CN107931331A - A kind of production method of two roller cold rolling seamless steel of high accuracy - Google Patents

A kind of production method of two roller cold rolling seamless steel of high accuracy Download PDF

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Publication number
CN107931331A
CN107931331A CN201711203624.3A CN201711203624A CN107931331A CN 107931331 A CN107931331 A CN 107931331A CN 201711203624 A CN201711203624 A CN 201711203624A CN 107931331 A CN107931331 A CN 107931331A
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CN
China
Prior art keywords
cold rolling
steel
roller
seamless steel
high accuracy
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CN201711203624.3A
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Chinese (zh)
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CN107931331B (en
Inventor
李亚辉
成永庆
张艳军
成金永
陈亚洲
郗浩亮
杨辉
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Hebei jin'ao Precision Manufacturing Co.,Ltd.
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Hebei Province Gold Mysterious Pipe Co Ltd
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Priority to CN201711203624.3A priority Critical patent/CN107931331B/en
Publication of CN107931331A publication Critical patent/CN107931331A/en
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Publication of CN107931331B publication Critical patent/CN107931331B/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B19/00Tube-rolling by rollers arranged outside the work and having their axes not perpendicular to the axis of the work
    • B21B19/02Tube-rolling by rollers arranged outside the work and having their axes not perpendicular to the axis of the work the axes of the rollers being arranged essentially diagonally to the axis of the work, e.g. "cross" tube-rolling ; Diescher mills, Stiefel disc piercers or Stiefel rotary piercers
    • B21B19/04Rolling basic material of solid, i.e. non-hollow, structure; Piercing, e.g. rotary piercing mills
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B27/00Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
    • B21B27/02Shape or construction of rolls
    • B21B27/024Rolls for bars, rods, rounds, tubes, wire or the like
    • B21B27/025Skew rolls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B45/00Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/004Heating the product
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B45/00Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/02Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
    • B21B45/0239Lubricating
    • B21B45/0242Lubricants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B45/00Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/02Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
    • B21B45/0269Cleaning
    • B21B45/0272Cleaning compositions

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Geometry (AREA)
  • Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)

Abstract

The invention discloses a kind of production method of two roller cold rolling seamless steel of high accuracy,The seamless steel pipe caliber φ 20mm produced by this method,More than wall thickness 2mm,Outside diameter,Id tolerance size range is within 0.02 0.04mm,Wherein this method includes heating steel billet,Hot-puncturing process,Cold-drawn finishing,Heat treatment,Pickling lubricates,The technological designs such as two roller cold rollings,Produce obtained two roller cold rolling seamless steel products and black making up the inner surface that three roller cold-rolled products produce by production technology characteristic,While the defects such as finish is low,By to traditional two roller mould for cold milling,Tube blank size,Product rolling mill practice,The redesign of equipment adjusting parameter,Two roller cold rollings are produced product size precision to be brought up in the range of 0.02 0.04mm by original >=0.1mm,Simplify with process,Process optimization,Production efficiency improves,Cost reduction and other effects.

Description

A kind of production method of two roller cold rolling seamless steel of high accuracy
Technical field
The present invention relates to metallurgical technology field, is specially a kind of production method of two roller cold rolling seamless steel of high accuracy.
Background technology
With the rapid development of Domestic Automotive Industry in recent years, automobile market competition.Seamless steel pipe is as life The raw material of auto parts and components are produced, steel pipe sizes precision, smoothness requirements are continuously improved in subsupplier man.Based on above-mentioned Development trend, seamless steel pipe process optimization, raising product quality are imperative.Two roller cold rolling seamless steels of country production work at present Skill is tube reducing in more than 20mm, subtracts wall and is controlled in 1-2mm, cogging lengthening coefficient between 2.2-2.6, the steel of this kind of technique productions Pipe reaction force is big, the dimensional accuracy of steel pipe within 0.1mm, three roller cold rolling seamless steel precision controllings it is of a relatively high Within 0.05mm;High tolerance size is produced in 0.02-0.04mm products, main production is:Steel billet sawing machine blanking → centering → hot-puncturing process is produced into hot-rolled tube billet(Hollow billet)→ hollow billet heat treatment → hollow billet crop end, section chamfering → acid Cold inspection mill → pickling, phosphatization, the roller cold rolling finished product of the roller cold rolling of saponification → bis- → oil removing → heat treatment → aligning → acid phospholeum → tri- are washed, And during by technique productions φ 20mm wall thickness 2mm above cold-rolled products, although tolerance dimension is qualified, because process characteristic is deposited It cannot meet customer need in the defects of interior surface blackening, brightless, slight pockmark, and the production technology is because be two passages Finish rolling, there are complex procedures, low production efficiency, the production cycle is long, processing charges is high the problems such as.
The content of the invention
In order to solve above-mentioned problems of the prior art, the present invention provides a kind of two roller cold roll seamless steel of high accuracy The production method of pipe, is rationally designed by device to hole shape, roller opening, middle thickness of pipe wall, outside diameter, lengthening coefficient etc., both met Two roller cold rolling dimensional accuracies are improved 0.02-0.04mm by the requirement of product endoporus roughness again.
To achieve the above object, it is provided by the invention lifting two roller cold rolling seamless steel production methods include heating steel billet, Technological design, the wherein process routes such as hot-puncturing process, cold-drawn finishing, heat treatment, pickling lubrication, two roller cold rollings are:Steel billet is sawed Bed blanking → centering → hot-puncturing process is produced into hot-rolled tube billet(Hollow billet)→ pickling it is cold inspection mill → pickling, phosphatization, saponification → Cold-drawn → heat treatment → aligning → crop end → two chamfers → pickling, phosphatization, the roller cold rolling of saponification → bis- production.
Seamless steel pipe caliber φ 20mm, more than the wall thickness 2mm of this method production, outside diameter, id tolerance size range exist Within 0.02-0.04mm, this method comprises the following steps:
The first step:Steel billet sawing machine blocks, and centering processing is carried out by puncher;
Second step:Heating of pipe blank carries out hot-puncturing process, bloom production into hollow billet;
3rd step:Preliminary pickling, through examining mill repair to enter lower a time;
4th step:Pickling, phosphatization, saponification process;
5th step:Steel pipe carries out preliminary cold-drawn finishing;
6th step:It is heat-treated after cold-drawn, reduces the hardness after steel pipe processing, reduce steel pipe tissue;
7th step:Cold rolling carries out straightening processing with pipe after heat treatment;
8th step:Cold rolling intermediate tube carries out crop end, and both ends carry out chamfered;
9th step:Cold rolling intermediate tube carries out sour phospholeum, lubricated
Tenth step:Finished product is produced using two-roll cold rolling mill, the roller opening size that wherein cold-rolling mill uses is according to mill product The middle specific roll of tube blank size, cold-rolling mill head revolution number, feed are adjusted when finished product rolls, and are adjusted by calculating Tube reducing wall thickness reducing amount during whole rolling, the control of rolling lengthening coefficient between 1.5-1.7mm;
11st step:Aligning, carries out steel pipe alignment processing using straightener, eliminates the bending situation produced in production process;
12nd step:Oil removing, steel pipe clean in except oil cylinder, remove steel pipe surfaces externally and internally greasy dirt, impurity;
13rd step:Immersion oil, after removing finish rolling greasy dirt, leaching antirust oil carries out antirust;
14th step:Examine, vortex, ultrasonic examination processing, check steel pipe surfaces externally and internally defect, micrometer, inside meter detection Tolerance dimension;
15th step:Qualified products packaging and storage.
Preferably, heating steel billet is divided into preheating zone, heating zone, 3rd area of soaking zone using walking beam furnace, to steel billet into Row Segmented heating, makes heating steel billet uniform, improves the efficiency of heating surface, and it is inclined that hollow billet surfaces externally and internally, wall thickness after perforating can be effectively ensured Difference, organize to obtain quality.
It is further preferred that preheating zone temperature range is 560oC-660oC, Heating Zone Temperature section are 1080oC~ 1160oC, soaking zone section are 1220oC-1270oC;According to heating various outer diameter steel billet, stepping furnace tap FREQUENCY CONTROL 25 ~ 40S/ branch, uses full-automatic 50 Mannesmann piercers of φ production hollow billet after heating steel billet tapping.
Preferably, sour cylinder sulphur acid strength is between 15%-25%, and below ferrous sulfate content 100g/L, temperature is in 40- 70oC;Phosphatization cylinder total acidity 25-37.5 drops, free acidity 1.5-2.5 drops, total acid free acid ratio is between 15-20, phosphatization cylinder Temperature is maintained at 65oC-75oC;Between saponification cylinder PH7.5-9.5, temperature is maintained at 70oC-85oC。
In the range of φ 20- φ 70mm produced by the invention, wall thickness 2-8mm, tolerance grade is high-precision in 0.02-0.04mm Two roller cold rolling seamless steels are spent, traditional φ 20mm wall thickness 2mm above heavy wall cold rolling seamless steels is changed and is opened by two roller cold rollings Base, then the technique produced by three roller cold rollings;So as to improve heavy caliber thick wall High Precision Cold seamless steel tube production efficiency, product Inner surface finish, realizes process simplification, process optimization, production efficiency raising, the purpose of cost reduction.
Brief description of the drawings
Fig. 1 is the structure size schematic diagram of cold-rolling mill roll in the present invention;
Fig. 2 is roller opening scale diagrams in the present invention.
Embodiment
A kind of production method of two roller cold rolling seamless steel of high accuracy of the present invention, the seamless steel pipe of this method production Caliber φ 20mm, more than wall thickness 2mm, within 0.02 ~ 0.04mm, its production stage is as follows for outside diameter, id tolerance size range:
The first step:Steel billet sawing machine blocks, and centering processing, centering φ 16- φ 18mm drill bits, punching are carried out by puncher Depth is handled in the range of 100-150mm by puncher centering, and the moment top that steel billet bites in perforation can be made accurate right Quasi- steel billet center, so as to reduce hollow billet eccentricity after perforation, reduces top and the direct Contact impact force of steel billet, Improve head lifetime.
Second step:Heating of pipe blank carries out hot-puncturing process, and bloom production is used walking beam furnace into hollow billet, heating steel billet It is divided into preheating zone(560oC-660oC), heating zone(1080oC-1160oC), 3rd area of soaking zone(1220oC-1270oC), to steel billet Segmented heating is carried out, makes heating steel billet uniform, improves the efficiency of heating surface;According to heating various outer diameter steel billet, stepping furnace tapping frequency Rate control uses full-automatic 50 Mannesmann piercers of φ production hollow billet after 25-40S/ branch, heating steel billet tapping.
3rd step:Preliminary pickling, through examining mill repair to enter lower a time(Use louvre blade or grinding wheel);
4th step:Pickling, phosphatization, saponification process, sour cylinder sulphur acid strength is between 15% ~ 25%, ferrous sulfate content 100g/L Hereinafter, temperature is in 40-70oC;Phosphatization cylinder total acidity 25-37.5 drops, free acidity 1.5-2.5 drops, total acid free acid ratio exist Between 15-20, phosphatization cylinder temperature is maintained at 65oC-75oC;Between saponification cylinder PH7.5-9.5, temperature is maintained at 70oC-85oC。
5th step:Steel pipe carries out preliminary cold-drawn finishing;
6th step:It is heat-treated after cold-drawn, reduces the hardness after steel pipe processing, reduce steel pipe tissue;
7th step:Cold rolling carries out straightening processing with pipe after heat treatment;
8th step:Cold rolling intermediate tube carries out crop end, and both ends carry out chamfered;
9th step:Cold rolling intermediate tube carries out sour phospholeum, lubricated, and processing method is same as above the 4th step.
Tenth step:Produce finished product using two-roll cold rolling mill, in the invention maximum feature used in production process mould, The design of device parameter etc.:
Produce roll used by two roller cold-rolled products to compare traditional roll, roll circumference profit is reduced after redesign With rate, roll circumference utilization rate is adjusted to 1/3 or so, radian is shown in Fig. 1 between 100 ° -150 °.
2. it is according to tube blank size among mill product to produce roll roller opening size used by two roller cold-rolled products Specific roll, roller opening size are more than the production middle pipe outside diameter 10mm-15mm of finished product, see Fig. 2.
3. cold-rolling mill head revolution number, feed are adjusted when finished product rolls, two roller cold-rolling equipment parameters ensure to roll Machine head turns round number >=80 time/h, in the range of the above of feed >=3.5mm/ time.
4. tube reducing wall thickness reducing amount when finished product is by calculating adjustment rolling, when mill product use middle pipe, diameter is more than Institute mill product outside diameter 10-15mm, wall thickness reducing amount control are controlled between 1.5-1.7mm in 0.5-1mm, rolling lengthening coefficient.
11st step:Aligning, carries out steel pipe alignment processing using straightener, eliminates the bending feelings produced in production process Condition.
12nd step:Oil removing, by being cleaned in except oil cylinder, removes steel pipe surfaces externally and internally greasy dirt, impurity;
13rd step:Immersion oil, after removing finish rolling greasy dirt, leaching antirust oil carries out antirust;
14th step:Examine, vortex, ultrasonic examination processing, check steel pipe surfaces externally and internally defect, micrometer, inside meter detection Tolerance dimension;
15th step:Qualified products packaging and storage.
Instinct invention, but do not limit the invention in any way are described in detail below with reference to instantiation.
Example one:
Produce 35#64*4.5*55 products in the present invention to produce according to aforementioned production method, through measuring outside diameter, internal diameter(mm)See below Table.
Table one
Table two
Example two
Our company produces 35#66.5*5 products, and product is produced according to foregoing invention process, through measuring outside diameter, internal diameter(mm) It see the table below.
Table one
Table two
Data can be seen that the invention produces two roller cold rolling seamless steels from two above example table, be entirely capable of meeting above-mentioned hair Outside diameter in bright method, tolerance in the range of 0.02 ~ 0.04mm of internal diameter, and production efficiency significantly improves, and endoporus roughness is bright Aobvious to improve, endoporus color is bright.

Claims (8)

1. a kind of production method of two roller cold rolling seamless steel of high accuracy, the seamless steel pipe caliber φ 20mm of this method production, wall Thick more than 2mm, outside diameter, id tolerance size range are within 0.02-0.04mm, it is characterised in that this method includes following step Suddenly:
The first step:Steel billet sawing machine blocks, and centering processing is carried out by puncher;
Second step:Heating of pipe blank carries out hot-puncturing process, bloom production into hollow billet;
3rd step:Preliminary pickling, through examining mill repair to enter lower a time;
4th step:Pickling, phosphatization, saponification process;
5th step:Steel pipe carries out preliminary cold-drawn finishing;
6th step:It is heat-treated after cold-drawn, reduces the hardness after steel pipe processing, reduce steel pipe tissue;
7th step:Cold rolling carries out straightening processing with pipe after heat treatment;
8th step:Cold rolling intermediate tube carries out crop end, and both ends carry out chamfered;
9th step:Cold rolling intermediate tube carries out sour phospholeum, lubricated
Tenth step:Finished product is produced using two-roll cold rolling mill;
11st step:Aligning, alignment processing is carried out using straightener to steel pipe;
12nd step:Oil removing, steel pipe carry out oil removal treatment in except oil cylinder;
13rd step:Immersion oil, after removing finish rolling greasy dirt, leaching antirust oil carries out antirust;
14th step:Examine, vortex, ultrasonic examination processing, check steel pipe surfaces externally and internally defect, micrometer, inside meter detection Tolerance dimension;
15th step:Qualified products packaging and storage.
A kind of 2. production method of two roller cold rolling seamless steel of high accuracy according to claim 1, it is characterised in that:
Second step:Perforated steel billit uses full-automatic temperature-controlling walking beam furnace when heating, and divides three-region type preheating, heating, soaking The preperforative heating work of hot rolling of steel billet is completed, the walking beam furnace efficiency of heating surface is high, homogeneous heating, after perforation being effectively ensured Hollow billet surfaces externally and internally, wall thickness deviation, the quality of tissue.
A kind of 3. production method of two roller cold rolling seamless steel of high accuracy according to claim 2, it is characterised in that:
Walking beam furnace is respectively 560 in the temperature that three-region type is preheated, heats, hankeredoC-660 oC、1080 oC -1160 oC With 1220 oC -1270 oC;According to heating various outer diameter steel billet, walking beam furnace taps FREQUENCY CONTROL in 25-40S/ branch, steel Full-automatic 50 Mannesmann piercers of φ production hollow billet is used after base heating tapping.
A kind of 4. production method of two roller cold rolling seamless steel of high accuracy according to claim 1, it is characterised in that:
4th step:Sour cylinder sulphur acid strength is between 15%-25% in acid cleaning process, below ferrous sulfate content 100g/L, temperature In 40-70 oC;Phosphatization cylinder total acidity 25-37.5 drops in parkerizing process, free acidity 1.5-2.5 drops, total acid free acid ratio exist Between 15-20, phosphatization cylinder temperature is maintained at 65 oC -75 oC;In saponification process between saponification cylinder PH7.5-9.5, temperature is maintained at 70 oC ~85 oC
A kind of 5. production method of two roller cold rolling seamless steel of high accuracy according to claim 1, it is characterised in that:
The roll circumference utilization rate of the two-roll cold rolling mill is 1/3 or so, and radian is 100o-150oBetween.
A kind of 6. production method of two roller cold rolling seamless steel of high accuracy according to claim 1, it is characterised in that:
The roller opening size of the two-roll cold rolling mill is more than the middle pipe outside diameter 10mm-15mm of production finished product.
A kind of 7. production method of two roller cold rolling seamless steel of high accuracy according to claim 1, it is characterised in that:
The two-roll cold rolling mill head turns round number >=80 time/h, feed >=more than 3.5mm/ times.
A kind of 8. production method of two roller cold rolling seamless steel of high accuracy according to claim 1, it is characterised in that:
Tube reducing wall thickness reducing amount during by calculating adjustment rolling, when rolled steel tube, use middle pipe, and diameter is more than institute's rolled steel tube Outside diameter 10-15mm, wall thickness reducing amount control are controlled between 1.5-1.7mm in 0.5-1mm, rolling lengthening coefficient.
CN201711203624.3A 2017-11-27 2017-11-27 A kind of production method of two roller cold rolling seamless steel of high-precision Active CN107931331B (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109158435A (en) * 2018-08-08 2019-01-08 浙江辛子精工机械股份有限公司 A kind of cold tube rolling outer surface oil-scraping device
CN111043408A (en) * 2019-11-08 2020-04-21 安徽莱鑫精密特种钢管有限公司 Novel stainless steel seamless steel pipe
CN111283011A (en) * 2020-03-09 2020-06-16 河北金奥管业有限公司 Production method of seamless steel tube of automobile steering column
CN111420993A (en) * 2020-04-07 2020-07-17 浙江巨龙钢业有限公司 High-precision seamless steel tube cold rolling equipment and machining method thereof
CN112276479A (en) * 2020-09-07 2021-01-29 湖北隐冠轴业有限公司 Rough machining process for main shaft of air-conditioning compressor of new energy automobile
CN113245369A (en) * 2021-05-19 2021-08-13 张家港保税区恒隆钢管有限公司 Manufacturing process of pipe for PMMA reactor
CN113441553A (en) * 2021-06-30 2021-09-28 北京科技大学 Seamless pipe and cold rolling method thereof
CN113600637A (en) * 2021-06-30 2021-11-05 北京科技大学 Seamless steel pipe and preparation method thereof
WO2022095272A1 (en) * 2020-11-04 2022-05-12 太原科技大学 Method for preparing high-performance and difficult-to-deform metal precision seamless tube

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US20030056558A1 (en) * 2001-09-21 2003-03-27 Hidetoshi Nishi Continuous pickling and cold-rolling equipment and operating method thereof
CN103921066A (en) * 2014-03-18 2014-07-16 泰州双羊精密无缝钢管有限公司 Method for manufacturing seamless steel pipes for shock absorbers
CN106825106A (en) * 2017-02-22 2017-06-13 长葛市鸣机械有限公司 The technique of thin-walled hot rolled seamless steel tube in a kind of double-core axle two-roller skew-rolling production
CN107214480A (en) * 2017-07-20 2017-09-29 繁昌县华特机械制造有限公司 A kind of manufacture method of large-caliber stainless steel seamless pipe
CN107338397A (en) * 2017-07-19 2017-11-10 浙江义腾特种钢管有限公司 A kind of direct fuel injection machine high pressure oil rail gapless stainless steel tube production technology

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US20030056558A1 (en) * 2001-09-21 2003-03-27 Hidetoshi Nishi Continuous pickling and cold-rolling equipment and operating method thereof
CN103921066A (en) * 2014-03-18 2014-07-16 泰州双羊精密无缝钢管有限公司 Method for manufacturing seamless steel pipes for shock absorbers
CN106825106A (en) * 2017-02-22 2017-06-13 长葛市鸣机械有限公司 The technique of thin-walled hot rolled seamless steel tube in a kind of double-core axle two-roller skew-rolling production
CN107338397A (en) * 2017-07-19 2017-11-10 浙江义腾特种钢管有限公司 A kind of direct fuel injection machine high pressure oil rail gapless stainless steel tube production technology
CN107214480A (en) * 2017-07-20 2017-09-29 繁昌县华特机械制造有限公司 A kind of manufacture method of large-caliber stainless steel seamless pipe

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109158435A (en) * 2018-08-08 2019-01-08 浙江辛子精工机械股份有限公司 A kind of cold tube rolling outer surface oil-scraping device
CN111043408A (en) * 2019-11-08 2020-04-21 安徽莱鑫精密特种钢管有限公司 Novel stainless steel seamless steel pipe
CN111283011A (en) * 2020-03-09 2020-06-16 河北金奥管业有限公司 Production method of seamless steel tube of automobile steering column
CN111420993B (en) * 2020-04-07 2021-09-17 浙江巨龙钢业有限公司 High-precision seamless steel tube cold rolling equipment and machining method thereof
CN111420993A (en) * 2020-04-07 2020-07-17 浙江巨龙钢业有限公司 High-precision seamless steel tube cold rolling equipment and machining method thereof
CN112276479A (en) * 2020-09-07 2021-01-29 湖北隐冠轴业有限公司 Rough machining process for main shaft of air-conditioning compressor of new energy automobile
WO2022095272A1 (en) * 2020-11-04 2022-05-12 太原科技大学 Method for preparing high-performance and difficult-to-deform metal precision seamless tube
CN113245369A (en) * 2021-05-19 2021-08-13 张家港保税区恒隆钢管有限公司 Manufacturing process of pipe for PMMA reactor
CN113245369B (en) * 2021-05-19 2022-08-09 张家港保税区亚鑫精密制管有限公司 Manufacturing process of pipe for PMMA reactor
CN113441553A (en) * 2021-06-30 2021-09-28 北京科技大学 Seamless pipe and cold rolling method thereof
CN113600637A (en) * 2021-06-30 2021-11-05 北京科技大学 Seamless steel pipe and preparation method thereof
CN113600637B (en) * 2021-06-30 2022-04-15 北京科技大学 Seamless steel pipe and preparation method thereof
CN113441553B (en) * 2021-06-30 2022-07-22 北京科技大学 Seamless pipe and cold rolling method thereof

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