CN108017828A - A kind of preparation method of plastics deicer - Google Patents
A kind of preparation method of plastics deicer Download PDFInfo
- Publication number
- CN108017828A CN108017828A CN201610961628.7A CN201610961628A CN108017828A CN 108017828 A CN108017828 A CN 108017828A CN 201610961628 A CN201610961628 A CN 201610961628A CN 108017828 A CN108017828 A CN 108017828A
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- Prior art keywords
- plastics
- deicer
- calcium oxide
- anhydrous calcium
- molecular weight
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
- C08L33/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
The present invention relates to a kind of preparation method of plastics deicer.The plastics deicer main component is anhydrous calcium oxide micro mist, three(Dioctyl pyrophosphoryl epoxide)Isopropyl titanate, ethylene-vinyl acetate copolymer, low molecular weight polyethylene.The preparation method of the plastics deicer is first to crush anhydrous calcium oxide, is prepared into anhydrous calcium oxide micro mist, then is mixed by weight percentage with other constituents, is made through bispin screw pelletizer extruding pelletization.Use, without heating, drying, do not consume energy, water removal effect is splendid after the plastics deicer is directly mixed by 1 3% weight with water containing plastic during use.
Description
Technical field
The invention belongs to technical field of plastic, is related to a kind of preparation method of plastics deicer.
Background technology
All plastics all contain a certain amount of moisture, need to remove the moisture in plastics, ability in plastics secondary operation
Processing(Extrusion, injection, blowing, calendering)Go out the plastic products of qualification.
Common plastics water-eliminating method, is that plastics are added heat drier, the moisture in plastics is allowed by thermal evaporation, so as to remove
The moisture in plastics is removed, or is removed the moisture in plastics with the method for heated-air drying.The physics water removal of this heat drying
Method, must there is special drying equipment, drying time length(Generally want 2-6 hours), energy consumption is higher, adds plastic processing
Cost.And the micro condensation water for being contained in plastic pellet bubble is difficult to remove.
The purpose of the present invention is disclosing a kind of chemical water-eliminating method of plastics, it is to utilize deicer, passes through chemical reaction
Mode, absorbs micro-moisture contained in plastics and is combined to novel substance, and removes the moisture in plastics.
The water-eliminating method is that secondary operation is directly carried out after deicer is mixed with plastics, without special drying equipment,
Save time and power, easy to use, the plastics water removal suitable for opaque plastic product secondary processing process.
The content of the invention
The present invention is realized by the technical solution of following technical measures composition.
The present invention discloses a kind of preparation method of plastics deicer.The plastics deicer is by anhydrous calcium oxide micro mist three
(Dioctyl pyrophosphoryl epoxide)Isopropyl titanate, ethylene-vinyl acetate copolymer and low molecular weight polyethylene, by melting mixing
Made of extruding pelletization.The percentage by weight of the deicer each component is:
Anhydrous calcium oxide micro mist 70-83%
Three(Dioctyl pyrophosphoryl epoxide)Isopropyl titanate 1-3%
Ethylene-vinyl acetate copolymer 15-25%
Low molecular weight polyethylene 1-2%
The anhydrous calcium oxide micro mist in the above-mentioned technical solutions, is to smash anhydrous calcium oxide into particle diameter at 100-110 DEG C
Micro mist less than 10 microns, the preferred scope of its weight percentage is 70-80%;Three(Dioctyl pyrophosphoryl epoxide)Metatitanic acid is different
Propyl ester purity is technical grade, its weight percentage general control is in 1.5-2.5%;Low molecular weight polyethylene molecular weight is less than
3000, its weight percentage general control is in 1.5-2%.
A kind of preparation method of plastics deicer disclosed by the invention:Anhydrous calcium oxide micro mist is added and has warmed up 100-
In 110 DEG C of super mixer, three are added(Dioctyl pyrophosphoryl epoxide)Isopropyl titanate, high-speed stirred 2-3 minutes, adds
Ethylene-vinyl acetate copolymer, high-speed stirred 2 minutes.Double-screw extruding pelletizing machine is added after releasing, in 120-160 DEG C of temperature
Lower melting extrusion is granulated, and the particle that will eventually cause is put into super mixer, is added low molecular weight polyethylene, is stirred at 120 DEG C
Mix 1-2 minutes, plastics deicer.
A kind of plastics deicer disclosed by the invention, it is a kind of chemical water-eliminating method, it, which removes water principle, is:
Anhydrous calcium oxide micro mist in deicer, the water run into plastics chemically react, and generation one kind can be filled out as plastics
The material calcium hydroxide of charge, so as to eliminate the moisture in plastics, i.e. CaO+H2O→Ca(OH)2.
A kind of plastics deicer disclosed by the invention, application method are to add the deicer of 1-5% in the plastic, are uniformly mixed
Afterwards, it is directly used in the melting extrusion processing of plastic products.Deicer can also be mixed with plastics it is even after, first make once grain, then
The processing of plastic products is carried out, simple and convenient using the deicer, not power consumption, does not take.Being processed into for plastic products can be reduced
This.
Embodiment:
By embodiment, the present invention is further described in detail.In example given below, the percentage of each component is
Percentage by weight of the group in deicer constituent.
Embodiment 1
Anhydrous calcium oxide micro mist 75%
Three(Dioctyl pyrophosphoryl epoxide)Isopropyl titanate 1.5%
Ethylene-vinyl acetate copolymer 22%
Low molecular weight polyethylene 1.5%
Super mixer is warming up to 100-110 DEG C in advance, adds anhydrous calcium oxide micro mist, and three(Dioctyl pyrophosphoryl epoxide)Titanium
Isopropyl propionate, high-speed stirred 3 minutes, adds ethylene-vinyl acetate copolymer, and high-speed stirred 2 minutes, releases mixture, adds
The pre- double-screw plastic granulator for being warming up to 120-160 DEG C, melting extrusion are granulated, and then the particle by caused by is put into mixed at high speed
In device, low molecular weight polyethylene is added, in 120 DEG C of high-speed stirreds one minute, that is, plastics deicer is made.
Embodiment 2
Anhydrous calcium oxide micro mist 76%
Three(Dioctyl pyrophosphoryl epoxide)Isopropyl titanate 2%
Ethylene-vinyl acetate copolymer 20%
Low molecular weight polyethylene 2%
Super mixer is warming up to 100-110 DEG C in advance, adds anhydrous calcium oxide micro mist and three(Dioctyl pyrophosphoryl epoxide)Titanium
Isopropyl propionate, high-speed stirred 3 minutes, adds ethylene-vinyl acetate copolymer, then high-speed stirred 2 minutes, releases mixture, add
Enter the pre- double-screw plastic granulator for being warming up to 120-160 DEG C, melting extrusion is granulated, and then the particle by caused by is put into mixed at a high speed
In clutch, low molecular weight polyethylene is added, in 120 DEG C of high-speed stirreds one minute, that is, plastics deicer is made.
Embodiment 3
Anhydrous calcium oxide micro mist 80%
Three(Dioctyl pyrophosphoryl epoxide)Isopropyl titanate 2%
Ethylene-vinyl acetate copolymer 16%
Low molecular weight polyethylene 2%
Super mixer is warming up to 100-110 DEG C in advance, adds anhydrous calcium oxide micro mist and three(Dioctyl pyrophosphoryl epoxide)Titanium
Isopropyl propionate, high-speed stirred 3 minutes, adds ethylene-vinyl acetate copolymer, then high-speed stirred 2 minutes, releases mixture, add
Enter the pre- double-screw plastic granulator for being warming up to 120-160 DEG C, melting extrusion is granulated, and then the particle by caused by is put into mixed at a high speed
In clutch, low molecular weight polyethylene is added, in 120 DEG C of high-speed stirreds one minute, that is, plastics deicer is made.
1 plastics deicer application effect of table compares
Claims (6)
1. a kind of plastics deicer preparation method, it is characterised in that the plastics deicer mainly contains anhydrous calcium oxide micro mist, three
(Dioctyl pyrophosphoryl epoxide)Isopropyl titanate, ethylene-vinyl acetate copolymer, low molecular weight polyethylene, the weight hundred of component
Point ratio is:
Anhydrous calcium oxide micro mist 70-83%
Three(Dioctyl pyrophosphoryl epoxide)Isopropyl titanate 1-3%
Ethylene-vinyl acetate copolymer 15-25%
Low molecular weight polyethylene 1-2%.
2. plastics deicer according to claim 1, it is characterised in that the anhydrous calcium oxide micro mist, particle diameter are less than 10
Micron.
3. plastics deicer according to claim 1, it is characterised in that described three(Dioctyl pyrophosphoryl epoxide)Metatitanic acid
Isopropyl ester, purity are technical grade.
4. plastics deicer according to claim 1, it is characterised in that the ethylene-vinyl acetate copolymer, VA contain
Measure as 25-30%;Average molecular weight 2000.
5. plastics deicer according to claim 1, it is characterised in that the low molecular weight polyethylene, molecular weight are less than
3000。
First to crush anhydrous calcium oxide micro mist is made 6. plastics deicer preparation method according to claim 1, then with its
He mixes component thing by weight percentage, is made through double-screw plastic granulator extruding pelletization.
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CN201610961628.7A CN108017828A (en) | 2016-10-28 | 2016-10-28 | A kind of preparation method of plastics deicer |
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CN201610961628.7A CN108017828A (en) | 2016-10-28 | 2016-10-28 | A kind of preparation method of plastics deicer |
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Citations (9)
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KR20020028029A (en) * | 2000-10-06 | 2002-04-15 | 권문구 | Poly vinyl chloride insulator for wire |
CN1594410A (en) * | 2004-07-06 | 2005-03-16 | 黄定强 | High performance anti-foaming dehumidification master batch for plastic process |
CN1611534A (en) * | 2003-10-31 | 2005-05-04 | 丁少忠 | Dehumidifying agent for plastic shaping and its preparing method |
CN1903927A (en) * | 2006-07-18 | 2007-01-31 | 黄定敏 | Plastic moisture removing foam eliminating mother particle |
CN102070808A (en) * | 2009-11-20 | 2011-05-25 | 梁树旺 | Dehydrating and drying master batch for plastic pipe and production method thereof |
CN102311570A (en) * | 2011-08-05 | 2012-01-11 | 大连方盛塑料有限公司 | Dehumidizer for plastic molding |
CN103627060A (en) * | 2012-08-21 | 2014-03-12 | 上海心尔新材料科技股份有限公司 | Long-acting defoaming dehumidifying drying master batch for plastic processing and preparation method thereof |
CN104130495A (en) * | 2014-08-12 | 2014-11-05 | 廊坊华博环保材料有限公司 | Water removal master batch for plastic drip irrigation pipe or drip irrigation zone and preparation method of water removal master batch |
CN105086068A (en) * | 2015-08-20 | 2015-11-25 | 福建博大塑业新材料有限公司 | Water-absorbing granule for HDPE (high-density polyethylene) tubes, and preparation method and application thereof |
-
2016
- 2016-10-28 CN CN201610961628.7A patent/CN108017828A/en active Pending
Patent Citations (9)
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KR20020028029A (en) * | 2000-10-06 | 2002-04-15 | 권문구 | Poly vinyl chloride insulator for wire |
CN1611534A (en) * | 2003-10-31 | 2005-05-04 | 丁少忠 | Dehumidifying agent for plastic shaping and its preparing method |
CN1594410A (en) * | 2004-07-06 | 2005-03-16 | 黄定强 | High performance anti-foaming dehumidification master batch for plastic process |
CN1903927A (en) * | 2006-07-18 | 2007-01-31 | 黄定敏 | Plastic moisture removing foam eliminating mother particle |
CN102070808A (en) * | 2009-11-20 | 2011-05-25 | 梁树旺 | Dehydrating and drying master batch for plastic pipe and production method thereof |
CN102311570A (en) * | 2011-08-05 | 2012-01-11 | 大连方盛塑料有限公司 | Dehumidizer for plastic molding |
CN103627060A (en) * | 2012-08-21 | 2014-03-12 | 上海心尔新材料科技股份有限公司 | Long-acting defoaming dehumidifying drying master batch for plastic processing and preparation method thereof |
CN104130495A (en) * | 2014-08-12 | 2014-11-05 | 廊坊华博环保材料有限公司 | Water removal master batch for plastic drip irrigation pipe or drip irrigation zone and preparation method of water removal master batch |
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