CN107936793A - A kind of aqueous finish paint - Google Patents
A kind of aqueous finish paint Download PDFInfo
- Publication number
- CN107936793A CN107936793A CN201711305486.XA CN201711305486A CN107936793A CN 107936793 A CN107936793 A CN 107936793A CN 201711305486 A CN201711305486 A CN 201711305486A CN 107936793 A CN107936793 A CN 107936793A
- Authority
- CN
- China
- Prior art keywords
- finish paint
- aqueous finish
- alkyd resins
- paint according
- aqueous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of aqueous finish paint, including following components：Aqueous alkide resin, wetting agent, fire retardant, thickener, drier, coalescents, pigment, deionized water and antirust agent.The present invention uses the base-material of SK1076 alkyd resins, SK1270 alkyd resins, 1800 alkyd resins of PC or 1880 alkyd resins of PC as finishing coat, it has the characteristics that, and good gloss of film, strong adhesive force, pliability are good, water-fast salt spray resistance is good and good weatherability；The antirust agent of addition can effectively prevent metal rusting when applied to metal surface, lift resistance to corrosion；The wetting agent used is silane coupling agent, it is possible to increase finishing coat further increases finishing coat to being coated the adhesive force in face to being coated the wettability in face, in addition, silane coupling agent also has antirust function, is used cooperatively with antirust agent, further lifts the resistance to corrosion of finishing coat；The fire retardant used can effectively prevent, delay or terminate flame transmission, so that finishing coat has fire retardancy.
Description
Technical field
The present invention relates to painting technical field, more particularly to a kind of aqueous finish paint.
Background technology
Finishing coat is the outermost coating of application, and the overall effect showed after application is embodied by this layer,
Therefore there is higher requirement to material therefor, it there should be good resistance to external condition, and there must be necessary color
It is mutually and decorative, and have protective effect to priming coat.The decorative effect and weatherability of finishing coat depend not only on paint base used, also
It is related to the proportioning of each component.
Existing finishing coat is mostly solvent-borne type, it is necessary to which using substantial amounts of organic solvent, the volatilization of organic solvent can be brought seriously
Problem of environmental pollution, in addition, also there is the safety issue transported, store and used for solvent-borne type finishing coat.With it is traditional
Solvent-borne type finishing coat is compared, and aqueous finish paint is using water as decentralized medium, has non-ignitable, nontoxic, free from environmental pollution, inexpensive, saving
The advantages that resource and the energy, receive significant attention.
But existing aqueous finish paint is also there are some performance shortcomings, as adhesive force is low, weatherability is poor, durability
Difference and poor water resistance etc..
The content of the invention
The present invention provides a kind of aqueous finish paint, and to solve, existing aqueous finish paint adhesive force is small, weatherability is poor, durability is poor
And the problems such as poor water resistance.
A kind of aqueous finish paint provided by the invention, by weight percentage, including following components：
According to one embodiment of present invention, further include：
Antirust agent 0.1-1%.
According to one embodiment of present invention, the antirust agent is water-soluble organic carboxyl acid alcohol amine salt, anhydrous sorbitol list
One kind in oleate, pentaerythritol ester, thiophosphate, inositol hexaphosphate.
According to one embodiment of present invention, the aqueous alkide resin is SK1076 alkyd resins, SK1270 alkyd trees
One kind in fat, PC-1800 alkyd resins, PC-1880 alkyd resins.
According to one embodiment of present invention, the wetting agent is 3- aminopropyl trimethoxysilanes, 3- aminopropyltriethoxies
Diethoxy silane, 3- aminopropyls ortho-siliformic acid, 3- aminopropyls dimethylethoxysilane, N- (β-aminoethyl)-γ-ammonia third
One kind in base trimethoxy silane, 3- aminopropyl diisopropyl Ethoxysilanes.
According to one embodiment of present invention, the fire retardant is melamine and condensed phosphate compound flame retardant, season
One or more of mixtures in the melamine salt of penta tetrol phosphate, endoxan polymer.
According to one embodiment of present invention, the thickener be non-ionic polyurethane association thickener, alkali soluble is swollen breast
One kind in the non-association thickener of liquid, hydrophobic alkali swellable emulsions association thickener.
According to one embodiment of present invention, the drier is cobalt naphthenate, manganese naphthenate, calcium naphthenate, aphthenic acids
One kind in zinc, 2 ethyl hexanoic acid cobalt, 2 ethyl hexanoic acid manganese and 2 ethyl hexanoic acid zinc.
According to one embodiment of present invention, the coalescents for alcohol ester-12, propandiol butyl ether, dipropylene,
One or more of mixtures in propylene glycol phenylate.
According to one embodiment of present invention, the pigment is iron oxide black, rutile type titanium white, carbon black, phthalocyanine blue
In one or more of mixtures.
A kind of aqueous finish paint provided by the invention can include the following benefits：The present invention uses SK1076 alkyd trees
The base-material of fat, SK1270 alkyd resins, PC-1800 alkyd resins or PC-1880 alkyd resins as finishing coat, it is with paint film light
The good, strong adhesive force in pool, pliability is good, water-fast salt spray resistance is good and the characteristics of good weatherability；The antirust agent of addition can be
Metal rusting is effectively prevented during applied to metal surface, lifts resistance to corrosion；The wetting agent used is silane coupling agent, can
Finishing coat is improved to being coated the wettability in face, further increases finishing coat to being coated the adhesive force in face, in addition, silane coupling agent
Also there is antirust function, be used cooperatively with antirust agent, further lift the resistance to corrosion of finishing coat；The fire retardant used is therein
Nitrogen and phosphorus produce cooperative effect, flame transmission can be effectively prevented, delay or terminate, so that finishing coat has fire retardancy；
The thickener used can increase the viscosity of finishing coat, improve the wet-film thickness of application, also have the function that anti-precipitation and anti-layering；
The drier used can speed up the oxidation polymerization process of active methylene group in aqueous alkide resin, make finishing coat rapid draing into
Film；The coalescents used can improve the film forming of coating and dried coating film speed under cryogenic conditions.
Embodiment
Embodiment 1
A kind of aqueous finish paint, by weight percentage, including following components：Aqueous alkide resin 65%, wetting agent 1%,
Fire retardant 8%, thickener 0.9%, drier 7%, coalescents 4.9%, pigment 10%, deionized water 3.2%.
Aqueous alkide resin is SK1076 alkyd resins, and wetting agent is 3- aminopropyl trimethoxysilanes, fire retardant three
Poly cyanamid and condensed phosphate compound flame retardant, thickener are non-ionic polyurethane association thickener, and drier is aphthenic acids
Cobalt, coalescents are alcohol ester-12 and propandiol butyl ether 1:1 mixing, pigment selective oxidation as needed is iron black, rutile titanium dioxide
One or more of mixtures in powder, carbon black, phthalocyanine blue.
Embodiment 2
A kind of aqueous finish paint, by weight percentage, including following components：Aqueous alkide resin 74%, wetting agent
0.8%, fire retardant 7%, thickener 0.8%, drier 5%, coalescents 4.3%, pigment 6%, deionized water 2.1%.
Aqueous alkide resin is SK1270 alkyd resins, and wetting agent is 3- aminopropyltriethoxy diethoxy silanes, fire retardant
For the melamine salt of pentaerythritol phosphate, thickener is the non-association thickener of alkali swellable emulsions, and drier is aphthenic acids
Manganese, coalescents are dipropylene, pigment selective oxidation iron oxide black as needed, rutile type titanium white, carbon black, phthalocyanine blue
In one or more of mixtures.
Embodiment 3
A kind of aqueous finish paint, by weight percentage, including following components：Aqueous alkide resin 81%, wetting agent
0.6%, fire retardant 6%, thickener 0.6%, drier 4.5%, coalescents 3.9%, pigment 1%, antirust agent 0.2%, goes
Ionized water 2.2%.
Aqueous alkide resin is PC-1800 alkyd resins, and wetting agent is 3- aminopropyl ortho-siliformic acids, and fire retardant is ring phosphorus
Amide polymer, thickener are the non-association thickener of alkali swellable emulsions, and drier is zinc naphthenate, and coalescents are propane diols
Phenylate, one or more of mixing in pigment selective oxidation iron oxide black as needed, rutile type titanium white, carbon black, phthalocyanine blue
Thing, antirust agent are water-soluble organic carboxyl acid alcohol amine salt.
Embodiment 4
A kind of aqueous finish paint, by weight percentage, including following components：Aqueous alkide resin 86%, wetting agent
0.4%, fire retardant 5%, thickener 0.3%, drier 1.6%, coalescents 2%, pigment 1%, antirust agent 0.3%, go from
Sub- water 3.4%.
Aqueous alkide resin is PC-1880 alkyd resins, and wetting agent is 3- aminopropyl dimethylethoxysilanes, fire retardant
For the melamine salt and endoxan polymer 1 of pentaerythritol phosphate:1 mixing, thickener are formed for hydrophobic alkali swellable emulsions
Thickener, drier are 2 ethyl hexanoic acid cobalt, and coalescents are propylene glycol phenylate, pigment selective oxidation iron as needed
One or more of mixtures in black, rutile type titanium white, carbon black, phthalocyanine blue, antirust agent are pentaerythritol ester.
Embodiment 5
A kind of aqueous finish paint, by weight percentage, including following components：Aqueous alkide resin 88%, wetting agent
0.2%, fire retardant 1%, thickener 0.2%, drier 2.1%, coalescents 1.5%, pigment 1%, antirust agent 0.5%, goes
Ionized water 5.5%.
Aqueous alkide resin is SK1270 alkyd resins, and wetting agent is 3- aminopropyl diisopropyl Ethoxysilanes, resistance
It is melamine and condensed phosphate compound flame retardant to fire agent, and thickener is hydrophobic alkali swellable emulsions association thickener, is urged dry
Agent is 2 ethyl hexanoic acid zinc, and coalescents are propandiol butyl ether, and pigment selective oxidation as needed is iron black, rutile titanium dioxide
One or more of mixtures in powder, carbon black, phthalocyanine blue, antirust agent are inositol hexaphosphate.
In conclusion a kind of aqueous finish paint provided in an embodiment of the present invention, using SK1076 alkyd resins, SK1270 alkyd
The base-material of resin, PC-1800 alkyd resins or PC-1880 alkyd resins as finishing coat, it is with gloss of film is good, adhesive force
By force, pliability is good, water-fast salt spray resistance is good and the characteristics of good weatherability；The antirust agent of addition can be applied to metal watch
Metal rusting is effectively prevented during face, lifts resistance to corrosion；The wetting agent used is silane coupling agent, it is possible to increase finishing coat is to quilt
The wettability in application face, further increases finishing coat to being coated the adhesive force in face, in addition, silane coupling agent also has antirust work(
Can, it is used cooperatively with antirust agent, further lifts the resistance to corrosion of finishing coat；The fire retardant nitrogen therein and phosphorus used produces association
Same effect, can effectively prevent, delays or terminate flame transmission, so that finishing coat has fire retardancy；The thickener used
The viscosity of finishing coat can be increased, improve the wet-film thickness of application, also there is anti-precipitation and anti-layering；The drier used
The oxidation polymerization process of active methylene group in aqueous alkide resin is can speed up, finishing coat rapid draing is formed a film；The film forming used
Auxiliary agent can improve the film forming of coating and dried coating film speed under cryogenic conditions.
Although the present invention has described it in detail and cited embodiments, but for those of ordinary skill in the art come
Say, it is clear that various schemes, modification and the change that can be made as specified above, should be construed as being included in the claims in the present invention
Within the scope of.
Claims (10)
- A kind of 1. aqueous finish paint, it is characterised in that by weight percentage, including following components：
- 2. aqueous finish paint according to claim 1, it is characterised in that further include：Antirust agent 0.1-1%.
- 3. aqueous finish paint according to claim 2, it is characterised in that the antirust agent is water-soluble organic carboxyl acid hydramine One kind in salt, sorbitan monooleate, pentaerythritol ester, thiophosphate, inositol hexaphosphate.
- 4. aqueous finish paint according to claim 1, it is characterised in that the aqueous alkide resin is SK1076 alkyd trees One kind in fat, SK1270 alkyd resins, PC-1800 alkyd resins, PC-1880 alkyd resins.
- 5. aqueous finish paint according to claim 1, it is characterised in that the wetting agent is 3- aminopropyl trimethoxy silicon Alkane, 3- aminopropyltriethoxies diethoxy silane, 3- aminopropyls ortho-siliformic acid, 3- aminopropyls dimethylethoxysilane, N- (β- Aminoethyl)-γ-aminopropyltrimethoxysilane, one kind in 3- aminopropyl diisopropyl Ethoxysilanes.
- 6. aqueous finish paint according to claim 1, it is characterised in that the fire retardant is melamine and condensed phosphate One or more of mixtures in compound flame retardant, the melamine salt of pentaerythritol phosphate, endoxan polymer.
- 7. aqueous finish paint according to claim 1, it is characterised in that the thickener increases for non-ionic polyurethane association type Thick dose, the non-association thickener of alkali swellable emulsions, one kind in hydrophobic alkali swellable emulsions association thickener.
- 8. aqueous finish paint according to claim 1, it is characterised in that the drier is cobalt naphthenate, manganese naphthenate, ring One kind in alkanoic acid calcium, zinc naphthenate, 2 ethyl hexanoic acid cobalt, 2 ethyl hexanoic acid manganese, 2 ethyl hexanoic acid zinc.
- 9. aqueous finish paint according to claim 1, it is characterised in that the coalescents are alcohol ester-12, propane diols fourth One or more of mixtures in ether, dipropylene, propylene glycol phenylate.
- 10. aqueous finish paint according to claim 1, it is characterised in that the pigment is iron oxide black, rutile titanium dioxide One or more of mixtures in powder, carbon black, phthalocyanine blue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711305486.XA CN107936793A (en) | 2017-12-11 | 2017-12-11 | A kind of aqueous finish paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711305486.XA CN107936793A (en) | 2017-12-11 | 2017-12-11 | A kind of aqueous finish paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107936793A true CN107936793A (en) | 2018-04-20 |
Family
ID=61945502
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711305486.XA Pending CN107936793A (en) | 2017-12-11 | 2017-12-11 | A kind of aqueous finish paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107936793A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109762647A (en) * | 2019-01-29 | 2019-05-17 | 汉中红润化工有限公司 | A kind of numerical control cutting liquid and preparation method thereof |
| CN111675968A (en) * | 2020-03-24 | 2020-09-18 | 山东华韵新材料有限公司 | Flame-retardant paint for fireproof, non-combustible and high-corrosion-resistance color-coated plate and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104250512A (en) * | 2014-09-25 | 2014-12-31 | 常熟市方塔涂料化工有限公司 | Water-based alcohol acid primer-topcoat antirust paint and preparation method thereof |
| CN104479527A (en) * | 2014-12-10 | 2015-04-01 | 成都拜迪新材料有限公司 | Water-based primer for railroad bridge and preparation method thereof |
| CN104845510A (en) * | 2014-12-04 | 2015-08-19 | 北京金汇利应用化工制品有限公司 | Paint containing waterborne alkyd resin and preparation method of paint |
| CN106280930A (en) * | 2015-06-11 | 2017-01-04 | 上海福岛化工科技发展有限公司 | Water alcohol acid aerosol finish paint and preparation method thereof |
| CN106957591A (en) * | 2017-03-07 | 2017-07-18 | 河北晨虹油漆有限公司 | Water alcohol acid finish paint and preparation method thereof |
-
2017
- 2017-12-11 CN CN201711305486.XA patent/CN107936793A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104250512A (en) * | 2014-09-25 | 2014-12-31 | 常熟市方塔涂料化工有限公司 | Water-based alcohol acid primer-topcoat antirust paint and preparation method thereof |
| CN104845510A (en) * | 2014-12-04 | 2015-08-19 | 北京金汇利应用化工制品有限公司 | Paint containing waterborne alkyd resin and preparation method of paint |
| CN104479527A (en) * | 2014-12-10 | 2015-04-01 | 成都拜迪新材料有限公司 | Water-based primer for railroad bridge and preparation method thereof |
| CN106280930A (en) * | 2015-06-11 | 2017-01-04 | 上海福岛化工科技发展有限公司 | Water alcohol acid aerosol finish paint and preparation method thereof |
| CN106957591A (en) * | 2017-03-07 | 2017-07-18 | 河北晨虹油漆有限公司 | Water alcohol acid finish paint and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109762647A (en) * | 2019-01-29 | 2019-05-17 | 汉中红润化工有限公司 | A kind of numerical control cutting liquid and preparation method thereof |
| CN111675968A (en) * | 2020-03-24 | 2020-09-18 | 山东华韵新材料有限公司 | Flame-retardant paint for fireproof, non-combustible and high-corrosion-resistance color-coated plate and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101747825B (en) | Environment-friendly solvent-free humidified and rusted anticorrosive paint | |
| CN104098972B (en) | Water-based antirust and antiseptic paint for metal and preparation method thereof | |
| CN104497730A (en) | Water-borne crack lacquer, preparation method and application method thereof | |
| CN110105861B (en) | Full-aqueous release coating for electrochemical aluminum hot stamping foil and preparation method thereof | |
| CN102839367A (en) | Self-repairing chromium-free passivation treatment fluid used for galvanized steel coil | |
| CN108912928A (en) | Fire-retardant, waterproof aqueous core shell acrylic esters resin coating and paint preparation method | |
| CN103666201A (en) | Long-acting acid-base resistant solvent-free anticorrosive paint as well as preparation method and application thereof | |
| CN105238189A (en) | Waterborne amino baking paint | |
| CN107936793A (en) | A kind of aqueous finish paint | |
| CN102559027A (en) | Water-based color correction special paint and color correction method thereof | |
| CN110698908A (en) | Coloring water-based paint composition and preparation method thereof | |
| US10316195B2 (en) | Zinc-based composite material and use thereof | |
| CN106756959B (en) | A kind of corrosion resistant galvanized steel plain sheet and preparation method | |
| CN109021749A (en) | A kind of exterior wall latex paint | |
| CN108977003A (en) | Watery anti-corrosion low temperature self-drying paint and anti-flash rusting coating process for ironcasting | |
| CN107892862A (en) | A kind of aqueous double-component anti-corrosive primer and preparation method thereof | |
| CN105238238A (en) | Water-based alkyd paint | |
| CN107746641A (en) | Unify water-based enamel paint and its preparation, application method in a kind of bottom surface | |
| CN107523197A (en) | A kind of novel aqueous polyester resin | |
| CN104789104B (en) | Hydroxyl group-containing polyurethane acrylate copolymer aqueous industrial paint with high mechanical performances | |
| JPH11279445A (en) | Paint | |
| CN104164168A (en) | Air-drying acrylic enamel | |
| CN109880417A (en) | Watersoluble metal self-drying paint and preparation method thereof | |
| CN103881556A (en) | UV elastic coating | |
| CN108329818A (en) | A kind of woodenware paint special |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180420 |