CN107938412A - A kind of efficiently Winestock machine and its application process - Google Patents

A kind of efficiently Winestock machine and its application process Download PDF

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Publication number
CN107938412A
CN107938412A CN201711161647.2A CN201711161647A CN107938412A CN 107938412 A CN107938412 A CN 107938412A CN 201711161647 A CN201711161647 A CN 201711161647A CN 107938412 A CN107938412 A CN 107938412A
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CN
China
Prior art keywords
deinking
level
waste paper
room
ink
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CN201711161647.2A
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Chinese (zh)
Inventor
龙海燕
林茂兰
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CHANGZHOU SIYU ENVIRONMENTAL PROTECTION MATERIAL TECHNOLOGY Co Ltd
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CHANGZHOU SIYU ENVIRONMENTAL PROTECTION MATERIAL TECHNOLOGY Co Ltd
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Priority to CN201711161647.2A priority Critical patent/CN107938412A/en
Publication of CN107938412A publication Critical patent/CN107938412A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • D21C5/005Treatment of cellulose-containing material with microorganisms or enzymes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21CPRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
    • D21C5/00Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
    • D21C5/02Working-up waste paper
    • D21C5/025De-inking
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/64Paper recycling

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Microbiology (AREA)
  • Paper (AREA)

Abstract

The present invention relates to a kind of efficient Winestock machine, belong to Deinking Technology field.The present invention makes ink in waste paper paper fiber upper process in mechanical oscillation and high temperature double action first, acted on cellulase in projection, so that ink and interfibrous connection become slack, the dissociation solution containing Natural surfactant component lecithin is recycled to completely disengage ink and fiber, then adsorbed and expected by hydro-thermal method synthesis hydrotalcite-like material, again with plants essential oil and tea polyphenols under the action of microorganism, houghite surface is modified, increase the oil loving ester group in houghite surface and alkyl quantity, adsorption capacity of the houghite to ink is further improved by the property of similar compatibility, obtain self-control deinking agent, the ink adsorbing and removing being finally kept completely separate with self-control deinking liquid with fiber, environment will not be polluted after deinking, have a extensive future.

Description

A kind of efficiently Winestock machine and its application process
Technical field
The present invention relates to a kind of efficiently Winestock machine and its application process, belong to Deinking Technology field.
Background technology
It is to solve paper industry to face that there is lack of raw materials, energy shortage and seriously polluted three major issues that waste paper, which recycles, Effective way.Waste paper recycling is exactly the other components available paper cellulose from paper(As ink, pigment, inorganic filler, Laser toner particle, adhesive etc.)In separate, to waste paper carry out regeneration treatment process.At present, waste paper becomes and makes The important source material source of paper industry, proportion are increasing.Pulping and paper-making is carried out using waste paper, substantial amounts of wood can be saved Material, reduces production cost, mitigates contaminated wastewater, reduces environmental protection investments, reduces water and energy consumption.
An important link is exactly deinking in waste paper pulp-making.At present, there are power consumption for the Mechanical Method of deinking Greatly, deinking efficiency is poor, slurry drainability is bad, whiteness is low, pulp quality cannot be guaranteed, only as a kind of auxiliary law application, Produce many drawbacks such as the difficult removal of sicker, the easy fouling of equipment.
Therefore, invent a kind of efficiently Winestock machine has positive meaning to Deinking Technology field.
The content of the invention
Present invention mainly solves technical problem:For in common mechanical de-inking method at present there are power consumption it is big, The defects of deinking efficiency is poor, whiteness is low, pulp quality cannot be guaranteed, there is provided a kind of efficiently Winestock machine and its application Method.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention:
A kind of efficient Winestock machine, including vibration rolling motor, curtain rolling shaft, roller shutter band, paper feed port, level-one deinking room, two Level deinking room, three-level deinking room, level Four deinking room, ink outlet port, it is characterised in that:Roller shutter band bottom carries folder, level-one deinking Room side wall is equipped with water spray projector, electromagnetic heater and enzyme liquid injector on from lower on the side wall of two level deinking room, Equipped with dissociation fluid injector on the side wall of three-level deinking room, deinking fluid injector and ultraviolet lamp are on from lower installed in the bottom On the side wall of level Four deinking room.
A kind of efficiently application process of Winestock machine is:The waste paper vertical folder for treating deinking is made on folder first It is naturally drooped, Vibration on Start-up rolling motor, and the waste paper of clamping is in vibrational state under the action of rolling motor is vibrated, at the same time Vibration rolling motor is by controlling curtain rolling shaft to drive roller shutter band that clamping being treated, deinked waste paper falls into level-one deinking room by paper feed port In, water spray projector starts, and sprays deionized water to the waste paper surface for treating deinking, after stopping 2min in level-one deinking room, volume Curtain band treats that deinked waste paper continues to drop in two level deinking room by clamping, and the electromagnetism positioned at two level deinking room side wall upper part point adds Hot device, which starts to treat deinked waste paper, carries out heating 10min, makes ink in waste paper paper fiber in mechanical oscillation and high temperature double action Upper process, after heating, starts enzyme liquid injector to deinked waste paper surface spraying cellulase solution 5min is treated, uses cellulose Enzyme effect is in projection so that ink and interfibrous connection become slack, and 30min is stood after sprinkling, is continued clamping Treat that deinked waste paper is dropped in three-level deinking room, dissociate fluid injector at this time and start, to treating deinked waste paper surface spraying dissociation solution 5min, completely disengages ink and fiber using dissociation solution, and clamping being treated, deinked waste paper drops to level Four and takes off after spray Deinking liquid spray is being treated deinked waste paper surface 3min, is utilizing demoulding by ink chamber, the deinking fluid injector on the side wall of level Four deinking room Liquid by the ink being kept completely separate with fiber adsorb, be again started up water spray projector to treat deinked waste paper surface spraying deionized water rush 10min is washed, the ink that liquid parting adsorbs is washed off, finally deinked waste paper 20min is treated with ultra violet lamp, is arranged by ink outlet port Go out the ink of removing, you can obtain deinked waste paper.
Water spray projector, electromagnetic heater, enzyme liquid injector, dissociation fluid injector, deinking fluid injector and the purple Outer lamp respectively has two, is symmetrically distributed on device side wall.
The heating-up temperature of the electromagnetic heater is 70~80 DEG C.
The mass fraction for the cellulase solution that the enzyme liquid injector ejects is 30%.
The dissociation solution that the dissociation fluid injector ejects is the ethanol solution of lecithin, the matter of lecithin ethanol solution It is 20% to measure fraction.
The liquid parting that the deinking fluid injector ejects is that self-control deinking agent and water are 1 in mass ratio:5 is mixed Suspension, wherein the preparation method of self-control deinking agent is as follows:
(1)It is 1 in mass ratio by magnesium nitrate, aluminum nitrate and water:2:10 are mixed to get mixing salt solution, then by mixing salt solution, The urea liquid and potassium rhodanate and citric acid mixing that mass fraction is 30%, add in hydrothermal reaction kettle together, 0.8~ 18~20h is reacted under conditions of 1.0MPa and 160~170 DEG C, is separated by filtration to obtain filter residue;
(2)It is 2 in mass ratio:5:1 will be fitted into fermentation tank after porous magnetite powder, dried orange peel essential oil, tea polyphenols mixing, will send out Fermentation tank is placed in the insulating box that temperature is 25~30 DEG C and is sealed by fermentation 12~15 days, is separated by filtration to obtain fermentation production after fermentation Thing, up to self-control deinking agent after high-temperature sterilization.
The application of the present invention:Naturally droop it on folder the waste paper vertical folder for treating deinking first, Vibration on Start-up volume Curtain motor, the waste paper of clamping is in vibrational state under the action of rolling motor is vibrated, while vibrates rolling motor and pass through control Curtain rolling shaft drives roller shutter band that clamping being treated, deinked waste paper is fallen into level-one deinking room by paper feed port, and water spray projector starts, to Treat the waste paper surface sprinkling deionized water of deinking, after stopping 2min in level-one deinking room, roller shutter band treats that deinking is given up by clamping Paper continues to drop in two level deinking room, and the electromagnetic heater positioned at two level deinking room side wall upper part point starts to treat deinked waste paper Heating 10min is carried out, ink after heating, is opened in waste paper paper fiber upper process in mechanical oscillation and high temperature double action Dynamic enzyme liquid injector is acted in projection to deinked waste paper surface spraying cellulase solution 5min is treated with cellulase so that Ink and interfibrous connection become slack, and 30min is stood after sprinkling, continues clamping treating that deinked waste paper drops to three-level In deinking room, fluid injector is dissociated at this time and is started, to deinked waste paper surface spraying dissociation solution 5min is treated, makes ink using dissociation solution Completely disengaged with fiber, the deinked waste paper for the treatment of of clamping is dropped into level Four deinking room after spray, on the side wall of level Four deinking room Deinking fluid injector by deinking liquid spray treating deinked waste paper surface 3min, the oil that will be kept completely separate using liquid parting with fiber Ink absorption, is again started up water spray projector to deinked waste paper surface spraying deionized water rinsing 10min is treated, by liquid parting absorption Ink washes off, and finally treats deinked waste paper 20min with ultra violet lamp, by the ink of ink outlet port discharge removing, you can obtain Deinked waste paper.
The beneficial effects of the invention are as follows:
The present invention makes ink be acted on cellulase in waste paper paper fiber upper process in mechanical oscillation and high temperature double action first In projection so that ink and interfibrous connection become slack, and recycle the dissociation containing Natural surfactant component lecithin Liquid completely disengages ink and fiber, is then adsorbed and expected by hydro-thermal method synthesis hydrotalcite-like material, added in the pot of Hydrothermal Synthesiss Potassium rhodanate and citric acid, under the action of potassium rhodanate so that the metal ion in houghite leave original lattice into Enter into citric acid organic phase, so as to produce hole on houghite surface, the generation in hole is so that the absorption of houghite is lived Property increase, while the adsorption capacity of ink is also improved, then with plants essential oil and tea polyphenols under the action of microorganism, it is right Houghite surface is modified, and the oil loving ester group in increase houghite surface and alkyl quantity, pass through the property of similar compatibility Matter further improves adsorption capacity of the houghite to ink, obtains self-control deinking agent, finally with self-control deinking liquid will and fiber The ink adsorbing and removing being kept completely separate, stripper apparatus of the invention, ink removal efficiency is up to 92~97%, while Deinking Pulp is white Degree can reach 78.3~79.6%ISO, and the content of residual ink is down to 60~70ppm, and adhesive content is down to 69~82ppm, Environment will not be polluted after deinking.
Brief description of the drawings
Fig. 1 is the front elevation of " a kind of efficient Winestock machine " of the invention.
Wherein, 1, vibration rolling motor;2nd, curtain rolling shaft;3rd, roller shutter band;4th, folder;5th, paper feed port;6th, level-one deinking room;7、 Two level deinking room;8th, three-level deinking room;9th, level Four deinking room;10th, ink outlet port;11st, water spray projector;12nd, electromagnetic heater; 13rd, enzyme liquid injector;14th, fluid injector is dissociated;15th, deinking fluid injector;16th, ultraviolet lamp.
Embodiment
A kind of efficient Winestock machine, including vibration rolling motor 1, curtain rolling shaft 2, roller shutter band 3, paper feed port 5, level-one take off Ink chamber 6, two level deinking room 7, three-level deinking room 8, level Four deinking room 9, ink outlet port 10, it is characterised in that:3 bottom of roller shutter band carries Folder 4,6 side wall of level-one deinking room are equipped with water spray projector 11, and electromagnetic heater 12 and enzyme liquid injector 13 are on from lower installation On the side wall of two level deinking room 7, equipped with dissociation fluid injector 14,15 He of deinking fluid injector on the side wall of three-level deinking room 8 Ultraviolet lamp 16 is on from lower on the side wall of the level Four deinking room 9 of the bottom.A kind of application of efficiently Winestock machine Method is:Naturally droop it on folder 4 the waste paper vertical folder for treating deinking first, Vibration on Start-up rolling motor 1, clamping Waste paper be in vibrational state under the action of rolling motor 1 is vibrated, while vibrate rolling motor 1 by controlling 2 band of curtain rolling shaft Clamping is treated that deinked waste paper is fallen into level-one deinking room 6 by paper feed port 5 by dynamic roller shutter band 3, and water spray projector 11 starts, to waiting to take off The waste paper surface sprinkling deionized water of ink, after stopping 2min in level-one deinking room 6, roller shutter band 3 treats deinked waste paper by clamping Continue to drop in two level deinking room 7, start to treat deinking positioned at the electromagnetic heater 12 of 7 side wall upper part of two level deinking room point and give up Paper carries out heating 10min, makes ink in waste paper paper fiber upper process in mechanical oscillation and high temperature double action, after heating, Start enzyme liquid injector 13 to deinked waste paper surface spraying cellulase solution 5min is treated, acted on cellulase in projection, So that ink and interfibrous connection become slack, 30min is stood after sprinkling, continues clamping treating that deinked waste paper drops to In three-level deinking room 8, fluid injector 14 is dissociated at this time and is started, to deinked waste paper surface spraying dissociation solution 5min is treated, utilizes dissociation Liquid completely disengages ink and fiber, and clamping being treated, deinked waste paper drops to level Four deinking room 9, level Four deinking after spray Deinking liquid spray is being treated deinked waste paper surface 3min by deinking fluid injector 15 on 9 side wall of room, using liquid parting will and fiber The ink absorption being kept completely separate, is again started up water spray projector 11 to treating deinked waste paper surface spraying deionized water rinsing 10min, The ink that liquid parting adsorbs is washed off, finally deinked waste paper 20min is treated with the irradiation of ultraviolet lamp 16, is discharged by ink outlet port 10 de- The ink removed, you can obtain deinked waste paper.The water spray projector 11, electromagnetic heater 12, enzyme liquid injector 13, dissociation solution Injector 14, deinking fluid injector 15 and ultraviolet lamp 16 respectively have two, are symmetrically distributed on device side wall.The electromagnetic heating The heating-up temperature of device 12 is 70~80 DEG C.The mass fraction for the cellulase solution that the enzyme liquid injector 13 ejects is 30%.The dissociation solution that the dissociation fluid injector 14 ejects is the ethanol solution of lecithin, the quality of lecithin ethanol solution Fraction is 20%.The liquid parting that the deinking fluid injector 15 ejects is that self-control deinking agent and water are 1 in mass ratio:5 mixing Suspension afterwards, wherein the preparation method of self-control deinking agent is as follows:It is 1 in mass ratio by magnesium nitrate, aluminum nitrate and water:2:10 is mixed Conjunction obtains mixing salt solution, then mixing salt solution, the urea liquid that mass fraction is 30% and potassium rhodanate and citric acid are mixed Close, add together in hydrothermal reaction kettle, 18~20h, filtering point are reacted under conditions of 0.8~1.0MPa and 160~170 DEG C From obtaining filter residue;It is 2 in mass ratio:5:1 will be fitted into fermentation tank after porous magnetite powder, dried orange peel essential oil, tea polyphenols mixing, Fermentation tank is placed in the insulating box that temperature is 25~30 DEG C and is sealed by fermentation 12~15 days, is separated by filtration is sent out after fermentation Ferment product, up to self-control deinking agent after high-temperature sterilization.

Claims (7)

1. a kind of efficient Winestock machine, including vibration rolling motor(1), curtain rolling shaft(2), roller shutter band(3), paper feed port(5)、 Level-one deinking room(6), two level deinking room(7), three-level deinking room(8), level Four deinking room(9), ink outlet port(10), its feature exists In:Roller shutter band(3)Bottom carries folder(4), level-one deinking room(6)Side wall is equipped with water spray projector(11), electromagnetic heater (12)With enzyme liquid injector(13)On two level deinking room is installed on from lower(7)Side wall on, three-level deinking room(8)Side wall on Equipped with dissociation fluid injector(14), deinking fluid injector(15)And ultraviolet lamp(16)Taken off on from the lower level Four installed in the bottom Ink chamber(9)Side wall on.
2. a kind of application process of efficiently Winestock machine described in claim 1 is:It is first that the waste paper for treating deinking is vertical It is clipped in folder(4)On, naturally droop it, Vibration on Start-up rolling motor(1), the waste paper of clamping is in vibration rolling motor(1)'s Effect is lower to be in vibrational state, while vibrates rolling motor(1)By controlling curtain rolling shaft(2)Drive roller shutter band(3)By clamping Treat deinked waste paper by paper feed port(5)Fall into level-one deinking room(6)In, water spray projector(11)Start, to the waste paper table for treating deinking Deionized water is sprayed in face, in level-one deinking room(6)After middle stop 2min, roller shutter band(3)By clamping treat that deinked waste paper continues under Drop to two level deinking room(7)In, positioned at two level deinking room(7)The electromagnetic heater of side wall upper part point(12)Start to treat deinking and give up Paper carries out heating 10min, makes ink in waste paper paper fiber upper process in mechanical oscillation and high temperature double action, after heating, Start enzyme liquid injector(13)To deinked waste paper surface spraying cellulase solution 5min is treated, projection is acted on cellulase On so that ink and interfibrous connection become slack, and 30min is stood after sprinkling, continues to treat clamping under deinked waste paper It is down to three-level deinking room(8)In, fluid injector is dissociated at this time(14)Start, to treating deinked waste paper surface spraying dissociation solution 5min, Ink and fiber are completely disengaged using dissociation solution, clamping is treated that deinked waste paper drops to level Four deinking room after spray (9), level Four deinking room(9)Deinking fluid injector on side wall(15)Deinking liquid spray is being treated into deinked waste paper surface 3min, profit The ink being kept completely separate with fiber is adsorbed with liquid parting, is again started up water spray projector(11)To treating deinked waste paper surface spraying Deionized water rinsing 10min, the ink that liquid parting adsorbs is washed off, finally uses ultraviolet lamp(16)Deinked waste paper is treated in irradiation 20min, by ink outlet port(10)Discharge the ink of removing, you can obtain deinked waste paper.
A kind of 3. efficient Winestock machine according to claim 1, it is characterised in that:The water spray projector (11), electromagnetic heater(12), enzyme liquid injector(13), dissociation fluid injector(14), deinking fluid injector(15)And ultraviolet lamp (16)Respectively there are two, be symmetrically distributed on device side wall.
A kind of 4. application process of efficiently Winestock machine according to claim 2, it is characterised in that:The electromagnetism Heater(12)Heating-up temperature be 70~80 DEG C.
A kind of 5. application process of efficiently Winestock machine according to claim 2, it is characterised in that:The enzyme liquid Injector(13)The mass fraction of the cellulase solution ejected is 30%.
A kind of 6. application process of efficiently Winestock machine according to claim 2, it is characterised in that:The dissociation Fluid injector(14)The dissociation solution ejected is the ethanol solution of lecithin, and the mass fraction of lecithin ethanol solution is 20%.
A kind of 7. application process of efficiently Winestock machine according to claim 2, it is characterised in that:The deinking Fluid injector(15)The liquid parting ejected is that self-control deinking agent and water are 1 in mass ratio:5 mixed suspensions, wherein certainly The preparation method of deinking agent processed is as follows:
(1)It is 1 in mass ratio by magnesium nitrate, aluminum nitrate and water:2:10 are mixed to get mixing salt solution, then by mixing salt solution, The urea liquid and potassium rhodanate and citric acid mixing that mass fraction is 30%, add in hydrothermal reaction kettle together, 0.8~ 18~20h is reacted under conditions of 1.0MPa and 160~170 DEG C, is separated by filtration to obtain filter residue;
(2)It is 2 in mass ratio:5:1 will be fitted into fermentation tank after porous magnetite powder, dried orange peel essential oil, tea polyphenols mixing, will send out Fermentation tank is placed in the insulating box that temperature is 25~30 DEG C and is sealed by fermentation 12~15 days, is separated by filtration to obtain fermentation production after fermentation Thing, up to self-control deinking agent after high-temperature sterilization.
CN201711161647.2A 2017-11-21 2017-11-21 A kind of efficiently Winestock machine and its application process Pending CN107938412A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108560299A (en) * 2018-04-22 2018-09-21 雷春生 A kind of preparation method of high retention papermaking filler
CN109024025A (en) * 2018-09-12 2018-12-18 王晨宇 A kind of waste paper regenerating process method

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108560299A (en) * 2018-04-22 2018-09-21 雷春生 A kind of preparation method of high retention papermaking filler
CN108560299B (en) * 2018-04-22 2020-06-09 广东华能特种纸有限公司 Preparation method of high-retention papermaking filler
CN109024025A (en) * 2018-09-12 2018-12-18 王晨宇 A kind of waste paper regenerating process method

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Application publication date: 20180420