CN107987352A - A kind of preparation method of light-high-strength stone paper - Google Patents
A kind of preparation method of light-high-strength stone paper Download PDFInfo
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- CN107987352A CN107987352A CN201711303560.4A CN201711303560A CN107987352A CN 107987352 A CN107987352 A CN 107987352A CN 201711303560 A CN201711303560 A CN 201711303560A CN 107987352 A CN107987352 A CN 107987352A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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Abstract
The present invention relates to stone paper preparing technical field, and in particular to a kind of preparation method of light-high-strength stone paper.The present invention carries out boiling by alkali and absolute ethyl alcohol to stalk crushed material first,Improve fiber plasticity and hydroxylating modification is carried out to fiber,Ball milling is coordinated to obtain polyhydroxy fibre bundle followed by the ice effect of splitting,Deposition kernel template is used as using polyhydroxy fibre bundle,Nanoscale hydrotalcite particles are produced by hydro-thermal method and are attached to polyhydroxy fibre bundle template surface,And potassium rhodanate and ammonium oxalate are added while hydro-thermal reaction,Ammonium oxalate is thermally decomposed into oxalic acid and ammonia first,Under the action of potassium rhodanate,So that the metal ion in hydrotalcite leaves original lattice position and enters oxalic acid organic phase,So as to produce hole on hydrotalcite lattice,Improve the adsorption activity of hydrotalcite,Finally calcining removes polyhydroxy fibre bundle kernel,Obtain the hollow nano hydrotalcite of high adsorption activity,Last and polyethylene blend,Matter light high-intensity stone paper is made.
Description
Technical field
The present invention relates to stone paper preparing technical field, and in particular to a kind of preparation method of light-high-strength stone paper.
Background technology
With the continuous enhancing of global low-carbon environment-friendly consciousness, people are directed to researching and developing environmentally protective material more and more
Material, stone paper at home and abroad gradually receive attention and development as a kind of novel environment friendly synthetic paper.The primary raw material of stone paper
For a large amount of stone powder, a small amount of resin and some auxiliary agents, through by these primary raw materials and mixing, is modified, being granulated, extruding, stretching
Stone paper is can be made into etc. technique.Stone paper have tensile strength is big, folding damage resistibility can it is good, tearing strength is high, water-fast, resistance to
Oil, chemical resistance protrude, non-aging, be not afraid of the excellent performance such as damage by worms, and all determine that stone paper is led in packaging material
Domain possesses more wide application space.
Go into operation currently on the market and promoted the use of stone paper, it is in journalism field, cultural paper, map, wall
Paper etc. has obtained preferable application, but according to the analysis of manufacturer, the weight ratio common plant of stone paper is fine at present
Dimension paper is big by 30%~50%, and which greatly limits the application range of stone paper.
In addition stone paper is one kind with organic polymer（Mainly polyolefin）It is primary raw material with inorganic filler, addition is few
Measure synthetic paper made of adjuvant.And cause stone paper there are the problem of poor compatibility between inorganic filler and organic polymer
Bond strength between raw material is not high, influences stone paper mechanical performance.The fire resistance of stone paper also needs to be further improved.
Therefore, it is made of paper to stone to invent the new stone paper of bond strength height and good flame resistance between a kind of light weight, raw material
Standby technical field has positive meaning.
The content of the invention
Present invention mainly solves technical problem, big for common stone paper weight at present, limit stone paper should
With inorganic filler and organic polymer poor compatibility in scope and stone paper material, cause stone paper bad mechanical property, and
A kind of the defects of anti-flammability is relatively low, there is provided preparation method of light-high-strength stone paper.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
A kind of preparation method of light-high-strength stone paper, it is characterised in that specifically preparation process is：
（1）Corn straw smashing is weighed, obtains stalk crushed material, by the sodium hydroxide that stalk crushed material and mass fraction are 30%
1~2h is boiled in heating after solution and absolute ethyl alcohol mixing, is separated by filtration to obtain filter residue, freezes filter residue 2 with liquid nitrogen spraying immediately
~3min, then the filter residue ball milling after freezing, excessively 100 mesh sieves, collection sieving powder are obtained into self-control polyhydroxy fibre bundle；
（2）30~40g magnesium nitrates, 28~30g aluminum nitrates, 20~25g zinc nitrates is weighed to be dissolved in 450~550mL deionized waters
Mixed solution is obtained, pre-reaction liquid is obtained after mixed solution and mass fraction are mixed for 30% ammonium hydroxide and potassium carbonate；
（3）Pre-reaction liquid is fitted into high pressure water heating kettle, then add into high pressure water heating kettle polyhydroxy fibre bundle, potassium rhodanate and
Ammonium oxalate, stirs 10~15min；
（4）Treat enclosed high pressure water heating kettle after above-mentioned stirring, heat temperature raising, hydro-thermal reaction, is separated by filtration and is precipitated, will be heavy
Shallow lake is put into Muffle furnace, and 400~600 DEG C, 2~4h of heat preservation sintering, during discharging obtains are heated to the speed of 20 DEG C/min
Empty nano hydrotalcite powder；
（5）After above-mentioned hollow nano hydrotalcite powder and ellagic acid, ursin, Rosa Damascana, dusty yeast and water are mixed
To mixed liquor, mixed liquor is fitted into fermentation tank, is sealed by fermentation, is separated by filtration to obtain fermentation filter residue, it is dry, obtain modified hollow
Nano hydrotalcite powder；
（6）Count in parts by weight, weigh the hollow nano hydrotalcite powder of 60~70 parts of above-mentioned modifications, 20~30 parts of polyethylene, 0.3
~0.5 part of neopelex and 3~5 parts of azodicarbonamides are added in kneading machine, are kneaded, are obtained batch mixing, will be upper
State batch mixing and move into extruding pelletization in double screw extruder, and cut, repaiied with 60~70 DEG C of temperature calendering formation with calender
Side, up to light-high-strength stone paper.
Step（1）Described in stalk crushed material and mass fraction be 30% sodium hydroxide solution and absolute ethyl alcohol
Mass ratio is 1:5:5.
Step（2）Described in mixed solution and mass fraction be 30% ammonium hydroxide and the mass ratio of potassium carbonate be 10:1:
1。
Step（3）Described in polyhydroxy fibre bundle addition be pre-reaction liquid quality 10%, the addition of potassium rhodanate
Measure as the 1% of pre-reaction liquid quality, the addition of ammonium oxalate is the 1% of pre-reaction liquid quality.
Step（4）Described in the pressure of hydro-thermal reaction be 1.5~1.8MPa, the temperature of heat temperature raising is 170~180
DEG C, the hydro-thermal reaction time is 25~30h.
Step（5）Described in hollow nano hydrotalcite powder and ellagic acid, ursin, Rosa Damascana, dusty yeast and
The mass ratio of water is 10:3:2:2:1:50, drying temperature is 105~110 DEG C, and drying time is 1~2h.
Step（6）Described in melting temperature be 70~80 DEG C, mixing time is 5~10min.
The beneficial effects of the invention are as follows：The present invention carries out boiling by alkali and absolute ethyl alcohol to stalk crushed material first, carries
High microsteping plasticity and to fiber carry out hydroxylating modification, followed by ice split effect coordinate ball milling obtain polyhydroxy fibre bundle, with
Polyhydroxy fibre bundle produces nanoscale hydrotalcite particles by hydro-thermal method and is attached to polyhydroxy fibre bundle as deposition kernel template
Template surface, and addition potassium rhodanate and ammonium oxalate, ammonium oxalate are thermally decomposed into oxalic acid and ammonia first while hydro-thermal reaction
Gas, under the action of potassium rhodanate so that the metal ion in hydrotalcite leaves original lattice position and enters oxalic acid organic phase,
So as to produce hole on hydrotalcite lattice, the adsorption activity of hydrotalcite is improved, finally calcining removes polyhydroxy fibre bundle kernel, obtains
To the hollow nano hydrotalcite of high adsorption activity, the nano hydrotalcite of high adsorption is improved the absorption property of polyethylene,
So that both bond strengths are improved, in addition under the action of oxalic acid, the metal ion in hollow hydrotalcite is partially activated,
Active function groups on the metal ion and polyethylene molecule of these activation form metal coordinate bond, further improve inorganic filler
Bond strength between polymer, improves compatibility between the two；
（2）The present invention also to hollow nano hydrotalcite carried out fermentation be modified, using microorganism will be enriched in Polyphenols ellagic acid,
Ursin, Rosa Damascana are degraded, and produce a large amount of free property aryls and ester group, and by the effect of microorganism by aryl
Nano hydrotalcite surface is incorporated into ester group, due to the introducing of nonpolar aryl so that nano hydrotalcite and nonpolar poly-
There is similar chemical attribute, so as to improve compatibility between the two between compound；
（3）The present invention instead of common mountain flour with hollow nano hydrotalcite and prepare stone paper, hollow powder use so that
Stone paper has lighter weight in the case of same volume, has reached the light requirement of stone paper, has widened stone paper
Application field, and hydrotalcite can decompose when burning is heated and absorb comburant surface heat to fire retardation, release at the same time
The oxygen on large quantity of moisture dilution combustion things surface is released, decomposes the activated magnesia of generation, Alumina build-up in combustible surface again
Further prevent the progress of burning, and it is whole it is fire-retardant during not only produced without any harmful substance, and its point
The product of solution can also largely absorb pernicious gas and smog caused by high molecular polymer burning fire-retardant while, constantly
Imperfect combustion fusing residue is absorbed, from elimination smog, prevention molten drop while burning is stopped quickly so that the present invention
Stone paper there is splendid flame retardant effect.
Embodiment
40~50min of corn straw smashing is weighed, obtains stalk crushed material, is 30% by stalk crushed material and mass fraction
Sodium hydroxide solution and absolute ethyl alcohol in mass ratio be 1:5:1~2h is boiled in heating after 5 mixing, is separated by filtration and is filtered
Slag, freezes 2~3min of filter residue with liquid nitrogen spraying immediately, then the filter residue after freezing is put into 1~2h of ball milling in ball mill, crosses 100
Mesh sieve, collects sieving powder and obtains self-control polyhydroxy fibre bundle；Weigh 30~40g magnesium nitrates, 28~30g aluminum nitrates, 20~25g
Zinc nitrate, which is dissolved in 450~550mL deionized waters, obtains mixed solution, by ammonium hydroxide that mixed solution and mass fraction are 30% with
And potassium carbonate is 10 in mass ratio:1:Pre-reaction liquid is obtained after 1 mixing；Pre-reaction liquid is fitted into high pressure water heating kettle, then to height
Press and the polyhydroxy fibre bundle of pre-reaction liquid quality 10%, the potassium rhodanate of pre-reaction liquid quality 1% and pre-reaction are added in water heating kettle
The ammonium oxalate of liquid quality 1%, stirs 10~15min；Enclosed high pressure water heating kettle after to be mixed, is heated under 1.5~1.8MPa
Be warming up to 170~180 DEG C, 25~30h of hydro-thermal reaction, is separated by filtration and is precipitated, precipitation is put into Muffle furnace, with 20 DEG C/
The speed of min is heated to 400~600 DEG C, 2~4h of heat preservation sintering, and discharging obtains hollow nano hydrotalcite powder；Will be hollow
Nano hydrotalcite powder and ellagic acid, ursin, Rosa Damascana, dusty yeast and water are 10 in mass ratio:3:2:2:1:50 is mixed
Mixed liquor is obtained after conjunction, mixed liquor is fitted into fermentation tank, sealing tank mouth is sealed by fermentation 7~9 days at 25~35 DEG C, filtering point
From fermentation filter residue is obtained, baking oven dry 1~2h at 105~110 DEG C is put into, obtains being modified hollow nano hydrotalcite powder；Press
Parts by weight meter, weighs the hollow nano hydrotalcite powder of 60~70 parts of modifications, 20~30 parts of polyethylene, 0.3~0.5 part of dodecane
Base benzene sulfonic acid sodium salt and 3~5 parts of azodicarbonamides are added in kneading machine, in temperature be 70~80 DEG C under the conditions of be kneaded 5~
10min, obtains batch mixing, and above-mentioned batch mixing is moved into extruding pelletization in double screw extruder, and with calender with 60~70 DEG C of temperature
Spend calendering formation, cutting, deburring, up to light-high-strength stone paper.
Example 1
Corn straw smashing 40min is weighed, obtains stalk crushed material, by the hydroxide that stalk crushed material and mass fraction are 30%
Sodium solution and absolute ethyl alcohol are 1 in mass ratio:5:1h is boiled in heating after 5 mixing, is separated by filtration to obtain filter residue, uses liquid nitrogen immediately
Spray refrigeration filter residue 2min, then the filter residue after freezing is put into ball milling 1h in ball mill, 100 mesh sieves are crossed, sieving powder is collected and obtains
To self-control polyhydroxy fibre bundle；Weigh 30g magnesium nitrates, 28g aluminum nitrates, 20g zinc nitrates and be dissolved in 450mL deionized waters and mixed
Solution is closed, is 10 in mass ratio by ammonium hydroxide and potassium carbonate that mixed solution and mass fraction are 30%:1:Obtained after 1 mixing pre-
Reaction solution；Pre-reaction liquid is fitted into high pressure water heating kettle, then the polyhydroxy of pre-reaction liquid quality 10% is added into high pressure water heating kettle
The ammonium oxalate of fibre bundle, the potassium rhodanate of pre-reaction liquid quality 1% and pre-reaction liquid quality 1%, stirs 10min；End to be mixed
Enclosed high pressure water heating kettle afterwards, is heated to 170 DEG C under 1.5MPa, and hydro-thermal reaction 25h, is separated by filtration and is precipitated, will be heavy
Shallow lake is put into Muffle furnace, is heated to 400 DEG C, heat preservation sintering 2h with the speed of 20 DEG C/min, discharging obtains hollow nanometer water
Talc powder body；It is in mass ratio by hollow nano hydrotalcite powder and ellagic acid, ursin, Rosa Damascana, dusty yeast and water
10:3:2:2:1:Mixed liquor is obtained after 50 mixing, mixed liquor is fitted into fermentation tank, sealing tank mouth is sealed by fermentation 7 at 25 DEG C
My god, it is separated by filtration to obtain fermentation filter residue, is put into baking oven dry 1h at 105 DEG C, obtains being modified hollow nano hydrotalcite powder；Press
Parts by weight meter, weighs the hollow nano hydrotalcite powder of 60 parts of modifications, 20 parts of polyethylene, 0.3 part of neopelex and 3
Part azodicarbonamide is added in kneading machine, is kneaded 5min under the conditions of being 70 DEG C in temperature, is obtained batch mixing, above-mentioned batch mixing is moved
Enter extruding pelletization in double screw extruder, and with calender with 60 DEG C of temperature calendering formation, cutting, deburring, up to lightweight height
Intensity stone paper.
Example 2
Corn straw smashing 45min is weighed, obtains stalk crushed material, by the hydroxide that stalk crushed material and mass fraction are 30%
Sodium solution and absolute ethyl alcohol are 1 in mass ratio:5:1h is boiled in heating after 5 mixing, is separated by filtration to obtain filter residue, uses liquid nitrogen immediately
Spray refrigeration filter residue 2min, then the filter residue after freezing is put into ball milling 1h in ball mill, 100 mesh sieves are crossed, sieving powder is collected and obtains
To self-control polyhydroxy fibre bundle；Weigh 35g magnesium nitrates, 29g aluminum nitrates, 23g zinc nitrates and be dissolved in 500mL deionized waters and mixed
Solution is closed, is 10 in mass ratio by ammonium hydroxide and potassium carbonate that mixed solution and mass fraction are 30%:1:Obtained after 1 mixing pre-
Reaction solution；Pre-reaction liquid is fitted into high pressure water heating kettle, then the polyhydroxy of pre-reaction liquid quality 10% is added into high pressure water heating kettle
The ammonium oxalate of fibre bundle, the potassium rhodanate of pre-reaction liquid quality 1% and pre-reaction liquid quality 1%, stirs 13min；End to be mixed
Enclosed high pressure water heating kettle afterwards, is heated to 175 DEG C under 1.7MPa, and hydro-thermal reaction 28h, is separated by filtration and is precipitated, will be heavy
Shallow lake is put into Muffle furnace, is heated to 500 DEG C, heat preservation sintering 3h with the speed of 20 DEG C/min, discharging obtains hollow nanometer water
Talc powder body；It is in mass ratio by hollow nano hydrotalcite powder and ellagic acid, ursin, Rosa Damascana, dusty yeast and water
10:3:2:2:1:Mixed liquor is obtained after 50 mixing, mixed liquor is fitted into fermentation tank, sealing tank mouth is sealed by fermentation 8 at 30 DEG C
My god, it is separated by filtration to obtain fermentation filter residue, is put into baking oven dry 1h at 108 DEG C, obtains being modified hollow nano hydrotalcite powder；Press
Parts by weight meter, weighs the hollow nano hydrotalcite powder of 65 parts of modifications, 25 parts of polyethylene, 0.4 part of neopelex and 3
~5 parts of azodicarbonamides are added in kneading machine, are kneaded 8min under the conditions of being 75 DEG C in temperature, are obtained batch mixing, will be above-mentioned mixed
Material moves into extruding pelletization in double screw extruder, and with calender with 65 DEG C of temperature calendering formation, cutting, deburring, up to light
Matter high intensity stone paper.
Example 3
Corn straw smashing 50min is weighed, obtains stalk crushed material, by the hydroxide that stalk crushed material and mass fraction are 30%
Sodium solution and absolute ethyl alcohol are 1 in mass ratio:5:2h is boiled in heating after 5 mixing, is separated by filtration to obtain filter residue, uses liquid nitrogen immediately
Spray refrigeration filter residue 3min, then the filter residue after freezing is put into ball milling 2h in ball mill, 100 mesh sieves are crossed, sieving powder is collected and obtains
To self-control polyhydroxy fibre bundle；Weigh 40g magnesium nitrates, 30g aluminum nitrates, 25g zinc nitrates and be dissolved in 550mL deionized waters and mixed
Solution is closed, is 10 in mass ratio by ammonium hydroxide and potassium carbonate that mixed solution and mass fraction are 30%:1:Obtained after 1 mixing pre-
Reaction solution；Pre-reaction liquid is fitted into high pressure water heating kettle, then the polyhydroxy of pre-reaction liquid quality 10% is added into high pressure water heating kettle
The ammonium oxalate of fibre bundle, the potassium rhodanate of pre-reaction liquid quality 1% and pre-reaction liquid quality 1%, stirs 15min；End to be mixed
Enclosed high pressure water heating kettle afterwards, is heated to 180 DEG C under 1.8MPa, and hydro-thermal reaction 30h, is separated by filtration and is precipitated, will be heavy
Shallow lake is put into Muffle furnace, is heated to 600 DEG C, heat preservation sintering 4h with the speed of 20 DEG C/min, discharging obtains hollow nanometer water
Talc powder body；It is in mass ratio by hollow nano hydrotalcite powder and ellagic acid, ursin, Rosa Damascana, dusty yeast and water
10:3:2:2:1:Mixed liquor is obtained after 50 mixing, mixed liquor is fitted into fermentation tank, sealing tank mouth is sealed by fermentation 9 at 35 DEG C
My god, it is separated by filtration to obtain fermentation filter residue, is put into baking oven dry 2h at 110 DEG C, obtains being modified hollow nano hydrotalcite powder；Press
Parts by weight meter, weighs the hollow nano hydrotalcite powder of 70 parts of modifications, 30 parts of polyethylene, 0.5 part of neopelex and 5
Part azodicarbonamide is added in kneading machine, is kneaded 10min under the conditions of being 80 DEG C in temperature, batch mixing is obtained, by above-mentioned batch mixing
Extruding pelletization in double screw extruder is moved into, and with calender with 70 DEG C of temperature calendering formation, cutting, deburring, up to lightweight
High intensity stone paper.
Reference examples
Reference examples are used as using the stone paper of Changzhou company production
Performance detection is carried out to the stone paper in stone paper produced by the present invention and reference examples, testing result is as shown in table 1：
Table 1
| Detection project | Example 1 | Example 2 | Example 3 | Reference examples |
| Density（g/cm3） | 0.34 | 0.35 | 0.33 | 0.84 |
| Elongation at break（%） | 650 | 660 | 690 | 540 |
| Fracture tensile strength（N/mm2） | 38 | 40 | 44 | 30 |
| Horizontal firing length（mm） | 4 | 3 | 2 | 10 |
| The vertical combustion time（s） | 0 | 0 | 0 | 1 |
It is light by detecting stone paper produced by the present invention it can be seen from data in upper table, it is fire-retardant, and high mechanical strength, have wide
Wealthy application prospect.
Claims (7)
1. a kind of preparation method of light-high-strength stone paper, it is characterised in that specifically preparation process is：
（1）Corn straw smashing is weighed, obtains stalk crushed material, by the sodium hydroxide that stalk crushed material and mass fraction are 30%
1~2h is boiled in heating after solution and absolute ethyl alcohol mixing, is separated by filtration to obtain filter residue, freezes filter residue 2 with liquid nitrogen spraying immediately
~3min, then the filter residue ball milling after freezing, excessively 100 mesh sieves, collection sieving powder are obtained into self-control polyhydroxy fibre bundle；
（2）30~40g magnesium nitrates, 28~30g aluminum nitrates, 20~25g zinc nitrates is weighed to be dissolved in 450~550mL deionized waters
Mixed solution is obtained, pre-reaction liquid is obtained after mixed solution and mass fraction are mixed for 30% ammonium hydroxide and potassium carbonate；
（3）Pre-reaction liquid is fitted into high pressure water heating kettle, then add into high pressure water heating kettle polyhydroxy fibre bundle, potassium rhodanate and
Ammonium oxalate, stirs 10~15min；
（4）Treat enclosed high pressure water heating kettle after above-mentioned stirring, heat temperature raising, hydro-thermal reaction, is separated by filtration and is precipitated, will be heavy
Shallow lake is put into Muffle furnace, and 400~600 DEG C, 2~4h of heat preservation sintering, during discharging obtains are heated to the speed of 20 DEG C/min
Empty nano hydrotalcite powder；
（5）After above-mentioned hollow nano hydrotalcite powder and ellagic acid, ursin, Rosa Damascana, dusty yeast and water are mixed
To mixed liquor, mixed liquor is fitted into fermentation tank, is sealed by fermentation, is separated by filtration to obtain fermentation filter residue, it is dry, obtain modified hollow
Nano hydrotalcite powder；
（6）Count in parts by weight, weigh the hollow nano hydrotalcite powder of 60~70 parts of above-mentioned modifications, 20~30 parts of polyethylene, 0.3
~0.5 part of neopelex and 3~5 parts of azodicarbonamides are added in kneading machine, are kneaded, are obtained batch mixing, will be upper
State batch mixing and move into extruding pelletization in double screw extruder, and cut, repaiied with 60~70 DEG C of temperature calendering formation with calender
Side, up to light-high-strength stone paper.
A kind of 2. preparation method of light-high-strength stone paper according to claim 1, it is characterised in that：Step（1）In
The sodium hydroxide solution and the mass ratio of absolute ethyl alcohol that the stalk crushed material and mass fraction are 30% are 1:5:5.
A kind of 3. preparation method of light-high-strength stone paper according to claim 1, it is characterised in that：Step（2）In
The ammonium hydroxide and the mass ratio of potassium carbonate that the mixed solution and mass fraction is 30% are 10:1:1.
A kind of 4. preparation method of light-high-strength stone paper according to claim 1, it is characterised in that：Step（3）In
The addition of the polyhydroxy fibre bundle is the 10% of pre-reaction liquid quality, and the addition of potassium rhodanate is pre-reaction liquid quality
1%, the addition of ammonium oxalate is the 1% of pre-reaction liquid quality.
A kind of 5. preparation method of light-high-strength stone paper according to claim 1, it is characterised in that：Step（4）In
The pressure of the hydro-thermal reaction is 1.5~1.8MPa, and the temperature of heat temperature raising is 170~180 DEG C, the hydro-thermal reaction time 25
~30h.
A kind of 6. preparation method of light-high-strength stone paper according to claim 1, it is characterised in that：Step（5）In
Hollow the nano hydrotalcite powder and ellagic acid, ursin, Rosa Damascana, the mass ratio of dusty yeast and water are 10:3:
2:2:1:50, drying temperature is 105~110 DEG C, and drying time is 1~2h.
A kind of 7. preparation method of light-high-strength stone paper according to claim 1, it is characterised in that：Step（6）In
The melting temperature is 70~80 DEG C, and mixing time is 5~10min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711303560.4A CN107987352A (en) | 2017-12-11 | 2017-12-11 | A kind of preparation method of light-high-strength stone paper |
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|---|---|---|---|
| CN201711303560.4A CN107987352A (en) | 2017-12-11 | 2017-12-11 | A kind of preparation method of light-high-strength stone paper |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108946804A (en) * | 2018-07-25 | 2018-12-07 | 佛山腾鲤新能源科技有限公司 | A kind of preparation method of titania nanotube used for solar batteries |
| CN115491923A (en) * | 2022-08-19 | 2022-12-20 | 浙江夏王纸业有限公司 | Preparation method of crack-resistant wear-resistant facing base paper |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105524298A (en) * | 2015-12-22 | 2016-04-27 | 成都新柯力化工科技有限公司 | Preparation method of composite ivory board dedicated inorganic powder |
-
2017
- 2017-12-11 CN CN201711303560.4A patent/CN107987352A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105524298A (en) * | 2015-12-22 | 2016-04-27 | 成都新柯力化工科技有限公司 | Preparation method of composite ivory board dedicated inorganic powder |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108946804A (en) * | 2018-07-25 | 2018-12-07 | 佛山腾鲤新能源科技有限公司 | A kind of preparation method of titania nanotube used for solar batteries |
| CN115491923A (en) * | 2022-08-19 | 2022-12-20 | 浙江夏王纸业有限公司 | Preparation method of crack-resistant wear-resistant facing base paper |
| CN115491923B (en) * | 2022-08-19 | 2023-06-13 | 浙江夏王纸业有限公司 | Preparation method of cracking-resistant wear-resistant facing base paper |
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Application publication date: 20180504 |