CN108003817A - High temperature surely glues acrylate pressure-sensitive adhesive and preparation method thereof - Google Patents
High temperature surely glues acrylate pressure-sensitive adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN108003817A CN108003817A CN201711320673.5A CN201711320673A CN108003817A CN 108003817 A CN108003817 A CN 108003817A CN 201711320673 A CN201711320673 A CN 201711320673A CN 108003817 A CN108003817 A CN 108003817A
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- China
- Prior art keywords
- high temperature
- sensitive adhesive
- acrylate pressure
- parts
- surely
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/062—Copolymers with monomers not covered by C09J133/06
- C09J133/066—Copolymers with monomers not covered by C09J133/06 containing -OH groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of high temperature surely to glue acrylate pressure-sensitive adhesive, and in parts by weight, its component is：30 40 parts of acrylic acid isooctyl；35 parts of acrylic acid；35 parts of hy-droxybutyl；40 50 parts of ethyl acetate；Steady 35 parts of sticky feature resin；13 parts of functional cross-links agent.It is an advantage of the invention that：Prepared product uses more convenient.The preparation method of acrylate pressure-sensitive adhesive is surely glued the invention also discloses the high temperature.
Description
Technical field
The present invention relates to adhesive techniques field, surely glues acrylate pressure-sensitive adhesive more particularly, to a kind of high temperature.This
Invention further relates to the preparation method that the high temperature surely glues acrylate pressure-sensitive adhesive.
Background technology
Surely temperature pressure sensitive band made of viscous adhesive is that one kind can also form more stable bonding force at high temperature to high temperature
Adhesive tape.The bonding force of the steady adhesive tape of high temperature is mainly Van der Waals force.After bonding plane is formed, the structure of gluing of surfaces will not be broken
It is bad.Pressure sensitive adhesive tape be it is a kind of to presser sensor, be not required to heat, be not required to solvent, be not required to larger pressure, only need to be slightly pressurized or use
Finger one is by the adhesive tape that bonding can be achieved.Its main feature is that it is viscous it is easily, take off be not difficult, shell without damage.It is existing to make on the market
Adhesive tape made of pressure-sensitive acrylate, after product fitting SUS steel plates have chance high temperature substantially, 180 ° of peeling forces are serious
Rising problem, common product is not stained to by protection face, but has portioned product to leave residue glue or ghost in protection face yet.
The content of the invention
In view of the deficiency of the prior art, the object of the present invention is to provide a kind of high temperature surely to glue Acrylate pressure sensitive
Adhesive, it has the characteristics that prepared adhesive tape is extremely easy to use.The invention also discloses the high temperature surely to glue acrylate
The preparation method of pressure-sensitive adhesive agent.
The technical solution adopted in the present invention is：High temperature surely glues acrylate pressure-sensitive adhesive, in parts by weight, its component
For：
The steady sticky feature resin is：138 resins.
The functional cross-links agent is：AIBN.
Afore-said hot surely glues the preparation method of acrylate pressure-sensitive adhesive, comprises the following steps successively：
(1) acrylic acid isooctyl, acrylic acid, hy-droxybutyl, ethyl acetate are mixed into reaction kettle, 25-
65-66 DEG C is heated in 35min；
(2) functional cross-links agent being added in reaction kettle, temperature control keeps 110-130min in 65-68 DEG C, afterwards, heating
To 72 DEG C of-73 DEG C of 50-70min of holding, afterwards, cooled to room temperature；
(3) steady sticky feature resin is added into reaction kettle, stirs evenly and form finished product.
The invention has the advantages that compared with the prior art,：Prepared product uses more convenient.The present invention's
The adhesive tape that high temperature is surely glued prepared by acrylate pressure-sensitive adhesive can be accomplished to be bonded in high temperature, then after recovering room temperature, product pair
The ascensional range of 180 ° of peeling forces on affixed object surface is minimum, can be applied to full-automatic production line of more robotic arm manipulations etc.
In various fields.
Embodiment
Embodiment 1
High temperature surely glues acrylate pressure-sensitive adhesive, and in parts by weight, its component is：
Wherein：
The steady sticky feature resin is：138 resins.
The functional cross-links agent is：AIBN.
The high temperature surely glues the preparation method of acrylate pressure-sensitive adhesive, comprises the following steps successively：
(1) acrylic acid isooctyl, acrylic acid, hy-droxybutyl, ethyl acetate are mixed into reaction kettle, in 25min
It is heated to 65 DEG C；
(2) functional cross-links agent is added in reaction kettle, temperature control keeps 110min in 65 DEG C.Afterwards, 72 DEG C of guarantors are warming up to
Hold 50min.Afterwards, cooled to room temperature；
(3) steady sticky feature resin is added into reaction kettle, stirs evenly and form finished product 1.
Embodiment 2
High temperature surely glues acrylate pressure-sensitive adhesive, and in parts by weight, its component is：
Wherein：
The steady sticky feature resin is：138 resins.
The functional cross-links agent is：AIBN.
The high temperature surely glues the preparation method of acrylate pressure-sensitive adhesive, comprises the following steps successively：
(1) acrylic acid isooctyl, acrylic acid, hy-droxybutyl, ethyl acetate are mixed into reaction kettle, in 30min
It is heated to 65.5 DEG C；
(2) functional cross-links agent is added in reaction kettle, temperature control keeps 120min in 66 DEG C.Afterwards, 72.5 DEG C are warming up to
Keep 60min.Afterwards, cooled to room temperature；
(3) steady sticky feature resin is added into reaction kettle, stirs evenly and form finished product 2.
Embodiment 3
High temperature surely glues acrylate pressure-sensitive adhesive, and in parts by weight, its component is：
Wherein：
The steady sticky feature resin is：138 resins.
The functional cross-links agent is：AIBN.
The high temperature surely glues the preparation method of acrylate pressure-sensitive adhesive, comprises the following steps successively：
(1) acrylic acid isooctyl, acrylic acid, hy-droxybutyl, ethyl acetate are mixed into reaction kettle, in 35min
It is heated to 66 DEG C；
(2) functional cross-links agent is added in reaction kettle, temperature control keeps 130min in 68 DEG C.Afterwards, 73 DEG C of guarantors are warming up to
Hold 60min.Afterwards, cooled to room temperature；
(3) steady sticky feature resin is added into reaction kettle, stirs evenly and form finished product 3.
Effect example
Finished product 1-3 is prepared as adhesive tape 1-3 according to common technology.Then, adhesive tape 1-3 is sticked to stainless steel mirror respectively
Face surface of steel plate is tested.As a result it is：
Adhesive tape 1：
Stainless steel mirror steel plate is bonded at 150 DEG C of temperature (high temperature i.e. mentioned in the present invention, similarly hereinafter) to toast 30 minutes,
Recover be to 180 ° of peeling forces of 25 DEG C of adhesive tapes of room temperature and body surface：68g, stainless steel mirror is bonded without high temperature normal product
180 ° of peeling forces of 20 minutes adhesive tapes of face steel plate and body surface are：62g.That is, 6g is risen.
Adhesive tape 2：
Stainless steel mirror steel plate is bonded at a temperature of 150 DEG C to toast 30 minutes, is recovered to 25 DEG C of adhesive tapes of room temperature and object table
180 ° of peeling forces in face are：74g, 20 minutes adhesive tapes of stainless steel mirror steel plate and body surface are bonded without high temperature normal product
180 ° of peeling forces be：64g.That is, 10g is risen.
Adhesive tape 3：
Stainless steel mirror steel plate is bonded at a temperature of 150 DEG C to toast 30 minutes, is recovered to 25 DEG C of adhesive tapes of room temperature and object table
180 ° of peeling forces in face are：68g, 20 minutes adhesive tapes of stainless steel mirror steel plate and body surface are bonded without high temperature normal product
180 ° of peeling forces be：59g.That is, 9g is risen.
Result above shows：
The high temperature of the present invention surely glues the adhesive tape prepared by acrylate pressure-sensitive adhesive, can accomplish to be bonded in high temperature, then extensive
After multiple room temperature, product rises control within 10%-20% to 180 ° of peeling forces on affixed object surface, more convenient.
The foregoing is merely the preferred embodiment of the present invention, is not intended to limit the scope of the invention, every utilization
The equivalent structure or equivalent flow shift that present specification is made, is directly or indirectly used in other relevant technologies
Field, is included within the scope of the present invention.
Claims (4)
1. high temperature surely glues acrylate pressure-sensitive adhesive, in parts by weight, its component is：
2. high temperature according to claim 1 surely glues acrylate pressure-sensitive adhesive, it is characterised in that：The steady sticky feature
Resin is：138 resins.
3. high temperature according to claim 1 surely glues acrylate pressure-sensitive adhesive, it is characterised in that：The functional cross-links
Agent is：AIBN.
4. high temperature according to any one of claims 1 to 3 surely glues the preparation method of acrylate pressure-sensitive adhesive, wrap successively
Include following steps：
(1) acrylic acid isooctyl, acrylic acid, hy-droxybutyl, ethyl acetate are mixed into reaction kettle, in 25-35min
It is heated to 65-66 DEG C；
(2) functional cross-links agent is added in reaction kettle, temperature control keeps 110-130min in 65-68 DEG C, afterwards, is warming up to 72
DEG C of-73 DEG C 50-70min of holding, afterwards, cooled to room temperature；
(3) steady sticky feature resin is added into reaction kettle, stirs evenly and form finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711320673.5A CN108003817A (en) | 2017-12-12 | 2017-12-12 | High temperature surely glues acrylate pressure-sensitive adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711320673.5A CN108003817A (en) | 2017-12-12 | 2017-12-12 | High temperature surely glues acrylate pressure-sensitive adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108003817A true CN108003817A (en) | 2018-05-08 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711320673.5A Pending CN108003817A (en) | 2017-12-12 | 2017-12-12 | High temperature surely glues acrylate pressure-sensitive adhesive and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753080A (en) * | 2017-01-13 | 2017-05-31 | 上海英诺威新材料科技有限公司 | Refractory metal plate diaphragm pressure sensitive adhesive and preparation method thereof |
| CN106967376A (en) * | 2017-03-24 | 2017-07-21 | 西安航天三沃化学有限公司 | A kind of solvent-type acrylic ester gum stick and preparation method thereof |
| CN107236491A (en) * | 2017-07-17 | 2017-10-10 | 江阴邦特科技有限公司 | Acrylic pressure sensitive gluing agent and preparation method thereof |
-
2017
- 2017-12-12 CN CN201711320673.5A patent/CN108003817A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106753080A (en) * | 2017-01-13 | 2017-05-31 | 上海英诺威新材料科技有限公司 | Refractory metal plate diaphragm pressure sensitive adhesive and preparation method thereof |
| CN106967376A (en) * | 2017-03-24 | 2017-07-21 | 西安航天三沃化学有限公司 | A kind of solvent-type acrylic ester gum stick and preparation method thereof |
| CN107236491A (en) * | 2017-07-17 | 2017-10-10 | 江阴邦特科技有限公司 | Acrylic pressure sensitive gluing agent and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180508 |
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| RJ01 | Rejection of invention patent application after publication |