inland lake and riverway sludge, by the curing agent and riverway sludge of the present invention (Moisture content is not more than 150%)By 90kg/m3It after ratio mixing, stirs 30 minutes, you can obtain losing flowability consolidating of can transporting outward Change soil.Testing result is as shown in table 1.
Table 1 cures testing result
The foregoing is merely presently preferred embodiments of the present invention, and all equivalent changes done according to scope of the present invention patent are with repairing Decorations should all belong to the covering scope of the present invention.

Claims (5)

1. a kind of rapid-hardening curing agent for urban rivers and lakes sludge solidification dredging, it is characterised in that:It counts in parts by weight, it is described Curing agent is made of following raw material:
Portland cement:1.8 ~ 2.0 parts;
S95 granulated blast-furnace slags:2.1 ~ 2.3 parts;
Quick lime:1.0 ~ 1.5 parts;
Flyash:2.0 ~ 2.5 parts;
Gypsum:0.3 ~ 0.6 part;
Calcium-base bentonite:0.4 ~ 0.8 part;
Metakaolin:0.5 ~ 1.0 part;
Accelerator:0.4 ~ 0.8 part.
2. the rapid-hardening curing agent according to claim 1 for urban rivers and lakes sludge solidification dredging, it is characterised in that:Institute Portland cement is stated as 42.5 Portland cements of P.O.
3. the rapid-hardening curing agent according to claim 1 for urban rivers and lakes sludge solidification dredging, it is characterised in that:Institute Quick lime is stated as CL90 quick limes.
4. the rapid-hardening curing agent according to claim 1 for urban rivers and lakes sludge solidification dredging, it is characterised in that:Institute Flyash is stated as II grades of flyash of F classes.
5. the rapid-hardening curing agent according to claim 1 for urban rivers and lakes sludge solidification dredging, it is characterised in that:
The raw material composition of the accelerator is calculated by weight as:3.5 parts of polyacrylamide, 2.2 parts of Sodium Polyacrylate, meta-aluminic acid 0.8 part of 2.0 parts of sodium, 0.5 part of aluminum sulfate, 1.0 parts of sodium nitrate and iron chloride.
CN201711334543.7A 2017-12-14 2017-12-14 A kind of rapid-hardening curing agent for urban rivers and lakes sludge solidification dredging Pending CN108046697A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109013637A (en) * 2018-06-08 2018-12-18 中建三局第二建设工程有限责任公司 A kind of in-situ modified solidification processing method of industry white clay
CN109258393A (en) * 2018-11-13 2019-01-25 湖北恒沁环保科技有限责任公司 It is a kind of with sludge solidification preparation planting soil and its application
CN109970314A (en) * 2018-12-25 2019-07-05 安徽佳明环保科技股份有限公司 A kind of compound drying agent and its preparation and application
CN113135730A (en) * 2021-05-17 2021-07-20 浙江久豪建筑勘测设计有限公司 Curing agent and curing process applied to soft soil foundation
CN114735905A (en) * 2022-03-08 2022-07-12 河北恒特环保工程有限公司 Environment-friendly dredging sludge curing agent for river and lake treatment and preparation method thereof

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CN105198367A (en) * 2015-08-17 2015-12-30 广州市建筑科学研究院有限公司 Curing agent capable of rapidly curing sludge at room temperature and use method thereof
CN105819798A (en) * 2015-01-04 2016-08-03 三川德青科技有限公司 Rapid-hardening high-strength sludge consolidation agent and preparation method thereof

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JP3319734B2 (en) * 2000-02-04 2002-09-03 繁行 河田 Architectural materials and their production and construction methods
CN105819798A (en) * 2015-01-04 2016-08-03 三川德青科技有限公司 Rapid-hardening high-strength sludge consolidation agent and preparation method thereof
CN105198367A (en) * 2015-08-17 2015-12-30 广州市建筑科学研究院有限公司 Curing agent capable of rapidly curing sludge at room temperature and use method thereof

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109013637A (en) * 2018-06-08 2018-12-18 中建三局第二建设工程有限责任公司 A kind of in-situ modified solidification processing method of industry white clay
CN109258393A (en) * 2018-11-13 2019-01-25 湖北恒沁环保科技有限责任公司 It is a kind of with sludge solidification preparation planting soil and its application
CN109970314A (en) * 2018-12-25 2019-07-05 安徽佳明环保科技股份有限公司 A kind of compound drying agent and its preparation and application
CN113135730A (en) * 2021-05-17 2021-07-20 浙江久豪建筑勘测设计有限公司 Curing agent and curing process applied to soft soil foundation
CN114735905A (en) * 2022-03-08 2022-07-12 河北恒特环保工程有限公司 Environment-friendly dredging sludge curing agent for river and lake treatment and preparation method thereof

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Application publication date: 20180518

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