CN108032577A - High intensity cleaning PE films and preparation method thereof - Google Patents
High intensity cleaning PE films and preparation method thereof Download PDFInfo
- Publication number
- CN108032577A CN108032577A CN201711104379.0A CN201711104379A CN108032577A CN 108032577 A CN108032577 A CN 108032577A CN 201711104379 A CN201711104379 A CN 201711104379A CN 108032577 A CN108032577 A CN 108032577A
- Authority
- CN
- China
- Prior art keywords
- high intensity
- layer
- outer layer
- internal layer
- puncture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/24—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of indefinite length
- B29C41/32—Making multilayered or multicoloured articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/34—Component parts, details or accessories; Auxiliary operations
- B29C41/46—Heating or cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
- B32B27/322—Layered products comprising a layer of synthetic resin comprising polyolefins comprising halogenated polyolefins, e.g. PTFE
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
- B32B2250/242—All polymers belonging to those covered by group B32B27/32
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/558—Impact strength, toughness
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
Present invention is disclosed a kind of high intensity cleaning PE films and preparation method thereof, it includes anti-puncture internal layer, linear high-density polyethylene strength enhancing middle level and the anti-puncture outer layer formed by the resin material that common polythene and hp-ldpe mix formed by the resin material that common polythene and hp-ldpe mix successively from inside to outside, and the weight ratio of the internal layer, middle level and outer layer is 1:1:1, and three forms one by casting machine co-extrusion.The beneficial effects are mainly as follows:It is reasonable in design, the purpose being modified to it is can reach by increasing hp-ldpe material in internal layer and outer layer, greatly strengthens its anti-puncture ability, packaging film breakage is effectively prevented from, causes unnecessary economic loss.Simultaneously as internal layer is made of the linear polyethylene material with high intensity, so that its integral strength is greatly enhanced, the security used is drastically increased.
Description
Technical field
The present invention relates to thin film technique field, specifically, more particularly to high intensity cleaning PE films and preparation method thereof.
Background technology
In recent years, a kind of new model of the container by the use of packaging film as plastic flexible package oneself through being used widely, packaging
Case transport packaging film, common packaging film content have:Oily substance, plasticizer, pitch and fruit juice etc..In the market liquid
Flexible packaging made from plastic film is mainly polyethylene (PE) co-extrusion film, but due to polyethylene(PE)The puncture resistant power of co-extrusion film is poor, holds
Cracky, causes leakage occurs using process and fruit juice aoxidizes, cause direct economic loss and some indirect economic loss,
Loss of material so is caused, while pollution can be also brought to environment, very big not side is brought to Container Transport material
Just.
The content of the invention
The purpose of the present invention is overcome the shortcomings of the prior art, there is provided a kind of high intensity cleaning PE films and its preparation
Method.
The purpose of the present invention is achieved through the following technical solutions:
A kind of high intensity cleaning PE films, it includes being mixed by common polythene and hp-ldpe from inside to outside successively
Resin material formed anti-puncture internal layer, linear high-density polyethylene strength enhancing middle level and forced down by common polythene and height
The anti-puncture outer layer that the resin material of density polyethylene mixing is formed, the weight ratio of the internal layer, middle level and outer layer is 1:1:1,
And three forms one by casting machine co-extrusion.
Preferably, the hp-ldpe in the internal layer accounts for 1% ~ 3% of quality in total material.
Preferably, the hp-ldpe in the outer layer accounts for 1% ~ 3% of quality in total material.
Preferably, the polytetrafluoroethylene (PTFE) being arranged on the outer layer.
Preferably, the thickness ratio of the internal layer, middle level and outer layer is:1:1.2:1.
Present invention further teaches a kind of preparation method of high intensity cleaning PE films, include the following steps,
The blend step of S1, raw material, send mixing common polythene and hp-ldpe into single screw extrusion machine and are kneaded,
The extruder temperature of the single screw extrusion machine is 150~190 DEG C, and the head temperature of first single screw extrusion machine is 170
~200 DEG C, 40~100 revs/min of the rotating speed of the screw rod, extrudes 30~50Mpa of tonnage, the height forces down close
Degree polyethylene accounts for 1% ~ 3% of quality in total material, forms puncture resistant layer;
S2, three-layer co-extruded step, Hi-fax is three-layer co-extruded as inside and outside two layers progress as intermediate layer, puncture resistant layer
Go out, three layers of fluidised form raw material merges extrusion in the casting machine, forms film bubble, and film bubble is cold under 10~20 DEG C of cooling wind
But it is molded;Film bubble is sent into draw-gear after collapser is pressed into flat and carries out traction stretching, and it is thin to form high intensity cleaning PE
Film.
The beneficial effects are mainly as follows:It is reasonable in design, forced down by increasing height in internal layer and outer layer
Density polyethylene materials can reach the purpose being modified to it, greatly strengthens its anti-puncture ability, is effectively prevented from packaging film and breaks
Damage, causes unnecessary economic loss.Simultaneously as internal layer is made of the linear polyethylene material with high intensity, so that
Its integral strength is greatly enhanced, drastically increase the security used.
Brief description of the drawings
Technical solution of the present invention is described further below in conjunction with the accompanying drawings:
Fig. 1:The structure diagram of the present invention.
Embodiment
Below with reference to embodiment shown in the drawings, the present invention will be described in detail.But these embodiments are simultaneously
The present invention is not limited to, structure that those of ordinary skill in the art are made according to these embodiments, method or functionally
Conversion is all contained in protection scope of the present invention.
As shown in Figure 1, present invention is disclosed a kind of high intensity cleaning PE films, it includes by commonly gathering successively from inside to outside
The anti-puncture internal layer 1 of the resin material formation of ethene and hp-ldpe mixing, linear high-density polyethylene intensity carry
Middle level 2 and the anti-puncture outer layer 3 formed by the resin material that common polythene and hp-ldpe mix are risen, it is described interior
The weight ratio of layer 1, middle level 2 and outer layer 3 is 1:1:1, and three forms one by casting machine co-extrusion.
In the present invention, the hp-ldpe in the internal layer 1 and outer layer 3 accounts for 1% ~ 3% of quality in total material.
Further, the polytetrafluoroethylene (PTFE) being arranged on the outer layer 3 is further included in the present invention, selects polytetrafluoroethylene (PTFE) to be
Because it has higher wearability, corrosion resistance, insulating properties etc..It is of course also possible to select other materials, the present invention is in
Protection domain in.
Preferably, the thickness ratio of the internal layer 1, middle level 2 and outer layer 3 is:1:1.2:1.
Present invention further teaches a kind of preparation method of high intensity cleaning PE films, include the following steps,
The blend step of S1, raw material, send mixing common polythene and hp-ldpe into single screw extrusion machine and are kneaded,
The extruder temperature of the single screw extrusion machine is 150~190 DEG C, and the head temperature of first single screw extrusion machine is 170
~200 DEG C, 40~100 revs/min of the rotating speed of the screw rod, extrudes 30~50Mpa of tonnage, the height forces down close
Degree polyethylene accounts for 1% ~ 3% of quality in total material, forms puncture resistant layer;
S2, three-layer co-extruded step, Hi-fax is three-layer co-extruded as inside and outside two layers progress as intermediate layer, puncture resistant layer
Go out, three layers of fluidised form raw material merges extrusion in the casting machine, forms film bubble, and film bubble is cold under 10~20 DEG C of cooling wind
But it is molded;Film bubble is sent into draw-gear after collapser is pressed into flat and carries out traction stretching, and it is thin to form high intensity cleaning PE
Film.
The beneficial effects are mainly as follows:It is reasonable in design, forced down by increasing height in internal layer and outer layer
Density polyethylene materials can reach the purpose being modified to it, greatly strengthens its anti-puncture ability, is effectively prevented from packaging film and breaks
Damage, causes unnecessary economic loss.Simultaneously as internal layer is made of the linear polyethylene material with high intensity, so that
Its integral strength is greatly enhanced, drastically increase the security used.
It should be appreciated that although the present specification is described in terms of embodiments, not each embodiment only includes one
A independent technical solution, this narrating mode of specification is only that those skilled in the art will should say for clarity
For bright book as an entirety, the technical solution in each embodiment may also be suitably combined to form those skilled in the art can
With the other embodiment of understanding.
Those listed above is a series of to be described in detail only for feasibility embodiment of the invention specifically
Bright, they simultaneously are not used to limit the scope of the invention, all equivalent implementations made without departing from skill spirit of the present invention
Or change should all be included in the protection scope of the present invention.
Claims (6)
1. high intensity cleaning PE films, it is characterised in that:It includes by common polythene and high pressure low density successively from inside to outside
The anti-puncture internal layer that the resin material of polyethylene mixing is formed(1), Hi-fax strength enhancing middle level(2)And by common poly- second
The anti-puncture outer layer that alkene and the resin material of hp-ldpe mixing are formed(3), the internal layer(1), middle level(2)It is and outer
Layer(3)Weight ratio be 1:1:1, and three forms one by casting machine co-extrusion.
2. high intensity cleaning PE films according to claim 1, it is characterised in that:The internal layer(1)In height force down it is close
Degree polyethylene accounts for 1% ~ 3% of quality in total material.
3. high intensity cleaning PE films according to claim 2, it is characterised in that:The outer layer(3)In height force down it is close
Degree polyethylene accounts for 1% ~ 3% of quality in total material.
4. high intensity cleaning PE films according to claim 1, it is characterised in that:Further include and be arranged on the outer layer(3)
On Teflon membranes.
5. high intensity cleaning PE films according to claim 1, it is characterised in that:The internal layer(1), middle level(2)It is and outer
Layer(3)Thickness ratio be:1:1.2:1.
6. the preparation method of high intensity cleaning PE films, it is characterised in that:Include the following steps,
The blend step of S1, raw material, send mixing common polythene and hp-ldpe into single screw extrusion machine and are kneaded,
The extruder temperature of the single screw extrusion machine is 150~190 DEG C, and the head temperature of first single screw extrusion machine is 170
~200 DEG C, 40~100 revs/min of the rotating speed of the screw rod, extrudes 30~50Mpa of tonnage, the height forces down close
Degree polyethylene accounts for 1% ~ 3% of quality in total material, forms puncture resistant layer;
S2, three-layer co-extruded step, Hi-fax is three-layer co-extruded as inside and outside two layers progress as intermediate layer, puncture resistant layer
Go out, three layers of fluidised form raw material merges extrusion in the casting machine, forms film bubble, and film bubble is cold under 10~20 DEG C of cooling wind
But it is molded;Film bubble is sent into draw-gear after collapser is pressed into flat and carries out traction stretching, and it is thin to form high intensity cleaning PE
Film.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201711104379.0A CN108032577A (en) | 2017-11-10 | 2017-11-10 | High intensity cleaning PE films and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201711104379.0A CN108032577A (en) | 2017-11-10 | 2017-11-10 | High intensity cleaning PE films and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
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CN108032577A true CN108032577A (en) | 2018-05-15 |
Family
ID=62093839
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201711104379.0A Withdrawn CN108032577A (en) | 2017-11-10 | 2017-11-10 | High intensity cleaning PE films and preparation method thereof |
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CN (1) | CN108032577A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109435403A (en) * | 2018-12-28 | 2019-03-08 | 大连大富塑料彩印有限公司 | A kind of puncture resistance composite membrane |
CN111471201A (en) * | 2020-05-20 | 2020-07-31 | 江苏大海塑料股份有限公司 | High-cleanness film and preparation method thereof |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102756520A (en) * | 2012-07-19 | 2012-10-31 | 山东天鹤塑胶股份有限公司 | Preparation method of high-transparency fruit and liquor packaging film for container |
CN102756523A (en) * | 2012-07-19 | 2012-10-31 | 山东天鹤塑胶股份有限公司 | Liquid packaging bag film for flexible container |
CN103879112A (en) * | 2014-02-26 | 2014-06-25 | 成都市兴恒泰印务有限公司 | Polyethylene film for plastic compound flexible package and blow molding method thereof |
CN104354415A (en) * | 2014-11-15 | 2015-02-18 | 佛山新长盛塑料薄膜有限公司 | Puncture-resistant oil-resistant heat-seal compound base film and preparation method thereof |
CN206465558U (en) * | 2017-02-09 | 2017-09-05 | 晋江市新合发塑胶印刷有限公司 | Anti stick packaging film |
-
2017
- 2017-11-10 CN CN201711104379.0A patent/CN108032577A/en not_active Withdrawn
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102756520A (en) * | 2012-07-19 | 2012-10-31 | 山东天鹤塑胶股份有限公司 | Preparation method of high-transparency fruit and liquor packaging film for container |
CN102756523A (en) * | 2012-07-19 | 2012-10-31 | 山东天鹤塑胶股份有限公司 | Liquid packaging bag film for flexible container |
CN103879112A (en) * | 2014-02-26 | 2014-06-25 | 成都市兴恒泰印务有限公司 | Polyethylene film for plastic compound flexible package and blow molding method thereof |
CN104354415A (en) * | 2014-11-15 | 2015-02-18 | 佛山新长盛塑料薄膜有限公司 | Puncture-resistant oil-resistant heat-seal compound base film and preparation method thereof |
CN206465558U (en) * | 2017-02-09 | 2017-09-05 | 晋江市新合发塑胶印刷有限公司 | Anti stick packaging film |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109435403A (en) * | 2018-12-28 | 2019-03-08 | 大连大富塑料彩印有限公司 | A kind of puncture resistance composite membrane |
CN111471201A (en) * | 2020-05-20 | 2020-07-31 | 江苏大海塑料股份有限公司 | High-cleanness film and preparation method thereof |
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PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
WW01 | Invention patent application withdrawn after publication | ||
WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180515 |