CN107964251A - Anticorrosive wood-plastic composite material and preparation method thereof - Google Patents
Anticorrosive wood-plastic composite material and preparation method thereof Download PDFInfo
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- CN107964251A CN107964251A CN201711091738.3A CN201711091738A CN107964251A CN 107964251 A CN107964251 A CN 107964251A CN 201711091738 A CN201711091738 A CN 201711091738A CN 107964251 A CN107964251 A CN 107964251A
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- composite material
- plastic composite
- anticorrosive wood
- plant waste
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
Abstract
The present invention relates to a kind of anticorrosive wood-plastic composite material, it is made of each component of following parts by weight：60~75 parts of plant waste, 12~24 parts of polyvinyl chloride, 3~5 parts of rutile powder, 2~6 parts of maleic anhydride, 0.6~1.2 part of calcium carbonate, 0.9~1.5 part of glass fibre, 1~4 part of Tissuemat E, 0.8~2.2 part of glyceryl monostearate, 1~2 part of organic tin stabilizer.The invention further relates to the preparation method of the anticorrosive wood-plastic composite material, comprise the following steps：Plant waste is cleaned, drying to water content is less than 5%, 100~120 mesh sieves of claying into power；Polyvinyl chloride is clayed into power, crosses 80~100 mesh sieves；Plant waste powder, polyvinyl chloride powder and other raw material are mixed, adds and 3~4h is kneaded in kneading machine, gains are then added into extruding pelletization in comminutor, obtain finished product.Gained anticorrosive wood-plastic composite material adds insect prevention antibacterial Chinese medicine component, possesses mothproof antibacterial effect, can be applicable on a large scale.
Description
Technical field
The present invention relates to wood processing field, more particularly, to a kind of anticorrosive wood-plastic composite material and preparation method thereof.
Background technology
Wood plastic composite is a kind of advanced composite material (ACM) for being surging forward in recent years both at home and abroad, be mainly used for building materials, furniture,
The industries such as logistics packaging.The advantages of timber and plastics are had concurrently due to wood plastic composite, the application in daily life and production
Also it is more and more extensive, there is vast potential for future development.But due to wherein containing more than 50% wood materials, especially humidity
When higher, or easily it is mouldy, grow bacterium, and timber utilization rate or excessive, therefore, it is necessary to improve its antiseptic property,
It is also required to develop other replacement raw material, to solve the problems, such as that timber resources is deficient.
The content of the invention
The object of the present invention is to provide a kind of anticorrosive wood-plastic composite material.
It is a further object of the present invention to provide a kind of preparation method of the anticorrosive wood-plastic composite material.
The object of the invention is achieved by the following technical programs：
A kind of anticorrosive wood-plastic composite material is provided, is made of each component of following parts by weight：60~75 parts of plant waste, gathers
12~24 parts of vinyl chloride, 3~5 parts of rutile powder, 2~6 parts of maleic anhydride, 0.6~1.2 part of calcium carbonate, glass fibre 0.9~
1.5 parts, 1~4 part of Tissuemat E, 0.8~2.2 part of glyceryl monostearate, 1~2 part of organic tin stabilizer.
Further, the plant waste includes 22~28 parts of wood leftover material, 20~25 parts of bagasse, corncob 12
~18 parts, 19~23 parts of shuck, 53~58 parts of Chinese medicine slag.
Further, the shuck includes 6~10 parts of walnut shell, 4~7 parts of chestnut shell, 8~13 parts of pinenut shell, peanut
2~5 parts of shell, 3~6 parts of Pericarppium Armeniacae Amarum, 15~19 parts of thunderbolt shell.
Further, the Chinese medicine slag includes 14~17 parts of asarum, 8~12 parts of the fruit of a cubeb litsea tree, 5~8 parts of Angelica sinensis, Dalmatian chrysanthemum 7
~11 parts, 10~14 parts of rhizoma nardostachyos, 6~10 parts of flaccid knotweed herb, 4~8 parts of realgar, 5~9 parts of fennel, 3~6 parts of levisticum, storehouse art 2~5
Part, 7~9 parts of rheum officinale.
Present invention also offers the preparation method of the anticorrosive wood-plastic composite material, comprise the following steps：
（1）Plant waste is cleaned, dry to be less than 5% to water content, 100~120 mesh sieves of claying into power, obtained plant is given up
Gurry powder；
（2）Polyvinyl chloride is clayed into power, crosses 80~100 mesh sieves；
（3）Plant waste powder, polyvinyl chloride powder and other raw material are mixed, adds and 3~4h is kneaded in kneading machine, so
Gains are added into extruding pelletization in comminutor afterwards, obtain finished product.
Further, step（3）In extrusion temperature be 220 DEG C.
Compared with prior art, the invention has the advantages that：
The present invention provides a kind of anticorrosive wood-plastic composite material, adds traditional Chinese medicine ingredients, possesses mothproof antibacterial effect, even in humidity
Under environment, it is not easy to mouldy infested, improves product quality, extend product service life, and plant powder abundance, belongs to
Recycled in resources circulation, meet the state basic policy of sustainable development, the simple and safe environmental protection of preparation process.
Embodiment
With reference to specific embodiment, the present invention is further illustrated.
Embodiment 1
Present embodiment discloses a kind of anticorrosive wood-plastic composite material, it is made of each component of following parts by weight：Plant waste
60 parts, 24 parts of polyvinyl chloride, 3 parts of rutile powder, 6 parts of maleic anhydride, 0.6 part of calcium carbonate, 1.5 parts of glass fibre, polyethylene
1 part of wax, 2.2 parts of glyceryl monostearate, 1 part of organic tin stabilizer.
The plant waste includes 28 parts of wood leftover material, 25 parts of bagasse, 12 parts of corncob, 23 parts of shuck, in
53 parts of the dregs of a decoction.
The shuck includes 10 parts of walnut shell, 4 parts of chestnut shell, 13 parts of pinenut shell, 2 parts of peanut shell, 6 parts of Pericarppium Armeniacae Amarum, thunderclap
15 parts of thunderbolt shell.
The Chinese medicine slag includes 17 parts of asarum, 8 parts of the fruit of a cubeb litsea tree, 8 parts of Angelica sinensis, 7 parts of Dalmatian chrysanthemum, 14 parts of rhizoma nardostachyos, flaccid knotweed herb 6
Part, 8 parts of realgar, 5 parts of fennel, 6 parts of levisticum, 2 parts of storehouse art, 9 parts of rheum officinale.
Embodiment 2
Present embodiment discloses a kind of anticorrosive wood-plastic composite material, it is made of each component of following parts by weight：Plant waste
75 parts, 12 parts of polyvinyl chloride, 5 parts of rutile powder, 2 parts of maleic anhydride, 1.2 parts of calcium carbonate, 0.9 part of glass fibre, polyethylene
4 parts of wax, 0.8 part of glyceryl monostearate, 2 parts of organic tin stabilizer.
The plant waste includes 22 parts of wood leftover material, 20 parts of bagasse, 18 parts of corncob, 19 parts of shuck, in
58 parts of the dregs of a decoction.
The shuck includes 6 parts of walnut shell, 7 parts of chestnut shell, 8 parts of pinenut shell, 5 parts of peanut shell, 3 parts of Pericarppium Armeniacae Amarum, thunderbolt
19 parts of shell.
The Chinese medicine slag includes 14 parts of asarum, 12 parts of the fruit of a cubeb litsea tree, 5 parts of Angelica sinensis, 11 parts of Dalmatian chrysanthemum, 10 parts of rhizoma nardostachyos, flaccid knotweed herb
10 parts, 4 parts of realgar, 9 parts of fennel, 3 parts of levisticum, 5 parts of storehouse art, 7 parts of rheum officinale.
Embodiment 3
Present embodiment discloses a kind of anticorrosive wood-plastic composite material, it is made of each component of following parts by weight：Plant waste
70 parts, 20 parts of polyvinyl chloride, 4 parts of rutile powder, 5 parts of maleic anhydride, 1 part of calcium carbonate, 1.3 parts of glass fibre, Tissuemat E 2
Part, 1.5 parts of glyceryl monostearate, 1.5 parts of organic tin stabilizer.
The plant waste includes 25 parts of wood leftover material, 22 parts of bagasse, 15 parts of corncob, 20 parts of shuck, in
55 parts of the dregs of a decoction.
The shuck includes 8 parts of walnut shell, 5 parts of chestnut shell, 10 parts of pinenut shell, 3 parts of peanut shell, 5 parts of Pericarppium Armeniacae Amarum, thunderbolt
18 parts of shell.
The Chinese medicine slag includes 15 parts of asarum, 9 parts of the fruit of a cubeb litsea tree, 7 parts of Angelica sinensis, 8 parts of Dalmatian chrysanthemum, 12 parts of rhizoma nardostachyos, flaccid knotweed herb 8
Part, 5 parts of realgar, 6 parts of fennel, 5 parts of levisticum, 3 parts of storehouse art, 8 parts of rheum officinale.
Embodiment 4
Present embodiment discloses a kind of anticorrosive wood-plastic composite material, it is made of each component of following parts by weight：Plant waste
65 parts, 15 parts of polyvinyl chloride, 3.5 parts of rutile powder, 3 parts of maleic anhydride, 0.8 part of calcium carbonate, 1 part of glass fibre, polyethylene
3 parts of wax, 1 part of glyceryl monostearate, 1.8 parts of organic tin stabilizer.
The plant waste includes 23 parts of wood leftover material, 24 parts of bagasse, 13 parts of corncob, 22 parts of shuck, in
57 parts of the dregs of a decoction.
The shuck includes 9 parts of walnut shell, 6 parts of chestnut shell, 12 parts of pinenut shell, 4 parts of peanut shell, 4 parts of Pericarppium Armeniacae Amarum, thunderbolt
16 parts of shell.
The Chinese medicine slag includes 16 parts of asarum, 10 parts of the fruit of a cubeb litsea tree, 6 parts of Angelica sinensis, 9 parts of Dalmatian chrysanthemum, 11 parts of rhizoma nardostachyos, flaccid knotweed herb 7
Part, 6 parts of realgar, 8 parts of fennel, 4 parts of levisticum, 4 parts of storehouse art, 7.5 parts of rheum officinale.
Embodiment 5
The components by weight percent of 1~4 any embodiment of Example prepares anticorrosive wood-plastic composite material, and preparation process is as follows：
（1）Plant waste is cleaned, drying to water content is 4%, and 100 mesh sieves of claying into power, are made plant waste powder
End；
（2）Polyvinyl chloride is clayed into power, crosses 100 mesh sieves；
（3）Plant waste powder, polyvinyl chloride powder and other raw material are mixed, adds in kneading machine and is kneaded 3h, then
Gains are added into extruding pelletization in comminutor, extrusion temperature is 220 DEG C, obtains finished product.
Embodiment 6
The components by weight percent of 1~4 any embodiment of Example prepares anticorrosive wood-plastic composite material, and preparation process is as follows：
（1）Plant waste is cleaned, dry to be less than 5% to water content, 120 mesh sieves of claying into power, are made plant waste powder
End；
（2）Polyvinyl chloride is clayed into power, crosses 80 mesh sieves；
（3）Plant waste powder, polyvinyl chloride powder and other raw material are mixed, adds in kneading machine and is kneaded 4h, then
Gains are added into extruding pelletization in comminutor, extrusion temperature is 220 DEG C, obtains finished product.
Embodiment 7
The components by weight percent of 1~4 any embodiment of Example prepares anticorrosive wood-plastic composite material, and preparation process is as follows：
（1）Plant waste is cleaned, dry to be less than 5% to water content, 110 mesh sieves of claying into power, are made plant waste powder
End；
（2）Polyvinyl chloride is clayed into power, crosses 90 mesh sieves；
（3）Plant waste powder, polyvinyl chloride powder and other raw material are mixed, adds in kneading machine and is kneaded 3.5h, so
Gains are added into extruding pelletization in comminutor afterwards, extrusion temperature is 220 DEG C, obtains finished product.
Claims (6)
1. a kind of anticorrosive wood-plastic composite material, it is characterised in that be made of each component of following weight fraction：Plant waste 60
~75 parts, 12~24 parts of polyvinyl chloride, 3~5 parts of rutile powder, 2~6 parts of maleic anhydride, 0.6~1.2 part of calcium carbonate, glass
0.9~1.5 part of fiber, 1~4 part of Tissuemat E, 0.8~2.2 part of glyceryl monostearate, 1~2 part of organic tin stabilizer.
2. anticorrosive wood-plastic composite material according to claim 1, it is characterised in that the plant waste includes timber side
22~28 parts of corner material, 20~25 parts of bagasse, 12~18 parts of corncob, 19~23 parts of shuck, 53~58 parts of Chinese medicine slag.
3. anticorrosive wood-plastic composite material according to claim 1 or 2, it is characterised in that the shuck includes walnut shell 6
~10 parts, 4~7 parts of chestnut shell, 8~13 parts of pinenut shell, 2~5 parts of peanut shell, 3~6 parts of Pericarppium Armeniacae Amarum, 15~19 parts of thunderbolt shell.
4. the anticorrosive wood-plastic composite material according to claim 1 or 3, it is characterised in that the Chinese medicine slag includes asarum 14
~17 parts, 8~12 parts of the fruit of a cubeb litsea tree, 5~8 parts of Angelica sinensis, 7~11 parts of Dalmatian chrysanthemum, 10~14 parts of rhizoma nardostachyos, 6~10 parts of flaccid knotweed herb, realgar
4~8 parts, 5~9 parts of fennel, 3~6 parts of levisticum, 2~5 parts of storehouse art, 7~9 parts of rheum officinale.
5. the preparation method of anticorrosive wood-plastic composite material according to claim 4, it is characterised in that comprise the following steps：
（1）Plant waste is cleaned, dry to be less than 5% to water content, 100~120 mesh sieves of claying into power, obtained plant is given up
Gurry powder；
（2）Polyvinyl chloride is clayed into power, crosses 80~100 mesh sieves；
（3）Plant waste powder, polyvinyl chloride powder and other raw material are mixed, adds and 3~4h is kneaded in kneading machine, so
Gains are added into extruding pelletization in comminutor afterwards, obtain finished product.
6. the preparation method of anticorrosive wood-plastic composite material according to claim 5, it is characterised in that step（3）In squeeze
Go out temperature for 220 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711091738.3A CN107964251A (en) | 2017-11-08 | 2017-11-08 | Anticorrosive wood-plastic composite material and preparation method thereof |
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| CN201711091738.3A CN107964251A (en) | 2017-11-08 | 2017-11-08 | Anticorrosive wood-plastic composite material and preparation method thereof |
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| CN107964251A true CN107964251A (en) | 2018-04-27 |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400052A (en) * | 2015-12-18 | 2016-03-16 | 南京聚锋新材料有限公司 | Chinese medicine residue reinforced reprocessed plastic composite material, and preparation method thereof |
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2017
- 2017-11-08 CN CN201711091738.3A patent/CN107964251A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105400052A (en) * | 2015-12-18 | 2016-03-16 | 南京聚锋新材料有限公司 | Chinese medicine residue reinforced reprocessed plastic composite material, and preparation method thereof |
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Application publication date: 20180427 |