CN108035004A - A kind of flame retardant viscose fiber and preparation method thereof - Google Patents
A kind of flame retardant viscose fiber and preparation method thereof Download PDFInfo
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- CN108035004A CN108035004A CN201711160066.7A CN201711160066A CN108035004A CN 108035004 A CN108035004 A CN 108035004A CN 201711160066 A CN201711160066 A CN 201711160066A CN 108035004 A CN108035004 A CN 108035004A
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- flame retardant
- viscose fiber
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
- D01F2/10—Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
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- Engineering & Computer Science (AREA)
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Abstract
The invention belongs to textile technology field, and in particular to a kind of flame retardant viscose fiber and preparation method thereof.The preparation method of the flame retardant viscose fiber, including dipping, experienced, yellow, dissolving, filtering, deaeration, spinning, washing, the process of desulfurization, wherein, in any process before be dissolved into spinning, sodium metasilicate is added into viscose solution, is uniformly mixed.The preparation method of flame retardant viscose fiber of the present invention is easier viscose solution filtering, saves fire retardant, and the fire resistance for the viscose solution filtering being prepared is good.
Description
Technical field
The invention belongs to textile technology field, specifically, is related to a kind of flame retardant viscose fiber and preparation method thereof.
Background technology
Viscose rayon refers to the alpha-cellulose extracted from the cellulosic material such as timber and plant straw, processed into spinning
Stoste, again through staple fibre made of wet spinning, be a kind of regenerated celulose fibre.The moisture percentage of viscose rayon meets human body
The physiological requirement of skin, have it is smooth it is nice and cool, ventilative, antistatic, dye the characteristic such as gorgeous.
Got over the improvement of people ' s living standards with the enhancing of people-oriented awareness of safety, the fire resistance of fibre
To be more concerned by people.There are many countries and regions to formulate product standard, it is specified that the vehicles, public place,
Some fibres that old man, children etc. use must possess fire resistance.With the development of fire resistance fibre technology, further
Fire resistance fibre is asked to have better performance in environmentally protective, heatproof, beneficial to textile process, comfort etc., to meet society's hair
The needs of exhibition.
The preparation of flame retardant viscose fiber mainly has three kinds of methods at present, is that graft copolymerization, mechanical mixture and coating are inhaled
It is attached.Graft copolymerization is that the monomer with fire retardancy is linked into the macromolecular of cellulose;Mechanical mixture is spun in viscose glue
Fire retardant is added in silk liquid;Coating absorption is that fire retardant is adhered to viscose rayon surface by means of the effect of adhesive.Wherein
Based on being produced with mechanical mixing, the fire retardant that uses is with phosphoric acid ester organic fire-retardant and silicates inorganic combustion inhibitor shape
Into industrialization, but it is the shortcomings that the fire resistance fibre of both the above fire retardant production, phosphorous flame-retardant fiber is released a large amount of in burning
Poisonous dense smoke, it is not environmentally friendly enough, and easily make one to suffocate.Fire retardant cost is very high, and product is mainly used for the extraordinary neck such as army, fire-fighting
Domain, big in civil field popularization and application difficulty, development prospect is simultaneously pessimistic.Silicon systems fire resistance fibre is poor there are alkaline resistance properties, washing
Fire-retardant composition loss is more, and there are larger limitation for popularization and application.
In view of this, it is special to propose the present invention.
The content of the invention
The technical problem to be solved in the present invention be to overcome the deficiencies of the prior art and provide a kind of flame retardant viscose fiber and its
Preparation method.
In order to solve the above technical problems, the present invention is using the basic conception of technical solution:
A kind of preparation method of flame retardant viscose fiber, including dipping, experienced, yellow, dissolving, filtering, deaeration, spinning, water
Wash, the process of desulfurization, wherein, in any process before be dissolved into spinning, sodium metasilicate is added into viscose solution, mixing is equal
It is even.
Preferably, in spinning process, aluminum sulfate is added in spinning bath or/and two baths.
In the prior art, it is same using certain being added to together after mixing sodium metasilicate and sodium aluminate solution before spinning
In process, there are following drawback for it:
1st, sodium metaaluminate easily and carbon dioxide reaction, is needed to be deployed into solution in commercial process and reused, and is somebody's turn to do
Solution can react generation aluminum hydroxide precipitation with the carbon dioxide in air, cause the filtration difficulty of viscose solution;
2nd, viscose solution is the product of carbon disulfide and alkali cellulose, wherein comprising a kind of side reaction product NaHS, and
NaHS+NaAlO2+H2O=Na2S+Al(OH)3↓, aluminum hydroxide precipitation can be equally generated, causes viscose solution filtration difficulty or stifled
Fill in spinning filter core or block spinneret orifice.
And the difficulty of viscose solution filtering can be aggravated if both materials are added at the same time in a certain same processes, and
And larger amount of sodium metasilicate and sodium metaaluminate are needed, cause material waste.
Technical scheme is using sodium metasilicate, aluminum sulfate, and substep is added in viscose solution in different processes,
The viscose rayon that can not only make to be prepared has good fire resistance, also overcomes above-mentioned viscose solution filtration difficulty
The defects of, make preparation process more controllable, easy to operate, while save material.
The present invention adds aluminum sulfate in spinning bath or/and two baths, can be to avoid obtained sial mixed gel material resistance
Combustion agent is lost in washing step and wastes fire retardant, influences flame retardant effect.
Preferably, the addition of sodium metasilicate is with SiO2It is calculated as 16~35% of first fibre weight in viscose solution;
The addition of sodium metasilicate is with SiO2Be calculated as first fibre weight in viscose solution reach 16% can reach it is preferable fire-retardant
Property, in the range of 16~35% additions, preparing the fire resistance of the flame retardant viscose fiber of gained increases and improves with content, when
When addition is 35%, anti-flammability oxygen index (OI) can be up to more than 33%, and performance is optimal, if addition is more than 35% fire-retardant oxygen index (OI)
Increase less.
Preferably, the modulus of the sodium metasilicate is 1~3.5;
Preferably, the dioxide-containing silica of sodium metasilicate is 12~20%.
Experimental study shows, if it exceeds 20%, gel easily occurs in viscose solution for the dioxide-containing silica of the sodium metasilicate
Phenomenon, and if dioxide-containing silica has a great influence the composition of viscose glue, effective composition cellulose contains in viscose glue less than 12%
Amount is reduced, and alkalinity is low, and viscosity is too low, and spinning technique cannot be optimal state.
Preferably, the temperature that sodium metasilicate adds viscose solution is 20~25 DEG C.
Researcher has found to add sodium metasilicate in viscose solution in 20~25 DEG C of temperature ranges, contributes to viscose rayon
Surface forms uniformly firm sial mixed gel fire retardant matter, and more resistant to washing and alkali cleaning.
Preferably, concentration of the aluminum sulfate in spinning bath or two baths is 5~50g/l.
Preferably, the viscosity of viscose solution is 35~49s, and first fibre content is 8.5~10%, alkalinity for 4.5~
5.8%, degree of ripeness is 8~11ml.
It is highly preferred that the viscosity of viscose solution is 40~45s, first fibre content is 8.5~9.5%, alkalinity for 4.8~
5.5%, degree of ripeness is 9~10ml.
Preferably, the composition of the spinning bath is 100~130g/l of sulfuric acid, 8~10g/l of zinc sulfate, sodium sulphate for 280~
340g/l, aluminum sulfate are 5~50g/l;
The composition of two bath is 5~30g/l of sulfuric acid, 5~50g/l of aluminum sulfate.
It is highly preferred that the composition of two bath is 15~28g/l of sulfuric acid, 20~40g/l of aluminum sulfate, it is most preferably sulfuric acid 25
~28g/l, 25~38g/l of aluminum sulfate.
The composition of above-described two bath coordinates the overall preparation process of the present invention, makes viscose rayon shaping more preferable, helps
In lifting fire resistance.
Another object of the present invention is to provide a kind of flame retardant viscose fiber, which uses according to above-mentioned interior
Hold any one described preparation method to obtain.
A further object of the present invention is to provide a kind of flame retardant viscose fiber, and the flame retardant viscose fiber is included by silicic acid
The sial mixed gel material that sodium is obtained with aluminum sulfate and sulfuric acid reaction.
Preferably, counted by 100 parts by weight of the flame retardant viscose fiber, the aluminium content in flame retardant viscose fiber is with Al2O3Meter
No more than 0.5 parts by weight.
Preferably, fire-retardant oxygen index (OI) index >=28% of the flame retardant viscose fiber, more preferably fire-retardant oxygen index (OI) index >=
33%.
The aluminium content of the flame retardant viscose fiber is low, and fire resistance is still preferable, reduces the additive amount of fire retardant, saves
Material.
Embodiment
To make the object, technical solutions and advantages of the present invention clearer, with reference to section Example to the present invention's
Technical solution is clearly and completely described, and following embodiments are merely to illustrate the present invention, is not used in the model of the limitation present invention
Enclose.
Embodiment 1
Using bamboo pulp as raw material, by impregnating, squeezing, crushing, the processing step such as experienced alkali cellulose, alkali fiber is made
Contain alkali 17.5%, alpha-cellulose (first is fine) 33.5% in element;
The sodium silicate aqueous solution that silica concentration is 10% is added to the sodium cellulose xanghate after alkali cellulose yellow
In, it is fire-retardant cellulose viscose glue with sodium cellulose xanghate mixed dissolution, the addition of sodium metasilicate is with SiO2It is calculated as in viscose solution
The 25% of first fibre weight, carries out spinning, sulfuric acid in spinning bath after filtered, maturation, deaeration, filtration step in spinning bath
110g/l, zinc sulfate 8g/l, sodium sulphate 320g/l, aluminum sulfate 10g/l, temperature be 45 DEG C, then through be plasticized drawing-off, cut-out,
Washing, using the desulfurization of sodium sulfite desulfurizing agent, oil, dry and prepare 1.67dtex × 38mm flame retardant viscose fiber.
Embodiment 2
Using Cotton Pulp as raw material, by impregnating, squeezing, crushing, the processing step such as experienced alkali cellulose, alkali fiber is made
Contain alkali 17.5%, alpha-cellulose (first is fine) 33.0% in element;
The sodium silicate aqueous solution that silica concentration is 13% is added to the sodium cellulose xanghate after alkali cellulose yellow
In, it is fire-retardant cellulose viscose glue with sodium cellulose xanghate mixed dissolution, the addition of sodium metasilicate is with SiO2It is calculated as in viscose solution
The 27% of first fibre weight, carries out spinning, sulfuric acid in spinning bath after filtered, maturation, deaeration, filtration step in spinning bath
120g/l, zinc sulfate 8g/l, sodium sulphate 320g/l, aluminum sulfate 16g/l, temperature be 43 DEG C, then through be plasticized drawing-off, cut-out,
Washing, using the desulfurization of sodium sulfite desulfurizing agent, oil, dry and prepare 2.22dtex × 51mm flame retardant viscose fiber.
Embodiment 3
Using bamboo pulp as raw material, by impregnating, squeezing, crushing, the processing step such as experienced alkali cellulose, alkali fiber is made
Contain alkali 17.5%, alpha-cellulose (first is fine) 33.0% in element;
The sodium silicate aqueous solution of silica concentration 15% is added to filtered, maturation, deaeration, filtering using syringe pump
In spinning glue after step, the addition of sodium metasilicate is with SiO225% of first fibre weight in viscose solution is calculated as, in spinning bath
Carry out spinning, sulfuric acid 122g/l in spinning bath, zinc sulfate 10g/l, sodium sulphate 325g/l, aluminum sulfate 20g/l, temperature 45
DEG C, then through be plasticized drawing-off, cut-out, washing, using the desulfurization of sodium sulfite desulfurizing agent, oil, dry prepare 3.33dtex ×
64mm flame retardant viscose fiber.
Embodiment 4
Using 70% bamboo pulp and 30% wood pulps as raw material, by impregnating, squeezing, crushing, the processing step system such as experienced
Alkali cellulose is obtained, alkali 17.5%, alpha-cellulose (first is fine) 33.0% are contained in alkali cellulose;
The sodium silicate aqueous solution that silica concentration is 15% is added to filtered, maturation, deaeration, mistake using syringe pump
Filter in the spinning glue after step, the addition of sodium metasilicate is with SiO216% of first fibre weight in viscose solution is calculated as, in spinning bath
Middle carry out spinning, sulfuric acid 122g/l in spinning bath, zinc sulfate 10g/l, sodium sulphate 325g/l, temperature is 45 DEG C, in spinning two
It is 20g/l that aluminum sulfate is added in bath, then through plasticizing drawing-off, cut-out, washing, using the desulfurization of sodium sulfite desulfurizing agent, oil, dry
Prepare 4.44dtex × 64mm flame retardant viscose fiber.
Embodiment 5
Using bamboo pulp as raw material, by impregnating, squeezing, crushing, the processing step such as experienced alkali cellulose, alkali fiber is made
Contain alkali 17.5%, alpha-cellulose (first is fine) 33.5% in element;
The sodium silicate aqueous solution that silica concentration is 12% is added to the sodium cellulose xanghate after alkali cellulose yellow
In, the addition of sodium metasilicate is with SiO225% of first fibre weight in viscose solution is calculated as, the wherein modulus of sodium metasilicate is 1~3.5,
The temperature that sodium metasilicate adds viscose solution is 20~25 DEG C, is fire-retardant cellulose viscose glue with sodium cellulose xanghate mixed dissolution, warp
Spinning is carried out after filtering, maturation, deaeration, filtration step in spinning bath;
Sulfuric acid 130g/l in spinning bath, zinc sulfate 10g/l, sodium sulphate 340g/l, aluminum sulfate 20g/l, then through plasticizing
Drawing-off, cut-out, washing, using the desulfurization of sodium sulfite desulfurizing agent, oil, dry and prepare flame retardant viscose fiber.
The flame retardant viscose fiber of gained is 100 parts by weight meters, and the aluminium content in flame retardant viscose fiber is with Al2O3It is calculated as 0.5 weight
Measure part.
The fire-retardant oxygen index (OI) index of the flame retardant viscose fiber is 30%.
Embodiment 6
Using Cotton Pulp as raw material, by impregnating, squeezing, crushing, the processing step such as experienced alkali cellulose, alkali fiber is made
Contain alkali 18%, alpha-cellulose (first is fine) 34.0% in element;
The sodium silicate aqueous solution that silica concentration is 20% is added to the sodium cellulose xanghate after alkali cellulose yellow
In, the addition of sodium metasilicate is with SiO235% of first fibre weight in viscose solution is calculated as, the wherein modulus of sodium metasilicate is 1~3.5,
The temperature that sodium metasilicate adds viscose solution is 20~25 DEG C, is fire-retardant cellulose viscose glue with sodium cellulose xanghate mixed dissolution, is glued
The viscosity of sol solution is 49s, and first fibre content is 10%, alkalinity 5.8%, degree of ripeness 11ml, filtered, maturation, deaeration,
Spinning is carried out after filtration step in spinning bath, sulfuric acid 100g/l in spinning bath, zinc sulfate 10g/l, sodium sulphate 280g/l, sulphur
Sour aluminium is 50g/l, and temperature is 40 DEG C, and the composition of two baths is sulfuric acid 5g/l, aluminum sulfate 5g/l, then through being plasticized drawing-off, cut-out, water
Wash, using the desulfurization of sodium sulfite desulfurizing agent, oil, dry prepare flame retardant viscose fiber.
The flame retardant viscose fiber of gained is 100 parts by weight meters, and the aluminium content in flame retardant viscose fiber is with Al2O3It is calculated as 0.3 weight
Measure part.
The fire-retardant oxygen index (OI) index of the flame retardant viscose fiber is 33%.
Embodiment 7
Using bamboo pulp as raw material, by impregnating, squeezing, crushing, the processing step such as experienced alkali cellulose, alkali fiber is made
Contain alkali 17.5%, alpha-cellulose (first is fine) 33.0% in element;
The sodium silicate aqueous solution of silica concentration 15% is added to filtered, maturation, deaeration, filtering using syringe pump
In spinning glue after step, the addition of sodium metasilicate is with SiO2It is calculated as 30% of first fibre weight in viscose solution, wherein sodium metasilicate
Modulus be 1~3.5, sodium metasilicate add viscose solution temperature be 20~25 DEG C, the viscosity of viscose solution is 35s, and first fibre contains
Measure as 8.5%, alkalinity 4.5%, degree of ripeness 8ml, carries out spinning in spinning bath, sulfuric acid 115g/l, sulphur in spinning bath
Sour zinc 8g/l, sodium sulphate 290g/l, aluminum sulfate 5g/l, the composition of two baths is sulfuric acid 18g/l, aluminum sulfate 50g/l, then through modeling
Change drawing-off, cut-out, washing, using the desulfurization of sodium sulfite desulfurizing agent, oil, dry and prepare flame retardant viscose fiber.
The flame retardant viscose fiber of gained is 100 parts by weight meters, and the aluminium content in flame retardant viscose fiber is with Al2O3It is calculated as 0.3 weight
Measure part.
The fire-retardant oxygen index (OI) index of the flame retardant viscose fiber is 31%.
Comparative example 1
The comparative example and embodiment 4 difference lies in:Aluminum sulfate is not added in the bath of spinning two.
Using 70% bamboo pulp and 30% wood pulps as raw material, by impregnating, squeezing, crushing, the processing step system such as experienced
Alkali cellulose is obtained, alkali 17.5%, alpha-cellulose (first is fine) 33.0% are contained in alkali cellulose;
The sodium silicate aqueous solution that silica concentration is 15% is added to filtered, maturation, deaeration, mistake using syringe pump
Filter in the spinning glue after step, the addition of sodium metasilicate is with SiO216% of first fibre weight in viscose solution is calculated as, in spinning bath
Middle carry out spinning, sulfuric acid 122g/l in spinning bath, zinc sulfate 10g/l, sodium sulphate 325g/l, temperature are 45 DEG C, then through plasticizing
Drawing-off, cut-out, washing, using the desulfurization of sodium sulfite desulfurizing agent, oil, dry prepare 4.44dtex × 64mm anti-flaming viscoses fibre
Dimension.
A. water-wash resistance contrasts
80 DEG C of temperature, bath raio 1:30, washing two minutes every time, is washed 10 times, drying altogether, and the oxygen of fiber refers to after detection process
Number.
Table 1
B. resistance to alkali cleaning contrast
Under conditions of bath raio is 1: 30, fire-retardant regenerated cellulose fiber is put into 80 DEG C of temperature, the NaOH of concentration 5g/L
Washed 2 minutes in solution.
Table 2
Comparative example 1 can be seen that according to above-mentioned test result and do not add aluminum sulfate in the bath of spinning two, what is obtained is viscous
The water-wash resistance of glue fiber is compared with resistance to alkali cleaning with the embodiment of the present invention 1~4, and fire resistance is poor, not water-fastness and alkali cleaning.
Comparative example 2
The comparative example and embodiment 6 difference lies in:The temperature that sodium metasilicate adds viscose solution is not 20~25 DEG C.
Using Cotton Pulp as raw material, by impregnating, squeezing, crushing, the processing step such as experienced alkali cellulose, alkali fiber is made
Contain alkali 18%, alpha-cellulose (first is fine) 34.0% in element;
The sodium silicate aqueous solution that silica concentration is 20% is added to the sodium cellulose xanghate after alkali cellulose yellow
In, the addition of sodium metasilicate is with SiO235% of first fibre weight in viscose solution is calculated as, the wherein modulus of sodium metasilicate is 1~3.5,
The temperature that sodium metasilicate adds viscose solution is 30 DEG C, is fire-retardant cellulose viscose glue with sodium cellulose xanghate mixed dissolution, viscose glue is molten
The viscosity of liquid is 49s, and first fibre content is 10%, alkalinity 5.8%, degree of ripeness 11ml, filtered, maturation, deaeration, filtering
Spinning is carried out after step in spinning bath, sulfuric acid 100g/l in spinning bath, zinc sulfate 10g/l, sodium sulphate 280g/l, aluminum sulfate
For 50g/l, temperature is 40 DEG C, and the compositions of two baths be sulfuric acid 5g/l, aluminum sulfate 5g/l, then through plasticizing drawing-off, cut-out, wash, make
With the desulfurization of sodium sulfite desulfurizing agent, oil, dry prepare flame retardant viscose fiber.
A. water-wash resistance contrasts
80 DEG C of temperature, bath raio 1:30, washing two minutes every time, is washed 10 times, drying altogether, and the oxygen of fiber refers to after detection process
Number.
Table 3
B. resistance to alkali cleaning contrast
Under conditions of bath raio is 1: 30, fire-retardant regenerated cellulose fiber is put into 80 DEG C of temperature, the NaOH of concentration 5g/L
Washed 2 minutes in solution.
Table 4
According to above-mentioned test result can be seen that sodium metasilicate in comparative example 2 add viscose solution temperature be not 20~
25 DEG C, the water-wash resistance of obtained viscose rayon compares fire resistance with resistance to alkali cleaning with the embodiment of the present invention 5~7 and also has and can carry
The space risen, and the technical solution of embodiment 5~7 obtains that fire resistance fibre performance is more preferable and water-fastness and alkali cleaning.
The above is only presently preferred embodiments of the present invention, not makees limitation in any form to the present invention, though
So the present invention is disclosed above with preferred embodiment, but is not limited to the present invention, any technology people for being familiar with this patent
Member without departing from the scope of the present invention, when the technology contents using above-mentioned prompting make it is a little change or be modified to
The equivalent embodiment of equivalent variations, as long as being the content without departing from technical solution of the present invention, the technical spirit pair according to the present invention
Any simple modification, equivalent change and modification that above example is made, in the range of still falling within the present invention program.
Claims (10)
1. a kind of preparation method of flame retardant viscose fiber, including dipping, experienced, yellow, dissolving, filtering, deaeration, spinning, washing,
The process of desulfurization, it is characterised in that in any process before be dissolved into spinning, sodium metasilicate is added into viscose solution, is mixed
Close uniform.
2. the preparation method of flame retardant viscose fiber according to claim 1, it is characterised in that in spinning process, by sulphur
Sour aluminium is added in spinning bath or/and two baths.
3. the preparation method of flame retardant viscose fiber according to claim 1 or 2, it is characterised in that the addition of sodium metasilicate
With SiO2It is calculated as 16~35% of first fibre weight in viscose solution;
Preferably, the modulus of the sodium metasilicate is 1~3.5;
Preferably, the dioxide-containing silica of sodium metasilicate is 12~20%.
4. according to the preparation method of claim 1-3 any one of them flame retardant viscose fiber, it is characterised in that sodium metasilicate adds
The temperature of viscose solution is 20~25 DEG C.
5. according to the preparation method of claim 2-4 any one of them flame retardant viscose fiber, it is characterised in that aluminum sulfate is being spun
Concentration in silk bath or two baths is 5~50g/l.
6. according to the preparation method of claim 1-5 any one of them flame retardant viscose fiber, it is characterised in that viscose solution
Viscosity is 35~49s, and first fibre content is 8.5~10%, and alkalinity is 4.5~5.8%, and degree of ripeness is 8~11ml.
7. according to the preparation method of claim 2-6 any one of them flame retardant viscose fiber, it is characterised in that the spinning bath
Composition be 100~130g/l of sulfuric acid, 8~10g/l of zinc sulfate, sodium sulphate is 280~340g/l, and aluminum sulfate is 5~50g/l;
The composition of two bath is 5~30g/l of sulfuric acid, 5~50g/l of aluminum sulfate.
8. a kind of flame retardant viscose fiber, it is characterised in that use and obtained according to claim 1-7 any one of them preparation methods
.
9. a kind of flame retardant viscose fiber, it is characterised in that the flame retardant viscose fiber is included by sodium metasilicate and aluminum sulfate and sulphur
The sial mixed gel material that acid reaction obtains.
10. flame retardant viscose fiber according to claim 8 or claim 9, it is characterised in that using the flame retardant viscose fiber as 100
Parts by weight meter, the aluminium content in flame retardant viscose fiber is with Al2O3Meter is no more than 0.5 parts by weight.
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CN109487362A (en) * | 2018-11-30 | 2019-03-19 | 山传雷 | A kind of inorganic fire-retarded phase-change energy-storage fibre cellulose fiber and preparation method thereof |
CN110359168A (en) * | 2019-08-14 | 2019-10-22 | 苏州百进纺织有限公司 | A kind of scribbled and fabric of flame-retardant viscose fiber and acrylic fibers fire resistance fibre |
CN115679465A (en) * | 2022-10-31 | 2023-02-03 | 潍坊欣龙生物材料有限公司 | Preparation method of light regenerated cellulose fibers |
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CN102286799A (en) * | 2011-08-22 | 2011-12-21 | 阜宁澳洋科技有限责任公司 | Fire-retardant viscose fiber and preparation method thereof |
CN102409420A (en) * | 2011-09-26 | 2012-04-11 | 宜宾丝丽雅股份有限公司 | Composite silicon-based flame-retardant viscose fiber and production method thereof |
CN103643332A (en) * | 2013-12-04 | 2014-03-19 | 阜宁澳洋科技有限责任公司 | Functional composite fiber and preparation method thereof |
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