CN107936698A - High dispersive blue ceramic ink - Google Patents

High dispersive blue ceramic ink Download PDF

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Publication number
CN107936698A
CN107936698A CN201711340039.8A CN201711340039A CN107936698A CN 107936698 A CN107936698 A CN 107936698A CN 201711340039 A CN201711340039 A CN 201711340039A CN 107936698 A CN107936698 A CN 107936698A
Authority
CN
China
Prior art keywords
ceramic ink
ink
parts
high dispersive
mass fraction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201711340039.8A
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Chinese (zh)
Inventor
毛海燕
谭海林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan Caigui New Material Co Ltd
Original Assignee
Foshan Caigui New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan Caigui New Material Co Ltd filed Critical Foshan Caigui New Material Co Ltd
Priority to CN201711340039.8A priority Critical patent/CN107936698A/en
Publication of CN107936698A publication Critical patent/CN107936698A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/32Inkjet printing inks characterised by colouring agents
    • C09D11/322Pigment inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/36Inkjet printing inks based on non-aqueous solvents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/30Inkjet printing inks
    • C09D11/38Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)

Abstract

The invention discloses high dispersive blue ceramic ink, and by mass fraction, its material component includes:55-65 parts of cobalt blue dye, 50-60 parts of solvent, 1-2 parts of dispersant, 5-8 parts of bonding agent, 2-5 parts of defoamer, 30-40 parts of water.The present invention provides high dispersive blue ceramic ink, ink is blue ceramic ink, enriches the distribution of color of existing ceramic ink, at the same time, the ink has polymolecularity, it is therefore prevented that ink causes printing head to block and influence the coloring intensity of pigment since dispersiveness is not ideal enough.

Description

High dispersive blue ceramic ink
Technical field
The present invention relates to technical field of ink, more particularly to high dispersive blue ceramic ink.
Background technology
Ceramic ink realizes the biometrics printing of ceramics, i.e., is printed upon functional ceramic ink using ink-jet technology In Ceramic Tiles, it is possible to achieve the personalization of architectural pottery and functionalization.Product can be increased substantially using inkjet printing technology Added value.
But existing ceramic ink, blue ceramic ink more single there are color, particularly relatively conventional.And Even if there is fraction of enterprise to make blue ceramic ink, and because of the dispersed not ideal enough of ink, printing is caused to spray Head blocks and influences the coloring intensity of pigment.
The content of the invention
In view of this, the present invention provides high dispersive blue ceramic ink, the color range of ceramic ink is enriched, together When, which has polymolecularity, it is therefore prevented that ink causes printing head to block and influence pigment since dispersiveness is not ideal enough Coloring intensity the problem of.
High dispersive blue ceramic ink, by mass fraction, its material component includes:
Preferably, by mass fraction, its material component is:
Preferably, by mass fraction, its material component is:
Preferably, the cobalt blue dye is CoAl2O4.
Preferably, the solvent is one kind in ethanol, isopropanol and ethylene glycol ether.
Preferably, the solvent is ethanol.
Preferably, the dispersant is one kind of dispersant 5040, HRE-40 and triethanolamine.
Preferably, the dispersant is triethanolamine.
Preferably, the bonding agent is chlorine wax tree fat.
Preferably, the defoamer is silicone emulsion.
The present invention provides high dispersive blue ceramic ink, ink is blue ceramic ink, enriches existing ceramic ink Distribution of color, meanwhile, which has polymolecularity, it is therefore prevented that ink due to dispersiveness it is not ideal enough, cause printing head Block and influence the coloring intensity of pigment.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical solution in the embodiment of the present invention is clearly and completely described, Obviously, described embodiment is part of the embodiment of the present invention, instead of all the embodiments.Based on the implementation in the present invention Example, those of ordinary skill in the art's all other embodiments obtained without making creative work, belongs to The scope of protection of the invention.
It should be appreciated that ought use in this specification and in the appended claims, term " comprising " and "comprising" instruction Described feature, entirety, step, operation, the presence of element and/or component, but it is not precluded from one or more of the other feature, whole Body, step, operation, element, component and/or its presence or addition for gathering.
It will be further appreciated that the term "and/or" used in description of the invention and the appended claims is Refer to any combinations and all possible combinations of one or more of the associated item listed, and including these combinations.
Embodiment 1
High dispersive blue ceramic ink, by mass fraction, its material component includes:
Its preparation method is:
By CoAl2O4Add into the mixed liquor of ethanol and water, mixing speed 230r/min, stir 5min, to completely it is molten Solution, obtains solution a;
Dispersant 5040, chlorine wax tree fat and silicone emulsion are added into solution a, with ball milling in ball mill, ball milling 60min, to granularity 150nm, obtains ceramic ink.
Embodiment 2
High dispersive blue ceramic ink, by mass fraction, its material component includes:
Its preparation method is:
By CoAl2O4Add into the mixed liquor of isopropanol and water, mixing speed 280r/min, 4min is stirred, to complete Dissolving, obtains solution a;
Triethanolamine, chlorine wax tree fat and silicone emulsion are added into solution a, with ball milling in ball mill, ball milling 80min, to granularity 180nm, obtains ceramic ink.
Embodiment 3
High dispersive blue ceramic ink, by mass fraction, its material component includes:
Its preparation method is:
By CoAl2O4Add into the mixed liquor of ethylene glycol ether and water, mixing speed 260r/min, stir 6min, To being completely dissolved, solution a is obtained;
Dispersant HRE-40, chlorine wax tree fat and silicone emulsion are added into solution a, with ball milling in ball mill, ball milling 70min, to granularity 170nm, obtains ceramic ink.
Embodiment 4
High dispersive blue ceramic ink, by mass fraction, its material component includes:
Its preparation method is:
By CoAl2O4Add into the mixed liquor of ethanol and water, mixing speed 250r/min, stir 7min, to completely it is molten Solution, obtains solution a;
Dispersant HRE-40, chlorine wax tree fat and silicone emulsion are added into solution a, with ball milling in ball mill, ball milling 65min, to granularity 180nm, obtains ceramic ink.
Embodiment 5
High dispersive blue ceramic ink, by mass fraction, its material component includes:
Its preparation method is:
By CoAl2O4Add into the mixed liquor of ethanol and water, mixing speed 270r/min, stir 5min, to completely it is molten Solution, obtains solution a;
Triethanolamine, chlorine wax tree fat and silicone emulsion are added into solution a, with ball milling in ball mill, ball milling 62min, to granularity 140nm, obtains ceramic ink.
The ceramic ink that embodiment 1 to 5 is produced, is tested:
Average grain diameter (nm) Stability (12h) Stability (24h)
Embodiment 1 150 Without sedimentation Without sedimentation
Embodiment 2 180 Without sedimentation Without sedimentation
Embodiment 3 170 Without sedimentation Without sedimentation
Embodiment 4 180 Without sedimentation A little
Embodiment 5 140 Without sedimentation Without sedimentation
According to the data in several tables, it can be seen that this blue ceramic ink particle diameter is small, high dispersive, and stability is good, it is therefore prevented that Ink causes printing head to block and influences the coloring intensity of pigment since dispersiveness is not ideal enough.
The steps in the embodiment of the present invention can be sequentially adjusted, merged and deleted according to actual needs.
It is described in detail herein, applies specific case and the principle of the present invention and embodiment are explained State, above example is only intended to help the method and its core concept for understanding the present invention;Meanwhile for the general skill of this area Art personnel, according to the thought of the present invention, there will be changes in specific embodiments and applications, in conclusion this Description should not be construed as limiting the invention.
It is apparent to those skilled in the art that for convenience and simplicity of description, the system of foregoing description With the specific work process of unit, the corresponding process in preceding method embodiment is may be referred to, details are not described herein.

Claims (10)

1. high dispersive blue ceramic ink, it is characterised in that its material component includes by mass fraction:
2. ceramic ink as claimed in claim 1, it is characterised in that its material component is by mass fraction:
3. ceramic ink as claimed in claim 1, it is characterised in that its material component is by mass fraction:
4. the ceramic ink as described in claim 1-3 is any, it is characterised in that:The cobalt blue dye is CoAl2O4
5. the ceramic ink as described in claim 1-3 is any, it is characterised in that:The solvent is ethanol, isopropanol and second One kind in allyl diglycol ether.
6. ceramic ink as claimed in claim 5, it is characterised in that:The solvent is ethanol.
7. the ceramic ink as described in claim 1-3 is any, it is characterised in that:The dispersant is dispersant 5040, HRE- 40 and one kind of triethanolamine.
8. ceramic ink as claimed in claim 7, it is characterised in that:The dispersant is triethanolamine.
9. the ceramic ink as described in claim 1-3 is any, it is characterised in that:The bonding agent is chlorine wax tree fat.
10. the ceramic ink as described in claim 1-3 is any, it is characterised in that:The defoamer is silicone emulsion.
CN201711340039.8A 2017-12-14 2017-12-14 High dispersive blue ceramic ink Pending CN107936698A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711340039.8A CN107936698A (en) 2017-12-14 2017-12-14 High dispersive blue ceramic ink

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711340039.8A CN107936698A (en) 2017-12-14 2017-12-14 High dispersive blue ceramic ink

Publications (1)

Publication Number Publication Date
CN107936698A true CN107936698A (en) 2018-04-20

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN201711340039.8A Pending CN107936698A (en) 2017-12-14 2017-12-14 High dispersive blue ceramic ink

Country Status (1)

Country Link
CN (1) CN107936698A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102675967A (en) * 2012-05-08 2012-09-19 中山大学 Water-based ceramic three-dimensional pattern printing ink and preparation method thereof
CN103642317A (en) * 2013-12-20 2014-03-19 佛山市三水区康立泰无机合成材料有限公司 Low temperature ceramic inkjet ink
CN103937327A (en) * 2014-04-02 2014-07-23 闽江学院 Water-soluble ceramic ink and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102675967A (en) * 2012-05-08 2012-09-19 中山大学 Water-based ceramic three-dimensional pattern printing ink and preparation method thereof
CN103642317A (en) * 2013-12-20 2014-03-19 佛山市三水区康立泰无机合成材料有限公司 Low temperature ceramic inkjet ink
CN103937327A (en) * 2014-04-02 2014-07-23 闽江学院 Water-soluble ceramic ink and preparation method thereof

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Application publication date: 20180420