CN108033651A - A kind of electroplating wastewater zero system - Google Patents
A kind of electroplating wastewater zero system Download PDFInfo
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- CN108033651A CN108033651A CN201711474164.8A CN201711474164A CN108033651A CN 108033651 A CN108033651 A CN 108033651A CN 201711474164 A CN201711474164 A CN 201711474164A CN 108033651 A CN108033651 A CN 108033651A
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- waste water
- water
- wastewater
- nickel
- basin
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- 239000002351 wastewater Substances 0.000 title claims abstract description 368
- 238000009713 electroplating Methods 0.000 title claims abstract description 14
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 206
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 113
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 103
- 230000001105 regulatory effect Effects 0.000 claims abstract description 91
- 238000005189 flocculation Methods 0.000 claims abstract description 67
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 60
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 60
- 239000011574 phosphorus Substances 0.000 claims abstract description 60
- 230000016615 flocculation Effects 0.000 claims abstract description 58
- 238000004069 wastewater sedimentation Methods 0.000 claims abstract description 54
- 238000006243 chemical reaction Methods 0.000 claims abstract description 44
- 239000010802 sludge Substances 0.000 claims abstract description 43
- 230000001112 coagulating effect Effects 0.000 claims abstract description 37
- 239000010865 sewage Substances 0.000 claims abstract description 23
- 239000012141 concentrate Substances 0.000 claims abstract description 11
- 239000012528 membrane Substances 0.000 claims abstract description 8
- 238000001704 evaporation Methods 0.000 claims abstract description 7
- 230000008020 evaporation Effects 0.000 claims abstract description 7
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims description 67
- 238000004043 dyeing Methods 0.000 claims description 44
- 238000001764 infiltration Methods 0.000 claims description 27
- 238000004062 sedimentation Methods 0.000 claims description 22
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 21
- 229910052760 oxygen Inorganic materials 0.000 claims description 21
- 239000001301 oxygen Substances 0.000 claims description 21
- 239000006004 Quartz sand Substances 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- 239000007788 liquid Substances 0.000 claims description 18
- 238000000108 ultra-filtration Methods 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 239000003513 alkali Substances 0.000 claims description 15
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 239000005416 organic matter Substances 0.000 claims description 12
- 238000000926 separation method Methods 0.000 claims description 12
- 239000007787 solid Substances 0.000 claims description 12
- 229910052573 porcelain Inorganic materials 0.000 claims description 10
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims description 9
- 229910002651 NO3 Inorganic materials 0.000 claims description 9
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 9
- 239000000084 colloidal system Substances 0.000 claims description 9
- 239000003456 ion exchange resin Substances 0.000 claims description 9
- 229920003303 ion-exchange polymer Polymers 0.000 claims description 9
- 238000005204 segregation Methods 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 230000000694 effects Effects 0.000 claims description 8
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 241000894006 Bacteria Species 0.000 claims description 6
- 239000000701 coagulant Substances 0.000 claims description 6
- 239000003814 drug Substances 0.000 claims description 6
- 239000000945 filler Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 238000001223 reverse osmosis Methods 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 239000006228 supernatant Substances 0.000 claims description 6
- 230000015572 biosynthetic process Effects 0.000 claims description 5
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 5
- 238000003786 synthesis reaction Methods 0.000 claims description 5
- 230000006835 compression Effects 0.000 claims description 4
- 238000007906 compression Methods 0.000 claims description 4
- 238000010612 desalination reaction Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- 239000013535 sea water Substances 0.000 claims description 4
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 claims description 3
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 claims description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 3
- 238000005273 aeration Methods 0.000 claims description 3
- 241001148470 aerobic bacillus Species 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 230000003139 buffering effect Effects 0.000 claims description 3
- 229910001424 calcium ion Inorganic materials 0.000 claims description 3
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 3
- 239000000706 filtrate Substances 0.000 claims description 3
- 230000003311 flocculating effect Effects 0.000 claims description 3
- 230000005484 gravity Effects 0.000 claims description 3
- 239000012510 hollow fiber Substances 0.000 claims description 3
- 239000012535 impurity Substances 0.000 claims description 3
- 229910001410 inorganic ion Inorganic materials 0.000 claims description 3
- 229910001425 magnesium ion Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 239000011572 manganese Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 150000002894 organic compounds Chemical class 0.000 claims description 3
- 125000001477 organic nitrogen group Chemical group 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 238000000247 postprecipitation Methods 0.000 claims description 3
- 239000008213 purified water Substances 0.000 claims description 3
- 230000035484 reaction time Effects 0.000 claims description 3
- 238000010992 reflux Methods 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 238000007781 pre-processing Methods 0.000 claims 1
- 230000001376 precipitating effect Effects 0.000 claims 1
- 238000005516 engineering process Methods 0.000 abstract description 6
- 239000003344 environmental pollutant Substances 0.000 abstract description 5
- 231100000719 pollutant Toxicity 0.000 abstract description 5
- 230000026676 system process Effects 0.000 description 5
- 238000011109 contamination Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003673 groundwater Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/42—Treatment of water, waste water, or sewage by ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/441—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by reverse osmosis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
- C02F1/444—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/16—Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/30—Aerobic and anaerobic processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
- Y02A20/131—Reverse-osmosis
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
A kind of electroplating wastewater zero system, the present invention relates to technical field of sewage;Nickel-containing waste water regulating reservoir, nickel-containing waste water PH regulating reservoirs, nickel-containing waste water buffer pool, nickel-containing waste water coagulating basin, the bottom of nickel-containing waste water flocculation basin and nickel-containing waste water sedimentation basin are connected by pipeline with nickel-containing sludge concentration basin, nickel-containing sludge concentration basin is connected with nickel-containing sludge compressor, and the concentrate in nickel-containing sludge compressor is connected by pipeline with nickel-containing waste water regulating reservoir;Connected between phosphorus-containing wastewater regulating reservoir, phosphorus-containing wastewater PH regulating reservoirs, phosphorus-containing wastewater reaction tank, phosphorus-containing wastewater coagulating basin, phosphorus-containing wastewater flocculation basin and phosphorus-containing wastewater sedimentation basin by pipeline.Its pollutants removal rate is high, operates steadily, and rationally using advanced membrane technology, reduces film and blocks, ensure the service life of film, improve the producing water ratio of film, while can reduce evaporation cost, and practicality is stronger.
Description
Technical field
The present invention relates to technical field of sewage, and in particular to a kind of electroplating wastewater zero system.
Background technology
In shortage of water resources, environmental pollution serious today, to alleviate the imbalance between supply and demand of water resource, containment water environment degradation
The impetus, the utilization ratio of water need to be improved, the discharge of pollutant is reduced, accomplish zero-emission as much as possible.But due to contaminated wastewater
Thing concentration is high, contamination class is more, cause wastewater zero discharge is ineffective, concentrated water amount is big, film it is dirty it is stifled it is serious, up-front investment is big, fortune
Seek that of high cost, treatment effect stability is poor, it would be highly desirable to improve.
The content of the invention
In view of the defects and deficiencies of the prior art, the present invention intends to provide a kind of simple in structure, design rationally, make
With convenient electroplating wastewater zero system, its pollutants removal rate is high, operates steadily, and floor space is few, reduces sludge quantity, closes
Reason utilizes advanced membrane technology, reduces film and blocks, ensures the service life of film, improve the producing water ratio of film, while can reduce steaming
Cost is sent out, practicality is stronger.
To achieve the above object, the technical solution adopted by the present invention is:It includes effluent segregation pretreatment system and synthesis
Processing system;Wherein effluent segregation pretreatment system is connected by pipeline with total system;The effluent segregation is located in advance
Reason system includes nickel-containing waste water pretreatment system, treatment of Phosphorus Containing Waste Water system, ammonia nitrogen waste water processing system and modifying porcelain
System;The nickel-containing waste water processing system by nickel-containing waste water regulating reservoir, nickel-containing waste water PH regulating reservoirs, nickel-containing waste water buffer pool,
Nickel-containing waste water coagulating basin, nickel-containing waste water flocculation basin, nickel-containing waste water sedimentation basin, nickel-containing sludge concentration basin and nickel-containing sludge compression mechanism
Into nickel-containing waste water regulating reservoir, nickel-containing waste water PH regulating reservoirs, nickel-containing waste water buffer pool, nickel-containing waste water coagulating basin, nickel-containing waste water flocculation
Connected between pond, nickel-containing waste water sedimentation basin by pipeline, wherein nickel-containing waste water regulating reservoir, nickel-containing waste water PH regulating reservoirs, Nickel-bearing Waste
Water buffer pool, nickel-containing waste water coagulating basin, the bottom of nickel-containing waste water flocculation basin and nickel-containing waste water sedimentation basin pass through pipeline and nickeliferous dirt
Mud thickener connects, and nickel-containing sludge concentration basin is connected with nickel-containing sludge compressor, and the concentrate in nickel-containing sludge compressor passes through
Pipeline is connected with nickel-containing waste water regulating reservoir;The treatment of Phosphorus Containing Waste Water system is by phosphorus-containing wastewater regulating reservoir, phosphorus-containing wastewater PH tune
Pond, phosphorus-containing wastewater reaction tank, phosphorus-containing wastewater coagulating basin, phosphorus-containing wastewater flocculation basin and phosphorus-containing wastewater sedimentation basin is saved to form, it is phosphorous useless
Water regulating reservoir, phosphorus-containing wastewater PH regulating reservoirs, phosphorus-containing wastewater reaction tank, phosphorus-containing wastewater coagulating basin, phosphorus-containing wastewater flocculation basin and phosphorous
Connected between effluent settling chamber by pipeline;The ammonia nitrogen waste water processing system is adjusted by ammonia nitrogen regulating reservoir, ammonia nitrogen waste water PH
Pond, ammonia nitrogen waste water reaction tank, ammonia nitrogen waste water coagulating basin, ammonia nitrogen waste water flocculation basin and ammonia nitrogen waste water sedimentation basin are formed, and ammonia nitrogen is adjusted
Pond, ammonia nitrogen waste water PH regulating reservoirs, ammonia nitrogen waste water reaction tank, ammonia nitrogen waste water coagulating basin, ammonia nitrogen waste water flocculation basin and ammonia nitrogen waste water sink
Shallow lake is connected between pond by pipeline;The modifying porcelain system by dyeing waste-water regulating reservoir, dyeing waste-water PH regulating reservoirs,
Dyeing waste-water reaction tank, dyeing waste-water flocculation basin, dyeing waste-water flocculation basin and dyeing waste-water sedimentation basin are formed, and dyeing waste-water is adjusted
Pond, dyeing waste-water PH regulating reservoirs, dyeing waste-water reaction tank, dyeing waste-water flocculation basin, dyeing waste-water flocculation basin and dyeing waste-water sink
Shallow lake is connected between pond by pipeline;The total system is by comprehensive wastewater regulating reservoir, comprehensive wastewater PH regulating reservoirs, synthesis
Waste water reaction pond, No.1 comprehensive wastewater coagulating basin, No.1 comprehensive wastewater flocculation basin, No.1 comprehensive wastewater sedimentation basin, PH demodulate pond,
Comprehensive wastewater oxygen compatibility pool, comprehensive wastewater aerobic tank, No. two comprehensive wastewater flocculation basins, No. two comprehensive wastewater sedimentation basins, comprehensive clear water
Pond, advanced treatment system, counter-infiltration system, concentrated water counter-infiltration system, MVR evaporators, comprehensive sludge concentration tank, comprehensive sludge pressure
Contracting mechanism into;Wherein comprehensive wastewater regulating reservoir, comprehensive wastewater PH regulating reservoirs, comprehensive wastewater reaction tank, No.1 comprehensive wastewater coagulation
Pond, No.1 comprehensive wastewater flocculation basin, No.1 comprehensive wastewater sedimentation basin, PH anti-tunes pond, comprehensive wastewater oxygen compatibility pool, comprehensive wastewater are aerobic
Pond, No. two comprehensive wastewater flocculation basins, No. two comprehensive wastewater sedimentation basins, comprehensive clear water reserviors are sequentially connected by pipeline, the depth
Degree processing system is made of quartz sand filter, active carbon filter, ion exchange resin tank and ultrafiltration system;Comprehensive clear water reserviors pass through
Pipeline is connected with quartz sand filter, quartz sand filter, active carbon filter, ion exchange resin tank, ultrafiltration system by pipeline according to
Secondary connection, ultrafiltration system are connected by pipeline with counter-infiltration system, and counter-infiltration system is connected by pipeline and concentrated water counter-infiltration system
Connect, concentrated water counter-infiltration system is connected by pipeline with MVR evaporators;The comprehensive wastewater regulating reservoir, comprehensive wastewater PH are adjusted
Pond, comprehensive wastewater reaction tank, No.1 comprehensive wastewater coagulating basin, No.1 comprehensive wastewater flocculation basin, No.1 comprehensive wastewater sedimentation basin, PH
Demodulate pond, comprehensive wastewater oxygen compatibility pool, comprehensive wastewater aerobic tank, No. two comprehensive wastewater flocculation basins and No. two comprehensive wastewater sedimentation basins
Bottom is connected by pipeline with comprehensive sludge concentration tank, and the concentrate of comprehensive sludge concentration tank passes through pipeline and comprehensive wastewater tune
Save pond connection.
Further, the ultrafiltration system is connected by pipeline with comprehensive clear water reserviors.
Further, the counter-infiltration system is connected by pipeline with reuse pool.
Further, the nickel-containing waste water sedimentation basin, phosphorus-containing wastewater sedimentation basin, ammonia nitrogen waste water sedimentation basin and dyeing waste-water
Sedimentation basin is connected by pipeline with pretreatment clear water reserviors.
Further, the comprehensive adjustment pond is connected by pipeline with emergency lagoon.
The workflow of the present invention is as follows:
1st, each waste water in workshop is collected to corresponding regulating reservoir through pipe network respectively, and regulating reservoir bottom sets perforated pipe, not timing into
Row air stirring, to realize that the homogeneous of waste water is measured;Then corresponding PH regulating reservoirs and anti-are promoted under the action of elevator pump
Ying Chi, reaction tank set mechanical agitation, are higher by post precipitation pond 1.5m, and bottom is maked somebody a mere figurehead, as dosing room and Ventilator Room;Nickel-containing waste water
Pretreatment system is divided into four lattice, and alkali is added in the first lattice, pH is adjusted to 9-10, dosage is controlled by pH meter;Second lattice are slow
Punching, improves the reaction time;3rd lattice and the 4th lattice are separately added into coagulant and flocculant, remove nickel and partial suspended in waste water
Thing;Phosphorus-containing wastewater four lattice of pretreatment system point, add alkali in the first lattice, pH are adjusted to neutrality, dosage is controlled by pH meter;The
Two lattice add dephosphorization agent, remove in waste water 15~40% COD, are down to 0.4mg/l from 400mg/l by phosphorus is phosphorous, the 3rd lattice and
4th lattice are separately added into coagulant and flocculant, it is ensured that effluent quality;Ammonia nitrogen waste water four lattice of pretreatment system point, in the first lattice)
Middle addition alkali, is adjusted to 9-10, dosage is controlled by pH meter by pH;Three lattice are separately added into except ammonia nitrogen medicament and coagulation-flocculation agent afterwards,
Reduce the content of ammonia nitrogen;Dyeing waste-water four lattice of pretreatment system point, add alkali in the first lattice, pH are adjusted to 8.5-9.5, dosing
Amount is controlled by pH meter;Three lattice are separately added into decolorising agent and coagulation-flocculation agent afterwards, reduce the colourity of waste water;By each of agent-feeding treatment
Stock waste water flow to sedimentation basin and carries out separation of solid and liquid certainly respectively;Sedimentation basin uses inclined-tube sedimentation tank, and inclined-tube sedimentation tank is former using laminar flow
Reason, improves the disposal ability of sedimentation basin, and water project situation is good, shortens particle settling height, so as to shorten the sedimentation time, handles
It is efficient, reduce the load of follow-up structures;
2nd, dosing room reaction tank in ammonia nitrogen waste water processing system, modifying porcelain system and total system
Lower section, the high 1m in dosing pond, top and ground maintain an equal level waste water station, and width is set at the top of dosing pond as 1.2m drawing medicine passages, can directly pushed up
Portion's dosing;
3rd, pretreated waste water flow to comprehensive wastewater regulating reservoir through gravity, by being lifted with comprehensive wastewater after mixing
After pump is promoted to comprehensive wastewater PH regulating reservoirs, then to sequentially enter comprehensive wastewater reaction tank, No.1 comprehensive wastewater coagulating basin, No.1 comprehensive
Waste water flocculating pond, No.1 comprehensive wastewater sedimentation basin are closed, enables to be difficult to the particle precipitated in water by adding alkali and coagulation-flocculation agent
It is aggregated with one another and forms colloid, the floccule body of bigger is then combined to form with the impurity in water body, the waste water that the reaction was complete is heavy
Separation of solid and liquid is carried out in the pond of shallow lake;
4th, after the supernatant by separation of solid and liquid enters PH anti-tunes pond, comprehensive wastewater oxygen compatibility pool is entered back into, denitrifying bacterium exists
Dissolved oxygen concentration is extremely low or anaerobic condition under can be by the use of nitrogen in nitrate as electron acceptor oxidation of organic compounds, by nitrate also
Original is into nitrogen, so as to fulfill the denitrification process of sewage;Its water outlet sets combined stuffing from comprehensive wastewater aerobic tank is flow in pond,
Bottom of pond aeration is oxygenated sewage, and sewage in pond body is in flow regime, to ensure that sewage is filled with the filler in sewage
Tap is touched, and avoids sewage from contacting inequality with filler, and organic matter further is converted into inorganic matter by aerobic bacteria effect, goes to decontaminate
Thing is contaminated, while organic matter is removed, the organic nitrogen in sewage is also oxidized to ammonia nitrogen, and ammonia nitrogen is in dissolved oxygen abundance, sludge age
In the case of longer, nitrite and nitrate are further converted into, aerobic tank end sets mixed-liquor return device, according to waste water
Actual treatment situation, select suitable reflux ratio;
5th, the waste water after comprehensive wastewater oxygen compatibility pool and the processing of comprehensive wastewater aerobic tank sequentially enters No. two comprehensive wastewaters
Flocculation basin, No. two comprehensive wastewater sedimentation basins, carry out separation of solid and liquid in secondary settling tank, reduce the suspended matter of water outlet, ensure water outlet water
Matter, after its supernatant enters comprehensive clear water reserviors, finally enters depth pretreatment system;Quartz sand filter in advanced treatment system
Using quartz sand as filtrate, the suspended matter in water removal is effectively removed, and remove the pollution such as water part colloid, iron, organic matter, manganese
Thing;Active carbon filter is built-in to fill out quartz sand thickness and high grade activated carbon, removes most of peculiar smell, organic matter, colloid, iron in waste water
And chlorine residue, the colourity of waste water is reduced, is purified water;Loaded resin in ion exchange resin tank, goes the calcium ions and magnesium ions in water removal, drop
Hardness in low water;Ultrafiltration system uses hollow fiber ultrafiltration film, retains the bacterium in waste water and partial organic substances;
6th, enter counter-infiltration system by the middle water of depth pretreatment system, for electroplating wastewater electrical conductivity it is high the characteristics of,
Select that producing water ratio is high, salt rejection rate is high, resistant to pollution sea water desalination membrane, various inorganic ions, colloidal substance in trap water and big
Molecule solute, its production water are discharged into reuse pool and are used for reuse, and concentrated water enters concentrated water counter-infiltration system, improves the producing water ratio of system,
Concentrated water amount is reduced, concentrated water counter-infiltration system is reverse osmosis using network pipe type;
7th, counter-infiltration system concentrated water enters MVR evaporators after water tank caches, and MVR evaporators utilize what is produced in evaporator
Indirect steam, compresses through compressor, pressure, temperature rise, heat content increase, and the heating chamber for being then delivered to evaporator is steamed as heating
Vapour uses, and feed liquid is maintained fluidized state, and heats steam and be then condensed into water in itself, and liquid reuse, concentrate are evaporated after evaporation
Committee is outer.
With the above structure, the present invention has the beneficial effect that:
1st, contaminant removal efficiency is high, and system operation is steady;
2nd, according to the concrete condition of waste water, dexterously using Individual pretreatment, effect stability, pollutant removal are thorough, behaviour
Make convenient, flexible operation;
3rd, reaction tank is maked somebody a mere figurehead, and stereovision is strong, reduces floor space;
The 4th, dosing room is dexterously set, rational in infrastructure, dispensing operation is convenient, and labor intensity is low;
5th, using special dephosphorization agent, sludge quantity is efficiently reduced, reduces fixed-end forces cost;
6th, technique is advanced, reasonably using advanced membrane technology and species, reduces the dirty service life blocked up, ensure film of film,
Water consumption processed is relatively low, reduces concentrated water amount, reduces evaporation cost.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing
There is attached drawing needed in technology description to be briefly described, it should be apparent that, drawings in the following description are only this
Some embodiments of invention, for those of ordinary skill in the art, without having to pay creative labor, may be used also
To obtain other attached drawings according to these attached drawings.
Fig. 1 is nickel-containing waste water pretreatment system process flow chart in the present invention.
Fig. 2 is treatment of Phosphorus Containing Waste Water system process figure in the present invention.
Fig. 3 is ammonia nitrogen waste water processing system process flow chart in the present invention.
Fig. 4 is modifying porcelain system process figure in the present invention.
Fig. 5 is total system process flow chart in the present invention.
Fig. 6 is nickel-containing sludge concentration basin and nickel-containing sludge compressor connection diagram in the present invention.
Fig. 7 is comprehensive sludge concentration tank and comprehensive sludge compressor connection diagram in the present invention.
Fig. 8 is the superstructure distribution plane figure of the present invention.
Fig. 9 is the understructure distribution plane figure of the present invention.
Figure 10 is sectional view along A-A in Fig. 8.
Figure 11 is B-B direction sectional view in Fig. 8.
Figure 12 be in Fig. 8 C-C to sectional view.
Embodiment
The present invention is further illustrated below in conjunction with the accompanying drawings.
Referring to as shown in Fig. 1-Figure 12, the technical solution that present embodiment uses is:It locates in advance comprising effluent segregation
Reason system and total system;Wherein effluent segregation pretreatment system is connected by pipeline with total system;Described
Effluent segregation pretreatment system include nickel-containing waste water pretreatment system, treatment of Phosphorus Containing Waste Water system, ammonia nitrogen waste water processing system and
Modifying porcelain system;The nickel-containing waste water processing system is by nickel-containing waste water regulating reservoir, nickel-containing waste water PH regulating reservoirs, nickeliferous
Waste water buffer pool, nickel-containing waste water coagulating basin, nickel-containing waste water flocculation basin, nickel-containing waste water sedimentation basin, nickel-containing sludge concentration basin and nickeliferous
Sludge compression mechanism into, nickel-containing waste water regulating reservoir, nickel-containing waste water PH regulating reservoirs, nickel-containing waste water buffer pool, nickel-containing waste water coagulating basin,
Connected between nickel-containing waste water flocculation basin, nickel-containing waste water sedimentation basin by pipeline, wherein nickel-containing waste water regulating reservoir, nickel-containing waste water PH tune
The bottom for saving pond, nickel-containing waste water buffer pool, nickel-containing waste water coagulating basin, nickel-containing waste water flocculation basin and nickel-containing waste water sedimentation basin passes through pipe
Road is connected with nickel-containing sludge concentration basin, and nickel-containing sludge concentration basin is connected with nickel-containing sludge compressor, in nickel-containing sludge compressor
Concentrate is connected by pipeline with nickel-containing waste water regulating reservoir;The treatment of Phosphorus Containing Waste Water system by phosphorus-containing wastewater regulating reservoir, contain
Phosphorus waste water PH regulating reservoirs, phosphorus-containing wastewater reaction tank, phosphorus-containing wastewater coagulating basin, phosphorus-containing wastewater flocculation basin and phosphorus-containing wastewater sedimentation basin structure
Into phosphorus-containing wastewater regulating reservoir, phosphorus-containing wastewater PH regulating reservoirs, phosphorus-containing wastewater reaction tank, phosphorus-containing wastewater coagulating basin, phosphorus-containing wastewater flocculation
Connected between pond and phosphorus-containing wastewater sedimentation basin by pipeline;The ammonia nitrogen waste water processing system is given up by ammonia nitrogen regulating reservoir, ammonia nitrogen
Water PH regulating reservoirs, ammonia nitrogen waste water reaction tank, ammonia nitrogen waste water coagulating basin, ammonia nitrogen waste water flocculation basin and ammonia nitrogen waste water sedimentation basin are formed,
Ammonia nitrogen regulating reservoir, ammonia nitrogen waste water PH regulating reservoirs, ammonia nitrogen waste water reaction tank, ammonia nitrogen waste water coagulating basin, ammonia nitrogen waste water flocculation basin and ammonia
Connected between nitrogen effluent settling chamber by pipeline;The modifying porcelain system is by dyeing waste-water regulating reservoir, dyeing waste-water
PH regulating reservoirs, dyeing waste-water reaction tank, dyeing waste-water flocculation basin, dyeing waste-water flocculation basin and dyeing waste-water sedimentation basin are formed, dye
Color wastewater equalization pond, dyeing waste-water PH regulating reservoirs, dyeing waste-water reaction tank, dyeing waste-water flocculation basin, dyeing waste-water flocculation basin and
Connected between dyeing waste-water sedimentation basin by pipeline;The total system is by comprehensive wastewater regulating reservoir, comprehensive wastewater PH
Regulating reservoir, comprehensive wastewater reaction tank, No.1 comprehensive wastewater coagulating basin, No.1 comprehensive wastewater flocculation basin, No.1 comprehensive wastewater precipitation
Pond, PH demodulate pond, comprehensive wastewater oxygen compatibility pool, comprehensive wastewater aerobic tank, No. two comprehensive wastewater flocculation basins, No. two comprehensive wastewater precipitations
Pond, comprehensive clear water reserviors, advanced treatment system, counter-infiltration system, MVR evaporators, comprehensive sludge concentration tank, comprehensive sludge compressor
Form;Wherein comprehensive wastewater regulating reservoir, comprehensive wastewater PH regulating reservoirs, comprehensive wastewater reaction tank, No.1 comprehensive wastewater coagulating basin, one
Number comprehensive wastewater flocculation basin, No.1 comprehensive wastewater sedimentation basin, PH demodulate pond, comprehensive wastewater oxygen compatibility pool, comprehensive wastewater aerobic tank, two
Number comprehensive wastewater flocculation basin, No. two comprehensive wastewater sedimentation basins, comprehensive clear water reserviors are sequentially connected by pipeline, the advanced treating
System is made of quartz sand filter, active carbon filter, ion exchange resin tank and ultrafiltration system;Comprehensive clear water reserviors by pipeline with
Quartz sand filter connects, and quartz sand filter, active carbon filter, ion exchange resin tank, ultrafiltration system are sequentially connected by pipeline,
Ultrafiltration system is connected by pipeline with counter-infiltration system, and counter-infiltration system is connected by pipeline with MVR evaporators;The synthesis
Wastewater equalization pond, comprehensive wastewater PH regulating reservoirs, comprehensive wastewater reaction tank, No.1 comprehensive wastewater coagulating basin, No.1 comprehensive wastewater wadding
Solidifying pond, No.1 comprehensive wastewater sedimentation basin, PH demodulate pond, comprehensive wastewater oxygen compatibility pool, comprehensive wastewater aerobic tank, No. two comprehensive wastewater waddings
Solidifying pond and the bottom of No. two comprehensive wastewater sedimentation basins are connected by pipeline with comprehensive sludge concentration tank, comprehensive sludge concentration tank
Concentrate is connected by pipeline with comprehensive wastewater regulating reservoir.
Further, the ultrafiltration system is connected by pipeline with comprehensive clear water reserviors.
Further, the counter-infiltration system is connected by pipeline with reuse pool.
Further, the nickel-containing waste water sedimentation basin, phosphorus-containing wastewater sedimentation basin, ammonia nitrogen waste water sedimentation basin and dyeing waste-water
Sedimentation basin is connected by pipeline with pretreatment clear water reserviors.
Further, the comprehensive adjustment pond is connected by pipeline with emergency lagoon.
The workflow of present embodiment is as follows:
1st, each waste water in workshop is collected to corresponding regulating reservoir through pipe network respectively, and regulating reservoir bottom sets perforated pipe, not timing into
Row air stirring, to realize that the homogeneous of waste water is measured;Then corresponding PH regulating reservoirs and anti-are promoted under the action of elevator pump
Ying Chi, reaction tank set mechanical agitation, are higher by post precipitation pond 1.5m, and bottom is maked somebody a mere figurehead, and as dosing room and Ventilator Room, increase useless
The stereovision of water station, conveniently observes the overall condition of waste water station, improves the utilization rate in space;Nickel-containing waste water pretreatment system point
For four lattice, (nickel-containing waste water PH regulating reservoirs) adds alkali in the first lattice, pH is adjusted to 9-10, dosage is controlled by pH meter;Second
Lattice are buffering (nickel-containing waste water buffer pool), improve the reaction time;3rd lattice and the 4th lattice (nickel-containing waste water coagulating basin, nickel-containing waste water
Flocculation basin) coagulant and flocculant are separately added into, remove nickel and partial suspended thing in waste water;Phosphorus-containing wastewater pretreatment system point
Four lattice, (phosphorus-containing wastewater PH regulating reservoirs) adds alkali in the first lattice, pH is adjusted to neutrality, dosage is controlled by pH meter;Second lattice
(phosphorus-containing wastewater reaction tank) adds special dephosphorization agent, removes in waste water 15~40% COD, and phosphorus is phosphorous from 400mg/l drops
To 0.4mg/l, the 3rd lattice and the 4th lattice (phosphorus-containing wastewater coagulating basin, phosphorus-containing wastewater flocculation basin) are separately added into coagulant and flocculation
Agent, it is ensured that effluent quality;Ammonia nitrogen waste water four lattice of pretreatment system point, add alkali in the first lattice (ammonia nitrogen waste water PH regulating reservoirs),
PH is adjusted to 9-10, dosage is controlled by pH meter;Three lattice (ammonia nitrogen waste water reaction tank, ammonia nitrogen waste water coagulating basin, ammonia nitrogen waste water wadding afterwards
Solidifying pond) it is separately added into and except ammonia nitrogen medicament and coagulation-flocculation agent, reduces the content of ammonia nitrogen;Dyeing waste-water four lattice of pretreatment system point,
Alkali is added in the first lattice (dyeing waste-water PH regulating reservoirs), pH is adjusted to 8.5-9.5, dosage is controlled by pH meter;Three lattice (dye afterwards
Color waste water reaction pond, dyeing waste-water flocculation basin, dyeing waste-water flocculation basin) decolorising agent and coagulation-flocculation agent are separately added into, reduce useless
The colourity of water;Sedimentation basin is flow to certainly respectively by each stock waste water of agent-feeding treatment carries out separation of solid and liquid;Sedimentation basin is sunk using inclined tube
Shallow lake pond, inclined-tube sedimentation tank utilize lamina flow principle, improve the disposal ability of sedimentation basin, and water project situation is good, shorten particle sedimentation away from
From so as to shorten the sedimentation time, treatment effeciency is high, reduces the load of follow-up structures;
2nd, dosing room reaction tank in ammonia nitrogen waste water processing system, modifying porcelain system and total system
Lower section, is connected by walkway board with ground, the high 1m in dosing pond, and top maintains an equal level with ground, and waste water station (adopt by the follow-up structures of regulating reservoir
It is buried with half, buried 1m), dosing pond top sets width and draws medicine passage as 1.2m, can be follow-up to draw prescription just directly in top dosing,
Work difficulty is reduced, improves work efficiency and dosing security, it is highly practical;
3rd, pretreated waste water flow to comprehensive wastewater regulating reservoir through gravity, by being lifted with comprehensive wastewater after mixing
After pump is promoted to comprehensive wastewater PH regulating reservoirs, then to sequentially enter comprehensive wastewater reaction tank, No.1 comprehensive wastewater coagulating basin, No.1 comprehensive
Waste water flocculating pond, No.1 comprehensive wastewater sedimentation basin are closed, enables to be difficult to the particle precipitated in water by adding alkali and coagulation-flocculation agent
It is aggregated with one another and forms colloid, the floccule body of bigger is then combined to form with the impurity in water body, improves the precipitation effect of sedimentation basin
Fruit, the waste water that the reaction was complete carry out separation of solid and liquid in sedimentation basin;
4th, after the supernatant by separation of solid and liquid enters PH anti-tunes pond, comprehensive wastewater oxygen compatibility pool is entered back into, denitrifying bacterium exists
Dissolved oxygen concentration is extremely low or anaerobic condition under can be by the use of nitrogen in nitrate as electron acceptor oxidation of organic compounds, by nitrate also
Original is into nitrogen, so as to fulfill the denitrification process of sewage;Its water outlet sets combined stuffing from comprehensive wastewater aerobic tank is flow in pond,
Bottom of pond aeration is oxygenated sewage, and sewage in pond body is in flow regime, to ensure that sewage is filled with the filler in sewage
Tap is touched, and avoids sewage from contacting inequality with filler, and organic matter further is converted into inorganic matter by aerobic bacteria effect, goes to decontaminate
Thing is contaminated, while organic matter is removed, the organic nitrogen in sewage is also oxidized to ammonia nitrogen, and ammonia nitrogen is in dissolved oxygen abundance, sludge age
In the case of longer, nitrite and nitrate are further converted into, aerobic tank end sets mixed-liquor return device, according to waste water
Actual treatment situation, select suitable reflux ratio, to reach optimal denitrification effect, ensure the water inlet of successive depths processing system
Water quality;
5th, the waste water after comprehensive wastewater oxygen compatibility pool and the processing of comprehensive wastewater aerobic tank sequentially enters No. two comprehensive wastewaters
Flocculation basin, No. two comprehensive wastewater sedimentation basins, carry out separation of solid and liquid in secondary settling tank, reduce the suspended matter of water outlet, ensure water outlet water
Matter, after its supernatant enters comprehensive clear water reserviors, finally enters depth pretreatment system;Quartz sand filter in advanced treatment system
Using quartz sand as filtrate, the suspended matter in water removal is effectively removed, and remove the pollution such as water part colloid, iron, organic matter, manganese
Thing;Active carbon filter is built-in to fill out quartz sand thickness and high grade activated carbon, removes most of peculiar smell, organic matter, colloid, iron in waste water
And chlorine residue, the colourity of waste water is reduced, is purified water;Loaded resin in ion exchange resin tank, goes the calcium ions and magnesium ions in water removal, drop
Hardness in low water;Ultrafiltration system uses hollow fiber ultrafiltration film, retains the bacterium in waste water and partial organic substances;The pretreatment system
It can ensure that reverse osmosis into water environment, reduce the pollution of film, reduce later stage operation energy consumption;
6th, enter counter-infiltration system by the middle water of depth pretreatment system, for electroplating wastewater electrical conductivity it is high the characteristics of,
Select that producing water ratio is high, salt rejection rate is high, resistant to pollution sea water desalination membrane, various inorganic ions, colloidal substance in trap water and big
Molecule solute, its production water are discharged into reuse pool and are used for reuse, and concentrated water enters concentrated water counter-infiltration system, improves the producing water ratio of system,
Concentrated water amount is reduced, concentrated water counter-infiltration system is reverse osmosis using network pipe type, the reverse osmosis spy for combining rolled film and DT films of network pipe type
Point, equivalent to 2.8 DT films of a disposal ability, its contamination resistance is strong, and for influent COD up to 20000mg/l, concentrated water TDS can
Up to 100000mg/l;The rate of recovery is high, for high pollution waste water, its rate of recovery up to 80%, scientifically using sea water desalination membrane and
The reverse osmosis combination of network pipe type, membranous system operates steadily, contamination resistance is strong, and producing water ratio is up to 90%, reduces concentrated water amount, reduces
The construction cost and operation cost of subsequent evaporation device, has saved the energy;
7th, counter-infiltration system concentrated water enters MVR evaporators after water tank caches, and MVR evaporators utilize what is produced in evaporator
Indirect steam, compresses through compressor, pressure, temperature rise, heat content increase, and the heating chamber for being then delivered to evaporator is steamed as heating
Vapour uses, and feed liquid is maintained fluidized state, and heats steam and be then condensed into water in itself, and liquid reuse, concentrate are evaporated after evaporation
Committee is outer.MVR evaporators, so as to greatly reduce energy consumption, reduce fortune since 100% recycles the potential of indirect steam
Row cost, the degree of automation is high, and compact-sized, floor space is small.
With the above structure, present embodiment has the beneficial effect that:A kind of plating that present embodiment provides
Wastewater zero discharge system, its pollutants removal rate is high, operates steadily, and floor space is few, sludge quantity is reduced, rationally using advanced
Membrane technology, reduces film and blocks, ensure the service life of film, improve the producing water ratio of film, while can reduce evaporation cost, practicality
It is stronger.
The above, is merely illustrative of the technical solution of the present invention and unrestricted, those of ordinary skill in the art are to this hair
The other modifications or equivalent substitution that bright technical solution is made, without departing from the spirit and scope of technical solution of the present invention,
It should all cover among scope of the presently claimed invention.
Claims (6)
- A kind of 1. electroplating wastewater zero system, it is characterised in that:It includes effluent segregation pretreatment system and integrated treatment system System;Wherein effluent segregation pretreatment system is connected by pipeline with total system;The effluent segregation pretreatment system Include nickel-containing waste water pretreatment system, treatment of Phosphorus Containing Waste Water system, ammonia nitrogen waste water processing system and modifying porcelain system;Institute The nickel-containing waste water processing system stated is by nickel-containing waste water regulating reservoir, nickel-containing waste water PH regulating reservoirs, nickel-containing waste water buffer pool, nickel-containing waste water Coagulating basin, nickel-containing waste water flocculation basin, nickel-containing waste water sedimentation basin, nickel-containing sludge concentration basin and nickel-containing sludge compression mechanism are into nickeliferous It is wastewater equalization pond, nickel-containing waste water PH regulating reservoirs, nickel-containing waste water buffer pool, nickel-containing waste water coagulating basin, nickel-containing waste water flocculation basin, nickeliferous Connected between effluent settling chamber by pipeline, wherein nickel-containing waste water regulating reservoir, nickel-containing waste water PH regulating reservoirs, nickel-containing waste water buffering Pond, nickel-containing waste water coagulating basin, the bottom of nickel-containing waste water flocculation basin and nickel-containing waste water sedimentation basin passes through pipeline and nickel-containing sludge concentrates Pond connects, and nickel-containing sludge concentration basin is connected with nickel-containing sludge compressor, the concentrate in nickel-containing sludge compressor by pipeline and Nickel-containing waste water regulating reservoir connects;The treatment of Phosphorus Containing Waste Water system by phosphorus-containing wastewater regulating reservoir, phosphorus-containing wastewater PH regulating reservoirs, contain Phosphorus waste water reaction pond, phosphorus-containing wastewater coagulating basin, phosphorus-containing wastewater flocculation basin and phosphorus-containing wastewater sedimentation basin are formed, and phosphorus-containing wastewater is adjusted Pond, phosphorus-containing wastewater PH regulating reservoirs, phosphorus-containing wastewater reaction tank, phosphorus-containing wastewater coagulating basin, phosphorus-containing wastewater flocculation basin and phosphorus-containing wastewater sink Shallow lake is connected between pond by pipeline;The ammonia nitrogen waste water processing system is by ammonia nitrogen regulating reservoir, ammonia nitrogen waste water PH regulating reservoirs, ammonia nitrogen Waste water reaction pond, ammonia nitrogen waste water coagulating basin, ammonia nitrogen waste water flocculation basin and ammonia nitrogen waste water sedimentation basin are formed, ammonia nitrogen regulating reservoir, ammonia nitrogen Between waste water PH regulating reservoirs, ammonia nitrogen waste water reaction tank, ammonia nitrogen waste water coagulating basin, ammonia nitrogen waste water flocculation basin and ammonia nitrogen waste water sedimentation basin Connected by pipeline;The modifying porcelain system is by dyeing waste-water regulating reservoir, dyeing waste-water PH regulating reservoirs, dyeing waste-water Reaction tank, dyeing waste-water flocculation basin, dyeing waste-water flocculation basin and dyeing waste-water sedimentation basin are formed, dyeing waste-water regulating reservoir, dyeing Between waste water PH regulating reservoirs, dyeing waste-water reaction tank, dyeing waste-water flocculation basin, dyeing waste-water flocculation basin and dyeing waste-water sedimentation basin Connected by pipeline;The total system is reacted by comprehensive wastewater regulating reservoir, comprehensive wastewater PH regulating reservoirs, comprehensive wastewater Pond, No.1 comprehensive wastewater coagulating basin, No.1 comprehensive wastewater flocculation basin, No.1 comprehensive wastewater sedimentation basin, PH demodulate pond, comprehensive wastewater Oxygen compatibility pool, comprehensive wastewater aerobic tank, No. two comprehensive wastewater flocculation basins, No. two comprehensive wastewater sedimentation basins, comprehensive clear water reserviors, depth Reason system, counter-infiltration system, MVR evaporators, comprehensive sludge concentration tank, comprehensive sludge compression mechanism into;Wherein comprehensive wastewater tune Save pond, comprehensive wastewater PH regulating reservoirs, comprehensive wastewater reaction tank, No.1 comprehensive wastewater coagulating basin, No.1 comprehensive wastewater flocculation basin, one Number comprehensive wastewater sedimentation basin, PH demodulate pond, comprehensive wastewater oxygen compatibility pool, comprehensive wastewater aerobic tank, No. two comprehensive wastewater flocculation basins, two Number comprehensive wastewater sedimentation basin, comprehensive clear water reserviors are sequentially connected by pipeline, and the advanced treatment system is by quartz sand filter, work Property char filter, ion exchange resin tank and ultrafiltration system form;Comprehensive clear water reserviors are connected by pipeline with quartz sand filter, quartz Sand filter, active carbon filter, ion exchange resin tank, ultrafiltration system are sequentially connected by pipeline, ultrafiltration system by pipeline with Counter-infiltration system connects, and counter-infiltration system is connected by pipeline with MVR evaporators;It is the comprehensive wastewater regulating reservoir, comprehensive useless Water PH regulating reservoirs, comprehensive wastewater reaction tank, No.1 comprehensive wastewater coagulating basin, No.1 comprehensive wastewater flocculation basin, No.1 comprehensive wastewater It is useless that sedimentation basin, PH demodulate pond, comprehensive wastewater oxygen compatibility pool, comprehensive wastewater aerobic tank, No. two comprehensive wastewater flocculation basins and No. two synthesis The bottom in water sedimentation pond be connected by pipeline with comprehensive sludge concentration tank, the concentrate of comprehensive sludge concentration tank by pipeline and Comprehensive wastewater regulating reservoir connects.
- A kind of 2. electroplating wastewater zero system according to claim 1, it is characterised in that:The ultrafiltration system passes through Pipeline is connected with comprehensive clear water reserviors.
- A kind of 3. electroplating wastewater zero system according to claim 1, it is characterised in that:The counter-infiltration system leads to Piping is connected with reuse pool.
- A kind of 4. electroplating wastewater zero system according to claim 1, it is characterised in that:The nickel-containing waste water precipitation Pond, phosphorus-containing wastewater sedimentation basin, ammonia nitrogen waste water sedimentation basin and dyeing waste-water sedimentation basin are connected by pipeline with pretreatment clear water reserviors.
- A kind of 5. electroplating wastewater zero system according to claim 1, it is characterised in that:The comprehensive adjustment pond leads to Piping is connected with emergency lagoon.
- A kind of 6. electroplating wastewater zero system, it is characterised in that:Its workflow is as follows:(1), each waste water in workshop is collected to corresponding regulating reservoir through pipe network respectively, and regulating reservoir bottom sets perforated pipe, and not timing carries out Air stirring, to realize that the homogeneous of waste water is measured;Then corresponding PH regulating reservoirs and reaction are promoted under the action of elevator pump Pond, reaction tank set mechanical agitation, are higher by post precipitation pond 1.5m, and bottom is maked somebody a mere figurehead, as dosing room and Ventilator Room;Nickel-containing waste water is pre- Processing system is divided into four lattice, and alkali is added in the first lattice, pH is adjusted to 9-10, dosage is controlled by pH meter;Second lattice are buffering, Improve the reaction time;3rd lattice and the 4th lattice are separately added into coagulant and flocculant, remove nickel and partial suspended thing in waste water; Phosphorus-containing wastewater four lattice of pretreatment system point, add alkali in the first lattice, pH are adjusted to neutrality, dosage is controlled by pH meter;Second Lattice add dephosphorization agent, remove in waste water 15~40% COD, are down to 0.4mg/l from 400mg/l by phosphorus is phosphorous, the 3rd lattice and the Four lattice are separately added into coagulant and flocculant, it is ensured that effluent quality;Ammonia nitrogen waste water four lattice of pretreatment system point, in the first lattice) in Alkali is added, pH is adjusted to 9-10, dosage is controlled by pH meter;Three lattice are separately added into except ammonia nitrogen medicament and coagulation-flocculation agent, drop afterwards The content of low ammonia nitrogen;Dyeing waste-water four lattice of pretreatment system point, add alkali in the first lattice, pH are adjusted to 8.5-9.5, dosage Controlled by pH meter;Three lattice are separately added into decolorising agent and coagulation-flocculation agent afterwards, reduce the colourity of waste water;By each stock of agent-feeding treatment Waste water flow to sedimentation basin and carries out separation of solid and liquid certainly respectively;Sedimentation basin uses inclined-tube sedimentation tank, and inclined-tube sedimentation tank utilizes lamina flow principle, The disposal ability of sedimentation basin is improved, water project situation is good, shortens particle settling height, so that the sedimentation time is shortened, processing effect Rate is high, reduces the load of follow-up structures;(2), dosing room is under reaction tank in ammonia nitrogen waste water processing system, modifying porcelain system and total system Side, the high 1m in dosing pond, top and ground maintain an equal level waste water station, and width is set at the top of dosing pond as 1.2m drawing medicine passages, can be directly at top Dosing;(3), pretreated waste water flow to comprehensive wastewater regulating reservoir through gravity, by elevator pump with comprehensive wastewater after mixing After being promoted to comprehensive wastewater PH regulating reservoirs, then sequentially enter comprehensive wastewater reaction tank, No.1 comprehensive wastewater coagulating basin, No.1 synthesis Waste water flocculating pond, No.1 comprehensive wastewater sedimentation basin, enable to be difficult to the particle precipitated in water mutually by adding alkali and coagulation-flocculation agent Phase-polymerization and form colloid, the floccule body of bigger is then combined to form with the impurity in water body, the waste water that the reaction was complete is precipitating Separation of solid and liquid is carried out in pond;(4), after the supernatant by separation of solid and liquid enters PH anti-tunes pond, comprehensive wastewater oxygen compatibility pool is entered back into, denitrifying bacterium is molten Solve that oxygen concentration is extremely low or anaerobic condition under can be by the use of nitrogen in nitrate as electron acceptor oxidation of organic compounds, by nitrate reduction Into nitrogen, so as to fulfill the denitrification process of sewage;Its water outlet sets combined stuffing, pond from comprehensive wastewater aerobic tank is flow in pond Bottom aeration is oxygenated sewage, and sewage in pond body is in flow regime, to ensure that sewage and the filler in sewage are abundant Contact, avoids sewage from contacting inequality with filler, and organic matter further is converted into inorganic matter by aerobic bacteria effect, removes depollution Thing, while organic matter is removed, the organic nitrogen in sewage is also oxidized to ammonia nitrogen, ammonia nitrogen dissolved oxygen is sufficient, sludge age compared with In the case of length, nitrite and nitrate are further converted into, aerobic tank end sets mixed-liquor return device, according to waste water Actual treatment situation, selects suitable reflux ratio;(5), the waste water after comprehensive wastewater oxygen compatibility pool and the processing of comprehensive wastewater aerobic tank sequentially enters No. two comprehensive wastewater waddings Solidifying pond, No. two comprehensive wastewater sedimentation basins, carry out separation of solid and liquid in secondary settling tank, reduce the suspended matter of water outlet, ensure effluent quality, After its supernatant enters comprehensive clear water reserviors, depth pretreatment system is finally entered;Quartz sand filter in advanced treatment system is adopted By the use of quartz sand as filtrate, the suspended matter in water removal is effectively removed, and remove the pollution such as water part colloid, iron, organic matter, manganese Thing;Active carbon filter is built-in to fill out quartz sand thickness and high grade activated carbon, removes most of peculiar smell, organic matter, colloid, iron in waste water And chlorine residue, the colourity of waste water is reduced, is purified water;Loaded resin in ion exchange resin tank, goes the calcium ions and magnesium ions in water removal, drop Hardness in low water;Ultrafiltration system uses hollow fiber ultrafiltration film, retains the bacterium in waste water and partial organic substances;(6), enter counter-infiltration system by the middle water of depth pretreatment system, for electroplating wastewater electrical conductivity it is high the characteristics of, choosing With producing water ratio is high, salt rejection rate is high, resistant to pollution sea water desalination membrane, the various inorganic ions, colloidal substance in trap water and big point Sub- solute, its production water are discharged into reuse pool and are used for reuse, and concentrated water enters concentrated water counter-infiltration system, improves the producing water ratio of system, drop Low concentrated water amount, concentrated water counter-infiltration system are reverse osmosis using network pipe type;(7), counter-infiltration system concentrated water enters MVR evaporators after water tank caches, and MVR evaporators utilize two produced in evaporator Secondary steam, compresses through compressor, pressure, temperature rise, heat content increase, is then delivered to the heating chamber of evaporator as heating steam Use, feed liquid is maintained fluidized state, and heat steam and be then condensed into water in itself, liquid reuse, concentrate committee are evaporated after evaporation Outside.
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CN108726733A (en) * | 2018-07-13 | 2018-11-02 | 苏州新工环境工程技术有限公司 | Treatment of Phosphorus Containing Waste Water system and its processing method |
CN109851157A (en) * | 2019-01-02 | 2019-06-07 | 广东益诺欧环保股份有限公司 | A kind of method and system handling high ammonia-nitrogen wastewater |
CN111410345A (en) * | 2020-04-20 | 2020-07-14 | 深圳市世清环保科技有限公司 | Method and system for treating comprehensive wastewater generated by anodic oxidation process |
CN111517559A (en) * | 2020-03-02 | 2020-08-11 | 东北电力大学 | Process system and method for treating wastewater generated in amino ether production process |
CN111592146A (en) * | 2020-06-03 | 2020-08-28 | 河南双辰环保工程有限公司 | Pretreatment method of chemical plating nickel-containing wastewater of hydraulic prop for coal mine |
CN112429922A (en) * | 2020-12-04 | 2021-03-02 | 江门全合精密电子有限公司 | Circuit board waste water processing system |
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