CN108018099A - A kind of fuel economizing emission reduction environmental-protection additive and preparation method thereof - Google Patents

A kind of fuel economizing emission reduction environmental-protection additive and preparation method thereof Download PDF

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CN108018099A
CN108018099A CN201711250605.6A CN201711250605A CN108018099A CN 108018099 A CN108018099 A CN 108018099A CN 201711250605 A CN201711250605 A CN 201711250605A CN 108018099 A CN108018099 A CN 108018099A
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parts
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emission reduction
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CN108018099B (en
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秦召贵
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Yanzhou Jining Dongfang Chemical Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/04Use of additives to fuels or fires for particular purposes for minimising corrosion or incrustation
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/16Hydrocarbons
    • C10L1/1608Well defined compounds, e.g. hexane, benzene
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    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1824Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1852Ethers; Acetals; Ketals; Orthoesters
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/185Ethers; Acetals; Ketals; Aldehydes; Ketones
    • C10L1/1857Aldehydes; Ketones
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/2222(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/222Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
    • C10L1/224Amides; Imides carboxylic acid amides, imides
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/22Organic compounds containing nitrogen
    • C10L1/23Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites
    • C10L1/231Organic compounds containing nitrogen containing at least one nitrogen-to-oxygen bond, e.g. nitro-compounds, nitrates, nitrites nitro compounds; nitrates; nitrites
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2230/00Function and purpose of a components of a fuel or the composition as a whole
    • C10L2230/22Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00Specifically adapted fuels
    • C10L2270/02Specifically adapted fuels for internal combustion engines

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention discloses a kind of fuel economizing emission reduction environmental-protection additive and preparation method thereof, belongs to technical field of petrochemical industry, a kind of fuel economizing emission reduction environmental-protection additive, it is characterised in that including following components:Alcohols, ketone, esters, ethers, amine, benzene class;Wherein, alcohols is 10 15 parts of 20 30 parts of ethanol, 8 10 parts of polyether alcohol and n-octyl alcohol;Ketone is 10 20 parts of acetone;Esters are 5 10 parts of 36 parts of isopropyl nitrate and amyl nitrate;Ethers is 13 parts of 10 20 parts of methyl tertiary butyl ether(MTBE) and propylene glycol t-butyl ether;Amine is 25 parts of 38 parts of hexamethylenetetramine and phthalic amide;Benzene class is 13 parts of ortho-xylene.The present invention is prepared into the fuel oil additive as liquid at a temperature of being 25 ± 5 DEG C in environment.Beneficial effects of the present invention are:It is reasonable with formula design, the fuel value of high fuel oil can be done, reduces boiling range temperature, increases power, reduces carbon deposit coking, tail gas pollution discharge is reduced, lifts power, oil-saving effect is obvious, the advantages that extending service life of a machine, reduce operating cost.

Description

A kind of fuel economizing emission reduction environmental-protection additive and preparation method thereof
Technical field
The invention discloses a kind of fuel economizing emission reduction environmental-protection additive and preparation method thereof, belongs to petrochemical technology neck Domain.
Background technology
With the continuous enhancing of people's environmental consciousness, and increasingly stringent environmental requirement, fuel oil is all being paid attention in countries in the world The raising of quality, oil-saving discharging-reducing technical products are most important, and with being continuously increased for automobile quantity, also day is increasingly for the pollution of air Weight, according to energy-saving and emission-reduction, there is an urgent need to improving fuel qualities, develop the requirement that new fuel source proposes higher, such as What improves the efficiency of combustion of fuel oil, reduces the discharge of pernicious gas, it has also become the important topic of countries in the world developmental research, for solution Certainly pollution of the fuel oil burning to environment, it is desirable to add additive in fuel oil to improve the efficiency of combustion of fuel oil, is reduced useless The discharge of gas, in addition to improving fuel oil combustion apparatus or engine in itself, it is also conscientiously may be used to improve fuel oil oil product using additive Capable measure, it need not transform fuel oil equipment, have the advantages that flexible, easy and cost is low etc., result of the test shows that fuel oil adds Add agent, moreover it is possible to effectively improve fuel performance, oil-saving discharging-reducing.
The content of the invention
For the problems of the prior art, shortcoming according to prior art of the invention, there is provided a kind of oil-saving discharging-reducing, is reduced The discharge of pollutant, extends fuel economizing emission reduction environmental-protection additive of equipment, the service life of engine and preparation method thereof, this The technical solution of invention is as follows:
A kind of fuel economizing emission reduction environmental-protection additive, including following components:Alcohols, ketone, esters, ethers, amine, benzene class;Its In, alcohols is 10-15 parts of 20-35 parts of ethanol, 2-10 parts of polyether alcohol and n-octyl alcohol;Ketone is 10-20 parts of acetone;Esters are nitre 5-10 parts of 3-6 parts of isopropyl propionate and amyl nitrate;Ethers is 1-3 parts of 10-20 parts of methyl tertiary butyl ether(MTBE) and propylene glycol t-butyl ether; Amine is 2-5 parts of 3-8 parts of hexamethylenetetramine and phthalic amide;Benzene class is 1-3 parts of ortho-xylene.
Preferably, the present invention includes following components:Alcohols is 25-30 parts of ethanol, 8-10 parts of polyether alcohol and n-octyl alcohol 13-15 Part;Ketone is 10-20 parts of acetone;Esters are 7-10 parts of 3-6 parts of isopropyl nitrate and amyl nitrate;Ethers is methyl tertiary butyl ether(MTBE) 15-20 parts and 1-3 parts of propylene glycol t-butyl ether;Amine is 2-5 parts of 3-5 parts of hexamethylenetetramine and phthalic amide;Benzene class For 1-3 parts of ortho-xylene.
Preferably, the present invention includes following components:28 parts of ethanol, 9 parts of polyether alcohol, 13 parts of n-octyl alcohol;10 parts of acetone;Nitric acid 5 parts of isopropyl ester, 8 parts of amyl nitrate;15 parts of methyl tertiary butyl ether(MTBE), 2 parts of propylene glycol t-butyl ether;3 parts of hexa, adjacent benzene 5 parts of diformamide;Amine:2 parts of ortho-xylene.
Preferably, the preparation method of the above-mentioned a kind of fuel economizing emission reduction environmental-protection additive of the present invention, specific preparation method It is as follows:
(1)2-10 parts of polyether alcohols, 10-15 parts of n-octyl alcohols are sequentially added to the reaction kettle of 20-35 parts of ethanol solutions of storage in proportion In, stirring 5min obtains solution A;
(2)10-20 parts of acetone are obtained into solution B in proportion, then add B solution in solution A;
(3)By 3-6 portions of isopropyl nitrates, 5-10 parts of amyl nitrates mix in proportion solution C then by C solution add AB mix In solution;
(4)10-20 parts of methyl tertiary butyl ether(MTBE)s, 1-3 parts of propylene glycol t-butyl ethers are mixed into obtain solution D and then by solution D in proportion Add in A, B, C mixed solution;
(5)By 3-8 parts of hexas, 2-5 parts of phthalic amides mix to obtain solution E, then add E solution in proportion A, in B, C, D mixed solution;
(6)1-3 parts of ortho-xylenes are proportionally added into A, B, C, D, E mixed solution, and stirs 20min and then obtains finished fluid Body, it is filtered to obtain fuel economizing emission reduction environmental-protection additive.
Preferably, the specific preparation method of the present invention is as follows:
(1)8-10 parts of polyether alcohols, 13-15 parts of n-octyl alcohols are sequentially added to the reaction kettle of 25-30 parts of ethanol solutions of storage in proportion In, stirring 5min obtains solution A;
(2)10-20 parts of acetone are obtained into solution B in proportion, then add B solution in solution A;
(3)By 3-6 portions of isopropyl nitrates, 7-10 parts of amyl nitrates mix in proportion solution C then by C solution add AB mix In solution;
(4)15-20 parts of methyl tertiary butyl ether(MTBE)s, 1-3 parts of propylene glycol t-butyl ethers are mixed into obtain solution D and then by solution D in proportion Add in A, B, C mixed solution;
(5)By 3-5 parts of hexas, 3-5 parts of phthalic amides mix to obtain solution E, then add E solution in proportion A, in B, C, D mixed solution;
(6)1-3 parts of ortho-xylenes are proportionally added into A, B, C, D, E mixed solution, and stirs 20min and then obtains finished fluid Body, it is filtered to obtain fuel economizing emission reduction environmental-protection additive.
Preferably, the specific preparation method of the present invention is as follows:
(1)In the reaction kettle that 9 parts of polyether alcohols, 13 parts of n-octyl alcohols are sequentially added to 28 parts of ethanol solutions of storage in proportion, stirring 5min obtains solution A;
(2)10 parts of acetone are obtained into solution B in proportion, B solution is then added into step(1)In the solution A of gained;
(3)By 5 portions of isopropyl nitrates, 8 parts of amyl nitrates mix in proportion solution C then by C solution add AB mixed solutions In;
(4)By 15 parts of methyl tertiary butyl ether(MTBE)s, 2 parts of propylene glycol t-butyl ethers mix in proportion solution D then by solution D add A, B, in C mixed solutions;
(5)By 3 parts of hexas, 5 parts of phthalic amides mix to obtain solution E in proportion, then by E solution add A, B, C, in D mixed solutions;
(6)2 parts of ortho-xylenes are proportionally added into A, B, C, D, E mixed solution, and stirs 20min and then obtains production liquid, It is filtered to obtain fuel economizing emission reduction environmental-protection additive.
Preferably, above-mentioned preparation method carries out in the environment of being 20 ± 5 DEG C in temperature.
Preferably, above-mentioned additive application is in gasoline and/or diesel oil.
The present invention application method be:By measure 1 in gasoline, diesel oil:1000 ratio directly adds use.
Beneficial effect compared with prior art of the invention:The additive can improve the fuel value of fuel oil, increase power, subtract Few carbon deposit coking, reduces tail gas pollution discharge, lifts power, and oil-saving effect is obvious, reduces the discharge of pollutant, extend equipment, The service life of engine, energy-saving and emission-reduction.
Embodiment
The invention will now be further described with reference to specific embodiments, the advantages and features of the present invention will be with description and It is apparent.But embodiment is only exemplary, does not form any restrictions to the scope of the present invention;Those skilled in the art should It should be appreciated that the details and form of technical solution of the present invention can be repaiied without departing from the spirit and scope of the invention Change or replace, but these modifications and replacement are each fallen within protection scope of the present invention.
Embodiment 1
Every part of component of the present embodiment is 50ml.
A kind of fuel economizing emission reduction environmental-protection additive, including following component:Ethanol 28, polyether alcohol 9, n-octyl alcohol 13, acetone 10th, isopropyl nitrate 5, amyl nitrate 8, methyl tertiary butyl ether(MTBE) 15, propylene glycol t-butyl ether 2, hexa 3, adjacent benzene two Formamide 5, ortho-xylene 2
The specific preparation method of the present embodiment is as follows:
(1)In the reaction kettle that 9 parts of polyether alcohols, 13 parts of n-octyl alcohols are sequentially added to 28 parts of ethanol solutions of storage in proportion, stirring 5min obtains solution A;
(2)10 parts of acetone are obtained into solution B in proportion, B solution is then added into step(1)In the solution A of gained;
(3)By 5 portions of isopropyl nitrates, 8 parts of amyl nitrates mix in proportion solution C then by C solution add AB mixed solutions In;
(4)By 15 parts of methyl tertiary butyl ether(MTBE)s, 2 parts of propylene glycol t-butyl ethers mix in proportion solution D then by solution D add A, B, in C mixed solutions;
(5)By 3 parts of hexas, 5 parts of phthalic amides mix to obtain solution E in proportion, then by E solution add A, B, C, in D mixed solutions;
(6)2 parts of ortho-xylenes are proportionally added into A, B, C, D, E mixed solution, and stirs 20min and then obtains production liquid, It is filtered to obtain fuel economizing emission reduction environmental-protection additive.
The preparation method of the present embodiment carries out in the environment of being 20 DEG C in temperature.
The additive application that the present embodiment obtains is in gasoline and diesel oil.
Embodiment 2
Every part of component of the present embodiment is 200ml.
A kind of fuel economizing emission reduction environmental-protection additive, including following component:Ethanol 32, polyether alcohol 2, n-octyl alcohol 10, third Ketone 18, isopropyl nitrate 3, amyl nitrate 6, methyl tertiary butyl ether(MTBE) 18, propylene glycol t-butyl ether 3, hexa 4, adjacent benzene Diformamide 2, ortho-xylene 2
The specific preparation method of the present embodiment is as follows:
(1)In the reaction kettle that 9 parts of polyether alcohols, 13 parts of n-octyl alcohols are sequentially added to 28 parts of ethanol solutions of storage in proportion, stirring 5min obtains solution A;
(2)10 parts of acetone are obtained into solution B in proportion, B solution is then added into step(1)In the solution A of gained;
(3)By 5 portions of isopropyl nitrates, 8 parts of amyl nitrates mix in proportion solution C then by C solution add AB mixed solutions In;
(4)By 15 parts of methyl tertiary butyl ether(MTBE)s, 2 parts of propylene glycol t-butyl ethers mix in proportion solution D then by solution D add A, B, in C mixed solutions;
(5)By 3 parts of hexas, 5 parts of phthalic amides mix to obtain solution E in proportion, then by E solution add A, B, C, in D mixed solutions;
(6)2 parts of ortho-xylenes are proportionally added into A, B, C, D, E mixed solution, and stirs 20min and then obtains production liquid, It is filtered to obtain fuel economizing emission reduction environmental-protection additive.
The preparation method of the present embodiment carries out in the environment of being 25 DEG C in temperature.
The additive application that the present embodiment obtains is in gasoline and diesel oil.
Embodiment 3
Every part of component of the present embodiment is 1000ml.
A kind of fuel economizing emission reduction environmental-protection additive, including following component:Ethanol 30, polyether alcohol 5, n-octyl alcohol 12, acetone 11st, isopropyl nitrate 4, amyl nitrate 6, methyl tertiary butyl ether(MTBE) 20, propylene glycol t-butyl ether 3, hexa 2, adjacent benzene two Formamide 4, ortho-xylene 3
The specific preparation method of the present embodiment is as follows:
(1)In the reaction kettle that 9 parts of polyether alcohols, 13 parts of n-octyl alcohols are sequentially added to 28 parts of ethanol solutions of storage in proportion, stirring 5min obtains solution A;
(2)10 parts of acetone are obtained into solution B in proportion, B solution is then added into step(1)In the solution A of gained;
(3)By 5 portions of isopropyl nitrates, 8 parts of amyl nitrates mix in proportion solution C then by C solution add AB mixed solutions In;
(4)By 15 parts of methyl tertiary butyl ether(MTBE)s, 2 parts of propylene glycol t-butyl ethers mix in proportion solution D then by solution D add A, B, in C mixed solutions;
(5)By 3 parts of hexas, 5 parts of phthalic amides mix to obtain solution E in proportion, then by E solution add A, B, C, in D mixed solutions;
(6)2 parts of ortho-xylenes are proportionally added into A, B, C, D, E mixed solution, and stirs 20min and then obtains production liquid, It is filtered to obtain fuel economizing emission reduction environmental-protection additive.
The preparation method of the present embodiment carries out in the environment of being 23 DEG C in temperature.
The additive application that the present embodiment obtains is in gasoline and diesel oil.
Experimental stage:The additive obtained to embodiment 1,2,3 three kind of different formulations and preparation method is not with adding this hair The regular gasoline of the product of bright preparation or the performance of diesel oil are detected, and application method is the volume of additive and bavin Water Oil Or Gas Match as 1:1000, vehicle type selection and vehicle condition contrast:
1st, Audi 2.0T in 2010 has travelled 95000 kilometers, and vehicle condition is good, uses gasoline 97#;
2nd, Toyota of Guangzhou Automobile Workshop has travelled 32000 kilometers in 2014 2.0, and vehicle condition is good, uses gasoline 97#;
3rd, the triumphant horse in Feitian has travelled 46000 kilometers in 2012, and vehicle condition is good, uses diesel oil 0#;
Route selects 327 Jining of national highway-Yanzhou section, with 100 kilometers of oil consumption meters, gasoline 97#, the equal road conditions of diesel oil 0#, equal speed per hour, Equal wind speed, carry on an equal basis it is severe under measure, obtained result such as following table(1):
By upper table(1)Understand, fuel-economizing result:The rate of economizing gasoline of 3 kinds of vehicles, three formulas corresponds to respectively:
Audi:19%、22%、16%;
Toyota of Guangzhou Automobile Workshop:20%、21%、11%;
Triumphant horse:20%、24%、18%;
Average rate of economizing gasoline 17.8%;
Wherein rate of economizing gasoline=(Non- doping vehicle fuel consumption-addition additive fuel consumption)/ non-doping vehicle fuel consumption.
The exhaust emissions of result of the test, tail gas main component are CO and CH compounds, and result is as follows after tested for same vehicle Table(2):
The discharge capacity decreasing value of tie substance=(Non- doping discharge capacity-addition additive discharge capacity)/ non-doping discharge Amount.
In summary experimental result is using the additive of the present invention, and basic fuel-economizing 17% or so, emission reduction 15% or so, has bright Aobvious effect.

Claims (8)

1. a kind of fuel economizing emission reduction environmental-protection additive, it is characterised in that including following components:Alcohols, ketone, esters, ethers, Amine, benzene class;Wherein, alcohols is 10-15 parts of 20-35 parts of ethanol, 2-10 parts of polyether alcohol and n-octyl alcohol;Ketone is acetone 10-20 Part;Esters are 5-10 parts of 3-6 parts of isopropyl nitrate and amyl nitrate;Ethers is 10-20 parts of methyl tertiary butyl ether(MTBE) and glycol tertiary 1-3 parts of butyl ether;Amine is 2-5 parts of 3-8 parts of hexamethylenetetramine and phthalic amide;Benzene class is 1-3 parts of ortho-xylene.
2. a kind of fuel economizing emission reduction environmental-protection additive according to claim 1, it is characterised in that including following components: Alcohols is 13-15 parts of 25-30 parts of ethanol, 8-10 parts of polyether alcohol and n-octyl alcohol;Ketone is 10-20 parts of acetone;Esters are different for nitric acid 7-10 parts of 3-6 parts of propyl ester and amyl nitrate;Ethers is 1-3 parts of 15-20 parts of methyl tertiary butyl ether(MTBE) and propylene glycol t-butyl ether;Amine For 2-5 parts of 3-5 parts of hexamethylenetetramine and phthalic amide;Benzene class is 1-3 parts of ortho-xylene.
3. a kind of fuel economizing emission reduction environmental-protection additive according to claim 1, it is characterised in that including following components: 28 parts of ethanol, 9 parts of polyether alcohol, 13 parts of n-octyl alcohol;10 parts of acetone;5 parts of isopropyl nitrate, 8 parts of amyl nitrate;Methyl tertiary butyl ether(MTBE) 15 parts, 2 parts of propylene glycol t-butyl ether;3 parts of hexa, 5 parts of phthalic amide;Amine:2 parts of ortho-xylene.
4. the preparation method of a kind of fuel economizing emission reduction environmental-protection additive according to claim 1, it is characterised in that specific Preparation method is as follows:
(1)2-10 parts of polyether alcohols, 10-15 parts of n-octyl alcohols are sequentially added to the reaction kettle of 20-35 parts of ethanol solutions of storage in proportion In, stirring 5min obtains solution A;
(2)10-20 parts of acetone are obtained into solution B in proportion, then add B solution in solution A;
(3)By 3-6 portions of isopropyl nitrates, 5-10 parts of amyl nitrates mix in proportion solution C then by C solution add AB mix In solution;
(4)10-20 parts of methyl tertiary butyl ether(MTBE)s, 1-3 parts of propylene glycol t-butyl ethers are mixed into obtain solution D and then by solution D in proportion Add in A, B, C mixed solution;
(5)By 3-8 parts of hexas, 2-5 parts of phthalic amides mix to obtain solution E, then add E solution in proportion A, in B, C, D mixed solution;
(6)1-3 parts of ortho-xylenes are proportionally added into A, B, C, D, E mixed solution, and stirs 20min and then obtains finished fluid Body, it is filtered to obtain fuel economizing emission reduction environmental-protection additive.
5. the preparation method of a kind of fuel economizing emission reduction environmental-protection additive according to claim 4, it is characterised in that specific Preparation method is as follows:
(1)8-10 parts of polyether alcohols, 13-15 parts of n-octyl alcohols are sequentially added to the reaction kettle of 25-30 parts of ethanol solutions of storage in proportion In, stirring 5min obtains solution A;
(2)10-20 parts of acetone are obtained into solution B in proportion, then add B solution in solution A;
(3)By 3-6 portions of isopropyl nitrates, 7-10 parts of amyl nitrates mix in proportion solution C then by C solution add AB mix In solution;
(4)15-20 parts of methyl tertiary butyl ether(MTBE)s, 1-3 parts of propylene glycol t-butyl ethers are mixed into obtain solution D and then by solution D in proportion Add in A, B, C mixed solution;
(5)By 3-5 parts of hexas, 3-5 parts of phthalic amides mix to obtain solution E, then add E solution in proportion A, in B, C, D mixed solution;
(6)1-3 parts of ortho-xylenes are proportionally added into A, B, C, D, E mixed solution, and stirs 20min and then obtains finished fluid Body, it is filtered to obtain fuel economizing emission reduction environmental-protection additive.
6. the preparation method of a kind of fuel economizing emission reduction environmental-protection additive according to claim 4, it is characterised in that specific Preparation method is as follows:
(1)In the reaction kettle that 9 parts of polyether alcohols, 13 parts of n-octyl alcohols are sequentially added to 28 parts of ethanol solutions of storage in proportion, stirring 5min obtains solution A;
(2)10 parts of acetone are obtained into solution B in proportion, B solution is then added into step(1)In the solution A of gained;
(3)By 5 portions of isopropyl nitrates, 8 parts of amyl nitrates mix in proportion solution C then by C solution add AB mixed solutions In;
(4)By 15 parts of methyl tertiary butyl ether(MTBE)s, 2 parts of propylene glycol t-butyl ethers mix in proportion solution D then by solution D add A, B, in C mixed solutions;
(5)By 3 parts of hexas, 5 parts of phthalic amides mix to obtain solution E in proportion, then by E solution add A, B, C, in D mixed solutions;
(6)2 parts of ortho-xylenes are proportionally added into A, B, C, D, E mixed solution, and stirs 20min and then obtains production liquid, It is filtered to obtain fuel economizing emission reduction environmental-protection additive.
7. a kind of preparation method of fuel economizing emission reduction environmental-protection additive according to claim 4 or 5 or 6, its feature exist In the preparation method carries out in the environment of being 20 ± 5 DEG C in temperature.
8. a kind of preparation method of fuel economizing emission reduction environmental-protection additive according to any one of claim 1 to 6, its It is characterized in that, the additive application is in gasoline and/or diesel oil.
CN201711250605.6A 2017-12-01 2017-12-01 Fuel oil saving emission reduction environment-friendly additive and preparation method thereof Expired - Fee Related CN108018099B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6835217B1 (en) * 2000-09-20 2004-12-28 Texaco, Inc. Fuel composition containing friction modifier
CN1597877A (en) * 2004-08-30 2005-03-23 何凤臣 Fuel oil additive for gasoline engine and diesel oil engine
CN102492497A (en) * 2011-12-15 2012-06-13 河北冀春能源投资集团有限公司 Additive of M50 methanol gasoline
WO2017049472A1 (en) * 2015-09-23 2017-03-30 Yashentech Corporation Diesel fuel compositions
CN107118816A (en) * 2017-07-08 2017-09-01 湖北文理学院 A kind of composite gasoline additive

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6835217B1 (en) * 2000-09-20 2004-12-28 Texaco, Inc. Fuel composition containing friction modifier
CN1597877A (en) * 2004-08-30 2005-03-23 何凤臣 Fuel oil additive for gasoline engine and diesel oil engine
CN102492497A (en) * 2011-12-15 2012-06-13 河北冀春能源投资集团有限公司 Additive of M50 methanol gasoline
WO2017049472A1 (en) * 2015-09-23 2017-03-30 Yashentech Corporation Diesel fuel compositions
CN107118816A (en) * 2017-07-08 2017-09-01 湖北文理学院 A kind of composite gasoline additive

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