CN108020878A - polarizer - Google Patents

polarizer Download PDF

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Publication number
CN108020878A
CN108020878A CN201711065090.2A CN201711065090A CN108020878A CN 108020878 A CN108020878 A CN 108020878A CN 201711065090 A CN201711065090 A CN 201711065090A CN 108020878 A CN108020878 A CN 108020878A
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CN
China
Prior art keywords
weight
methyl
polarizing film
polarizer
light polarizing
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Pending
Application number
CN201711065090.2A
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Chinese (zh)
Inventor
后藤周作
长田润枝
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Nitto Denko Corp
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Nitto Denko Corp
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Publication of CN108020878A publication Critical patent/CN108020878A/en
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Classifications

    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B5/00—Optical elements other than lenses
    • G02B5/30—Polarising elements
    • G02B5/3025—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state
    • G02B5/3033—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid
    • G02B5/3041—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks
    • G02B5/305—Polarisers, i.e. arrangements capable of producing a definite output polarisation state from an unpolarised input state in the form of a thin sheet or foil, e.g. Polaroid comprising multiple thin layers, e.g. multilayer stacks including organic materials, e.g. polymeric layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04—Interconnection of layers
    • B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • G—PHYSICS
    • G02—OPTICS
    • G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333—Constructional arrangements; Manufacturing methods
    • G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
    • G02F1/133528—Polarisers

Abstract

A kind of polarizer is provided, it is the polarizer with slim light polarizing film, and the change with high monomer transmitance and orthogonal form and aspect is suppressed.A kind of polarizer, it meets following formula (1) and (2) with the light polarizing film below 8 μm of thickness.(in formula, Y is, using 2 degree of visual fields (illuminant-C) of JIS Z8701 measure, the singleton transmittance (%) for regard correction by sensitiveness, a is orthogonal form and aspect a values, and b is orthogonal form and aspect b values.)√(a2+b2)≤2 × Y 84.7 ... formulas (1), Y >=42.5 ... formula (2).

Description

Polarizer
Technical field
The present invention relates to polarizer.
Background technology
For the liquid crystal display device as representational image display device, because of its image forming mode, in liquid crystal list The both sides fitting polarizer of member.Usual polarizer includes light polarizing film and protects the protective layer of light polarizing film.Image is required to show in recent years The slimming of showing device, thereupon, it is desirable to the slimming of polarizer.
Therefore, motion has formation polyvinyl alcohol (PVA) resin on resin base material, which is stretched and contaminated Color is so as to obtain the method (for example, patent document 1) of light polarizing film.According to such method, can obtain thickness it is thin (for example, 8 Below μm) light polarizing film (below sometimes referred to as " slim light polarizing film "), therefore by the slimming for contributing to above-mentioned image display device And attract attention.But for the polarizer with slim light polarizing film, it is desirable to which polarized light property further improves.
Prior art literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2000-338329 publications
The content of the invention
Problems to be solved by the invention
The inventors of the present invention have made intensive studies for the polarized light property of the polarizer with slim light polarizing film, learn with The raising of singleton transmittance, the orthogonal form and aspect of transmitted light exist to change (for example, from neutral gray to blueness side from muted color To change) tendency, showing the form and aspect of image sometimes becomes unnatural.
The present invention be in order to solve above-mentioned new knowledge to problem and complete, its main purpose is to provide a kind of polarisation Plate, it is the polarizer with slim light polarizing film, and the change with high monomer transmitance and orthogonal form and aspect is suppressed.
The solution used to solve the problem
The polarizer of the present invention has the light polarizing film below 8 μm of thickness, meets following formula (1) and (2).
√(a2+b2)≤2 × Y-84.7 formulas (1)
The formula (2) of Y >=42.5
(in formula, Y is to be measured, passed through regarding the monomer of correction by sensitiveness using 2 degree of visual fields (illuminant-C) of JIS Z8701 Rate (%), a are orthogonal form and aspect a values, and b is orthogonal form and aspect b values.)
In 1 embodiment, above-mentioned light polarizing film has absorption spectrum included in the wavelength region of 380nm~480nm The dye compound of maximum absorption wavelength.
In 1 embodiment, also there is the adhesive phase at least one-sided configuration of above-mentioned light polarizing film, the adhesive phase There is the dye compound of the maximum absorption wavelength of absorption spectrum included in the wavelength region of 380nm~480nm.
In 1 embodiment, also there is the protective layer at least one-sided configuration of above-mentioned light polarizing film, which includes There is the dye compound of the maximum absorption wavelength of absorption spectrum in the wavelength region of 380nm~480nm.
In 1 embodiment, wavelength region of the above-mentioned dye compound in 380nm~430nm has absorption spectrum The half breadth of maximum absorption wavelength and the absorption spectrum of the maximum absorption wave strong point is 10nm~60nm.
According to another aspect of the present invention, there is provided liquid crystal panel.The liquid crystal panel possesses above-mentioned polarizer.
According to another aspect of the present invention, there is provided liquid crystal display device.The liquid crystal display device possesses above-mentioned liquid crystal panel.
The effect of invention
According to the present invention it is possible to obtain a kind of polarizer, it is the polarizer with slim light polarizing film, saturating with high monomer The change for crossing rate and orthogonal form and aspect is suppressed.
Brief description of the drawings
Figure 1A is the schematic cross-section of the polarizer of 1 embodiment of the present invention.
Figure 1B is the schematic cross-section of the polarizer of another embodiment of the present invention.
Fig. 1 C are the schematic cross-section of the polarizer of another embodiment of the present invention.
Fig. 2 is the singleton transmittance of polarizer and the variable quantity of orthogonal form and aspect for representing to obtain in embodiment and comparative example The figure of relation.
Description of reference numerals
10 light polarizing films
21 protective layers
22 protective layers
30 adhesive phases
100 polarizers
Embodiment
A. polarizer
The polarizer of the present invention has the light polarizing film below 8 μm of thickness, while meets following formula (1) and (2).
√(a2+b2)≤2 × Y-84.7 formulas (1)
The formula (2) of Y >=42.5
(in formula, Y is to be measured, passed through regarding the monomer of correction by sensitiveness using 2 degree of visual fields (illuminant-C) of JIS Z8701 Rate (%), a are orthogonal form and aspect a values, and b is orthogonal form and aspect b values.)
Such as above-mentioned formula (2) defined, the singleton transmittance (Y) of polarizer of the invention is more than 42.5%, is preferably More than 43.0%.On the other hand, the singleton transmittance (Y) of polarizer is limited to 50% in theory, practical upper limit 46%.Separately Outside, orthogonal form and aspect a values are stronger in the bigger expression green of negative direction, red stronger in the bigger expression of positive direction.On the other hand, it is orthogonal Form and aspect b values are stronger in the bigger expression blueness of negative direction, stronger in the bigger expression yellow of positive direction.Therefore, √ (a2+b2) value get over It is small, then mean orthogonal form and aspect as neutrality, while meet that the polarizer of above-mentioned formula (1) and (2) not only has enough in practical High singleton transmittance, the change of orthogonal form and aspect are also inhibited well.Such polarizer is that the present invention realizes first , can actually provide such polarizer industrially has very excellent effect.
It should be noted that the reasons why failing to realize such polarizer in the past is as follows.That is, slim light polarizing film is because thickness Small and necessarily than the iodine of thick (for example, more than 20 μm) light polarizing film content is few.Reach high optics from so few content of iodine From the viewpoint of characteristic, in the manufacture of slim light polarizing film, regarding sensitive wavelength region there is the PVA- iodine absorbed to be complexed The formation of thing is preferential.Therefore, there is the iodine absorbed (for example, wavelength 290nm nearby nearby has with 360nm in ultraviolet region There is the free iodide ion (I of maximum absorption3 -)) forming amount tail off and the polarized light property of the areas adjacent reduce the result is that： Produce the change (for example, changing to blueness) of orthogonal form and aspect.That is, in the polarizer with slim light polarizing film, make near 550nm Polarized light property improves the change increase of then orthogonal form and aspect, both are tradeoff.
In the polarizer of the present invention, √ (a2+b2) it is preferably 0~5.5, more preferably 0.1~3.0, more preferably 0.1~2.0.In addition, orthogonal form and aspect a values be preferably -3.0~1.0, more preferably -1.0~0.8, orthogonal form and aspect b values preferably - 5.0~0, more preferably -4.0~0, more preferably -3.0~0, are still more preferably -2.0~0.
Embodiment illustrated of the present invention is illustrated below, but the present invention is from the limitation of these embodiments.
A-1. the overall structure of polarizer
Figure 1A is the schematic cross-section of the polarizer of 1 embodiment of the present invention, and Figure 1B is another implementation of the present invention The schematic cross-section of the polarizer of mode, Fig. 1 C are the schematic cross-section of the polarizer of another embodiment of the present invention.Figure 1A In, polarizer 100A has light polarizing film 10 and unilateral the 1st protective layer 21 set in light polarizing film 10.In Figure 1B, polarizer 100B has what light polarizing film 10, unilateral the 1st protective layer 21 set in light polarizing film 10 and the opposite side in light polarizing film 10 were set Adhesive phase 30.In Fig. 1 C, polarizer 100C have light polarizing film 10, light polarizing film 10 unilateral the 1st protective layer 21 set, The 2nd protective layer 22 that the opposite side of light polarizing film 10 is set and set in the side opposite with light polarizing film 10 of the 2nd protective layer 22 Adhesive phase 30.1st protective layer 21 and the 2nd protective layer 22 can be arranged on light polarizing film 10 by adhesive linkage (not shown) respectively One side, can not also by adhesive linkage and with 10 closely sealed setting of light polarizing film.In addition, protection is set respectively in the both sides of light polarizing film 10 During layer, they can be same composition, or differently composed.Adhesive phase can be protected with mould release film until for reality Untill.
In 1 embodiment, polarizer of the invention has included in the wavelength region of 380nm~480nm absorbs light The dye compound of the maximum absorption wavelength of spectrum.Polarizer is by that comprising the dye compound, can not influence near 550nm Suitably suppress the light leak (blue light leaks out) in short wavelength region polarized light property.As a result, it can take into account inclined near 550nm The raising of light characteristic and the suppression of the change (predominantly changing to blueness) of orthogonal form and aspect.The dye compound may be embodied in partially In the arbitrary structural element of tabula rasa.As the structural element for the polarizer that can include the dye compound, can include partially Light film, protective layer, adhesive phase, adhesive linkage etc..The dye compound can be only contained in 1 structural element, can also be wrapped It is contained in the structural element of more than 2.It should be noted that above-mentioned maximum absorption wavelength refers to, in the ripple of 380nm~480nm In the light splitting absorption spectrum in long region there are it is multiple absorb it is very big when, wherein show maximum absorbance the very big wavelength of absorption Implication.
Above-mentioned dye compound is preferably that the maximum absorption wavelength of absorption spectrum is present in the wavelength zone of 380nm~430nm The compound in domain, the maximum absorption wavelength of more preferably absorption spectrum are present in the chemical combination of the wavelength region of 380nm~420nm Thing.By the way that such dye compound is applied to polarizer, suitably press down while the polarized light property near 550nm can not be influenced The light leak (blue light leaks out) in short wavelength region processed.
The half breadth of the absorption spectrum of the maximum absorption wave strong point of above-mentioned dye compound is preferably below 110nm, more Preferably 5nm~80nm, more preferably 10nm~60nm.Half breadth is by that in above range, can prevent from recognizing The reduction of the optical characteristics in the high region (for example, long wavelength side higher than 430nm) of property.Half breadth for example passes through following survey The method of determining is obtained.
The assay method ＞ of ＜ half breadths
Above-mentioned half breadth is using ultraviolet-uisible spectrophotometer (for example, U-4100, Hitachi High-Tech Science Corporation. are manufactured), measured under the following conditions by the transmission extinction spectrum of the solution of dye compound. Spectrophotometric spectra obtained from concentration is measured is adjusted according in a manner of the absorbance of maximum absorption wavelength is 1.0, will be peak Half breadth of the interval (full width at half maximum (FWHM)) of wavelength between 2 points of the 50% of value as the dye compound.
(determination condition)
Solvent：Toluene or chloroform
Cuvette：Quartz colorimetric utensil
Optical path length：10mm
As above-mentioned dye compound, such as organic system dye compound, inorganic system's dye compound can be included.Its In, from the viewpoint of the maintenance of dispersiveness and the transparency, preferred organic system dye compound.Dye compound can individually make With furthermore it is possible to mix two or more use.
As above-mentioned organic system dye compound, can include：Azomethine based compound, indoles based compound, cinnamic acid Based compound, pyridine based compound, porphyrin based compound, diazosulfide based compound etc..
As above-mentioned organic pigment compound, commercially available material can be suitably used.Specifically, as above-mentioned indoles system Compound, can include BONASORB UA3911 (trade name, the maximum absorption wavelength of absorption spectrum：398nm, half breadth： 48nm, Orient Chemical Industries Co., Ltd. manufactures), BONASORB UA3912 (trade name, absorption spectrum Maximum absorption wavelength：386nm, half breadth：53nm, Orient Chemical Industries Co., Ltd. manufacture)； As cinnamic acid based compound, SOM-5-0106 (trade name, the maximum absorption wavelength of absorption spectrum can be included：416nm, half It is worth width：50nm, Orient Chemical Industries Co., Ltd. manufacture)；As pyridine based compound, can enumerate Go out FDB-009 (trade name, the maximum absorption wavelength of absorption spectrum：394nm, half breadth：43nm、YAMADACHEMICAL CO., LTD. is manufactured)；As porphyrin based compound, FDB-001 (trade name, the maximum absorption wavelength of absorption spectrum can be included： 420nm, half breadth：14nm, YAMADA CHEMICAL CO., LTD. manufacture) etc..
The compounding amount of above-mentioned dye compound can suitably be set so that polarizer meets above-mentioned formula (1) and (2).
A-2. light polarizing film
Representational above-mentioned light polarizing film for dichroic substance by the polyvinyl alcohol (hereinafter referred to as " PVA ") of gas absorption quantity is resin Film.The thickness of light polarizing film is less than 8 μm, is preferably less than 7 μm, more preferably less than 5 μm.On the other hand, the thickness of light polarizing film Preferably more than 0.5 μm, more preferably more than 1.0 μm.
Light polarizing film preferably shows absorption dichroism in any wavelength of wavelength 380nm~780nm.The monomer of light polarizing film is saturating It is more than 42.5% that it is representational, which to cross rate, is preferably more than 43.0%.The degree of polarization of light polarizing film is preferably more than 99.8%, more excellent Elect more than 99.9% as, more preferably more than 99.95%.
As above-mentioned dichroic substance, such as iodine, organic dyestuff can be included.These can be two or more alone or in combination Use.Dichroic substance is preferably iodine.
As the PVA systems resin for forming above-mentioned PVA resin films, any suitable resin can be used.Such as it can enumerate Go out polyvinyl alcohol, ethylene-vinyl alcohol copolymer.Polyvinyl alcohol is by the way that polyvinyl acetate saponification is obtained.Ethylene-vinyl alcohol Copolymer is by the way that ethylene-vinyl acetate copolymer saponification is obtained.The saponification degree of PVA systems resin be usually 85 moles of %~ 100 moles of %, are preferably 95.0 moles of %~99.95 mole %, more preferably 99.0 moles of %~99.93 mole %. Saponification degree can be obtained according to JIS K 6726-1994.By using the PVA systems resin of such saponification degree, can obtain resistance to The excellent light polarizing film of long property.When saponification degree is excessive, there is the worry of gelation.
The average degree of polymerization of PVA systems resin can suitably be selected according to purpose.Average degree of polymerization is usually 1000~ 10000, it is preferably 1200~4500, more preferably 1500~4300.It should be noted that average degree of polymerization can basis JIS K 6726-1994 are obtained.
As the manufacture method of light polarizing film, any suitable method can be used.Representational is by PVA systems resin Film implements various processing to manufacture light polarizing film.As the PVA resin films for implementing various processing, any suitable side can be used Formula.Specifically, the PVA resins that can be PVA based resin films or be formed on resin base material.
In 1 embodiment, PVA resins making layered product is formed on resin base material, by the layered product Implement various processing so as to manufacture light polarizing film.Painting of the PVA resins for example by including PVA systems resin to resin base material coating Cloth liquid and formed.As coating fluid, representational is PVA systems resin is dissolved in the solution that solvent forms.As making PVA The fat-solvent solvent of system tree, such as using：Water, dimethyl sulfoxide, dimethylformamide, dimethylacetylamide, N- crassitudes The amines such as polyalcohols, ethylenediamine, the diethylenetriamines such as ketone, various glycols, trimethylolpropane.These can individually or It is used in combination of two or more.Preferred water among these.The PVA systems resin concentration of solution is preferably relative to 100 parts by weight of solvent The parts by weight of 3 parts by weight~20.
Additive can be included in above-mentioned coating fluid.As additive, such as plasticizer, surfactant can be included Deng.As plasticizer, such as the polyalcohols such as ethylene glycol, glycerine can be included.As surfactant, for example, can include it is non-from Sub- surfactant.These can be further improved for uniformity, dyeability, the draftability for the PVA resins for making gained Purpose and use.In addition, as additive, such as easy bonding composition can be included.By using easy bonding composition, can make The adaptation of resin base material and PVA resins improves.As a result, shelled for example, PVA resins can be suppressed from resin base material From a problem that, aftermentioned dyeing can be carried out well, stretched in water.As easy bonding composition, such as use acetoacetyl The modified PVAs such as base modified PVA.In addition, as additive, the halogenations such as potassium iodide, sodium iodide, lithium iodide, sodium chloride can be included Thing, urea etc..It by adding these, can improve optical characteristics (for example, singleton transmittance).The compounding amount of additive can be with Suitably set according to purpose etc..
In the embodiment that light polarizing film includes above-mentioned dye compound, representational is to match somebody with somebody colour mixture in above-mentioned coating fluid Plain compound.The compounding amount of dye compound can be the parts by weight of 0.01 parts by weight~10 relative to 100 parts by weight of PVA systems resin Left and right, is preferably parts by weight of 0.02 parts by weight~5 or so.
As the coating method of coating fluid, any suitable method can be used.Such as can include rolling method, spin-coating method, Bar rubbing method, dip coating, mold coating method, curtain coating method, spraying process, scraper for coating method (comma rubbing method etc.) etc..
The coating temperature of coating fluid is preferably more than 50 DEG C.It is preferred that by dried coating film.Drying temperature is preferably more than 50 DEG C.
The thickness of PVA resins is preferably 3 μm~40 μm (before stretching), more preferably 3 μm~20 μm.
As the constituent material of above-mentioned resin base material, any suitable material can be used.Such as it can include：Gather to benzene Olefin-based resin, (methyl) acrylic acid series such as the ester system such as naphthalate system resin resin, cyclic olefine resin, polypropylene Resin, polyamide series resin, polycarbonate-based resin, their copolymer resin.Preferably using polyethylene terephthalate Ester system resin.Wherein, preferably using amorphous PET series resin.As amorphous poly terephthalic acid second two The specific example of alcohol ester system resin, can include also comprising M-phthalic acid as dicarboxylic acids copolymer, also include hexamethylene Copolymer of the dimethanol as glycol.
The glass transition temperature (Tg) of resin base material is preferably less than 100 DEG C.By using such resin base material, In the stretching of aftermentioned layered product, the crystallization of PVA resins can be suppressed and fully ensure draftability (especially water Draftability in middle stretching).As a result, the light polarizing film with excellent optical properties (for example, degree of polarization) can be manufactured.The opposing party Face, the glass transition temperature of resin base material is preferably more than 60 DEG C.It should be noted that glass transition temperature (Tg) is root The value obtained according to JIS K7121.
The thickness of resin base material is preferably 20 μm~300 μm, more preferably 50 μm~200 μm.Can to resin base material surface To implement surface modification treatment (for example, sided corona treatment etc.), adhesive layer can also be formed.
As above-mentioned various processing, such as dyeing processing, stretch processing, insoluble processing, crosslinking Treatment, clear can be included Wash processing, drying process.These processing can suitably be selected according to purpose.In addition, processing sequence, the opportunity of processing, processing time Number etc. can suitably be set.Each processing is illustrated below.
(dyeing processing)
Representational above-mentioned dyeing processing is to be dyed PVA resin films to carry out with dichroic substance.It is it is preferred that logical Crossing makes dichroic substance absorption on PVA resin films to carry out.As the adsorption method, such as PVA systems tree of sening as an envoy to can be enumerated Method that adipose membrane (layered product) is immersed in the dyeing liquor comprising dichroic substance, coat above-mentioned dyeing on PVA resin films The method of liquid, by above-mentioned dyeing liquor be sprayed on method on PVA resin films etc..It is preferred that layered product is set to be immersed in the side in dyeing liquor Method.This is because dichroic substance can be adsorbed well.
When using iodine as above-mentioned dichroic substance, above-mentioned dyeing liquor is preferably iodine aqueous solution.The compounding amount of iodine relative to 100 parts by weight of water, are preferably the parts by weight of 0.1 parts by weight~0.5.It is preferably water-soluble in iodine in order to improve the solubility of iodine in water Iodide are compounded in liquid.As iodide, such as can include：Potassium iodide, lithium iodide, sodium iodide, zinc iodide, silver iodide, iodine Change lead, cupric iodide, barium iodide, calcium iodide, stannic iodide, titanium iodide etc..Preferred potassium iodide among these.The compounding amount phase of iodide It is preferably the parts by weight of 0.02 parts by weight~20 for 100 parts by weight of water, the parts by weight of more preferably 0.1 parts by weight~10.
In order to suppress the dissolving of PVA systems resin, the liquid temperature during dyeing of dyeing liquor is preferably 20 DEG C~50 DEG C.Make PVA systems When resin film is immersed in dyeing liquor, in order to ensure the transmitance of PVA resin films, dip time is preferably 5 seconds~5 points.Separately Outside, dyeing condition (concentration, liquid temperature, dip time) can be set so that the degree of polarization or monomer of the light polarizing film finally obtained Transmitance is in defined scope.In 1 embodiment, so as to get the degree of polarization of light polarizing film set for more than 99.98% Determine dip time.In another embodiment, so as to get light polarizing film singleton transmittance for more than 42.5% come set dipping Time.
(stretch processing)
As the drawing process of layered product, any suitable method can be used.Specifically, it can be fixing end stretching (for example, method using tentering stretching-machine) or free end are stretched (for example, making layered product pass through the different roller of peripheral speed Between carry out simple tension method).Furthermore it is possible to be simultaneously bi-directionally stretching (for example, method using simultaneously bi-directionally stretching-machine), It can also be biaxial tension successively.The stretching of layered product can be carried out by single phase, can also be carried out by the multistage.Pass through When multistage carries out, the stretching ratio (maximum tension multiplying power) of aftermentioned layered product is the product of the stretching ratio in each stage.
Stretch processing can be stretching mode or aerial in the water that layered product is immersed in stretch bath to carry out Stretching mode.Preferably at least implement stretch processing in 1 water, in further preferred combination water at stretch processing and aerial stretching Reason., can (representational be 80 in the glass transition temperature than above-mentioned resin base material, PVA resin films by being stretched in water DEG C or so) stretch at low temperature, PVA resin films can be stretched high magnification while its crystallization is suppressed.It is tied Fruit, can manufacture the light polarizing film with excellent optical characteristics (for example, degree of polarization).
As the draw direction of layered product, any suitable direction can be selected.In 1 embodiment, along strip Layered product length direction stretching.Specifically, layered product is conveyed along its length, is its conveying direction (MD).Another In one embodiment, stretched along the width of strip layered product.Specifically, layered product is conveyed along its length, is The direction (TD) orthogonal with its conveying direction (MD).
The draft temperature of layered product can be set as any suitable according to the formation material of resin base material, stretching mode etc. Value.During using aerial stretching mode, draft temperature is preferably more than the glass transition temperature (Tg) of resin base material, further excellent Elect more than+10 DEG C of the glass transition temperature (Tg) of resin base material as, particularly preferably more than Tg+15 DEG C.On the other hand, it is laminated The draft temperature of body is preferably less than 170 DEG C.By being stretched at such temperatures, the crystalline substance of PVA systems resin can be suppressed Bodyization rapidly carries out, suppresses unfavorable condition caused by the crystallization (for example, hindering taking for the PVA resin films based on stretching To).
As stretching mode, using during stretching mode, the liquid temperature of stretch bath is preferably 40 DEG C~85 DEG C in water, it is more preferably 50 DEG C~85 DEG C.If such temperature, then stretch with can suppressing dissolving and the high magnification of PVA resin films.It is specific and Speech, as described above, the glass transition temperature (Tg) of resin base material is preferably due to the relation of the formation with PVA resin films More than 60 DEG C.At this time, if draft temperature is less than 40 DEG C, even if considering the plasticized for the resin base material that water is brought, there is also nothing The worry that method stretches well.On the other hand, the temperature of stretch bath more high temperature, the dissolubility of PVA resin films is higher, exists It cannot get the worry of excellent optical characteristics.
It is preferable (boric acid water using during stretching mode, making layered product be immersed in boric acid aqueous solution in water to carry out stretching Middle stretching).By using boric acid aqueous solution as stretch bath, applied when can assign resistance to Tensile to PVA resin films The rigidity of power and in water undissolved water resistance.Specifically, boric acid generate tetrahydroxy acid anion in aqueous and Hydrogen bond crosslinks can be passed through with PVA systems resin.As a result, rigidity and water resistance can be assigned to PVA resin films, can be good Ground stretches, and can make the light polarizing film with excellent optical characteristics.
Above-mentioned boric acid aqueous solution is preferably obtained by making boric acid and/or borate being dissolved in the water as solvent.Boron Acid concentration is preferably the parts by weight of 1 parts by weight~10 relative to 100 parts by weight of water.By by boric acid concentration be set as 1 parts by weight with On, the dissolving of PVA resin films can be effectively inhibited, the light polarizing film of higher characteristic can be made.It should be noted that also may be used The dissolvings such as the boron compounds such as borax, glyoxal, glutaraldehyde are obtained in a solvent in addition to boric acid or borate with use Aqueous solution.
It is preferred that the compounding iodide in above-mentioned stretch bath (boric acid aqueous solution).By being compounded iodide, can suppress to adsorb The dissolution of iodine on PVA resin films.The specific example of iodide is as described above.The concentration of iodide is relative to 100 weight of water Part is measured, is preferably the parts by weight of 0.05 parts by weight~15, the parts by weight of more preferably 0.5 parts by weight~8.
Dip time of the layered product in stretch bath is preferably 15 seconds~5 points.
The stretching ratio (maximum tension multiplying power) of layered product is long relative to the original of layered product, is preferably more than 5.0 times.So High stretching ratio can reach by using stretching mode in such as water (being stretched in boric acid water).It should be noted that this " maximum tension multiplying power " refers to stretching ratio when layered product will be broken in specification, refers to by confirming to be laminated otherwise The stretching ratio of body fracture, lower than the value 0.2 value.
Preferably, stretch processing carries out after dyeing processing in water.
(insoluble processing)
Representational above-mentioned insoluble processing is to be carried out by making PVA resin films be immersed in boric acid aqueous solution.Especially It, by implementing insoluble processing, can assign PVA resin film water resistances when using stretching mode in water.The boric acid water The concentration of solution is preferably the parts by weight of 1 parts by weight~4 relative to 100 parts by weight of water.The liquid temperature of insoluble bath (boric acid aqueous solution) Preferably 20 DEG C~40 DEG C.Preferably, insoluble processing is after layered product making, in dyeing processing, water before stretch processing Carry out.
(crosslinking Treatment)
Representational above-mentioned crosslinking Treatment is PVA resin films is immersed in boric acid aqueous solution to carry out.Pass through implementation Crosslinking Treatment, can assign water resistance to PVA resin films.The concentration of the boric acid aqueous solution is relative to 100 parts by weight of water, preferably For the parts by weight of 1 parts by weight~4.In addition, when carrying out crosslinking Treatment after above-mentioned dyeing processing, iodide are preferably further compounded. By being compounded iodide, dissolution of the absorption in the iodine of PVA resin films can be suppressed.The compounding amount of iodide is relative to water 100 Parts by weight, are preferably the parts by weight of 1 parts by weight~5.The specific example of iodide is as described above.The liquid of crosslinking bath (boric acid aqueous solution) Temperature is preferably 20 DEG C~50 DEG C.Preferably, stretch processing carries out crosslinking Treatment before in water.In preferred embodiment In, carried out according to the order of stretch processing in dyeing processing, crosslinking Treatment and water.
(cleaning treatment)
Representational above-mentioned cleaning treatment is PVA resin films is immersed in potassium iodide aqueous solution to carry out.
(drying process)
Drying temperature in drying process is preferably 30 DEG C~100 DEG C.
A-3. protective layer
, can be directly using the resin base material used in the manufacture of above-mentioned light polarizing film as above-mentioned protective layer.Alternatively, can be with Light polarizing film is transferred to any suitable resin film from resin base material, using the resin film as protective layer.Set in protective layer Put in the embodiment of the both sides of light polarizing film, for example, can directly be used above-mentioned resin base material as the 1st protective layer, The side opposite with configuring the resin base material side of light polarizing film is laminated any suitable resin film as the 2nd protective layer.Example again Such as, light polarizing film can be transferred to any suitable resin film as the 1st protective layer from resin base material, light polarizing film with Put the opposite side in the 1st protective layer side and be laminated another any suitable resin film as the 2nd protective layer.
When resin film is used as protective layer, the representational resin film is to be laminated in light polarizing film by adhesive linkage.It is viscous It is to be formed by bonding agent or adhesive that it is representational, which to connect layer,.As the bonding agent for forming adhesive linkage, isocyanates system can be included The water system bonding agents such as bonding agent, polyethenol series bonding agent, ultraviolet hardening bonding agent, electronic beam solidified bonding agent etc..
Above-mentioned resin film can be the excellent resin film of isotropism, or can be with phase difference, play light Learn the resin film of compensation layer function.When using having dephased resin film, its phase difference characteristics can be adjusted suitably For value necessary to optical compensation.
As the formation material of above-mentioned resin film, for example, can include：(methyl) acrylic resin, two acetic acid are fine Tie up the olefin-based trees such as cyclic olefine resin, the polypropylene such as cellulose-based resin, the norbornene resins such as element, Triafol T The ester system such as fat, PET series resin resin, polyamide series resin, polycarbonate-based resin, they are total to Copolymer resin etc..It should be noted that " (methyl) acrylic resin " refers to acrylic resin and/or metha crylic Resin.
In 1 embodiment, as above-mentioned (methyl) acrylic resin, using with glutarimide structure (methyl) acrylic resin.(methyl) acrylic resin with glutarimide structure (is also referred to as glutarimide below Resin) it is recorded in for example：Japanese Unexamined Patent Publication 2006-309033 publications, Japanese Unexamined Patent Publication 2006-317560 publications, Japanese Unexamined Patent Publication 2006-328329 publications, Japanese Unexamined Patent Publication 2006-328334 publications, Japanese Unexamined Patent Publication 2006-337491 publications, Japan are special Open 2006-337492 publications, Japanese Unexamined Patent Publication 2006-337493 publications, Japanese Unexamined Patent Publication 2006-337569 publications, Japan Special open 2007-009182 publications, Japanese Unexamined Patent Publication 2009-161744 publications (for example, Production Example 1), Japanese Unexamined Patent Publication 2010- No. 284840 publications.These are quoted in the present specification to record as reference.
In the embodiment that protective layer includes above-mentioned dye compound, the compounding amount example of the dye compound in protective layer It can be such as parts by weight of 0.01 parts by weight~10 or so relative to 100 parts by weight of resin solid content, be preferably 0.02 parts by weight ~5 parts by weight or so.
Above-mentioned resin film is film-made by any suitable method.As film-forming method, such as melting extrusion can be included Method, liquation casting method (liquation the tape casting), rolling process, compression forming method etc..Preferred molten extrusion molding among these.In addition, tree Membrane of lipoprotein can implement stretch processing.
The mean transmissivity of wavelength 450nm~500nm of protective layer comprising above-mentioned dye compound be preferably 70% with On, more preferably more than 75%, the mean transmissivity of wavelength 500nm~780nm is preferably more than 80%, more preferably 85% with On.It should be noted that in this specification, " mean transmissivity of 400~430nm of wavelength " refers to 400~430nm's of wavelength Region is with 5nm distance computation transmitances, for the average value of the transmitance calculated.Mean transmissivity in other wavelength regions Equally.
The thickness of protective layer is generally 10 μm~100 μm, is preferably 10 μm~50 μm, more preferably 10 μm~30 μm.
A-4. adhesive phase
Above-mentioned adhesive phase is formed by adhesive composition.The embodiment of above-mentioned dye compound is included in adhesive phase In, representational is that above-mentioned dye compound is compounded in the adhesive composition.
Above-mentioned adhesive composition is preferably the adhesive composition of the heat cross-linked type comprising base polymer and crosslinking agent. Due to without that comprising photoinitiator, when dye compound is compounded in adhesive composition, can prevent dye compound Absorption and the absorption of photoinitiator interfere.
Can be the bonding such as acrylic acid series, synthetic rubber system, rubber series, silicon-type as above-mentioned adhesive composition Agent.From the point of view of the viewpoints such as the transparency, heat resistance, the acrylic acid series preferably using (methyl) acrylic acid series polymeric compounds as basic polymer Adhesive.
Above-mentioned (methyl) acrylic acid series polymeric compounds are preferably by (methyl) acrylate comprising the alkyl with carbon number 2~14 Monomer component polymerize and obtained, more preferably using (methyl) acrylate comprising the alkyl with carbon number 2~14 as The monomer component of main monomer is polymerize and is obtained.Herein, main monomer refers to relative to composition (methyl) acrylic acid series polymeric compounds Whole monomer components be preferably more than 60 weight % more preferably more than 70 weight %.It should be noted that in this specification " (methyl) acrylic acid " be acrylic acid and/or methacrylic acid implication.
As (methyl) acrylate of the alkyl with carbon number 2~14, such as can include：(methyl) acrylic acid second Ester, (methyl) n-butyl acrylate, (methyl) tert-butyl acrylate, (methyl) isobutyl acrylate, (methyl) Hexyl 2-propenoate, (methyl) 2-ethylhexyl acrylate, (methyl) n-octyl, (methyl) Isooctyl acrylate monomer, (methyl) acrylic acid are just Nonyl ester, the different nonyl ester of (methyl) acrylic acid, the positive last of the ten Heavenly stems ester of (methyl) acrylic acid, (methyl) isodecyl acrylate, (methyl) acrylic acid are just Dodecyl ester, (methyl) acrylic acid n-tridecane base ester, (methyl) n-myristyl base ester etc., these can individually make With a kind or mix two or more use.
Above-mentioned monomer component can include other poly- beyond (methyl) acrylate with the alkyl that carbon number is 2~14 Conjunction property monomer.As above-mentioned other polymerizable monomers, as long as it is double with unsaturation with (methyl) acryloyl group or vinyl etc. The polymerizable monomer of the relevant polymerizable functional group of key just has no particular limits, such as can include hydroxyl monomer, containing carboxylic Base monomer etc..
As hydroxyl monomer, can use without particular limitation with (methyl) acryloyl group or vinyl etc. with The polymerizable functional group of unsaturated double-bond and the material with hydroxyl.As hydroxyl monomer, such as (methyl) can be included Acrylic acid 2- hydroxyl ethyl esters, (methyl) acrylic acid 3- hydroxypropyl acrylates, (methyl) acrylic acid 4- hydroxy butyl esters, (methyl) acrylic acid 6- hydroxyls oneself Ester, (methyl) acrylic acid 8- hydroxyls monooctyl ester, (methyl) acrylic acid 10- hydroxyls last of the ten Heavenly stems ester, (methyl) acrylic acid 12- hydroxy dodecyl acrylates, (methyl) acrylic acid (4- hydroxymethylcyclohexyls) methyl esters etc., these can be used alone or mix two or more use.
The content of hydroxyl monomer is below 10 weight % preferably in monomer component, more preferably 0~5 weight %, into One step is preferably 0.1~2 weight %.
As carboxyl group-containing monomer, can use without particular limitation with (methyl) acryloyl group or vinyl etc. with The polymerizable functional group of unsaturated double-bond and the material with carboxyl.As carboxyl group-containing monomer, such as can include：Acrylic acid, Methacrylic acid, (methyl) carboxyethyl acrylates, (methyl) acrylic acid carboxyl pentyl ester, itaconic acid, maleic acid, fumaric acid, bar Beans acid etc., they can be used alone or are applied in combination.
The content of carboxyl group-containing monomer is below 5 weight % preferably in monomer component.
As other comonomers, as long as it is relevant with unsaturated double-bond with (methyl) acryloyl group or vinyl etc. The material of polymerizable functional group can use without limitation, can include：For example, (methyl) cyclohexyl acrylate, (first Base) (methyl) acrylic acid ester ring type hydrocarbon ester such as acrylic acid norbornene ester, (methyl) isobornyl acrylate；For example, (methyl) propylene Acid phenenyl ester etc. (methyl) benzyl acrylate；For example, the vinyl ester such as vinylacetate, vinyl propionate；For example, styrene Etc. styrenic monomers；For example, (methyl) glycidyl acrylate, (methyl) acrylic acid methylglycidyl esters etc. contain epoxy Base monomer；For example, acrylamide, acrylamide, acryloyl morpholine (ACMO), n-vinyl pyrrolidone (NVP) Deng amide-containing monomer；For example, N, N- dimethyl aminoethyl (methyl) acrylate, N, N- dimethylaminopropyls (methyl) The emulsion stabilities such as acrylate；For example, n-vinyl pyrrolidone, N- vinyl-Epsilon-caprolactams, methyl ethylene pyrroles The ring-type nitrogen containing monomer such as alkanone；For example, (methyl) methoxyethyl acrylate, (methyl) ethoxyethyl acrylate etc. contain alcoxyl Base monomer；For example, the cyano-containing monomer such as acrylonitrile, methacrylonitrile；For example, 2- methacryloxyethyl isocyanates etc. Functional monomer；For example, the olefinic monomers such as ethene, propylene, isoprene, butadiene, isobutene；For example, vinyl ethers etc. Vinyl ether monomer；For example, the halogen atom-containing monomer such as ethlyene dichloride；N- vinylcarboxylic acid amide types etc..
In addition, as co-polymerized monomer, can include：Such as N- N-cyclohexylmaleimides, N- isopropyl maleimides The maleimide amine system monomers such as amine, N- lauryls maleimide, N-phenylmaleimide；Such as N- methyl clothing health acyl is sub- Amine, N- ethyl clothing health acid imide, N- butyl clothing health acid imide, N- octyl group clothing health acid imide, N-2- ethylhexyl clothing health acid imide, The clothing health imide series monomers such as N- cyclohexyl clothing health acid imide, N- lauryl clothing health acid imides；Such as N- (methyl) acryloyl-oxy Methylene succinimide, N- (methyl) acryloyl group -6- oxo hexa-methylenes succinimide, N- (methyl) acryloyl The succinimide system monomers such as eight methylene succinimide of base -8- oxos；For example, styrene sulfonic acid, allyl sulphonic acid, 2- (methyl) acrylamide -2- methyl propane sulfonic acids, (methyl) acrylamide propane sulfonic, (methyl) acrylic acid sulphur propyl ester, (first Base) monomer containing sulfonic group such as propane sulfonic acid.
In addition, as co-polymerized monomer, such as (methyl) polyalkylene glycol acrylate ester, (methyl) acrylic acid can be included and gathered The glycol system propylene such as propylene glycol ester, (methyl) methoxyethyl glycol ester, (methyl) methoxyethyl polypropylene glycol ester Acid ester monomer；It is and such as (methyl) tetrahydrofurfuryl acrylate, former containing heterocycle, halogen containing fluorine atom (methyl) acrylate etc. Acrylate monomer of son etc..
And then as co-polymerized monomer, multi-functional monomer can be used.As multi-functional monomer, it can enumerate and provide There is compound of unsaturated double-bond of more than 2 (methyl) acryloyl groups, vinyl etc. etc..Such as it can include：Ethylene glycol two (methyl) acrylate, diethylene glycol two (methyl) acrylate, triethylene glycol two (methyl) acrylate, trimethylolpropane (single or multiple) ethylene glycol two (methyl) acrylate, third such as three (methyl) acrylate, tetraethylene glycol two (methyl) acrylate Two (the first of (single or multiple) aklylene glycol such as glycol two (methyl) acrylate etc. (single or multiple) propane diols two (methyl) acrylate Base) acrylate and neopentyl glycol two (methyl) acrylate, 1,6-HD two (methyl) acrylate, pentaerythrite Two (methyl) acrylate, trimethylolpropane tris (methyl) acrylate, pentaerythrite three (methyl) acrylate, two seasons penta The carboxylate of (methyl) acrylic acid such as tetrol six (methyl) acrylate and polyalcohol；The polyfunctional vinyls such as divinylbenzene Compound；(methyl) allyl acrylate, (methyl) vinyl acrylate etc. have compound of unsaturated double-bond of reactivity etc.. In addition, as multi-functional monomer, can also use the addition on the skeleton of polyester, epoxy group, carbamate etc. have 2 with On as (methyl) acryloyl group of the functional group identical with monomer component, vinyl etc. unsaturated double-bond polyester (methyl) Acrylate, epoxy (methyl) acrylate, carbamate (methyl) acrylate etc..
The ratio of comonomer beyond hydroxyl monomer, carboxyl group-containing monomer in monomer component be preferably 40 weight % with Under, more preferably 0~30 weight %, more preferably 0~20 weight %.
The weight average molecular weight of above-mentioned (methyl) acrylic acid series polymeric compounds is preferably 1,200,000~3,000,000 scope, more preferably 1200000~2,700,000, more preferably 1,200,000~2,500,000.Weight average molecular weight is by that within that range, can make heat-resisting Property, the transparency, corrosion resistance, durability etc. are excellent.Weight average molecular weight is measured by GPC (gel permeation chromatography), by poly- The value that styrene calculates.
The manufacture of above-mentioned (methyl) acrylic acid series polymeric compounds can suitably select polymerisation in solution, polymerisation in bulk, emulsion polymerization, Manufacture method known to various radical polymerizations etc..In addition, obtained (methyl) acrylic acid series polymeric compounds can be random copolymerization Any one of thing, block copolymer, graft copolymer.
In polymerisation in solution, as polymer solvent, such as ethyl acetate, toluene etc. are used.As specific polymerisation in solution example Son, reacts and adds polymerization initiator under the non-active gas air-flows such as nitrogen, usual 50~70 DEG C or so, 5~30 it is small when it is left Carried out under right reaction condition.
There is no particular limitation for the polymerization initiator that uses radical polymerization, chain-transferring agent, emulsifying agent etc., can be suitable Selection uses.It should be noted that the weight average molecular weight of (methyl) acrylic acid series polymeric compounds can turn according to polymerization initiator, chain Move the usage amount of agent, reaction condition controls, its usage amount is suitably adjusted according to their species.
As above-mentioned polymerization initiator, such as can include：Double (the 2- amidines of 2,2 '-azobis isobutyronitrile, 2,2 '-azo Base propane) dihydrochloride, double [2- (5- methyl -2- imidazoline -2- bases) propane] dihydrochloride of 2,2 '-azo, 2,2 '-azo be double (2- methyl-props amidine) dithionate, 2,2 '-azo double (N, N '-dimethyleneisobutylamidine), double [N- (the 2- carboxylic second of 2,2 '-azo Base) -2- methyl-props amidine] azo initiators such as hydrate (trade name " VA-057 ", Wako Pure Chemical Industries, Ltd. manufacture)； The persulfates such as potassium peroxydisulfate, ammonium persulfate；Dicetyl peroxydicarbonate two (2- ethylhexyls) ester, two (uncle 4- of dicetyl peroxydicarbonate Butylcyclohexyl) ester, peroxide-butyl carbonate, new peroxide tert-butyl caprate, the tertiary own ester of peroxidating neopentanoic acid, peroxide Change the neopentanoic acid tert-butyl ester, dilauroyl peroxide, two positive decoyl of peroxidating, peroxidating -2 ethyl hexanoic acid 1,1,3,3- tetramethyls Butyl ester, peroxidating two (4- toluyls), benzoyl peroxide, peroxidating tert-butyl isobutyrate, (the tertiary hexyl peroxides of 1,1- bis- Change) the peroxide series initiators such as hexamethylene, tert-butyl hydroperoxide, hydrogen peroxide；The group of persulfate and sodium hydrogensulfite Combination of conjunction, peroxide and sodium ascorbate etc. makes the redox series initiators that peroxide and reducing agent are composed Deng.
Above-mentioned polymerization initiator can be used alone, and in addition can also mix two or more use, content as a whole, 100 parts by weight of monomer component relative to above-mentioned (methyl) acrylic acid series polymeric compounds of formation are preferably 0.005~1 parts by weight left side It is right.
For above-mentioned adhesive composition, in order to improve the adaptation under the conditions of high temperature and humidity, various silane can be added Coupling agent.As silane coupling agent, the material with any suitable functional group can be used.As functional group, such as can arrange Enumerate vinyl, epoxy group, amino, sulfydryl, (methyl) acryloxy, acetoacetyl, isocyanate group, styryl, Polysulfide base etc..Specifically, such as can include：Vinyltriethoxysilane, vinyl tripropoxy silane, vinyl three Isopropoxy silane, vinyltributoxysilane etc. contain vinyl silicane coupling agent；γ-glycidoxypropyl group trimethoxy Silane, γ-glycidoxypropyl group triethoxysilane, 3- glycidoxypropyls diethoxy silane, 2- (3,4- rings Oxygen cyclohexyl) ethyl trimethoxy silane etc. contains epoxy silane coupling；Gamma-amino propyl trimethoxy silicane, N- β-(ammonia Base ethyl)-gamma-amino hydroxypropyl methyl dimethoxysilane, N- (2- amino-ethyls) 3- amino propyl methyls dimethoxysilane, γ-triethoxysilyl-N- (1,3- dimethyl butane) propylamine, N- phenyl-gamma-amino propyl trimethoxy silicane etc. Containing amino silicane coupling agent；γ-mercaptopropyi methyl dimethoxysilane etc. contains mercaptosilane coupling agents；To styrene trimethoxy The silane coupling agents containing styryl such as base silane；γ-acryloxypropyl trimethoxy silane, γ-methacryloxy Propyl-triethoxysilicane etc. contains (methyl) acryl silane coupling agents；3- isocyanatopropyl triethoxysilanes etc. contain Isocyanato silanes coupling agent；Coupling agents of base silane containing polysulfide such as double (triethoxysilylpropyltetrasulfide) tetrasulfides etc..
Above-mentioned silane coupling agent can be used alone, and in addition can also mix two or more use, content as a whole, It is preferably more preferably 0.01~1 weight below 1 parts by weight relative to 100 parts by weight of above-mentioned base polymer (solid constituent) Part, more preferably 0.02~0.8 parts by weight.The compounding amount of silane coupling agent then produces unreacted coupling more than 1 parts by weight Agent component, it is not preferred in terms of durability.
It should be noted that when above-mentioned silane coupling agent can be copolymerized by radical polymerization and above-mentioned monomer component, should Silane coupling agent may be used as above-mentioned monomer component.Its ratio is relative to 100 parts by weight of above-mentioned base polymer (solid constituent) Preferably 0.005~0.7 parts by weight.
Further, above-mentioned adhesive composition by add crosslinking agent can assign with the durability of adhesive it is relevant in Poly- power, therefore it is preferred that.
As crosslinking agent, using multi-functional compounds, organic system crosslinking agent, multi-functional metal complex can be included Thing.As organic system crosslinking agent, epoxy crosslinking agent, isocyanates system crosslinking agent, carbodiimide system crosslinking agent, Asia can be included Amine system crosslinking agent, oxazolines system crosslinking agent, aziridine system crosslinking agent, peroxide system crosslinking agent etc..Multi-functional metal complex Thing refers to polyvalent metal atom and organic compound covalent bonding or the material of coordination bonding.As polyvalent metal atom, can arrange Enumerate Al, Cr, Zr, Co, Cu, Fe, Ni, V, Zn, In, Ca, Mg, Mn, Y, Ce, Sr, Ba, Mo, La, Sn, Ti etc..As covalent bond Atom in the organic compound of conjunction or coordination bonding, can include oxygen atom etc., as organic compound, can include alkyl Ester, alcoholic compound, carboxylic acid compound, ether compound, ketone compound etc..These crosslinking agents can be used alone or combine 2 kinds It is used above.Among these, preferably they are applied in combination for preferably peroxide system crosslinking agent, isocyanates system crosslinking agent.
Above-mentioned isocyanates system crosslinking agent refers to that there are more than 2 isocyanate group (to include isocyanates in 1 molecule The isocyanates regenerative functional group that base is got up by the temporary protection such as end-capping reagent or a few polymers) compound.
As isocyanates system crosslinking agent, can include：The aromatic series such as toluene di-isocyanate(TDI), xylene diisocyanate The aliphatic isocyanic acid such as the alicyclic isocyanates such as isocyanates, isophorone diisocyanate, hexamethylene diisocyanate Ester etc..
As peroxide system crosslinking agent, various peroxide are used.As peroxide, two (2- ethyls can be included Hexyl) peroxy dicarbonate, two (4- tert-butylcyclohexyls) peroxy dicarbonates, di-sec-butyl peroxy dicarbonate, Tert-butyl hydroperoxide neodecanoic acid ester, tert-hexyl peroxide pivalate, t-butylperoxy pivarate, two bay of peroxidating Acyl, two positive decoyl of peroxidating, 1,1,3,3- tetramethyl butyl peroxidating isobutyrate, the peroxidating of 1,1,3,3- tetramethyl butyls- 2 ethyl hexanoic acid ester, peroxidating two (4- toluyls), benzoyl peroxide, tert-butyl hydroperoxide isobutyrate etc..These Among, particularly preferably using two excellent (4- tert-butylcyclohexyls) peroxy dicarbonates of cross-linking reaction efficiency, peroxidating two Lauroyl, benzoyl peroxide.
The compounding ratio of crosslinking agent in adhesive composition is commonly angled relative to above-mentioned base polymer (solid constituent) 100 Parts by weight, are compounded according to crosslinking agent (solid constituent) for the ratio below 10 parts by weight or so.The compounding ratio of above-mentioned crosslinking agent Preferably 0.01~10 parts by weight, more preferably 0.01~5 parts by weight or so.In addition, especially it is crosslinked using peroxide system It is preferably 0.05~1 parts by weight or so relative to 100 parts by weight of base polymer (solid constituent) during agent, more preferably 0.06 ~0.5 parts by weight.
For above-mentioned adhesive composition, as needed, can also suitably make in the range of the purpose of the present invention not departing from Use various additives.As additive, can include：Viscosity modifier, peel off conditioning agent, tackifiers, plasticizer, softening agent, Filler, pigment, colouring agent (pigment, dyestuff etc.), the pH of the formation such as glass fibre, bead, metal powder, other inorganic powders Conditioning agent (acid or alkali), antioxidant, ultra-violet absorber etc..
In addition, as described above, when adhesive phase includes above-mentioned dye compound, representational is in adhesive composition It is compounded dye compound.The compounding amount of dye compound in adhesive composition is for example relative to polymer solids component 100 Parts by weight are parts by weight of 0.01 parts by weight~10 or so, are preferably parts by weight of 0.02 parts by weight~5 or so.
Adhesive phase can arbitrarily make its drying or solid for example, by above-mentioned adhesive composition is coated on base material Change to be formed.As the base material, above-mentioned protective layer, light polarizing film can be used.Alternatively, it is also possible to thin using any suitable demoulding Film is as base material.
As the method above-mentioned adhesive composition being coated on above-mentioned base material, can use any suitable method. As this method, such as can include：Roller coat cloth, roller lick coating, intaglio plate coating, reversion type coating, roller brushing cloth, spraying, leaching Stain roller coat cloth, rod painting, scraper for coating, airblade coating, curtain coating, lip coating, die coating etc..
The mean transmissivity of wavelength 400nm~430nm of adhesive phase comprising above-mentioned dye compound is preferably 30% Hereinafter, it is more preferably less than 20%.In addition, wavelength 450nm~500nm's of the adhesive phase comprising above-mentioned dye compound is flat Equal transmitance is preferably more than 70%, is more preferably more than 75%, and the mean transmissivity of wavelength 500nm~780nm is preferably More than 80%, more preferably more than 85%.
The thickness of adhesive phase from the viewpoint of the function of ensuring light of the absorbing wavelength less than 430nm, be preferably 7 μm with On, more preferably more than 10 μm, more preferably more than 15 μm.The upper limit value of the thickness of adhesive phase for example can be 80 μm Below.
B. liquid crystal panel
The liquid crystal panel of the present invention includes liquid crystal cells and the polarizer configured in the both sides of the liquid crystal cells.In the liquid crystal At least one of the polarizer of the both sides configuration of unit is above-mentioned polarizer, and preferably both are above-mentioned polarizer.
C. liquid crystal display device
The liquid crystal display device of the present invention possesses above-mentioned liquid crystal panel.In the liquid crystal display device of the present invention, liquid crystal panel Configured with any suitable method.
Embodiment
The present invention is illustrated below according to embodiment, but the present invention is not restricted by the embodiments.Need what is illustrated It is that in embodiment unless otherwise specified, thickness uses digital micrometer (Anritsu Corporation manufactures, trade name " KC-351C ") measure.
[manufacture of 1 adhesive composition of Production Example (A1)]
The preparation ＞ of ＜ (methyl) acrylic acid series polymeric compounds
Added in the four-hole boiling flask for possessing agitating vane, thermometer, nitrogen ingress pipe, cooler and contain butyl acrylate (BA) 99 parts by weight, the monomer mixture of 1 parts by weight of acrylic acid 4- hydroxy butyl esters (HBA).
Further, relative to 100 parts by weight of above-mentioned monomer mixture (solid constituent), using as the 2 of polymerization initiator, 2 '-azodiisobutyronitrile, 0.1 parts by weight are together added with ethyl acetate, are slowly stirred and are imported nitrogen progress nitrogen displacement, so Afterwards by the liquid temperature in flask be maintained at 55 DEG C nearby carry out 7 it is small when polymerisation.Thereafter, acetic acid is added in obtained reaction solution Ethyl ester, preparation are adjusted to solid component concentration 30%, weight average molecular weight 1,600,000 (methyl) acrylic polymer solution.
The preparation ＞ of ＜ acrylic adhesive compositions
Relative to 100 parts by weight of solid constituent of obtained (methyl) acrylic polymer solution, isocyanates is added It is crosslinking agent (trade name：Takenate D110N, trimethylolpropane xylene diisocyanate, Mitsui Chemicals, Inc Manufacture) 0.1 parts by weight, the benzoyl peroxide (trade name of peroxide system crosslinking agent：NYPER BMT, Japanese grease strain formula meeting Society manufactures) 0.4 parts by weight and silane coupling agent (trade name：KBM403, Shin-Etsu Chemial Co., Ltd's manufacture) 0.08 weight Part, the diazosulfide compound dissolved in ethyl acetate in the way of solid constituent is 5% are (shown in following formula (I)s The maximum absorption wavelength of dye compound, absorption spectrum：420nm, fluorescent quantum yield：93%th, half breadth：100nm)0.1 Parts by weight (solids by weight) simultaneously stir, and thus obtain acrylic adhesive composition (A1).
The making ＞ of ＜ adhesive phases
Aforesaid propylene acid system adhesive composition (A1) is uniformly coated on fountain type coating machine and is shelled through silicon-type The mould release film formed from the pet film (PET film, transparent base) of 38 μm of the thickness of agent processing Surface, dry 2 minutes in 155 DEG C of air circulating type constant temperature oven, form the adhesive phase of 20 μm of thickness.
[manufacture of 2 adhesive composition of Production Example (A2)]
The additive amount of diazosulfide compound is set as 0.3 parts by weight (solids by weight), in addition, with manufacture Example 1 similarly obtains adhesive composition (A2).
[manufacture of 3 adhesive composition of Production Example (A3)]
The additive amount of diazosulfide compound is set as 0.6 parts by weight (solids by weight), in addition, with manufacture Example 1 similarly obtains adhesive composition (A3).
[manufacture of 4 adhesive composition of Production Example (B)]
Instead of 0.1 parts by weight of diazosulfide compound (solids by weight), BONASORB UA3911 (commodity are used Indoles based compound, the maximum absorption wavelength of absorption spectrum shown in name, following formula (II)s：398nm, half breadth：48nm、 Orient Chemical Industries Co., Ltd.s manufacture) 1 parts by weight (solids by weight), in addition, with manufacture Example 1 similarly obtains adhesive composition (B).
[manufacture of 5 adhesive composition of Production Example (C)]
Instead of 0.1 parts by weight of diazosulfide compound (solids by weight), FDB-009 (trade name, following formula are used (III) merocyanine (merocyanine) pigment, the maximum absorption wavelength of absorption spectrum shown in：394nm, half breadth： 43nm, YAMADA CHEMICAL CO., LTD. manufacture) 1 parts by weight (solids by weight), it is in addition, same with Production Example 1 Obtain adhesive composition (C) sample.
[manufacture of 6 adhesive composition of Production Example (D)]
Diazosulfide compound is not added with, in addition, adhesive composition (D) is obtained in the same manner as Production Example 1.
[manufacture of 7 protective layer used resin film of Production Example]
Obtain being fabricated in the same manner as the Production Example 1 of Japanese Unexamined Patent Publication 2009-161744 publications has glutaryl Asia 40 μm of thickness, the moisture permeability 80g/m of the metha crylic resin composition of amine ring element2Acrylic films.
[embodiment 1]
(light polarizing film)
As resin base material, prepare 100 μm of thickness, Tg75 DEG C of the amorphous with 7 moles of % isophthalic acid units gathers Ethylene glycol terephthalate (IPA is copolymerized PET) film.Sided corona treatment (58W/m is implemented to the film surface2/min)。
Prepare comprising acetoacetyl modified PVA (Nippon Synthetic Chemical Industry Co.'s manufacture, trade name：GOHSEFIMER Z200, average degree of polymerization：1200th, saponification degree：99.0 moles of %, acetoacetylate degree：5%；1 parts by weight) and PVA it is (average poly- It is right：4200th, saponification degree：99.2 mole %；9 parts by weight) PVA systems resin, relative to 100 parts by weight of PVA systems resin, add Add 13 parts by weight of potassium iodide, prepare PVA systems resin aqueous solution (PVA systems resin concentration：5.5 weight %).By the aqueous solution according to Dried thickness is that 13 μm of mode is coated on the sided corona treatment face of resin base material, passes through heated-air drying under 60 DEG C of atmosphere Drying in 10 minutes is carried out, the PVA resins of 9 μm of thickness are formed on resin base material.So make layered product.
Obtained layered product is stretched to 2.4 times (aerial assisting tensions) at 140 DEG C in atmosphere first.
Then, layered product is impregnated 30 seconds in the boric acid aqueous solution of 30 DEG C of liquid temperature makes PVA resins insoluble.It is right In the boric acid aqueous solution of this process, boric acid content is set as 3 parts by weight relative to 100 parts by weight of water.
Then, by layered product in the dyeing liquor comprising iodine and potassium iodide of 30 DEG C of liquid temperature, according to obtained light polarizing film The mode that singleton transmittance is 42~45% or so impregnates random time and is dyed.Using water as solvent, iodine concentration is set dyeing liquor It is set in the range of 0.1~0.4 weight %, iodate potassium concn is set as in the range of 0.7~2.8 weight %, iodine and potassium iodide The ratio between concentration be set as 1：7.
Then, layered product is impregnated 60 seconds in 30 DEG C of boric acid aqueous solution, the PVA resin beds for having adsorbed iodine is implemented Crosslinking Treatment.For the boric acid aqueous solution of this process, boric acid content is set as 3 parts by weight, potassium iodide relative to 100 parts by weight of water Content is set as 3 parts by weight relative to 100 parts by weight of water.
Further, by layered product in boric acid aqueous solution, at 70 DEG C of draft temperature, edge and aerial assisting tension before Same direction is stretched to 2.3 times (5.50 times of final stretching ratios).For the boric acid aqueous solution of this process, boric acid content phase It is set as 3.5 parts by weight for 100 parts by weight of water, iodate potassium content is set as 5 parts by weight relative to 100 parts by weight of water.
Then, it is set as the aqueous cleaning layered product of 4 parts by weight relative to 100 parts by weight of water with iodate potassium content, leads to 60 DEG C of warm air drying is crossed, the light polarizing film of 5 μm of thickness is obtained on resin base material.
(polarizer)
For obtained light polarizing film (being in the face of opposite side with resin base material), it is bonded and manufactures by curing type bonding agent The acrylic films of example 7.Specifically, curing type is coated in the way of thickness is 1.0 μm on acrylic films to glue Agent is connect, makes its fitting using roller machine.Thereafter, from acrylic films side, irradiation luminous ray cures curing type bonding agent.
Then, obtained adhesive phase in Production Example 1 is bonded on the acrylic films, obtain with resin base material/ The polarizer of light polarizing film/acrylic films/adhesive phase/mould release film structure.
[embodiment 2-1 and 2-2]
Instead of adhesive composition (A1), adhesive phase is formed using adhesive composition (A2), in addition, with implementation Example 1 similarly makes polarizer.
[embodiment 3-1 and 3-2]
Instead of adhesive composition (A1), adhesive phase is formed using adhesive composition (A3), in addition, with implementation Example 1 similarly makes polarizer.
[embodiment 4-1~4-4]
Instead of adhesive composition (A1), adhesive phase is formed using adhesive composition (B), in addition, with implementation Example 1 similarly makes polarizer.
[embodiment 5-1~5-4]
Instead of adhesive composition (A1), adhesive phase is formed using adhesive composition (C), in addition, with implementation Example 1 similarly makes polarizer.
[comparative example 1-1~1-35]
Instead of adhesive composition (A1), adhesive phase is formed using adhesive composition (D), in addition, with implementation Example 1 similarly makes polarizer.
[comparative example 2-1~2-2]
(light polarizing film)
The method that embodiment 1 according to Japanese Unexamined Patent Publication 2013-182162 publications is recorded makes light polarizing film.Specifically, It is as follows.
By 100 μm non-stretched polypropylene (PP) film (fusing point of thickness：163 DEG C) it is used as resin base material.
Using polyvinyl alcohol (hereinafter referred to as PVA) powder, (Nippon Synthetic Chemical Industry Co. manufactures Z-200：Average polymerization 99.0 moles of degree 1200, saponification degree %), 95 DEG C of hot water is dissolved in, prepares the aqueous solution of 3wt%.Use TESTER SANGYO Obtained aqueous solution coated in implementing on the resin base material of sided corona treatment, is made it be maintained at 80 by the applicator CO. manufactured DEG C baking oven in dry 10 minutes, form the prime coat of 0.2 μm of thickness.
Using the applicator of TESTER SANGYO CO. manufactures by 10wt%PVA aqueous solutions (JAPAN VAM＆POVAL CO., LTD. manufactures JF-23：98.0~99.0 moles of average degree of polymerization 2400, saponification degree %) coated on above-mentioned prime coat.Make Foregoing coat film is 20 minutes dry in 80 DEG C of baking oven is maintained at, and makes the layer of resin base material/prime coat/PVA resins Stack.
Obtained layered product is implemented to the free end simple tension of 5.8 times of longitudinal direction in 160 DEG C of baking oven is maintained at, is obtained Oriented film.The thickness of PVA layers after stretching is 6.0 μm.
The oriented film made iodine 0.35wt%, potassium iodide 10wt%, 26 DEG C of liquid temperature aqueous solution in, according to obtaining Light polarizing film singleton transmittance be 42~45% or so mode impregnate random time.
Then, potassium iodide 5.0wt%, boric acid 9.5wt%, 76 DEG C of liquid temperature aqueous solution in impregnate 300 seconds.
Further, by after impregnating 10 seconds and being cleaned in the pure water of 10 DEG C of liquid temperature, being maintained at 80 DEG C of baking oven Middle drying 200 seconds.
In this way, the light polarizing film of 6.0 μm of thickness is obtained on resin base material.
(polarizer)
Come using the light polarizing film and replacement adhesive composition (A) that obtain as described above using adhesive composition (D) Adhesive phase is formed, in addition, makes polarizer similarly to Example 1.
The polarizer obtained to each embodiment and comparative example carries out following measure.
(optical characteristics of polarizer)
(1) singleton transmittance
Passed through using the monomer of ultraviolet-uisible spectrophotometer (Japan Spectroscopy Corporation manufactures V7100) measure polarizer Rate.Singleton transmittance is that the Y value regarding correction by sensitiveness is measured and carried out using 2 degree of visual fields (illuminant-C) of JIS Z 8701.
(2) orthogonal form and aspect
Using ultraviolet-uisible spectrophotometer (Japan Spectroscopy Corporation manufacture V7100), the orthogonal color of polarizer is measured Phase a values and b values.
It should be noted that said determination is peeled off, in the bonding exposed by resin base material and mould release film from polarizer State (that is, [light polarizing film/acrylic films/adhesive phase/propylene of the acrylic films of Production Example 7 is fitted with oxidant layer Acid system film] structure) under carry out.This is in order to enable will not be reflected because of the surface of resin base material different and measurement result is produced It is raw to influence.In any embodiment and comparative example, the refractive index of acrylic films is about 1.50, the refractive index of light polarizing film is about 1.53rd, the refractive index of most surface is combined as 1.50/1.53, and structure of the measurement result without influence surveyed with surface reflection It is fixed.
Said determination the results are shown in Tables 1 and 2.In addition, the singleton transmittance (Y) of the polarizer of embodiment and comparative example Fig. 2 is shown in the relation of orthogonal form and aspect.It should be noted that in table, orthogonal form and aspect a values are denoted as " orthogonal a ", orthogonal form and aspect b values It is denoted as " orthogonal b ".
Table 1
Table 2
As shown in Tables 1 and 2 and Fig. 2, the polarizer of embodiment is satisfied by both formula (1) and formula (2), has high monomer The change (change from muted color to blue direction and/or red direction) of transmitance and orthogonal form and aspect is suppressed well. On the other hand, the polarizer of comparative example fails to meet both formula (1) and formula (2), the change of orthogonal form and aspect when singleton transmittance becomes higher Change also becomes larger.
Industrial applicability
The polarizer of the present invention is suitable for image display device.Specifically, LCD TV, liquid crystal display are suitable for Device, mobile phone, digital camera, video camera, portable game machine, automobile navigation, duplicator, printer, facsimile machine, clock, The liquid crystal panel of micro-wave oven etc..

Claims (7)

1. a kind of polarizer, its with the light polarizing film below 8 μm of thickness,
Meet following formula (1) and formula (2)：
√(a2+b2)≤2 × Y-84.7 formulas (1)
The formula (2) of Y >=42.5
In formula, Y is that the singleton transmittance regarding correction by sensitiveness is measured and carried out using 2 degree of visual fields (illuminant-C) of JIS Z8701 (%), a are orthogonal form and aspect a values, and b is orthogonal form and aspect b values.
2. polarizer according to claim 1, wherein, the light polarizing film has included in the wavelength region of 380nm~480nm There is the dye compound of the maximum absorption wavelength of absorption spectrum.
3. polarizer according to claim 1 or 2, it also has the adhesive at least one-sided configuration of the light polarizing film Layer,
The adhesive phase has the pigmented of the maximum absorption wavelength of absorption spectrum included in the wavelength region of 380nm~480nm Compound.
4. according to polarizer according to any one of claims 1 to 3, it also has at least one-sided configuration in the light polarizing film Protective layer,
The protective layer has the pigment chemical combination of the maximum absorption wavelength of absorption spectrum included in the wavelength region of 380nm~480nm Thing.
5. the polarizer according to any one of claim 2~4, wherein, the dye compound is in 380nm~430nm Wavelength region there is the maximum absorption wavelength of absorption spectrum and the half breadth of the absorption spectrum of the maximum absorption wave strong point is 10nm~60nm.
6. a kind of liquid crystal panel, it possesses polarizer according to any one of claims 1 to 5.
7. a kind of liquid crystal display device, it possesses the liquid crystal panel described in claim 6.
CN201711065090.2A 2016-11-02 2017-11-02 polarizer Pending CN108020878A (en)

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Application publication date: 20180511