CN107973577A - Guardrail base preparation method - Google Patents

Guardrail base preparation method Download PDF

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Publication number
CN107973577A
CN107973577A CN201711203749.6A CN201711203749A CN107973577A CN 107973577 A CN107973577 A CN 107973577A CN 201711203749 A CN201711203749 A CN 201711203749A CN 107973577 A CN107973577 A CN 107973577A
Authority
CN
China
Prior art keywords
guardrail base
parts
guardrail
filler material
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711203749.6A
Other languages
Chinese (zh)
Inventor
倪红军
顾涛
唐伟佳
吕帅帅
汪兴兴
李志扬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nantong University
Original Assignee
Nantong University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nantong University filed Critical Nantong University
Priority to CN201711203749.6A priority Critical patent/CN107973577A/en
Publication of CN107973577A publication Critical patent/CN107973577A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/04Waste materials; Refuse
    • C04B18/14Waste materials; Refuse from metallurgical processes
    • C04B18/141Slags
    • C04B18/144Slags from the production of specific metals other than iron or of specific alloys, e.g. ferrochrome slags
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01FADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
    • E01F15/00Safety arrangements for slowing, redirecting or stopping errant vehicles, e.g. guard posts or bollards; Arrangements for reducing damage to roadside structures due to vehicular impact
    • E01F15/02Continuous barriers extending along roads or between traffic lanes
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00663Uses not provided for elsewhere in C04B2111/00 as filling material for cavities or the like
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

This application discloses a kind of guardrail base preparation method, including step:High molecular material is used as raw material 3D printing guardrail base substrate;Prepare guardrail base filler material;The guardrail base filler material is placed in the guardrail base substrate, high molecular material is used outside the guardrail base filler material as raw material 3D printing guardrail base shell.According to technical solution provided by the embodiments of the present application, expect to carry out the preparation of guardrail base eventually by using aluminium ash, by aluminium ash, material is recycled eventually, the cost of guardrail base making can be saved, in combination with 3D printing technique, so that the preparation process of guardrail base is more simple and convenient, while it may also reach up refuse reclamation and energy-saving and environment-friendly purpose.

Description

Guardrail base preparation method
Technical field
The disclosure relates generally to a kind of aluminium ash material regenerative use technology, more particularly to guardrail base preparation method eventually.
Background technology
Aluminium ash is expected eventually, is primarily referred to as the aluminium ash that can not be further utilized after recovered metallic aluminium, and enterprise is usually by aluminium ash Whole material is stored up and landfill disposal.Prolonged accumulation, not only occupies substantial amounts of soil, but also serious ground contamination environment, Even underground water.Therefore, material annoyings enterprise to large-scale, reasonable manner processing aluminium ash always eventually.
With increasing for vehicle, traffic accident probability of happening also increases as, and the effect of isolation guardrail is increasingly prominent on road Go out.At present, common isolation guardrail has solid cast, highly reliable because its quality is big, is widely used, however its into This also remains high;Although coordinating concrete to be poured into a mould using hollow iron sheet at present, cost is also higher.Therefore, one kind is sought The packing material of material of low cost as guardrail base, has great significance the development for promoting communication.
The content of the invention
In view of drawbacks described above of the prior art or deficiency, are intended to provide a kind of guardrail base preparation method.
On the one hand, there is provided a kind of guardrail base preparation method, including step:S1:High molecular material is used to be beaten for raw material 3D Print guardrail base substrate;
S2:Prepare guardrail base filler material;
S3:The guardrail base filler material is placed in the guardrail base substrate, in the guardrail base filler material Outside uses high molecular material as raw material 3D printing guardrail base shell.
According to technical solution provided by the embodiments of the present application, expect to carry out the preparation of guardrail base eventually by using aluminium ash, will Material is recycled aluminium ash eventually, the cost of guardrail base making can be saved, in combination with 3D printing technique so that guardrail base Preparation process it is more simple and convenient, while may also reach up refuse reclamation and energy-saving and environment-friendly purpose.
Brief description of the drawings
By reading the detailed description made to non-limiting example made with reference to the following drawings, the application's is other Feature, objects and advantages will become more apparent upon:
Fig. 1 is guardrail base structure diagram in the embodiment of the present invention;
Fig. 2 is guardrail base preparation method flow chart in the embodiment of the present invention;
Fig. 3 is to prepare guardrail base filler material flow chart in the embodiment of the present invention.
Embodiment
The application is described in further detail with reference to the accompanying drawings and examples.It is understood that this place is retouched The specific embodiment stated is used only for explaining related invention, rather than the restriction to the invention.It also should be noted that in order to It illustrate only easy to describe, in attached drawing with inventing relevant part.
It should be noted that in the case where there is no conflict, the feature in embodiment and embodiment in the application can phase Mutually combination.Describe the application in detail below with reference to the accompanying drawings and in conjunction with the embodiments.
Please refer to Fig.2, the embodiment of the present invention provides a kind of guardrail base preparation method, including step:S1:Using macromolecule Material is raw material 3D printing guardrail base substrate;
S2:Prepare guardrail base filler material;
S3:The guardrail base filler material is placed in the guardrail base substrate, in the guardrail base filler material Outside uses high molecular material as raw material 3D printing guardrail base shell.
As shown in Figure 1, printing guardrail base 1 by 3D printing technique first in the present embodiment, will then prepare Guardrail base filler material 2 be placed in guardrail base substrate 1, pass through 3D printing technique again in the periphery of guardrail base filler material 2 Shell 3 is printed, operating procedure is convenient and simple.
Further, the high molecular material for ABS (Acrylonitrile Butadiene Styrene, acrylonitrile- Butadiene-styrene), PVA (polyvinyl alcohol, vinylalcohol polymer, polyvinyl alcohol), PLA One or more in (polylactic acid, polylactic acid).This implementation is by 3D printing technique using high molecular material as raw material The printing of guardrail base is carried out, 3D printing technique is applied to the field of traffic guardrail base preparation, high-volume is coped with and protects The preparation of column base, and cost is relatively low, easy to operate, science and technology environmental protection.
Further, described " preparing guardrail base filler material " specifically includes following steps:
S21:Initial feed is cleaned, desalination, denitrogenate, dry, ball-milling treatment formed aluminium ash filling material, it is described just Beginning raw material is mainly made of the component of following mass fraction:0-5 parts of pure aluminum, 20-40 parts of aluminium oxide, 10-30 parts of aluminium nitride;
S22:The aluminium ash filling material is uniformly mixed with auxiliary material;
S23:Above-mentioned mixed material is subjected to static pressure processing, forms guardrail base filler material blank;
S24:The guardrail base filler material blank is subjected to high-temperature steam curing and forms guardrail base filler material.
In the present embodiment using aluminium ash eventually material as initial feed carry out guardrail base filler material system, aluminium ash eventually expect in into Divide species more, predominantly pure aluminum, aluminium oxide, aluminium nitride, it is also possible to standby to expect to carry out again eventually by aluminium ash including some fluorides Utilize, the cost of guardrail base making can be saved, while reach refuse reclamation.Initial feed is cleaned first, is removed Salt, denitrogenate, dry, ball-milling treatment formation aluminium ash filling material, raw material of the granularity between 10-200 mesh is ultimately formed, by upper The step of stating controls the granularity of raw material within range above so that obtained aluminium ash filling material granularity is thinner, rear The guardrail base filler material prepared in continuous step is more convenient, and structure is more preferable.
Further, the removal of impurities, which is handled, is specially:The initial feed is immersed in the water, 10- is stood after stirring 30min, removes upper strata floating material, takes out bottom and is insoluble in the first sediment of water, and the volume ratio of the initial feed and water is 1:1.Material impurity is more eventually for aluminium ash as initial feed, carries out removal of impurities processing first, is about 1 using solid-liquid volume ratio:1 water First step removal of impurities is carried out, soaking the shorter time first removes impurity therein.
Further, it is described except salt treatment is specially:First sediment is immersed in the water, solid-liquid volume ratio is 1:5- 1:10,2-3h is stood after stirring, then removes the upper solution of 40%-70%, takes out remaining liq and the second sediment.
It is subsequent that except salt treatment is soaked the first sediment after removal of impurities, the dopant species during aluminium ash is expected eventually are more, It is mainly fluoride salt, chlorate etc. of the aluminium ash eventually in material in the solution of immersion.
Further, it is described to denitrogenate processing and be specially:High temperature is carried out to the remaining liq and second sediment to remove Nitrogen 1-2h, obtains the 3rd sediment, and the high temperature denitrogenates temperature as 100-120 DEG C.
Then the second sediment and remaining liq are carried out denitrogenating processing, denitrogenated broken using ultrasonic wave stirring in processing procedure Broken mode crushes second sediment, carries out broken by the second sediment so that sediment granularity diminishes, denitrogenates Processing is faster and more thorough.
Further, the drying and processing is:3rd sediment is put into 100-150 DEG C of baking oven and is dried 3-6h.Drying and processing then is carried out to the 3rd sediment, the sediment after drying can just polish, granularity is diminished, is easy to The preparation of follow-up aluminium ash filling material, the granularity after polishing in the present embodiment are controlled between 10-200 mesh, and raw material are mutually mixed Conjunction is then suppressed, by granularity control it is smaller various raw material can be facilitated to be mutually mixed uniformly, and be easy to follow-up pressure Step processed.
Further, described " being uniformly mixed the aluminium ash filling material with auxiliary material " is specially:
The each component of following mass parts is mixed:45-60 parts of aluminium ash filling material, 5-10 parts of quick lime, white lime 8-12 parts, 3-5 parts of gypsum, 10-20 parts of cement, 2-5 parts of SILICA FUME, 5-10 parts of engineering sand, 0.09-0.24 parts of high energy water-reducing agent, 0.18-0.36 parts of Rocky sand crystal, 0.09-0.24 parts of calcium formate, 6-13 parts of water.
A series of aluminium ash filling material obtained after processing is mixed with other auxiliary materials of each component, using mechanical agitation Mode stir evenly the preparation for carrying out guardrail base filler material, raw material after stirring is into static pressure processing is crossed, 15-20MPa's Constant pressure 5-10min under pressure so that the guardrail base filler material stable structure of preparation.By raw material are mixed in this present embodiment After be pressed to form guardrail base filler material, in order to enable the filler material after shaping is more firm and increase guardrail bottom Seat filler material shaping speed, has selected in the present embodiment mixing material quick lime and white lime to carry out the system of guardrail base filler material It is standby;The addition of the calcium formate of certain component can speed up the speed that each component mutually solidifies, and improve production efficiency.
Further, the high-temperature steam curing is specially that the guardrail base filler material blank is placed on 60 DEG C -80 DEG C Steam-cured 6-12h in water vapor atmosphere.Guardrail base filler material blank is formed after static pressure processing stripping forming, which is filled out Charge blank be placed in the water vapor atmosphere of certain temperature carry out it is steam-cured so that stable structure in the blank, above-mentioned high temperature steam Foster step can also be carried out by the way of naturally steam-cured, and guardrail base filler material blank is placed in natural environment and is carried out Maintenance also can reach same effect, but need longer time.
The application expects to carry out the preparation of guardrail base, the grey material eventually of aluminium is recycled, Neng Goujie eventually by using aluminium ash The cost that guardrail base makes is saved, in combination with 3D printing technique so that the preparation process of guardrail base is more simple and convenient, together When may also reach up refuse reclamation and energy-saving and environment-friendly purpose.
Above description is only the preferred embodiment of the application and the explanation to institute's application technology principle.People in the art Member should be appreciated that invention scope involved in the application, however it is not limited to the technology that the particular combination of above-mentioned technical characteristic forms Scheme, while should also cover in the case where not departing from the inventive concept, carried out by above-mentioned technical characteristic or its equivalent feature The other technical solutions for being combined and being formed.Such as features described above has similar work(with (but not limited to) disclosed herein The technical solution that the technical characteristic of energy is replaced mutually and formed.

Claims (10)

1. a kind of guardrail base preparation method, it is characterised in that including step:
S1:High molecular material is used as raw material 3D printing guardrail base substrate;
S2:Prepare guardrail base filler material;
S3:The guardrail base filler material is placed in the guardrail base substrate, outside the guardrail base filler material High molecular material is used as raw material 3D printing guardrail base shell.
2. guardrail base preparation method according to claim 1, it is characterised in that described " preparing guardrail base filler material " Specifically include following steps:
S21:Initial feed is cleaned, desalination, denitrogenate, dry, ball-milling treatment forms aluminium ash filling material, described initial former Material is mainly made of the component of following mass fraction:0-5 parts of pure aluminum, 20-40 parts of aluminium oxide, 10-30 parts of aluminium nitride;
S22:The aluminium ash filling material is uniformly mixed with auxiliary material;
S23:Above-mentioned mixed material is subjected to static pressure processing, forms guardrail base filler material blank;
S24:The guardrail base filler material blank is subjected to high-temperature steam curing and forms guardrail base filler material.
3. guardrail base preparation method according to claim 2, it is characterised in that the removal of impurities, which is handled, is specially:By institute State initial feed to be immersed in the water, stand 10-30min after stirring, remove upper strata floating material, take out bottom and be insoluble in the first heavy of water The volume ratio of starch, the initial feed and water is 1:1.
4. guardrail base preparation method according to claim 3, it is characterised in that described except salt treatment is specially:By institute State the first sediment to be immersed in the water, solid-liquid volume ratio is 1:5-1:10,2-3h is stood after stirring, then removes 40%-70%'s Upper solution, takes out remaining liq and the second sediment.
5. guardrail base preparation method according to claim 4, it is characterised in that described to denitrogenate processing and be specially:To institute State remaining liq and second sediment carries out high temperature and denitrogenates 1-2h, obtain the 3rd sediment, the high temperature denitrogenates temperature and is 100-120℃。
6. guardrail base preparation method according to claim 5, it is characterised in that the drying and processing is:By described Three sediments are put into 100-150 DEG C of baking oven and 3-6h are dried.
7. guardrail base preparation method according to claim 2, it is characterised in that described " by the aluminium ash filling material It is uniformly mixed with auxiliary material " be specially:
The each component of following mass parts is mixed:45-60 parts of aluminium ash filling material, 5-10 parts of quick lime, white lime 8-12 Part, 3-5 parts of gypsum, 10-20 parts of cement, 2-5 parts of SILICA FUME, 5-10 parts of engineering sand, 0.09-0.24 parts of high energy water-reducing agent, rock sand 0.18-0.36 parts brilliant, 0.09-0.24 parts of calcium formate, 6-13 parts of water.
8. guardrail base preparation method according to claim 2, it is characterised in that the static pressure processing is specially in 15- Constant pressure 5-10min under the pressure of 20MPa.
9. guardrail base preparation method according to claim 2, it is characterised in that the high-temperature steam curing is specially by described in Guardrail base filler material blank is placed on steam-cured 6-12h in 60 DEG C -80 DEG C of water vapor atmosphere.
10. guardrail base preparation method according to claim 1, it is characterised in that the high molecular material for ABS, One or more in PVA, PLA.
CN201711203749.6A 2017-11-27 2017-11-27 Guardrail base preparation method Pending CN107973577A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711203749.6A CN107973577A (en) 2017-11-27 2017-11-27 Guardrail base preparation method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711203749.6A CN107973577A (en) 2017-11-27 2017-11-27 Guardrail base preparation method

Publications (1)

Publication Number Publication Date
CN107973577A true CN107973577A (en) 2018-05-01

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Application Number Title Priority Date Filing Date
CN201711203749.6A Pending CN107973577A (en) 2017-11-27 2017-11-27 Guardrail base preparation method

Country Status (1)

Country Link
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201610533U (en) * 2009-10-21 2010-10-20 丛兰国 Guardrail base
CN104446245A (en) * 2014-11-21 2015-03-25 苏州大乘环保建材有限公司 Super early-strength mortar
CN106892441A (en) * 2017-02-24 2017-06-27 南通大学 Aluminium ash Application way

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201610533U (en) * 2009-10-21 2010-10-20 丛兰国 Guardrail base
CN104446245A (en) * 2014-11-21 2015-03-25 苏州大乘环保建材有限公司 Super early-strength mortar
CN106892441A (en) * 2017-02-24 2017-06-27 南通大学 Aluminium ash Application way

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
李远兵 等: "《铝工业固体废弃物综合利用》", 31 March 2015, 冶金工业出版社 *

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Application publication date: 20180501

RJ01 Rejection of invention patent application after publication