CN108003799A - Random patch of a kind of water-fastness multipurpose and preparation method thereof - Google Patents
Random patch of a kind of water-fastness multipurpose and preparation method thereof Download PDFInfo
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- CN108003799A CN108003799A CN201711308427.8A CN201711308427A CN108003799A CN 108003799 A CN108003799 A CN 108003799A CN 201711308427 A CN201711308427 A CN 201711308427A CN 108003799 A CN108003799 A CN 108003799A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F287/00—Macromolecular compounds obtained by polymerising monomers on to block polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F289/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds not provided for in groups C08F251/00 - C08F287/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
- C08G18/3203—Polyhydroxy compounds
- C08G18/3206—Polyhydroxy compounds aliphatic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
Abstract
Arbitrarily pasted the invention discloses a kind of water-fastness multipurpose and preparation method thereof, a kind of water-fastness multipurpose is arbitrarily pasted, its raw material components includes：Acrylate, modified polyurethane resin, 1,4 butanediols two (3 sulfydryl acrylic acid) are modified raw rubber, liquid rosin glyceride, aerosil, methylene diacrylamide, modified SEBS, emulsifying agent SE 10N and benzoin methyl ether, wherein, the mass ratio that acrylate, modified polyurethane resin, Isosorbide-5-Nitrae butanediol two (3 sulfydryl acrylic acid) are modified raw rubber, liquid rosin glyceride, aerosil, methylene diacrylamide, modified SEBS, emulsifying agent SE 10N and benzoin methyl ether is 100：23~36：27~41：7~16：18~31：2~9：13~19：29~46：3~10.The water-fastness multipurpose of the present invention is arbitrarily pasted, and is had excellent tack and is held viscosity, and can reuse；Water-fastness multipurpose is arbitrarily pasted cleaned using clear water after can recover original adhesive property.
Description
Technical field
Arbitrarily pasted the present invention relates to a kind of water-fastness multipurpose and preparation method thereof, belong to random patch field.
Background technology
Polyacrylate pressure-sensitive be under catalyst action as obtained from Raolical polymerizable resin.Polypropylene
Acid esters pressure sensitive adhesive has excellent high- and low-temperature resistance, and nontoxic, and mass loss rate is low, and it is few to coagulate volatile matter, polyacrylate pressure
Quick glue is widely used in the fields such as adhesive tape, adhesive, film.
At present, acrylate pressure sensitive adhesive in tack and holds the further lifting of viscosity needs.
The content of the invention
The present invention provides a kind of water-fastness multipurpose arbitrarily patch and preparation method thereof, and the water-fastness multipurpose of the application is arbitrarily pasted
With excellent tack and hold viscosity.
In order to solve the above technical problems, the technical solution adopted in the present invention is as follows：
A kind of water-fastness multipurpose is arbitrarily pasted, its raw material components includes：Acrylate, modified polyurethane resin, 1,
4- butanediols two (3- sulfydryls acrylic acid) are modified the double acryloyls of raw rubber, liquid rosin glyceride, aerosil, methene
Amine, modified SEBS, emulsifying agent SE-10N and benzoin methyl ether, wherein, acrylate, modified polyurethane resin, Isosorbide-5-Nitrae-fourth
Glycol two (3- sulfydryls acrylic acid) is modified raw rubber, liquid rosin glyceride, aerosil, methylene diacrylamide, changes
Property SEBS, emulsifying agent SE-10N and benzoin methyl ether mass ratio be 100：23~36：27~41：7~16：18~31：2~9：
13~19：29~46：3~10.
Applicant it has been investigated that, liquid rosin glyceride has low softening point, can keep arbitrarily patch have when in use
There are excellent initial bonding strength and holding power；Aerosil has strengthening action, can improve the initial bonding strength and holding power arbitrarily pasted；
Methylene diacrylamide has difunctional structure, can improve the crosslink density arbitrarily pasted, so that it is strong to improve the cohesion arbitrarily pasted
Degree；Emulsifying agent SE-10N can maintain the stability of system in material mixed process；Each raw material components by mutually cooperateing with and promoting,
Initial bonding strength and holding power lifting highly significant.
In order to further improve the initial bonding strength and holding power that arbitrarily paste, it is preferable that acrylate is by triisopropylsilyl
Acrylate, 2- propylheptyls acrylate, tetrahydrofuran acrylate, Isooctyl acrylate monomer and benzoin methyl ether reaction system
, wherein, triisopropylsilyl acrylate, 2- propylheptyls acrylate, tetrahydrofuran acrylate, Isooctyl acrylate monomer
Mass ratio with benzoin methyl ether is 70：41~56：32~39：105~120：2~9.Above-mentioned triisopropylsilyl acrylic acid
Ester, 2- propylheptyls acrylate, tetrahydrofuran acrylate and Isooctyl acrylate monomer purpose in order to improve arbitrarily paste just
Viscous force and holding power.Applicant it has been investigated that, triisopropylsilyl acrylate, 2- propylheptyls acrylate, tetrahydrochysene furan
Mutter acrylate and Isooctyl acrylate monomer monomer has extremely low glass transition temperature, its polymer synthesized equally has low
Glass transition temperature, can assign acrylate excellent initial bonding strength and holding power, final acrylate can carry
The initial bonding strength and holding power that height arbitrarily pastes.
In order to further improve the initial bonding strength and holding power that arbitrarily paste, it is preferable that modified polyurethane resin is by toluene diisocyanate
Acid esters, 1,4- butanediols, Polyol X 8000, Voranol 8000LM, dibutyltin dilaurate and acrylamide reaction
It is made, wherein, toluene di-isocyanate(TDI), 1,4-butanediol, Polyol X 8000, Voranol 8000LM, dibutyltindilaurylmercaptide
The mass ratio of cinnamic acid ester and acrylamide is 50：9~13：104~259：110~320：0.1~0.6：12~21.Applicant passes through
Research finds that acrylamide can improve the photochemical activity of polyurethane resin；Polyol X 8000 and Voranol 8000LM tools
There are excellent wellability, stickiness and lower glass transition temperatures, there is low glass using it as polyurethane resin prepared by raw material
Change transition temperature, excellent initial bonding strength and holding power；At the end of polyurethane resin reacts, polyurethane tree is used as using acrylamide
The reaction terminating agent of fat, can not only keep the stability of polyurethane resin, moreover it is possible to improve the photochemical activity of polyurethane resin, most
Eventually, modified polyurethane resin can improve the initial bonding strength and holding power arbitrarily pasted.
In order to further improve the initial bonding strength and holding power that arbitrarily paste, it is preferable that 1,4-butanediol two (3- sulfydryls acrylic acid)
Modified raw rubber is by raw rubber, 1,4- butanediols two (3- sulfydryls acrylic acid), ethylene glycol two (3- sulfydryls acrylic acid) and activated carbon
Powder reaction is made, wherein, raw rubber, 1,4-butanediol two (3- sulfydryls acrylic acid), ethylene glycol two (3- sulfydryls acrylic acid) and work
Property powdered carbon mass ratio be 100：12~20：8~19：13~27；The mesh number of active powdered carbon is 1250 mesh.The application is to activated carbon
The selection of powder and mesh number be in order to improve the initial bonding strength of raw rubber, applicant it has been investigated that, raw rubber has excellent first viscous
Contain sulfydryl in power and wellability, 1,4-butanediol two (3- sulfydryls acrylic acid) and ethylene glycol two (3- sulfydryls acrylic acid) structure,
Raw rubber can be promoted to vulcanize and improve the cross-link intensity of raw rubber, so as to improve the initial bonding strength and holding power of raw rubber；Activated carbon
Powder can assist raw rubber to improve its initial bonding strength, finally, be modified as supporting material and porous material using the effect of its micro-porous adsorption
Raw rubber can improve the initial bonding strength and holding power arbitrarily pasted.
In order to further improve the initial bonding strength arbitrarily pasted, holding power and cohesive strength, it is preferable that modified SEBS is by SEBS, third
Olefin(e) acid, aluminium chloride, iron chloride and dimethylformamide reaction are made, wherein, SEBS, acrylic acid, aluminium chloride, iron chloride and diformazan
The mass ratio of base formamide is 100：85~97：7~15：9~16：150~185.The purpose of the application SEBS in order to improve with
Initial bonding strength, holding power and the cohesive strength for patch of anticipating；In order to improve the photochemical activity of SEBS, SEBS has the purpose of acrylic acid in itself
There is certain adhesive property, under the action of catalyst iron chloride and aluminium chloride, acrylic acid can be grafted in SEBS molecular structures,
Assign SEBS photochemical activities, modified SEBS can not only improve the photochemical activity of SEBS, moreover it is possible to improve arbitrarily paste initial bonding strength,
Holding power and cohesive strength.
The preparation method that above-mentioned water-fastness multipurpose is arbitrarily pasted, by acrylate, modified polyurethane resin, Isosorbide-5-Nitrae-fourth
Glycol two (3- sulfydryls acrylic acid) is modified raw rubber, liquid rosin glyceride, aerosil, methylene diacrylamide, changes
Property SEBS, emulsifying agent SE-10N and benzoin methyl ether are according to mass ratio 100：23~36：27~41：7~16：18~31：2~9：
13~19：29~46：3~10 are added in reaction kettle, the bar that low whipping speed is 43~58r/min, temperature is 39~51 DEG C
19~35min is reacted under part, through 1000~3000W, 2~9s of high voltage mercury lamp radiation, that is, water-fastness multipurpose is obtained and arbitrarily pastes.This
The first purpose for applying for liquid rosin glyceride and aerosil is to improve the initial bonding strength and holding power that arbitrarily paste；First
The first purpose for pitching bisacrylamide is to improve the cohesive strength arbitrarily pasted；The first purpose of emulsifying agent SE-10N be in order to
Maintain the stability of system in material mixed process.
The application method that the water-fastness multipurpose of the application is arbitrarily pasted is：The material that the above method is prepared to gained is as needed
Variously-shaped bulk is prepared into, is that product arbitrarily pastes, arbitrarily patch is the cementitious product in each face, will arbitrarily paste one
Then the object of required fixation is attached to and arbitrarily sticks in required position by face paste, you can play fixation, arbitrarily patch can be multiple
Reuse, during having and being arbitrarily attached to and be used for multiple times, when being dirty, wash with water, then proceed to use.
It is preferred that the preparation method of modified SEBS is：SEBS, acrylic acid, aluminium chloride, iron chloride and dimethylformamide are pressed
It is 100 according to mass ratio：85~97：7~15：9~16：150~185 are added in reactor, and low whipping speed is 86~105r/
Min, temperature react 2~5h under conditions of being 85~108 DEG C, product is evaporated under reduced pressure 0.5h through 125 DEG C, -0.06MPa, then successively
Washed 3 times through water washing 3 times, ethanol, 75 DEG C, -0.05MPa vacuum drying 15min, obtain modified SEBS.
It is preferred that the preparation method of the modified raw rubber of 1,4-butanediol two (3- sulfydryls acrylic acid) is：By raw rubber, 1,4- fourths
Glycol two (3- sulfydryls acrylic acid), ethylene glycol two (3- sulfydryls acrylic acid) and active powdered carbon are according to mass ratio 100：12~20：8~
19：13~27 are added in high-speed mixer, under conditions of low whipping speed is 600~800r/min, temperature is 90~105 DEG C
5~10min is reacted, 1,4-butanediol two (3- sulfydryls acrylic acid) is obtained and is modified raw rubber.
It is preferred that the preparation method of modified polyurethane resin is：By toluene di-isocyanate(TDI), 1,4- butanediols, Polyol X
8000th, Voranol 8000LM and dibutyltin dilaurate are added in reaction kettle, and low whipping speed is 75~96r/
Min, temperature react 1.5~3h under conditions of being 85~98 DEG C, and reaction kettle then is cooled to 50 DEG C, third is added into reaction kettle
Acrylamide, maintains 50 DEG C, reacts 10min under the conditions of 60r/min, that is, obtain modified polyurethane resin, wherein, toluene diisocynate
Ester, 1,4- butanediols, Polyol X 8000, Voranol 8000LM, the quality of dibutyltin dilaurate and acrylamide
Than for 50：9~13：104~259：110~320：0.1~0.6：12~21.
It is preferred that the preparation method of acrylate is：By triisopropylsilyl acrylate, 2- propylheptyl acrylic acid
Ester, tetrahydrofuran acrylate, Isooctyl acrylate monomer and benzoin methyl ether are according to mass ratio 70：41~56：32~39：105~
120：2~9 are added in reaction kettle, under conditions of low whipping speed is 67~83r/min, temperature is 37~46 DEG C react 15~
30min, through 1000~3000W, 1~7s of high voltage mercury lamp radiation, that is, obtains acrylate.
The unmentioned technology of the present invention is with reference to the prior art.
The water-fastness multipurpose of the present invention is arbitrarily pasted, and is had excellent tack and is held viscosity, can apply plastics, rubber,
The surfaces such as fiber, timber, metal, leather, cloth, wall, ceramic tile, any trace is will not leave behind after tearing from these material surfaces,
And it can reuse；Water-fastness multipurpose is arbitrarily pasted cleaned using clear water after can recover original adhesive property；When random patch table
When pollutant occurs in face, it can be lived again by the method that clear water cleans.
Embodiment
For a better understanding of the present invention, with reference to the embodiment content that the present invention is furture elucidated, but the present invention
Content is not limited solely to the following examples.
Reagent producer：Triisopropylsilyl acrylate, emulsifying agent SE-10N producers have for Wuhan La Nabai medication chemistries
Limit company；2- propylheptyl acrylate, 1,4-butanediol two (3- sulfydryls acrylic acid) producer have for Guangzhou essence moral chemical material
Limit company；Tetrahydrofuran acrylate producer is Xiao Nan branch companies of Hubei Yuancheng Saichuang Technology Co., Ltd.；Acrylic acid producer is
Jinan element Chemical Co., Ltd.；Aerosil producer is Tian Sheng great achievements Chemical Co., Ltd. of Shenzhen；Raw rubber producer
For Dongying City Hai Ruisen limited rubbers company；Methylene diacrylamide producer is Jin Teng Yilong Industry Co., Ltd. of Shenzhen；Propylene
Suan Yi monooctyl esters producer is Zhangjiagang bonded area Wang Hui Chemical trades Co., Ltd；Benzoin methyl ether producer has for the vast think of chemical industry in Shanghai
Limit company；SEBS producers are Guangzhou Cheng Hao trade Co., Ltds；New material science and technology is washed one's hair for upper sea God by 8000 producers of Polyol X to be had
Limit company；Voranol 8000LM producers are Shanghai Xiang Kang developments in science and technology Co., Ltd；Toluene di-isocyanate(TDI) producer is Shandong
One hundred Hongxin Materials Co., Ltd；Dibutyltin dilaurate producer is Shanghai De Yin Chemical Co., Ltd.s；1,4- butanediols factory
Chemical Industry Science Co., Ltd is sprouted for upper Haixing County by family；Active powdered carbon producer is Lingshou County radiance mineral products processing Co., Ltd；Liquid
Rosin glycerides Guangzhou Song Bao Chemical Co., Ltd.s；Aluminium chloride, iron chloride, dimethylformamide producer are Chinese medicines group chemistry examination
Agent Co., Ltd；Polyurethane resin producer is Jining Hua Kai resin Co., Ltd；Acrylate producer praises middleization for Nanjing
Work Science and Technology Ltd..
Embodiment 1
A kind of water-fastness multipurpose is arbitrarily pasted, and its preparation method comprises the following steps：
(1), 100 parts of SEBS, 91 parts of acrylic acid, 9 parts of aluminium chloride, 12 parts of iron chloride and 175 parts of dimethylformamides are weighed to add
Enter into reactor, low whipping speed 95r/min, 3h reacted under the conditions of 98 DEG C of maintenance system temperature, product through 125 DEG C ,-
0.06MPa is evaporated under reduced pressure 0.5h, and through 500mL water washings 3 times, (water used in washing is 500mL every time, other tables similar everywhere
Reach, implication is similar), 500mL ethanol wash 3 times, 75 DEG C, -0.05MPa vacuum drying 15min, obtain modified SEBS；
(2), 100 parts of raw rubbers, 16 parts of 1,4- butanediols two (3- sulfydryls acrylic acid), 13 parts of (3- mercaptos of ethylene glycol two are weighed
Base acrylic acid) and 18 parts of active powdered carbons be added in high-speed mixer, low whipping speed 680r/min, maintenance system temperature
7min is reacted under the conditions of 100 DEG C, 1,4-butanediol two (3- sulfydryls acrylic acid) is obtained and is modified raw rubber；
(3), 50 parts of toluene di-isocyanate(TDI)s, 11 parts of 1,4- butanediols, 181 parts of 8000,217 parts of Polyol X are weighed
Voranol 8000LM and 0.3 part of dibutyltin dilaurate are added in reaction kettle, mixing speed 85r/min, are maintained
2h is reacted under the conditions of 95 DEG C of system temperature, after reaction kettle is cooled to 50 DEG C, 17 parts of acrylamides are added in reaction kettle, dimension
Hold 50 DEG C, react 10min under the conditions of 60r/min, that is, obtain modified polyurethane resin；
(4), 70 parts of triisopropylsilyl acrylate, 51 parts of 2- propylheptyls acrylate, 36 parts of tetrahydrofurans are weighed
Acrylate, 110 parts of Isooctyl acrylate monomers and 4 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 75r/min,
20min is reacted under the conditions of 53 DEG C of maintenance system temperature, through 1000W high voltage mercury lamp radiation 2s, that is, obtains acrylate；
(5), 100 parts of acrylates, 29 parts of modified polyurethane resins, 36 parts of (3- sulfydryls of 1,4- butanediols two are weighed
Acrylic acid) modified raw rubber, 10 parts of liquid rosin glyceride, 23 parts of aerosils, 5 parts of methylene diacrylamides, 15 parts
Modified SEBS, 33 parts of emulsifying agent SE-10N, 5 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 52r/min, dimension
Hold and react 25min under the conditions of 45 DEG C of system temperature, through 2000W high voltage mercury lamp radiation 5s, that is, obtain water-fastness multipurpose and arbitrarily paste.
Embodiment 2
A kind of water-fastness multipurpose is arbitrarily pasted, and its preparation method comprises the following steps：
(1), 100 parts of SEBS, 85 parts of acrylic acid, 7 parts of aluminium chloride, 9 parts of iron chloride and 150 parts of dimethylformamides are weighed to add
Enter into reactor, low whipping speed 86r/min, 2h reacted under the conditions of 85 DEG C of maintenance system temperature, product through 125 DEG C ,-
0.06MPa is evaporated under reduced pressure 0.5h, is washed 3 times through 500mL water washings 3 times, 500mL ethanol, 75 DEG C, -0.05MPa vacuum drying
15min, obtains modified SEBS；
(2), 100 parts of raw rubbers, 12 parts of 1,4- butanediols two (3- sulfydryls acrylic acid), 8 parts of (3- sulfydryls of ethylene glycol two are weighed
Acrylic acid) and 13 parts of active powdered carbons be added in high-speed mixer, low whipping speed 600r/min, 90 DEG C of maintenance system temperature
Under the conditions of react 5min, obtain 1,4-butanediol two (3- sulfydryls acrylic acid) be modified raw rubber；
(3), 50 parts of toluene di-isocyanate(TDI)s, 9 parts of 1,4- butanediols, 104 parts of 8000,110 parts of Polyol X are weighed
Voranol 8000LM and 0.1 part of dibutyltin dilaurate are added in reaction kettle, low whipping speed 75r/min, dimension
Hold and react 1.5h under the conditions of 85 DEG C of system temperature, after reaction kettle is cooled to 50 DEG C, 12 parts of acrylamides are added to reaction kettle
In, 10min is reacted under the conditions of 50 DEG C of maintenance, 60r/min, that is, obtains modified polyurethane resin；
(4), 70 parts of triisopropylsilyl acrylate, 41 parts of 2- propylheptyls acrylate, 32 parts of tetrahydrofurans are weighed
Acrylate, 105 parts of Isooctyl acrylate monomers and 2 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 67r/min,
15min is reacted under the conditions of 37 DEG C of maintenance system temperature, through 1000W high voltage mercury lamp radiation 7s, that is, obtains acrylate；
(5), 100 parts of acrylates, 23 parts of modified polyurethane resins, 27 parts of (3- sulfydryls of 1,4- butanediols two are weighed
Acrylic acid) modified raw rubber, 7 parts of liquid rosin glyceride, 18 parts of aerosils, 2 parts of methylene diacrylamides, 13 parts change
Property SEBS, 29 parts of emulsifying agent SE-10N, 3 parts of benzoin methyl ethers be added in reaction kettle, low whipping speed 43r/min, maintains
19min is reacted under the conditions of 39 DEG C of system temperature, through 1000W high voltage mercury lamp radiation 9s, that is, water-fastness multipurpose is obtained and arbitrarily pastes.
Embodiment 3
A kind of water-fastness multipurpose is arbitrarily pasted, and its preparation method comprises the following steps：
(1), 100 parts of SEBS, 97 parts of acrylic acid, 15 parts of aluminium chloride, 16 parts of iron chloride and 185 parts of dimethylformamides are weighed
It is added in reactor, low whipping speed 105r/min, reacts 5h under the conditions of 108 DEG C of maintenance system temperature, product is through 125
DEG C, -0.06MPa vacuum distillation 0.5h, 3 times are washed through 500mL water washings 3 times, 500mL ethanol, 75 DEG C, -0.05MPa vacuum does
Dry 15min, obtains modified SEBS；
(2), 100 parts of raw rubbers, 20 parts of 1,4- butanediols two (3- sulfydryls acrylic acid), 19 parts of (3- mercaptos of ethylene glycol two are weighed
Base acrylic acid) and 27 parts of active powdered carbons be added in high-speed mixer, low whipping speed 800r/min, maintenance system temperature
10min is reacted under the conditions of 105 DEG C, 1,4-butanediol two (3- sulfydryls acrylic acid) is obtained and is modified raw rubber；
(3), 50 parts of toluene di-isocyanate(TDI)s, 13 parts of 1,4- butanediols, 259 parts of 8000,320 parts of Polyol X are weighed
Voranol 8000LM and 0.6 part of dibutyltin dilaurate are added in reaction kettle, low whipping speed 96r/min, dimension
Hold and react 3h under the conditions of 98 DEG C of system temperature, after reaction kettle is cooled to 50 DEG C, 21 parts of acrylamides are added in reaction kettle,
10min is reacted under the conditions of 50 DEG C of maintenance, 60r/min, that is, obtains modified polyurethane resin；
(4), 70 parts of triisopropylsilyl acrylate, 56 parts of 2- propylheptyls acrylate, 39 parts of tetrahydrofurans are weighed
Acrylate, 120 parts of Isooctyl acrylate monomers and 9 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 83r/min,
30min is reacted under the conditions of 46 DEG C of maintenance system temperature, through 3000W high voltage mercury lamp radiation 1s, that is, obtains acrylate；
(5), 100 parts of acrylates, 36 parts of modified polyurethane resins, 41 parts of (3- sulfydryls of 1,4- butanediols two are weighed
Acrylic acid) modified raw rubber, 16 parts of liquid rosin glyceride, 31 parts of aerosils, 9 parts of methylene diacrylamides, 19 parts
Modified SEBS, 46 parts of emulsifying agent SE-10N, 10 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 58r/min, dimension
Hold and react 35min under the conditions of 51 DEG C of system temperature, through 3000W high voltage mercury lamp radiation 2s, that is, obtain water-fastness multipurpose and arbitrarily paste.
Embodiment 4
A kind of water-fastness multipurpose is arbitrarily pasted, and its preparation method comprises the following steps：
(1), 100 parts of SEBS, 87 parts of acrylic acid, 10 parts of aluminium chloride, 15 parts of iron chloride and 165 parts of dimethylformamides are weighed
Be added in reactor, low whipping speed 90r/min, 4h reacted under the conditions of 90 DEG C of maintenance system temperature, product through 125 DEG C ,-
0.06MPa is evaporated under reduced pressure 0.5h, is washed 3 times through 500mL water washings 3 times, 500mL ethanol, 75 DEG C, -0.05MPa vacuum drying
15min, obtains modified SEBS；
(2), 100 parts of raw rubbers, 15 parts of 1,4- butanediols two (3- sulfydryls acrylic acid), 10 parts of (3- mercaptos of ethylene glycol two are weighed
Base acrylic acid) and 15 parts of active powdered carbons be added in high-speed mixer, low whipping speed 700r/min, maintenance system temperature 95
7min is reacted under the conditions of DEG C, 1,4-butanediol two (3- sulfydryls acrylic acid) is obtained and is modified raw rubber；
(3), 50 parts of toluene di-isocyanate(TDI)s, 10 parts of 1,4- butanediols, 109 parts of 8000,320 parts of Polyol X are weighed
Voranol 8000LM and 0.3 part of dibutyltin dilaurate are added in reaction kettle, low whipping speed 80r/min, dimension
Hold and react 2.5h under the conditions of 95 DEG C of system temperature, after reaction kettle is cooled to 50 DEG C, 15 parts of acrylamides are added to reaction kettle
In, 10min is reacted under the conditions of 50 DEG C of maintenance, 60r/min, that is, obtains modified polyurethane resin；
(4), 70 parts of triisopropylsilyl acrylate, 46 parts of 2- propylheptyls acrylate, 37 parts of tetrahydrofurans are weighed
Acrylate, 108 parts of Isooctyl acrylate monomers and 6 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 80r/min,
18min is reacted under the conditions of 43 DEG C of maintenance system temperature, through 1000W high voltage mercury lamp radiation 4s, that is, obtains acrylate；
(5), 100 parts of acrylates, 27 parts of modified polyurethane resins, 29 parts of (3- sulfydryls of 1,4- butanediols two are weighed
Acrylic acid) modified raw rubber, 9 parts of liquid rosin glyceride, 19 parts of aerosils, 8 parts of methylene diacrylamides, 17 parts change
Property SEBS, 41 parts of emulsifying agent SE-10N, 9 parts of benzoin methyl ethers be added in reaction kettle, low whipping speed 55r/min, maintains
30min is reacted under the conditions of 50 DEG C of system temperature, through 1000W high voltage mercury lamp radiation 8s, that is, water-fastness multipurpose is obtained and arbitrarily pastes.
Embodiment 5
A kind of water-fastness multipurpose is arbitrarily pasted, and its preparation method comprises the following steps：
(1), 100 parts of SEBS, 88 parts of acrylic acid, 11 parts of aluminium chloride, 13 parts of iron chloride and 173 parts of dimethylformamides are weighed
Be added in reactor, low whipping speed 89r/min, 3h reacted under the conditions of 87 DEG C of maintenance system temperature, product through 125 DEG C ,-
0.06MPa is evaporated under reduced pressure 0.5h, is washed 3 times through 500mL water washings 3 times, 500mL ethanol, 75 DEG C, -0.05MPa vacuum drying
15min, obtains modified SEBS；
(2), 100 parts of raw rubbers, 16 parts of 1,4- butanediols two (3- sulfydryls acrylic acid), 14 parts of (3- mercaptos of ethylene glycol two are weighed
Base acrylic acid) and 16 parts of active powdered carbons be added in high-speed mixer, low whipping speed 700r/min, maintenance system temperature
9min is reacted under the conditions of 102 DEG C, 1,4-butanediol two (3- sulfydryls acrylic acid) is obtained and is modified raw rubber；
(3), 50 parts of toluene di-isocyanate(TDI)s, 11 parts of 1,4- butanediols, 157 parts of 8000,280 parts of Polyol X are weighed
Voranol 8000LM and 0.5 part of dibutyltin dilaurate are added in reaction kettle, low whipping speed 83r/min, dimension
Hold and react 1.9h under the conditions of 86 DEG C of system temperature, after reaction kettle is cooled to 50 DEG C, 16 parts of acrylamides are added to reaction kettle
In, 10min is reacted under the conditions of 50 DEG C of maintenance, 60r/min, that is, obtains modified polyurethane resin；
(4), 70 parts of triisopropylsilyl acrylate, 53 parts of 2- propylheptyls acrylate, 34 parts of tetrahydrofurans are weighed
Acrylate, 117 parts of Isooctyl acrylate monomers and 7 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 81r/min,
18min is reacted under the conditions of 38 DEG C of maintenance system temperature, through 2000W high voltage mercury lamp radiation 3s, that is, obtains acrylate；
(5), 100 parts of acrylates, 33 parts of modified polyurethane resins, 37 parts of (3- sulfydryls of 1,4- butanediols two are weighed
Acrylic acid) modified raw rubber, 14 parts of liquid rosin glyceride, 19 parts of aerosils, 8 parts of methylene diacrylamides, 15 parts
Modified SEBS, 37 parts of emulsifying agent SE-10N, 5 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 51r/min, dimension
Hold and react 32min under the conditions of 46 DEG C of system temperature, through 3000W high voltage mercury lamp radiation 3s, that is, obtain water-fastness multipurpose and arbitrarily paste.
Embodiment 6
A kind of water-fastness multipurpose is arbitrarily pasted, and its preparation method comprises the following steps：
(1), 100 parts of SEBS, 93 parts of acrylic acid, 14 parts of aluminium chloride, 13 parts of iron chloride and 178 parts of dimethylformamides are weighed
It is added in reactor, low whipping speed 98r/min, reacts 3.5h under the conditions of 89 DEG C of maintenance system temperature, product is through 125
DEG C, -0.06MPa vacuum distillation 0.5h, 3 times are washed through 500mL water washings 3 times, 500mL ethanol, 75 DEG C, -0.05MPa vacuum does
Dry 15min, obtains modified SEBS；
(2), 100 parts of raw rubbers, 17 parts of 1,4- butanediols two (3- sulfydryls acrylic acid), 13 parts of (3- mercaptos of ethylene glycol two are weighed
Base acrylic acid) and 16 parts of active powdered carbons be added in high-speed mixer, low whipping speed 750r/min, maintenance system temperature
7min is reacted under the conditions of 101 DEG C, 1,4-butanediol two (3- sulfydryls acrylic acid) is obtained and is modified raw rubber；
(3), 50 parts of toluene di-isocyanate(TDI)s, 12 parts of 1,4- butanediols, 178 parts of 8000,237 parts of Polyol X are weighed
Voranol 8000LM and 0.3 part of dibutyltin dilaurate are added in reaction kettle, are 87r/min by mixing speed, dimension
Hold and react 2h under the conditions of 96 DEG C of system temperature, after reaction kettle is cooled to 50 DEG C, 19 parts of acrylamides are added in reaction kettle,
10min is reacted under the conditions of 50 DEG C of maintenance, 60r/min, that is, obtains modified polyurethane resin；
(4), 70 parts of triisopropylsilyl acrylate, 50 parts of 2- propylheptyls acrylate, 35 parts of tetrahydrofurans are weighed
Acrylate, 115 parts of Isooctyl acrylate monomers and 5 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 80r/min,
23min is reacted under the conditions of 38 DEG C of maintenance system temperature, through 1000W high voltage mercury lamp radiation 5s, that is, obtains acrylate；
(5), 100 parts of acrylates, 33 parts of modified polyurethane resins, 39 parts of (3- sulfydryls of 1,4- butanediols two are weighed
Acrylic acid) modified raw rubber, 11 parts of liquid rosin glyceride, 27 parts of aerosils, 6 parts of methylene diacrylamides, 18 parts
Modified SEBS, 34 parts of emulsifying agent SE-10N, 8 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 52r/min, dimension
Hold and react 33min under the conditions of 41 DEG C of system temperature, through 2000W high voltage mercury lamp radiation 6s, that is, obtain water-fastness multipurpose and arbitrarily paste.
Embodiment 7
A kind of water-fastness multipurpose is arbitrarily pasted, and its preparation method comprises the following steps：
(1), 100 parts of SEBS, 91 parts of acrylic acid, 9 parts of aluminium chloride, 14 parts of iron chloride and 168 parts of dimethylformamides are weighed
It is added in reactor, low whipping speed 100r/min, reacts 4.5h under the conditions of 102 DEG C of maintenance system temperature, product is through 125
DEG C, -0.06MPa vacuum distillation 0.5h, 3 times are washed through 500mL water washings 3 times, 500mL ethanol, 75 DEG C, -0.05MPa vacuum does
Dry 15min, obtains modified SEBS；
(2), 100 parts of raw rubbers, 18 parts of 1,4- butanediols two (3- sulfydryls acrylic acid), 17 parts of (3- mercaptos of ethylene glycol two are weighed
Base acrylic acid) and 23 parts of active powdered carbons be added in high-speed mixer, low whipping speed 770r/min, maintenance system temperature 96
7min is reacted under the conditions of DEG C, 1,4-butanediol two (3- sulfydryls acrylic acid) is obtained and is modified raw rubber；
(3), 50 parts of toluene di-isocyanate(TDI)s, 10 parts of 1,4- butanediols, 179 parts of 8000,245 parts of Polyol X are weighed
Voranol 8000LM and 0.4 part of dibutyltin dilaurate are added in reaction kettle, low whipping speed 88r/min, dimension
Hold and react 2h under the conditions of 89 DEG C of system temperature, after reaction kettle is cooled to 50 DEG C, 17 parts of acrylamides are added in reaction kettle,
10min is reacted under the conditions of 50 DEG C of maintenance, 60r/min, that is, obtains modified polyurethane resin；
(4), 70 parts of triisopropylsilyl acrylate, 47 parts of 2- propylheptyls acrylate, 36 parts of tetrahydrofurans are weighed
Acrylate, 112 parts of Isooctyl acrylate monomers and 4 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 77r/min,
26min is reacted under the conditions of 39 DEG C of maintenance system temperature, through 2000W high voltage mercury lamp radiation 6s, that is, obtains acrylate；
(5), 100 parts of acrylates, 29 parts of modified polyurethane resins, 38 parts of (3- sulfydryls of 1,4- butanediols two are weighed
Acrylic acid) modified raw rubber, 13 parts of liquid rosin glyceride, 26 parts of aerosils, 7 parts of methylene diacrylamides, 14 parts
Modified SEBS, 37 parts of emulsifying agent SE-10N, 6 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 55r/min, dimension
Hold and react 30min under the conditions of 44 DEG C of system temperature, through 3000W high voltage mercury lamp radiation 5s, that is, obtain water-fastness multipurpose and arbitrarily paste.
Embodiment 8
A kind of water-fastness multipurpose is arbitrarily pasted, and its preparation method comprises the following steps：
(1), 100 parts of SEBS, 90 parts of acrylic acid, 13 parts of aluminium chloride, 14 parts of iron chloride and 181 parts of dimethylformamides are weighed
It is added in reactor, low whipping speed 100r/min, reacts 4h under the conditions of 102 DEG C of maintenance system temperature, product is through 125
DEG C, -0.06MPa vacuum distillation 0.5h, 3 times are washed through 500mL water washings 3 times, 500mL ethanol, 75 DEG C, -0.05MPa vacuum does
Dry 15min, obtains modified SEBS；
(2), 100 parts of raw rubbers, 17 parts of 1,4- butanediols two (3- sulfydryls acrylic acid), 17 parts of (3- mercaptos of ethylene glycol two are weighed
Base acrylic acid) and 25 parts of active powdered carbons be added in high-speed mixer, low whipping speed 780r/min, maintenance system temperature 95
7min is reacted under the conditions of DEG C, 1,4-butanediol two (3- sulfydryls acrylic acid) is obtained and is modified raw rubber；
(3), 50 parts of toluene di-isocyanate(TDI)s, 10 parts of 1,4- butanediols, 236 parts of 8000,237 parts of Polyol X are weighed
Voranol 8000LM and 0.5 part of dibutyltin dilaurate are added in reaction kettle, low whipping speed 87r/min, dimension
Hold and react 2.7h under the conditions of 91 DEG C of system temperature, after reaction kettle is cooled to 50 DEG C, 20 parts of acrylamides are added to reaction kettle
In, 10min is reacted under the conditions of 50 DEG C of maintenance, 60r/min, that is, obtains modified polyurethane resin；
(4), 70 parts of triisopropylsilyl acrylate, 47 parts of 2- propylheptyls acrylate, 36 parts of tetrahydrofurans are weighed
Acrylate, 109 parts of Isooctyl acrylate monomers and 7 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 80r/min,
26min is reacted under the conditions of 41 DEG C of maintenance system temperature, through 3000W high voltage mercury lamp radiation 4s, that is, obtains acrylate；
(5), 100 parts of acrylates, 33 parts of modified polyurethane resins, 33 parts of (3- sulfydryls of 1,4- butanediols two are weighed
Acrylic acid) modified raw rubber, 12 parts of liquid rosin glyceride, 24 parts of aerosils, 8 parts of methylene diacrylamides, 17 parts
Modified SEBS, 36 parts of emulsifying agent SE-10N, 8 parts of benzoin methyl ethers are added in reaction kettle, low whipping speed 52r/min, dimension
Hold and react 35min under the conditions of 41 DEG C of system temperature, through 3000W high voltage mercury lamp radiation 6s, that is, obtain water-fastness multipurpose and arbitrarily paste.
So note can be applied in plastics, rubber, fiber, timber, metal, leather, cloth, wall, ceramic tile obtained by embodiment 1-8
Deng surface, any trace is will not leave behind after tearing from these material surfaces, and can be reused；Energy after random patch is cleaned with clear water
Recover original adhesive property, when arbitrarily pollutant occurs in patch surface, can be lived again by the method that clear water cleans.
Reference examples 1
In this reference examples, modified SEBS is not added, other components and preparation method are same as Example 1.
Reference examples 2
In this reference examples, 1,4-butanediol two (3- sulfydryls acrylic acid) is not added and is modified raw rubber, other components are with preparing
Method is same as Example 1.
Reference examples 3
In this reference examples, modified polyurethane resin is not added, other components and preparation method are same as Example 1.
Reference examples 4
In this reference examples, acrylate is not added, other components and preparation method are same as Example 1.
Reference examples 5
In this reference examples, adding liquid rosin glycerides, other components and preparation method be not same as Example 1.
Reference examples 6
In this reference examples, aerosil is not added, other components and preparation method are same as Example 1.
Reference examples 7
In this reference examples, methylene diacrylamide is not added, other components and preparation method are same as Example 1.
Reference examples 8
In this reference examples, emulsifying agent SE-10N is not added, and other components and preparation method are same as Example 1.
Reference examples 9
The modified SEBS in common SEBS alternate embodiments 1, other components and preparation side are selected in this reference examples, in formula
Method is same as Example 1.
Reference examples 10
(the 3- sulfydryl propylene of 1,4-butanediol two in common raw rubber alternate embodiment 1 is selected in this reference examples, in formula
Acid) raw rubber is modified, other components and preparation method are same as Example 1.
Reference examples 11
The modified polyurethane resin in common polyurethane resin alternate embodiment 1 is selected in this reference examples, in formula, it is other
Component is same as Example 1 with preparation method.
Reference examples 12
The acrylate in common acrylate resin alternate embodiment 1 is selected in this reference examples, in formula, it is other
Component is same as Example 1 with preparation method.
Tack is tested by GB/T 4852-2002 standards；
Viscosity is held to be tested by GB/T 2792-2014 standards；
The performance parameter that water-fastness multipurpose made from 1 embodiment 1~8 of table is arbitrarily pasted
The performance parameter that water-fastness multipurpose made from 2 embodiment 1 of table and reference examples 1~12 is arbitrarily pasted
Claims (10)
1. a kind of water-fastness multipurpose is arbitrarily pasted, it is characterised in that：Its raw material components includes：Acrylate, modified poly- ammonia
Ester resin, 1,4- butanediols two (3- sulfydryls acrylic acid) are modified raw rubber, liquid rosin glyceride, aerosil, methene
Bisacrylamide, modified SEBS, emulsifying agent SE-10N and benzoin methyl ether, wherein, acrylate, modified polyurethane tree
Fat, 1,4- butanediols two (3- sulfydryls acrylic acid) are modified raw rubber, liquid rosin glyceride, aerosil, methene double third
Acrylamide, modified SEBS, the mass ratio of emulsifying agent SE-10N and benzoin methyl ether are 100：23~36：27~41：7~16：18
~31：2~9：13~19：29~46：3~10.
2. water-fastness multipurpose as claimed in claim 1 is arbitrarily pasted, it is characterised in that：Acrylate is by triisopropyl silicon
Base acrylate, 2- propylheptyls acrylate, tetrahydrofuran acrylate, Isooctyl acrylate monomer and benzoin methyl ether reaction system
, wherein, triisopropylsilyl acrylate, 2- propylheptyls acrylate, tetrahydrofuran acrylate, Isooctyl acrylate monomer
Mass ratio with benzoin methyl ether is 70：41~56：32~39：105~120：2~9.
3. water-fastness multipurpose as claimed in claim 1 or 2 is arbitrarily pasted, it is characterised in that：Modified polyurethane resin is by toluene
Diisocyanate, 1,4- butanediols, Polyol X 8000, Voranol 8000LM, dibutyltin dilaurate and acryloyl
Amine reaction is made, wherein, toluene di-isocyanate(TDI), 1,4-butanediol, Polyol X 8000, Voranol8000LM, dibutyl
The mass ratio of tin dilaurate and acrylamide is 50：9~13：104~259：110~320：0.1~0.6：12~21.
4. water-fastness multipurpose as claimed in claim 1 or 2 is arbitrarily pasted, it is characterised in that：(the 3- sulfydryls third of 1,4- butanediols two
Olefin(e) acid) raw rubber is modified by raw rubber, 1,4- butanediols two (3- sulfydryls acrylic acid), ethylene glycol two (3- sulfydryls acrylic acid) and is lived
Property powdered carbon reaction be made, wherein, raw rubber, 1,4-butanediol two (3- sulfydryls acrylic acid), ethylene glycol two (3- sulfydryls acrylic acid)
Mass ratio with active powdered carbon is 100：12~20：8~19：13~27；The mesh number of active powdered carbon is 1250 mesh.
5. water-fastness multipurpose as claimed in claim 1 or 2 is arbitrarily pasted, it is characterised in that：Modified SEBS is by SEBS, propylene
Acid, aluminium chloride, iron chloride and dimethylformamide reaction are made, wherein, SEBS, acrylic acid, aluminium chloride, iron chloride and dimethyl
The mass ratio of formamide is 100：85~97：7~15：9~16：150~185.
6. the preparation method that the water-fastness multipurpose described in claim 1-5 any one is arbitrarily pasted, it is characterised in that：By propylene
Acid ester resin, modified polyurethane resin, 1,4- butanediols two (3- sulfydryls acrylic acid) be modified raw rubber, liquid rosin glyceride,
Aerosil, methylene diacrylamide, modified SEBS, emulsifying agent SE-10N and benzoin methyl ether are according to mass ratio 100：23
~36：27~41：7~16：18~31：2~9：13~19：29~46：3~10 are added in reaction kettle, and low whipping speed is
43~58r/min, temperature react 19~35min under conditions of being 39~51 DEG C, through 1000~3000W high voltage mercury lamp radiations 2~
9s, that is, obtain water-fastness multipurpose and arbitrarily paste.
7. preparation method as claimed in claim 6, it is characterised in that：The preparation method of modified SEBS is：By SEBS, propylene
Acid, aluminium chloride, iron chloride and dimethylformamide are 100 according to mass ratio：85~97：7~15：9~16：150~185 add
Into reactor, 2~5h, product warp are reacted under conditions of low whipping speed is 86~105r/min, temperature is 85~108 DEG C
125 DEG C, -0.06MPa vacuum distillation 0.5h, then wash 3 times through water washing 3 times, ethanol successively, 75 DEG C, -0.05MPa vacuum does
Dry 15min, obtains modified SEBS.
8. preparation method as claimed in claims 6 or 7, it is characterised in that：1,4- butanediols two (3- sulfydryls acrylic acid) are modified
The preparation method of raw rubber is：By raw rubber, 1,4- butanediols two (3- sulfydryls acrylic acid), ethylene glycol two (3- sulfydryls acrylic acid)
With active powdered carbon according to mass ratio 100：12~20：8~19：13~27 are added in high-speed mixer, low whipping speed 600
~800r/min, temperature react 5~10min under conditions of being 90~105 DEG C, obtain 1,4-butanediol two (3- sulfydryls acrylic acid)
Modified raw rubber.
9. preparation method as claimed in claims 6 or 7, it is characterised in that：The preparation method of modified polyurethane resin is：By first
Phenylene diisocyanate, 1,4- butanediols, Polyol X 8000, Voranol 8000LM and dibutyltin dilaurate add
Into reaction kettle, 1.5~3h is reacted under conditions of low whipping speed is 75~96r/min, temperature is 85~98 DEG C, then will be anti-
Answer kettle to be cooled to 50 DEG C, acrylamide is added into reaction kettle, 10min is reacted under the conditions of 50 DEG C of maintenance, 60r/min, that is, obtains
Modified polyurethane resin, wherein, toluene di-isocyanate(TDI), 1,4-butanediol, Polyol X 8000, Voranol 8000LM, two
The mass ratio of butyl tin dilaurate and acrylamide is 50：9~13：104~259：110~320：0.1~0.6：12~
21。
10. preparation method as claimed in claims 6 or 7, it is characterised in that：The preparation method of acrylate is：By three
Isopropyl silicon substrate acrylate, 2- propylheptyls acrylate, tetrahydrofuran acrylate, Isooctyl acrylate monomer and styrax first
Ether is according to mass ratio 70：41~56：32~39：105~120：2~9 are added in reaction kettle, and low whipping speed is 67~83r/
Min, temperature react 15~30min under conditions of being 37~46 DEG C, through 1000~3000W, 1~7s of high voltage mercury lamp radiation, that is, obtain
Acrylate.
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