CN108034026A - The preparation method of ion liquid microemulsion, poly ion liquid base Signa Gel and preparation method thereof - Google Patents
The preparation method of ion liquid microemulsion, poly ion liquid base Signa Gel and preparation method thereof Download PDFInfo
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- CN108034026A CN108034026A CN201711470162.1A CN201711470162A CN108034026A CN 108034026 A CN108034026 A CN 108034026A CN 201711470162 A CN201711470162 A CN 201711470162A CN 108034026 A CN108034026 A CN 108034026A
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- 239000007788 liquid Substances 0.000 title claims abstract description 93
- 229920000831 ionic polymer Polymers 0.000 title claims abstract description 47
- 239000004530 micro-emulsion Substances 0.000 title claims abstract description 39
- 238000002360 preparation method Methods 0.000 title claims abstract description 31
- 238000001879 gelation Methods 0.000 title description 2
- 239000002608 ionic liquid Substances 0.000 claims abstract description 30
- 238000011065 in-situ storage Methods 0.000 claims abstract description 14
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 238000002156 mixing Methods 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 4
- 150000002500 ions Chemical class 0.000 claims description 41
- -1 1- butyl -3- methylimidazoles hexafluorophosphate Chemical class 0.000 claims description 8
- BDERNNFJNOPAEC-UHFFFAOYSA-N n-propyl alcohol Natural products CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 8
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 5
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 5
- CBFCDTFDPHXCNY-UHFFFAOYSA-N octyldodecane Natural products CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- NQTADLQHYWFPDB-UHFFFAOYSA-N N-Hydroxysuccinimide Chemical class ON1C(=O)CCC1=O NQTADLQHYWFPDB-UHFFFAOYSA-N 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical class C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 claims description 2
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- YCLSOMLVSHPPFV-UHFFFAOYSA-N 3-(2-carboxyethyldisulfanyl)propanoic acid Chemical class OC(=O)CCSSCCC(O)=O YCLSOMLVSHPPFV-UHFFFAOYSA-N 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- AUONHKJOIZSQGR-UHFFFAOYSA-N oxophosphane Chemical compound P=O AUONHKJOIZSQGR-UHFFFAOYSA-N 0.000 claims 1
- 239000004094 surface-active agent Substances 0.000 abstract description 15
- 230000003213 activating effect Effects 0.000 abstract description 2
- 238000012703 microemulsion polymerization Methods 0.000 abstract description 2
- 239000003463 adsorbent Substances 0.000 description 5
- 229920002678 cellulose Polymers 0.000 description 5
- 239000001913 cellulose Substances 0.000 description 5
- 238000004146 energy storage Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- IQQRAVYLUAZUGX-UHFFFAOYSA-N 1-butyl-3-methylimidazolium Chemical compound CCCCN1C=C[N+](C)=C1 IQQRAVYLUAZUGX-UHFFFAOYSA-N 0.000 description 4
- WXMVWUBWIHZLMQ-UHFFFAOYSA-N 3-methyl-1-octylimidazolium Chemical compound CCCCCCCCN1C=C[N+](C)=C1 WXMVWUBWIHZLMQ-UHFFFAOYSA-N 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- 125000004386 diacrylate group Chemical group 0.000 description 4
- 229920001223 polyethylene glycol Polymers 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- DZGUJOWBVDZNNF-UHFFFAOYSA-N azanium;2-methylprop-2-enoate Chemical compound [NH4+].CC(=C)C([O-])=O DZGUJOWBVDZNNF-UHFFFAOYSA-N 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- RVEJOWGVUQQIIZ-UHFFFAOYSA-N 1-hexyl-3-methylimidazolium Chemical compound CCCCCCN1C=C[N+](C)=C1 RVEJOWGVUQQIIZ-UHFFFAOYSA-N 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical class [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 2
- DTTDXHDYTWQDCS-UHFFFAOYSA-N 1-phenylcyclohexan-1-ol Chemical compound C=1C=CC=CC=1C1(O)CCCCC1 DTTDXHDYTWQDCS-UHFFFAOYSA-N 0.000 description 1
- ODJQKYXPKWQWNK-UHFFFAOYSA-N 3,3'-Thiobispropanoic acid Chemical compound OC(=O)CCSCCC(O)=O ODJQKYXPKWQWNK-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000003490 Thiodipropionic acid Substances 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002322 conducting polymer Substances 0.000 description 1
- 229920001940 conductive polymer Polymers 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- 239000011245 gel electrolyte Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000593 microemulsion method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 235000019303 thiodipropionic acid Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
- C08F283/065—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals on to unsaturated polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
- C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Secondary Cells (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses the preparation method of ion liquid microemulsion：(1) raw material is weighed by following percentage by weight：5.7~15.7 parts of polarity phase ionic liquid；15.3~25.2 parts of nonpolar phase ionic liquid；53.9~65 parts of polymerisable surfactant；4.7~10.4 parts of crosslinking agent；(2) obtained raw material mixing will be weighed, in 20 DEG C~100 DEG C stirrings, is prepared into ion liquid microemulsion.The invention also discloses the preparation method of poly ion liquid base Signa Gel, photoinitiator is added in ion liquid microemulsion, then with ultra violet lamp, poly ion liquid gel is prepared in situ out.The preparation method of the present invention effectively reduces the residue problem of classical microemulsion polymerization rear surface activating agent, and surfactant molecule is set covalently to be firmly bound to poly ion liquid surface, the poly ion liquid base Signa Gel of preparation not only has higher electrical conductivity, while has good mechanical property.
Description
Technical field
The present invention relates to the preparation of the preparation field of ionic gel type electrolyte, more particularly to ion liquid microemulsion
Method, poly ion liquid base Signa Gel and preparation method thereof.
Background technology
High-performance ionic gel type electrolyte, not only the good electric conductivity with ionic liquid and not volatile grade are special
Point, while have the shape of ordinary gel electrolyte and the advantage of structure-controllable concurrently, thus in novel solar battery, function membrane material
The fields such as material, elastic devices have larger application potential.However, the mechanical property and electrical conductivity of conventional ion gel are improved at the same time
It is conflicting, because when improving ionic gel mechanical property, certainly will need to improve the content of polymeric matrix, but this can be reduced
Ionic conductivity.Equally, if increasing carrier concentration to improve electrical conductivity, and the mechanical property of ionic gel will be reduced.
In the recent period, the conducting polymer as obtained by double bond containing ion liquid polymerization --- poly ion liquid (Polymeric
Ionic liquids) not only there is high electrical conductivity, while have polymer and " green solvent " concurrently --- ionic liquid it is excellent
Performance, and the mobility of ionic liquid is overcome, it is obtained Preliminary Applications in electrolyte field, and show wide answer
Use prospect.But up to the present, most of poly ion liquid gel mechanical poor-performings, significantly limit polyion liquid
The application of body gel.Therefore, prepare and coagulated with very good mechanical properties, high conductivity and electrochemically stable poly ion liquid
Glue is of great significance.
The content of the invention
In order to overcome the disadvantages mentioned above of the prior art and deficiency, it is an object of the invention to provide a kind of ionic liquid micro emulsion
The preparation method of liquid, can be prepared in situ poly ion liquid base Signa Gel, open ion liquid microemulsion architectural study and answer
Frontier.
The purpose of the present invention is achieved through the following technical solutions：
The preparation method of ion liquid microemulsion, comprises the following steps：
(1) raw material is weighed by following percentage by weight：
(2) step (1) is weighed to obtained raw material to mix, in 20 DEG C~100 DEG C stirrings, is prepared into ionic liquid micro emulsion
Liquid.
Preferably, the polarity phase ionic liquid is the 1- pi-allyl -3- methylimidazoles containing the double bond that may participate in polymerization
Villaumite ([AMIm] Cl), 1- pi-allyl -3- ethyl imidazol(e)s villaumite ([AEIm] Cl), 1- pi-allyl -3- butyl imidazole villaumites
At least one of ([ABIm] Cl).
Preferably, the nonpolar phase ionic liquid is 1- butyl -3- methylimidazoles hexafluorophosphates ([Bmim] PF6)、
1- hexyl -3- methylimidazoles hexafluorophosphates ([Hmim] PF6), 1- octyl group -3- butyl imidazoles hexafluorophosphates ([Omim] PF6)
At least one of.
Preferably, the polymerisable surfactant for allyloxy Nonylphenoxy propyl alcohol polyoxyethylene ether ammonium sulfate,
At least one of allyloxy Nonylphenoxy propyl alcohol polyoxyethylene ether, didecyl Dimethy olefin(e) acid ammonium.
Preferably, the crosslinking agent is polyethyleneglycol diacrylate, ethylene glycol dimethacrylate, 3,3'-, bis- sulphur
For at least one of dipropionic acid two (N- hydroxysuccinimides) ester.
Preferably, step (2) stirring, is specially：Mixing speed is 300rpm~1200rpm, mixing time 10
Minute~30 minutes.
Preferably, the preparation method of poly ion liquid base Signa Gel, comprises the following steps：
At room temperature, added in the ion liquid microemulsion that the preparation method of the ion liquid microemulsion is prepared
Photoinitiator, then with ultra violet lamp, poly ion liquid gel is prepared in situ out；The quality of the photoinitiator is ionic liquid
Microemulsion and the 0.5~3.6% of photoinitiator gross mass.
Preferably, the photoinitiator for 2- hydroxy-2-methyl -1- phenylacetones, 1- hydroxycyclohexyl phenyl ketones, 2,
At least one of 4,6- trimethylbenzoy-dipheny phosphine oxides.
Preferably, the time of the ultra violet lamp is 0.5~5h.
Poly ion liquid base Signa Gel, is prepared by the preparation method of the poly ion liquid base Signa Gel.
Compared with prior art, the present invention has the following advantages and beneficial effect：
(1) ion liquid microemulsion prepared by the present invention, can be prepared by adding photoinitiator original position light initiation polymerization, this
Kind preparation method effectively reduces the residue problem of classical microemulsion polymerization rear surface activating agent, and makes surfactant molecule
Poly ion liquid surface is covalently firmly bound to, plays self-characteristic, weight is played for improving product mechanical property
Act on.
(2) preparation method of poly ion liquid base Signa Gel of the invention, polarity phase and nonpolar phase are ionic liquid
Body, wherein polarity phase ionic liquid is as polymerization reaction monomer, and surfactant may also participate in polymerisation, opens ion
Liquid microemulsion architectural study and the frontier of application.
(3) ion liquid microemulsion of the invention, the preparation method of poly ion liquid base Signa Gel, preparation method letter
Single, easy to operate, easily controllable, production cost is low.
(4) new poly ion liquid base Signa Gel prepared by the present invention not only has higher electrical conductivity, has at the same time
Good mechanical property, still has higher elasticity modulus at relatively high temperatures, and raw material is easy to get, asepsis environment-protecting, reaction condition
Simplify.
Embodiment
With reference to embodiment, the present invention is described in further detail, but the implementation of the present invention is not limited to this.
Embodiment 1
Claim raw material by following percentage by weight：Polarity phase ionic liquid [AMIm] Cl5.7%, nonpolar phase ionic liquid
[Bmim]PF615.3%, surfactant allyloxy Nonylphenoxy propyl alcohol polyoxyethylene ether ammonium sulfate 65%, crosslinking agent gathers
Glycol diacrylate 10.4%, photoinitiator 2- hydroxy-2-methyl -1- phenylacetones 3.6%.
The ion liquid microemulsion light-initiated method for preparing poly ion liquid Signa Gel in situ：By above-mentioned polarity phase ion
Example mixes by mass percentage for liquid, nonpolar phase ionic liquid, surfactant, crosslinking agent, at a temperature of 100 DEG C, with 300
Rev/min mixing speed, stir 30 minutes, be prepared into ion liquid microemulsion.At room temperature, it is micro- to above-mentioned novel ion liquid
Add photoinitiator in emulsion system, then with ultra violet lamp 0.5h, poly ion liquid gel is prepared in situ out.
Appearance, rheological property, mechanics is carried out to magnetic cellulose base poly ion liquid adsorbent manufactured in the present embodiment to draw
Stretch and tested with electrochemical AC impedance, specific performance parameter is shown in Table 1.The result shows that gained poly ion liquid gel has high energy storage
Modulus, strong mechanical property and high conductivity.
Embodiment 2
Claim raw material by following percentage by weight：Polarity phase ionic liquid [AMIm] Cl5.7%, nonpolar phase ionic liquid
[Bmim]PF615.3%, surfactant allyloxy Nonylphenoxy propyl alcohol polyoxyethylene ether ammonium sulfate 65%, crosslinking agent
Polyethyleneglycol diacrylate 10.4%, photoinitiator 2- hydroxy-2-methyl -1- phenylacetones 3.6%.
The ion liquid microemulsion light-initiated method for preparing poly ion liquid Signa Gel in situ：By above-mentioned polarity phase ion
Example mixes by mass percentage for liquid, nonpolar phase ionic liquid, surfactant, crosslinking agent, at a temperature of 20 DEG C, with 1200
Rev/min mixing speed, stir 10 minutes, be prepared into novel ion liquid microemulsion.At room temperature, to above-mentioned novel ion liquid
Add photoinitiator in body microemulsion system, then with ultra violet lamp 5h, poly ion liquid gel is prepared in situ out.
Appearance, rheological property, mechanics is carried out to magnetic cellulose base poly ion liquid adsorbent manufactured in the present embodiment to draw
Stretch and tested with electrochemical AC impedance, specific performance parameter is shown in Table 1.The result shows that gained poly ion liquid gel has high energy storage
Modulus, strong mechanical property and high conductivity.
Embodiment 3
Claim raw material by following percentage by weight：Polarity phase ionic liquid [ABIm] Cl 10.7%, nonpolar phase ionic liquid
[Omim]PF621.3%, surfactant didecyl Dimethy ammonium methacrylate 56.8%, crosslinking agent 3,3'- bis- is thio
Dipropionic acid two (N- hydroxysuccinimides) ester 7.6%, photoinitiator 2,4,6- trimethylbenzoy-dipheny phosphine oxides
3.6%.
The ion liquid microemulsion light-initiated method for preparing poly ion liquid Signa Gel in situ：By above-mentioned polarity phase ion
Example mixes by mass percentage for liquid, nonpolar phase ionic liquid, surfactant, crosslinking agent, at a temperature of 60 DEG C, with 750
Rev/min mixing speed, stir 20 minutes, be prepared into novel ion liquid microemulsion.At room temperature, to above-mentioned novel ion liquid
Add photoinitiator in body microemulsion system, then with ultra violet lamp 3h, poly ion liquid gel is prepared in situ out.
Appearance, rheological property, mechanics is carried out to magnetic cellulose base poly ion liquid adsorbent manufactured in the present embodiment to draw
Stretch and tested with electrochemical AC impedance, specific performance parameter is shown in Table 1.The result shows that gained poly ion liquid gel has high energy storage
Modulus, strong mechanical property and high conductivity.
Embodiment 4
Claim raw material by following percentage by weight：Polarity phase ionic liquid [AMIm] Cl 2.3%, [ABIm] Cl3.4% are non-
Polarity phase ionic liquid [Bmim] PF610.3%th, [Omim] PF65%, surfactant allyloxy Nonylphenoxy propyl alcohol gathers
Ethylene oxide ether ammonium sulfate 35%, didecyl Dimethy ammonium methacrylate 30%, crosslinking agent polyethyleneglycol diacrylate
10.4%, photoinitiator 2- hydroxy-2-methyl -1- phenylacetone 3.6%.
The ion liquid microemulsion light-initiated method for preparing poly ion liquid Signa Gel in situ：By above-mentioned polarity phase ion
Example mixes by mass percentage for liquid, nonpolar phase ionic liquid, surfactant, crosslinking agent, at a temperature of 100 DEG C, with 300
Rev/min mixing speed, stir 30 minutes, be prepared into novel ion liquid microemulsion.At room temperature, to above-mentioned novel ion liquid
Add photoinitiator in body microemulsion system, then with ultra violet lamp 0.5h, poly ion liquid gel is prepared in situ out.
Appearance, rheological property, mechanics is carried out to magnetic cellulose base poly ion liquid adsorbent manufactured in the present embodiment to draw
Stretch and tested with electrochemical AC impedance, specific performance parameter is shown in Table 1.The result shows that gained poly ion liquid gel has high energy storage
Modulus, strong mechanical property and high conductivity.
Embodiment 5
Claim raw material by following percentage by weight：Polarity phase ionic liquid [AEIm] Cl 2.3%, [ABIm] Cl3.4% are non-
Polarity phase ionic liquid [Hmim] PF610.3%th, [Omim] PF65%, surfactant allyloxy Nonylphenoxy propyl alcohol gathers
Ethylene oxide ether 35%, didecyl Dimethy ammonium methacrylate 30%, crosslinking agent polyethyleneglycol diacrylate 6.2%, second
Diol dimethacrylate 4.2%, photoinitiator 2- hydroxy-2-methyl -1- phenylacetones 1.8%, 1- hydroxy-cyclohexyl benzene
Base ketone 1.8%.
The ion liquid microemulsion light-initiated method for preparing poly ion liquid Signa Gel in situ：By above-mentioned polarity phase ion
Example mixes by mass percentage for liquid, nonpolar phase ionic liquid, surfactant, crosslinking agent, at a temperature of 20 DEG C, with 1200
Rev/min mixing speed, stir 10 minutes, be prepared into novel ion liquid microemulsion.At room temperature, to above-mentioned novel ion liquid
Add photoinitiator in body microemulsion system, then with ultra violet lamp 5h, poly ion liquid gel is prepared in situ out.
Appearance, rheological property, mechanics is carried out to magnetic cellulose base poly ion liquid adsorbent manufactured in the present embodiment to draw
Stretch and tested with electrochemical AC impedance, specific performance parameter is shown in Table 1.The result shows that gained poly ion liquid gel has high energy storage
Modulus, strong mechanical property and high conductivity.
The various performance parameters of 1 gained poly ion liquid gel of table
The detection method of various performance parameters is as follows in table 1：
(1) storage modulus：Stress control rheometer AR2000ex is tested.
(2) tensile strength：Linkam tension force thermal station TST350 is tested.
(3) room-temperature conductivity：Electrochemical workstation IviumStat is tested.
Above-described embodiment is the preferable embodiment of the present invention, but embodiments of the present invention and from the embodiment
Limitation, other any Spirit Essences without departing from the present invention with made under principle change, modification, replacement, combine, simplification,
Equivalent substitute mode is should be, is included within protection scope of the present invention.
Claims (10)
1. the preparation method of ion liquid microemulsion, it is characterised in that comprise the following steps：
(1) raw material is weighed by following percentage by weight：
(2) step (1) is weighed to obtained raw material to mix, in 20 DEG C~100 DEG C stirrings, is prepared into ion liquid microemulsion.
2. the preparation method of ion liquid microemulsion according to claim 1, it is characterised in that the polarity phase ionic liquid
Body is 1- pi-allyl -3- methylimidazole villaumites, in 1- pi-allyl -3- ethyl imidazol(e)s villaumite, 1- pi-allyl -3- butyl imidazole villaumites
At least one.
3. the preparation method of ion liquid microemulsion according to claim 1, it is characterised in that the nonpolar phase ion
Liquid is 1- butyl -3- methylimidazoles hexafluorophosphate, 1- hexyl -3- methylimidazoles hexafluorophosphate, 1- octyl group -3- butyl miaows
At least one of azoles hexafluorophosphate.
4. the preparation method of ion liquid microemulsion according to claim 1, it is characterised in that live on the polymerizable surface
Property agent for allyloxy Nonylphenoxy propyl alcohol polyoxyethylene ether ammonium sulfate, allyloxy Nonylphenoxy propyl alcohol polyoxyethylene
At least one of ether, didecyl Dimethy olefin(e) acid ammonium.
5. the preparation method of ion liquid microemulsion according to claim 1, it is characterised in that the crosslinking agent is poly- second
In omega-diol diacrylate, ethylene glycol dimethacrylate, 3,3'- dithiodipropionic acids two (N- hydroxysuccinimides) ester
At least one.
6. the preparation method of ion liquid microemulsion according to claim 1, it is characterised in that step (2) described stirring,
Specially：Mixing speed is 300rpm~1200rpm, and mixing time is 10 minutes~30 minutes.
7. the preparation method of poly ion liquid base Signa Gel, it is characterised in that comprise the following steps：
At room temperature, the ionic liquid being prepared in the preparation method of claim 1~6 any one of them ion liquid microemulsion
Add photoinitiator in body microemulsion, then with ultra violet lamp, poly ion liquid gel is prepared in situ out；The photoinitiator
Quality is the 0.5~3.6% of ion liquid microemulsion and photoinitiator gross mass.
8. the preparation method of poly ion liquid base Signa Gel according to claim 7, it is characterised in that described light-initiated
Agent is 2- hydroxy-2-methyl -1- phenylacetones, 1- hydroxycyclohexyl phenyl ketones, 2,4,6- trimethylbenzoy-diphenies
At least one of phosphine oxide.
9. the preparation method of poly ion liquid base Signa Gel according to claim 7, it is characterised in that the ultraviolet lamp
The time of irradiation is 0.5~5h.
10. poly ion liquid base Signa Gel, it is characterised in that by claim 7~9 any one of them poly ion liquid base
The preparation method of Signa Gel is prepared.
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| CN201711470162.1A CN108034026A (en) | 2017-12-29 | 2017-12-29 | The preparation method of ion liquid microemulsion, poly ion liquid base Signa Gel and preparation method thereof |
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| CN201711470162.1A CN108034026A (en) | 2017-12-29 | 2017-12-29 | The preparation method of ion liquid microemulsion, poly ion liquid base Signa Gel and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109796594A (en) * | 2019-01-03 | 2019-05-24 | 鲁东大学 | A kind of porous poly ion liquid conductive film and preparation method thereof |
| CN110387245A (en) * | 2019-08-28 | 2019-10-29 | 浙江海洋大学 | A kind of diesel fuel contaminated soil restorative procedure based on conductivity |
| CN113651913A (en) * | 2021-09-10 | 2021-11-16 | 浙江巨化股份有限公司氟聚厂 | Preparation method of high-strength polytetrafluoroethylene resin |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109796594A (en) * | 2019-01-03 | 2019-05-24 | 鲁东大学 | A kind of porous poly ion liquid conductive film and preparation method thereof |
| CN110387245A (en) * | 2019-08-28 | 2019-10-29 | 浙江海洋大学 | A kind of diesel fuel contaminated soil restorative procedure based on conductivity |
| CN110387245B (en) * | 2019-08-28 | 2021-06-08 | 浙江海洋大学 | Diesel oil contaminated soil remediation method based on conductivity |
| CN113651913A (en) * | 2021-09-10 | 2021-11-16 | 浙江巨化股份有限公司氟聚厂 | Preparation method of high-strength polytetrafluoroethylene resin |
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