CN107987796A - Energy-saving environment protection mixed refrigerant and preparation method thereof - Google Patents
Energy-saving environment protection mixed refrigerant and preparation method thereof Download PDFInfo
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- CN107987796A CN107987796A CN201711127568.XA CN201711127568A CN107987796A CN 107987796 A CN107987796 A CN 107987796A CN 201711127568 A CN201711127568 A CN 201711127568A CN 107987796 A CN107987796 A CN 107987796A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M131/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen
- C10M131/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen containing carbon, hydrogen and halogen only
- C10M131/04—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing halogen containing carbon, hydrogen and halogen only aliphatic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M171/00—Lubricating compositions characterised by purely physical criteria, e.g. containing as base-material, thickener or additive, ingredients which are characterised exclusively by their numerically specified physical properties, i.e. containing ingredients which are physically well-defined but for which the chemical nature is either unspecified or only very vaguely indicated
- C10M171/008—Lubricant compositions compatible with refrigerants
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/22—All components of a mixture being fluoro compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/32—The mixture being azeotropic
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
- C10M2211/022—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only aliphatic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
- C10N2020/09—Characteristics associated with water
- C10N2020/097—Refrigerants
- C10N2020/101—Containing Hydrofluorocarbons
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/30—Refrigerators lubricants or compressors lubricants
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
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- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
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- Materials Engineering (AREA)
- Lubricants (AREA)
Abstract
A kind of energy-saving environment protection mixed refrigerant, by the CH that percentage by weight is 3 60%2FCF3(R134a) and 97 40% CHF2CF3(R125) form.The mix refrigerant preparation method, comprises the following steps:A. stirring container is evacuated to deeper vacuum；B. the CH for meeting weight ratio is added2FCF3；C. the CHF for meeting weight ratio is added2CF3；D. by container Stirring 0.2 2 it is small when；E. dispense.Wooden advantageous effect of the invention is:Absolutely without " fluorine " (CFC, HCFC):CFC or HCFC can be directly replaced, nothing needs to change any existing refrigeration plant, it is not required that special lubricating oil for maintenance；Energy Efficiency Ratio is high, can be energy saving by 12.5% to 25% than conventional refrigerants.It the method can be widely used in:Air-conditioning system, cold drink equipment, refrigeration transportation cabinet, refrigerating chamber, the cabinet that keeps in cold storage, the storage system of supermarket, the refrigerator of bakery and large-scale iced chamber etc..
Description
Technical field
The present invention relates to a kind of refrigerant, more particularly to a kind of energy-saving environment protection mixed refrigerant and preparation method thereof.
Background technology
It is well known that the ozone layer in earth overhead just uses pernicious gas days such as " freon " (CFC, HCFC) multiple one by the mankind
Day it is lost, seriously endangers the mankind and various biological existence.In the prior art, an atmosphere difluoromethane (CHClF2, R22) and
R502 (azeotropic mixture being made of R22 and Rll5) has been widely used as the system in air-conditioning, refrigerator, refrigerator etc refrigerating plant
Cryogen；Meanwhile halogenated hydrocarbons is also widely used in the fields such as fire-fighting, cleaning, production foamed polymer.
In recent years, EU countries disables one after another various contains " fluorine " (CFC, HCFC) preparation.In China, State Council also ratifies reality
Shi Liao《China is phased out ozone depleting substances national scheme》, in this scheme, clear stipulaties all trades and professions should be
Stopped using before in July, 2007 and various contain " fluorine " (CFC, HCFC) refrigerant.Therefore, numerous scientific workers, are engaged in refrigeration work
The engineers and technicians of journey technological development research just put into a large amount of man power and materials, find better performances and to atmospheric ozone layer without
The novel refrigerant of destruction, and require to can be suitably used for refrigeration plant and parts.Through developmental research for many years, it was found that one
A little refrigerant materials, but be all difficult to solely be used as mono- 22 substitutes of R, then, the numerous and confused research and development for putting into Diversity refrigerant.
For environmental protection refrigerant currently on the market, have a disadvantage that:
One Rl 34A (CH2FCF of first generation environmental protection refrigerant:), it is a kind of environmental protection refrigerant in transition period.It has will not
The advantages of destroying earth's ozone layer；But its shortcomings that, is:1st, Energy Efficiency Ratio is very low, and compared with using CFC, it can increase energy consumption
40%；2nd, existing compressor and hot channel, must be reequiped using Rl 34A, increases production cost.
Second generation environmental protection refrigerant-R407C, R410A, although they and 100% nothing " fluorine " (CFC, HCFC), necessary
Used on it have changed compressor and hot channel, and the lubricating oil for maintenance of special expensive must be used.Energy Efficiency Ratio is with fluorine
Leon is close.
Because before this, the refrigeration unit of most of air-conditioning and refrigeration all uses systems of the R12 or R22 containing CFC or HCFC
Agent.If using the refrigerant of the first generation (R134A) or the second generation (R407C, R410A) instead, new engine just must be reequiped or former
The capacity for having machine reduces.Then, it is badly in need of finding one kind and meeting world's environmental requirement now, can also continue to use original dress
It is standby, it is not necessary to spend the cost added, can more achieve the purpose that environmentally friendly mixed type refrigerant in a short period of time.
The content of the invention
The present invention provides a kind of energy conservation and environmental protection to make up the above-mentioned deficiency of the prior art, does not destroy ozone layer, does not produce
The mix refrigerant that greenhouse effects simultaneously can be used instead directly on existing refrigeration machine.
The present invention solve the above problems used by technical solution be:A kind of energy-saving environment protection mixed refrigerant is provided, should
CH of the mix refrigerant by percentage by weight for 3-60%2FCF3With the CH of 97-40%2FCF3Composition.
A preferred embodiment of energy-saving environment protection mixed refrigerant, the mix refrigerant are by percentage by weight according to the present invention
The CH of 10-18%2FCF3With the CH of 90-82%2FCF3Composition.
A preferred embodiment of energy-saving environment protection mixed refrigerant, the mix refrigerant are by percentage by weight according to the present invention
The CH of 38-46%2FCF3With the CH of 62-54%2FCF3Composition.
A preferred embodiment of energy-saving environment protection mixed refrigerant, the mix refrigerant are also blended with weight ratio according to the present invention
For the lubricating oil of 0.3-2.2%.
The preparation method of energy-saving environment protection mixed refrigerant according to the present invention, it is characterised in that:
A:Stirring container is evacuated to deeper vacuum；
C:Add the CH for meeting weight ratio2FCF3；
D:Add the CH for meeting weight ratio2FCF3；
E:By container Stirring 0.2-2 it is small when；
F:Packing.
The preparation method of energy-saving environment protection mixed refrigerant according to the present invention, it is characterised in that:Including step B:Add 0.3-
2.2% lubricating oil.
The preparation method of energy-saving environment protection mixed refrigerant according to the present invention, it is characterised in that:Container Stirring in step E
Time is 1.5, Bu Shi.
The preparation method of energy-saving environment protection mixed refrigerant according to the present invention, it is characterised in that:Step F includes following substep
Suddenly:
Fl, be sufficiently stirred rear undelayed, and semi-finished product by the gross are directly dispensed as early as possible；Packing delay, turn to perform fZ；
Before f2, packing, when stirring 0.21.3 is small again, cylinder of steel is rolled after filling, is sufficiently mixed it.
In the present invention:C tramples CH2FCF3(R 1 34a)、CH2FCF3(R125) Ozone Depletion Potential ODP is 0, no
Ozone layer can be destroyed.In the present invention, suitable CH2FCF3(Rl 34a) and CH2FCF3(R 1 25) mixing after, become R42IA or
R42lB, is the mixture of azeotropic, no longer separates.The present invention in performance, as adiabatic condensation temperature under boiling point, critical-temperature, 375 pas,
The value of refrigerating capacity etc. is all approached with R-22, and required lubricator is also identical.The present invention can not redesign or reequip it is existing cold
R-22 is substituted under conditions of jelly system comprehensively, compared to the energy that R-22 can also save 12.5-25%.
Compared with the second generation (R407C, R410A) refrigerant, it is advantageous in that the present invention:
Compared with the second generation (R407C, R410A) refrigerant, it is advantageous in that the present invention:Consumption rate is less than R-
407C10%:The pressure of required compressor is less than R-407C.
The present invention is heat-resisting azeotropic mixture, is sent out with being stored in transport in cylinder in the state of liquid in any refrigeration system
In the case of raw leakage, it refrigerant of the present invention can be used directly to add, systemic-function do not influenced.
The present invention is used as a kind of efficient refrigerant, and a most obvious efficiency is that temperature is higher, and refrigerating capacity is higher.This
Invention from 3 DEG C or so of butter and the storage temperature of fruit, to -30 DEG C of medium storage temperature under all operational excellences；The present invention
Compressor can also be started when -40 DEG C, in the winter time using Teat pump boiler when it is particularly practical.Many examples show, make
Worked with the compressor of the present invention under lower cryogenic temperature, the maximum operational efficiency for reaching pointed can be approached.The present invention
It is the refrigerant being particularly suitable for be had been found in terms of refrigeration.
The present invention has drawn the experience in first and second generation, has both been environmental protection refrigerant, more can substitute R12 or R22 immediately and
It is not required to that original machine is replaced or changed.The present invention not only conforms to world's environmental requirement, can also continue to use original equipment,
The cost added need not be spent, can more achieve the purpose that environmental protection in a short period of time.
It is of the invention to be advantageous in that relative to the prior art:Absolutely without " fluorine " (CFC, HCFC).
It is of the invention to be advantageous in that relative to the prior art:CFC or HCFC can be directly replaced, it is any without needing to change
Existing refrigeration plant, it is not required that special lubricating oil for maintenance.
It is of the invention to be advantageous in that relative to the prior art:Energy Efficiency Ratio is high, it was proved that, it compares conventional refrigeration
Agent energy energy saving 12.5% to 25%.
It the method can be widely used in:Air-conditioning system, cold drink equipment, refrigeration transportation cabinet, refrigerating chamber, keep in cold storage refuse, supermarket
Storage system, the cold of bakery refuse and large-scale iced chamber etc..
In conclusion energy-saving environment protection mixed refrigerant of the present invention possesses state-of-the art technology, use cost can saved
Premise is issued to the purpose of environmental protection, is the scheme for being easiest to be esthetically acceptable to the consumers.
Embodiment
With reference to embodiment, the present invention will be described.
Embodiment 1.
The present invention is a kind of energy-saving environment protection mixed refrigerant, the CH preferably by percentage by weight for 10-18%2FCF3And 90-
82% CH2FCF3Composition.
A kind of energy-saving environment protection mixed refrigerant of the present invention, preferably admixes the lubricating oil that weight ratio is 0.3-2.2%.
A kind of preparation method of energy-saving environment protection mixed refrigerant of the present invention, it is characterised in that:
A:Stirring container is evacuated to deeper vacuum；
B:Add the lubricating oil of 0.3-2.2%:
C:Add the CH of 10-18%2FCF3
D:Add the CH of 90-82%2FCF3；
E:By container Stirring 1.5 it is small when；
F:Packing.During packing, it is sufficiently stirred rear undelayed, semi-finished product by the gross is directly dispensed as early as possible；Packing delay,
Before packing, 0.2-1.3 is stirred again, hour, rolls cylinder of steel after filling, be sufficiently mixed it.
A kind of preparation method of energy-saving environment protection mixed refrigerant of the present invention, can be described as:Stirring container is first evacuated to depth
Vacuum；Sequentially add lubricating oil, the CH of 10-18% that weight ratio is 0.3-2.2%2FCF3After the C of 90-82% any ZCr3:Will
When container Stirring 1.5 is small；Dispense immediately.If packing delay, before packing, when stirring 0.2-1.3 is small again, rolled after filling
Dynamic cylinder of steel, is sufficiently mixed it.
Packing instructions:Tighten, 25b dot9mil steel plates, 260psi pressure.
In the present invention, CH2FCF3(RI 34a) and CH2FCF3(R125) after mixing, become R421B, be the mixing of azeotropic
Thing, no longer separates.
The mix refrigerant is primarily adapted for use in professional refrigerator and uses.
Embodiment 2.
The present invention is a kind of energy-saving environment protection mixed refrigerant, the CH preferably by percentage by weight for 38-46%2FCF3And 62-
54% CH2FCF3Composition.
A kind of energy-saving environment protection mixed refrigerant of the present invention, preferably admixes the lubricating oil that weight ratio is 0.3-2.2%.
A kind of preparation method of energy-saving environment protection mixed refrigerant of the present invention, it is characterised in that:
A:Stirring container is evacuated to deeper vacuum；
B:Add the lubricating oil of 0.3-2.2%；
C:Add the CH of 38-46%2FCF3；
D:Add the CH of 62-54%2FCF3；
E:By container Stirring 1.5, after hour；
F:Packing.During packing, it is sufficiently stirred rear undelayed, semi-finished product by the gross is directly dispensed as early as possible；Packing delay,
Before packing, when stirring 0.2-1.3 is small again, cylinder of steel is rolled after filling, is sufficiently mixed it.
A kind of preparation method of energy-saving environment protection mixed refrigerant of the present invention, can be described as:It is true that stirring container is evacuated to depth
It is empty；Sequentially add lubricating oil, the CH of 38-46% that weight ratio is 0.3-2.2%2FCF3, 62-54% CH2FCF3Afterwards:Again will
When container Stirring 1.5 is small；Dispense immediately.If packing delay, before packing, when stirring 0.2-1.3 is small again, rolled after filling
Dynamic cylinder of steel, is sufficiently mixed it.
Packing instructions:Tighten, 25b dot 9mil steel plates, 260psi pressure.
In the present invention, CH2FCF3(R134a) and CH2FCF3(R12s) after mixing, become R421A, be the mixture of azeotropic,
No longer separate.
The mix refrigerant is primarily adapted for use in general air-conditioning and uses.
Above-mentioned embodiment is only exemplary description, and those skilled in the art are not departing from the scope of the invention protected
In the case of spirit, various embodiments can be designed according to different actual needs.
Claims (8)
- A kind of 1. energy-saving environment protection mixed refrigerant, it is characterised in that:CH of the mix refrigerant by percentage by weight for 3-60%2FCF3With the CHF of 97-40%2CF3Composition.
- 2. mix refrigerant according to claim 1, it is characterised in that:CH of the mix refrigerant by percentage by weight for 10-18%2FCF3With the CHF of 90-82%ZCF3Composition.
- 3. mix refrigerant according to claim 1, it is characterised in that:CH of the mix refrigerant by percentage by weight for 38-46%2FCF3With the CHF of 62-54%2CF3Composition.
- 4. according to the mix refrigerant described in claim 1 or 2 or 3, it is characterised in that:The mix refrigerant is also blended with the lubricating oil that weight ratio is 0.3-2.20.
- 5. the mix refrigerant preparation method according to Claims 1-4, it is characterised in that:A:Stirring container is evacuated to deeper vacuum；C:Add the CH for meeting weight ratio2FCF3:D:Add the CHF for meeting weight ratio2CF3:E:By container Stirring 0.2-2 it is small when；F:Packing.
- 6. mix refrigerant preparation method according to claim 5, it is characterised in that:Further include step B:Add the lubricating oil of 0.3-2.2%.
- 7. mix refrigerant preparation method according to claim 6, it is characterised in that:When the container Stirring time is 1.5 small in step E.
- 8. mix refrigerant preparation method according to claim 7, it is characterised in that:Step F include it is following step by step:Fl, be sufficiently stirred rear undelayed, and semi-finished product by the gross are directly dispensed as early as possible；Packing delay, turn to perform f2；Before f2, packing, 0.2-1.3, Bu Shi are stirred again, cylinder of steel is rolled after filling, is sufficiently mixed it.
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| CN201711127568.XA CN107987796A (en) | 2017-11-15 | 2017-11-15 | Energy-saving environment protection mixed refrigerant and preparation method thereof |
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| CN201711127568.XA CN107987796A (en) | 2017-11-15 | 2017-11-15 | Energy-saving environment protection mixed refrigerant and preparation method thereof |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101045856A (en) * | 2006-03-31 | 2007-10-03 | 美高地科技（深圳）有限公司 | Energy-saving environment protection mixed refrigerant and preparation method thereof |
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- 2017-11-15 CN CN201711127568.XA patent/CN107987796A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101045856A (en) * | 2006-03-31 | 2007-10-03 | 美高地科技（深圳）有限公司 | Energy-saving environment protection mixed refrigerant and preparation method thereof |
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Application publication date: 20180504 |