CN107936417A - A kind of degredation plastic film - Google Patents

A kind of degredation plastic film Download PDF

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Publication number
CN107936417A
CN107936417A CN201711416197.7A CN201711416197A CN107936417A CN 107936417 A CN107936417 A CN 107936417A CN 201711416197 A CN201711416197 A CN 201711416197A CN 107936417 A CN107936417 A CN 107936417A
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CN
China
Prior art keywords
starch
plastic film
plastic foil
degredation
thick
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Pending
Application number
CN201711416197.7A
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Chinese (zh)
Inventor
汪子璇
王永梅
李璟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Agricultural University AHAU
Hangzhou Bite Greenpack Co Ltd
Original Assignee
Anhui Agricultural University AHAU
Hangzhou Bite Greenpack Co Ltd
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Application filed by Anhui Agricultural University AHAU, Hangzhou Bite Greenpack Co Ltd filed Critical Anhui Agricultural University AHAU
Priority to CN201711416197.7A priority Critical patent/CN107936417A/en
Publication of CN107936417A publication Critical patent/CN107936417A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/04—Homopolymers or copolymers of ethene
    • C08J2323/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2403/00—Characterised by the use of starch, amylose or amylopectin or of their derivatives or degradation products
    • C08J2403/02—Starch; Degradation products thereof, e.g. dextrin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to plastics technical field of membrane, and in particular to a kind of degredation plastic film.The plastic foil by weight percentage, including thermoplastic resin 66.7% ~ 71.8%, cerium 0.2% ~ 0.5%, lanthanum 0.3% ~ 0.6%, samarium 0.8% ~ 1.2%, lutetium 0.4% ~ 0.7%, scandium 7.6% ~ 9.1% and starch 16.5% ~ 23.2%.The plastic foil has the photopermeability than general plastic foil higher, and can degrade under certain condition, so as to reduce the influence to environment.

Description

A kind of degredation plastic film
Technical field
The present invention relates to plastics technical field of membrane, and in particular to a kind of degredation plastic film.This plastic foil has with leading to With the performance that plastic foil is similar, and can degrade under certain environment.
Background technology
Plastic foil is using thin made of polyvinyl chloride, polyethylene, polypropylene, polystyrene and other thermoplastic resins Film, for packing, and as coating layer.Commercially shared share is increasing for plastics package and plastic packet product, Particularly composite plastic flexible package, has been widely used for the fields such as food, medicine, chemical industry, wherein again with packaging for foodstuff institute Accounting example is maximum, such as beverage packaging, quick-frozen food packaging, cooking food packaging, fast food packaging etc., these products are all given People's life brings great convenience.
Although plastic foil has brought great benefit, but with the use of plastic foil, to people life and Environment brings many problems, and very big pollution is particularly caused to environment.This is all due to that plastic foil can not be timely Caused by degraded.Even if plastic foil has suitable negative effect, but can not be given up at present, it is therefore desirable to develops energy The plastic foil enough degraded, so as to which on the premise of plastic foil is widely used, it is negative to reduce the pollution that plastic foil is brought etc. as much as possible Face is rung.
The content of the invention
The purpose of the present invention is to solve the above problem, there is provided a kind of degredation plastic film.
The plastic foil of the present invention possesses with other by the similar performance of plastic foil prepared by general-purpose plastics, still, this hair Bright plastic foil can degrade under certain environment, so that reduce plastic foil widely uses the environmental pollution brought.
In order to reach foregoing invention purpose, the present invention uses following technical scheme：
A kind of degredation plastic film, the plastic foil by weight percentage, including thermoplastic resin 66.7% ~ 71.8%, cerium 0.2% ~ 0.5%, lanthanum 0.3% ~ 0.6%, samarium 0.8% ~ 1.2%, lutetium 0.4% ~ 0.7%, thick scandium powder 7.6% ~ 9.1% and starch 16.5% ~ 23.2%。
The degraded of current plastic foil operates：In plastic packing product（Plastic foil）Production process in add it is a certain amount of Additive（Such as starch, modified starch or other celluloses, photosensitizer, biodegradation agent）, make the stabilization of plastic packing article Property decline, be easier to degrade in natural environment, still, make plastic foil degradation effect bad by adding starch at present, utilize Biodegradable principle added in resin starch year may be degraded, but degrade cycle it is longer.
The invention using key component of the starch as degraded, and while starch is added, add and aid in Compounding agent samarium, for improving the structure of material, so as to structurally alter the solution speed of plastics, accelerate plastic degradation；Match somebody with somebody Mixture lutetium, for catalyst article, catalytic action, accelerated degradation are produced to degraded；Compounding agent scandium, not only can be with decomposition plastics, together When can be used as half initiator, enable plastics Auto-decomposition, so as to accelerate degradation speed；Starch, is helped as main degraded Agent, the degraded to plastics produce facilitation.
Preferably, the starch is modified starch.
Preferably, the thermoplastic resin is polyvinyl chloride, polyethylene, polypropylene, polystyrene.
Preferably, the thermoplastic resin is polyethylene.
Preferably, the plastic foil by weight percentage, including polyethylene 68.7% ~ 70.1%, cerium 0.2% ~ 0.5%, lanthanum 0.3% ~ 0.6%, samarium 0.95% ~ 1.03%, lutetium 0.7% ~ 0.52%, thick scandium powder 8.3% ~ 8.9% and starch 19.2% ~ 20.8%.
Preferably, the plastic foil by weight percentage, including polyethylene 69.2%, cerium 0.3%, lanthanum 0.5%, samarium 1.0%, Lutetium 0.5%, thick 8.5 % of scandium powder and starch 20.2%.
Preferably, the thermoplastic resin is polypropylene.
Preferably, the plastic foil by weight percentage, polypropylene 66.7% ~ 71.8%, cerium 0.2% ~ 0.5%, lanthanum 0.3% ~ 0.6%th, samarium 0.8% ~ 1.2%, lutetium 0.4% ~ 0.7%, thick scandium powder 7.6% ~ 9.1% and starch 16.5% ~ 23.2%.
Preferably, hydrazine hydrate 0.5%-0.8% and tetraphenyltin 0.3-0.5% are further included.
The purpose for adding hydrazine hydrate and tetraphenyltin is in order to change the structure of resin, to thin from structure and in crystallization Film is improved, can be in follow-up degradation process, and degradation reaction and degradation rate are rapider.And pass through addition The two, can be controlled the useful life of film, make its degradation process more controllable, can more easily control film Service life.The degradation rate in degradation process can be adjusted by hydrazine hydrate and tetraphenyltin, so as to effectively making It is balanced with service life and degraded.
Preferably, the content of scandium element is 0.3%-3% in the thick scandium powder.
Compared with prior art, the present invention beneficial effect is：
Absorption of the plastic foil of the present invention to light is preferable, has the photopermeability than general plastic foil higher；
The plastic foil of the present invention starts to degrade after can exceeding service life under field conditions (factors), and within certain period by high score Sub- weight polymers are reduced to oligomer, until that will not form adverse effect to environment, so as to reduce the harm to environment.
Brief description of the drawings
Fig. 1 is the degraded comparison diagram after embodiment 1 and 1 polyvinyl chloride film of documents use 3 months outdoors；
Fig. 2 is the degraded comparison diagram of embodiment 2 and 2 polyethylene film of documents after using 3 months outdoors；
The degraded comparison diagram of Fig. 3 embodiments 3,4,5 and 3 polyethylene film of documents after using 3 months outdoors；
The degraded comparison diagram of Fig. 4 embodiments 8,9,10 and 3 polyethylene film of documents after using 3 months outdoors；
Fig. 5 is degraded comparison diagram of the polypropylene film of embodiment 6,7 and documents 4 after using 3 months outdoors；
Fig. 6 is the degraded comparison diagram of embodiment 3,4,5 and embodiment 8,9,10.
Embodiment
Explanation is further described to technical scheme below by specific embodiment.
If without specified otherwise, the raw material employed in the embodiment of the present invention is raw material commonly used in the art, is implemented Method employed in example, is the conventional method of this area.
Embodiment 1：
A kind of degredation plastic film, the plastic foil by weight percentage, including polyvinyl chloride 66.7%, cerium 0.5%, lanthanum 0.3%th, samarium 1.2%, lutetium 0.4%, thick scandium powder 9.1% and starch 21.8%.The content of scandium element is 0.3%-3% in thick scandium powder.
Embodiment 2：
A kind of degredation plastic film, the plastic foil by weight percentage, including polystyrene 71.8%, cerium 0.2%, lanthanum 0.6%th, samarium 0.8%, lutetium 0.7%, thick scandium powder 7.6% and starch 18.3%.The content of scandium element is 0.3%-3% in thick scandium powder.
Embodiment 3：
A kind of degredation plastic film, the plastic foil by weight percentage, including polyethylene 68.7%, cerium 0.5%, lanthanum 0.3%th, samarium 1.03%, lutetium 0.47%, thick scandium powder 8.9% and starch 20.1%.The content of scandium element is 0.3%-3% in thick scandium powder.
Embodiment 4：
A kind of degredation plastic film, the plastic foil by weight percentage, including polyethylene 70.1%, cerium 0.2%, lanthanum 0.6%th, samarium 0.95%, lutetium 0.52%, thick scandium powder 8.3% and starch 19.33%.The content of scandium element is 0.3%-3% in thick scandium powder.
Embodiment 5：
A kind of degredation plastic film, the plastic foil by weight percentage, including polyethylene 69.2%, cerium 0.3%, lanthanum 0.5%th, samarium 1.0%, lutetium 0.5%, thick 8.5 % of scandium powder and starch 20%.The content of scandium element is 0.3%-3% in thick scandium powder.
Embodiment 6：
A kind of degredation plastic film, the plastic foil by weight percentage, polypropylene 66.7%, cerium 0.2%, lanthanum 0.6%, samarium 0.8%th, lutetium 0.7%, thick scandium powder 7.8% and starch 23.2%.The content of scandium element is 0.3%-3% in thick scandium powder.
Embodiment 7：
A kind of degredation plastic film, the plastic foil by weight percentage, polypropylene 71.8%, cerium 0.2%, lanthanum 0.6%, samarium 0.8%th, lutetium 0.7%, thick scandium powder 7.6% and starch 18.3%.The content of scandium element is 0.3%-3% in thick scandium powder.
Embodiment 8：
It is corresponding with embodiment 3, a kind of degredation plastic film, the plastic foil by weight percentage, including polyethylene 67.6%th, cerium 0.5%, lanthanum 0.3%, samarium 1.03%, lutetium 0.47%, thick scandium powder 8.9%, starch 20.1%, hydrazine hydrate 0.8% and tetraphenyl Tin 0.3%.The content of scandium element is 0.3%-3% in thick scandium powder.
Embodiment 9：
It is corresponding with embodiment 4, a kind of degredation plastic film, the plastic foil by weight percentage, including polyethylene 69.1%th, cerium 0.2%, lanthanum 0.6%, samarium 0.95%, lutetium 0.52%, thick scandium powder 8.3%, starch 19.33%, 0.5% and four benzene of hydrazine hydrate Base tin 0.5%.The content of scandium element is 0.3%-3% in thick scandium powder.
Embodiment 10：
It is corresponding with embodiment 5, the plastic foil by weight percentage, including polyethylene 68.1%, cerium 0.3%, lanthanum 0.5%, samarium 1.0%th, lutetium 0.5%, thick 8.5 % of scandium powder, starch 20.2%, hydrazine hydrate 0.7% and tetraphenyltin 0.4%.Scandium element in thick scandium powder Content is 0.3%-3%.
Comparative example 1
General polyvinyl chloride.
Comparative example 2
General purpose polystyrene.
Comparative example 3
General polyethylene.
Comparative example 4
General purpose polypropylene.
Results contrast is analyzed.
By embodiment 1- embodiments 7 and the plastics of comparative example 1- contrasts 4, the film that thickness is 1 micron is prepared into, then The performance of testing film.By the film for preparing the various embodiments described above, to simulate degradation, date comprision is carried out；
Specially：
Embodiment 1 and the polyvinyl chloride film of documents 1 are contrasted；
Embodiment 2 and the polystyrene of documents 2 are contrasted；
The polyethylene of embodiment 3,4,5 and documents 3 is contrasted；
The polypropylene of embodiment 6,7 and the polypropylene of documents 4 are contrasted；
The polyethylene of embodiment 8,9,10 and documents 3 is contrasted；
The polyethylene of embodiment 3,4,5 and embodiment 8,9,10 is contrasted；
Fig. 1 is the degraded comparison diagram after embodiment 1 and 1 polyvinyl chloride film of documents use 3 months outdoors；
Fig. 2 is the degraded comparison diagram of embodiment 2 and 2 polystyrene film of documents after using 3 months outdoors；
The degraded comparison diagram of Fig. 3 embodiments 3,4,5 and 3 polyethylene film of documents after using 3 months outdoors；
The degraded comparison diagram of Fig. 4 embodiments 8,9,10 and 3 polyethylene film of documents after using 3 months outdoors；
Fig. 5 is degraded comparison diagram of the polypropylene film of embodiment 6,7 and documents 4 after using 3 months outdoors；
Fig. 6 is the degraded comparison diagram of embodiment 3,4,5 and embodiment 8,9,10.
Above-mentioned data result is contrasted to can be seen that（As shown in Fig. 1,2,3,4 and 5）, general film is to occur in a short time Degraded, and film prepared by the present invention has the service life more shorter than General plastics film, meanwhile, it is capable to be used reaching Rapidly degrade after service life, so as to avoid polluting environment harm.
As shown in fig. 6, addition hydrazine hydrate and the generation of tetraphenyltin degradation time curve are micro- on the basis of original formula Wonderful change, in the starting stage, the degradation rate of embodiment 8,9,10 is not faster than embodiment 3,4,5, but certain reaching After degree, the plastic film of embodiment 8,9,10 accelerates degradation rate, poly- so as to be degraded within the shorter time Right lower oligomer.

Claims (10)

  1. A kind of 1. degredation plastic film, it is characterised in that the plastic foil by weight percentage, including thermoplastic resin 66.7% ~ 71.8%, cerium 0.2% ~ 0.5%, lanthanum 0.3% ~ 0.6%, samarium 0.8% ~ 1.2%, lutetium 0.4% ~ 0.7%, thick 7.6% ~ 9.1% He of scandium powder Starch 16.5% ~ 23.2%.
  2. 2. a kind of degredation plastic film according to claim 1, it is characterised in that the starch is modified starch.
  3. 3. a kind of degredation plastic film according to claim 1 or 2, it is characterised in that the thermoplastic resin is poly- Vinyl chloride, polyethylene, polypropylene, polystyrene.
  4. 4. a kind of degredation plastic film according to claim 3, it is characterised in that the thermoplastic resin is poly- second Alkene.
  5. 5. a kind of degredation plastic film according to claim 4, it is characterised in that the plastic foil is by weight percentage Meter, including polyethylene 68.7% ~ 70.1%, cerium 0.2% ~ 0.5%, lanthanum 0.3% ~ 0.6%, samarium 0.95% ~ 1.03%, lutetium 0.7% ~ 0.52%, Thick scandium powder 8.3% ~ 8.9% and starch 19.2% ~ 20.8%.
  6. 6. a kind of degredation plastic film according to claim 4, it is characterised in that the plastic foil is by weight percentage Meter, including polyethylene 69.2%, cerium 0.3%, lanthanum 0.5%, samarium 1.0%, lutetium 0.5%, thick 8.5 % of scandium powder and starch 20.2%.
  7. 7. a kind of degredation plastic film according to claim 3, it is characterised in that the thermoplastic resin is poly- third Alkene.
  8. 8. a kind of degredation plastic film according to claim 7, it is characterised in that the plastic foil is by weight percentage Meter, polypropylene 66.7% ~ 71.8%, cerium 0.2% ~ 0.5%, lanthanum 0.3% ~ 0.6%, samarium 0.8% ~ 1.2%, lutetium 0.4% ~ 0.7%, thick scandium powder 7.6% ~ 9.1% and starch 16.5% ~ 23.2%.
  9. 9. a kind of degredation plastic film according to claim 1 or 5 or 6 or 8, it is characterised in that further include hydration connection Ammonia 0.5%-0.8% and tetraphenyltin 0.3-0.5%.
  10. 10. a kind of degredation plastic film according to claim 1 or 5 or 6 or 8, it is characterised in that in the thick scandium powder The content of scandium element is 0.3%-3%.
CN201711416197.7A 2017-12-25 2017-12-25 A kind of degredation plastic film Pending CN107936417A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109082095A (en) * 2018-06-21 2018-12-25 福建满山红新材料科技有限公司 A kind of moisture absorption damp-proof plastic film for packaging
CN114276600A (en) * 2021-12-23 2022-04-05 南通宝加利新材料有限公司 Preparation method of degradable PE film

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101181678A (en) * 2007-10-26 2008-05-21 广东省生态环境与土壤研究所 Rare earth modified photocatalyst as well as degradable plastic film prepared thereby and preparation method thereof
US20090056209A1 (en) * 2007-08-28 2009-03-05 Epi Environmental Technologies (Nevada) Inc. Biodegradable agricultural film
CN102352064A (en) * 2011-07-06 2012-02-15 丁邦瑞 Dual-degradant additive for promoting photo oxidative degradation and biodegradation of polymer
CN106987045A (en) * 2017-05-18 2017-07-28 聂超 It is a kind of to trigger environmental protection macromolecule new material of multiple degrading and preparation method thereof
CN107434867A (en) * 2016-05-25 2017-12-05 鸿明环保科技股份有限公司 The degradable sheet material of novel low carbon and its product

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20090056209A1 (en) * 2007-08-28 2009-03-05 Epi Environmental Technologies (Nevada) Inc. Biodegradable agricultural film
CN101181678A (en) * 2007-10-26 2008-05-21 广东省生态环境与土壤研究所 Rare earth modified photocatalyst as well as degradable plastic film prepared thereby and preparation method thereof
CN102352064A (en) * 2011-07-06 2012-02-15 丁邦瑞 Dual-degradant additive for promoting photo oxidative degradation and biodegradation of polymer
CN107434867A (en) * 2016-05-25 2017-12-05 鸿明环保科技股份有限公司 The degradable sheet material of novel low carbon and its product
CN106987045A (en) * 2017-05-18 2017-07-28 聂超 It is a kind of to trigger environmental protection macromolecule new material of multiple degrading and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109082095A (en) * 2018-06-21 2018-12-25 福建满山红新材料科技有限公司 A kind of moisture absorption damp-proof plastic film for packaging
CN114276600A (en) * 2021-12-23 2022-04-05 南通宝加利新材料有限公司 Preparation method of degradable PE film

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Application publication date: 20180420