CN108018133A - Without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent - Google Patents
Without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent Download PDFInfo
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- CN108018133A CN108018133A CN201711381543.2A CN201711381543A CN108018133A CN 108018133 A CN108018133 A CN 108018133A CN 201711381543 A CN201711381543 A CN 201711381543A CN 108018133 A CN108018133 A CN 108018133A
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/1226—Phosphorus containing
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/667—Neutral esters, e.g. sorbitan esters
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Abstract
The invention discloses a kind of mah-jong cleaning agent without aviation kerosine, its preparing raw material includes：Deionized water, glycolic, polymer modification hydroxyapatite, acetic acid, ethyl acetate, potassium chloride, ethylene glycol monostearate, lauric acid amide of ethanol, dipropylene glycol.The cleaning agent anti-microbial property of the present invention is good, of low cost, environmentally protective and have rapid cleaning ability, in addition the cleaning agent odorlessness, mahjong surface is painted without any corrosivity and will not be very extensive to mahjong demagnetization, market prospects.
Description
Technical field
The invention belongs to cleaning agent technical field, more particularly it relates to it is a kind of without aviation kerosine can be quick
Clean asepsis environment-protecting antibacterial cleaning agent of mahjong and preparation method thereof.
Background technology
Mahjong is widely used in daily life, is constantly touched due to the use of during, and attachment is substantial amounts of above
Dirt, if do not cleaned effectively to these, directly contributes mahjong weather stain, service life is short, and class is rudimentary.It is existing
The cleaning agent of technology does not have the unified cleaning agent specifically for mahjong, and cleaning agent currently on the market is not suitable for mostly
The cleaning of mahjong, pollution is also bigger, not environmentally protective enough, also without antibacterial ability.
Hence it is highly desirable to by the improvement of formula, obtain without aviation kerosine can rapid cleaning mahjong without poison ring
Protect antibacterial cleaning agent.
The content of the invention
To solve the above-mentioned problems, one aspect of the present invention provide without aviation kerosine can rapid cleaning mahjong nothing
Malicious environment-friendly antibacterial cleaning agent, it is characterised in that in parts by weight, its preparing raw material includes following components：
100 parts of deionized water
1-10 parts of glycolic
10-20 parts of polymer modification hydroxyapatite
1-10 parts of acetic acid
1-5 parts of ethyl acetate
1-5 parts of potassium chloride
1-5 parts of ethylene glycol monostearate
1-5 parts of lauric acid amide of ethanol
1-5 parts of dipropylene glycol；
Preferably, its preparing raw material includes following components：
100 parts of deionized water
1-8 parts of glycolic
10-15 parts of polymer modification hydroxyapatite
2-8 parts of acetic acid
1-3 parts of ethyl acetate
1-2 parts of potassium chloride
1-4 parts of ethylene glycol monostearate
2-4 parts of lauric acid amide of ethanol
2-5 parts of dipropylene glycol.
It is highly preferred that its preparing raw material includes following components：
100 parts of deionized water
5 parts of glycolic
13 parts of polymer modification hydroxyapatite
5 parts of acetic acid
1.6 parts of ethyl acetate
1.3 parts of potassium chloride
2.7 parts of ethylene glycol monostearate
3 parts of lauric acid amide of ethanol
3 parts of dipropylene glycol.
In one embodiment, the preparation method of the polymer modification hydroxyapatite is：
（1）In the three-necked bottle of 1000 ml dryings, add to 1,12- dibromo-dodecanes, 0.1 mol, Isosorbide-5-Nitrae-lupetazin
0.02 mol, 0.072 mol of aminopromazine and dimethyl sulfoxide (DMSO) 50ml, after reacting 5h at 50 DEG C, vacuum distillation removes dimethyl
Sulfoxide, obtains polyquaternium；
（2）1000 milliliters it is dry be connected with the three-necked bottle of blender, water knockout drum and condenser pipe, sequentially add 0.02 mole
4'4- dimercaptos diphenyl sulfide, 0.018 mole of 4'4- dichloro diphenyl sulfone, 0.05 mole of Anhydrous potassium carbonate, 40 milliliters of dimethyl Asias
Sulfone and 18 milliliters of toluene, lead to nitrogen protection after twenty minutes, be heated to 150 DEG C reaction 4 it is small when, then reaction temperature is risen to
160 DEG C, constant temperature the reaction was continued 8 it is small when after, be down to room temperature, then ice bath three-necked bottle and logical nitrogen protection under, be slowly added dropwise dense
Hydrochloric acid, after system PH is less than 4, reaction solution is poured into acetone, resulting sediment uses deionized water and acetone respectively
After washing three times repeatedly, dry 24h at 50 DEG C, obtains poly thioether sulfone in vacuum drying oven；
（3）In 500 milliliters of round-bottomed flasks, 2 grams of hyaluronic acid, 5 grams of hydrogen peroxide, 20 grams of deionized water, hydroxide are sequentially added
1.3 grams of potassium, above-mentioned steps（1）5 grams of gained polyquaternium, above-mentioned steps（2）5 grams of gained poly thioether sulfone, 1 gram of KH-550, KH-
560 3 grams, 8 grams of hydroxyapatite, 150 grams of dimethyl sulfoxide (DMSO), after leading to nitrogen protection 1h, system temperature is risen to 110 DEG C, reaction
4 it is small when after, be down to room temperature, discharge in ethanol, obtain fluffy solid, the fluffy solid is washed respectively with deionized water and ethanol
3 times, when finally vacuum drying 24 is small at 50 DEG C, obtain polymer modification hydroxyapatite.
Preferably, it is described without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent, with weight
Part meter, its preparing raw material also include 1-5 parts of methyl-silicone oil.
It is highly preferred that it is described without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent, with weight
Part meter is measured, its preparing raw material also includes 3 parts of methyl-silicone oil.
Preferably, it is described without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent, with weight
Part meter, its preparing raw material is also comprising double 1-5 parts of (the methylol) -2- imidazolones of 4,5- dihydroxy -1,3-.
It is highly preferred that it is described without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent, with weight
Part meter is measured, its preparing raw material is also comprising double 2 parts of (the methylol) -2- imidazolones of 4,5- dihydroxy -1,3-.
The present invention also provides without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent preparation side
Method, including：Preparing raw material is added in mixer after being sufficiently mixed 30 minutes, discharging obtains, its stir speed (S.S.) is 100-1000
Rev/min.
Preferably, the stir speed (S.S.) is 600 revs/min.
Compared with prior art, beneficial effects of the present invention are：
1st, the anti-microbial property and cleaning ability of cleaning agent are improved by the addition of polymer modification hydroxyapatite.
2nd, can be further by adding double (the methylol) -2- imidazolones of 4,5- dihydroxy -1,3- and methyl-silicone oil
Improve cleaning speed and cleaning performance.
Embodiment
Raw material：
Hyaluronic acid model C Q-9004-61-9, it is biological purchased from the universe is held.Hydroxyapatite, 2 microns of average grain diameter, purchased from Xi'an four
Season.Other raw materials are purchased from Aladdin reagent.
Embodiment 1
Following preparing raw materials by weight are added in mixer after being sufficiently mixed 30 minutes, discharging obtains, stir speed (S.S.)
For 600 revs/min；
Preparing raw material：
100 parts of deionized water
1 part of glycolic
10 parts of polymer modification hydroxyapatite
1 part of acetic acid
1 part of ethyl acetate
1 part of potassium chloride
1 part of ethylene glycol monostearate
1 part of lauric acid amide of ethanol
1 part of dipropylene glycol；
The preparation method of the polymer modification hydroxyapatite is：
（1）In the three-necked bottle of 1000 ml dryings, add to 1,12- dibromo-dodecanes, 0.1 mol, Isosorbide-5-Nitrae-lupetazin
0.02 mol, 0.072 mol of aminopromazine and dimethyl sulfoxide (DMSO) 50ml, after reacting 5h at 50 DEG C, vacuum distillation removes dimethyl
Sulfoxide, obtains polyquaternium；
（2）1000 milliliters it is dry be connected with the three-necked bottle of blender, water knockout drum and condenser pipe, sequentially add 0.02 mole
4'4- dimercaptos diphenyl sulfide, 0.018 mole of 4'4- dichloro diphenyl sulfone, 0.05 mole of Anhydrous potassium carbonate, 40 milliliters of dimethyl Asias
Sulfone and 18 milliliters of toluene, lead to nitrogen protection after twenty minutes, be heated to 150 DEG C reaction 4 it is small when, then reaction temperature is risen to
160 DEG C, constant temperature the reaction was continued 8 it is small when after, be down to room temperature, then ice bath three-necked bottle and logical nitrogen protection under, be slowly added dropwise dense
Hydrochloric acid, after system PH is less than 4, reaction solution is poured into acetone, resulting sediment uses deionized water and acetone respectively
After washing three times repeatedly, dry 24h at 50 DEG C, obtains poly thioether sulfone in vacuum drying oven；
（3）In 500 milliliters of round-bottomed flasks, 2 grams of hyaluronic acid, 5 grams of hydrogen peroxide, 20 grams of deionized water, hydroxide are sequentially added
1.3 grams of potassium, above-mentioned steps（1）5 grams of gained polyquaternium, above-mentioned steps（2）5 grams of gained poly thioether sulfone, 1 gram of KH-550, KH-
560 3 grams, 8 grams of hydroxyapatite, 150 grams of dimethyl sulfoxide (DMSO), after leading to nitrogen protection 1h, system temperature is risen to 110 DEG C, reaction
4 it is small when after, be down to room temperature, discharge in ethanol, obtain fluffy solid, the fluffy solid is washed respectively with deionized water and ethanol
3 times, when finally vacuum drying 24 is small at 50 DEG C, obtain polymer modification hydroxyapatite.
Embodiment 2
Following preparing raw materials by weight are added in mixer after being sufficiently mixed 30 minutes, discharging obtains, stir speed (S.S.)
For 600 revs/min；
Preparing raw material：
100 parts of deionized water
1 part of glycolic
10 parts of polymer modification hydroxyapatite
2 parts of acetic acid
1 part of ethyl acetate
1 part of potassium chloride
1 part of ethylene glycol monostearate
2 parts of lauric acid amide of ethanol
2 parts of dipropylene glycol；
The preparation method of the polymer modification hydroxyapatite is：
（1）In the three-necked bottle of 1000 ml dryings, add to 1,12- dibromo-dodecanes, 0.1 mol, Isosorbide-5-Nitrae-lupetazin
0.02 mol, 0.072 mol of aminopromazine and dimethyl sulfoxide (DMSO) 50ml, after reacting 5h at 50 DEG C, vacuum distillation removes dimethyl
Sulfoxide, obtains polyquaternium；
（2）1000 milliliters it is dry be connected with the three-necked bottle of blender, water knockout drum and condenser pipe, sequentially add 0.02 mole
4'4- dimercaptos diphenyl sulfide, 0.018 mole of 4'4- dichloro diphenyl sulfone, 0.05 mole of Anhydrous potassium carbonate, 40 milliliters of dimethyl Asias
Sulfone and 18 milliliters of toluene, lead to nitrogen protection after twenty minutes, be heated to 150 DEG C reaction 4 it is small when, then reaction temperature is risen to
160 DEG C, constant temperature the reaction was continued 8 it is small when after, be down to room temperature, then ice bath three-necked bottle and logical nitrogen protection under, be slowly added dropwise dense
Hydrochloric acid, after system PH is less than 4, reaction solution is poured into acetone, resulting sediment uses deionized water and acetone respectively
After washing three times repeatedly, dry 24h at 50 DEG C, obtains poly thioether sulfone in vacuum drying oven；
（3）In 500 milliliters of round-bottomed flasks, 2 grams of hyaluronic acid, 5 grams of hydrogen peroxide, 20 grams of deionized water, hydroxide are sequentially added
1.3 grams of potassium, above-mentioned steps（1）5 grams of gained polyquaternium, above-mentioned steps（2）5 grams of gained poly thioether sulfone, 1 gram of KH-550, KH-
560 3 grams, 8 grams of hydroxyapatite, 150 grams of dimethyl sulfoxide (DMSO), after leading to nitrogen protection 1h, system temperature is risen to 110 DEG C, reaction
4 it is small when after, be down to room temperature, discharge in ethanol, obtain fluffy solid, the fluffy solid is washed respectively with deionized water and ethanol
3 times, when finally vacuum drying 24 is small at 50 DEG C, obtain polymer modification hydroxyapatite.
Embodiment 3
Following preparing raw materials by weight are added in mixer after being sufficiently mixed 30 minutes, discharging obtains, stir speed (S.S.)
For 600 revs/min；
Preparing raw material：
100 parts of deionized water
5 parts of glycolic
13 parts of polymer modification hydroxyapatite
5 parts of acetic acid
1.6 parts of ethyl acetate
1.3 parts of potassium chloride
2.7 parts of ethylene glycol monostearate
3 parts of lauric acid amide of ethanol
3 parts of dipropylene glycol；
The preparation method of the polymer modification hydroxyapatite is：
（1）In the three-necked bottle of 1000 ml dryings, add to 1,12- dibromo-dodecanes, 0.1 mol, Isosorbide-5-Nitrae-lupetazin
0.02 mol, 0.072 mol of aminopromazine and dimethyl sulfoxide (DMSO) 50ml, after reacting 5h at 50 DEG C, vacuum distillation removes dimethyl
Sulfoxide, obtains polyquaternium；
（2）1000 milliliters it is dry be connected with the three-necked bottle of blender, water knockout drum and condenser pipe, sequentially add 0.02 mole
4'4- dimercaptos diphenyl sulfide, 0.018 mole of 4'4- dichloro diphenyl sulfone, 0.05 mole of Anhydrous potassium carbonate, 40 milliliters of dimethyl Asias
Sulfone and 18 milliliters of toluene, lead to nitrogen protection after twenty minutes, be heated to 150 DEG C reaction 4 it is small when, then reaction temperature is risen to
160 DEG C, constant temperature the reaction was continued 8 it is small when after, be down to room temperature, then ice bath three-necked bottle and logical nitrogen protection under, be slowly added dropwise dense
Hydrochloric acid, after system PH is less than 4, reaction solution is poured into acetone, resulting sediment uses deionized water and acetone respectively
After washing three times repeatedly, dry 24h at 50 DEG C, obtains poly thioether sulfone in vacuum drying oven；
（3）In 500 milliliters of round-bottomed flasks, 2 grams of hyaluronic acid, 5 grams of hydrogen peroxide, 20 grams of deionized water, hydroxide are sequentially added
1.3 grams of potassium, above-mentioned steps（1）5 grams of gained polyquaternium, above-mentioned steps（2）5 grams of gained poly thioether sulfone, 1 gram of KH-550, KH-
560 3 grams, 8 grams of hydroxyapatite, 150 grams of dimethyl sulfoxide (DMSO), after leading to nitrogen protection 1h, system temperature is risen to 110 DEG C, reaction
4 it is small when after, be down to room temperature, discharge in ethanol, obtain fluffy solid, the fluffy solid is washed respectively with deionized water and ethanol
3 times, when finally vacuum drying 24 is small at 50 DEG C, obtain polymer modification hydroxyapatite.
Embodiment 4
Following preparing raw materials by weight are added in mixer after being sufficiently mixed 30 minutes, discharging obtains, stir speed (S.S.)
For 600 revs/min；
Preparing raw material：
100 parts of deionized water
5 parts of glycolic
13 parts of polymer modification hydroxyapatite
5 parts of acetic acid
1.6 parts of ethyl acetate
1.3 parts of potassium chloride
2.7 parts of ethylene glycol monostearate
3 parts of lauric acid amide of ethanol
3 parts of dipropylene glycol
3 parts of methyl-silicone oil
Double 2 parts of (the methylol) -2- imidazolones of 4,5- dihydroxy -1,3-；
The preparation method of the polymer modification hydroxyapatite is：
（1）In the three-necked bottle of 1000 ml dryings, add to 1,12- dibromo-dodecanes, 0.1 mol, Isosorbide-5-Nitrae-lupetazin
0.02 mol, 0.072 mol of aminopromazine and dimethyl sulfoxide (DMSO) 50ml, after reacting 5h at 50 DEG C, vacuum distillation removes dimethyl
Sulfoxide, obtains polyquaternium；
（2）1000 milliliters it is dry be connected with the three-necked bottle of blender, water knockout drum and condenser pipe, sequentially add 0.02 mole
4'4- dimercaptos diphenyl sulfide, 0.018 mole of 4'4- dichloro diphenyl sulfone, 0.05 mole of Anhydrous potassium carbonate, 40 milliliters of dimethyl Asias
Sulfone and 18 milliliters of toluene, lead to nitrogen protection after twenty minutes, be heated to 150 DEG C reaction 4 it is small when, then reaction temperature is risen to
160 DEG C, constant temperature the reaction was continued 8 it is small when after, be down to room temperature, then ice bath three-necked bottle and logical nitrogen protection under, be slowly added dropwise dense
Hydrochloric acid, after system PH is less than 4, reaction solution is poured into acetone, resulting sediment uses deionized water and acetone respectively
After washing three times repeatedly, dry 24h at 50 DEG C, obtains poly thioether sulfone in vacuum drying oven；
（3）In 500 milliliters of round-bottomed flasks, 2 grams of hyaluronic acid, 5 grams of hydrogen peroxide, 20 grams of deionized water, hydroxide are sequentially added
1.3 grams of potassium, above-mentioned steps（1）5 grams of gained polyquaternium, above-mentioned steps（2）5 grams of gained poly thioether sulfone, 1 gram of KH-550, KH-
560 3 grams, 8 grams of hydroxyapatite, 150 grams of dimethyl sulfoxide (DMSO), after leading to nitrogen protection 1h, system temperature is risen to 110 DEG C, reaction
4 it is small when after, be down to room temperature, discharge in ethanol, obtain fluffy solid, the fluffy solid is washed respectively with deionized water and ethanol
3 times, when finally vacuum drying 24 is small at 50 DEG C, obtain polymer modification hydroxyapatite.
Comparative example 1
Following preparing raw materials by weight are added in mixer after being sufficiently mixed 30 minutes, discharging obtains, stir speed (S.S.)
For 600 revs/min；
Preparing raw material：
100 parts of deionized water
5 parts of glycolic
13 parts of hydroxyapatite
5 parts of acetic acid
1.6 parts of ethyl acetate
1.3 parts of potassium chloride
2.7 parts of ethylene glycol monostearate
3 parts of lauric acid amide of ethanol
3 parts of dipropylene glycol
3 parts of methyl-silicone oil
Double 2 parts of (the methylol) -2- imidazolones of 4,5- dihydroxy -1,3-.
Comparative example 2
Following preparing raw materials by weight are added in mixer after being sufficiently mixed 30 minutes, discharging obtains, stir speed (S.S.)
For 600 revs/min；
Preparing raw material：
100 parts of deionized water
5 parts of glycolic
13 parts of polymer modification hydroxyapatite
5 parts of acetic acid
1.6 parts of ethyl acetate
1.3 parts of potassium chloride
2.7 parts of ethylene glycol monostearate
3 parts of lauric acid amide of ethanol
3 parts of dipropylene glycol
3 parts of methyl-silicone oil
Double 2 parts of (the methylol) -2- imidazolones of 4,5- dihydroxy -1,3-；
The preparation method of the polymer modification hydroxyapatite is：
（1）1000 milliliters it is dry be connected with the three-necked bottle of blender, water knockout drum and condenser pipe, sequentially add 0.02 mole
4'4- dimercaptos diphenyl sulfide, 0.018 mole of 4'4- dichloro diphenyl sulfone, 0.05 mole of Anhydrous potassium carbonate, 40 milliliters of dimethyl Asias
Sulfone and 18 milliliters of toluene, lead to nitrogen protection after twenty minutes, be heated to 150 DEG C reaction 4 it is small when, then reaction temperature is risen to
160 DEG C, constant temperature the reaction was continued 8 it is small when after, be down to room temperature, then ice bath three-necked bottle and logical nitrogen protection under, be slowly added dropwise dense
Hydrochloric acid, after system PH is less than 4, reaction solution is poured into acetone, resulting sediment uses deionized water and acetone respectively
After washing three times repeatedly, dry 24h at 50 DEG C, obtains poly thioether sulfone in vacuum drying oven；
（2）In 500 milliliters of round-bottomed flasks, 2 grams of hyaluronic acid, 5 grams of hydrogen peroxide, 20 grams of deionized water, hydroxide are sequentially added
1.3 grams of potassium, above-mentioned steps（1）5 grams of gained poly thioether sulfone, 1 gram of KH-550,3 grams of KH-560,8 grams of hydroxyapatite, dimethyl
150 grams of sulfoxide, after leading to nitrogen protection 1h, 110 DEG C are risen to by system temperature, when reaction 4 is small after, be down to room temperature, discharge in ethanol
In, fluffy solid is obtained, the fluffy solid is washed respectively 3 times with deionized water and ethanol, is finally dried in vacuo 24 at 50 DEG C
Hour, obtain polymer modification hydroxyapatite.
Comparative example 3
Following preparing raw materials by weight are added in mixer after being sufficiently mixed 30 minutes, discharging obtains, stir speed (S.S.)
For 600 revs/min；
Preparing raw material：
100 parts of deionized water
5 parts of glycolic
13 parts of polymer modification hydroxyapatite
5 parts of acetic acid
1.6 parts of ethyl acetate
1.3 parts of potassium chloride
2.7 parts of ethylene glycol monostearate
3 parts of lauric acid amide of ethanol
3 parts of dipropylene glycol
3 parts of methyl-silicone oil
Double 2 parts of (the methylol) -2- imidazolones of 4,5- dihydroxy -1,3-；
The preparation method of the polymer modification hydroxyapatite is：
（1）In the three-necked bottle of 1000 ml dryings, add to 1,12- dibromo-dodecanes, 0.1 mol, Isosorbide-5-Nitrae-lupetazin
0.02 mol, 0.072 mol of aminopromazine and dimethyl sulfoxide (DMSO) 50ml, after reacting 5h at 50 DEG C, vacuum distillation removes dimethyl
Sulfoxide, obtains polyquaternium；
（2）1000 milliliters it is dry be connected with the three-necked bottle of blender, water knockout drum and condenser pipe, sequentially add 0.02 mole
4'4- dimercaptos diphenyl sulfide, 0.018 mole of 4'4- dichloro diphenyl sulfone, 0.05 mole of Anhydrous potassium carbonate, 40 milliliters of dimethyl Asias
Sulfone and 18 milliliters of toluene, lead to nitrogen protection after twenty minutes, be heated to 150 DEG C reaction 4 it is small when, then reaction temperature is risen to
160 DEG C, constant temperature the reaction was continued 8 it is small when after, be down to room temperature, then ice bath three-necked bottle and logical nitrogen protection under, be slowly added dropwise dense
Hydrochloric acid, after system PH is less than 4, reaction solution is poured into acetone, resulting sediment uses deionized water and acetone respectively
After washing three times repeatedly, dry 24h at 50 DEG C, obtains poly thioether sulfone in vacuum drying oven；
（3）In 500 milliliters of round-bottomed flasks, 5 grams of hydrogen peroxide, 20 grams of deionized water, 1.3 grams of potassium hydroxide, above-mentioned is sequentially added
Step（1）5 grams of gained polyquaternium, above-mentioned steps（2）5 grams of gained poly thioether sulfone, 1 gram of KH-550,3 grams of KH-560, hydroxyl
8 grams of apatite, 150 grams of dimethyl sulfoxide (DMSO), after leading to nitrogen protection 1h, 110 DEG C are risen to by system temperature, when reaction 4 is small after, be down to
Room temperature, discharges in ethanol, obtains fluffy solid, washs the fluffy solid respectively 3 times with deionized water and ethanol, finally exists
When vacuum drying 24 is small at 50 DEG C, polymer modification hydroxyapatite is obtained.
Test method
Used mahjong is rinsed in the cleaning agent of embodiment 1-4 and comparative example 1-3, test clean rinsing time and
Removal of bacteria rate.
Table 1
| Test event | Clean rinsing time | The degerming rate of gold-coloured staphylococci | The degerming rate of Escherichia coli |
| Embodiment 1 | 10 minutes | 93.5% | 96.6% |
| Embodiment 2 | 8 minutes | 97.1% | 97.8% |
| Embodiment 3 | 5 minutes | 95.5% | 92.8% |
| Embodiment 4 | 2 minutes | 97.5% | 98.1% |
| Comparative example 1 | It can not clean | - | - |
| Comparative example 2 | It can not clean（It is insoluble） | - | - |
| Comparative example 3 | 15 minutes | 90% | 87% |
Claims (10)
1. without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent, it is characterised in that in parts by weight,
Its preparing raw material includes following components：
100 parts of deionized water
1-10 parts of glycolic
10-20 parts of polymer modification hydroxyapatite
1-10 parts of acetic acid
1-5 parts of ethyl acetate
1-5 parts of potassium chloride
1-5 parts of ethylene glycol monostearate
1-5 parts of lauric acid amide of ethanol
1-5 parts of dipropylene glycol.
2. it is according to claim 1 without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent, its
It is characterized in that, in parts by weight, its preparing raw material includes following components：
100 parts of deionized water
1-8 parts of glycolic
10-15 parts of polymer modification hydroxyapatite
2-8 parts of acetic acid
1-3 parts of ethyl acetate
1-2 parts of potassium chloride
1-4 parts of ethylene glycol monostearate
2-4 parts of lauric acid amide of ethanol
2-5 parts of dipropylene glycol.
3. it is according to claim 2 without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent, its
It is characterized in that, in parts by weight, its preparing raw material includes following components：
100 parts of deionized water
5 parts of glycolic
13 parts of polymer modification hydroxyapatite
5 parts of acetic acid
1.6 parts of ethyl acetate
1.3 parts of potassium chloride
2.7 parts of ethylene glycol monostearate
3 parts of lauric acid amide of ethanol
3 parts of dipropylene glycol.
4. according to claim 1-3 any one of them without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial it is clear
Lotion, it is characterised in that the preparation method of the polymer modification hydroxyapatite is：
（1）In the three-necked bottle of 1000 ml dryings, add to 1,12- dibromo-dodecanes, 0.1 mol, Isosorbide-5-Nitrae-lupetazin
0.02 mol, 0.072 mol of aminopromazine and dimethyl sulfoxide (DMSO) 50ml, after reacting 5h at 50 DEG C, vacuum distillation removes dimethyl
Sulfoxide, obtains polyquaternium；
（2）1000 milliliters it is dry be connected with the three-necked bottle of blender, water knockout drum and condenser pipe, sequentially add 0.02 mole
4'4- dimercaptos diphenyl sulfide, 0.018 mole of 4'4- dichloro diphenyl sulfone, 0.05 mole of Anhydrous potassium carbonate, 40 milliliters of dimethyl Asias
Sulfone and 18 milliliters of toluene, lead to nitrogen protection after twenty minutes, be heated to 150 DEG C reaction 4 it is small when, then reaction temperature is risen to
160 DEG C, constant temperature the reaction was continued 8 it is small when after, be down to room temperature, then ice bath three-necked bottle and logical nitrogen protection under, be slowly added dropwise dense
Hydrochloric acid, after system PH is less than 4, reaction solution is poured into acetone, resulting sediment uses deionized water and acetone respectively
After washing three times repeatedly, dry 24h at 50 DEG C, obtains poly thioether sulfone in vacuum drying oven；
（3）In 500 milliliters of round-bottomed flasks, 2 grams of hyaluronic acid, 5 grams of hydrogen peroxide, 20 grams of deionized water, hydroxide are sequentially added
1.3 grams of potassium, above-mentioned steps（1）5 grams of gained polyquaternium, above-mentioned steps（2）5 grams of gained poly thioether sulfone, 1 gram of KH-550, KH-
560 3 grams, 8 grams of hydroxyapatite, 150 grams of dimethyl sulfoxide (DMSO), after leading to nitrogen protection 1h, system temperature is risen to 110 DEG C, reaction
4 it is small when after, be down to room temperature, discharge in ethanol, obtain fluffy solid, the fluffy solid is washed respectively with deionized water and ethanol
3 times, when finally vacuum drying 24 is small at 50 DEG C, obtain polymer modification hydroxyapatite.
5. it is according to claim 1 without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent, its
It is characterized in that, in parts by weight, its preparing raw material also includes 1-5 parts of methyl-silicone oil.
6. it is according to claim 5 without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent, its
It is characterized in that, in parts by weight, its preparing raw material also includes 3 parts of methyl-silicone oil.
7. it is according to claim 6 without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent, its
It is characterized in that, in parts by weight, its preparing raw material is also comprising double (the methylol) -2- imidazolones 1-5 of 4,5- dihydroxy -1,3-
Part.
8. it is according to claim 7 without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent, its
It is characterized in that, in parts by weight, its preparing raw material is also comprising double 2 parts of (the methylol) -2- imidazolones of 4,5- dihydroxy -1,3-.
9. without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent preparation method, it is characterised in that
Including：The preparing raw material of any one of claim 1-8 is added in mixer after being sufficiently mixed 30 minutes, discharging obtains, it is stirred
Speed is mixed as 100-1000 revs/min.
10. it is according to claim 7 without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent
Preparation method, it is characterised in that the stir speed (S.S.) is 600 revs/min.
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| CN201711381543.2A CN108018133A (en) | 2017-12-20 | 2017-12-20 | Without aviation kerosine can rapid cleaning mahjong asepsis environment-protecting antibacterial cleaning agent |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111892994A (en) * | 2020-08-19 | 2020-11-06 | 枣阳市高科化工有限公司 | Environment-friendly metal surface oil stain cleaning agent and preparation method thereof |
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| CN104130884A (en) * | 2014-07-04 | 2014-11-05 | 谢伟杰 | Tile cleaning agent |
| CN106085627A (en) * | 2016-06-21 | 2016-11-09 | 平潭迈康生物科技有限公司 | A kind of natural environmental-protective cleaning agent |
| CN107057569A (en) * | 2017-01-16 | 2017-08-18 | 惠州市博罗至诚化工有限公司 | A kind of nano inorganic silicate zinc-rich composite anticorrosion coating and preparation method thereof |
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| CN1202925A (en) * | 1995-10-25 | 1998-12-23 | 雷克特和科尔曼公司 | Germicidal acidic hard surface cleaning compositions |
| CN1360625A (en) * | 1999-07-09 | 2002-07-24 | 肖特玻璃制造厂 | Non-toxic, microbicidal detergent |
| CN104130884A (en) * | 2014-07-04 | 2014-11-05 | 谢伟杰 | Tile cleaning agent |
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| CN111892994A (en) * | 2020-08-19 | 2020-11-06 | 枣阳市高科化工有限公司 | Environment-friendly metal surface oil stain cleaning agent and preparation method thereof |
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