CN108033645A - A kind of chemical wastewater treatment technique - Google Patents

A kind of chemical wastewater treatment technique Download PDF

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Publication number
CN108033645A
CN108033645A CN201711422986.1A CN201711422986A CN108033645A CN 108033645 A CN108033645 A CN 108033645A CN 201711422986 A CN201711422986 A CN 201711422986A CN 108033645 A CN108033645 A CN 108033645A
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China
Prior art keywords
level
waste water
distribution reservoir
reservoir
pond
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Pending
Application number
CN201711422986.1A
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Chinese (zh)
Inventor
邓辅商
邓辅唐
曾郴林
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YUNNAN JINYE ECOLOGICAL CONSTRUCTION GROUP CO Ltd
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YUNNAN JINYE ECOLOGICAL CONSTRUCTION GROUP CO Ltd
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Priority to CN201711422986.1A priority Critical patent/CN108033645A/en
Publication of CN108033645A publication Critical patent/CN108033645A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/38Treatment of water, waste water, or sewage by centrifugal separation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/467Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction
    • C02F1/4672Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrochemical disinfection; by electrooxydation or by electroreduction by electrooxydation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices
    • C02F2201/4612Controlling or monitoring
    • C02F2201/46145Fluid flow
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1268Membrane bioreactor systems
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F7/00Aeration of stretches of water

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  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention belongs to chemical field, more particularly to a kind of chemical wastewater treatment technique, level-one tune acid distribution reservoir, level-one Aerated micro-electrolysis reactor, two level tune acid distribution reservoir, the reaction of two level Aerated micro-electrolysis, coagulation regulating reservoir, centrifuge, level-one distribution reservoir, level-one electrocatalysis oxidation device, two level distribution reservoir are sequentially entered behind the adjusted pond of waste water, two level electrocatalysis oxidation device, the connection of biochemical buffer pond, are finally discharged after MBR membrane bioreactors.The present invention provides a kind of chemical wastewater treatment technique, realizes low construction cost and operating cost, on the basis of reaching optimal outlet effect, which is pre-processed, can effectively reduce the COD value of waste water using materialization treatment process and improve its biodegradability.

Description

A kind of chemical wastewater treatment technique
Technical field
The invention belongs to chemical field, and in particular to a kind of chemical wastewater treatment technique.
Background technology
Film corporate boss will produce hollow-fibre membrane, due to adding necessary organic solvent in production technology, cause to give up Organic concentration in water is higher, main ingredient therein for DMAC (dimethylacetylamide), DMF (dimethylformamide), PVDF (Kynoar), PVP (polyvinylpyrrolidone), PEG (polyethylene glycol), glycerine and ethanol etc., so that the life The COD value of waste water of production. art is higher, and toxicity is larger, and biodegradability is poor.Due to produce the COD value of waste water relatively up to 30000 ~ 40000mg/L or so, technique water inlet through be diluted to COD value for 2500mg/L or so when, total water outlet COD value is still left in 400mg/L The right side, is unable to reach national effluent quality requirement.Therefore need to pre-process waste water, improve the biodegradability of waste water, make MBR The effect of bigger is played, improves effluent quality.
The content of the invention
To solve the above-mentioned problems, the present invention provides a kind of chemical wastewater treatment technique, and the waste water can be located in advance Reason, the COD value of waste water is effectively reduced using materialization treatment process and improves its biodegradability.
A kind of chemical wastewater treatment technique, it is micro- that level-one tune acid distribution reservoir, level-one aeration are sequentially entered behind the adjusted pond of waste water Electrolysis reactor, two level tune acid distribution reservoir, the reaction of two level Aerated micro-electrolysis, coagulation regulating reservoir, centrifuge, level-one distribution reservoir, one Level electrocatalysis oxidation device, two level distribution reservoir, two level electrocatalysis oxidation device, the connection of biochemical buffer pond, finally by MBR membrane bioreactions Discharged after answering device, wherein:
(1) homogeneous adjusting is handled
Waste water carries out Homogenization Treatments in homogeneous regulating reservoir, and hydraulic detention time 3d, homogeneous regulating reservoir is interior to be equipped with blast aeration Pipeline, for abundant homogeneous waste water;
(2) acid treatment is adjusted
Waste water carries out acidification in sour distribution reservoir is adjusted, hydraulic detention time 2.0h, adjusts the PH to 3 ~ 4 of waste water, in pond Wall does anti-corrosion, and aerating pipelines are equipped with pond and are used to adjust sour mixing;
(3) Aerated micro-electrolysis reaction treatment
In Aerated micro-electrolysis reactor, retention time of sewage 2.5h, is provided with electromagnetic flowmeter on equipment connecting line, is used for Statistics and control flow;
(4) coagulation adjusting is handled
Waste water pH value is adjusted to after 8 ~ 9 in coagulation regulating reservoir iron cement is removed by centrifuge, waste water is laggard through removing iron cement Enter electro-oxidation reactor and biochemical reactor;
(5)Centrifugal treating
By sedimentation centrifuge, the iron cement in light electrolysis water outlet is isolated into Come from mixed liquor, easy to the processing of next step;
(6) electrochemical catalytic oxidization is handled
Residence time 2.0h in waste water electrochemical catalytic oxidization equipment, equipment is interior to be equipped with electrode plate and catalyst, passes through what power supply provided Electroxidation effect occurs for DC current;
(7) biochemical buffer is handled
In biochemical buffer pond mix the waste water from electrified equipment, part sanitary sewage, part low concentration production waste water and Part rainwater etc., biochemical MBR influent CODs are reduced to a certain extent, while improve the biodegradability of waste water;
(8) MBR membrane biological reactions are handled
In MBR membrane bioreactors, it is 7d that waste water, which stops total time, and aerobic zone and film area are equipped with aerating pipelines in reactor.
Further, hydrochloric acid or sulfuric acid are added in the level-one tune acid distribution reservoir.
Further, 1 ceria of catalyst is added while hydrochloric acid or sulfuric acid are added in the two level tune acid distribution reservoir.
Further, alkali is added to be white lime in the coagulation regulating reservoir.
Further, 2 iron oxide of catalyst is added in the two level distribution reservoir.
Beneficial effects of the present invention:The present invention provides a kind of chemical wastewater treatment technique, realizes low construction cost and fortune Row cost, on the basis of reaching optimal outlet effect, pre-processes the waste water, can effectively be reduced using materialization treatment process useless The COD value of water simultaneously improves its biodegradability.
Brief description of the drawings
Fig. 1 is a kind of artwork of chemical wastewater treatment technique.
Embodiment
First, wastewater treatment scale and water quality situation
(1) waste treatment capacity is designed
According to Workshop production status and demand for development, production waste water water is 160m3/d。
(2) raw water quality situation
The raw water quality situation tool that enterprise provides, which is stopped, to be shown in Table 1.
Table 1 produces waste water quality
2nd, embodiment
1. concrete technology flow process
(1) technological process
According to field pilot test and with reference to inside and outside engineering practice is enclosed, the sewage treatment technology process is as shown in Figure 1.
(2) technological process explanation
By raw water quality water change greatly, and according to engine request, the influent waste water of materializing strategy technique need COD to dilute 20000mg/L or so is adjusted, therefore homogeneous regulating reservoir is set in technique front end.Regulating reservoir water outlet sequentially enters level-one tune acid Distribution reservoir, level-one Aerated micro-electrolysis reactor, two level tune acid distribution reservoir, two level Aerated micro-electrolysis reactor, coagulation adjust buffering Pond, centrifuge, electroxidation level distribution reservoir, level-one electro-oxidation reactor, electroxidation two level distribution reservoir, two level electro-oxidation reactor, Biochemical buffer, subsequently into original MBR techniques.
2. main units, equipment and parameter
(1) homogeneous regulating reservoir
It is 16.0mX10.0mX3.2m that homogeneous, which adjusts pool size, and hydraulic detention time 3d., which is adjusted, holds all 480m3.Drum is equipped with pond Wind aerating pipelines.
(2) sour distribution reservoir is adjusted
It is 3.2mX3.2mX1.5m, hydraulic detention time 2.0h to adjust sour water distribution pool size, adjusts the PH to 3 ~ 4 of waste water.Pond inner wall Anti-corrosion is done, aerating pipelines are equipped with pond and are used to adjust sour mixing.
(3) Aerated micro-electrolysis reactor
Aerated micro-electrolysis reactor size is φ 2.0mX3.0m, retention time of sewage 2.5h.Air inflow is 0.7m3/ h, inflow For 1.4m3/h.Electromagnetic flowmeter is installed on equipment connecting line.
(4) coagulation regulating reservoir
Coagulation regulating reservoir dischargeable capacity 25m3.Since light electrolysis water outlet iron-holder is higher, so needing to adjust light electrolysis water outlet Removed after PH by centrifuging, waste water could enter electro-oxidation reactor and biochemical reactor after going iron ions.In coagulation tune Section is adjusted waste water pH value to 8 ~ 9 in pond.
(5)Centrifuge
Centrifuge uses LW355-1460 type horizontal spiral discharge sedimentation centrifuges, it is by the iron cement in light electrolysis water outlet from mixing Come is isolated in liquid, easy to the processing of next step.
(6) electrochemical catalytic oxidization equipment
The size of electrochemical catalytic oxidization equipment is 1.7mX1.25mX2.0m, dischargeable capacity 4m3, retention time of sewage 2.0h.In equipment Equipped with electrode plate and special filler, the DC current provided by power supply occurs electroxidation and acts on.Air inflow is 0.5m3/ h, into Water is 1.1m3/h。
(7) biochemical buffer pond
The size in biochemical buffer pond is 16.0mX10.0mX3.2m.Mix the sewage from electrified equipment, part sanitary sewage, Part low concentration production waste water and part rainwater etc., biochemical MBR influent CODs are reduced to a certain extent, while improve waste water Biodegradability.
(8) MBR membrane bioreactors
The size of MBR membrane bioreactors is 9.0mX3.0mX3.0m, irony reactor, dischargeable capacity 80m3, waste water stop Total time is 7d.Aerobic zone and film area are equipped with aerating pipelines in reactor.
3. operating condition
3.1 each unit operating conditions are specifically shown in Table 2.
2 each processing unit effluent quality of table
Effluent quality after 3.2 wastewater treatments
Waste water effluent quality after processing need to reach《Integrated wastewater discharge standard》(GB8978-196) primary standard, its water outlet Water quality is specifically shown in Table 3.
3 effluent quality index of table
It was found from from each processing unit operation result in table 2, when raw water influent COD value is 19500mg/L, materializing strategy process COD, which is removed, reaches 81.1%, and organic matter treatment effeciency is higher;B/C values bring up to 0.5 ~ 0.6 by intake 0.2, and biodegradability has It is greatly improved.MBR biochemical treatments, the effluent quality as known to table 3 are passed through in materializing strategy water outlet again after the adjusting in biochemical buffer pond Reach discharge standard.

Claims (5)

1. a kind of chemical wastewater treatment technique, it is characterised in that level-one tune acid distribution reservoir, one are sequentially entered behind the adjusted pond of waste water Level Aerated micro-electrolysis reactor, two level tune acid distribution reservoir, the reaction of two level Aerated micro-electrolysis, coagulation regulating reservoir, centrifuge, a grading Pond, level-one electrocatalysis oxidation device, two level distribution reservoir, two level electrocatalysis oxidation device, the connection of biochemical buffer pond, finally by MBR Discharged after membrane bioreactor, wherein:
(1) homogeneous adjusting is handled
Waste water carries out Homogenization Treatments in homogeneous regulating reservoir, and hydraulic detention time 3d, homogeneous regulating reservoir is interior to be equipped with blast aeration Pipeline;
(2) acid treatment is adjusted
Waste water is subjected to acidification in sour distribution reservoir is adjusted, hydraulic detention time 2.0h adjusts the PH to 3 ~ 4 of waste water, in pond Wall does anti-corrosion, and aerating pipelines are equipped with pond and are used to adjust sour mixing;
(3) Aerated micro-electrolysis reaction treatment
In Aerated micro-electrolysis reactor, retention time of sewage 2.5h, is provided with electromagnetic flowmeter on equipment connecting line, is used for Statistics and control flow;
(4) coagulation adjusting is handled
Waste water pH value is adjusted to after 8 ~ 9 in coagulation regulating reservoir iron cement is removed by centrifuge, waste water is laggard through removing iron cement Enter electro-oxidation reactor and biochemical reactor;
(5)Centrifugal treating
By sedimentation centrifuge, the iron cement in light electrolysis water outlet is isolated into Come from mixed liquor, easy to the processing of next step;
(6) electrochemical catalytic oxidization is handled
Residence time 2.0h in waste water electrochemical catalytic oxidization equipment, equipment is interior to be equipped with electrode plate and catalyst, passes through what power supply provided Electroxidation effect occurs for DC current;
(7) biochemical buffer is handled
In biochemical buffer pond mix the waste water from electrified equipment, part sanitary sewage, part low concentration production waste water and Part rainwater etc., biochemical MBR influent CODs are reduced to a certain extent, while improve the biodegradability of waste water;
(8) MBR membrane biological reactions are handled
In MBR membrane bioreactors, it is 7d that waste water, which stops total time, and aerobic zone and film area are equipped with aerating pipelines in reactor.
A kind of 2. chemical wastewater treatment technique as claimed in claim 1, it is characterised in that the level-one tune acid distribution reservoir Middle addition hydrochloric acid or sulfuric acid.
3. a kind of chemical wastewater treatment technique as claimed in claim 1, it is characterised in that add in the two level tune acid distribution reservoir 1 ceria of catalyst is added while entering hydrochloric acid or sulfuric acid.
4. a kind of chemical wastewater treatment technique as claimed in claim 1, it is characterised in that in the coagulation regulating reservoir plus alkali is White lime.
5. a kind of chemical wastewater treatment technique as claimed in claim 1, it is characterised in that add and urge in the two level distribution reservoir 2 iron oxide of agent.
CN201711422986.1A 2017-12-25 2017-12-25 A kind of chemical wastewater treatment technique Pending CN108033645A (en)

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CN201711422986.1A CN108033645A (en) 2017-12-25 2017-12-25 A kind of chemical wastewater treatment technique

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CN108033645A true CN108033645A (en) 2018-05-15

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115385515A (en) * 2021-05-24 2022-11-25 上海斯纳普膜分离科技有限公司 Treatment method of membrane-making wastewater

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105084470A (en) * 2014-05-09 2015-11-25 广州桑尼环保科技有限公司 Spherical catalytic microelectrolytic environment-friendly material and preparation method therefor
CN105800862A (en) * 2014-12-31 2016-07-27 北京清大国华环境股份有限公司 Rubber wastewater treatment method and apparatus thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105084470A (en) * 2014-05-09 2015-11-25 广州桑尼环保科技有限公司 Spherical catalytic microelectrolytic environment-friendly material and preparation method therefor
CN105800862A (en) * 2014-12-31 2016-07-27 北京清大国华环境股份有限公司 Rubber wastewater treatment method and apparatus thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
渐明柱;李德生;薛敏涛;陈爱华;范太兴;: "电化学预处理与MBR工艺联合处理制膜废水" *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115385515A (en) * 2021-05-24 2022-11-25 上海斯纳普膜分离科技有限公司 Treatment method of membrane-making wastewater

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Application publication date: 20180515