CN107952340A - A kind of low-temperature denitration method - Google Patents

A kind of low-temperature denitration method Download PDF

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Publication number
CN107952340A
CN107952340A CN201711181233.6A CN201711181233A CN107952340A CN 107952340 A CN107952340 A CN 107952340A CN 201711181233 A CN201711181233 A CN 201711181233A CN 107952340 A CN107952340 A CN 107952340A
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CN
China
Prior art keywords
cathode
fixedly connected
frame plate
pipe frame
voltage
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711181233.6A
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Chinese (zh)
Inventor
李连清
夏飞
李瑞龙
林凡昌
康艳艳
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SHANDONG LIAOCHENG SANYANG ENVIRONMENTAL PROTECTION INDUSTRY Co Ltd
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SHANDONG LIAOCHENG SANYANG ENVIRONMENTAL PROTECTION INDUSTRY Co Ltd
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Application filed by SHANDONG LIAOCHENG SANYANG ENVIRONMENTAL PROTECTION INDUSTRY Co Ltd filed Critical SHANDONG LIAOCHENG SANYANG ENVIRONMENTAL PROTECTION INDUSTRY Co Ltd
Priority to CN201711181233.6A priority Critical patent/CN107952340A/en
Publication of CN107952340A publication Critical patent/CN107952340A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/32Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
    • B01D53/323Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 by electrostatic effects or by high-voltage electric fields
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • B01D2257/404Nitrogen oxides other than dinitrogen oxide
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

A kind of low-temperature denitration method, is to lure that the NO in flue gas is decomposed into N and O into using high voltage pulse electric field, and then synthesizes nitrogen and oxygen, realizes the purpose of inexpensive pollution-free low temperature denitration, and has dust removing effects concurrently.Its structure is:In body (2), it is fixedly connected with cathode pipe frame plate (4) and lower cathode pipe frame plate (7), cathode tube (5) is fixedly connected with therebetween, the heart wherein, there are anode screw rod (6) or prickle bar (26), the high pressure line (10) for the other end for pressing through wall porcelain vase (11) with height by Anodic frame (3) or lower anode frame (8) is electrically connected, and the other end of high pressure line (10) is electrically connected with the high-voltage output end of pulsed high voltage generator (13) or high-frequency and high-voltage impulse power supply (27).Its input terminal is electrically connected with utility grid (29).

Description

A kind of low-temperature denitration method
Technical field:
Nitric oxide production method in industrial smoke is eliminated and reduced the present invention relates to one kind.
Background technology:
Gas denitrifying technology can be divided into two major class of dry and wet, the wherein selective catalytic reduction in Dry denitration at present (SCR) and selective non-catalytic reduction (SNCR) technology be market most widely used (accounting for 80% denitrating flue gas market), technology most Ripe denitration technology, its principle are the spray reducing agents such as ammonium hydroxide or urea into flue gas, direct at high temperature (or the association of catalyst With under) with flue gas in NOx occur redox reaction, NOx is reduced into nitrogen and water.But the technology also has its very big office Sex-limited, since chemical reaction needs to carry out at high temperature, and for medium small boiler and Industrial Boiler, exhaust gas temperature is remote The required high temperature of chemical reaction cannot be reached, so, denitration effect is bad during low temperature.In addition, even if high-temperature boiler denitration is imitated When fruit is good, the reducing agents such as substantial amounts of ammonia or urea are also consumed, by taking the 2500t/d line denitrations of 18, Chongqing as an example, to reality The target of ten thousand tons of emission reduction NOx2 now, then must use SNCR denitration, if selection ammonium hydroxide (concentration 25%) is used as reducing agent, year More than 60,000 tons of ammonium hydroxide, or 1.5 ten thousand tons of urea of consumption need to be consumed.And produce these ammonia or urea and consume 2.6 ten thousand tons of coal again and while produce Raw many other pollutant (23.36 tons of COD, 9.3 tons of ammonia nitrogen, 0.047 ton of cyanide, 10.9 tons of SS, petroleum-types 1.56 tons, 0.031 ton of volatile phenol, 0.156 ton of sulfide, 150,000 tons of water), so again can produce some new pollutions at the same time.Ammonia Water or urea are all the fertilizer for the increasing crop yield that people painstakingly fix and capture from air with consuming resource, now But they are bred calamities for the future again to return to its owner in good conditions and becomes nitrogen again and be discharged into air, be the caving-in bash lost more than gain really.
The content of the invention:
The present invention discloses a kind of method that low-temperature denitration is realized using high-frequency impulse high voltage electric field, it is therefore an objective to:Do not make On the premise of with consumptive material, the denitration of industrial waste gas is realized with simpler method.
Technical solution is:Allow the low-temperature flue gas with nitre more out of a large cylindrical container and the equipotential pipe of container By the way that every tube center is provided with thorniness screw rod one longer than pipe and with pipe insulating, and screw rod upper end is with in sub End is all fixed on two similar shelfs of size, and the shelf on top connects with supporting the porous plate of pipe to be fixed by high-tension porcelain insulator Connect, or the shelf corner on top presses through the fixation suspention connection of wall porcelain insulator by insulator or height, and wall insulation porcelain is pressed through in height The top of bottle is passed through high-frequency impulse high-voltage electricity.Thorniness screw rod is vacantly hanging in the center of pipe, the shelf of lower part;In the middle part of screw rod Position, by every group of two nuts, grip the multiple claw type electrode slices of connection, claw type electrode slice is the stainless steel of multijaw Piece, on every screw rod, is fixed with 20~200 claw type electrode slices and forms thorniness, or use commercially available prickle bar.
Under high-frequency impulse high-voltage electricity is drawn by the high top for pressing through wall porcelain insulator, make thorniness screw rod or prickle bar powered. After energization, between claw type electrode slice on screw rod and the pipe for connecing power cathode, high-frequency impulse high voltage electric field will be formed, when When band nitre (NOx, wherein NO account for more than 90%) flue gas is by the high voltage pulse electric field, the unstable NO in flue gas will be decomposed For nomadic nitrogen and free oxygen, and then form N2 and O2, realize the purpose without using the consumptive material denitration such as ammonium hydroxide and urea.Experiment card Bright, the present invention must use high-frequency impulse high voltage electric field just effective, if using direct current constant electric field, regardless of voltage levels or polarity How, at all can not denitration, can only produce the effect of electrostatic precipitation.
The present invention declare patent on the same day and meanwhile declared two different utility model patents, title is respectively:" arteries and veins Leap high piezoelectric field low-temperature denitration device " and " high voltage pulse electric field low-temperature denitration and cleaner ".
The claimed technical characteristic of the present invention is:In the body, cathode pipe frame plate and lower cathode tube are fixedly connected with Frame plate, between upper cathode pipe frame plate and lower cathode pipe frame plate, is fixedly connected with cathode tube, in cathode tube hub, there is anode spiral shell Bar or prickle bar, anode screw rod or prickle bar upper end are fixedly connected with Anodic frame, its lower end is fixedly connected with lower anode frame, on Anode frame presses through wall porcelain vase with high-tension porcelain insulator or height and is fixedly connected, and the other end that height presses through wall porcelain vase is electrically connected with high pressure line, The other end of high pressure line is electrically connected with the high-voltage output end of pulsed high voltage generator or high-frequency and high-voltage impulse power supply, pulsed high-voltage The input terminal of source or high-frequency and high-voltage impulse power supply is electrically connected with utility grid.
The beneficial effects of the invention are as follows:
1. the present invention's breaks a new path to realize not consuming ammonium hydroxide and urea and carry out low-temperature denitration.
2. economize on electricity, water-saving, power consumption saves, substantially not water consumption, and denitration cost is low, easy to spread.
Brief description of the drawings:It is described with reference to the drawings below:
Fig. 1 is the generally longitudinally sectional view of the embodiment of the present invention 1.
Fig. 2 is the enlarged partial sectional view of Fig. 1 upper left corners of the present invention circled.
Fig. 3 is the generally longitudinally sectional view of the embodiment of the present invention 2.
Fig. 4 is the enlarged partial sectional view of Fig. 3 upper left corners of the present invention circled.
Fig. 5 is the electrical connection diagram of the embodiment of the present invention 2.
In figure:Flange disk on 1., 2. bodies, 3. Anodic framves, cathode pipe frame plate on 4., 5. cathode tubes, 6. anodes Screw rod, 7. times cathode pipe frame plates, 8. times anode frames, 9. lower interface ring flanges, 10. high pressure lines, 11. height press through wall porcelain vase, and 12. High-voltage output line, 13. pulsed high voltage generators, 14. iron casees, 15. high-tension porcelain insulators, 16. claw type electrode slices, 17. nuts, 18. smoke evacuations Mouthful, 19. spray tube arrays, 20. insulator branch cylinders, 21. hush panels, 22. smoke inlets, 23. bottom plates, 24. sewage draining valves, 25. peaces Tubulature, 26. prickle bars, 27. high-frequency and high-voltage impulse power supplies, 28. electric power incoming lines, 29. utility grids, Z. weights.
Embodiment
Embodiment 1
The embodiment of the present invention 1 is shown in Fig. 1, Fig. 2, including upper flange disk 1, body 2, Anodic frame 3, upper cathode pipe frame plate 4, cathode tube 5, anode screw rod 6, lower cathode pipe frame plate 7, lower anode frame 8, lower interface ring flange 9, high pressure line 10, height presses through wall Porcelain vase 11, high-voltage output line 12, pulsed high voltage generator 13, iron case 14, high-tension porcelain insulator 15, claw type electrode slice 16, nut 17.
Upper flange disk 1 and lower interface ring flange 9 are shape, the identical part of specification, are a paripheral zone circles The circular ring shape plate in hole, is made of metallic plate or fiberglass, is fixedly connected with body 2, and body 2 is a cylindrical hollow container, It is made of metallic plate or fiberglass, top and the bottom are tapered, suitable for reading to be fixedly connected with upper flange disk 1, lower mouth and lower interface Ring flange 9 is fixedly connected, and in body 2, is fixedly connected with cathode pipe frame plate 4 and lower cathode pipe frame plate 7, upper cathode pipe frame plate 4 and lower cathode pipe frame plate 7 be shape, specification, the identical part of size, be a circular slab with array of circular apertures, by gold Belong to plate or electroconductive frp (glass fiber reinforced plastic surface graphite spraying layer) is made, be around fixedly connected with body 2, in upper cathode pipe frame plate Between 4 and lower cathode pipe frame plate 7, cathode tube 5 is fixedly connected with, cathode tube 5 is the circle made of metallic plate or electroconductive frp Pipe, the upper end are fixedly connected with upper cathode pipe frame plate 4, and lower end is fixedly connected with lower cathode pipe frame plate 7, in upper cathode pipe frame plate 4 Top, is fixedly connected with 4 high-tension porcelain insulators 15, and high-tension porcelain insulator 15 is commercially available finished product, above high-tension porcelain insulator 15, is fixedly connected with Anodic frame 3, Anodic frame 3 and lower anode frame 8 are shape, specification, the identical part of size, are welded with stainless steel square tube The more gridirons being connected into, the infall of more gridirons are drilled with hole, anode screw rod 6 are fixedly connected with hole, and anode screw rod 6 is stainless steel Screw rod, upper end are fixed on Anodic frame 3, and middle part is vacantly at 5 center of cathode tube, and lower end is fixed on lower anode frame 8, at middle part Cathode tube 5 inside place, by every group of two nuts 17, grip one claw type electrode slice 16 (see Fig. 2) of connection, pawl Shape electrode slice 16 is that the multijaw profile of center band circular hole is the polygon stainless steel substrates of subcircular, fixed on every anode screw rod 6 It is connected with 20~200 claw type electrode slices 16.
In the lower outside of body 2, iron case 14 is fixedly connected with, iron case 14 is to use square iron case made of metallic plate, In iron case 14, pulsed high voltage generator 13 is fixedly connected with, which is commercially available finished product, the pulsed high voltage generator The pulsed high-voltage of 13 outputs presses through wall porcelain vase 11 and high pressure line 10 by high-voltage output line 12, height, is electrically connected to lower anode On frame 8.
In use, lower interface ring flange 9 is fixedly attached on outlet flue, upper flange disk 1 can cigarette receiving chimney, as long as will Pulsed high voltage generator 13 accesses power grid for powering on, and between the claw type electrode slice 16 and cathode tube 5 on anode screw rod 6, will produce Raw high voltage pulse electric field, when flue gas is by the high voltage pulse electric field, the NO in flue gas will be decomposed into nomadic nitrogen and free oxygen, And then nitrogen and oxygen are formed, realize the purpose without using the consumptive material denitration such as ammonium hydroxide and urea.This example can realize plural serial stage With depth denitration.
Embodiment 2
See Fig. 3,4,5, the difference with embodiment 1 is:Spray tube array 19 is introduced, spray tube array 19 is passed through by water pipe The logical array being formed by connecting, end are blocked, are drilled with spray apertures below, are around fixedly connected on the inner wall of body 2, right end export Outside body 2, and then it is connected with 10 through connection of water inlet pipe, water inlet pipe 10 by valve (being not shown on figure) with tap water.In this way, The dust adsorbed on anode screw rod 6 and cathode tube 5 can be rinsed after a loss of power, since the water after flushing can destroy insulation, So height presses through wall porcelain vase 11, high pressure line 10, high-tension porcelain insulator 15, these are afraid of that wet element cannot be installed on inside, but The insulator branch cylinder 20 in installing pipe 25 is fixedly connected on by 4 installing pipes 25 for being fixedly connected on 2 surrounding of body, and perforation To realize insulation, high pressure line 10 is also from the output terminal of exterior high-frequency and high-voltage impulse power supply 27, by high pressure line 10, directly Guide to the high top for pressing through wall porcelain vase 11.Concrete structure is:In the top surrounding of body 2, perforation is fixedly connected with 4 installing pipes 25, installing pipe 25 be with 2 same material of body made of circular cylinder, outer end is formed with ring flange, and installing pipe 25 is to install Shangyang Pole frame 3 and set, once install, the central macropore of the ring flange of 25 termination of installing pipe to be closed using hush panel 21 with Leakproof cigarette, hush panel 21 are circular slabs made of one piece and 2 same material of body, and bolt and nut and installing pipe 25 are used before being completed The ring flange of termination is fixedly connected.On the top of installing pipe 25, also through connection has insulator branch cylinder 20, and insulator branch cylinder 20 is With 2 same material of body made of top closing circular cylinder (cup-shaped of handstand), in wherein 3 insulator branch cylinders 20 The heart, is all fixedly connected with a high-tension porcelain insulator 15, the center of another insulator branch cylinder 4 (Fig. 3 top lefts that), is fixedly connected One height presses through wall porcelain vase 11, and it is all commercially available finished product that high-tension porcelain insulator 15 and height, which press through wall porcelain vase 11, and high-tension porcelain insulator 15 and height press through Wall porcelain vase 11 has electric heater unit to prevent humidity, and height presses through in wall porcelain vase 11 and is provided with screw rod.Height presses through wall porcelain vase 11 Screw rod upper end is electrically connected with high pressure line 10, the lead-out terminal of another termination high-frequency and high-voltage impulse power supply 27 of high pressure line 10, The importation of high-frequency and high-voltage impulse power supply 27 is electrically connected by electric power incoming line 28 with utility grid 29.High-frequency and high-voltage impulse power supply 27 It is commercially available finished product.
Element arrangements, structure inside body 2 are substantially the same manner as Example 1, except that:It is fixed on Anodic frame 3 Anode screw rod 6 between lower anode frame 8, is changed to prickle bar 26,26 internal layer of prickle bar is stainless steel thin bar, and outer layer is formed with crowded The irregular lead prickle gone out, belongs to commercially available finished product, and the upper end is fixed on Anodic frame 3, and middle part is vacantly in cathode tube 5 The heart, lower end are fixed on lower anode frame 8, and bottom is also fixedly connected with weight Z.
In addition difference is:The structure of the top and bottom of body 2 is different, 2 top and bottom shape of body in embodiment 1, Size is identical, can so conveniently realize multi-section serial to improve denitration efficiency, and embodiment 2 is due to introducing spray Pipe array 19, to handle the dirt swept away by shower water, inclined, flat bottom plate 23 is made in lower part, and high side is installed into cigarette Mouth 22, low side (on the left of Fig. 3) installation sewage draining valve 24, concrete structure are:It is fixed at 2 bottom side of body (on the right side of Fig. 3) Through connection has a smoke inlet 22, smoke inlet 22 be with 2 same material of body made of penetrate through circular cylinder, the other end of smoke inlet 22 Connect boiler flue outlet or other equipment.In 2 bottom of body, bottom plate 23 is formed with, bottom plate 23 is made of and 2 same material of body Tablet, convenient for blowdown, bottom plate 23 tilts installation.Opposite side in 2 bottom of body, fixed through connection have sewage draining valve 24, sewage draining valve 24 is commercially available finished product, and the dirt for manually periodically being swept away the water sprayed by spray tube array 19 can be relied on to arrange Go out.
In use, smoke inlet 22 is fixedly attached on the outlet flue of original equipment, smoke outlet 18 can cigarette receiving chimney, as long as will High-frequency and high-voltage impulse power supply 27 accesses utility grid 29 for powering on, and device can work.Principle is same as above, and is repeated no more.

Claims (1)

1. a kind of low-temperature denitration method, including upper flange disk (1), body (2), upper cathode carrier (3), upper cathode pipe frame plate (4), cathode tube (5), cathode screw rod (6), lower cathode pipe frame plate (7), lower cathode carrier (8), lower interface ring flange (9), high pressure connect Line (10), height press through wall porcelain vase (11), high-voltage output line (12), pulsed high voltage generator (13), iron case (14), high-tension porcelain insulator (15), claw type electrode slice (16), nut (17), smoke outlet (18), spray tube array (19), insulator branch cylinder (20), hush panel (21), smoke inlet (22), bottom plate (23), sewage draining valve (24), installing pipe (25), prickle bar (26), high-frequency and high-voltage impulse power supply (27), electric power incoming line (28), utility grid (29), it is characterised in that in body (2), be fixedly connected with cathode pipe frame plate (4) With lower cathode pipe frame plate (7), between upper cathode pipe frame plate (4) and lower cathode pipe frame plate (7), cathode tube (5) is fixedly connected with, At cathode tube (5) center, there are anode screw rod (6) or prickle bar (26), anode screw rod (6) or prickle bar (26) upper end and Anodic Frame (3) is fixedly connected, its lower end is fixedly connected with lower anode frame (8), and Anodic frame (3) presses through wall with high-tension porcelain insulator (15) or height Porcelain vase (11) is fixedly connected, and the other end that height presses through wall porcelain vase (11) is electrically connected with high pressure line (10), high pressure line (10) The other end is electrically connected with the high-voltage output end of pulsed high voltage generator (13) or high-frequency and high-voltage impulse power supply (27), pulsed high voltage generator (13) or the input terminal of high-frequency and high-voltage impulse power supply (27) is electrically connected with utility grid (29).
CN201711181233.6A 2017-11-14 2017-11-14 A kind of low-temperature denitration method Pending CN107952340A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111939710A (en) * 2020-09-03 2020-11-17 中钢集团天澄环保科技股份有限公司 Top vertical air intake electrostatic fabric filter
CN115839547A (en) * 2022-06-30 2023-03-24 湖北信业热能工程有限公司 Hot blast stove for flue gas desulfurization and denitration emission

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1185988A (en) * 1997-11-28 1998-07-01 复旦大学 Technology for treating low temperature plasma waste gas
CN102371888A (en) * 2011-06-24 2012-03-14 北京大学 Vehicle-mounted plasma generator for purifying nitric oxide in vehicle tail gas
CN102935326A (en) * 2012-11-10 2013-02-20 大连理工大学 Array-type narrow-gap coaxial streamer discharge reactor for gaseous pollutant pretreatment
CN104437017A (en) * 2013-09-18 2015-03-25 北京达特集成技术有限责任公司 Plasma waste-gas treatment device with self-flushing function
CN106907215A (en) * 2017-02-27 2017-06-30 上海必修福企业管理有限公司 A kind of apparatus and method for processing engine discharging tail gas
CN206500014U (en) * 2016-12-29 2017-09-19 南京西普环保科技有限公司 A kind of low-temperature plasma Benitration reactor

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1185988A (en) * 1997-11-28 1998-07-01 复旦大学 Technology for treating low temperature plasma waste gas
CN102371888A (en) * 2011-06-24 2012-03-14 北京大学 Vehicle-mounted plasma generator for purifying nitric oxide in vehicle tail gas
CN102935326A (en) * 2012-11-10 2013-02-20 大连理工大学 Array-type narrow-gap coaxial streamer discharge reactor for gaseous pollutant pretreatment
CN104437017A (en) * 2013-09-18 2015-03-25 北京达特集成技术有限责任公司 Plasma waste-gas treatment device with self-flushing function
CN206500014U (en) * 2016-12-29 2017-09-19 南京西普环保科技有限公司 A kind of low-temperature plasma Benitration reactor
CN106907215A (en) * 2017-02-27 2017-06-30 上海必修福企业管理有限公司 A kind of apparatus and method for processing engine discharging tail gas

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111939710A (en) * 2020-09-03 2020-11-17 中钢集团天澄环保科技股份有限公司 Top vertical air intake electrostatic fabric filter
CN115839547A (en) * 2022-06-30 2023-03-24 湖北信业热能工程有限公司 Hot blast stove for flue gas desulfurization and denitration emission
CN115839547B (en) * 2022-06-30 2023-12-26 湖北信业热能工程有限公司 Hot-blast stove for desulfurizing and denitrating flue gas

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Application publication date: 20180424