CN107954737A - A kind of building and ornament materials with purifying formaldehyde and preparation method thereof - Google Patents
A kind of building and ornament materials with purifying formaldehyde and preparation method thereof Download PDFInfo
- Publication number
- CN107954737A CN107954737A CN201610905792.6A CN201610905792A CN107954737A CN 107954737 A CN107954737 A CN 107954737A CN 201610905792 A CN201610905792 A CN 201610905792A CN 107954737 A CN107954737 A CN 107954737A
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- China
- Prior art keywords
- formaldehyde
- parts
- purifying
- building
- ornament materials
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Links
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 title claims abstract description 270
- 239000000463 material Substances 0.000 title claims abstract description 67
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 53
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000012629 purifying agent Substances 0.000 claims abstract description 28
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004088 foaming agent Substances 0.000 claims abstract description 15
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 14
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000002253 acid Substances 0.000 claims abstract description 12
- 239000001110 calcium chloride Substances 0.000 claims abstract description 12
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 12
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims abstract description 12
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 12
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 12
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 12
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- 150000001414 amino alcohols Chemical class 0.000 claims abstract description 10
- 150000003839 salts Chemical class 0.000 claims abstract description 10
- 229920000881 Modified starch Polymers 0.000 claims abstract description 9
- 235000019426 modified starch Nutrition 0.000 claims abstract description 9
- 239000007767 bonding agent Substances 0.000 claims abstract description 7
- 239000004615 ingredient Substances 0.000 claims abstract description 7
- 239000004368 Modified starch Substances 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims description 18
- 238000000498 ball milling Methods 0.000 claims description 17
- 239000000853 adhesive Substances 0.000 claims description 14
- 230000001070 adhesive effect Effects 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 9
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 7
- -1 polyoxy Polymers 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 238000000465 moulding Methods 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- 239000004568 cement Substances 0.000 claims description 5
- 229920002401 polyacrylamide Polymers 0.000 claims description 5
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 5
- IMSKKIASJKRGKI-UHFFFAOYSA-N 1,2-bis(methylamino)ethanol Chemical compound CNCC(O)NC IMSKKIASJKRGKI-UHFFFAOYSA-N 0.000 claims description 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical class CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- 230000008859 change Effects 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- 239000004922 lacquer Substances 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 102000004169 proteins and genes Human genes 0.000 claims description 3
- 108090000623 proteins and genes Proteins 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 3
- QOADFRWPXNWKQS-UHFFFAOYSA-N 1,2-bis(ethylamino)ethanol Chemical class C(C)NC(CNCC)O QOADFRWPXNWKQS-UHFFFAOYSA-N 0.000 claims description 2
- QYYAFOFOLYOYID-UHFFFAOYSA-N 1,2-dianilinoethanol Chemical compound C=1C=CC=CC=1NC(O)CNC1=CC=CC=C1 QYYAFOFOLYOYID-UHFFFAOYSA-N 0.000 claims description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 238000003760 magnetic stirring Methods 0.000 claims description 2
- 238000010907 mechanical stirring Methods 0.000 claims description 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- PASHVRUKOFIRIK-UHFFFAOYSA-L calcium sulfate dihydrate Chemical compound O.O.[Ca+2].[O-]S([O-])(=O)=O PASHVRUKOFIRIK-UHFFFAOYSA-L 0.000 claims 1
- 239000001768 carboxy methyl cellulose Substances 0.000 claims 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 1
- 125000000031 ethylamino group Chemical group [H]C([H])([H])C([H])([H])N([H])[*] 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 238000005187 foaming Methods 0.000 claims 1
- 239000004584 polyacrylic acid Substances 0.000 claims 1
- 238000004887 air purification Methods 0.000 abstract description 2
- 230000006870 function Effects 0.000 description 7
- 239000010440 gypsum Substances 0.000 description 7
- 229910052602 gypsum Inorganic materials 0.000 description 7
- 239000007788 liquid Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 150000001299 aldehydes Chemical class 0.000 description 4
- 238000005575 aldol reaction Methods 0.000 description 4
- 239000004035 construction material Substances 0.000 description 4
- 230000036541 health Effects 0.000 description 4
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 4
- 229940068984 polyvinyl alcohol Drugs 0.000 description 4
- 238000000746 purification Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000001802 infusion Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000009423 ventilation Methods 0.000 description 2
- GPWNWKWQOLEVEQ-UHFFFAOYSA-N 2,4-diaminopyrimidine-5-carbaldehyde Chemical compound NC1=NC=C(C=O)C(N)=N1 GPWNWKWQOLEVEQ-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 235000008331 Pinus X rigitaeda Nutrition 0.000 description 1
- 235000011613 Pinus brutia Nutrition 0.000 description 1
- 241000018646 Pinus brutia Species 0.000 description 1
- 229920002845 Poly(methacrylic acid) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940077388 benzenesulfonate Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 210000003169 central nervous system Anatomy 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000036737 immune function Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 230000009325 pulmonary function Effects 0.000 description 1
- 150000004040 pyrrolidinones Chemical class 0.000 description 1
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 210000002345 respiratory system Anatomy 0.000 description 1
- 229930182490 saponin Natural products 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000010265 sodium sulphite Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
- C04B40/0039—Premixtures of ingredients
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8668—Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/001—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing unburned clay
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20707—Titanium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/209—Other metals
- B01D2255/2094—Tin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/30—Silica
Abstract
The invention belongs to technical field of air purification, is related to a kind of building and ornament materials with purifying formaldehyde and preparation method thereof.The material is made of following ingredients in parts by weight：1~20 part of formaldehyde purifying agent, 100 parts of base materials, 0.5~1 portion of modified starch, 1~1.5 part of bonding agent, 0.6~1 part of lignocellulosic, 0.01~0.1 part of foaming agent and 65~75 parts of water compositions, wherein formaldehyde purifying agent is made of following ingredients in parts by weight：The soluble salt of weak acid of 2~10 parts of polyvinylpyrrolidones, 1~6 part of water-soluble high-molecular compound, 4~42 parts of chiral amino alcohols, 1~7 part of titanium dioxide, 1~7 part of stannic oxide, 1~7 part of silica, 2~6 parts of magnesia, 1~13 part of activated carbon, 1~9 part of calcium chloride and 1~13 part.The material of the present invention can fast, stably, efficiently purifying formaldehyde, be suitable for large-scale promotion application.
Description
Technical field
The invention belongs to technical field of air purification, be related to it is a kind of have the function of the building and ornament materials of purifying formaldehyde and its
Preparation method.
Background technology
Formaldehyde is magma noxious material, can be combined with the amino in protein, and then generates formylated albumen.Formaldehyde for
It is different that the influence of health includes allotriosmia, respiratory tract, abnormal pulmonary function, central nervous system effects, immune function
Inhereditary material in normal and damaging cells, harm is serious, must examine.Therefore, China's standard provides the formaldehyde in room air
Concentration cannot be more than 0.08mg/m3, and the concentration of formaldehyde in public place air must not exceed 0.12mg/m3。
At present, Formaldehyde Pollution of Indoor Air becomes the most important air pollution problem inside rooms in China, seriously endangers the life of people
Life health.In daily life, building and ornament materials are widely used in fitment process, and the common building ornament materials now sold is big
The harmful substance such as meeting release formaldehyde more, can not ensure the health of indoor environment.
One of hot spot studied as environmental pollution improvement for the administering method of formaldehyde pollution, researcher proposes more
The method that kind administers formaldehyde pollution, including ventilation ventilation, plant purification method, physisorphtion etc..But existing method is not
Can quickly, efficiently and thoroughly solve the problems, such as formaldehyde pollution.It is more and more tighter as the stealthy killer in people's daily life, formaldehyde
The physics such as the health of human body, common dilution, absorption is endangered except carbaldehyde Method cannot meet people for interior in important place
The requirement of air quality.Therefore, study it is a kind of can efficiently, the new decorative material for building of fast purification formaldehyde be it is current urgently
The problem of solution.
A kind of construction material that can absorb formaldehyde, function therein are disclosed in 103351151 A of Chinese invention patent CN
Material is the sorbing materials such as diatomite and graphite powder.Disclosed in 103601459 A of Chinese invention patent CN and utilize plant fiber
The gypsum-based construction material and its application process for administering indoor formaldehyde are prepared, functional material therein is partial carbonization plant fiber.
A kind of environmental-friendly construction material for absorbing formaldehyde is disclosed in 104046087 A of Chinese invention patent CN, functional material therein is
The sorbing materials such as the decanning dusts of shell, diatomite, sepiolite.The above-mentioned formaldehyde construction material that removes can only be mostly realized for formaldehyde
Absorption, and be unable to reach the purpose of elimination.
The content of the invention
In order to solve the above-mentioned technical problem, the present invention is intended to provide a kind of quick, efficient, long-acting have purifying formaldehyde work(
Building and ornament materials of energy and preparation method thereof.
Specifically, the present invention adopts the following technical scheme that：
A kind of to have the function of the building and ornament materials of purifying formaldehyde, it is made of following ingredients in parts by weight：1~20
Part formaldehyde purifying agent, 100 parts of base materials, 0.5~1 portion of modified starch, 1~1.5 part of bonding agent, 0.6~1 part of lignocellulosic,
0.01~0.1 part of foaming agent and 65~75 parts of water compositions.
There are the building and ornament materials of purifying formaldehyde above-mentioned, the formaldehyde purifying agent is by under in parts by weight
Row component forms：2~10 parts of polyvinylpyrrolidones, 1~6 part of water-soluble high-molecular compound, 4~42 parts of chiral amino alcohols, 1
~7 parts of titanium dioxide, 1~7 part of stannic oxide, 1~7 part of silica, 2~6 parts of magnesia, 1~13 part of activated carbon, 1~9 part
Calcium chloride and 1~13 part of soluble salt of weak acid.
Preferably, the formaldehyde purifying agent is made of following ingredients in parts by weight：4~8 parts of polyvinylpyrrolidones,
2~5 parts of water-soluble high-molecular compounds, 10~30 parts of chiral amino alcohols, 2~6 parts of titanium dioxide, 2~6 parts of stannic oxides, 2~
The soluble salt of weak acid of 6 parts of silica, 3~5 parts of magnesia, 3~10 parts of activated carbons, 2~6 parts of calcium chloride and 3~10 parts.
It is furthermore preferred that the formaldehyde purifying agent is made of following ingredients in parts by weight：6 parts of polyvinylpyrrolidones, 4
Part water-soluble high-molecular compound, 20 parts of chiral amino alcohols, 3 parts of titanium dioxide, 3 parts of stannic oxides, 3 parts of silica, 4 parts of oxygen
Change magnesium, 6 parts of activated carbons, 4 parts of calcium chloride and 6 parts of soluble salts of weak acid.
In above-mentioned formaldehyde purifying agent, the water-soluble high-molecular compound is selected from polyethylene glycol (PEG), polyacrylamide
(PAM), polyacrylic acid (PAA), carboxymethyl cellulose (CMC), polyethylene glycol oxide (PEO), polyvinyl alcohol (PVA), poly- methyl-prop
Any one or more mixture formed with arbitrary proportion in olefin(e) acid (PMAA).
In above-mentioned formaldehyde purifying agent, the chiral amino alcohol is mixed outer for two kinds of enantiomter molecule equimolars
Raceme, selected from 1,2-dimethylaminoethanol, 2,3- dimethylaminos propyl alcohol, 1,2-diethylaminoethanol, 1,2- diphenylamino second
Alcohol, 1,2,2- triphenyl -1,2- diaminourea ethanol, 2,2- diethyl -1,2- diaminourea ethanol, N- methyl-N-ethylaminos three
Any one or more mixture formed with arbitrary proportion in butanol, structural formula are as follows.
In above-mentioned formaldehyde purifying agent, the solubility salt of weak acid shows alkalescence after ionization, selected from carbonate, bicarbonate
Any one or more mixture formed with arbitrary proportion in salt, sulphite, silicate, saturated monocarboxylic acid salt.
There are the building and ornament materials of purifying formaldehyde above-mentioned, the base-material is powdered base material, including gypsum
Powder, powder of lacquer putty for use on, cement, clay etc..
There are the building and ornament materials of purifying formaldehyde above-mentioned, the bonding agent is aqueous adhesive, including poly-
Vinyl alcohol aqueous adhesive, vinyl acetate esters aqueous adhesive, acrylic compounds aqueous adhesive, the water-based bonding of polyurethanes
Agent, epoxy resin aqueous adhesive, phenolic resin class aqueous adhesive, organic silicon aqueous adhesive etc..
There are the building and ornament materials of purifying formaldehyde above-mentioned, the foaming agent includes rosin tree epoxy-type foaming agent
(such as rosin soap), surfactant type foaming agent (such as neopelex, polyethylene glycol), protein active thing type hair
Infusion (such as Tea Saponin foaming agent, animal hair infusion) and compound foaming agent.
A kind of preparation method with the building and ornament materials of purifying formaldehyde, it includes the following steps：
1) by the polyvinylpyrrolidone of formula ratio and water-soluble high-molecular compound ball milling mixing, mixture A is obtained；
2) it is the titanium dioxide of formula ratio, stannic oxide, silica, magnesia, activated carbon, calcium chloride, solubility is weak
Hydrochlorate and chiral amino alcohol are added to ball milling mixing in the mixture A obtained in step 1), obtain mixture B, by 200~
300 mesh filter screens filter, and obtain formaldehyde purifying agent；
3) base material of formula ratio and modified starch are mixed, obtains mixture C；
4) formaldehyde purifying agent obtained in the bonding agent of formula ratio, lignocellulosic, water and step 2) is stirred evenly, obtained
To mixture D；
5) mixture D obtained in step 4) is added in the mixture C obtained in step 3), adds formula ratio
Foaming agent mixes, and by integrated molding, obtains the building and ornament materials with purifying formaldehyde.
In above-mentioned preparation method, ball milling mixing is completed by ball mill described in step 1), speed for 300~
800rpm, time are 30~60 minutes.
In above-mentioned preparation method, ball milling mixing is completed by ball mill described in step 2), speed for 300~
800rpm, time are 30~120 minutes.
In above-mentioned preparation method, mixing described in step 3) is completed by mixer.
In above-mentioned preparation method, stirring described in step 4) is completed by mechanical stirring device or magnetic stirring apparatus.
In above-mentioned preparation method, mixing described in step 5) is completed by mixer, and speed is 200~1000rpm, when
Between be 30~90 minutes.
In above-mentioned preparation method, integrated molding described in step 5) is completed by extruded type forming machine.
Except by formaldehyde purifying agent applied to powdered base material come in addition to preparing building and ornament materials, can also be according to formaldehyde
Cleanser:Solvent=1:50~2000 weight ratio, formaldehyde purifying agent is added in solvent (such as water, ethanol) and is configured to first
Aldehyde scavenging solution, has the function of building for purifying formaldehyde on the surface of molded substrate by spraying or brushing purifying formaldehyde liquid to prepare
Ornament materials is built, wherein the dosage of the purifying formaldehyde liquid is 1~1000g/m2。
There are the building and ornament materials of purifying formaldehyde above-mentioned, the molded substrate includes plank, slabstone, gypsum
Plate, armoured concrete slab, ceramic tile, wallpaper etc..
There are the building and ornament materials of purifying formaldehyde in the present invention, activated carbon has higher chemistry surely because of it
Qualitative, larger specific surface area and be used as the absorption carrier in formaldehyde purifying agent；Chiral amino alcohol is in alkalescence and/or catalysis bar
Aldol reaction can occur with formaldehyde under part, so as to have the function that purifying formaldehyde；Magnesia can be absorbed in air
Water and carbon dioxide, and then basic magnesium carbonate is generated, alkaline environment is provided for aldol reaction, and after the magnesia moisture absorption not
It can influence the solid state of composite material；Soluble salt of weak acid can ensure that formaldehyde purifying agent is chronically under alkaline condition, is had
Beneficial to the lasting progress of aldol reaction；Titanium dioxide, stannic oxide, silica etc. because its own with catalytic performance and by with
Make catalyst, improve the efficiency of aldol reaction, enhancing composite material removes the ability of formaldehyde；As binding agent, polyethylene
Said components can be combined together by pyrrolidones and water soluble polymer in the form of stable homogeneous, promote formaldehyde purifying agent
With the highly effective reaction of formaldehyde.
Compared with prior art, the building and ornament materials with purifying formaldehyde in the present invention can not only realize first
The quick adsorption of aldehyde, and can be eliminated by chemical reaction, whole purification process shows quick, stable, efficient
Feature.In addition, the raw materials for production for being used to prepare building and ornament materials are cheap and easy to get, preparation process is simple and easy to do, is suitable for advising greatly
Mould promotes and applies, great market prospects.
Brief description of the drawings
Fig. 1 is the SEM spectrograms of the building and ornament materials finished product in embodiment 1.
Fig. 2 is that the building and ornament materials of the application present invention purify the effect diagram of the formaldehyde in air.
Embodiment
Further description is made to the technical solution in the present invention below in conjunction with attached drawing and specific embodiment.Unless
It is otherwise noted, instrument, material, reagent used in the following example etc. can be obtained by routine business means.
Embodiment 1：There is the preparation of the gypsum material of purifying formaldehyde.
1) use ball mill, by 2g polyvinylpyrrolidones and 1g polyethylene glycol under the speed of 300rpm ball milling mixing 60
Minute, obtain mixture A；
2) by 1g titanium dioxide, 1g stannic oxides, 1g silica, 2g magnesia, 1g activated carbons, 1g calcium chloride, 1g carbon
Sour sodium and 4g 1,2-dimethylaminoethanol are added in the mixture A obtained in step 1), and ball milling mixes under the speed of 300rpm
Close 120 minutes, obtain mixture B, filtered by 200 mesh filter screens, obtain formaldehyde purifying agent；
3) mixer is used, 100g land plasters, 0.5g modified starches are mixed, obtain mixture C；
4) mechanical agitation is used, the first that will be obtained in 1g polyvinyl alcohol, 0.6g lignocellulosics, 65g water and 1g steps 2)
Aldehyde cleanser stirs evenly, and obtains mixture D；
5) mixture D obtained in step 4) is added in the mixture C obtained in step 3), adds 0.01g pines
Perfumed soap, is mixed 90 minutes under the speed of 200rpm using mixer, then using extruded type forming machine integrated molding, obtained
There is the gypsum material of purifying formaldehyde, its SEM spectrogram is as shown in Figure 1.
Embodiment 2：There is the preparation of the putty material of purifying formaldehyde.
1) ball mill is used, ball milling mixes under the speed of 800rpm by 10g polyvinylpyrrolidones and 6g polyacrylamides
Close 30 minutes, obtain mixture A；
2) by 7g titanium dioxide, 7g stannic oxides, 7g silica, 6g magnesia, 13g activated carbons, 9g calcium chloride, 13g
Sodium sulfite and 42g 2,3- dimethylamino propyl alcohol are added in the mixture A obtained in step 1), under the speed of 800rpm
Ball milling mixing 30 minutes, obtains mixture B, is filtered by 200 mesh filter screens, obtains formaldehyde purifying agent；
3) mixer is used, 100g powder of lacquer putty for use on, 1g modified starches are mixed, obtain mixture C；
4) mechanical agitation is used, by what is obtained in 1.5g vinyl acetates, 1g lignocellulosics, 75g water and 20g steps 2)
Formaldehyde purifying agent stirs evenly, and obtains mixture D；
5) mixture D obtained in step 4) is added in the mixture C obtained in step 3), adds 0.1g 12
Sodium alkyl benzene sulfonate, is mixed 30 minutes under the speed of 1000rpm using mixer, is then molded using extruded type machine integrated
Shaping, obtains the putty material with purifying formaldehyde.
Embodiment 3：There is the preparation of the china clay material of purifying formaldehyde.
1) ball mill is used, ball milling mixes under the speed of 500rpm by 4g polyvinylpyrrolidones and 2g carboxymethyl celluloses
Close 40 minutes, obtain mixture A；
2) by 6g titanium dioxide, 6g stannic oxides, 5g silica, 3g magnesia, 3g activated carbons, 2g calcium chloride, 3g carbon
Sour hydrogen sodium and 10g 1,2- diphenylamino ethanol is added in the mixture A obtained in step 1), the ball under the speed of 500rpm
Mill mixing 80 minutes, obtains mixture B, is filtered by 200 mesh filter screens, obtains formaldehyde purifying agent；
3) mixer is used, 100g clay, 0.8g modified starches are mixed, obtain mixture C；
4) mechanical agitation is used, the first that will be obtained in 1.2g polyurethane, 0.8g lignocellulosics, 70g water and 5g steps 2)
Aldehyde cleanser stirs evenly, and obtains mixture D；
5) mixture D obtained in step 4) is added in the mixture C obtained in step 3), adds 0.05g and gather
Ethylene glycol, is mixed 60 minutes under the speed of 500rpm using mixer, then using extruded type forming machine integrated molding, obtained
To having the function of the china clay material of purifying formaldehyde.
Embodiment 4：There is the preparation of the cement material of purifying formaldehyde.
1) use ball mill, by 6g polyvinylpyrrolidones and 4g polyacrylamides under the speed of 800rpm ball milling mixing
30 minutes, obtain mixture A；
2) by 3g titanium dioxide, 3g stannic oxides, 3g silica, 4g magnesia, 6g activated carbons, 4g calcium chloride, 6g second
Sour three butanol of sodium and 20g N- methyl-N-ethylaminos is added in the mixture A obtained in step 1), in the speed of 800rpm
Lower ball milling mixing 30 minutes, obtains mixture B, is filtered by 200 mesh filter screens, obtains formaldehyde purifying agent；
3) mixer is used, 100g cement, 1g modified starches are mixed, obtain mixture C；
4) mechanical agitation is used, by what is obtained in 1.5g vinyl acetates, 1g lignocellulosics, 75g water and 20g steps 2)
Formaldehyde purifying agent stirs evenly, and obtains mixture D；
5) mixture D obtained in step 4) is added in the mixture C obtained in step 3), adds 0.1g tea soaps
Plain foaming agent, 30 minutes are mixed using mixer under the speed of 1000rpm, then using extruded type shaping it is machine integrated into
Type, obtains the cement material with purifying formaldehyde.
Embodiment 5：There is the preparation of the gypsum material of purifying formaldehyde.
1) use ball mill, by 2g polyvinylpyrrolidones and 1g polyethylene glycol under the speed of 300rpm ball milling mixing 60
Minute, obtain mixture A；
2) by 2g titanium dioxide, 2g stannic oxides, 5g silica, 2g magnesia, 1g activated carbons, 1g calcium chloride, 1g carbon
Sour sodium and 4g 1,2-dimethylaminoethanol are added in the mixture A obtained in step 1), and ball milling mixes under the speed of 300rpm
Close 120 minutes, obtain mixture B, filtered by 200 mesh filter screens, obtain formaldehyde purifying agent；
3) formaldehyde purifying agent obtained in 5g steps 2) is added in 500g water, is disperseed by way of ultrasonic vibration
It is even, obtain purifying formaldehyde liquid；
4) the purifying formaldehyde liquid obtained in step 4) is brushed on the plasterboard of 1m × 1m repeatedly, obtained net with formaldehyde
Change the gypsum material of function.
Embodiment 6：The purifying formaldehyde effect experiment of building and ornament materials in the present invention.
The building and ornament materials in 50g embodiments 1~5 are weighed respectively as sample to be tested, while according to CN103351151
Described in method prepare corresponding material and weigh 50g as parallel control product.
The center of enclosed experiment device is placed in micropore box except formaldehyde products are respectively charged into by above-mentioned, adds 3.3 μ
Shutoff device door, opening warm table, unlatching fan stir immediately after 30% formaldehyde liquid of l so that formaldehyde gas is uniformly distributed
In whole experimental provision, while the formaldehyde gas concentration in experimental provision is recorded using formaldehyde sensor in real time, and under
Formula calculates formaldehyde removal rate (%)：Formaldehyde removal rate=(C0-Ct)/C0× 100%, wherein：C0For initial content, CtFor certain moment
Real-time content, corresponding experimental result is as shown in Figure 2.
As shown in Figure 2, the curve of existing product removal formaldehyde is substantially linear, shows over time at the uniform velocity
The situation of removal, when experimental period is 50 minutes, formaldehyde removal rate can reach 44% or so.In contrast, the building of the present invention
Ornament materials can just reach more than 80% formaldehyde removal rate testing in initial 4~6 minutes.It is it can be seen from the above that of the invention
Building and ornament materials possess the quick, function of high-efficient purification formaldehyde really.
Claims (9)
1. a kind of have the function of the building and ornament materials of purifying formaldehyde, it is made of following ingredients in parts by weight：1~20 part
Formaldehyde purifying agent, 100 parts of base materials, 0.5~1 portion of modified starch, 1~1.5 part of bonding agent, 0.6~1 part of lignocellulosic, 0.01
~0.1 part of foaming agent and 65~75 parts of water compositions；Wherein：
The formaldehyde purifying agent is made of following ingredients in parts by weight：2~10 parts of polyvinylpyrrolidones, 1~6 part it is water-soluble
Property high-molecular compound, 4~42 parts of chiral amino alcohols, 1~7 part of titanium dioxide, 1~7 part of stannic oxide, 1~7 part of titanium dioxide
The soluble salt of weak acid of silicon, 2~6 parts of magnesia, 1~13 part of activated carbon, 1~9 part of calcium chloride and 1~13 part.
2. according to claim 1 have the function of the building and ornament materials of purifying formaldehyde, it is characterised in that：
The water-soluble high-molecular compound is selected from polyethylene glycol, polyacrylamide, polyacrylic acid, carboxymethyl cellulose, polyoxy
Change any one or more mixture formed with arbitrary proportion in ethene, polyvinyl alcohol, polymethylacrylic acid.
3. according to claim 1 have the function of the building and ornament materials of purifying formaldehyde, it is characterised in that：
The chiral amino alcohol is selected from 1,2- dimethylaminoethanol, 2,3- dimethylaminos propyl alcohol, 1,2- diethylaminoethanols, 1,2-
Diphenylamino ethanol, 1,2,2- triphenyl -1,2- diaminourea ethanol, 2,2- diethyl -1,2- diaminourea ethanol, N- methyl-N-
Any one or more mixture formed with arbitrary proportion in three butanol of ethylamino.
4. according to claim 1 have the function of the building and ornament materials of purifying formaldehyde, it is characterised in that：
Solubility salt of weak acid the appointing in carbonate, bicarbonate, sulphite, silicate, saturated monocarboxylic acid salt
The one or more mixtures formed with arbitrary proportion of meaning.
5. according to claim 1 have the function of the building and ornament materials of purifying formaldehyde, it is characterised in that：
The base material is powdered base material, including land plaster, powder of lacquer putty for use on, cement and clay.
6. according to claim 1 have the function of the building and ornament materials of purifying formaldehyde, it is characterised in that：
The bonding agent is aqueous adhesive, including polyvinyl alcohol aqueous adhesive, vinyl acetate esters aqueous adhesive, third
Olefin(e) acid class aqueous adhesive, polyurethanes aqueous adhesive, epoxy resin aqueous adhesive, phenolic resin class aqueous adhesive
With organic silicon aqueous adhesive.
7. according to claim 1 have the function of the building and ornament materials of purifying formaldehyde, it is characterised in that：
The foaming agent includes rosin tree epoxy-type foaming agent, surfactant type foaming agent, protein active thing type foaming agent and answers
Mould assembly foaming agent.
A kind of 8. preparation with the building and ornament materials of purifying formaldehyde according to any one of claim 1 to 7
Method, it includes the following steps：
1) by the polyvinylpyrrolidone of formula ratio and water-soluble high-molecular compound ball milling mixing, mixture A is obtained；
2) by the titanium dioxide of formula ratio, stannic oxide, silica, magnesia, activated carbon, calcium chloride, soluble salt of weak acid
Ball milling mixing in the mixture A obtained in step 1) is added to chiral amino alcohol, obtains mixture B, by 200~300 mesh
Strainer filtering, obtains formaldehyde purifying agent；
3) base material of formula ratio and modified starch are mixed, obtains mixture C；
4) formaldehyde purifying agent obtained in the bonding agent of formula ratio, lignocellulosic, water and step 2) is stirred evenly, is mixed
Compound D；
5) mixture D obtained in step 4) is added in the mixture C obtained in step 3), adds the foaming of formula ratio
Agent mixes, and by integrated molding, obtains the building and ornament materials with purifying formaldehyde.
9. preparation method according to claim 8, it is characterised in that：
Ball milling mixing is completed by ball mill described in step 1), and speed is 300~800rpm, and the time is 30~60 minutes；
Ball milling mixing is completed by ball mill described in step 2), and speed is 300~800rpm, and the time is 30~120 minutes；
Mixing is completed by mixer described in step 3)；
Stirring is completed by mechanical stirring device or magnetic stirring apparatus described in step 4)；
Mixing is completed by mixer described in step 5), and speed is 200~1000rpm, and the time is 30~90 minutes；
Integrated molding described in step 5) is completed by extruded type forming machine.
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| CN108676374A (en) * | 2018-05-05 | 2018-10-19 | 安徽乐金环境科技有限公司 | A kind of preparation method of the cellular plastic of catalytic degradation formaldehyde |
| CN108671744A (en) * | 2018-05-05 | 2018-10-19 | 安徽乐金环境科技有限公司 | A kind of preparation method of anion formaldehyde catalytic purification agent |
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| CN108794882A (en) * | 2018-05-16 | 2018-11-13 | 黄欣 | A kind of architectural decoration environment-friendly materials and preparation method thereof |
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| EP3747848A1 (en) * | 2019-06-07 | 2020-12-09 | Marius Bierig | Thoron-reducing and room air improving activated carbon admixture for loam plaster systems |
| CN113984753A (en) * | 2021-11-04 | 2022-01-28 | 长春美泰仪器有限公司 | Formaldehyde detection test paper, preparation method thereof and formaldehyde detection system |
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