CN108018665A - A kind of natural ramie fiber enhancing polymer matrix composite felt material removes formaldehyde and acetaldehyde treating method and apparatus - Google Patents

A kind of natural ramie fiber enhancing polymer matrix composite felt material removes formaldehyde and acetaldehyde treating method and apparatus Download PDF

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Publication number
CN108018665A
CN108018665A CN201810012651.0A CN201810012651A CN108018665A CN 108018665 A CN108018665 A CN 108018665A CN 201810012651 A CN201810012651 A CN 201810012651A CN 108018665 A CN108018665 A CN 108018665A
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China
Prior art keywords
felt material
polymer matrix
acetaldehyde
matrix composite
enhancing polymer
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Pending
Application number
CN201810012651.0A
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Chinese (zh)
Inventor
刘雪强
李志刚
潘国立
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CHANGCHUN BOCHAO AUTO ACCESSORIES Co Ltd
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CHANGCHUN BOCHAO AUTO ACCESSORIES Co Ltd
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Priority to CN201810012651.0A priority Critical patent/CN108018665A/en
Publication of CN108018665A publication Critical patent/CN108018665A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C7/00Heating or cooling textile fabrics
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B1/00Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating
    • D06B1/02Applying liquids, gases or vapours onto textile materials to effect treatment, e.g. washing, dyeing, bleaching, sizing or impregnating by spraying or projecting
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06CFINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
    • D06C29/00Finishing or dressing, of textile fabrics, not provided for in the preceding groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Reinforced Plastic Materials (AREA)

Abstract

The invention discloses a kind of natural ramie fiber enhancing polymer matrix composite felt material to remove formaldehyde and acetaldehyde treating method and apparatus, belongs to automotive material and manufactures and designs field.The present invention first heats natural fiber enhancing polymer matrix composite felt material, sprays adsorbent, air draft ventilation process;Then negative-pressure adsorption is carried out, excludes and adsorb the formaldehyde of release, acetaldehyde;Then a kind of formaldehydeless, acetaldehyde natural fiber enhancing polymer matrix felt material is obtained.Natural fiber produced by the present invention enhancing composite felt material has good environmental protection, formaldehydeless, acetaldehyde release, light weight, widely used.The fields such as automobile, rail vehicle, aerospace, building, decoration, packaging are can be widely applied to, are had a good application prospect.The treatment process is a kind of low cost, environment-friendly type flaxen fiber composite material felt material except formaldehyde, acetaldehyde technique.

Description

A kind of natural ramie fiber enhancing polymer matrix composite felt material removes formaldehyde and acetaldehyde processing side Method and device
Technical field
Belong to fibre reinforced composites preparation field.
Background technology
With the development of the society, the demands such as environmental protection, energy-saving material-saving are continuously improved in people, to automobile and automotive upholstery material The requirement of material is also higher and higher, Market competition.Lightweight is the trend of development of automobile, therefore lightweighting materials are on automobile Application also will be more and more common.Flaxen fiber has good performance as organic material, and environmentally protective.
And VOC problems are automotive interior materials to solve the problems, such as, traditional processing method be difficult remove completely it is compound Formaldehyde, acetaldehyde in material, the composite material produced are still more difficult to meet stringent automotive upholstery national legislation VOC release requests.Therefore, low cost removes formaldehyde, the acetaldehyde in flaxen fiber enhancing composite felt material, is urgently solved in industry development Problem certainly.
The content of the invention
In order to solve the prior art can not remove completely natural ramie fiber enhancing polymer matrix composite felt material in formaldehyde and The problem of acetaldehyde, the invention discloses a kind of natural ramie fiber enhancing polymer matrix composite felt material except the processing side of formaldehyde and acetaldehyde Method and device.
A kind of natural ramie fiber enhancing polymer matrix composite felt material is except the processing method of formaldehyde and acetaldehyde, and specific steps are such as Under:
1) natural ramie fiber enhancing polymer matrix composite felt material being heated, heating-up temperature is 150~300 DEG C, 5~20 minutes processing times;
2) treat that backward its of felt material cooling sprays adsorbent suspension, to solution complete wetting felt material;
3) fan-drying processing is carried out to felt material;
4) negative-pressure adsorption being carried out to felt material by way of vacuumizing, vacuum is 1~10kPa, pressurize 5~30 minutes, Remove releasable formaldehyde and acetaldehyde in natural ramie fiber.
Natural ramie fiber can be 1~5 kind in jute, flax, sisal hemp, hemp and ramee;Polymer fiber can To be 1~6 kind in PP, PE, PC, PA6, PA66 and PLA fiber;Adsorbent is silane coupler modified nano clay.
Adsorbent suspension collocation method is as follows:By the nanoclay of the 0.5-2wt% of the flaxen fiber gross mass, The dispersant of 0.25-1wt%, the silane coupling agent of 1-2wt% are added to the water, formed concentration be 10-30wt% nanoclay- Coupling agent suspension;The nanoclay-coupling agent suspension is stirred into 0.5-2h under 1000-1350rpm rotating speeds;By described in Nanoclay-coupling agent suspension stirs 1.5-3h under 1700-2000rpm rotating speeds, forms the coupling agent mixing of nanoclay Liquid.
A kind of natural ramie fiber enhancing polymer matrix composite felt material except the processing unit of formaldehyde and acetaldehyde, by heating unit 1, Sprinkling equipment 2, air exhausting device 3, closed container 4 and vacuum extractor 5 form;Heating unit 1 is hollow babinet, heater strip Box inside uniformly is installed on, conveyer belt 6 is hollow out of babinet to be passed through, and sprinkling equipment 2 and air exhausting device 3 are sequentially arranged at transmission The top of band 6, closed container 4 are connected with vacuum extractor 5.Heating unit 1 is used to complete to strengthen polymer to natural ramie fiber The heating stepses of base composite felt material;The step of sprinkling equipment 2 is used to complete spray adsorbent suspension, air exhausting device 3 has been used for The step of paired felt material carries out fan-drying processing;Closed container 4 and vacuum extractor 5 are used to complete negative-pressure adsorption step.
Beneficial effects of the present invention:
Natural ramie fiber enhancing composite felt material produced by the present invention has good environmental protection, formaldehydeless, acetaldehyde release, quality Gently, it is widely used.The fields such as automobile, rail vehicle, aerospace, building, decoration, packaging are can be widely applied to, are had good Application prospect.The processing method is low cost, environment-friendly type flaxen fiber composite material felt material except formaldehyde, acetaldehyde method.
Brief description of the drawings
Fig. 1 is that natural ramie fiber strengthens polymer matrix composite felt material except formaldehyde and the processing unit schematic diagram of acetaldehyde.
Embodiment
Embodiment 1
A kind of natural ramie fiber enhancing polymer matrix composite felt material removes the processing unit of formaldehyde and acetaldehyde in the present embodiment, by Heating unit 1, sprinkling equipment 2, air exhausting device 3, closed container 4 and vacuum extractor 5 form;Heating unit 1 is hollow Babinet, heater strip are uniformly installed on box inside, and conveyer belt 6 is hollow out of babinet to be passed through, sprinkling equipment 2 and air exhausting device 3 according to Secondary to be installed on the top of conveyer belt 6, closed container 4 is connected with vacuum extractor 5.Heating unit 1 is used to complete fine to natural fiber crops The heating stepses of dimension enhancing polymer matrix composite felt material;The step of sprinkling equipment 2 is used to complete spray adsorbent suspension, air draft The step of device 3 is used to complete to carry out fan-drying processing to felt material;Closed container 4 and vacuum extractor 5 are used to complete to bear Press adsorption step.
Embodiment 2
1) tossa enhancing polymer matrix composite felt material is heated, heating-up temperature is 170 DEG C, processing time 10 minutes;
2) treat that backward its of felt material cooling sprays adsorbent suspension, to solution complete wetting felt material;
3) fan-drying processing is carried out to felt material;
4) negative-pressure adsorption is carried out to felt material by way of vacuumizing, vacuum 5kPa, pressurize 20 minutes, removes jute Releasable formaldehyde and acetaldehyde in fiber-reinforced polymer-matrix composite felt material.
It for formaldehyde is 0.05mg/kg to use the burst size of pocket type method VOC test methods method test formaldehyde and acetaldehyde, acetaldehyde For 0.07mg/kg, TVOC is 3C μ g/g.Comply with the national standard requirements.
Embodiment 3
1) china-hemp fibers enhancing polymer matrix composite felt material is heated, heating-up temperature is 220 DEG C, processing time 20 minutes;
2) treat that backward its of felt material cooling sprays adsorbent suspension, to solution complete wetting felt material;
3) fan-drying processing is carried out to felt material;
4) negative-pressure adsorption is carried out to felt material by way of vacuumizing, vacuum 8kPa, pressurize 10 minutes, removes Chinese fiber crops Releasable formaldehyde and acetaldehyde in fiber-reinforced polymer-matrix composite felt material.
It for formaldehyde is 0.03mg/kg to use the burst size of pocket type method VOC test methods method test formaldehyde and acetaldehyde, acetaldehyde For 0.05mg/kg, TVOC is 2C μ g/g.Comply with the national standard requirements.
Embodiment 4
1) flax fiber enhancing polymer matrix composite felt material is heated, heating-up temperature is 190 DEG C, processing time 15 minutes;
2) treat that backward its of felt material cooling sprays adsorbent suspension, to solution complete wetting felt material;
3) fan-drying processing is carried out to felt material;
4) negative-pressure adsorption is carried out to felt material by way of vacuumizing, vacuum 10Kpa, pressurize 30 minutes, removes sub- Releasable formaldehyde and acetaldehyde in flaxen fiber enhancing polymer matrix composite felt material.
It for formaldehyde is 0.06mg/kg to use the burst size of pocket type method VOC test methods method test formaldehyde and acetaldehyde, acetaldehyde For 0.05mg/kg, TVOC is 2C μ g/g.Comply with the national standard requirements.
The collocation method of adsorbent suspension can be in the following ways:
1st, the 0.5wt% nano imvites of composite fibre gross mass are taken, 0.25wt% polyvinylpyrrolidones are as scattered Agent, 1wt% silane coupling agents are added to the water, and concentration 20wt% suspension is made, and are first stirred with mechanical agitator under 1350rpm 1h, then stirs 2h in 1700rpm, prepares dispersed nanoclay suspension.
2nd, take the 1wt% nano imvites of composite fibre gross mass, 0.25wt% polyvinylpyrrolidones as dispersant, 1.5wt% silane coupling agents are added to the water, and the suspension of concentration 20wt% is made, and are first stirred with mechanical agitator under 1350rpm 1h is mixed, then 2h is stirred in 1700rpm, prepares dispersed nanoclay suspension.
3rd, take the 2wt% nano imvites of composite fibre gross mass, 1wt% polyvinylpyrrolidones as dispersant, 2wt% silane coupling agents are added to the water, and the suspension of concentration 20wt% is made, and are first stirred with mechanical agitator under 1350rpm 1h, then stirs 2h in 1700rpm, prepares dispersed nanoclay suspension.

Claims (9)

1. a kind of natural ramie fiber enhancing polymer matrix composite felt material is comprised the following steps that except the processing method of formaldehyde and acetaldehyde:
1) natural ramie fiber enhancing polymer matrix composite felt material is heated, heating-up temperature is 150~300 DEG C, processing 5~20 minutes time;
2) treat that backward its of felt material cooling sprays adsorbent suspension, to solution complete wetting felt material;
3) fan-drying processing is carried out to felt material;
4) negative-pressure adsorption is carried out to felt material by way of vacuumizing, vacuum is 1~10kPa, and pressurize 5~30 minutes, removes Releasable formaldehyde and acetaldehyde in natural ramie fiber;
Natural ramie fiber is 1~5 kind in jute, flax, sisal hemp, hemp and ramee;Polymer fiber can be PP, 1~6 kind in PE, PC, PA6, PA66 and PLA fiber;The adsorbent is silane coupler modified nano clay.
2. natural ramie fiber enhancing polymer matrix composite felt material according to claim 1 is except the processing side of formaldehyde and acetaldehyde Method, it is characterised in that the adsorbent suspension configures in accordance with the following steps:By the 0.5-2wt% of the flaxen fiber gross mass Nanoclay, the dispersant of 0.25-1wt%, the silane coupling agent of 1-2wt% be added to the water, it is 10-30wt% to form concentration Nanoclay-coupling agent suspension;The nanoclay-coupling agent suspension is stirred under 1000-1350rpm rotating speeds 0.5-2h;The nanoclay-coupling agent suspension is stirred into 1.5-3h under 1700-2000rpm rotating speeds, forms nanoclay Coupling agent mixed liquor.
3. natural ramie fiber enhancing polymer matrix composite felt material according to claim 2 is except the processing side of formaldehyde and acetaldehyde Method, it is characterised in that take the 0.5wt% nano imvites of composite fibre gross mass, 0.25wt% polyvinylpyrrolidone conducts Dispersant, 1wt% silane coupling agents are added to the water, and concentration 20wt% suspension is made, first with mechanical agitator under 1350rpm 1h is stirred, then 2h is stirred in 1700rpm, prepares dispersed nanoclay suspension.
4. natural ramie fiber enhancing polymer matrix composite felt material according to claim 2 is except the processing side of formaldehyde and acetaldehyde Method, it is characterised in that take the 1wt% nano imvites of composite fibre gross mass, 0.25wt% polyvinylpyrrolidones, which are used as, to be divided Powder, 1.5wt% silane coupling agents are added to the water, and the suspension of concentration 20wt% is made, first with mechanical agitator in 1350rpm Lower stirring 1h, then stirs 2h in 1700rpm, prepares dispersed nanoclay suspension.
5. natural ramie fiber enhancing polymer matrix composite felt material according to claim 2 is except the processing side of formaldehyde and acetaldehyde Method, it is characterised in that take the 2wt% nano imvites of composite fibre gross mass, 1wt% polyvinylpyrrolidones are as scattered Agent, 2wt% silane coupling agents are added to the water, and the suspension of concentration 20wt% is made, and are first stirred with mechanical agitator under 1350rpm 1h is mixed, then 2h is stirred in 1700rpm, prepares dispersed nanoclay suspension.
6. the natural ramie fiber enhancing polymer matrix composite felt material according to Claims 1 to 5 any one removes formaldehyde and second The processing method of aldehyde, it is characterised in that
Step 1) heats tossa enhancing polymer matrix composite felt material, and heating-up temperature is 170 DEG C, processing time 10 minutes;And step 4) by way of vacuumizing to felt material carry out negative-pressure adsorption, vacuum 5kPa, pressurize 20 minutes, Remove releasable formaldehyde and acetaldehyde in tossa enhancing polymer matrix composite felt material.
7. the natural ramie fiber enhancing polymer matrix composite felt material according to Claims 1 to 5 any one removes formaldehyde and second The processing method of aldehyde, it is characterised in that
Step 1) heats china-hemp fibers enhancing polymer matrix composite felt material, and heating-up temperature is 220 DEG C, processing time 20 minutes;And step 4) by way of vacuumizing to felt material carry out negative-pressure adsorption, vacuum 8kPa, pressurize 10 minutes, Remove releasable formaldehyde and acetaldehyde in china-hemp fibers enhancing polymer matrix composite felt material.
8. the natural ramie fiber enhancing polymer matrix composite felt material according to Claims 1 to 5 any one removes formaldehyde and second The processing method of aldehyde, it is characterised in that
Step 1) heats flax fiber enhancing polymer matrix composite felt material, and heating-up temperature is 190 DEG C, processing time 15 minutes;And step 4) by way of vacuumizing to felt material carry out negative-pressure adsorption, vacuum 10kPa, pressurize 30 minutes, Remove releasable formaldehyde and acetaldehyde in flax fiber enhancing polymer matrix composite felt material.
A kind of 9. processing that formaldehyde and acetaldehyde are removed for natural ramie fiber as claimed in claim 1 enhancing polymer matrix composite felt material The device of method, it is characterised in that the device is by heating unit (1), sprinkling equipment (2), air exhausting device (3), closed container (4) formed with vacuum extractor (5);Heating unit (1) is hollow babinet, and heater strip is uniformly installed on box inside, transmission (6) are hollow out of babinet passes through for band, and sprinkling equipment (2) and air exhausting device (3) are sequentially arranged at conveyer belt (6) top, closed Container (4) is connected with vacuum extractor (5);Heating unit (1) is used to complete to strengthen polymer matrix composite felt to natural ramie fiber The heating stepses of material;The step of sprinkling equipment (2) is used to complete spray adsorbent suspension, air exhausting device (3) is used for completion pair Felt material carries out the step of fan-drying processing;Closed container (4) and vacuum extractor (5) are used to complete negative-pressure adsorption step.
CN201810012651.0A 2018-01-05 2018-01-05 A kind of natural ramie fiber enhancing polymer matrix composite felt material removes formaldehyde and acetaldehyde treating method and apparatus Pending CN108018665A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108943926A (en) * 2018-07-03 2018-12-07 蔡菁菁 A kind of linen fiber composite plates and preparation method of the low VOC content for roof of the vehicle

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202730459U (en) * 2012-03-15 2013-02-13 江苏金呢工程织物股份有限公司 Special atomizing modification device for polyester forming fabric
US20150044924A1 (en) * 2012-03-02 2015-02-12 Avic Composite Corporation Ltd. Composite having plant fiber textile and fabricating method thereof
CN104690979A (en) * 2015-02-16 2015-06-10 长春博超汽车零部件股份有限公司 Low-VOC natural fiber composite as well as preparation method and application of composite
CN104924636A (en) * 2015-03-26 2015-09-23 马文志 Production method and device of environment-friendly fireproof insulation polystyrene board

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150044924A1 (en) * 2012-03-02 2015-02-12 Avic Composite Corporation Ltd. Composite having plant fiber textile and fabricating method thereof
CN202730459U (en) * 2012-03-15 2013-02-13 江苏金呢工程织物股份有限公司 Special atomizing modification device for polyester forming fabric
CN104690979A (en) * 2015-02-16 2015-06-10 长春博超汽车零部件股份有限公司 Low-VOC natural fiber composite as well as preparation method and application of composite
CN104924636A (en) * 2015-03-26 2015-09-23 马文志 Production method and device of environment-friendly fireproof insulation polystyrene board

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108943926A (en) * 2018-07-03 2018-12-07 蔡菁菁 A kind of linen fiber composite plates and preparation method of the low VOC content for roof of the vehicle

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Application publication date: 20180511