CN108018520A - A kind of device and method that can improve injection shaping composite pipe blank bond strength - Google Patents

A kind of device and method that can improve injection shaping composite pipe blank bond strength Download PDF

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Publication number
CN108018520A
CN108018520A CN201610931028.6A CN201610931028A CN108018520A CN 108018520 A CN108018520 A CN 108018520A CN 201610931028 A CN201610931028 A CN 201610931028A CN 108018520 A CN108018520 A CN 108018520A
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atomization
foundry alloy
pipe
temperature
atomizer
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CN108018520B (en
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任三兵
樊俊飞
赵顺利
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Baoshan Iron and Steel Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Metal Powder And Suspensions Thereof (AREA)

Abstract

A kind of device that can improve injection shaping composite pipe blank bond strength, including the smelting furnace with temp sensing function, middle turn-up mechanism and atomization storehouse, its internal compound foundry alloy heating is smelted into compound foundry alloy steel stream by smelting furnace, is reached and is sent into atomization storehouse by middle turn-up mechanism after temperature requirement.Atomization storehouse is passed through inert gas, makes to keep nonoxidizing atmosphere in stove, and the lower part for being atomized storehouse is provided with the air intake device of the exhausting in atomization.Baffle mechanism is set below middle turn-up mechanism atomizer, initial period opens atomizer, while compound foundry alloy steel stream is poured into middle turn-up mechanism, start the baffle mechanism, it is moved into the purging that atomization gases at high pressure are blocked below atomizer, after molten drop sprays, according to steel grade cast temperature and flow velocity, set baffle mechanism Backoff time, the matrix pipe below baffle mechanism is set to avoid and initial low-temperature metal drop contact, uniform metal injection drop temperature, improves the combination power of atomization metal and matrix pipe.

Description

A kind of device and method that can improve injection shaping composite pipe blank bond strength
Technical field
The present invention relates to the manufacturing field that injection prepares composite material, more particularly to a kind of can improve to spray shaping multiple tube The device of the bond strength of base and corresponding application process.
Background technology
At present, injection shaping is a kind of new technology that special material is prepared using the method quickly solidified, which has concurrently There are the dual characteristics of nearly end form processing and semi-solid processing.High-pressure inert gas will be from tundish in injection shaping atomizer The interior alloy liquid stream by catheter outflow is atomized into tiny molten drop, and molten drop flies and gradual under the action of high-speed flow Cooling, is deposited on the effigurate depositor of tool before these molten drops not yet solidify completely, is penetrated by varying molten drop Stream and the relative position of depositor and the forms of motion of depositor, can obtain the different shapes such as disk (column), pipe (ring), plate (band) Semi-finished product blank.
Traditional pipe manufacturing technology can produce seamless tube blank, it can be difficult to production composite pipe blank base, even if to produce And difficulty is bigger.Therefore the technology of some existing production composite pipe blank bases utilizes the mode of injection shaping mostly.
Chinese patent CN200410022954.9-《Jet deposition prepares the method and its equipment of large ring》Disclose one The method that kind jet deposition prepares large ring, grains will be formed using inert gas by molten metal or alloy atomization, Inject directly on matrix, through hitting, coalescing, solidifying and form deposit preform, and the movement of crucible and atomizer and the rotation of matrix Turn, elevating movement by intelligent control, matrix using interior hot method heating, it is characterized in that:The molten metal degree of superheat for 150 DEG C~ 350 DEG C, jetting height is 100~300mm, and atomization air pressure is 0.8~1.2MPa, a diameter of 3.0~6.0mm of liquid stream, and matrix turns Speed is 1~10rpm, and crucible movement rate is 5~20mm/s, and matrix lifting speed is 0.1~1.0mm/min.Wood invention also public affairs Equipment used by this method is opened.The invention is that a kind of preparation for large ring will not produce the injection that breaks of cracking and sink The method that product prepares large ring.
Contrasted by field conduct, the tissue that major advantage is to control different radial positions of this method can System respectively goes out the larger pipe of wall thickness.But it also has the shortcomings that obvious:
Matrix, deposit preform and substrate support seat etc. need to move along a straight line back and forth during preparation.Due to deposition blank and The part quality moved together is big, causes inertia very big, it is difficult to controls, so as to constrain size and the quality rule of deposition pipe Mould, while cause shuttle speed quickly, can not possibly also constrain the cooling rate of deposit preform, it can only be produced necessarily furthermore with the technique The composite pipe blank base of length, and pipe is installed and fetches and delivers inconvenience, limits the development of the technique.
103962558 A of patent CN disclose it is a kind of prepare horizontal pipe bad supporting mechanism and atomization system, molten steel is melted Tundish is poured into after change, when molten metal flows through nozzle by the catheter of tundish bottom, the high pressure sprayed in nozzle is high Fast inert gas atomizer forms an atomizer (atomizing) cone, atomizing particle is deposited on the pipe matrix of lower section, pipe into tiny particle Matrix moves forward under the drive of supporting mechanism while rotating;Pipe matrix is before atomizer (atomizing) cone of entering through high-frequency induction Coil quickly heats up to 800 DEG C or so, can effectively strengthen the combination power for spraying layer and pipe matrix.When pipe deposition finishes it Equipment is slowly removed under the drive of supporting mechanism afterwards, follow-up pipe follows up at the same time, carries out continuous production, ultimately forms compound Pipe base.
The starting stage that this technique is shaped in injection, since molten steel flows through tundish and catheter, temperature substantially reduces, Liquid phase ratio substantially reduces in the metallic particles formed after atomization, and result in after complex matrix collides is difficult often to be incorporated in one Rise, so as to form the source of cracking.
In addition, high change after the previous emperor is presented in the temperature of casting steel stream at initial stage, the temperature of initial steel stream is relatively low, in atomization and Temperature is lower during deposition, it is difficult to effectively realize the bonding with complex matrix.
In conclusion shaping production composite pipe blank base using injection under the prior art remains various shortcomings, therefore these are lacked The improvement of point seems even more important for preparing composite pipe blank base for injection.
The content of the invention
To solve the above-mentioned problems, the present invention provides a kind of device that can improve injection shaping composite pipe blank bond strength And method, its is described in detail below:
A kind of device that can improve injection shaping composite pipe blank bond strength, including the melting with thermocouple temperature measurement function Stove, middle turn-up mechanism and atomization storehouse, it is characterised in that:
Its internal compound foundry alloy heating is smelted into compound foundry alloy steel stream by the smelting furnace, and passes through thermocouple Thermometric, reaches and is sent into atomization storehouse by middle turn-up mechanism after temperature requirement;
The atomization storehouse is passed through inert gas by its inert gas piping set, makes to keep non-oxide gas in stove Atmosphere, the lower part for being atomized storehouse are provided with the air intake device of the exhausting in atomization;
The Liquid pouring pipe that the tundish actuator base is set streams the compound foundry alloy steel entered from smelting furnace into mist Change nozzle, compound foundry alloy steel stream is atomized into tiny molten drop by the gases at high pressure of atomizer, and sprayed in atomization A baffle mechanism is provided with below mouth, in atomized spray initial period, the atomization gases at high pressure for opening atomizer switch, While compound foundry alloy steel stream is poured into middle turn-up mechanism, start the baffle mechanism, be moved into the lower section of atomizer, hide The purging of initial atomization gases at high pressure is blocked, after the molten drop injection of compound foundry alloy steel stream atomization, is poured according to steel grade Cast temperature and flow velocity, set the Backoff time of baffle mechanism, make the matrix pipe below baffle mechanism avoid with it is initial The molten drop contact of low temperature, the uniform temperature of metal injection drop, improves the combination power of atomization metal and matrix pipe.
A kind of device that can improve injection shaping composite pipe blank bond strength according to the present invention, it is characterised in that described Baffle mechanism cross sectional shape for sector.
A kind of method that can improve injection shaping composite pipe blank bond strength, injection shaping can be improved based on above-mentioned one kind The device of composite pipe blank bond strength, it comprises the following steps that described:
1) the compound foundry alloy heating in its internal crucible is smelted into compound foundry alloy steel stream by smelting furnace, and passes through heat Galvanic couple thermometric, taps after reaching temperature requirement, is sent into middle turn-up mechanism;
2) atomization storehouse is passed through inert gas by its inert gas piping set, makes to keep nonoxidizing atmosphere in stove, in Between turn-up mechanism Liquid pouring pipe prepare the compound foundry alloy steel entered from smelting furnace is streamed into atomizer;
3) in atomized spray initial period, the atomization gases at high pressure for opening atomizer switch, in compound foundry alloy steel stream While being poured into middle turn-up mechanism, start baffle mechanism, be moved into the lower section of atomizer, it is high to shelter from initial atomization Calm the anger the purging of body, since heat dissipation of the purging to matrix pipe of initial atomization gases at high pressure is very big, pass through baffle mechanism Blocked, very effective can reduce temperature drop of the atomization gas to depositing base;
4) after the molten drop injection of compound foundry alloy steel stream atomization, according to steel grade cast temperature and flow velocity, setting gear The Backoff time of trigger structure, makes the matrix pipe below baffle mechanism avoid the molten drop with initial low temperature from contacting, The uniformly temperature of metal injection drop, improves the combination power of atomization metal and matrix pipe, until completing to spray formed composite Pipe;
5) in step 4), often also slag and surface are tiny molten for the molten drop of the initial low temperature in casting cycle Slag, the field trash in initial flow stock is got rid of by baffle mechanism, can significantly prevent field trash in matrix pipe (5) Surface forms formation of crack;
6) in step 4), with the rollback of baffle mechanism, to the in-house molten steel of tundish establish liquid level reserve it is more abundant Time so that its in follow-up course of injection stablize liquid level, regime flow.
A kind of key point of device and method that can improve injection shaping composite pipe blank bond strength of the present invention is, pours Casting initial stage blocks initial flow stock using baffle mechanism, and after stream stock temperature reaches the temperature of process requirements, starting baffle retreats, So that high-temperature atomizing particle injects directly on complex matrix surface, so that reach combining closely for atomization metal and deposited metal, Simultaneously because the heat transfer effect of high-temperature metal particle and matrix so that matrix blank temperature raises, after can more closely combining Continuous atomization metal.
Obtained using a kind of device and method that can improve injection shaping composite pipe blank bond strength of the present invention as follows Beneficial effect:
(1) a kind of device and method that can improve injection shaping composite pipe blank bond strength of the invention, passes through baffle machine Structure is blocked, and matrix pipe can be made, which to avoid heat dissipation of the gas purging of starting stage on matrix pipe, to be influenced, effective to reduce Temperature drop of the atomization gas to matrix pipe;
(2) a kind of device and method that can improve injection shaping composite pipe blank bond strength of the invention, passes through baffle machine Structure has blocked the field trash such as tiny slag of slag and surface in the initial flow stock of casting cycle, can significantly prevent from being mingled with Thing forms formation of crack in matrix surface;
(3) a kind of device and method that can improve injection shaping composite pipe blank bond strength of the invention, passes through baffle machine Structure has blocked low temperature stream stock so that the temperature of follow-up steel stream constantly rises, so as to uniformly spray the temperature of molten steel, further improves The combination power of atomization metal and matrix pipe.
(4) a kind of device and method that can improve injection shaping composite pipe blank bond strength of the invention, passes through baffle machine The effect of structure, establishes liquid level to the in-house molten steel of tundish and reserves compared with plenty of time, so that it is in follow-up injection Stablize liquid level, regime flow in journey.
Brief description of the drawings
Fig. 1 is a kind of device part of device and method that can improve injection shaping composite pipe blank bond strength of the present invention Concrete structure schematic diagram;
In figure:1- smelting furnaces, 1a- thermocouples, 2- centres turn-up mechanism, 2a- Liquid pouring pipes, 2b- atomizers, 3- atomizations storehouse, 3a- inert gas pipings, 3b- air intake devices, 4- baffle mechanisms, 5- matrix pipes.
Embodiment
With reference to the accompanying drawings and examples to a kind of dress that can improve injection shaping composite pipe blank bond strength of the present invention Put and method is further described.
As shown in Figure 1, a kind of device that can improve injection shaping composite pipe blank bond strength, including with thermocouple temperature measurement Its internal compound foundry alloy heating is smelted into compound mother by the smelting furnace 1 of function, middle turn-up mechanism 2 and atomization storehouse 3, smelting furnace Steel alloy stream, and by thermocouple 1a thermometrics, reaches and is sent into atomization storehouse 3 by middle turn-up mechanism 2 after temperature requirement;
Atomization storehouse 3 is passed through inert gas by its inert gas piping 3a set, makes to keep nonoxidizing atmosphere, mist in stove The lower part for changing storehouse is provided with the air intake device 3b of the exhausting in atomization;
The Liquid pouring pipe 2a that middle 2 bottom of turn-up mechanism is set streams the compound foundry alloy steel entered from smelting furnace 1 into atomization Nozzle 2b, tiny molten drop is atomized into by the gases at high pressure of atomizer by compound foundry alloy steel stream, and is sprayed in atomization A baffle mechanism 4 is provided with below mouth, in atomized spray initial period, the atomization gases at high pressure for opening atomizer switch, While compound foundry alloy steel stream is poured into middle turn-up mechanism, starts the baffle mechanism, be moved into the lower section of atomizer, The purging of initial atomization gases at high pressure is sheltered from, after the molten drop injection of compound foundry alloy steel stream atomization, according to steel grade Cast temperature and flow velocity, set the Backoff time of baffle mechanism, make the matrix pipe below the baffle mechanism avoid with initially Low temperature molten drop contact, the uniform temperature of metal injection drop, improves the combination power of atomization metal and matrix pipe.
The cross sectional shape of baffle mechanism is sector.
A kind of method that can improve injection shaping composite pipe blank bond strength, injection shaping can be improved based on above-mentioned one kind The device of composite pipe blank bond strength, it comprises the following steps that described:
1) the compound foundry alloy heating in its internal crucible is smelted into compound foundry alloy steel stream by smelting furnace 1, and is passed through Thermocouple 1a thermometrics, tap after reaching temperature requirement, are sent into middle turn-up mechanism 2;
2) atomization storehouse 3 is passed through inert gas by its inert gas piping 3a set, makes to keep nonoxidizing atmosphere in stove, The Liquid pouring pipe 2a of middle turn-up mechanism 2 prepares to stream the compound foundry alloy steel entered from smelting furnace 1 into atomizer 2b;
3) in atomized spray initial period, the atomization gases at high pressure for opening atomizer 2b switch, in compound foundry alloy steel While stream is poured into middle turn-up mechanism 2, starts baffle mechanism 4, be moved into the lower section of atomizer, shelter from initial mist Change the purging of gases at high pressure, since heat dissipation of the initial purging for being atomized gases at high pressure to matrix pipe 5 is very big, pass through baffle Mechanism is blocked, and very effective can reduce temperature drop of the atomization gas to depositing base;
4) after the molten drop injection of compound foundry alloy steel stream atomization, according to steel grade cast temperature and flow velocity, setting gear The Backoff time of trigger structure 4, connects the molten drop with initial low temperature that avoids of the matrix pipe 5 below baffle mechanism Touch, the uniform temperature of metal injection drop, improve the combination power of atomization metal and matrix pipe, until completing injection shaping again Close pipe;
5) in step 4), often also slag and surface are tiny molten for the molten drop of the initial low temperature in casting cycle Slag, the field trash in initial flow stock is got rid of by baffle mechanism 4, can significantly prevent field trash in matrix pipe 5 Surface forms formation of crack;
6) in step 4), with the rollback of baffle mechanism 4, establish liquid level to middle 2 inside molten steel of turn-up mechanism and reserve and relatively fill The abundant time, so that it stablizes liquid level, regime flow in follow-up course of injection.
A kind of key point of device and method that can improve injection shaping composite pipe blank bond strength of the present invention is, pours Casting initial stage blocks initial flow stock using baffle mechanism, and after stream stock temperature reaches the temperature of process requirements, starting baffle retreats, So that high-temperature atomizing particle injects directly on complex matrix surface, so that reach combining closely for atomization metal and deposited metal, Simultaneously because the heat transfer effect of high-temperature metal particle and matrix so that matrix blank temperature raises, after can more closely combining Continuous atomization metal.
Embodiment
The preparation method of carbon steel pipe and alloy steel composite pipe is as follows:
Carbon steel pipe matrix (i.e. matrix pipe 4), thickness 3mm, pipe clamping and conveying device are installed in storehouse is atomized first Movement and the rotary speed of matrix pipe can be controlled.Steel alloy masterbatch is added in the crucible of smelting furnace 1, after heating fusing, When the degree of superheat is maintained at 150 DEG C, tilt pouring enters middle turn-up mechanism 2.Baffle mechanism is apart from the distance of drain pipe end 300mm, starts baffle mechanism and is moved into below atomizer.Molten steel cast tundish moment, open atomizer into Row atomization metal, 5s rear baffles gradually retract, and translational speed is set as 50mm/s.So that atomization metal particle injects directly to base On body pipe, the translational speed of pipe is set as 50mm/min, and velocity of rotation is set as 100rad/min.With injection into OK, pipe is gradually moved, ultimately forms composite pipe blank.
The present invention it is a kind of can improve injection shaping composite pipe blank bond strength device and method, by baffle mechanism into Row blocks, and matrix pipe can be made, which to avoid heat dissipation of the gas purging of starting stage on matrix pipe, to be influenced, and is effectively reduced mist Change temperature drop of the gas to matrix pipe;The present invention has blocked slag and surface in the initial flow stock of casting cycle by baffle mechanism The field trashes such as tiny slag, can significantly prevent field trash from forming formation of crack in matrix surface;The present invention passes through baffle Low temperature stream stock has blocked in mechanism so that the temperature of follow-up steel stream constantly rises, so as to uniformly spray the temperature of molten steel, further carries The combination power of high atomization metal and matrix pipe;The present invention is built by the effect of baffle mechanism to the in-house molten steel of tundish Vertical liquid level is reserved compared with plenty of time, so that it stablizes liquid level, regime flow in follow-up course of injection.
A kind of device and method that can improve injection shaping composite pipe blank bond strength of the present invention is suitable for various compound The injection figuration manufacture field of pipe.

Claims (3)

1. a kind of device that can improve injection shaping composite pipe blank bond strength, including the smelting furnace with thermocouple temperature measurement function (1), middle turn-up mechanism (2) and atomization storehouse (3), it is characterised in that:
Its internal compound foundry alloy heating is smelted into compound foundry alloy steel stream by the smelting furnace (1), and passes through thermocouple (1a) thermometric, reaches and is sent into atomization storehouse (3) by middle turn-up mechanism (2) after temperature requirement;
The inert gas piping (3a) that the atomization storehouse (3) is set by it is passed through inert gas, makes to keep non-oxide in stove Atmosphere, the lower part for being atomized storehouse are provided with the air intake device (3b) of the exhausting in atomization;
The compound foundry alloy steel stream that the Liquid pouring pipe (2a) that described middle turn-up mechanism (2) bottom is set will enter from smelting furnace (1) Atomizer (2b) is sent into, compound foundry alloy steel stream is atomized into tiny molten drop by the gases at high pressure of atomizer, And a baffle mechanism (4) is provided with below atomizer, it is high in atomized spray initial period, the atomization for opening atomizer Gas switch is pressed, while compound foundry alloy steel stream is poured into middle turn-up mechanism, starts the baffle mechanism, is moved into atomization The lower section of nozzle, shelters from the purging of initial atomization gases at high pressure, when the molten drop injection of compound foundry alloy steel stream atomization Afterwards, according to steel grade cast temperature and flow velocity, the Backoff time of baffle mechanism is set, makes the matrix pipe below baffle mechanism (5) the molten drop with initial low temperature that avoids contacts, and the uniform temperature of metal injection drop, improves atomization metal and base The combination power of body pipe.
A kind of 2. device that can improve injection shaping composite pipe blank bond strength as claimed in claim 1, it is characterised in that institute The cross sectional shape for the baffle mechanism stated is sector.
3. a kind of method that can improve injection shaping composite pipe blank bond strength, one kind based on the claims can improve spray The device of formed composite pipe bond strength is penetrated, it comprises the following steps that described:
1) the compound foundry alloy heating in its internal crucible is smelted into compound foundry alloy steel stream by smelting furnace (1), and passes through heat Galvanic couple (1a) thermometric, taps after reaching temperature requirement, is sent into middle turn-up mechanism (2);
2) inert gas piping (3a) that atomization storehouse (3) is set by it is passed through inert gas, makes to keep nonoxidizing atmosphere in stove, The Liquid pouring pipe (2a) of middle turn-up mechanism (2) prepares to stream the compound foundry alloy steel entered from smelting furnace (1) into atomizer (2b);
3) in atomized spray initial period, the atomization gases at high pressure for opening atomizer (2b) switch, in compound foundry alloy steel stream While being poured into middle turn-up mechanism (2), start baffle mechanism (4), be moved into the lower section of atomizer, shelter from initial The purging of gases at high pressure is atomized, since heat dissipation of the initial purging for being atomized gases at high pressure to matrix pipe (5) is very big, is passed through Baffle mechanism is blocked, and very effective can reduce temperature drop of the atomization gas to depositing base;
4) after the molten drop injection of compound foundry alloy steel stream atomization, according to steel grade cast temperature and flow velocity, baffle machine is set The Backoff time of structure (4), connects the molten drop with initial low temperature that avoids of the matrix pipe (5) below baffle mechanism Touch, the uniform temperature of metal injection drop, improve the combination power of atomization metal and matrix pipe, until completing injection shaping again Close pipe;
5) in step 4), the molten drop of the initial low temperature in casting cycle often also has the tiny slag of slag and surface, leads to Cross baffle mechanism (4) and get rid of field trash in initial flow stock, significantly can prevent field trash from being formed in matrix surface Formation of crack;
6) in step 4), with the rollback of baffle mechanism (4), establish liquid level to the internal molten steel of middle turn-up mechanism (2) and reserve and relatively fill The abundant time, so that it stablizes liquid level, regime flow in follow-up course of injection.
CN201610931028.6A 2016-10-31 2016-10-31 Device and method capable of improving bonding strength of spray-formed composite pipe blank Active CN108018520B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114406909A (en) * 2022-01-19 2022-04-29 成都飞机工业(集团)有限责任公司 Sand blasting protection device and sand blasting device

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Publication number Priority date Publication date Assignee Title
CN101549404A (en) * 2008-03-31 2009-10-07 杨云峰 Process and equipment for precise spray forming and layer-by-layer rolling repair and manufacturing
CN103962558A (en) * 2013-01-24 2014-08-06 宝山钢铁股份有限公司 Method for preparing composite tube blank continuously by spray forming
CN106132599A (en) * 2014-03-31 2016-11-16 杰富意钢铁株式会社 The manufacture method of atomized metal pow der
WO2016184455A1 (en) * 2015-05-19 2016-11-24 Technische Universität Bergakademie Freiberg Device and method for atomizing molten materials

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101549404A (en) * 2008-03-31 2009-10-07 杨云峰 Process and equipment for precise spray forming and layer-by-layer rolling repair and manufacturing
CN103962558A (en) * 2013-01-24 2014-08-06 宝山钢铁股份有限公司 Method for preparing composite tube blank continuously by spray forming
CN106132599A (en) * 2014-03-31 2016-11-16 杰富意钢铁株式会社 The manufacture method of atomized metal pow der
WO2016184455A1 (en) * 2015-05-19 2016-11-24 Technische Universität Bergakademie Freiberg Device and method for atomizing molten materials

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114406909A (en) * 2022-01-19 2022-04-29 成都飞机工业(集团)有限责任公司 Sand blasting protection device and sand blasting device

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