CN107955584A - A kind of phase-change material for latent heat storage - Google Patents

A kind of phase-change material for latent heat storage Download PDF

Info

Publication number
CN107955584A
CN107955584A CN201711377532.7A CN201711377532A CN107955584A CN 107955584 A CN107955584 A CN 107955584A CN 201711377532 A CN201711377532 A CN 201711377532A CN 107955584 A CN107955584 A CN 107955584A
Authority
CN
China
Prior art keywords
phase
change material
latent heat
heat storage
srcl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711377532.7A
Other languages
Chinese (zh)
Inventor
张成如
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shandong Lianxing Energy Group Co Ltd
Original Assignee
Shandong Lianxing Energy Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shandong Lianxing Energy Group Co Ltd filed Critical Shandong Lianxing Energy Group Co Ltd
Priority to CN201711377532.7A priority Critical patent/CN107955584A/en
Publication of CN107955584A publication Critical patent/CN107955584A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02Materials undergoing a change of physical state when used
    • C09K5/06Materials undergoing a change of physical state when used the change of state being from liquid to solid or vice versa
    • C09K5/063Materials absorbing or liberating heat during crystallisation; Heat storage materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

The invention discloses a kind of phase-change material for latent heat storage, including following component:Na2SO4·10H2O, borax, SrCl2·H2O.The present invention adds nucleator and thickener in inorganic hydrated salt class phase transformation material, solves the problems, such as to be nucleated poor performance during crystalline hydrate salt crystallization in the prior art.

Description

A kind of phase-change material for latent heat storage
Technical field
The present invention relates to hot technical field of energy storage, more particularly to a kind of phase-change material for latent heat storage.
Background technology
Phase-change material (PCM-Phase Change Material) refers to vary with temperature and change state of matter and simultaneously can The material of latent heat is provided.The process of transformation physical property is known as phase transition process, and at this moment phase-change material will absorb or release is substantial amounts of Latent heat.Simultaneously because during phase transformation, temperature it is nearly constant, therefore can be used for adjusting the temperature of surrounding environment, And can be with Reusability.Since the application of phase-change material is quite varied, it has become the new material of people's pay attention to day by day.
Many inorganic crystal hydrated salts usually have the fusing point of the larger heat of transformation and fixation, and the crystallization water of abjection dissolves salt And absorb heat, inverse process occurs for when cooling, absorbs crystallization water heat release, so being used frequently as latent heat type heat accumulating.Crystalline hydrate Salt is typically middle low temperature heat storage phase-changing material, its main feature is that use scope is wide, price is relatively inexpensive, and thermal conductivity factor is big, and density is big, single Position volume storage density is big, is generally in neutrality.The drawback is that degree of supercooling is big, easily separates out, the reason is that most of crystalline hydrate salt Poor performance is nucleated during crystallization.Present invention mainly solves this problem.
The content of the invention
The present invention provides a kind of phase-change material for latent heat storage aiming at above-mentioned defect.The present invention Nucleator and thickener are added in inorganic hydrated salt class phase transformation material, when solving crystalline hydrate salt crystallization in the prior art into The problem of core poor performance.
A kind of phase-change material technical solution for latent heat storage of the present invention is, including following component:Na2SO4· 10H2O, borax, SrCl2·H2O。
A kind of phase-change material for latent heat storage, further includes atlapulgite.
A kind of phase-change material for latent heat storage, is made of following component by weight:Na2SO4· 10H2O 65-85, borax 1-3, SrCl2·H2O 1-3, atlapulgite 2-8.
A kind of phase-change material for latent heat storage, is made of following component by weight:Na2SO4· 10H2O 75, borax 2, SrCl2·H2O 1, atlapulgite 6.
Beneficial effects of the present invention are:The present invention adds nucleator and thickener in inorganic hydrated salt class phase transformation material, Solve the problems, such as to be nucleated poor performance during crystalline hydrate salt crystallization in the prior art.Degree of supercooling is less than 2 DEG C, and crystalline rate is small, brilliant Body is laxer, and more transparent.
Embodiment:
For a better understanding of the present invention, below with instantiation come the technical solution that the present invention will be described in detail, but it is of the invention It is not limited thereto.
Embodiment 1
A kind of phase-change material for latent heat storage, is made of following component by weight:Na2SO4·10H2O 75, borax 2,SrCl2·H2O 1, atlapulgite 6.For degree of supercooling close to 0 DEG C, crystalline rate is small, and crystal is laxer, and more transparent.
Embodiment 2
A kind of phase-change material for latent heat storage, is made of following component by weight:Na2SO4·10H2O 65, borax 1,SrCl2·H2O 2, atlapulgite 2.Degree of supercooling is less than 2 DEG C, and crystalline rate is small, and crystal is laxer, and more transparent.
Embodiment 3
A kind of phase-change material for latent heat storage, is made of following component by weight:Na2SO4·10H2O 85, borax 3,SrCl2·H2O 3, atlapulgite 8.Degree of supercooling is less than 2 DEG C, and crystalline rate is small, and crystal is laxer, and more transparent.

Claims (4)

1. a kind of phase-change material for latent heat storage, it is characterised in that including following component:Na2SO4·10H2O, borax, SrCl2·H2O。
2. a kind of phase-change material for latent heat storage according to claim 1, it is characterised in that further include active white Soil.
3. a kind of phase-change material for latent heat storage according to claim 2, it is characterised in that by by weight Following component forms:Na2SO4·10H2O 65-85, borax 1-3, SrCl2·H2O 1-3, atlapulgite 2-8.
4. a kind of phase-change material for latent heat storage according to claim 2, it is characterised in that by by weight Following component forms:Na2SO4·10H2O 75, borax 2, SrCl2·H2O 1, atlapulgite 6.
CN201711377532.7A 2017-12-19 2017-12-19 A kind of phase-change material for latent heat storage Pending CN107955584A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711377532.7A CN107955584A (en) 2017-12-19 2017-12-19 A kind of phase-change material for latent heat storage

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711377532.7A CN107955584A (en) 2017-12-19 2017-12-19 A kind of phase-change material for latent heat storage

Publications (1)

Publication Number Publication Date
CN107955584A true CN107955584A (en) 2018-04-24

Family

ID=61959382

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711377532.7A Pending CN107955584A (en) 2017-12-19 2017-12-19 A kind of phase-change material for latent heat storage

Country Status (1)

Country Link
CN (1) CN107955584A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108795390A (en) * 2018-07-31 2018-11-13 青海大学 A kind of phase-changing energy storage material containing thickener

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106753254A (en) * 2016-11-18 2017-05-31 青海大学 A kind of inorganic hydrated salt composite phase-change heat-storage material and its preparation and application

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106753254A (en) * 2016-11-18 2017-05-31 青海大学 A kind of inorganic hydrated salt composite phase-change heat-storage material and its preparation and application

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
唐钰成等: "《低成本消除相变储热材料分层的方法》", 《河北科学院学报》 *
张寅平等编著: "《相变贮能-理论和应用》", 30 November 1996 *
黄丽等: "《聚合物复合材料》", 31 January 2012, 中国轻工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108795390A (en) * 2018-07-31 2018-11-13 青海大学 A kind of phase-changing energy storage material containing thickener

Similar Documents

Publication Publication Date Title
CN104531077A (en) Preparation method of expanded-graphite-base hydrated salt composite solid-solid phase-change energy storage material
CN108467711B (en) Inorganic composite phase change material and preparation method thereof
CN102660231A (en) Inorganic phase-change material and preparation method thereof
CN104419381A (en) Phase change material and preparation method thereof
NO159939B (en) HEAT STORAGE MATERIALS WITH REVERSIBLE LIQUID / FAST PHASE CHANGE AND USE THEREOF.
WO2009041396A1 (en) Aqueous solution for clathrate hydrate formation, heat-storage agent, process for producing clathrate hydrate or slurry thereof, method of storing/radiating heat, and process for preparing aqueous solution for forming latent-heat-storage agent or major component thereof
CN105950120A (en) Phase change material for solar energy storage
CN107556972A (en) Normal low temperature phase change energy-accumulating medium and preparation method thereof
CN107523272B (en) High-thermal-conductivity binary low-eutectic-temperature-coefficient hydrated salt phase-change material and preparation method thereof
CN103194183A (en) Preparation method of alkanol self-temperature control phase change material
CN105505329A (en) Method for reducing condensate depression of hydrous salt phase change material by adding antisolvent
CN107955584A (en) A kind of phase-change material for latent heat storage
CN105694823A (en) Preparation method of disodium hydrogen phosphate heat storage system suitable for greenhouses
JP6864742B2 (en) Cold storage material and cold storage pack
CN103059816A (en) Efficient phase change energy storage materials and preparation method thereof
CN102876299A (en) 35-DEG C energy storage material composition
CN113429939B (en) Low super-cooling degree inorganic salt phase change energy storage material
KR20100134855A (en) Microcapsules using a phase change material and printing-processing composition and processes for producing the same
CN103045175A (en) High-performance moderate-temperature phase-change energy-storage material and preparation method thereof
US4971713A (en) Thermal energy storage compositions with nucleating agents
CN111978925A (en) Composite phase-change material for cleaning and heating and preparation method thereof
CN112574714A (en) Preparation method of graphene phase-change composite material
JPS60243189A (en) Heat storage material
CN102408878B (en) Phase change energy storage material
CN107384325B (en) Method for prolonging service life of hydrated salt phase change material

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20180424